Clean N Easy BC36 Mould & Mildew ITW AAMTech Australia
Chemwatch Hazard Alert Code: 3
Chemwatch: 8551-39
Issue Date: 27/06/2017
Version No: 3.1.1.1
Print Date: 03/08/2017
Safety Data Sheet according to WHS and ADG requirements
S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING Product Identifier Product name Synonyms Proper shipping name Other means of identification
Clean N Easy BC36 Mould & Mildew Not Available HYPOCHLORITE SOLUTION Not Available
Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses
Mould and mildew killer.
Details of the supplier of the safety data sheet Registered company name Address
ITW AAMTech Australia 1-9 Nina Link, Dandenong South VIC 3175 Australia
Telephone
1800 177 989
Fax
1800 308 556
Website Email
www.aamtech.com.au
[email protected]
Emergency telephone number Association / Organisation
Not Available
Emergency telephone numbers
1800 039 008
Other emergency telephone numbers
0800 2436 2255
SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code. Poisons Schedule Classification
[1]
Legend:
S5 Metal Corrosion Category 1, Skin Corrosion/Irritation Category 1B, Serious Eye Damage Category 1 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
Hazard pictogram(s)
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Clean N Easy BC36 Mould & Mildew
SIGNAL WORD
Issue Date: 27/06/2017 Print Date: 03/08/2017
DANGER
Hazard statement(s) H290
May be corrosive to metals.
H314
Causes severe skin burns and eye damage.
AUH031
Contact with acid liberates toxic gas
Precautionary statement(s) Prevention P101
If medical advice is needed, have product container or label at hand.
P102
Keep out of reach of children.
P103
Read label before use.
P260
Do not breathe dust/fume/gas/mist/vapours/spray.
Precautionary statement(s) Response P301+P330+P331
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310
Immediately call a POISON CENTER or doctor/physician.
Precautionary statement(s) Storage P405
Store locked up.
Precautionary statement(s) Disposal P501
Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures
Mixtures CAS No
%[weight]
Name
7681-52-9
<10
sodium hypochlorite
balance
non hazardous ingredients including
7732-18-5
water
SECTION 4 FIRST AID MEASURES Description of first aid measures
Eye Contact
Skin Contact
Inhalation
If this product comes in contact with the eyes: Immediately hold eyelids apart and flush the eye continuously with running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes. Transport to hospital or doctor without delay. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes or combustion products are inhaled remove from contaminated area. Lay patient down. Keep warm and rested. Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
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Transport to hospital, or doctor. Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema. Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs). As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested. Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered. This must definitely be left to a doctor or person authorised by him/her. (ICSC13719) For advice, contact a Poisons Information Centre or a doctor at once. Urgent hospital treatment is likely to be needed. If swallowed do NOT induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. Observe the patient carefully. Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. Transport to hospital or doctor without delay.
Ingestion
Indication of any immediate medical attention and special treatment needed For acute or repeated exposures to hypochlorite solutions: Release of small amounts of hypochlorous acid and acid gases from the stomach following ingestion, is usually too low to cause damage but may be irritating to mucous membranes. Buffering with antacid may be helpful if discomfort is evident. Evaluate as potential caustic exposure. Decontaminate skin and eyes with copious saline irrigation. Check exposed eyes for corneal abrasions with fluorescein staining. Emesis or lavage and catharsis may be indicated for mild caustic exposure. Chlorine exposures require evaluation of acid/base and respiratory status. Inhalation of vapours or mists may result in pulmonary oedema. ELLENHORN and BARCELOUX: Medical Toxicology.
SECTION 5 FIREFIGHTING MEASURES Extinguishing media Water spray or fog. Foam. Dry chemical powder. BCF (where regulations permit).
Special hazards arising from the substrate or mixture Fire Incompatibility
None known.
Advice for firefighters Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course. Use fire fighting procedures suitable for surrounding area.
Fire Fighting
Fire/Explosion Hazard
HAZCHEM
Non combustible. Not considered to be a significant fire risk. Expansion or decomposition on heating may lead to violent rupture of containers. Decomposes on heating and may produce toxic fumes of carbon monoxide (CO). Decomposition may produce toxic fumes of: , hydrogen chloride May emit corrosive fumes. 2X
SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures See section 8
Environmental precautions See section 12
Methods and material for containment and cleaning up Continued...
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Clean N Easy BC36 Mould & Mildew
Minor Spills
Clean up all spills immediately. Avoid breathing vapours and contact with skin and eyes. Control personal contact with the substance, by using protective equipment. Contain and absorb spill with sand, earth, inert material or vermiculite.
Major Spills
Clear area of personnel and move upwind. Alert Fire Brigade and tell them location and nature of hazard. Wear full body protective clothing with breathing apparatus. Prevent, by any means available, spillage from entering drains or water course.
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE Precautions for safe handling
Safe handling
Other information
DO NOT allow clothing wet with material to stay in contact with skin Limit all unnecessary personal contact. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Avoid contact with incompatible materials. Store in original containers. Keep containers securely sealed. Store in a cool, dry, well-ventilated area. Store away from incompatible materials and foodstuff containers.
Conditions for safe storage, including any incompatibilities
Suitable container
Storage incompatibility
Lined metal can, lined metal pail/ can. Plastic pail. Polyliner drum. Packing as recommended by manufacturer. Contact with acids produces toxic fumes of chlorine Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Not Available EMERGENCY LIMITS Ingredient
Material name
TEEL-1
TEEL-2
TEEL-3
sodium hypochlorite
Sodium hypochlorite pentahydrate
13 mg/m3
140 mg/m3
290 mg/m3
sodium hypochlorite
Sodium hypochlorite
2 mg/m3
54 mg/m3
630 mg/m3
Ingredient
Original IDLH
Revised IDLH
sodium hypochlorite
Not Available
Not Available
water
Not Available
Not Available
Exposure controls
Appropriate engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment.
Personal protection
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Clean N Easy BC36 Mould & Mildew
Eye and face protection Skin protection
Chemical goggles. Full face shield may be required for supplementary but never for primary protection of eyes. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. See Hand protection below Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
Hands/feet protection Body protection
Other protection
Thermal hazards
See Other protection below Overalls. PVC Apron. PVC protective suit may be required if exposure severe. Eyewash unit. Not Available
Respiratory protection Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance
Physical state
Clear yellow alkaline liquid with chlorine odour; mixes with water. Relative density (Water = 1)
Liquid
1.2
Odour
Not Available
Partition coefficient n-octanol / water
Not Available
Odour threshold
Not Available
Auto-ignition temperature (°C)
Not Available
pH (as supplied)
Not Available
Decomposition temperature
Not Available
Melting point / freezing point (°C)
Not Available
Viscosity (cSt)
Not Available
Initial boiling point and boiling range (°C)
Molecular weight (g/mol)
100
Not Applicable
Flash point (°C)
Not Applicable
Taste
Not Available
Evaporation rate
same as water
Explosive properties
Not Available
Flammability
Not Applicable
Oxidising properties
Not Available
Upper Explosive Limit (%)
Not Applicable
Surface Tension (dyn/cm or mN/m)
Not Available
Lower Explosive Limit (%)
Not Applicable
Volatile Component (%vol)
Not Available
Vapour pressure (kPa)
Not Available
Gas group
Not Available
Solubility in water (g/L) Vapour density (Air = 1)
Miscible
pH as a solution (1%)
Not Available
VOC g/L
12.5 Not Available
SECTION 10 STABILITY AND REACTIVITY Reactivity Chemical stability
See section 7 Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur.
Possibility of hazardous reactions
See section 7
Conditions to avoid
See section 7
Incompatible materials
See section 7
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Hazardous decomposition products
Print Date: 03/08/2017
See section 5
SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects
Inhaled
Ingestion
Skin Contact
Eye
Chronic
Clean N Easy BC36 Mould & Mildew
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the course of normal handling, may be damaging to the health of the individual. There is some evidence to suggest that the material can cause respiratory irritation in some persons. The body's response to such irritation can cause further lung damage. The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion. Accidental ingestion of the material may be damaging to the health of the individual. Swallowing hypochlorites may cause burning in the mouth and throat, abdominal cramps, nausea, vomiting, diarrhea, pain, inflammation f the mouth and stomach, low blood pressure, shock, confusion and delirium. Severe poisonings may lead to convulsion, coma and death. Hypochlorites irritate the mouth, throat and stomach; the hypochlorous acid liberated in the stomach can cause tearing of the stomach wall, with bleeding, and can be fatal. The material can produce chemical burns following direct contact with the skin. Open cuts, abraded or irritated skin should not be exposed to this material Contact may cause severe itchiness, skin lesions and mild eczema. Exudation and sloughing may occur. Two patients were reported with chronic allergic dermatitis of the hand, related to sensitization to sodium hypochlorite as the active component of laundry bleach. Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. The material can produce chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating. 51r41l Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue. Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure. There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
TOXICITY
IRRITATION
Not Available
Not Available
TOXICITY
Oral (rat) LD50: >237 mg/kg
IRRITATION [1]
Eye (rabbit): 10 mg - moderate
sodium hypochlorite Eye (rabbit): 100 mg - moderate Skin (rabbit): 500 mg/24h-moderate
water
Legend:
SODIUM HYPOCHLORITE
WATER
TOXICITY
IRRITATION
Not Available
Not Available
1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without eosinophilia. Hypochlorite salts are classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. Hypochlorite salts are extremely corrosive and can cause severe damage to the eyes and skin. A number of skin cancers have been observed in mice, when applied to their skin. as sodium hypochlorite pentahydrate No significant acute toxicological data identified in literature search.
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Acute Toxicity
Carcinogenicity
Skin Irritation/Corrosion
Reproductivity
Serious Eye Damage/Irritation
STOT - Single Exposure
Respiratory or Skin sensitisation
STOT - Repeated Exposure
Mutagenicity
Aspiration Hazard Legend:
– Data available but does not fill the criteria for classification – Data available to make classification – Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION Toxicity Clean N Easy BC36 Mould & Mildew
sodium hypochlorite
water
Legend:
ENDPOINT
TEST DURATION (HR)
SPECIES
VALUE
SOURCE
Not Available
Not Available
Not Available
Not Available
Not Available
ENDPOINT
TEST DURATION (HR)
SPECIES
VALUE
SOURCE
LC50
96
Fish
0.032mg/L
4
EC50
48
Crustacea
0.026mg/L
2
EC50
72
Algae or other aquatic plants
0.0183mg/L
2
NOEC
72
Algae or other aquatic plants
0.0054mg/L
2
ENDPOINT
TEST DURATION (HR)
SPECIES
VALUE
SOURCE
Not Available
Not Available
Not Available
Not Available
Not Available
Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Very toxic to aquatic organisms. DO NOT discharge into sewer or waterways.
Persistence and degradability Ingredient
Persistence: Water/Soil
Persistence: Air
water
LOW
LOW
Bioaccumulative potential Ingredient
Bioaccumulation
water
LOW (LogKOW = -1.38)
Mobility in soil Ingredient
Mobility
water
LOW (KOC = 14.3)
SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Product / Packaging disposal
Recycle wherever possible or consult manufacturer for recycling options. Consult State Land Waste Management Authority for disposal. Bury residue in an authorised landfill. Recycle containers if possible, or dispose of in an authorised landfill.
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SECTION 14 TRANSPORT INFORMATION Labels Required
Marine Pollutant HAZCHEM
NO 2X
Land transport (ADG) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazard Special precautions for user
1791 HYPOCHLORITE SOLUTION Class
8
Subrisk
Not Applicable
III Not Applicable Special provisions
223
Limited quantity
5L
Air transport (ICAO-IATA / DGR) UN number UN proper shipping name
1791 Hypochlorite solution ICAO/IATA Class
Transport hazard class(es)
Packing group Environmental hazard
Special precautions for user
8
ICAO / IATA Subrisk
Not Applicable
ERG Code
8L
III Not Applicable Special provisions
A3 A803
Cargo Only Packing Instructions
856
Cargo Only Maximum Qty / Pack
60 L
Passenger and Cargo Packing Instructions
852
Passenger and Cargo Maximum Qty / Pack
5L
Passenger and Cargo Limited Quantity Packing Instructions
Y841
Passenger and Cargo Limited Maximum Qty / Pack
1L
Sea transport (IMDG-Code / GGVSee) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazard
Special precautions for user
1791 HYPOCHLORITE SOLUTION IMDG Class
8
IMDG Subrisk
Not Applicable
III Marine Pollutant EMS Number
F-A , S-B
Special provisions
223
Limited Quantities
5L
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Transport in bulk according to Annex II of MARPOL and the IBC code Source
Product name
Pollution Category
Ship Type
IMO MARPOL (Annex II) - List of Noxious Liquid Substances Carried in Bulk
Sodium hypochlorite solution (15% or less)
Y
2
SECTION 15 REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture SODIUM HYPOCHLORITE(7681-52-9) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Hazardous Substances Information System - Consolidated Lists Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) - Agents Classified by the IARC Monographs
WATER(7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS) National Inventory
Status
Australia - AICS
Y
Canada - DSL
Y
Canada - NDSL
N (water; sodium hypochlorite)
China - IECSC
Y
Europe - EINEC / ELINCS / NLP
Y
Japan - ENCS
Y
Korea - KECI
Y
New Zealand - NZIoC
Y
Philippines - PICCS
Y
USA - TSCA
Y
Legend:
Y = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION Other information Ingredients with multiple cas numbers Name
CAS No
sodium hypochlorite
7681-52-9, 10022-70-5
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
end of SDS
