Correction to “Self-Regeneration of Chirality with l-Cysteine through 1

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Addition/Correction Cite This: J. Org. Chem. XXXX, XXX, XXX−XXX

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Correction to “Self-Regeneration of Chirality with L‑Cysteine through 1,3-Dipolar Cycloadditions between Diazoalkanes and Enantiomerically Pure Thiazolines: Experimental and Computational Studies” J. Gracia-Vitoria, I. Osante,* C. Cativiela,* P. Merino,* and T. Tejero J. Org. Chem. 2018, 83 (7), 3960−3972. DOI: 10.1021/acs.joc.8b00312

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e have inadvertently misassigned the diastereotopic faces discussed in the manuscript. Thoughout the manuscript, the diastereotopic face Si−Si should be reassigned as Re−Si and the diastereotopic face Re−Re should be reassigned as Si−Re. Pages 3963, 3964 and 3965: Si−Si should be changed to Re−Si and Re−Re should be changed to Si−Re in the text as well as in Scheme 5 and Figures 6 and 8. For clarity, we enclose Scheme 5 and Figures 6 and 8 with the correct nomenclature: Scheme 5. Calculated Channels for the Reaction between 8a−c and D1−D6a

a

The endo approach is defined with respect to R1.

© XXXX American Chemical Society

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DOI: 10.1021/acs.joc.8b01135 J. Org. Chem. XXXX, XXX, XXX−XXX

The Journal of Organic Chemistry

Addition/Correction

Figure 6. Global electronic density transfer (GEDT) calculated at the M06-2X/6-311+G(d,p)/PCM = THF//M06-2X/6-31+G(d,p) level of theory for the reactions between 8a−c and D1−D6.

Figure 8. Energy barriers (M06-2X/6-311+G(d,p)/PCM = THF// M06-2X/6-31+G(d,p)) for the reactions between 8a−c and D1−D6.

B

DOI: 10.1021/acs.joc.8b01135 J. Org. Chem. XXXX, XXX, XXX−XXX