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233RD ACS NATIONAL MEETING CHICAGO, March 25-29
THE COLD AND WINDY but architects ally beautiful city of Chicago will set the scene for the American Chemical Society's 233rd national meeting. The ACS president, 28 technical divisions, one secretariat, and three committees will host the original programming in 682 half-day oral sessions and 96 poster sessions. More than 9,400 papers will be presented. One overarching theme selected by ACS President Katie Hunt and the Committee on Divisional Activities is "Sustainability of Energy, Food, and Water." This program consists of 47 sessions contributed by MEETING & EXPOSITION INFORMATION ONLINE Access up-to-date meeting details and the official version of the technical program on the attendee website at chemistry.org/meetings/chicago2007 This website will be updated as the meeting nears and includes Registra tion, Housing, Technical Programming, Exposition, Workshops, and Social & Special Events among other activities. Because some locations may change after C&EN's press time, be sure to pick up a program on-site during the meeting.
numerous divisions. Other symposia and events include "Sustainability and Chem istry: Tomorrow's Challenge for Today's Students" and presentation of Student Affiliates ACS Chapter Awards. This year's ACS national awards dinner and ceremony will be held on Tuesday evening, March 27. George M. Whitesides will deliver the Priestley Medal Address at this event; other winners will deliver their addresses throughout the meeting. Special and social events, professional development programming, exhibitor workshops, short courses, C8cEN-Chemjobs Career Fair activities, and student ac tivities will also compete for your time and attention. The exposition will feature more than 250 exhibiting companies in more than 500 booths showcasing the firms' ser vices; instruments; publications; and sci entific software and computer hardware; as well as chromatographic, lab, and safety equipment in McCormick Place Lakeside Hall D from Monday morning through 1 PM on Wednesday.
REGISTRATION EARLY REGISTRATION. Early registra tion for the national meeting closed on March 2, and registrations or payments WWW.CEN-0NLINE.ORG
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received after March 2 will be processed at standard registration rates. Attendees who registered by March 2 should receive their badge credentials in the mail before the meeting. International registrants and early registrants who do not receive their badge credentials before the meeting must pick them up at any ACS Attendee Regis tration location during the meeting. Please REGISTRATION CATEGORY
STANDARD ON-SITE FEE
MEMBER ACS member or $385 society affiliate Postdoctoral member 385 Emeritus member 195 Retired member 195 50-year member No Fee Unemployed member No Fee (Dues waiver required) Precollege teacher 78 Graduate student, less than 138 postdoctoral Undergraduate student 78 One-day registrant 195 NONMEMBER Chemical scientist $675 Postdoctoral registrant 675 Visitor: Nonchemical scientist or 385 chemical technician Precollege teacher 78 Graduate student, less than 320 postdoctoral Undergraduate student 160 One-day registrant 385 Guest of registrant3 35 EXPOSITION VISITORS Adult, exposition only $35 Student, exposition only 10 a Guest registration is restricted to a spouse or fam ily member of registered attendee having no affilia tion with the field of chemical science and who is not eligible to become an ACS member. Only one guest registration is allowed per registering attendee, and the guest registration must be completed and paid by the registering attendee at time of original registration.
TECHNICAL PROGRAM
HOUSING & T R A N S P O R T A T I O N FOR THE CHICAGO MEETING Limited housing assistance wiii be avail able through March 16 on the attendee website at chemistry.org/meetings/ chicago2007. Find the most up-to-date hotel details, local maps, transportation advice, and ACS shuttle routes.
bring your e-mail confirmation for faster processing. STANDARD & ON-SITE REGISTRATION.
Standard registration fees are in effect between March 3 and March 23. Register online at chemistry.org/meetings/national/ registration.html anytime before the meet ing ends on the afternoon of March 23. A valid membership number must be entered during registration to register as a member and receive your ACS member discount on registration fees. Attendees who register after March 2 must pick up their badge credentials at any ACS Attendee Registra tion location during the meeting. Please bring your e-mail confirmation for faster processing. In Chicago, attendees can pick up their badge credentials or complete a new reg istration using credit card, cash, check, or money order at the main ACS Attendee Registration location (McCormick Place, Lakeside Hall E) on Saturday, 3 to 6 PM; Sunday, 7:30 AM to 8 PM; Monday to Wednesday, 7:30 AM to 6 PM; and Thurs day, 7:30 AM to 1 PM. A satellite location will also be available for attendees who wish to pick up their badge credentials or com plete new registrations with credit cards only (Hyatt Regency Chicago, Grand Ball room Registration) on Saturday, 3 to 6 PM; and Sunday to Wednesday, 7:30 AM to 9 PM.
SOCIAL AND SPECIAL EVENTS MANY SOCIAL and special events will be held by a variety of event organizers during the meeting. Event participation is open to all interested registrants. Some events require that a ticket be purchased in order to participate. Each of the following events is coded to indicate what is required to par ticipate: T—ticket or registration required; NT—sponsored, no ticket or registration required; COD—payment due based on in dividual consumption at event.
HOW TO PURCHASE TICKETS. Event tickets can be purchased through ACS At tendee Registration online until March 28 or on-site between March 24 and 28. At tendees who purchase tickets after March 2 will need to pick up their tickets at any ACS Attendee Registration location dur ing the meeting. All tickets are available on a first-come, first-sold basis, and ticket sales for specific events will close 24 hours prior to the event. Some event organizers may offer a limited number of tickets for sale at the event if they are still available. Cancellations or refund requests must be made by March 22 in ac cordance with the ACS Social Event Can cellation Policy at chemistry.org/meetings/ national/registration.html.
SATURDAY, M A R C H 2 4
9 AM t o 5 PM
McCormick Place, Lakeside Hall D outside Exposition Graduate School Recruiters Tea for Un dergraduate Students/NT 10:30 AM t o noon
Westin Michigan Ave., Wellington Room CHED High School/College Interface Luncheon/Ticket No. SE-02/$28 Noon t o 1:30 PM
McCormick Place, Room S100A PRES Sustainability of Energy, Food & Water Reception/NT 4:30 to 6 PM
McCormick Place, Room S100A Younger Chemist Committee Open Meet ing & Reception/NT 4:30 to 6:30 PM
Hyatt Regency Chicago, Gold Coast Room
Chemistry in Action: It's Easy Being Green Community Outreach Project for Upper Elementary & Middle School Students/NT 11 AM to 1PM
Town Hall Meeting To Meet Nominees for ACS President-Elect 2 0 0 8 / N T 4:45 to 5:45 PM
Notebaert Nature Museum, 2430 North Cannon Dr.
Sheraton Chicago, Sheraton Ballrooms II 8c III
Committee on the Advancement of Women Chemists (COACh) Reception/ NT 5 t o 7 PM
Committee on Minority Affairs Social Hour/NT 5 to 7 PM
Sheraton Chicago, Missouri Room
Westin Michigan Ave., Governors Room CHED Social Hour & Dinner/Ticket No. SE-01/$50 6:30 to 9:30 PM
Harry Caray's Restaurant, 33 West Kinzie St.
GEOC Social Hour/NT 5 to 6 PM
Chicago Marriott, Chicago Ballroom F Macalester College Alumni Reception in Honor of A. Truman Schwartz/NT 5:30 to 7 PM
Hyatt Regency Chicago, Grand Β SUNDAY, M A R C H 2 5 Chemjobs Career Fair/T 8 AM to 5:30 PM
McCormick Place, North Hall Β
International Activities Committee & USNC Reception for International At tendees/NT 5:30 t o 7:30 PM
Sheraton Chicago, Superior Room Undergraduate Students Hospitality Center/NT 8 AM t o 5 PM
Westin Michigan Ave., Wellington Room CHED High School Teachers Program/T 8:30 AM t o 5 PM
Chinese American Chemical Society Din ner/Ticket No. SE-04/$27 5:30 t o 9:30 PM
House of Fortune, 2407 South Wentworth Ave.
McCormick Place, Room N228
District V Councilor Caucus/NT 6 t o 7 PM
Places & Spaces: Mapping Science Ex hibit/NT
Sheraton Chicago, Mississippi Room
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District IV Councilor Caucus/NT 6 t o 7 PM Sheraton Chicago, Ohio Room
ORGN Social Hour & Poster Session/NT 8 t o 10 PM Hyatt Regency Chicago, Riverside Center
Western Councilor Caucus/NT 6 t o 7 PM Sheraton Chicago, Michigan Room Β
Undergraduate Students Social Hour/ NT 8:30 t o 11:30 PM McCormick Place, Room S100 B/C
Middle Atlantic Councilor Caucus/NT 6 t o 7 PM Sheraton Chicago, Huron Room District II Councilor Caucus/NT 6 t o 7 PM Sheraton Chicago, Ontario Room Iowa State University-Chemistry Alumni & Friends Social Hour/NT 6 t o 7:30 PM Chicago Marriott, Chicago Ballroom A/B POLY Social Hour & Poster Session/NT 6 t o 8 PM Hyatt Regency Chicago, Riverside Center TECH National Chemical Technician Award Dinner/Ticket No. SE-03/$65 6 t o 9:30 PM Maggiano's Little Italy, 516 North Clark St. Student Affiliates ACS Chapter Awards/ NT 7 t o 8:30 PM McCormick Place, Room S100A MEDI Social Hour & Poster Session/NT 7 to 9 PM Hyatt Regency Chicago, Riverside Center I NOR Social Hour & Poster Session/NT 7 to 10 PM Hyatt Regency Chicago, Riverside Center First-Time-Attendee Orientation & Re ception/Ticket No. SE-05/Free 7:30 t o 9 PM McCormick Place, Lakeside Hall D CHED Social Hour & Poster Session/NT 7:30 to 9 PM Hyatt Regency Chicago, Riverside Center
SPECIAL & SOCIAL EVENTS are continually updated on the attendee website at chemistry.org/meetings/ chicago2007.
MONDAY, M A R C H 2 6 Women in Industry Breakfast/Ticket No. SE-07 (regular)/$30 & Ticket No. SE-08 (student)/$17 7:30 to 9 AM Sheraton Chicago, Chicago Ballroom X
Purdue University-Chemistry Alumni Luncheon/Ticket No. SE-13/$10 Noon t o 1:30 PM McCormick Center, Room E266 Corporation Associates Awards Lunch eon/Ticket No. S E - l l / $ 3 0 12:30 t o 1:30 PM Hyatt Regency Chicago, Grand D North CHED Social Hour & Poster Session/NT 2 t o 4 PM Hyatt Regency Chicago, Riverside Center
Chemjobs Career Fair/T 8 AM t o 5:30 PM McCormick Place, North Hall Β
Afternoon Treats in the Exposition sponsored by ACS 2007 Member-Get-AMember Campaign and ACS Meetings & Expositions/Ticket in your Registration Credentials/Free 3 t o 4:30 PM McCormick Place, Lakeside Hall D
Undergraduate Students Hospitality Center/NT 8 AM t o 5 PM Westin Michigan Ave., Wellington Room
University of Wisconsin Alumni & Friends Social Hour/NT 4 t o 6 PM Hyatt Regency Chicago, Gold Coast Room
Graduate School Recruiting Breakfast for Undergraduate Students/NT 8 t o 10 AM Westin Michigan Ave., Wellington Room
POLY Excellence in Graduate Polymer Research Reception/NT 5 t o 6 PM McCormick Place, Room E258
ACS Exposition/T 9 AM t o 5 PM McCormick Place, Lakeside Hall D
University of Illinois Alumni & Friends Reception/NT 5 t o 8 PM Intercontinental Chicago, King Arthur Court
Places & Spaces: Mapping Science Ex hibit/NT 9 AM t o 5 PM McCormick Place, Lakeside Hall D outside Exposition CHED Social Hour & Poster Session/NT 11 AM t o 1 PM Hyatt Regency Chicago, Riverside Center National Science Foundation Town Hall Meeting/NT 11 AM t o 2 PM McCormick Place, Room S100 B/C
PRF/Research Corporation Reception in Honor of the 2007 Recipient of the ACS Award for Research at an Undergraduate Institution/NT 5:30 t o 7:30 PM Sheraton Chicago, Chicago Ballroom X University of Northern Iowa Alumni So cial Hour/NT 5:30 t o 7:30 PM Hyatt Regency Chicago, Plaza Room A
Committee on Minority Affairs Reception & Luncheon/Ticket No. SE-09/$45 11:30 AM t o 1:30 PM Sheraton Chicago, Chicago Ballroom X
Northwestern University Alumni & Friends Reception/NT 5:30 t o 7:30 PM Hyatt Regency Chicago, Columbus Room H
PRES Sustainability Luncheon/Ticket No. SE-10/$20 11:45 AM t o 1:15 PM McCormick Place, Room E258
University of Cincinnati Reception/NT 5:30 t o 7:30 PM Chicago Marriott, Purdue/Wisconsin Rooms
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TECHNICAL PROGRAM
POLY/PMSE Awards Reception/NT 5:30 t o 8 PM Hyatt Regency Chicago, Grand D North
8 t o 10 PM Hyatt Regency Chicago, Riverside Center
TUESDAY, M A R C H 2 7 Corporation Associates Reception for Undergraduate Students/NT 6 t o 7:30 PM Westin Michigan Ave., Cotillion Ballroom COLL Social Hour & Poster Session/NT 6 t o 8 PM Sheraton Chicago, River Center Exhibit Hall lota Sigma Pi Alumni Social Hour/NT 6 t o 8 PM Hyatt Regency Chicago, Dusable Room Michigan Tech University Alumni Reception/NT 6 t o 8 PM Hyatt Regency Chicago, Columbus Hall A/B CARB Claude Hudson Award Dinner/ Ticket No. SE-27/$50 6 t o 9 PM University Club of Chicago, y6 East Monroe St. Grady-Stack Award for Interpreting Chemistry for the Public Reception/ Ticket No. SE-26/Free 6:30 t o 8 PM Art Institute of Chicago, i n South Michigan Ave. PHYS Elsevier's Ahmed Zewail Prize in Molecular Sciences Reception/NT 6:30 t o 8 PM Swissôtel Chicago, Engelberg Suite
University of Minnesota Alumni & Friends Breakfast/Ticket No. SE-14/$10 7:30 t o 9 AM McCormick Place, Room E258 Silver Circle & Retiree Breakfast/Ticket No. SE-15/$10 7:30 t o 9 AM Hyatt Regency Chicago, Columbus Hall A/B Cornell-Chemistry Sponsored Breakfast/NT 7:45 t o 9 AM McCormick Place, Room N136 Chemjobs Career Fair/T 8 AM t o 5:30 PM McCormick Place, North Hall Β
COLL Luncheon/Ticket No. SE-19/$30 Noon t o 1:45 PM McCormick Place, Room E258 Committee on Community Activities Re ception & Open Meeting/NT 1:30 to 3 PM Chicago Marriott, Iowa Room Division Officers' Caucus/NT 3:30 t o 5 PM Sheraton Chicago, Superior Room A Division Councilors' Caucus/NT 5 t o 6:30 PM Sheraton Chicago, Superior Room A CHED GSSPC Reception/NT 4:30 t o 6 PM McCormick Place, Room N140
ACS Exposition/T 9 AM t o 5 PM McCormick Place, Lakeside Hall D
GEOC Award Reception/NT 5to7PM Chicago Marriott, Northwestern/Ohio Rooms
Places & Spaces: Mapping Science Ex hibit/NT 9 AM t o 5 PM McCormick Place, Lakeside Hall D outside Exposition
Illinois State University-Chemistry Alumni Reception in Honor of Professor Cheryl Stevenson/NT 5 t o 7 PM Westin Michigan Ave., Michigan Room
Morning Treats in the Exposition spon sored by Nature Publishing Group/Tick et in your Registration Credentials/Free 10 t o 11:30 AM McCormick Place, Lakeside Hall D
University of California, Los AngelesChemistry & Biochemistry Social Event/ NT 5 t o 7 PM Hyatt Regency Chicago, Columbus Hall E/F
NUCL Social Hour/NT 6:30 t o 8:30 PM Hyatt Regency Chicago, Water Tower
Women Chemists Committee/Eli Lilly Travel Award Reception & Poster Ses sion/NT 11:30 AM t o noon Sheraton Chicago, Chicago Ballroom VI
University of Arizona-Chemistry Alumni 6 Friends Social Hour/NT 6:30 t o 8:30 PM Westin Michigan Ave., Buckingham Room
Alpha Chi Sigma Luncheon/Ticket No. SE-24/$30 11:30 AM t o 1:30 PM McCormick Place, Room N134
COMP Barry Honig's 65th Birthday Dinner/Ticket No. SE-12/$95 7 t o 9 PM Hyatt Regency Chicago, Columbus Hall K/L
CINF Luncheon/Ticket No. SE-16/$25 Noon t o 1:30 PM McCormick Place, Room N136
Sci-Mix Interdivisional Poster Session & Mixer/Drink Tickets in Your Registration Credentials/Free
Sheraton Chicago, Chicago Ballroom VI/ VII
Women Chemists Committee Luncheon/ Ticket No. S Ε-17 (regular)/$45 & SE-18 (student)/$27 Noon t o 1:30 PM WWW.CEN-0NLINE.ORG
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District 1 Councilor Caucus/NT 5:30 t o 7 PM Sheraton Chicago, Huron Room CINF Reception/NT 5:30 t o 8:30 PM Hyatt Regency Chicago, Columbus A/B Joint PMSE/POLY Poster Session/NT 6 t o 8 PM Hyatt Regency Chicago, Riverside Center University of Missouri, St. Louis, Alumni Hour/NT 6 t o 8 PM Hyatt Regency McCormick, Room 21C
CARB Social Hour & Poster Session/NT 6 t o 8 PM
WEDNESDAY, M A R C H 2 8
Hyatt Regency Chicago, Riverside Center COMP Social Hour & Poster Session/ NT 6 t o 8 PM
Sheraton Chicago, River Center Exhibit Hall ENVR Social Hour & Dinner/Ticket No. SE-20/$60 6 to 8 PM
Jake Melnick's Corner Top Restaurant, 41 East Superior St. AGRO Social Hour/NT 6 to 8:30 PM
Hyatt Regency Chicago, Grand Β CELL Anselme Payen Award Social Hour & Dinner/Ticket No. SE-21/$50 6 to 10 PM
Harry Caray's Restaurant, 33 West Kinzie St. HIST 85th Birthday Dinner/Ticket No. SE-25/$45 7 to 9 PM
Szechwan Restaurant, 625 North Michigan Ave. 2007 ACS Awards Banquet & Ceremony and General Meeting of the Society/ Ticket No. SE-22/$125 6:30 to 10 PM
George M. Whitesides will deliver the Priestley Medal Address during the general meeting. Fairmont Chicago, Imperial Ballroom FUEL/PETR Joint Division Dinner/Ticket No. SE-23/$40 7 to 10 PM
Parthenon Restaurant, 314 South HalstedSt. I NOR Social Hour & Poster Session/NT 7 to 10 PM
Chemjobs Career Fair/T 8 AM to 5:30 PM
McCormick Place, North Hall Β Exhibitors Meeting & Breakfast/NT 8 to 8:55 AM
McCormick Place, Lakeside Hall D, Exhibi tors Lounge theme of sustainability. You can also plan your meeting itinerary using our Personal Scheduler software from the website.
ACS Exposition/T 9 AM to 1 PM
McCormick Place, Lakeside Hall D Places & Spaces: Mapping Science Ex hibit/NT 9 AM to 5 PM
McCormick Place, Lakeside Hall D outside Exposition ENVR Social Hour & Poster Session/NT 6 to 8 PM
Hyatt Regency Chicago, Riverside Center MEDI Social Hour & Poster Session/NT 7to9PM
Hyatt Regency Chicago, Riverside Center PHYS Social Hour & Poster Session/ COD 7:30 to 10 PM
Hyatt Regency Chicago, Riverside Center ORGN Social Hour & Poster Session/ COD 8 to 10 PM
Hyatt Regency Chicago, Riverside Center
THURSDAY, M A R C H 2 9 Places & Spaces: Mapping Science Exhibit 9 AM to 1 PM
McCormick Place, Lakeside Hall D outside Exposition
Hyatt Regency Chicago, Riverside Center ORGN Social Hour & Poster Session/ COD 8 t o 10 PM
Hyatt Regency Chicago, Riverside Center l&EC Social Hour & Poster Session/NT 8 t o 10 PM
Hyatt Regency Chicago, Riverside Center
O R A L & POSTER PRESENTATION G U I D E L I N E S FOR A U T H O R S Speakers and poster presenters should read the guidelines on the at tendee website at chemistry.org/meet ings/chicago2007 in order to prepare effectively for their presentation.
ABSTRACTS & SPEAKER INSTRUCTIONS ONLINE TECHNICAL PROGRAM. The
technical program for the 233rd national meeting is available online at chemistry. org/meetings/chicago2007. You can search for divisions, secretariats, or committees; symposia; speakers; or keywords from abstracts as well as the multidisciplinary WWW.CEN-0NLINE.ORG
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ABSTRACTS (CD-ROM). Abstracts of all scientific sessions at the meeting can be purchased in CD-ROM format between Jan. 8 and March 29 through ACS Attendee Registration. The ACS member fee is $50 each, and the nonmember fee is $75 each. Attendees can pick up their abstracts onsite at any ACS Attendee Registration loca tion during the meeting, March 24-29. You can also have your abstracts shipped to you if you place your order before March 2, pay an $8.00 postage fee per item, and provide a valid street address located within the U.S. or Canada. If you are not attending the meeting, you can purchase abstracts only from ACS Office of Society Services, Room 521,1155—16th St., N.W., Washington, DC 20036; (800) 227-5558. Abstract CD-ROMs and their shipping costs are nonrefundable. SPEAKER INSTRUCTIONS. All speakers,
authors, and poster presenters must reg ister and pay the appropriate registration fee to attend the meeting. Invited speakers should contact their symposium organizer or division program chair to clarify terms of their invitation. All presenters should prepare for their presentation by checking the following details: the status of your abstract at oasys. acs.org/acs/233nm/oasys.htm (using your abstract ID number and password from your acceptance notice); mode of presenta tion (oral or poster); and the time, length, and location of your presentation. Plan your schedule to guarantee that you arrive in your presentation room no less than 30 minutes before your scheduled speaking time or set up your poster one hour before the scheduled start of the poster session. If you need to withdraw your presentation, please send a withdrawal notice to help@ acs.org and contact your symposium orga nizer immediately. •
233RD ACS NATIONAL MEETING M a r c h 2 5 - 2 6 · Chicago, Westin Hotel, Michigan Avenue All events will take place at the Westin Michigan Avenue Graduate School Reality Check Hotel in Chicago, with the exception of the UndergraduateGOVERNOR'S SUITE Research Poster Sessions and Sci-Mix, which will be held at S:00 - 1 0 : 3 0 A.M. the Hyatt Regency Chicago, and the SAACS Chapter Awards A panel of graduate students, faculty, and university Ceremony and Undergraduate Social, which will be held atrecruiters will discuss everything you ever wanted McCormick Place. to know about graduate school in the chemical sciences: how to get in, how to stay in, and how to get out. Co-sponsored by the Younger Chemists SUNDAY, M A R C H 2 5 Committee.
Undergraduate Hospitality Center
Morning Tea with Graduate School Recruiters
WELLINGTON BALLROOM 8:00 A.M. - SiOO P.M. All undergraduates are invited to the hospitality center to grab breakfast (co-sponsored by Chase Education Finance) and network with other chemi cal science students, ACS staff, and the national meeting program planners. Career information pamphlets will also be available.
WELLINGTON BALLROOM 10:30 A.M. - NOON Meet representatives from graduate schools who will share information about graduate programs in the chemical sciences available at their institutions. Tea and snacks will be served.
Making the Most of Your First ACS Meeting
Chem Demo Exchange Using Household Chemicals
WELLINGTON BALLROOM 8:00 - θ : 0 0 Α.Μ. Come learn tips on how to get the most out of your national meeting experience—where to go, what to see, and more.
Writing the SAACS Chapter Report WELLINGTON BALLROOM 9:00 - 10:30 A.M. Get tips on preparing clear and concise reports, check out the new on-line report submission system, and gain insights into the report review process.
Undergraduate chemical science students—join us in Chicago for an educational program designed specifically for you. Attend symposia on sustainability and automotive chemistry, meet with graduate school recruiters, learn tips for successful chapter reports and outreach, explore new research, and network with your peers. Don't miss out!
COTILLION BALLROOM 10:30 A.M. - NOON SAACS chapters will share how they incorporate common household materials into educational hands-on demonstrations for use in science and outreach activities. Students will also be displaying booths from the 100 th Anniversary of the Minnesota Local Section.
ACS Community Outreach Programs—You Can Make a Difference GOVERNOR'S SUITE 12:30 - 1 : 3 0 P.M. Get the inside scoop on upcoming Chemists Celebrate Earth Day and National Chemistry Week themes, ideas for activities, and tips for motivating volunteers. Co-sponsored by the Committee on Community Activities.
Automotive Chemistry I: More Than Just the Tail Pipe CONSORT 2 : 0 0 - 3 : 0 0 P.M.
The many ways chemists contribute to the automo tive industry and research on vehicle and manufac turing emissions will be discussed. Co-sponsored by the Divisions of Fuel Chemistry, Petroleum Chemis try and Environmental Chemistry.
MONDAY, M A R C H 2 6
Undergraduate Hospitality Center WELLINGTON B A L L R O O M 8:00 A.M. - 5:00 R M .
Graduate School Recruiting Breakfast WELLINGTON B A L L R O O M 8:00 - 10:00 A.M.
Eminent Scientist Lecture featuring Omar Yaahi: Pores without Walls for clean Energy common
BALLROOM SOUTH S : 0 0 - β : 0 0 P.M.
Professor Yagbi from University of California-Los Angeles will discuss new classes of crystalline porous materials and their applications for clean energy.
Chemistry Survival Guide: Reducing the Frustration of Learning and Teaching Chemistry
Meet representatives from graduate schools who will share information about graduate programs in the chemical sciences available at their institutions.
Up Close and Personal: ACS Corporation Associates Reception for Undergraduates
MICHIGAN 3 : 0 0 - 5 : 0 0 P.M.
COTILLION B A L L R O O M N O R T H 6 : 0 0 - 7 : 3 0 P.M.
Finding chemistry difficult to learn or teach? Explore the reasons why and consider ways to address them.
Sustainability and Chemistry: Tomorrow's Challenge for Today's Students, Presidential Event
Dress for Success Workshop
CONSORT 9:00 - 1 0 : 0 0 A.M.
G O V E R N O R ' S SUITE 3 : 0 0 - 4 : 0 0 P.M.
Having a good resume is only the first step in secur ing your dream job. Find out what it takes to make a good impression and how to present yourself in a complete and professional fashion.
Kids & Chemistry Workshop BUCKINGHAM 4 : 0 0 - 5 : 0 0 P.M.
Participants will get tips on planning and presenting science activities to elementary school children and will learn about safety and liability issues.
SAACS Chapter Awards Ceremony, Presidential Event M C C O R M I C K PLACE, S O U T H B U I L D I N G , LEVEL 1 , G R A N D BALLROOM S100A 7 : 0 0 - 8 : 3 0 P.M.
The Annual Student Affiliates Chapter Award Cer emony honors chapters that have been recognized as outstanding, commendable, and honorable men tion chapters for their accomplishments during the 2005-2006 academic year.
Undergraduate Social M C C O R M I C K PLACE, S O U T H B U I L D I N G , LEVEL 1 , G R A N D BALLROOM SIOOBC 8 : 3 0 - 11:30 P.M.
All undergraduates are invited to attend this social where there will be great food and music. The SAACS chapters from Northwestern University and DePaul University will host this event.
This session will explore the challenges and oppor tunities for ensuring that chemistry meets the needs of the present without compromising the ability of future generations to meet their own needs. Co-sponsored by the ACS Committee on Environ mental Improvement and the ACS President.
Automotive Chemistry II: More than Just the Tail Pipe CONSORT 1 0 : 0 0 - 11:00 A . M .
Opportunities in coatings and advances in fuel cell technology will be discussed. Co-sponsored by the Divisions of Fuel Chemistry Petroleum Chemistry, and Environmental Chemistry.
Undergraduate Research Poster Session I HYATT REGENCY C H I C A G O , RIVERSIDE CENTER 11:00 A . M . - 1:00 P.M.
Sponsored by the Division of Chemical Education and co-sponsored by the Divisions of Analytical Chemistry Polymer Chemistry and Polymeric Mate rials: Science and Engineering.
Undergraduate Research Poster Session II HYATT REGENCY C H I C A G O , RIVERSIDE CENTER 2 : 0 0 - 4 : 0 0 P.M.
Sponsored by the Division of Chemical Education and co-sponsored by the Divisions of Biochemical Technology Biological Chemistry Environmental Chemistry Medicinal Chemistry and Physical Chemistry.
II
Hosted by the ACS Committee on Corporation Asso ciates, the reception will feature roundtable discus sions on topics including Bachelor's versus Master's degrees, the advantages of co-ops and internships, entering the workforce, women in industry, entering graduate school, and much more.
Sci-Mix / Successful Student Affiliates Chapter Poster Session HYATT R E G E N C Y C H I C A G O , RIVERSIDE CENTER 8 : 0 0 - 1 0 : 0 0 P.M.
Successful Student Affiliates Chapters will showcase their activities during the largest ACS poster session that includes Divisional posters and other exhibits as well. All events are sponsored or co-sponsored by the Society Committee on Education Task Force on Undergraduate Programming Program Chair: Mark Benvenuto, University of Detroit-Mercy, Detroit, Ml; Chair: Etta Gravely North Carolina A&TState University, Greensboro, NC. For more information, contact the ACS Student Affiliates Program, 1 -800-2275558, ext
[email protected]
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Brought to you by C&EN Chemjobs and ACS Career Management & Development
March 2 5 - 2 8 , 2007 North Hall B, McCormick Place Chicago, IL
8:00 AM-5:30 PM A r e y o u interested in s p e a k i n g w i t h e m p l o y e r s t o discuss e m p l o y m e n t opportunities? P e r h a p s y o u w o u l d like t o brush up o n y o u r interviewing skills, find out h o w t o w r i t e a w i n n i n g r e s u m e , or g e t v a l u a b l e i n f o r m a t i o n o n various c a r e e r m a n a g e m e n t a n d d e v e l o p m e n t t o p i c s . T h e C h e m j o b s C a r e e r Fair c a n provide all of t h e s e things a n d m o r e ! For additional information on all services provided at the Chemjobs Career Fair, please visit http://cen-chemjobs.org/careerfair. Job Seekers and employers must sign up January 2 9 - March 28 to participate.
Professional Development Workshop Schedule All workshops will be held in Rooms A and B, located in North Hall Β of McCormick Place. IMPORTANT: Workshop times are subject to change. Please consult the Web version of the workshop schedule http://chemistry.org/careers/workshops.html or the Chemjobs Career Fair onsite brochure for final workshop times. SUNDAY,
MARCH
25
MONDAY,
MARCH
26
8:30 AM - 10:00 AM Mock Interview Demonstration
8:30 AM - 10:00 AM Mock Interview Demonstration
8:30 AM - 10:00 AM Finding A Position in Industry
8:30 AM - 10:00 AM First Year on the Job
10:30 A M - N o o r
Communication Skills for Chemical Professionals
10:30 A M - N o o n
Résumé Preparation for Recent Graduates
1:30 PM - 5:00 PM
Academic Employment Initiative: How Do I Get That First Job? Presidential Event.
1:30 PM - 3:00 PM
Effective Interviewing Techniques for Chemical Professionals
3:30 PM - 5:00 PM
Career Strategies—Critical Steps to Success
CHEMJDBS. O R G
10:30 AM - Noon
Finding A Position in Industry
0:30 AM - Noon
Overcoming Barriers: Current Issues Facing Foreign-Born Chemical Professionals Light refreshments provided.
Noon - 1:00 PM
SPECIAL PROGRAMMING! Research Foundation and Its Role in Supporting International Research Collaborations Lunch will be provided.
1:30 PM - 3:00 PM
Résumé Preparation for Experienced Chemical Professionals
1:30 PM - 4:30 PM
Negotiation Techniques
3:30 PM - 5:00 PK
Effective Interviewing Techniques for Chemical Professionals
Life
begins with chemistry.
Your f u t u r e begins with
chemjobs.on TUESDAY, M A R C H 27 8:30 AM - 10:00 AM Mock Interview Demonstration 8:30 AM - 10:00 AM Starting a Chemical Consulting Busines 10:30 AM - Noon
Finding A Position in Industry
10:30 AM - Noon
Communication Skills for Chemical Professionals
1:30 PM - 3:00 PM
Résumé Preparation for Recent Graduates
1:30 PM - 3:30 PM
Navigating the Federal Employment Process Panel discussion.
3:30 PM - 5:00 PM 4:00 PM - 5:30 PM
Effective Interviewing Techniques for Recent Graduates ng Excellent Research Proposals
W E D N E S D A Y , M A R C H 28 8:30 AM - 10:00 AM Mock Interview Demonstration 8:30 AM - 10:00 AM Preparing a CV for Chemical Professionals 10:30 AM - Noon
Communication Skills for Chemical Professionals
10:30 AM - Noon
Career Strategies—Critical Steps to Success
1:30 PM - 3:00 PM
Which Path Should I T a k e Industry or Academia?
1:30 PM - 3:30 PM
Negotiating Techniques
4:00 PM - 5:30 PM
Effective Interviewing Techniques for Academic Positions
4:00 PM - 5:30 PM
First Year on the Job
Other Career-Oriented Technical Programming Please consult the online technical program at http://chemistry.org/meetings/chicago2007 or the onsite program distributed during the meeting for final details on this programming. Sunday, March 25 I 2:25 PM - 4:30 PM Single Interest Group (SIG) Topics: Business Start Ups and Consultants Symposium. Room 23 A/B, Hyatt Regency McCormick. Sponsored by PROF and co-sponsored with CEPA. Monday, March 26 I 8:30 AM - 11:55 AM Benefit Trends for the Chemical Workforce Symposium. Room 21 -C, Hyatt Regency McCormick. Sponsored by PROF and co-sponsored by Corporation Associates, CEPA, SCHB, WCC, and YCC. Tuesday, March 27 I 1:00 PM - 4:20 PM Ethics for the Chemical Professional Symposium. Room 20 A/B, Hyatt Regency McCormick. Sponsored by PROF and co-sponsored with Committee on Ethics and CEPA. Tuesday, March 27 I 2:00 PM - 4:00 PM Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Presidential Event. Room S-100A, McCormick Place. Co-sponsored by CHED, CEPA, COMSCI, and IAC. Tuesday, March 27 I 2:00 PM - 4:30 PM Best Steps for the Chemical Entrepreneurs Panel Discussion. Room 23 A/B, Hyatt Regency McCormick. Sponsored by SCHB.
»£«
American Chemical Society
TECHNICAL PROGRAM
PRES/SUST
TUESDAY AFTERNOON
Presidential Event F. Walworth, Program Chair
O T H E R S Y M P O S I A O F INTEREST: Educating for Sustainability (see SUST, Mon)
Pressing Challenges and Technology Opportunities for a Sustainable Future (see SUST, Mon) SOCIAL EVENTS: Luncheon: Mon Reception: Sun SUNDAY MORNING Undergraduate Research in Polymer Science Sponsored by POLY, Cosponsored with PRES SUNDAY EVENING Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with PROF, YCC, and PRES Undergraduate Research in Polymer Science Sponsored by POLY, Cosponsored with PRES MONDAY MORNING Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry Solar Photon Conversion Sponsored by PHYS, Cosponsored with PRES, and SUST Sustainability and Chemistry: Tomorrow's Challenge for Today's Students Sponsored by SOCED, Cosponsored with SOCED, CEI, PRES, and SUST MONDAY AFTERNOON Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry Solar Fuels and Biofuels Sponsored by PHYS, Cosponsored with PRES, and SUST
McCormick Place South Room S100A, Level 1 Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT Organizers
Women Achieving Success: The ACS as a Platform in Leadership Development Sponsored by WCC, Cosponsored with PROF, and PRES
Nanoscience Fostered Advances in Sustainability Green Chemistry and Nanoparticle Reactivity Sponsored by COLL, Cosponsored with SUST
M O N D A Y EVENING
S U N D A Y EVENING
Nanoscience Fostered Advances in Sustainability Poster Sponsored by COLL, Cosponsored with SUST
Energy and Environmental Inorganic Chemistry Sponsored by INOR, Cosponsored with SUST
Women Achieving Success: The ACS as a Platform in Leadership Development Sponsored by WCC, Cosponsored with PROF, and PRES
SUST Sustainability of Energy, Food, and Water S. P. Shoemaker, Κ. Β. Anderson, and B. J. Marinas, Program Chairs SUNDAY MORNING BMGT Presents an Executive Overview of Energy Programming for the Chicago ACS Meeting Sponsored by BMGT, Cosponsored with SUST Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Greenhouse Gas Capture and Sequestration Capture Sponsored by FUEL, Cosponsored with SUST Nanoscience Fostered Advances in Sustainability Sustainability in Energy Sponsored by COLL, Cosponsored with SUST Nuclear Energy: International Efforts Toward a Sustainable Future Sponsored by NUCL, Cosponsored with SUST Sustainability and Chemical Education: Industry's Perspective Sponsored by CHED, Cosponsored with l&EC, CEI, and SUST SUNDAY AFTERNOON Section A McCormick Place Lakeside Arie Crown Theater
Inorganic Chemistry in Water Sponsored by INOR, Cosponsored with SUST MONDAY MORNING
2-TECH
C. T. Hunt,
Organizer
1:00 Discussion. Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Greenhouse Gas Capture and Sequestration
Section A McCormick Place South Room S106A, Level 1
Section A McCormick Place Lakeside Arie Crown Theater
Sustainability in Water Supply: Catalytic Control of Emerging Micropollutants Cosponsored with ENVR
Pressing Challenges and Technology Opportunities for a Sustainable Future
B. J . Marinas, C. J . Werth, and T. J . Strathmann, Organizers
C. T. Hunt,
8:25 Introductory Remarks. T. Strathmann. 8:30 9. Heterogeneous catalytic reduction of water contaminants by oxygen atom transfer reactions. J. R. Shapley 9:00 10. Metal catalyzed reduction as a strategy for selective treatment of drinking water- and wastewater-derived micropollut ants. T. J. Strathmann, A. J. Frierdich, L. E. Knitt, C. E. Joseph 9:25 11. Abiotic destruction of RDX by hydrogen sulfide via black carbon cata lysts. J. M. Kemper III, W. A. Mitch 9:50 12. Catalytic reduction of nitrate using Pd-based bimetallic catalysts under sulfide fouling conditons. B. P. Chaplin, J. R. Shapley, C. J. Werth 10:15 Intermission. 10:25 13. Ultraviolet- and solar light-activated nanostructured T i 0 2 photocatalysts: Appli cation in the destruction of cyanotoxins, a group of emerging drinking water contami nants. D. D. Dionyslou, M. G. Antoniou, H. Choi, A. A. de la Cruz, J. A. Shoemaker 10:55 14. Probing the role of fluoroquinolone adsorption and speciation in the visiblelight photocatalytic degradation of these antibacterial agents. T. Paul, P. L. Miller, T. J. Strathmann 11:20 15. Enhanced photocatalytic activity of Ta 2 05/Si0 2 mixed oxides. R. Chandrasekharan, N. Ndiege, R. I. Masel, M. A. Shannon 11:45 16. Rapid demethylation and further degradation of sertraline by hydrogen peroxide and Fe-TAML activators. E. S. Beach, Y. Xiang, C. P. Horwitz, T. J. Collins
Organizer
8:00 Introductory Remarks. Catherine T. Hunt, ACS President. 8:15 Discussion. 8:45 1 . Sustainability for food productions: A natural. M. K. Wagner 9:15 2. Contributions to ensuring sustainable and secure energy supplies. A. Geertsema 9:45 3. Challenges to a successful biofuels industry and department of energy efforts to overcome them. A. A. Krasner 10:15 4. Sustainable water management: Challenges ahead. A. J. B. Zehnder 10:45 Panel Discussion. 11:15 Concluding Remarks. Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry Solar Photon Conversion Sponsored by PHYS, Cosponsored with PRES, and SUST Sustainability and Chemistry: Tomorrow's Challenge for Today's Students Sponsored by SOCED, Cosponsored with SOCED, CEI, PRES, and SUST MONDAY AFTERNOON Section A McCormick Place Lakeside Arie Crown Theater Educating for Sustainability C. T. Hunt,
Organizer Section Β
1:30 Introductory Remarks. Catherine T. Hunt, ACS President. 1:45 5. Science education sustainability and the practicing scientist. S. J. Olesik 2:15 6. Educating for sustainability. C. Lehmann 2:45 7. Impact of chemistry on sustainable water with its nexus to the economy, energy, and the environment. M. A. Shannon 3:15 8. So you want to change the world: University education for sustainable food systems. T. P. Tomich 3:45 Panel Discussion. 4:15 Concluding Remarks. Catherine Hunt, ACS President. Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST
Sustainability: A World View
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Developing Issues in Energy and Fuels Sponsored by FUEL, Cosponsored with SUST
TUESDAY MORNING 2:00 Introductory Remarks. Charles P. Casey. 2:05 1. Partly cloudy with a chance of show ers: The future of U.S. chemistry — benchmarks and challenges. C. P. Casey 2:20 2. Partly cloudy with a chance of show ers: The future of U.S. chemistry — benchmarks and challenges. S. T. Ceyer 2:35 3. Benchmarking the research competi tiveness of U.S. chemical engineering. L. L. Hegedus 2:50 4. Benchmarking the research competi tiveness of U.S. chemical engineering. E. W. Kaler 3:05 5. Enhancing innovation and competi tiveness through investments in funda mental research. M. S. Wrighton 3:30 Closing Remarks. Catherine T. Hunt, ACS President. 3:35 Panel Discussion.
TUESDAY MORNING Going with the Flow: Water Sustainability Past, Present, Future Sponsored by HIST, Cosponsored with PRES, SUST, and ENVR
Solar Fuels and Biofuels Sponsored by PHYS, Cosponsored with PRES, and SUST
Section A
C. P. Casey and F. Walworth, Sustainability: A World View (see SUST, Sun)
Carbon Sequestration Sponsored by FUEL, Cosponsored with SUST
Clean Coal Sponsored by FUEL, Cosponsored with SUST Nanoscience Fostered Advances in Sustainability Environmental Remediation Sponsored by COLL, Cosponsored with SUST Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry
McCormick Place South RoomS104A, Level 1 Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Cosponsored with ENVR B. J . Marinas, Y. Lu, and P. W. Bohn, Organizers 8:30 Introductory Remarks. P. Bohn. 8:35 17. A systems approach to high-sensi tivity detection of water contamination using array-based sensors. D. R. Walt, R. Hayman, S. Ahn, K. L. Brogan, S. Tzipori, U. Zuckerman 9:25 18. Occurrence and potential humanhealth significance of synthetic organic contaminants in sources of drinking water. R. J. Gilliom, J. S. Zogorski, G. C. Delzer, M. J. Focazio, P. L Toccalino 9:50 19. H 2 Oconee and beyond: Keeping an eye on middle Georgia's water supply. L. M. Peaden, C. H. Lisse 10:15 Intermission. 10:30 20. Hindered transport of polyelectrolytes in single cylindrical nanopores pre pared by focused ion beam milling in polymethylmethacrylate membranes. E. N. Gatimu, P. W. Bohn
SUST 10:55 2 1 . Incorporation of a DNAzyme into Au-coated nanocapillary array membranes with an internal standard for Pb(ll) sensing. D. P. Wernette, Y. Lu 11:20 22. Microfluidic/nanofluidic sensors using catalytic DNA for heavy metal detection. D. Cropek, T. S. Dalavoy, B. Flachsbart, Y. Lu, P. W. Bohn, M. A. Shannon, J. V. Sweedler 11:45 23. Monitoring drinking water treatment stages using fluorescence spectroscopy. M. J. M. Wells, M. A. Easterly, M. Y. Aboul Eish Section C McCormick Place South RoomS104B, Level 1 Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Cosponsored with ENVR B. J . Marinas, M. Elimelech, and E. Morgenroth, Organizers 8:30 Introductory Remarks. M. Elimelech. 8:35 24. High recovery membrane RO desalination of brackish water: Opportunities and limitations. Y. Cohen 9:25 25. Maltery wastewater reuse tests at pilot-scale. H. De Wever, W. Boënne, M. Danau, Κ. Lambert, Κ. Hardy, J. Limbos 9:50 26. Influence of shear on floe structure development and fouling potential in MBRs. A. L. Menniti, E. Morgenroth 10:15 Intermission. 10:30 27. Organic and inorganic fouling mechanisms in anaerobic membrane bioreactors. P. T. Tontcheva, S. I. Padmasiri, B. Norddahl, L. Raskin, E. Morgenroth 10:55 28. Organic fouling during ultrafiltra tion: Effect of membrane surface rough ness. M. Zhou, J. Kilduff, G. Belfort 11:20 29. Influence of high shear on micro bial community activity and structure in an anaerobic membrane bioreactor. S. I. Padmasiri, P. T. Tontcheva, M. Fitch, M-N. Pons, B. Norddahl, E. Morgenroth, L. Raskin
Section D McCormick Place South RoomS106B, Level 1 Sustainability of Food Systems: Carbohydrate Economy Cosponsored with CARB, and BIOT S. P. Shoemaker and G. Eggleston, Organizers, Presiding 8:20 Introductory Remarks. 8:30 30. Processing corn into carbohydrates for food and fuel using cellulose conver sion technology. M. R. Ladisch 9:00 3 1 . Sustainability of the sugar industry: Future value addition from sugarcane and sugarbeet. G. Eggleston 9:30 32. Product and by-product optimization in processing agricultural products: A case for barley to ethanol. R. A. Flores 10:00 Intermission. 10:20 33. Cellulosic ethanol and sustainabil ity: There is no "food vs. fuel" conflict. Β. Ε. Dale 10:50 34. Can we produce biofuels sustainably and how would we know. S. R. Kaffka 11:20 35. Biorefining the future. A. J. Ragauskas 11:50 Panel Discussion. Section Ε McCormick Place South Room S105B/C, Level 1 Sustainable Food and Agriculture for African Drought Areas Causes, Impact, and Non-technology Considerations Cosponsored with AGFD J. Finley, J . V. Leland, and S. R. Yates, Organizers, Presiding 8:30 Introductory Remarks.
8:35 36. Will scientists in the public sector be active participants or supporting players in agricultural biotechnology? R. N. Beachy 9:20 37. Dealing with drought in a warming world. D. T. Avery 10:05 Intermission. 10:15 38. Drought in Africa: An ever-present environmental hazard. S. E. Nicholson 11:00 39. The politics of drought stress tolerant crops in Africa. R. L. Paarlberg Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Clean Coal Sponsored by FUEL, Cosponsored with SUST Fluorine and Energy Sponsored by FLUO, Cosponsored with SUST Going with the Flow: Water Sustainability Past, Present, Future Sponsored by HIST, Cosponsored with PRES, SUST, and ENVR Nanoscience Fostered Advances in Sustainability Bio-inspired Nanosystems Sponsored by COLL, Cosponsored with SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Health and Regulatory Concerns of DBPs and Analytical Methods Sponsored by ENVR, Cosponsored with CEI, and SUST Sustainable Resources: Science and Information Sources Sponsored by CINF, Cosponsored with AGRO, FUEL, and SUST TUESDAY AFTERNOON Section A McCormick Place South RoomS106A, Level 1 Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Cosponsored with ENVR B. J. Marinas and E. A. Mintz,
Organizers
1:30 Introductory Remarks. B. J. Marinas. 1:35 40. Challenges and opportunities for new disinfection processes from a regula tory perspective. S. Regli 2:25 4 1 . Effect of bacterial specific growth rate and growth in biofilms on kinetics of inactivation with monochloramine. D. Berry, D. Holder, D. Dai, C. Xi, L. Raskin 2:50 42. Inactivation of Mycobacterium avium with free chlorine. J . Luh, B. J. Marinas 3:15 Intermission. 3:30 43. Characterization of a novel bacteri cidal material consisting of Ag on a fiber glass substrate. G. N. Nangmenyi, J. Economy, Z. Yue 3:55 44. Inorganic cluster-amphiphile based coagulants for removal of pathogens from water supplies or wastewater streams. M. Nyman, S. G. Thoma, J. M. Bieker 4:20 45. Monitoring of polyelectrolyte flocculants at trace levels in water by fluorescent tagging. D. R. Dixon, R. J. Eldridge 4:45 46. Adhesion kinetics and reversibility of coliphage MS2 to silica. T. H. Nguyen
2:00 48. Analysis of pharmaceuticals and endocrine disruptors by liquid chromatography-tandem mass spectrometry. B. Vanderford, S. Snyder 2:25 49. Fluorescent and colorimetric sen sors for metal contaminants in water based on catalytic DNA. J . Liu, A. Brown, H. Kim, D. P. Wernette, Y. Lu 2:50 50. Colorimetric detection of mercuric ion (Hg 2+ ) in aqueous media using DNAfunctionalized gold nanoparticles. J-S. Lee, M. S. Han, C. A. Mirkin 3:15 Intermission. 3:30 5 1 . How well are we doing with ppt level detection of emerging micropollutants? J. Drewes, S. Snyder, A. Eaton, D. L. Sedlak 3:55 52. Electrokinetic transport in single nanocapillaries studied by axially-opposed dual confocal microscopy. T. L. King, J. V. Sweedler, P. W. Bohn 4:20 53. Fabrication of a real-time detector (RTD) for accurate temperature compen sation in a micro-conductivity sensor. M. A. Shannon, I. A. Adeniyi, M. C. Nsumuna, C. Connell, W. M. Lopez 4:45 54. SERS based immunoassay for the detection of Cryptosporidium parvum in drinking water. K. Rule, P. J. Vikesland Section C McCormick Place South RoomS104B, Level 1 Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Cosponsored with ENVR B. J . Marinas, M. Elimelech, and E. Morgenroth, Organizers 1:30 Introductory Remarks. E. Morgenroth. 1:35 55. Novel route for the preparation of nanoparticle-filled polymeric membranes: Example of the synthesis of biofouling resistant Ag-polysulfone ultrafilters. J. S. Taurozzi, V. Z. Bosak, A. F. Burban, M. L Bruening, V. V. Tarabara 2:00 56. Development of tailorable mem branes for targeted rejection. J. Matthews, K. L. Jones, H. Mohamed, J. N. Turner 2:25 57. Preparation of polyimide for use as substrate in a thermally stable composite membrane. C. Ba, J. Economy 2:50 58. Amphophilic graft copolymers for high-flux, fouling resistant membranes for ultrafiltration and nanofiltration. A. Asatekin, A. M. Mayes 3:15 Intermission. 3:30 59. Preparation of polyelectrolyte multi layer films consisting of sulfonated poly (ether ether ketone) which alternates with various anionic layers. J. Wang, Z. Yue, J. Economy 3:55 60. Fouling and NOM removal in MF systems with mixed adsorbents. J . Kim, W. Shi, M. M. Benjamin 4:20 6 1 . Molecular dynamics simulations of the NOM adsorption on polymeric mem brane surface in the presence of metal ions. W-Y. Ahn, A. G. Kalinichev, M. M. Clark Section D McCormick Place South RoomS104B, Level 1 Sustainability of Food Systems: Carbohydrate Economy Cosponsored with CARB, and BIOT
Section Β McCormick Place South RoomS104A, L e v e l ! Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Cosponsored with ENVR B. J . Marinas, Y. Lu, and P. W. Bohn, Organizers 1:30 Introductory Remarks. Y. Lu. 1:35 47. How sustainable is your water testing method? J. L. Young, R. K. Brahman, L H. Keith
S. P. Shoemaker and G. Eggleston, Organizers, Presiding 1:25 Introductory Remarks. 1:30 62. Sustainable land use, household food security, and the global economy: Markets, people and environment-develop ment dilemmas across the humid tropics. T. P. Tomich 2:00 63. Trees in the tropics: The untapped sustainable resource for food and environ mental security. H-Y. Shapiro 2:30 64. Sustainable food supply chain management in a competitive global environment. G. A. Lewis 3:00 Intermission.
3:20 65. Capturing the value of rice and its coproducts for food sustainability. Ε. Τ. Champagne 3:50 66. Prebiotic carbohydrate-related research within the USDA Agricultural Research Service. G. Cote 4:20 67. Bioenergy recovery from food leftovers. R. Zhang 4:50 Panel Discussion. Section Ε McCormick Place South Room S105B/C, Level 1 Sustainable Food and Agriculture for African Drought Areas Causes, Impact, and Non-technology Considerations Cosponsored with AGFD J. Finley, J. V. Leland, and S. R. Yates, Organizers, Presiding 1:15 Introductory Remarks. 1:20 68. From bench to the farm: The impact of biotech on farming and the crop value chain. G. M. Kishore 2:05 69. Challenges in the development of stress-tolerant crops using biotechnology in Africa. C. S. Prakash 2:50 Intermission. 3:00 70. GMOs, are they really safe? Β. Μ. Chassy 3:45 Panel Discussion. How do we imple ment the technology? Agricultural Biomass, Biobased Products, and Biofuels Defining the Challenges Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Energy Research in Inorganic Chemistry Sponsored by INOR, Cosponsored with SUST Fluorine and Energy Sponsored by FLUO, Cosponsored with SUST Nanoscience Fostered Advances in Sustainability Sensors Sponsored by COLL, Cosponsored with SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Reactivity of NOM toward DBP Formation Sponsored by ENVR, Cosponsored with CEI, and SUST T U E S D A Y EVENING Energy and Environmental Inorganic Chemistry Sponsored by INOR, Cosponsored with SUST WEDNESDAY MORNING Section A McCormick Place South Room S106A, Level 1 Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Cosponsored with ENVR B. J . Marinas and E. A. Mintz,
Organizers
8:30 Introductory Remarks. E. Mintz. 8:35 7 1 . Synthesis, characterization, and photocatalytic properties of nitrogen doped titanium oxide nanoparticles. Q. Li, J-K. Shang
Please refrain from using cellular telephones and cameras during technical sessions.
TECH-3
TECHNICAL PROGRAM
SUST 9:00 72. Antimicrobial materials for water disinfection based on visible-light photocatalysis. P-G. Wu, R-C. Xie, J-K. Shang 9:25 73. Preparation of T i 0 2 / A l 2 0 3 and N doped ΤΊΟ2/ΑΙ2Ο3 composites, and appli cations to photodeactivation of bacteria and viruses. E. A. Mintz, W. N. Harris III, Κ. Κ. Bota, S. Mehrabi, L Moeti, R. Chandrasekharan, M. A. Shannon 9:50 74. Characterizing, understanding, and improving the control of viral pathogens in drinking water treatment. M. A. Page, B. J. Marinas 10:15 Intermission. 10:30 75. Inactivation kinetics of Mycobacte rium avium with chlorine dioxide. J. P. Vicuna-Reyes, B. J. Marinas 10:55 76. Inactivation of adenoviruses with UV and chlorine. K. Sirikanchana, J. Shisler, B. J. Marinas 11:20 77. Risks from electrochemical drink ing water disinfection. M. H. Bergmann, J. Rollin 11:45 78. Inactivation of Bacillus subtilis spores with sequential or combined pro cesses using ozone and UV. Y-J. Jung, B. S. Oh, J. W. Kang Section Β McCormick Place South RoomS104A, Level 1 Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Cosponsored with ENVR B. J. Marinas, Q. Li, and T. H. Nguyen, Organizers 8:30 Introductory Remarks. Q. Li. 8:35 79. Predicting the performance of fixed-bed granular activated carbon adsorbers. J. C. Crittenden 9:25 80. MTBE adsorption kinetics on alter native adsorbents and packed bed adsorber performance. A. Rossner, D. R. U. Knappe 9:50 8 1 . Adsorption of emerging organic contaminant mixtures by alternative adsor bents. D. R. U. Knappe, A. A. Rossner Campos, S. Snyder 10:15 Intermission. 10:30 82. Sorption of tetracycline from water by activated carbons. J. Chen, J. Zheng 10:55 83. Removal of trace formaldehyde from air and water using porous materials. Z. Yue, J. L. Langer, J. Economy 11:20 84. Prediction of organic contaminant adsorption isotherms on activated carbons. D. R. U. Knappe, I. A. Mezzari, T. F. Speth 11:45 85. Assessing the removal of emerg ing organic contaminants by activated carbon adsorption using quantitative struc ture property relationships. E. R. V. Dickenson, J. Drewes Section C McCormick Place South RoomS104B, Level 1 Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Cosponsored with ENVR B. J . Marinas, M. Elimelech, and E. Morgenroth, Organizers 8:30 Introductory Remarks. M. Elimelech. 8:35 86. Predicting the rejection of organic micropollutants during nanofiltration/reverse osmosis treatment. J. Drewes, C. Bellona 9:00 87. Parameters affecting polar trace organics removal in activated sludge and membrane bioreactor systems. H. De Wever, S. Weiss, T. Reemtsma, J. Vereecken, J. Miiller, T. Knepper, S. Gonzalez, D. Barcelo 9:25 88. The role of EPS in biofouling of reverse osmosis membranes. M. Herzberg, M. Elimelech 9:50 89. Protein antifouling mechanisms of PAN UF membranes incorporating PAN-gPEO additive. S. Kang, A. Asatekin, A. M. Mayes, M. Elimelech 10:15 Intermission.
4-TECH
10:30 90. Numerical simulation of the flow in a membrane containing a ladder-type turbulent promoter. B. Liu, J. Ma, S. Huang, L Zhang 10:55 9 1 . Gene expression in reverse osmo sis membrane biofilms. M. Herzberg, M. Elimelech
Section Β McCormick Place South RoomS104A, Level 1 Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Cosponsored with ENVR
Section Ε McCormick Place South RoomS105B/C, Level 1 Sustainable Food and Agriculture for African Drought Areas Irrigation and Water Management Strategies Cosponsored with AGFD J. Finley, J. V. Leland, and S. R. Yates, Organizers, Presiding 9:00 Introductory Remarks. 9:05 92. Irrigation of forage crops with saline drainage waters: Volumetric iysimeter studies and modeling of root water uptake and drainage. Τ. Η. Skaggs 9:50 93. Reuse of saline drainage water for irrigation. S. R. Grattan 10:35 Intermission. 10:45 94. Use of saline and recycled water as an alternative irrigation water supply: Chemical and agronomic considerations. D. L. Suarez 11:30 Panel Discussion. Agricultural Biomass, Biobased Products, and Biofuels Process and Product Control Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Clean Coal Sponsored by FUEL, Cosponsored with SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Probing Formation of DBPs Sponsored by ENVR, Cosponsored with CEI, and SUST WEDNESDAY AFTERNOON
B. J . Marinas, Q. Li, and T. H. Nguyen, Organizers 1:30 Introductory Remarks, Q. Li. 1:35 102. Uptake of natural organic matter by anion exchange resins. Τ. Η. Boyer, P. C. Singer, G. Aiken 2:00 103. Preparation of modified clay adsor bents for the removal of humic acid. J-Q. Jiang 2:25 104. Trace contaminant removal by activated carbon: Factors affecting the competitive effects of natural organic matter. G. Tang, B. J. Marinas, V. L. Snoeyink 2:50 105. Preparation and characterization of iron nanoparticle-containing mesoporous carbon for removal of natural organic matter (NOM). S. Seo, H. Jung, H. Choi 3:15 Intermission. 3:30 106. Effect of carbon pore size distribu tion on the adsorption of TCE and atrazine in the presence of dissolved natural organic matter. A. Yadav, Y. Guo, T. Karanfil 3:55 107. Physical factors controlling the adsorption of polyaromatic synthetic organic chemicals by carbonaceous adsor bents. Y. Guo, T. Karanfil, S. Inizan 4:20 108. Interfacial water/vapor structure of Nal aqueous solutions. N. Ji, V. Ostroverkhov, G. Waychunas, Y. R. Shen 4:45 109. Water interaction with nanostructured silicon oxide surface. L. Zhang, Y. R. Shen, G. A. Waychunas Section C McCormick Place South RoomS104B, Level 1 Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Cosponsored with ENVR B. J . Marinas and J . G. Georgiadis, Organizers
Section A McCormick Place South Room S106A, Level 1 Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Cosponsored with ENVR B. J . Marinas, U. von Gunten, and M. S. Elovitz, Organizers 1:30 Introductory Remarks. U. von Gunten. 1:35 95. Oxidation processes in water purifi cation: The fundamental reactions. C. von Sonntag 2:25 96. Evaluation and comparison of advanced treatment processes for removal of chemical pollutants during water reuse. P. Ruiz-Haas, K. G. Linden, K. D. Cho, J. Bandy 2:50 97. Emerging contaminant oxidation using ozone. S. Snyder 3:15 Intermission. 3:30 98. Oxidative treatment of steroid estro gens in pure synthetic and real waters: Formation of oxidation products and change of estrogenic activity. Y. Lee, U. von Gunten 3:55 99. Evaluation of ozone and ozone/UV process for DEP removal: Kinetic study and degradation pathway. B. S. Oh, K. S. Kim, Y-J. Jung, M. Koga, R. Shinohara, J. W. Kang 4:20 100. Stop-flow studies of the kinetics of halogenation of the endocrine disruptor ethynyl estradiol (EE2). G. V. Korshin, J. Lu 4:45 101. Ultrasound effects on destruction of estrogen hormones in aqueous system. H. F. Fu, S. Abburi, M. Nayak, R. P. Suri
1:30 Introductory Remarks. B. Marinas. 1:35 110. Desalination: The quest to be salt-free. A. E. Childress 2:25 111. Coupled effects of scaling and colloidal deposition on the performance of reverse osmosis membranes. F. Wang, V. V. Tarabara 2:50 112. Quantification of functional groups in the active layer of high-pressure mem branes. O. Coronell, B. J. Marinas, D. G. Cahill, X. Zhang 3:15 Intermission. 3:30 113. Development of a hydrogelbridged nanofluidic membrane system for water desalination. S. Prakash, J. Lucido, J. G. Georgiadis, M. A. Shannon 3:55 114. Water transport and pore morphol ogy of HEMA gel films as fluid intercon nects in active membranes. H. R. Fitzhenry, S. Prakash, C. V. Falkenberg, G. Mensing, J. G. Georgiadis, M. A. Shannon 4:20 115. Development of nanofiltration membranes based on rigid star amphiphiles. Y. Lu, T. Suzuki, W. Zhang, C. Wang, B. Mi, J. S. Moore, B. J. Marinas
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4:45 116. Development of nanofiltration membranes based on rigid star amphiphiles: Membrane performance character ization. T. Suzuki, Y. Lu, W. Zhang, C. Wang, B. Mi, J. S. Moore, B. J. Marinas Section Ε McCormick Place South RoomS105B/C, Level 1 Sustainable Food and Agriculture for African Drought Areas Biotechnology for Nutritional Enhancement Cosponsored with AGFD J. Finley, J . V. Leland, and S. R. Yates, Organizers, Presiding 1:15 Introductory Remarks. 1:20 117. Golden Rice and beyond: The power of biofortification. I. Potrykus 2:05 118. Folate biofortification of food crops through pathway engineering. K. R. Schubert, T. Hossain 2:50 Intermission. 3:00 119. ABC transport proteins and nutri tional enhancement. T. Smith, B. Wei, H. Pakrasi 3:45 Panel Discussion. Agricultural Biomass, Biobased Products, and Biofuels Process Characterization Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Environmental Issues in Energy and Fuels Sponsored by FUEL, Cosponsored with SUST Great Lakes Research: Environmental Issues for a Freshwater Ecosystem Sponsored by CINF, Cosponsored with ENVR, and SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation and Control of Regulated DBPs Sponsored by ENVR, Cosponsored with CEI, and SUST W E D N E S D A Y EVENING Section A McCormick Place South Room S106A, Level 1 Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Posters Cosponsored with ENVR B. J . Marinas, M. Elimelech, and E. Morgenroth, Organizers 6:00-8:00 120. Biofouling potential of surface modified microporous polyethersulfone membranes. R. Malaisamy, Y. Kouwonou, K. L. Jones 121. Charged polymer nanofiltration mem branes for selective retention. N. G. Lovell, A. M. Mayes, I. Taniguchi, A. Asatekin 122. Modeling the treatment performance of a submerged membrane bioreactor using artificial neural network. G. Civelekoglu, N. O. Yigit, M. Kitis 123. Pure water production and recovery of nickel ions from electroplating rinse water by electrodeionization process. L. Huixia, W. Jianyou, F. Xueqi Section Β McCormick Place South Room S104A, Level 1 Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Posters Cosponsored with ENVR B. J . Marinas, Q. Li, and T. H. Nguyen, Organizers 6:00-8:00 124. Algal removal by clay adsorption. J-Q. Jiang 125. Solid/water interface charge density of surface functionalized materials studied by atomic force microscope. Y. Wu, S. Prakash, C. Gupta, M. A. Shannon
SUST
Section C
Section F
Hyatt Regency Chicago Riverside Center
Hyatt Regency Chicago Riverside Center
Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Posters Cosponsored with ENVR B. J . Marinas and J . G. Georgiadis, Organizers 6:00-8:00 126. Concentration polarization disruption in high-pressure membranes. J. Minier-Matar, O. Coronell, B. Mi, C. V. Falkenberg, J. G. Georgiadis, B. J. Marinas 127. Hydration structure of Na + and CI" ions from ambient to supercritical conditions. A. G. Kalinichev, Y. E. Gorbaty, G. V. Bondarenko, R. J. Kirkpatrick Section D Hyatt Regency Chicago Riverside Center Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Posters Cosponsored with ENVR B. J . Marinas and E. A. Mintz,
Organizers
Sustainability in Water Supply: Catalytic Control of Emerging Micropollutants Posters Cosponsored with ENVR
Section Β
B. J . Marinas, C. J . Werth, and T. J . Strathmann, Organizers 6:00-8:00 139. Catalytic hydrodehalogenation of iodinated X-ray contrast media with supported palladium catalysts. L. E. Knitt, J. R. Shapley, T. J. Strathmann 140. Effects of natural water ions, pH, pH control technique, and catalyst loading on nitrate reduction using Pd-based alumina supported bimetallic catalysts. C. S. Wojnar, B. P. Chaplin, C. J. Werth, J. K. Choe 141. Sensors for study of reactive oxygen species associated with TiON photooxidation catalysis. R. C. Wilson, M. Stewart, I. Oh, A. Scheeline 142. Synthesis and characterization of irondoped titanium dioxide materials. M. W. Hurst, P. L. Miller, T. J. Strathmann 143. Stability of nickel catalysts: Mechanisms for deactivation and regeneration. A. J. Frierdich, T. J. Strathmann, J. R. Shapley Section G
6:00-8:00 128. Effect of magnetic fields on the growth and physiological changes of Saccharomyces cerevisiae. S. Wang, L. Li, B. Li 129. Disinfection and related effects of non thermal ultrasonic irradiation on Saccharomyces cerevisiae. L. Zhou, B. Li, L. Li, X. Zhang, X. Li 130. Antimicrobial activity of silver-impreg nated alumina in a hard water environ ment. G. M. Cameron, D. Collait, Ε. A. Mintz, C. W. Ingram, G. Ananaba 131. Chelated iron sources are inhibitors of Pseudomonas aeruginosa biofilms and distribute efficiently in an in vitro model of drug delivery to the human lung. D. J. Musk Jr., P. J. Hergenrother 132. Evaluation of a novel plasma treatment concept for water disinfection. H. De Wever, H. Elslander, W. Boënne, L. Diels, D. Zander, M. De Roeck, R. Rego 133. Platform for virus and cell membrane mimics. L. Hong, L. Zhang, Y. Yu, B. Wang, S. Granick, E. Luijten, G. C. L Wong
Hyatt Regency Chicago Riverside Center Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Posters Cosponsored with ENVR B. J . Marinas, Y. Lu, and P. W. Bohn, Organizers 6:00-8:00 144. Occurrence of perchlorate at water treatment plants of the Tone River Basin in Japan. K. Kosaka, M. Asami, Y. Matsuoka, M. Kamoshita, S. Kunikane Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Poster Session Sponsored by ENVR, Cosponsored with CEI, and SUST
Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Posters Cosponsored with ENVR B. J. Marinas, U. von Gunten, M. S. Elovitz, and J. L. Acero,
Organizers
6:00-8:00 134. The effect of ozone dosage and hydrodynamic conditions on permeate flux in hybrid ozonation-ultrafiltration. J. Kim, A. L. Alpatova, L. M. Wright, M. J. Baumann, S. H. R. Davies, V. V. Tarabara, S. J. Masten 135. Biological removal of nitrogen and car bon from nylon-6 wastewater with a com bined system. F. Liu, C. Zhao, D. Zhao, G.Liu 136. Studies of the degradation of the endo crine disruptor ethynyl estradiol (EE2) in a flow-through electrochemical reactor. J. Kim, G. V. Korshin 137. Hydroxyl radical (·ΟΗ) mediated oxida tion of dimethyl phthalate ester in water. T. An, P. Kamat 138. UV/H202 Enhanced photocatalytic oxidation of phosphamidon. I. C. Poyer, J. C. Bezares-Cruz, A. Nienow, I. Hua, C. T. Jafvert
McCormick Place South RoomS104A, Level 1 Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Cosponsored with ENVR B. J . Marinas, Q. Li, and T. H. Nguyen, Organizers 8:30 Introductory Remarks. T. H. Nguyen. 8:35 153. Ligand-modified polymeric sorbents for the remediation of drinking water: An overview and future directions. S. D. Alexandratos, A. N. Pustam 9:00 154. Development of Aza222-based polymers, colloidal sorbents, and mem branes for the removal of mercury from aqueous solutions. Μ. Υ. Redko, J. S. Taurozzi, K. Manes, J. E. Jackson, V. V. Tarabara 9:25 155. Sulfonated ACF on fiberglass for Pb 2 + removal from water. Z. Yue, M. Zavareh, C. W. Ingram, J. Economy 9:50 156. Removal of boron and arsenic by hydrotalcite-like compounds (HT). J-Q. Jiang 10:15 Intermission. 10:30 157. Nanotechnology for drinking water purification. A. W. Apblett, S. I. Kuriyavar, M. Chehbouni, A. P. Piquette 10:55 158. Magnetite nanoparticles for treatment of arsenic from the drinking water. H. J. Shipley, S. Yean, A. T. Kan, M. B. Tomson 11:20 159. Arsenic removal from drinking water using nanoscale magnetite and iron salt. S. Yean, H. J. Shipley, A. T. Kan, M. B. Tomson 11:45 160. Design of crosslinked anion exchange fiber filter from a vinylbenzyl chloride precursor for groundwater arse nate removal. J . Zhang, J. L. Meyer, L. Dominguez, J. Economy
McCormick Place South RoomS104B, Level 1
Section A McCormick Place South Room S106A, Level 1
B. J. Marinas and J . G. Georgiadis, Organizers
Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Cosponsored with ENVR
8:30 Introductory Remarks. J. Georgiadis. 8:35 161. Prototype for ice distillation method for water desalination. M. C. Nsumuna, D. Agonafer, R. Romanow, G. Mensing, J. G. Georgiadis, M. A. Shannon 9:00 162. Forward osmosis and membrane distillation for high recovery desalination of brackish water. T. Y. Cath, C. R. Martinetti, A. E. Childress 9:25 163. Hybrid approach for enhancement of water recovery and concentrate minimi zation. P. Xu, J. Drewes, S. Sethi 9:50 164. Ion partitioning behaviors in OS membranes FT30. X. Zhang, D. G. Cahill, O. Coronell, B. J. Marinas
B. J . Marinas, U. von Gunten, M. S. Elovitz, and J . L. Acero,
Organizers
8:30 Introductory Remarks. M. Elovitz. 8:35 145. Removal of antimicrobial com pounds and their associated biochemical activity by UV photolysis and U V / H 2 0 2 processes. C. Baeza, D. R. U. Knappe 9:00 146. Moiety-specific oxidation reactions and consequent changes in biochemical activities of antibacterial compounds dur ing aqueous ozonation processes. M. C. Dodd, H-P. E. Kohler, U. von Gunten 9:25 147. Oxidation of phenyl-urea herbi cides by ozone and advanced oxidation processes. J. L. Acero, F. J. Benitez, F. J. Real, C. Garcia 9:50 148. Oxidation of phenylurea herbicides induced by excited triplet states. S. Canonica 10:15 Intermission. 10:30 149. Direct and indirect (via H202) UV photodegradation of nicotine in water. J. C. Bezares-Cruz, I. C. Poyer, A. Nienow, I. Hua, C. T. Jafvert 10:55 150. Hydroxyl radical mediated degra dation of phenylarsonic acid. T. Xu, P. V. Kamat, Κ. Ε. O'Shea
9:50 166. From genomics screens on the Arabidopsis model system to effective drought tolerance products in crops. O. J. Ratcliffe 10:35 Intermission. 10:45 167. Identification of novel root to shoot signals that control water loss under drought in maize. D. P. Schachtman, L. Ernst, S. Alvarez, J. Q. Goodger, B. Berla, J. Jung, E. Lockhart 11:30 168. Water deficit- and salinity-tolerant plants: Traits for improving yields in the face of abiotic stress. M. P. Apse, E. Blumwald Agricultural Biomass, Biobased Products, and Biofuels Improving Bioproduct Design Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Environmental Challenges of Fuel Utilization in the Developing World Sponsored by FUEL, Cosponsored with SUST Environmental Inorganic Chemistry Sponsored by INOR, Cosponsored with SUST Environmental Issues in Energy and Fuels Sponsored by FUEL, Cosponsored with SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation, Fate, and Control of Nitrosamines Sponsored by ENVR, Cosponsored with CEI, and SUST THURSDAY AFTERNOON Section A McCormick Place South Room S106A, Level 1 Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Cosponsored with ENVR B. J . Marinas, U. von Gunten, M. S. Elovitz, and J . L. Acero,
Organizers
Section C
Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Cosponsored with ENVR
THURSDAY MORNING Section Ε Hyatt Regency Chicago Riverside Center
11:20 151. Destruction of PCBs using sulfate radical-based advanced oxidation pro cesses. A. Rastogi, S. R. Al-Abed, D. D. Dionysiou 11:45 152. Ultrasonically induced degrada tion of 2-methylisobomeol and geosmin. W. Song, W. J. Cooper, Κ. Ε. O'Shea
Section Ε McCormick Place South RoomS105B/C, Level 1
1:30 Introductory Remarks. J. Acero. 1:35 169. Reaction kinetics and transforma tion of carbadox and structurally related compounds with aqueous chlorine. A. D. Shah, J-H. Kim, C-H. Huang 2:00 170. Study on degradation of trace nitrobenzene in drinking water by ceramic honeycomb-catalyzed ozonation. Z. Lei 2:25 171. The effect of ozonation on initial ozone demand of prechlorinated water. H. Yamada, E. Hasegawa, H. Tsuno 2:50 172. Examination of mechanisms and yields of in situ generation of hydroxyl radicals and ozone in a flow-through electrochemical reactor. G. V. Korshin, J. Kim 3:15 Intermission. 3:30 173. Comparing the efficiency of hydroxyl radical formation during ozone and UV advanced oxidation processes. E. J. Rosenfeldt, K. G. Linden, S. Canonica, U. von Gunten 3:55 174. Electron pulse radiolysis determi nation of hydroxyl radical rate constants with Suwannee River fulvic acid and other dissolved organic matter isolates. P. K. Westerhoff 4:20 175. Evaluation of hydroxyl radical removal efficiency using model organics in different quality wastewaters. J. R. Peller, S. P. Mezyk, W. J. Cooper
Sustainable Food and Agriculture for African Drought Areas Biotechnology for Drought Tolerant Agriculture Cosponsored with AGFD J. Finley, J . V. Leland, and S. R. Yates, Organizers, Presiding 9:00 Introductory Remarks. 9:05 165. The benefits of new technology in addressing drought stress in agriculture. F. J. Perlak, N. L. DiNicola
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-5
SUST/AGFD 4:45 176. Compute-aided pathway genera tion for aqueous phase advanced oxida tion processes. K. Li, D. Minakata, J. C. Crittenden, P. K. Westerhoff Section Β McCormick Place South RoomS104A, Level 1
TECHNICAL PROGRAM SUNDAY AFTERNOON
AGFD I Division of Agricultural & Food Chemistry A. M. Rimando, Program Chair
Section A McCormick Place Lakeside Room E259, Level 2 Soluble Cellulose as Dietary Fiber in Human Nutrition and Health Nutritional Studies and Food Chemistry
4:45 30. Marine microbes: The critical role they play in sustainable production of starting materials for the synthesis of drug leads and the structure for the elusive Pfiesteria-associated fish killing toxin using 13C enrichment and dual cryoprobe NMR studies. J. Peng, R. Hill, A. Place, C. Anklin, M. T. Hamann MONDAY MORNING
Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Cosponsored with ENVR B. J. Marinas, Q. Li, and T. H. Nguyen, Organizers 1:30 Introductory Remarks. T.H. Nguyen. 1:35 177. Highly efficient systems for arsenic removal based on supported iron oxide adsorbents. J. Wang, J. S. Ince, Z. Yue, J. Economy 2:00 178. Development of functionalized nanoporous inorganic-organic sorbents for removal of phenols and heavy metals from water. F. Ding, M. Zavareh, C. W. Ingram 2:25 179. A low-cost and sustainable house hold scale potable water treatment system to remove arsenic from contaminated groundwater. R. Banavali, C. J. Webb, J. A. Trejo 2:50 180. Toxic metal remediation in drinking water on the Navajo reservation using commercial pitcher filters. F. M. Geiger 3:15 Intermission. 3:30 181. Removal of arsenic from aqueous solution by dried hyacinth roots: Effects of solution chemistry and the role of metal (hydro)oxides. J. Chen, J. Zheng 3:55 182. Predicting the performance of arsenic adsorption media under varying water chemistries: A study using rapid small-scale column tests (RSSCTs). A. R. Aragon 4:20 183. Environmentally benign hardness removal with ion exchange fibers and harvested rain water/snowmelt. A. K. SenGupta, J. Greenleaf 4:45 184. Interfacial structures of acidic and basic aqueous solutions. C. Tian, N. Ji, V. Ostroverkhov, G. Waychunas, Y. R. Shen Section Ε McCormick Place South Room S105B/C, Level 1 Sustainable Food and Agriculture for African Drought Areas Biotechnology for Drought Tolerant Agriculture Cosponsored with AGFD J. Finley, J . V. Leland, and S. R. Yates, Organizers, Presiding 1:15 Introductory Remarks. 1:20 185. A multifaceted strategy to improve drought tolerance in maize. M. J . Oliver, H. T. Nguyen, R. E. Sharp 2:05 186. Membrane lipids in signaling plant water loss and response to hyperosmotic stress. Y. Hong, S. C. Bahn, X. Pan, X. Wang 2:50 Intermission. 3:00 187. Nitrogen utilization efficiency and applications to African agriculture. J. C. Kridl 3:45 Panel Discussion. Agricultural Biomass, Biobased Products, and Biofuels The Cellulosic Challenge Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Environmental Issues in Energy and Fuels Sponsored by FUEL, Cosponsored with SUST Inorganic Chemistry in Water Sponsored by INOR, Cosponsored with SUST Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water DBP Issues in Distribution Systems Sponsored by ENVR, Cosponsored with CEI, and SUST
6-TECH
OTHER SYMPOSIA OF INTEREST: Sustainable Food and Agriculture for African Drought Areas (see SUST, Tue, Wed, Thu) SOCIAL EVENTS: AGFD Executive Committee meeting: Sun AGFD Future Programs meeting: Mon Social Hour: Tue SUNDAY MORNING Section A McCormick Place Lakeside Room E259, Level 2 Soluble Cellulose as Dietary Fiber in Human Nutrition and Health Human Clinical Studies: Prevention of Metabolic Diseases S. K. Lynch, M. Turowski, and W. H. Yokoyama, Organizers 8:30 Introductory Remarks. 8:35 1. Dietary portfolio including viscous fibers to control serum cholesterol. D. J . Jenkins, C. W. Kendall 9:15 2. Efficacy of hydroxypropylmethylcellulose in lowering blood cholesterol. J. Dressman 9:45 3. High-viscosity hydroxypropylmethylcellulose: A promising agent for metabolic risk factor management. K. C. Maki 10:15 Intermission. 10:35 4. Decreases in adiposity by viscous indigestible polysaccharides in rats. D. D. Gallaher, L. M. Freiburger, J-A. Nazare 10:55 5. Human health benefits from con sumption of soluble fibers. Κ. Μ. Behall 11:15 6. Glycémie index: Effect of fiber on postprandial glycemia. C. W. Kendall, D. J. Jenkins 11:45 Concluding Remarks. Section Β McCormick Place Lakeside Room E264, Level 2 Natural Products, Diets and Cancer Prevention N. Suh and A. M. Rimando, C. Gerhauser,
Organizers
Presiding
8:10 Introductory Remarks. 8:15 7. Natural products for cancer chemoprevention: Progress and promise. H. Mukhtar 8:45 8. Prevention of gastrointestinal tract cancers with berries. G. D. Stoner, T. Chen 9:15 9. Novel approaches for colon cancer prevention by types of dietary fat, pterostilbene and other food components. B. S. Reddy, H. Newmark, N. Suh, A. M. Rimando, C. V. Rao 9:45 10. Dietary calcium and (phytoestro gens modulate vitamin D synthesis in colonocytes: A model for colon cancer prevention. H. S. Cross 10:15 Intermission. 10:25 11. Dietary grape seed proanthocyanidins inhibit photocarcinogenesis through prevention of UV-induced suppression of immune responses via induction of interleukin-12 in mice. S. K. Katiyar 10:55 12. Chemoprevention of inflammationassociated carcinogenesis afforded by dietary phytochemicals. Y-J. Surh 11:25 13. Molecular mechanism of prostate cancer prevention by a dietary nutrient inositol hexaphosphate. R. Agarwal
S. K. Lynch, M. Turowski, and W. H. Yokoyama, Organizers 1:15 Introductory Remarks. 1:20 14. Effects of HPMC on intralumenal characteristics that may be important to its hypocholesterolemic activity in humans. C. Reppas 1:40 15. Prevention of insulin resistance, hypertension and weight gain in hamsters fed soluble cellulose. W. H. Yokoyama, Y-J. Hong, M. Turowski, S. K. Lynch 2:00 16. Potential nutritional benefits and unique in product functionalities of methylcellulose. D. Lis, A. McPherson 2:20 17. Methylcellulose as bulk laxative. R. Zilberboim 2:40 Intermission. 2:55 18. Composition and properties of edible water soluble celluloses. J. R. Conklin 3:15 19. Chemical characterization of cellu lose ethers. M. J. Rinken 3:35 20. Determination of soluble celluloses in food matrices. R. Hartmann, M. Turowski, Β. Deshmukh, J. R. Conklin, S. K. Lynch 3:55 2 1 . Modified celluloses in the restau rant. A. J. Taylor, R. Edwards-Stuart, H. Blumenthal, C. Young, J. Hort 4:15 22. Role of cellulosic gums in bakery products: Gluten-free products. C. M. Rosell 4:35 Concluding Remarks.
Section A McCormick Place East Room E264, Level 2 Micro/Nano Encapsulation of Active Food Ingredients ACS Symposium Honors David Julian McClements Q. Huang, P. Given, M. C. Qian, and W . H. Yokoyama, Organizers 8:30 Introductory Remarks. 8:35 Award. 8:45 Introduction of Awardee. 8:50 3 1 . Application of nanolaminated biopolymer structures in foods. D. J. McClements 9:30 Intermission. 9:45 32. Protein-polyelectrolyte coacervates: Macro- and meso-phase separation. P. L. Dubin 10:10 33. Self-assembly of proteins at poly saccharide surfaces. Q. Huang 10:35 34. Milk protein nanotubes: Formation, structure and stability of a-lactalbumin nanotubes for application in food and non-food systems. C. G. de Kruif 11:00 35. Design and function of protein based microrods and microspheres. E. van der Linden Section Β
Section Β McCormick Place Lakeside Room E264, Level 2
McCormick Place Lakeside Room E259, Level 2
Natural Products, Diets and Cancer Prevention Metabolism, Bioavailability, and Dietary Prevention
General Papers
A. M. Rimando, N. Suh, Organizer,
Organizer Presiding
1:00 Introductory Remarks. 1:05 23. Cancer chemopreventive potential of apple juice and apple juice extracts. L Pan, H. Zessner, F. Will, K. Klimo, N. Frank, H. Dietrich, H. Bartsch, H. Becker, C. Gerhauser 1:35 24. Apple phytochemicals in the pre vention of cancer: Mechanisms of action. R. H. Liu 2:05 25. Modulation of the carcinogen activa tion and cellular signaling pathways by naturally occurring plant phenols. W. Baer-Dubowska, R. Mikstacka 2:35 26. Bioavailability issues in studying the health effects of plant polyphenol^ com pounds. C. S. Yang, J. D. Lambert, S. Sang 3:05 Intermission. 3:15 27. Natural products and their pleiotropic interactions with molecular targets: Toward the molecular basis for cancer chemoprevention. A. D. Mesecar, A. L. Eggler, B. Calamini, R. B. van Breemen, J. M. Pezzuto 3:45 28. Inducers of the Phase 2 response: Combined direct and indirect antioxidant protection against electrophiles and oxi dants. A. T. Dinkova-Kostova 4:15 29. Translating knowledge generated by epidemiological and in vitro studies into dietary cancer prevention. Ε. Η. Jeffery, R. M. Bheemreddy, R-H. Lai
Please refrain from using cellular telephones and cameras during technical sessions.
A. M. Rimando, M. Appell,
Organizer
Presiding
8:15 Introductory Remarks. 8:20 36. Polyphenols in common beverages enrich lower density lipoproteins and increase their oxidative resistance in vivo after human consumption of a single serving. J . A. Vinson, J. Jang, J. Yang, Y. Dabbagh, X. Liang 8:40 37. Cranberry phytochemicals: In vitro evidence for anticancer activity. C. C. Neto, A. M. Liberty, J. W. Amoroso, E. Domingues, P. E. Hart, R. A. R. Hurta 9:00 38. Blueberry skins lower plasma and liver cholesterol and triglycerides in hyper cholesterolemia hamsters. A. M. Rimando, W. H. Yokoyama, A. Patny, M. A. Avery, C. S. Mizuno 9:20 39. Developments of aroma and aroma precursor in Pinot Noir grapes and their contribution to wine aroma determined by stir bar sorptive extraction. M. C. Qian, Y. Fang 9:40 Intermission. 9:50 40. Bioassay-guided isolation of antimycobacterial compounds from Strychnos mitsherlichii and Clavija procera, two ethnomedicinal Peruvian plants. J. C. Aponte, R. E. Rojas, L. Caviedes, R. H. Gilman, C. Sarasara, W. H. Lewis, A. J. Vaisberg, G. B. Hammond 10:10 4 1 . Bioactivity-guided isolation of in vitro quinone reductase (QR) inducing agents from soybean (Glycine max ssp.). B. Boiling, K. L Parkin 10:30 42. 2'-EpAorobanchol and solanacol, two unique germination stimulants for root parasitic weeds produced by tobacco plants. X. Xie, D. Kusumoto, Y. Takeuchi, K. Yoneyama, Y. Yamada 10:50 43. Innovative modified gum acacia: A potential emulsifier for beverage emul sions. N. Naouli, R. S. Riefler, G. Andon 11:10 44. Comparison between Raman and near-infrared spectroscopic measurement of glucose and urea in bovine blood ultrafiltrate. M. Ren, M. A. Arnold
AGFD 11:30 45. Studies on phytosterols in bamboo shoot using UPLC-APCI-MS. B. Lu, X. Wu, Y. Zhang MONDAY AFTERNOON Section A McCormick Place Lakeside Room E264, Level 2 Micro/Nano Encapsulation of Active Food Ingredients Novel Characterization Methods and Theoretical Approaches Q. Huang, P. Given, M. C. Qian, and W . H. Yokoyama, Organizers 1:15 Introductory Remarks. 1:20 46. Molecular packing in glassy carbo hydrates: Implications for encapsulation and biostabilization. J. Ubbink, D. Kilburn, J. Claude, S. Townrow, A. Alam 1:45 47. Design of multilayered biopolymer interfacial films for enhanced emulsion stability and for controlled release: A theoretical study. R. Ettelaie, E. Dickinson, A. Akinshina 2:10 48. Assembly and disassembly of biopolyelectrolyte multilayers and their potential for the encapsulation and con trolled release of active ingredients from foods. R. Parker, J. Moffat, T. Noel, S. G. Ring 2:35 Intermission. 2:55 49. Transport mechanisms in the micellar solubilization of emulsion droplets. S. R. Dungan 3:20 50. Real time monitoring of interactions occurring in oil-in-water emulsions: Diffus ing wave and ultrasonic spectroscopy. M. Alexander, J. Liu, M. Corredig 3:45 5 1 . Characterization of encapsulated ingredients. N. K. Vail, J. D. Oxley Section Β McCormick Place Lakeside Room E259, Level 2 Graduate Student Symposium C. J . Brine,
Organizer
1:30 Introductory Remarks. 1:35 52. Development of hypoallergenic fermented soybean products. Y. S. Song, J. Frias, E. de Mejia 2:05 53. Anticancer potential and mecha nisms of lunasin and soy protein hydrolysates. W. Wang, E. de Mejia 2:35 54. Evaluation mechanism of resistance by Fusarium to the manzamine alkaloids. N. Kasanah, A. G. Shilabin, L. A. Lucas, D. E. Wedge, M. T. Hamann 3:05 Intermission. 3:20 55. Ursolic acid and proanthocyanidins from cranberry( Vacc/n/tvm macrocarpon) inhibit colony formation and proliferation in HCT-116 and HT-29 colon and MCF-7 breast tumor cells. A. M. Liberty, P. E. Hart, C. C. Neto 3:50 56. Enhancing the availability of wholegrain wheat antioxidants through postharvest treatments and improving process ing conditions. J. Moore, L. Yu 4:20 57. Scavenging of reactive carbonyl species by dietary compounds. D. Tan Section C McCormick Place Lakeside Room E354A/B, Level 3 General Posters A. M. Rimando, D. Weerasinghe,
Organizer Presiding
2:00-4:00 58. A survey of the alpha-mangostin content of commercial mangosteen beverages. W. G. Geilman, B-N. Zhou, B. J. West 59. Garcinia mangostana liquid dietary suppplement-Mango.xan®: Its anti-inflam matory effects. A. K. Palu, W. G. Geilman, B. J. West
60. Long term feeding trial with grapefruit flavonoids. E. G. Miller, M. H. Wasson, S. E. Taylor, R. D. Spears, G. K. Jayaprakasha, B. S. Patil 61. Isolation and identification of flavonol glycosides in American cranberry fruit using HPLC and GC-MS. Y. Zuo, H. Chen, Y. Deng 62. Distribution of catechins, epicatechins, and methylxanthines in green tea available in regular and decaffeinated form. S. Kafley, M. G. Ondrus, C. Rohrer 63. Effect of extraction parameters on poly phenols in caffeinated and decaffeinated green tea. S. G. Gudala, M. G. Ondrus, C. Rohrer 64. Effects of shelf-life on phytonutrients in beer beverages. C. Rohrer, S. Majoni 65. Quantitative combination effects between sulforaphane and 3,3'-diindolylmethane on proliferation of human colon cancer cells in vitro. G. Pappa, H. Bartsch, C. Gerhauser 66. Methylothiostilbenes as inhibitors of CYP1A1, CYP1A2 and CYP1B1 activities. R. Mikstacka, W. Baer-Dubowska, M. Wieczorek, S. Sobiak 67. Varietal differences in phenolic content and antioxidant activity of asparagus. E. Cakir, V. Sweet, J. Tang, J. R. Powers 68. Phenolic content and inhibitory activity of aldose reductase of medicinal plant extracts from several genera. J. Gavillân-Suârez, M. A. Ramirez-Vicéns, M. C. Quinones, Y. Rivera 69. Effects of nitrogen application on the antioxidant properties of basil (Ocimum basilicum L ) . P. M. Nguyen, D. R. Taub, E. D. Niemeyer 70. Selective analysis of 4-hydroxyproline and proline in gelatin hydrolysates using LCIPAD. J. Russell, M. Koppang 7 1 . Chemical characteristics and anticoagulant activity of sulfated polysaccharide fractions from Monostroma latissium. W. Mao, H. Zhang, H. Li 72. Polysaccharides from marine green seaweed Ulva pertusa and their characteristics. W. Mao, X. Zang 73. Physicochemical properties of partially hydrolyzed waxy rice starches. J-S. Shin, S. H. Yoo, C-T. Kim, C-S. Park, M-Y. Baik 74. Correlation between gluten protein composition and rheological properties. G. Liu, L Li, B. Li, Q. Lu, L Chen, L Han 75. Effect of content of wet gluten of wheat flour on rheological properties. L. Li, G. Liu, B. Li, Q. Lu, S. Guo 76. Effects of pressing procedure and storage conditions on the rheology and microstructure of Queso Blanco. M. H. Tunick, D. L. Van Hekken, P. H. Cooke 77. Effect of ultrasound on the stability of casein in pasteurized milk. B. Li, W. Xiong, L. Li, L. Chen 78. Effect of microwave radiation on the physicochemical properties of maize starches. Z. Luo 79. Effect of roasting temperature and time on physicochemical characteristics of roasted soybean powder. J. H. Eo, M. Park, F. H. Hsieh, J . B. Eun 80. Tensile strength and sorption characteristics of stearic acid-cysteine-soy protein isolate blend films. L. Li, G. Liu, B. Li, Q. Lu, L Chen, G. Huang 8 1 . Encapsulation of MCT oil in modified starches by spray drying. H. Yoshii, M. Yasuda, H. Tobe, T. L. Neoh, T. Furuta 82. Kinetics of molecular encapsulation of 1-methylcyclopropene into a-cyclodextrin. T. L. Neoh, K. Yamauchi, H. Yoshii, T. Furuta 83. Pyrolysis of agricultural waste over nanoporous materials from zeolites. M. Yu, S. K. Ahn, S. I. Chang, J. Y. Koo, J. Y. Lee, Y-K. Park 84. Microalgae culture for wastewater treatment and biodiesel production. F. Yu, Q. Kong, P. Chen, R. Ruan 85. Phytotoxicity of trichothecenes using an Arabidopsis detached leaf assay. S. P. McCormick, A. E. Desjardins, M. Appell 86. Subterranean termite (Reticulitermes speratus) and common cutworm (Spodoptera litura) antifeedants in tropical Asia Resak. M. Morimoto, H. Fukumoto, Y. Fukuda, T. Kitayama, K. Komai
87. Migration and diffusion of common antioxidant additives from and through food contact polymers. W. M. Heiserman, W. Limm, T. H. Begley, R. A. Walker 88. Mineral contents in seed coat and canning quality of selected cultivars of dark red kidney beans (Phaseolus vulgaris L ) . A. K. Anderson, X. J. Wu 89. Changes of physicochemical characteristics and volatile flavor compounds of Jinyangju, a Korean traditional rice wine sterilized at different temperatures. J. B. Eun, T. Y. Jin, S. H. Choi 90. Stability of fat soluble vitamins in commercial vitamin tablets during storage. J-H. Kim, S. H. Yoo, C-S. Park, M-Y. Baik 91. NMR state diagram application study: Maillard reaction in model storage systems around transition point temperature. J. Zhang, R. Ruan, X. Lin, P. Chen, F. Yu 92. Nondestructive detection of deep muscle bruising in salmon by near infrared spectroscopy. A. G. Cavinato, M. M. Hammers, D. M. Mayes, M. Lin, B. A. Rasco 93. Nonlethal detection of bacterial kidney disease in Pacific salmon by near infrared spectroscopy. A. G. Cavinato, T. L. Boethin, M. M. Hammers, K. Troutman, T. Hoffnagle, A. Greenlee 94. Reduction of parasites and diseases in honeybees. E. J. Geels, A. Korver, S. Hanenberg 95. Ab initio study of acetylated derivatives of deoxynivalenol and nivalenol. M. Appell, S. P. McCormick, A. E. Desjardins 96. HPLC Determination of chlorate metabolism in ruminai fluid. R. C. Beier, M. E. Hume, R. C. Anderson, C. E. Oliver, T. R. Callaway, T. S. Edrington, D. J. Nisbet 97. Development of a method for the determination of copper (Cu), iron (Fe) and nickel (Ni) in edible oils by graphite furnace atomic absorption spectrometry (GFAAS). R. Boisvert, N. Boivin, A. Santagati 98. Recognition and inhibition of B. cereus spores in milk and juice using glycoconjugates. P. Bobryshev 99. Isolation and physicochemical characterization of EU rubber from Eucommia ulmoides leaves. Y. Su, J. Peng, Q. Sun, J. Yue, N. Yoshihisa, R. Sun 100. Studies and development of a new method for effective extraction of the alkaloids from Lotus stem. Q-L. Feng, D-Q. Liu, F. Lv 101. GC/MS analysis of the chemical constituents of mint volatile oil in the county of Shangri-La, Yunnan province. Y. Yu Sr., Z. Guo Sr. 102. Detection of glutathione/glutahione-Stransferase interaction by surface plasmon resonance with BSA-modified chip. L. Chen 103. Detection of potato virus by microarray and RT labeling method. N. He, Y. Gu, J. Chen, S. Li 104. Protein engineering of Sulfolobus solfataricus maltooligosyltrehalose synthase to alter its selectivity. T-Y. Fang, W-C. Tseng, C-H. Pan, Y-T. Chung 105. Detection of potato spindle tuber viroid using RNA hybridization chips. N. He, Y. Gu, J. Chen, S. Li 106. Assessment of hydrogen bonds between maltooligosyltrehalose synthase and pentamaltose by computer simulation and site directed mutagenesis. W-C. Tseng, T-Y. Fang, C-R. Lin 107. Kinetic model of ultrasound-assisted supercritical carbon dioxide extraction. D-L Luo Sr., Y. Nie III, J-Y. Guo Sr. 108. Mechanism of ultrasound-assisted extraction in supercritical carbon dioxide reverse microemulsions. D-L. Luo Sr., Y. Nie III, T-Q. Qiu Sr. 109. Synthesis of medium chain triglycerides utilizing camphor seed oil. D-L. Luo Sr., Y. Nie III 110. Study on purification and stability of the pigment from fructus rhodomyrti. H. Ruqiang Sr., D. Qian Jr., D. Weiling Jr., L. Chunhong Jr. 111. Preservation of idli batter: A hurdle approach. P. Nisha, L. Ananthanarayan, R. W. Sabnis 112. Synthesis of a new dendritic oligosaccharide with alkyl spacer. T. Yoshida 113. Withdrawn.
M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center
Sci-Mix A. M. Rimando, Organizer,
Presiding
8:00-10:00 58-60, 64-66, 7 1 , 76-77, 80, 83-84, 86, 90-91, 93, 95, 9 8 , 1 0 2 , 1 0 5 , 1 1 2 . See previous listings. TUESDAY MORNING Section A McCormick Place South Room S103A, Level 1 Micro/Nano Encapsulation of Active Food Ingredients Assembly of Novel Delivery Systems Q. Huang, P. Given, M. C. Qian, and W. H. Yokoyama, Organizers 8:30 Introductory Remarks. 8:35 114. USDA nanotechnology research and development for improving food quality and value. H. Chen 9:00 115. Novel ingredient delivery systems using nanosome technology. W. Haehnlein 9:25 116. Modulating lipid delivery in food emulsions. P. J. Wilde, M. J. Ridout, A. R. Mackie, M. S. J. Wickham, R. M. Faulks 9:50 Intermission. 10:10 117. Formation of single surfactant microemulsions. H. L. Rosano, N. Naouli, J. L. Cavallo, G. E. Krammer 10:35 118. Lipid structures as delivery vehicles in foods. P. R. Smith 11:00 119. Benefits of a soy lecithin based nanotechnology for the animal and human food industry. S. E. Peters, C. H. Brain TUESDAY AFTERNOON Section A McCormick Place South RoomS103A, Level 1 Micro/Nano Encapsulation of Active Food Ingredients Assembly of Novel Delivery Systems Q. Huang, P. Given, M. C. Qian, and W. H. Yokoyama, Organizers 1:15 Introductory Remarks. 1:20 120. Complex coacervate core micelles as potential carriers of functional ingredients. W. Norde 1:45 121. Nano- and microparticles from globular proteins: Applications to controlled release of food ingredients. M. Subirade, L. Chen, C. Mercier 2:10 122. Nano, microencapsulation of bioactive macromolecules for controlled release delivery (nanoshells and clay nanotubules). Y. M. Lvov 2:35 Intermission. 2:55 123. Nanoencapsulation systems based on milk proteins and phospholipids. H. Singh 3:20 124. Controlled self-organization of zein nanostructures for encapsulation of active food ingredients. Q. Wang, G. W. Padua 3:45 125. Green nanocomposites films for food encapsulation. A. K. Mohanty 4:10 126. Materials for encapsulation of food ingredients: Understanding the properties to find practical solutions. C. MeCrae, B. Guthrie, J. Heigis, G. Mondro, W. Shieh
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-7
TECHNICAL PROGRAM
AGFD/AGRO WEDNESDAY MORNING Section A McCormick Place South RoomS103A, Level 1 Micro/Nano Encapsulation of Active Food Ingredients Novel Delivery Systems for Health Promotion Applications Q. Huang, P. Given, M. C. Qian, and W . H. Yokoyama, Organizers 8:30 Introductory Remarks. 8:35 127. Micellar cubic structures, QL, and micellosomes for improved solubilization and bioavailability on nutraceuticals. N. Garti, R. Efrat 9:00 128. Solubilization and crystallization kinetics of lipophilic materials into nm-size O/W emulsion. K. Sato 9:25 129. BioSwitch: A release-on-demand delivery system. H. Boumans 9:50 Intermission. 10:10 130. Enhancing stability and bioavail ability of polyphenols using nanoemulsions. X. Wang, Y-W. Wang, Q. Huang 10:35 131. Enhancement of microcapsule barrier properties. J. D. Oxley, Ν. Κ. Vail 11:00 132. Microencapsulation using coacervation for delivery of omega-3 oils into foods. C. J. Barrow, Y-L. Jin, J. Curtis, S. Cloutier WEDNESDAY AFTERNOON Section A McCormick Place South RoomS103A, Level 1 Micro/Nano Encapsulation of Active Food Ingredients Novel Delivery Systems for Flavor/Aroma Applications Q. Huang, P. Given, M. C. Qian, and W . H. Yokoyama, Organizers 1:15 Introductory Remarks. 1:20 133. Delivering flavor: From the molecu lar to the sensory level. A. J . Taylor, R. S. Linforth, J. Hort 1:45 134. Citrus and vegetable oil microemulsions. N. Naouli, H. L Rosano 2:10 135. Capped mesoporous silica nanoparticles for controlled release of drugs, proteins, nutrients, and flavor chemicals. V. S-Y. Lin 2:35 Intermission. 2:55 136. Delivering flavorings via spray chilling. J. M. Finney, G. A. Reineccius 3:20 137. Approaches to encapsulation of active food ingredients in spray drying. A. Millqvist Fureby 3:45 138. Shelf-life oxidation study of coacervated orange oil. D. J. Paetznick, G. A. Reineccius
10:35 145. Analysis of phenolics and glucosinoiates in broccoli seeds and sprouts. M. Berhow, G. N. Jham, S. F. Vaughn, B. Tisserat, S. M. Duval 10:55 146. In vivo studies of the anti-inflam matory actions of citrus polymethoxylated flavones. J. A. Manthey 11:15 147. Separation techniques impact proanthocyanidin bioactivity and degree of polymerization. J. L. Alwerdt, D. Seigler, E. DeMejia, G. Yousef, M. A. Lila THURSDAY AFTERNOON Section A McCormick Place South RoomS103A, Level 1 Functional Plant Phenolics Functionality of Phenolics in Biological Systems M. Berhow,
Organizer
1:15 Introductory Remarks. 1:35 148. Induction of cytochrome P450 monooxygenases by allelochemicals ameliorates xenobiotic toxicity in Helicoverpa zea. Z. Wen, R. S. Zeng, G. Niu, M. R. Berenbaum, M. A. Schuler 1:55 149. Antimicrobial activity of an apple extract. J. J. Willie 2:15 150. Manipulating the lipid resorcinol pathway to enhance plant allelopathy. F. E. Dayan, D. Cook, S. R. Baerson, Z. Pan, A. Rimando, S. O. Duke 2:35 151. Phenolic bioavailability: Roles of gut microbes. S. Hendrich 2:55 152. Activity of plant phenolics function ing as sources of insect resistance in plants. P. F. Dowd, R. O. Musser, Ε. Τ. Johnson 3:15 153. Feruloylated vegetables oils: Synthesis and applications of UV-absorbing/antioxidative lipids. D. L. Compton, J. A. Laszlo 3:35 154. Phenolics from purple carrots have higher radical scavenging activity. G. Jayaprakash, J. B. Patil, B. Patil 3:55 155. Transgenic phenolic production in corn silks moderately enhances insect resistance. E. T. Johnson, M. Berhow, P. F. Dowd 4:15 156. Exogenous carbon applications enhances the simultaneous occurrence of growth, morphogenesis and rosmarinic acid levels in spearmint plantlets in vitro. B. Tisserat, M. Berhow, S. F. Vaughn
AGRO Division of Agrochemicals J. J. Johnston and L. L. McConnell, Program Chairs
THURSDAY MORNING Section A McCormick Place South RoomS103A, Level 1 Functional Plant Phenolics Analysis and Evaluation M. Berhow,
BUSINESS MEETING: Business Meeting: Sun
Organizer
8:30 Introductory Remarks. 8:35 139. Circular dichroism, a powerful tool for definition of the absolute configuration of proanthocyanidins. D. Ferreira 8:55 140. Withdrawn. 9:15 141. Polyphenols in Mate tea depend on cultivation and preparation conditions. C. Heck, E. de Mejia 9:35 142. Recent development in application of polyphenols in polymer materials. Q. Shen, L-H. Zhang 9:55 143. Polyphenols in white tea and their stability during storage. E. de Mejia, H. C. Lin 10:15 144. Influence of sample preparation on assay of functional phenolic phytochemicals. D. L. Luthria
8-TECH
SOCIAL EVENTS: AGRO Symposium Ideas & Organizer Info: Wed Grad Student Luncheon: Mon Social Hour: Tue
8:55 2. Current and future giyphosate-resis tant crops of Monsanto. G. M. Dill Jr. 9:20 3. New multiple herbicide crop resis tance and formulation technologies to augment the utility of glyphosate. J. M. Green, C. B. Hazel, D. R. Forney, L M. Pugh 9:45 4. Athenix technology for GRCs. N. Duck, B. VandeBerg, V. Heinrichs, L. Schouten, N. Carozzi, M. Koziel 10:10 Intermission. 10:25 5. Grower perceptions and experi ences with giyphosate-resistant weeds. C. Foresman, L. Glasgow 10:50 6. Glufosinate-resistant crops. J. Fischer 11:15 7. Economic impact of giyphosateresistant crops. L. P. Gianessi Section Β McCormick Place East Room E267, Level 2 Young Scientist Pre- and Post-Doctoral Research Award Symposium Cosponsored with WCC A. S. Felsot, Organizer,
8:25 Introductory Remarks. 8:30 8. Microwave-assisted synthesis of /V-vanillylformamide. Μ. Μ. Bobylev, B. D. Keller 8:50 9. Progress in synthesis and evaluation of potential nestmate recognition cues in the Argentine ant (Linepithema humile). R. Sulc, K. J. Shea, N. D. Tsutsui, M. Eîrandt, C. W. Torres, M. Lagrimas 9:10 10. Development of new recyclable technologies for the production of biodiesel from soybean oil at room-temperature. V. R. Chinta Reddy, J. G. Verkade 9:30 11. Bacterial degradation of toxaphene and DDT in laboratory microcosms and mesocosms. Y. Cheng, A. Ogram 9:50 12. Effect of manganese and copper on the transformation of tetracycline antibiotics. W-R. Chen, C-H. Huang 10:10 Intermission. 10:25 13. Fate and transport of biosolidsborne triclocarban. E. A. Hodges, G. A. O'Connor 10:45 14. Environmental studies on the fate of pharma proteins produced in transgenic corns. H. Kosaki, J. Wolt, J. R. Coats 11:05 15. Phototransformation of penoxsulam in aqueous methanol and acetonitrile. S. K. Pramanik, A. Bhattacharyya 11:25 16. Laboratory evaluation of the environmental fate of two monoterpenoid insecticides: Thymol and phenethyl propionate. D. Hu, J. R. Coats 11:45 17. In vitro reduction of sodium 3 6 CIchlorate in bovine ruminai fluid. C. E. Oliver, M. L. Bauer, J. S. Caton, R. C. Anderson, D. J. Smith SUNDAY AFTERNOON Section A McCormick Place East Room E265, Level 2 Glyphosate-Resistant Crops and Weeds: Present and Future Evolved Glyphosate-Resistant Weeds and Weed Shifts S. Powles,
Organizer
S. O. Duke, Organizer, SUNDAY MORNING Section A McCormick Place East Room E265, Level 2 Glyphosate-Resistant Crops and Weeds: Present and Future Glyphosate-Resistant Crops and Their Economic Impacts S. O. Duke,
Organizer
S. Powles, Organizer,
Presiding
8:30 1 . Glyphosate: A once-in-a-century herbicide. S. O. Duke, S. B. Powles
Presiding
Presiding
1:30 Introductory Remarks. 1:35 18. Giyphosate-resistant weeds in North America: The reasons and future implications for US agriculture. J. W. Wilcut, I. C. Burke 2:00 19. Giyphosate-resistant weeds of South America: An overview. M. M. Vila-Aiub, R. A. Vidal 2:25 20. Giyphosate-resistant weeds in Australia, Asia, Africa, and Europe. S. B. Powles, S. O. Duke 2:50 Intermission. 3:05 2 1 . Evaluating an altered target-site variant of EPSPS for glyphosate resistance. R. D. Sammons, M. Alibhai, S. Flasinski, A. Boland, C. Kavanaugh, Y. Qi, J. You, S. Reiser
3:30 22. Resistance to glyphosate from altered translocation patterns. C. Preston, A. M. Wakelin 3:55 23. Weed species shifts in GRCs. M. D. K. Owen Section Β McCormick Place East Room E267, Level 2 Young Scientist Pre- and Post-Doctoral Research Award Symposium Cosponsored with WCC A. S. Felsot,
Organizer
1:30 24. Synthesized pheromone summons female sea lamprey into traps. N.S.Johnson, W.Li 1:50 25. Mosquito repellents: Studies on natural product structure-activity. G. E. Paluch 2:10 26. Solving the mystery of ladybug's noxious odor. L. Cai, J. A. Koziel, M. O'neal 2:30 27. Conjugated linoleic acid: A potential insect control agent. L. J. Gereszek, J. R. Coats, D. C. Beitz 2:50 Intermission. 3:05 28. Investigating the mechanisms of glyphosate resistance in Lolium multiflorum. A. Perez-Jones, N. Polge, J. Colquhoun, C. A. Mallory-Smith 3:25 29. Chemical and biological availabili ties of sediment-associated pyrethroid insecticides. J . You, S. Pehkonen, M. J. Lydy, D. P. Weston 3:45 30. Herbicide-induced hypoxic stress and hemoglobin gene regulation in an aquatic insect. T. D. Anderson, Κ. Υ. Zhu 4:05 3 1 . Development of methods to deter mine the aquatic fate and non-target effects of transgenic Bt proteins on aquatic invertebrates: Toward risk assessment. K. R. Prihoda, J. R. Coats Section C McCormick Place East Room E266, Level 2 Veterinary Pharmaceuticals in the Environment K. L. D. Henderson and J. R. Coats, Organizers, Presiding 1:30 Introductory Remarks. 1:35 32. Fate of chlorate salts excreted from animals. D. J. Smith, C. E. Oliver, H. Hakk, R. C. Anderson, G. L Larsen 2:00 33. Mobility of a veterinary antibiotic tylosin in agricultural soil columns. D. Hu, K. L Henderson, J. R. Coats 2:25 34. Comparative biotransformation of fluoroquinolone antibiotics in matrices of agricultural relevance. H. G. Wetzstein, J. Schneider, W. Karl 2:50 Intermission. 3:05 35. Abiotic transformation of tetracycline antibiotics in a natural surface water and in the presence of M n 0 2 . K. F. Rubert IV, C. J. Hedman, J. A. Pedersen 3:30 36. Livestock hormones in the environ ment. Y-W. Huang, J. M. Bandeff 3:55 37. CAFOs and emerging contami nants: Research by the USGS TOXICS Program. D. W. Kolpin, M. T. Meyer, L B. Barber, Ε. Τ Furlong, S. K. Haack, M. R. Burkhardt, J. L. Gray, K. A. Loftin
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
AGRO
MONDAY MORNING
MONDAY AFTERNOON
Section A
Section A
McCormick Place East Room E265, Level 2
McCormick Place East Room E265, Level 2
Glyphosate-Resistant Crops and Weeds: Present and Future Resistance Management and IPM Aspects
Glyphosate-Resistant Crops and Weeds: Present and Future Health and Environmental Aspects of Glyphosate-Resistant Crops
S. O. Duke,
Organizer S. Powles,
S. Powles, Organizer,
Presiding
8:45 38. Simulation modeling to aid in glyphosate-resistance management. P. Neve 9:10 39. Sustainable use of glyphosate in North American cropping systems. D. I. Gustafson 9:35 40. Sustaining glyphosate in South American cropping system. P. J. Christoffoleti, J. B. Galli, D. N. Ribeiro, B. A. B. Martins, M. S. Moreira 10:00 Intermission. 10:15 4 1 . Managing the risk of glyphosate resistance in Australian glyphosate-resistant cotton production systems. J. Werth, C. Preston, I. Taylor, G. Charles, G. Roberts, J. Baker 10:40 42. Impacts of conservation crop production systems on soil and water resources: Glyphosate-resistant crops (GRCs) are part of the management toolbox. M. A. Locke, R. M. Zablotowicz, Κ. Ν. Reddy 11:05 43. Disease control activities of glyphosate in glyphosate-resistant crops. P. C. Feng, P. M. Caldwell, G. J. Baley, F. C. Kohn Section Β McCormick Place East Room E267, Level 2 Veterinary Pharmaceuticals in the Environment K. L. D. Henderson and J . R. Coats, Organizers, Presiding 8:20 44. Environmental risk assessment of tylosin, narasin, and monensin. A. N. Perkins, R. D. Meyerhoff, A. Kelly, J. S. Teeter, S. D. Banks 8:45 45. Risks of agricultural pharmaceuti cals in surface waters and soil. K. R. Solomon, L. Lissemore, D. Hillis, P. K. Sibley 9:10 46. Characterization of chlortetracyclineinduced glutathione S-transferase to conju gate chloroacetanilide and chlorotriazine herbicides. M. H. Farkas, J. O. Berry, D. Aga 9:35 47. Risk assessment considerations for veterinary medicines in aquatic ecosys tems. B. W. Brooks, D. B. Huggett, R. A. Brain, G. T. Ankley 10:00 Intermission. 10:15 48. Targets, effects and risks in aquatic plants exposed to veterinary antibi otics. R. A. Brain, K. R. Solomon, B. W. Brooks 10:40 49. From laboratory results to field findings: Perception vs. reality on the effects of veterinary medicinal products (VMPs) toward non-target organisms. Z.Yan 11:05 50. Risks from veterinary medicines in the environment to humans and ecosys tems. A. B. A. Boxall
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizer
S. O. Duke, Organizer,
Presiding
1:35 Introductory Remarks. 1:40 5 1 . Pollen vs. seed movement: Gene migration from glyphosate-resistant crops. C A. Mallory-Smith 2:10 52. Fate of glyphosate in soil and the possibility of leaching to ground and sur face waters. Ο. Κ. Borggaard, A. L Gimsing 2:40 53. Safety assessment of GR genes in food and feed. W. F. Heydens 3:10 Intermission. 3:25 54. Assessing the environmental conse quences of glyphosate-resistant weeds in the US. G. C Nelson, J. G. Gardner, D. S. Bullock 3:55 55. Comparison of environmental effects of glyphosate-resistant crops vs. what they replace in Europe. G. A. Kleter 4:25 56. Glyphosate and hormesis: Environ mental implications. E. D. Velini, E. Alves, M. C. Godoy, D. K. Meschede, S. O. Duke 4:55 Panel Discussion.
M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Sci-Mix J. J . Johnston, Organizer,
Presiding
8:00-10:00 73, 75-76, 79-81, 85, 87, 93-94, 98,100, 102-109. See subsequent listings. TUESDAY MORNING Section A McCormick Place Lakeside Room E354, Level 3 General Posters
Section Β
J. J . Johnston,
McCormick Place East Room E267, Level 2 Veterinary Pharmaceuticals in the Environment K. L. D. Henderson and J. R. Coats, Organizers, Presiding 1:30 57. Evaluation of the fate of erythromy cin A in aquaculture sediments. Y-H. Kim, C E. Cerniglia 1:55 58. Bioavailability of veterinary antibiot ics in surface water. K. L. D. Henderson, T. B. Moorman, J. R. Coats 2:20 59. Oxytetracycline at environmental interfaces studied by nonlinear optics. P. L Hayes, J. M. Gibbs-Davis, M. J. Musorrafiti, A. L. Mifflin, K. A. Scheldt, F. M. Geiger 2:45 60. Sorption, fate, and transport of endogenous steroid hormones in soils. H. Hakk, F. X. M. Casey, G. L. Larsen 3:10 Intermission. 3:25 6 1 . Sorption behaviors and binding mechanisms of ibuprofen with AI and Fe oxides and kaolinite. X. Huang, G. D. Foster 3:50 62. Degradation and bioavailability of sulfamethazine in pond water microcosms. T. B. Moorman, K. L. Henderson, J. R. Coats 4:15 Concluding Remarks. Section C McCormick Place Lakeside Room E272a, Level 2 General AGRO Papers: New Developments and Issues in Agrochemical Sciences J. J . Johnston, Organizer,
3:25 67. Real-time detection of organophosphorus pesticides using carbon nanotubebased, field-effect transistor. Y. Lei, N. Liu, Q. Zhang, W. Chen, A. Mulchandani 3:50 68. Topical insect repellent based on refined oil of Nepeta cataria. Y. I. Gonzalez, D. L. Hallahan 4:15 69. Uptake and translocation of resi dues into strawberry plants from 1 4 Cfurfural treated soil. M. F. Kovacs Jr., A. C. Katz, G. J. Burger, M. E. Dix, D. Teixeira 4:40 70. Role of mineral phosphorus fertiliza tion on corn (Zea mays L.) Cd upptake. M. Lâszlc-, B. S. Panwar, M. S. Grevai
Presiding
1:30 63. Effect of nonionic surfactants on the oxidation of carbaryl by anodic Fenton treatment. L. Kong, A. T. Lemley 1:55 64. Odorants from anaerobically-digested food waste and swine slurry. H. Kim, I. Lee, S-G. Hong 2:20 65. Moved to General Posters 2:45 66. Method development for multiresidue pesticide extraction from natural and processed foods. R. E. Hunter Jr. 3:10 Intermission.
Organizer
8:00-10:00 Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and GIS. 65. Determination of pesticide levels in human urine using high pressure liquid chromatography-tandem mass spectroscopy. J. E. Norrgran, R. Bravo, P. A. Restrepo, R. D. Walker, D. B. Barr 71. Using GIS data to discern sources for pesticide runoff contributions to the Choptank River watershed. C. J. Hapeman, W. D. Hively, M. Lang, L. L. McConnell, C. P. Rice, G. W. McCarty, T. R. Fisher, A. M. Sadeghi 72. Review of published studies on agricultural field buffer strip performance. S. H. Jackson, W. Chen, A. F. Rose, P. L. Havens, M. Thompson, T. S. Ramanarayanan, J. Hanzas, P. Hendley 73. Web based on-demand report and GIS data generation for a nationwide, potablewell monitoring program. A. C. Newcombe, K. G. Peterson 74. Framework for detailed endangered species determination development in support of pesticide product registration. J. M. Giddings, D. Howes, B. D. McGaughey 75. Tiered approach to the use of best available data on species locations in pesticide assessments on endangered species. B. D. McGaughey, D. Howes, K. H. Carr, A. T. Hall, S. Wall 76. FitoMarche: A tool to assess pesticide vulnerability maps and to estimate pesticide leaching in a stochastic way. M. Balderacchi, A. Di Guardo, M. Trevisan, C. Vischetti 77. Rural domestic well sensitivity: A case study for a shift from a pure hydrogeologic/detection analysis to a coupled hydrogeologic/detection/contextual study construct. P. Miller, C. M. Harbourt, J. J. Prenger, P. Hendley 78. Using a combination of NASS cropping data and market research information to improve the spatial resolution of pesticide use estimates. C M. Holmes, P. Hendley, J. Amos 79. GeoSTAC: Enabling efficient environmental assessments. A. M. Wadley, M. F. Winchell, C. M. Holmes, J. Amos, R. Srinivasan, D. J. Healy, P. L. Havens, D. A. Staats
80. GIS toolset to streamline pesticide exposure vulnerability analysis of community drinking water sources. T. S. Ramanarayanan, Z. Tang, R. Srinivasan, M. F. Winchell 81. Assessment of spatial exposure vulnerability using a watershed regression model. Z. Tang, T. Ramanarayanan 82. Measured impact of herbicide tolerant corn on occurrence of conventional corn herbicides in surface water. Κ. Η. Carr, D. I. Gustafson Agricultural Biomass, Biobased Products, and Biofuels. 83. Near-critical hydrolysis of lignocellulosic biomass. L Ngo Tenlep, D. E. Raynie 84. Amine hydroxy derivative of soybean oil as a lubricant additive. B. K. Sharma, A. Biswas, S. Z. Erhan 85. Direct production of bioethanol from raw starch by immobilized yeast cells surface engineered with amylolytic enzymes. J-P. Chen, K-W. Wu 86. Succinoylation and characterization of cellulose in ionic liquid. C. F. Liu, R. Sun, A. P. Zhang, J. L Ren 87. Coumarin derivatives as novel antifungal seed treatments. Y. V. Kuzmichev, J. C. Laas, R. R. Pavlis, N. L. Brooker 88. Bioconversion and optimization of potato waste to lactic acid. D. P. Adhikari, E. Ashiamah-Finch, J. Fumey, L. Kallestad, A. Frances, F-H. Chang 89. Fixed-bed, biodiesel-production technol ogy. P. Zhang, J. Jarnefeld 90. Water solubilization of lignocellulosic biorenewables via derivatization with phosphite esters. R. Oshel, M. V. Nandakumar, S. Urgaonkar, D. G. Hendricker, J. G. Verkade Glyphosate-Resistant Crops and Weeds. 91. Low dose selection for glyphosate resis tance in cross-pollinated Lolium rigidum vs. self-pollinated Avena Mua. R. Busi, S. B. Powles 92. Photosynthesis and respiration rate of Lolium multiflorum (Italian ryegrass) biotypes resistant to glyphosate. D. N. Ribeiro, P. J. Christoffoleti, R. De Prado, L. Vargas, R. Vivian, Β. Α. Β. Martins Sustainable Household, Structural, and Residential Pest Managment. 93. Biochemical and molecular characteriza tion of bivalent anticholinesterases to the malarial mosquito. T. D. Anderson, D. C. Klorig, D. Wong, P. R. Carlier, J. R. Bloomquist Sustainable Forest Pest Managment. 94. Winter detection of southern pine beetles using analytical georeferenced data. W. E. Holmes, A. E. Brown, Z. A. Parisa Veterinary Pharmaceuticals in the Environment. 95. Plant glutathione S-transferases as mediators of antibiotic detoxification. M. H. Farkas, D. Aga, J. O. Berry 96. Investigating the fate of the veterinary antibiotics monensin, lasalocid, and tylosin in agricultural systems. S. A. Sassman, L. S. Lee 97. Transformation of sulfamethazine by hydrous manganese oxides. J . Gao, J. A. Pedersen New Developments in Agrochemical Sciences. 98. Electrospray ionization mass spectroscopy shows speciation of phytate to be pH dependent. L Heighten, W. F. Schmidt, C. P. Rice, R. L. Siefert 99. Antiviral activity of Keggin-type heteropoly compounds on tobacco plants. S. Uskokovic-Markovic, M. Todrovic, U. B. Mioc, B. Krstic, N. Dukic 100. Study on chemical character and activity of polysaccharides from several marine green alga collected in different localities and periods. W. Mao, H. Sun, X. Zang 101. Ecological efficiency of use of organomineral composts in agriculture. S. B. Pardaev 102. Dissipation of bromide ion following an in-furrow application to bare soil. A. C. Newcombe, R. Speth, T. Wiepke, N. Chamkasem, S. Chen
TECH-9
TECHNICAL PROGRAM
AGRO 103. Human exposure to surface pesticide residues: Dislodgeable foliar residues and pilot studies to predict bioavailability. Y. LI, J. J. Keenan, M. M. Bigelow, Z. Chen, H. Vega, R. I. Krieger 104. Molecular modeling for screening of pesticide-nucleotide binding potentials. D. W. Boerth 105. Multiple-inlet plus intermittent rice irrigation increases rainfall capture and reduces non-point source runoff. J . H. Massey, M. C. Smith, A. B. Johnson 106. Runoff losses of three pesticides and a conservative tracer from warm-season turf using simulated rainfall. P. A. Ampin, J. H. Massey, B. R. Stewart, M. C. Smith, A. B. Johnson, R. P. Maiers, A. A. Andrews 107. Bioreporter-based chemical sensor of arsenic in agricultural samples. D. L. Schroeder, A. C. Nagel, B. D. Gross, T. S. Reed, B. Applegate, D. E. Nivens 108. Remote sensing of agricultural contaminants using biosensor networks over TCP/IP. B. D. Gross, T. S. Reed, A. Stoklosa, D. L. Schroeder, A. C. Nagel, B. Co, D. E. Nivens 109. Crystal and molecular structures of organophosphorus pesticides. G. B. Hall, R. G. Baughman 110. Influence of composts repared from tobacco wastes and phosphogypsum on the agrochemical properties of carbonate meadow soils of Zarafshan Valley. T. K. Ortikov, S. A. Khazratkulov 111. Cd, Ni, Pb, Se, and Hg bioaccumulation and phytoremediation characteristics of Crotalaria (Crotalaria juncea L.) under mineral nitrogen fertilization influence. M. Lâszlo, M. S. Grevai, B. S. Panwar 112. Triticale (X Triticosecale W.) AI, Cd, Co, Cr, Cu, Sr, Pb and Zn bioaccumulation in a long term field mineral fertilization experiment. M. Lâszlo 113. Rye (Secale céréale L.) As, Cd, Hg, Ni, Pb, and Se phytotranslocation in a longterm field fertilization experiment. M. Lâszlo 114. Phytoremediation aspects of Cd kinetics in Hungarian and Indian soils. M. Lâszlo, B. S. Panwar, M. S. Grevai 115. Impact of mineral NPK fertilization on wheat (Triticum aestivum L.) Cd, Hg, Ni, Pb, and Se translocation. M. Lâszlo, M. S. Grevai, B. S. Panwar Section C McCormick Place South RoomS105D, Level 1 International Award for Research in Agrochemicals: Symposium in Honor of Gerald T. Brooks Cosponsored with BASF Corporation D. W. G a m m o n and R. D. Wauchope, Organizers 10:15 Award Presentation. 10:30 116.1956-2006: Fifty years of insect toxicology. G. T. Brooks 11:00 117. Gerry Brooks' epoxide hydrolase: Thirty-five years to a pharmaceutical. B. D. Hammock 11:25 118. Pyrethroid action at calcium channels: Neurotoxicological implications. J. M. Clark Sustainable Resources: Science and Information Sources Sponsored by CINF, Cosponsored with AGRO, FUEL, and SUST
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
10-TECH
TUESDAY AFTERNOON
Section C
Section Β
Section A
McCormick Place South Room S105D, Level 1
McCormick Place South RoomS103D, Level 1
International Award for Research in Agrochemicals: Symposium in Honor of Gerald T. Brooks Cosponsored with BASF Corporation
Agricultural Biomass, Biobased Products, and Biofuels Process and Product Control Cosponsored with FUEL, SUST, CELL, and CINF
D. W. G a m m o n and R. D. Wauchope, Organizers
J. N. Seiber, J . H. Massey, and J. R. Barone, Organizers
McCormick Place South RoomS103B/C, Level 1 Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems Groundwater S. H. Jackson and P. Hendley, R. J. Gilliom, Organizer,
Organizers
Presiding
1:20 Introductory Remarks. R. J. Gilliom. 1:30 119. Hawaii's GIS-based screening tool for pesticide leaching assessment. C. Ray, F. Stenemo, R. Yost, S. Matsuda 1:55 120. Multivariate approaches for determining groundwater vulnerability to agrochemical movement in soil, Part 1 : Classification and regression tree analysis of California Central Valley. J. Troiano, S. Huber, F. Spurlock, J. Marade, C. Dharmasri, W. Phelps, W. Chen 2:20 121. Multivariate approaches for determining groundwater vulnerability to agrochemical movement in soil, Part 2: Cluster analysis of California statewide groundwater vulnerability. J. Troiano, F. Spurlock, J. Marade, W. Chen 2:45 122. Modeling atrazine occurrence in shallow groundwater in agricultural areas of the United States. P. E. Stackelberg, R. J. Gilliom, D. M. Wolock, N. Nakagaki 3:10 Intermission. 3:25 123. Use of a geographic information system (GIS) with process-based simulation modeling to predict atrazine concentrations in shallow groundwater across the United States: Simulation approach and testing against nationwide observations. J. E. Barbash, F. D. Voss 3:50 124. Mapping the vulnerability of European groundwater to the leaching of pesticides with a process-based metamodel of EuroPEARL. A. Tiktak, J. Boesten, M. Vanclooster
1:30 132. DDT and cyclodiene resistance: Old mechanisms give resistance to new compounds. R. H. ffrench-Constant 1:55 133. Insect P450: Diversity of structure and function. R. Feyereisen 2:20 134. Pharmacokinetic approaches to optimize insecticidal chemistry. M. G. Ford 2:45 135. Pyrethroids, knockdown resistance, and sodium channels. D. M. Soderlund 3:10 Intermission. 3:25 136. Cyclodiene-induced alterations in mammalian dopaminergic pathways as a possible cause of environmentally-induced Parkinsonism. J. R. Bloomquist 3:50 137. Bioassays for persistent organic pollutants in receptor-mediated reporter gene expression systems. H. Ohkawa, H. Inui, Y. Tanaka 4:15 138. In vitro metabolic interactions of pesticides in humans. E. Hodgson 4:40 Concluding Remarks. WEDNESDAY MORNING Section A McCormick Place South Room S103B/C, Level 1 Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems Surface Water S. H. Jackson and R. J. Gilliom, Organizers
Section Β
P. Hendley, Organizer,
McCormick Place South RoomS103D, Level 1
8:30 Introductory Remarks. P. Hendley. 8:35 139. Connecting watersheds and water quality: Understanding the transport of agricultural chemicals to streams. D. M. Wolock 9:00 140. Estimating pesticide concentrations in U.S. streams from watershed characteristics and pesticide properties. W. W. Stone, C. G. Crawford, R. J. Gilliom 9:25 141. Flow accumulation-based application of the WARP model to identify stream segments with high pesticide exposure risk. M. F. Winchell, S. H. Jackson, J. Hanzas 9:50 142. Hydrology-based screening tool for estimating catchment vulnerability to corn herbicide runoff. C. Leu, P. Sweeney 10:15 Intermission. 10:30 143. Estimating the likelihood of occurrence of selected pesticides and nutrients at specific concentrations in Coastal Plain streams on the basis of landscape characteristics. S. W. Ator, J. M. Denver, A. C. Neale, A. M. Pitchford 10:55 144. Integration of spatially detailed information to assess the role of agricultural sources in nutrient loading to the Chesapeake Bay. S. D. Preston, J. W. Brakebill 11:20 145. Regression models for explaining and predicting organochlorine pesticide concentrations in whole fish from U.S. streams. L H. Nowell, C. G. Crawford, N. Nakagaki, G. P. Thelin, D. M. Wolock 11:45 146. Examining the relative proximity of agriculture to surface water across Europe. C. M. Holmes, M. Matella, P. Hendley, P. Sweeney, S. J. Maund
Agricultural Biomass, Biobased Products, and Biofuels Defining the Challenges Cosponsored with FUEL, SUST, CELL, and CINF C. J . Hapeman, J . H. Massey, and J. R. Barone, Organizers J. N. Seiber, Organizer,
Presiding
1:20 Introductory Remarks. 1:25 125. Agricultural biomass, biobased products, and biofuels: Challenges and opportunités. G. Buchanan 1:55 126. Biomass-to-ethanol conversion: Strategies for developing flexible biorefineries. W. J. Orts, K. M. Holtman, G. M. Glenn, R. Offeman, G. H. Robertson, S. H. Imam, D. W. S. Wong 2:20 127. Chemical and physical properties of pretreated biomass that affect enzyme accessibility and digestibility. M. F. Davis, C. Ishizawa, T. Jeoh, W. S. Adney, M. E. Himmel, D. K. Johnson 2:45 128. Biodiesel: Science based regulation and consumer protection. K. L. Armbrust, J. Rodriguez 3:10 Intermission. 3:25 129. Enzyme and microbial bioconversion of agricultural and forestry residues for transportation fuel. J. D. Peterson, K. Brandon, D. Cook, E. DeCrescenzo, E. de Ximines, A. Jangid, Z. Cvetkovich, J. Young 3:50 130. Coproduction of fuel ethanol and new value added coproducts. D. B. Johnston 4:15 131. Energy balance of switchgrass grown for cellulosic ethanol in the Northern Plains, USA. M. R. Schmer, K. P. Vogel, R. B. Mitchell, R. K. Perrin 4:40 Panel Discussion.
Presiding
C. J . Hapeman, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 147. Biobased: Making it competitive and sustainable. R. Fireovid 9:00 148. Developing herbaceous energy crops as feedstocks for bioethanol produc tion. B. S. Dien, M. A. Cotta, H-J. G. Jung, K. P. Vogel 9:25 149. Alternative feedstocks for renew able green energy fuel. A. E. Brown, E. R. Easterling, E. C. Rogers, W. E. Holmes, R. Hernandez, W. T. French 9:50 150. Aspergillus flavus genomic data mining provides clues for its use in pro ducing biobased products. J. Yu, W. C. Nierman, D. Bhatnagar, T. E. Cleveland 10:15 Intermission. 10:30 151. Fully automated molecular biol ogy routines for evaluation and character ization of industrial yeast strains optimized for ethanol production from cellulosic biomass and for biobased-pesticide expression. S. R. Hughes 10:55 152. Biological abatement for removal of inhibitors from biomass sugars. N. N. Nichols, C. K. Chambliss, G. P. van Walsum, L. N. Sharma, B. S. Dien 11:20 153. FT-IR analysis of oil feedstock and biodiesel quality. J. R. Barone 11:45 154. Effects of production practices on biodiesel quality. J. Rodriguez, K. L. Armbrust Section C McCormick Place South RoomS105D, Level 1 Recent Advances in Sustainable Household, Structural, and Residential Pest Management C. J. Peterson and D. M. Stout II, Organizers 8:10 155. Biological activities of a bait toxi cant for population management of subter ranean termites. N-Y. Su 8:35 156. Metaflumizone: A semicarbazone insecticide for structural pest control from BASF. R. W. Davis, D. Calibeo-Hayes, C. Klein, J. Schuh 9:00 157. MIKRON formulation: A new process for making pesticides. D. L. Richman, J. B. Ballard 9:25 158. Natural product technologies for use in pest management. G. E. Paluch, J. R. Coats 9:50 159. Quo vadis: Recent advances in the management of German cockroaches. R. A. Suranyi, D. L. Sundquist 10:15 Intermission. 10:30 160. Initial soil penetration of aqueous termiticide solutions. C. J. Peterson 10:55 161. American healthy homes survey: A national study of residential pesticides measured from floor wipes. D. M. Stout II, K. Bradham, V. R. Highsmith, C. W. Croghan, P. A. Jones, W. Friedman, E. A. Pinzer, D. Cox, G. Dewalt 11:20 162. Residential exposure to piperonyl butoxide through pyrethroid insecticide use. M. K. Williams, D. Holmes, L. A. Hoepner, D. E. Camann, F. P. Perera, R. M. Whyatt 11:45 163. Potential for human exposures to pet-borne diazinon residues following residential lawn applications. M. K. Morgan, D. M. Stout II, P. P. Egeghy
AGRO/ANYL
WEDNESDAY AFTERNOON Section A McCormick Place South RoomS103B/C, Level 1 Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems Integrated Approaches and Spatial Data Applications S. H. Jackson and P. Hendley,
3:55 177. Biobased industrial lubricants. S. Z. Erhan, B. K. Sharma 4:20 178. Recent advances in bioconversion of agricultural biomass to butanol by fermentation: Employing potential of avail able renewable resources to produce a superior biofuel. N. Qureshi, B. C. Saha, X-L Li, S. R. Hughes, M. A. Cotta 4:45 179. Synthesis of long-chain unsaturated-a,Q)-dicarboxylic acids from renew able materials via olefin metathesis. H. L Ngo, T. A. Foglia
Organizers
Presiding
1:35 164. Assessing the potential transfer of pesticides to groundwater and surface waters throughout Europe: The EU-funded project FOOTPRINT. I. G. Dubus 2:00 165. National assessment of pesticide environmental risk from agricultural sources using a microsimulation modeling approach. R. L. Kellogg, S. Plotkin 2:25 166. ArcSWAT: A tool for parameteriza tion of common watershed water quality models and landscape characterization. R. Srinivasan, M. F. Winchell 2:50 167. GeoSTAC (GEOSpatial Tools and ACcess): A compilation of standardized geospatial data and tools for agrochemical exposure assessments. P. L. Havens, K. Carr, P. Hendley, S. Jackson, T. Ramanarayanan, D. A. Staats, M. Thomson, C. Holmes, J. Amos, A. Wadley, M. Winchell, R. Srinivasan 3:15 Intermission. 3:30 168. Development and application of spatially-distributed pesticide use information for assessing water quality. G. P. Thelin, N. Nakagaki 3:55 169. Applications of the preferential flow model MACRO to the estimation of pesticide loss in the agricultural landscape: A histori cal perspective. I. G. Dubus, N. J. Jarvis 4:20 170. A procedure to identify representa tiveness of experimental site for pesticide leaching field study at European level. M. Balderacchi, J. Hollis, C. Gustin, M. Trevisan, E. Capri 4:45 171. Preserving local variability and large scale spatial structure in semi-national assessments. C. M. Harbourt, J. Amos, P. Miller, J. J. Prenger, P. Hendley Section Β McCormick Place South RoomS103D, Level 1 Agricultural Biomass, Biobased Products, and Biofuels Process Characterization Cosponsored with FUEL, SUST, CELL, and CINF J. N. Seiber, C. J . Hapeman, and J. H. Massey, Organizers
McCormick Place South RoomS103D, Level 1
McCormick Place South RoomS105D, Level 1 Sustainable Forest Pest Management E. A. Arthur, R. Ripperger, and C. J . Peterson, Organizers, Presiding
Agricultural Biomass, Biobased Products, and Biofuels Improving Bioproduct Design Cosponsored with FUEL, SUST, CELL, and CINF
1:20 Introductory Remarks. 1:35 180. Streamside management zones for protecting water quality: A critical review of current knowledge. J. L. Michael 2:00 181. New and old methods of protection of trees against bark beetles: What works, what doesn't, and why. K. D. Klepzig, B. L. Strom, L. M. Roton 2:25 182. Efficacy of verbenone flakes for area-wide and individual tree protection from attack by mountain pine beetle in western North America. N. Erbilgin, N. Gilette, S. Mori, M. Hansen, J. Stein, J. Webster, D. Owen, G. Fiddler, D. L. Wood 2:50 183. Technological advances using disparlure for slowing the spread of gypsy moth. A. H. Onken 3:15 Intermission. 3:30 184. Imidacloprid and management of hemlock woolly adelgid in forests: Fine tuning for environmental stewardship. R. S. Cowles 3:55 185. Compatibility of eastern hemlock {Tsuga canadensis) wood tissue with an enzyme-linked immunosorbent assay for imidacloprid residue detection. B. M. Eisenback, D. E. Mullins, S. M. Salom, L. T. Kok 4:20 186. Eastern Hemlock water use: Impli cations for systemic insecticide application. J. M. Vose, C. R. Ford 4:45 187. Immediate impact of imidacloprid treatment for control of hemlock woolly adelgid on aquatic macroinvertebrate communities. J. Hanula, M. Churchel, C. W. Berisford, J. Vose
J. N. Seiber, C. J . Hapeman, and J. R. Barone, Organizers
THURSDAY MORNING
McCormick Place South RoomS105D, Level 1
Section A
J. H. Massey, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 172. Product identification from the cata lytic cracking of c/s-9-octadecenoic acid. T. J . Benson, R. Hernandez, W. T. French, M. G. White, E. G. Alley, W. E. Holmes 2:00 173. Parthenium argentatum as a source of biobased products. C. M. McMahan, K. Cornish, M. Whalen 2:25 174. Castor oil: Biosynthesis and uses. T. A. McKeon, X. He, G. Q. Chen, J-T. Lin 2:50 175. Structure-function relationships of a catalytically efficient β-D-xylosidase. D. B. Jordan 3:15 Intermission. 3:30 176. Enzymatic dewatering of distillers grains. A. B. Henriques, D. B. Johnston, Μ. Η. Al-Dahhan
Section C
Pesticide Runoff/Leaching Mitigation by Riparian Buffers: Application of the REMM
McCormick Place South RoomS103B/C, Level 1
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems Risk Assessment and Ecological Applications R. J . Gilliom and P. Hendley, S. H. Jackson, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 195. Properties of biodegradable feather keratin polymers. J. R. Barone 9:00 196. Biopolymers from polylactic acid and milk proteins. C. Onwulata, P. Tomasula 9:25 197. Extraction and electrospinning of zein extracted from corn gluten meal using acetic acid. G. W. Selling, Κ. Κ. Woods 9:50 198. Improved physical properties of zein using glyoxal as a crosslinker. Κ. Κ. Woods, G. W. Selling 10:15 Intermission. 10:30 199. Arthropod repelling constituents from a southern folk remedy: Investiga tions of the American beautyberry, Callicarpa americana. C. L. Cantrell, C. T. Bryson, S. O. Duke, J. A. Klun, J. F. Carroll 10:55 200. Biobased herbicides. F. E. Dayan, S. O. Duke 11:20 201. Single-use, disposable food containers: Starch-based alternatives to petroleum-based plastics. G. M. Glenn, C. N. Ludvik, A. P. Klamczynski, W. J. Oils, S. H. Imam, D. Wood 11:45 202. Incorporation of bacteriocin in edible pectin films for antimicrobial pack aging. L Liu, T. Jin, C-K. Liu, Κ. Β. Hicks, A. K. Mohanty, R. Bhardwaj, M. Misra
M. Nett, J. R. Barone, Organizer,
12:10 211. Comparison of REMM and PRZM implemented as a vegetated filter strip model. J. J. Prenger, J. M. Cheplick, W. M. Williams, A. M. Ritter, N. J. Snyder 12:35 Concluding Remarks. THURSDAY AFTERNOON Section A McCormick Place South Room S103B/C, Level 1
Section Β
Section C R. J . Gilliom, Organizer,
10:30 192. Application of spatial analysis in estimating drinking water exposure for the AAmethyl carbamate cumulative risk assessment. N. C. Thurman, D. Young 10:55 193. Use of geospatial data in endan gered species risk assessments for pesti cides. M. Corbin, N. C. Thurman, M. Thawley 11:20 194. Framework for a spatial aquatic model for pesticide risk assessments. M. Corbin, N. C. Thurman, M. Thawley
Organizers
Presiding
8:30 Introductory Remarks. S. H. Jackson. 8:35 188. Using National Agricultural Pesti cide Risk Analysis (NAPRA) WWW deci sion support system to estimate the envi ronmental exposure of fungicide use on soybean rust in Indiana. D. Deb, B. A. Engel, L Hahn 9:00 189. SADA: A freeware decision sup port tool integrating GIS, sample design, spatial modeling, and environmental risk assessment. R. N. Stewart 9:25 190. Landscape dynamics of Bt, bats, and insect resistance in the Winter Garden region of Texas. S. T. Purucker, P. Federico, T. G. Hallam, K. Kennard, G. F. McCracken 9:50 191. Generic spatial-aggregation tool for ecological modeling: NhdPlus case study. R. Srinivasan, S. Mylevaganam 10:15 Intermission.
Organizer
R. C. Everich and R. D. Wauchope, Organizers, Presiding 8:20 Introductory Remarks. 8:35 203. Field evaluation and simulation modeling of pesticide runoff buffer effec tiveness. R. C. Everich 9:00 204. Herbicide abatement by a riparian wetland system. C. P. Rice, K. Bialek, G. W. McCarty, W. D. Hively, J. Angier 9:25 205. Vegetative buffer management to mitigate potential off-site pesticide move ment in the Mississippi Delta. M. A. Locke, M. T. Moore, R. M. Zablotowicz, M. A. Weaver, R. L Bingner 9:50 206. Riparian ecosystem management model (REMM): Regulatory interests and perspective. R. D. Jones 10:15 Intermission. 10:30 207. EXPRESS: The EXAMS/PRZM exposure simulation shell. L. Burns 10:55 208. Application of REMM to design edge-of-field buffers. R. Lowrance, R. G. Williams, R. D. Wauchope 11:20 209. REMM pesticide algorithms: Sensitivity testing. R. D. Wauchope 11:45 210. Estimating buffer width size for pesticide labels using a new version of REMM. T. L Estes
Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems Risk Assessment and Ecological Applications R. J . Gilliom and P. Hendley, S. H. Jackson, Organizer,
Organizers
Presiding
1:30 212. Analysis of ecological risk posed by pesticides to surface waters in England. C. M. Holmes, R. Williams, C. D. Brown, S. Beulke, W. van Beinum, C. Wells, E. J. Pemberton 1:55 213. FOCUS surface water scenarios: Relevance at the zonal/member state level. G. O. Hughes, O. Price 2:20 214. Spatial approaches in agrochemi cal risk assessments: Challenges for the next decade. P. Hendley 2:45 Concluding Remarks by Session Chairs. Section Β McCormick Place South Room S103D, Level 1 Agricultural Biomass, Biobased Products, and Biofuels The Cellulosic Challenge Cosponsored with FUEL, SUST, CELL, and CINF J. N. Seiber, C. J . Hapeman, and J. H. Massey, Organizers J. R. Barone, Organizer,
Presiding
1:05 Introductory Remarks. 1:10 215. Fast pyrolysis and biooil produc tion from energy crops being developed within USDA-ARS. A. A. Boateng 1:35 216. Steam explosion method for pro ducing microcrystalline cellulose from agricultural residues. F. A. Agblevor, M. M. Ibrahim, W. K. El-Zawawy 2:00 217. Developing enzyme systems for biomass destruction. D. Wong, C. Lee, K. Wagschal, M. Smith, G. Robertson, W.Orts 2:25 218. Process for obtaining cellulose acetate from agricultural by-products. A. Biswas, B. C. Saha, J. W. Lawton Jr., R. L Shogren, J. L. Willett 2:50 Intermission. 3:05 219. Fuel from herbaceous feedstocks: A switchgrass-centric perspective. G. Sarath, B. S. Dien, K. P. Vogel, H-J. G. Jung 3:30 220. Hydrothermal conversion of wood: Reaction kinetics and process develop ment. B. Zhang, M. von Keitz, K. Valentas 3:55 221. Fractionating lignocellulose by using cellulose solvent and organic sol vent. Y-H. P. Zhang, G. Moxley 4:20 Concluding Remarks.
ANYL Division of Analytical Chemistry C. G. Enke, Program Chair MONDAY MORNING Undergraduate Research Poster Session: Analytical Chemistry Sponsored by CHED, Cosponsored with SOCED, and ANYL
TECH-11
TECHNICAL PROGRAM
BIOT/BIOL/BMGT/CARB
BIOT
BMGT
Division of Biochemical Technology T. A. Good and A. A. Shukla, Program Chairs
Division of Business Development & Management
10:35 1 1 . High performance polyolefin mem brane in lithium ion battery application. K. Kono, P. Brant, K. Takita, K. Kimishima 11:05 12. Relating polymer rheology and miscibility to chemical architecture. D. J. Lohse 11:35 Concluding Remarks.
Section A
TUESDAY MORNING
O T H E R S Y M P O S I A O F INTEREST: Benchmarking the Research Competi tiveness of U.S. Chemistry and Chemical Engineering (see PRES, Tue)
Sustainability of Food Systems: Carbohydrate Economy Sponsored by SUST, Cosponsored with CARB, and BIOT
Interfacing Big Pharma with Emerging Technologies (see SCHB, Mon)
TUESDAY AFTERNOON
Ethics for the Chemical Professional (see PROF, Tue)
Sustainability of Food Systems: Carbohydrate Economy Sponsored by SUST, Cosponsored with CARB, and BIOT
Nanotechnology and the Environ ment: Focus on Green Nanotechnol ogy (see l&EC, Sun, Tue)
WEDNESDAY MORNING Advanced Mining and Use of Life Science Information Sponsored by CINF, Cosponsored with CSA Trust, BIOT, BTEC, MEDI, and COMP
S O C I A L EVENT: Energy Networking Session: Sun SUNDAY MORNING Section A
BIOL
I
Division of Biological Chemistry
Hyatt Regency McCormick 20A/B BMGT Presents an Executive Overview of Energy Programming for the Chicago ACS Meeting Cosponsored with SUST
T. Begley, Program Chair J . L. Bryant and B. Gordon III,
Organizers
MONDAY MORNING
Ε. Μ. Yokley, Organizer,
Nakanishi Prize: Symposium in Honor of Hung-wen Liu Sponsored by ORGN, Cosponsored with BIOL
9:45 Introductory Remarks. 9:50 1. Thematic programming for Chicago: Energy overview. Κ. Β. Anderson 10:05 2. An overview of energy programming in the Environmental Division. J. Marwan, G. Coimbatore 10:20 3. Developing issues in energy and fuels: An overview of energy programming in the FUEL Division. J. J. Helble 10:40 4. An overview of energy programming in the CINF Division. L Solla, B. Town 10:55 5. Sustainable nuclear energy pro gramming highlights of the Division of Nuclear Chemistry and Technology DNCT . H. Nitsche 11:15 6. The role of the ACS Petroleum Research Fund in basic energy research. C. Hollinsed 11:35 Concluding Remarks.
MONDAY AFTERNOON Exploring and Exploiting Nature with Biomimetics Biomolecular Self-assembly and Biocatalysis Sponsored by CHED, Cosponsored with WCC, BIOL, and I NOR Undergraduate Research Poster Session: Biochemistry Sponsored by CHED, Cosponsored with SOCED, BIOL, and BIOT TUESDAY MORNING Exploring and Exploiting Nature with Biomimetics Rational Manipulation of Biomolecular Architecture Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR TUESDAY AFTERNOON Exploring and Exploiting Nature with Biomimetics Molecular Recognition and Drug Delivery Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR
Please refrain from using cellular telephones and cameras during technical sessions.
12-TECH
Presiding
MONDAY MORNING Section A Hyatt Regency McCormick 20A/B ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu Next Generation Product R&D: Science and Engineering Cosponsored with PMSE, and WCC A. O. Patil,
Division of Carbohydrate Chemistry D. P. Arya, Program Chair
MONDAY AFTERNOON
J. L. Bryant, Program Chair
SOCIAL EVENT:
MONDAY AFTERNOON Undergraduate Research Poster Session: Biochemistry Sponsored by CHED, Cosponsored with SOCED, BIOL, and BIOT
ΗΕΤΠ
Organizer
8:15 Introductory Remarks. 8:20 7. Living isospecific alkene polymeriza tion. G. W. Coates, A. M. Anderson, A. E. Cherian, G. J. Domski, J. B. Edson, J. M. Rose, A. Tanna 8:50 8. Advanced catalyst technologies and high-throughput experimentation at Exxon Mobil. J. S. Beck 9:20 9. Synthesis of composite polymer membranes by field-directed drop deposi tion. H-C. Chang, P. Wang 9:50 Intermission. 10:05 10. Origins of controlled adhesion in stretch cling films. P. Brant, M. Arvedson, P. M. German
Hyatt Regency McCormick 20A/B
Hudson Award Dinner: Mon SUNDAY MORNING
ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu Next Generation Product R&D: Science and Engineering Cosponsored with PMSE, and WCC A. O. Patil,
Organizer
Section A McCormick Place North Room N226, Level 2 Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Cosponsored with HIST, MEDI, and ORGN
1:15 Introductory Remarks. 1:20 13. Tailored surface adsorption for rheological control of sooted oils. J. Emert, D. A. Weitz, C. Osuji, Y-Y. Won, Y. E. Zhu 1:50 14. Recyclable, heterogeneous, Lewis acid-catalyzed polymerization of acrylates with non-polar alkenes. A. Sen 2:20 15. Generations of polyolefins catalyst discovery: An overview. G. A. Vaughan 2:50 Intermission. 3:05 16. Alternative fuels and advanced technology vehicles: Overview of activities and opportunities. K. O. Havelka 3:35 17. New monomers and comb poly mers. A. O. Patil, S. Zushma, M. Varma-Nair 4:05 18. Award Address (ACS Award in Industrial Chemistry, sponsored by ACS Division of Business Development and Management). Advanced synthetic lubri cant development at ExxonMobil. M. M. Wu 4:45 Concluding Remarks.
8:45 1. From Claude S. Hudson to Pierre Sinay: More than a hundred years of carbohydrate chemistry research (19032007). M. Manoharan 9:00 2. Award Address (Claude S. Hudson Award in Carbohydrate Chemistry, spon sored by National Starch and Chemical Company). Cyclodextrin Chemistry. P. Sinay 9:40 3. Shedding light on glycans. C. R. Bertozzi 10:15 4. Diastereoselective glycosylate: Recent advances. D. Crich 10:50 Intermission. 11:00 5. Post-translational glycosylation: Challenges and opportunities. C-H. Wong 11:35 6. Total asymmetric synthesis of carbohydrates and analogs using the "Naked Sugars". P. Vogel
TUESDAY MORNING
SUNDAY AFTERNOON
Section A
Section A
Hyatt Regency McCormick 20A/B
McCormick Place North Room N226, Level 2
General Papers Pertaining to Management of the Chemical Enterprise Cosponsored with PROF
Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Cosponsored with HIST, MEDI, and ORGN
J. L. Bryant,
Organizer
8:30 Introductory Remarks. 8:35 19. Meet sustainability goals using a framework for life cycle review of products. G. L. Adams 9:00 20. Managing a research outsourcing relationship: A tale of undergraduate summer research. S. D. Warren, D. S. McComas, W. R. Ohlstrom, H. Glass, D. J. Vachon 9:25 2 1 . Hiring and retention of key employ ees: Selecting and sourcing. J . Sass 9:50 22. Hiring and retention of key employ ees: Hiring. M. Driscoll 10:15 23. Hiring and retention of key employ ees: Development. L. Prior 10:40 24. Hiring and retention of key employ ees: Retention. L. Prior 11:05 Concluding Remarks. From Lab to Market: Protecting and Commercializing New Knowledge Sponsored by CHAL, Cosponsored with BMGT, and SCHB
M. Manoharan,
M. Manoharan,
Organizer
Organizer
2:00 7. Recent developments in the chemis try of n-pentenyl orthoesters. B. Fraser-Reid, S. R. Chaudhuri, C. V. S. Murty, J. Lu 2:35 8. Chemoenzymatic synthesis of hepa rin and heparan sulfates. R. J. Linhardt, M. Weiwer, J. Liu, P. L. DeAngelis, J. S. Dordick 3:10 9. Rationally engineered low molecular weight heparin. G. Venkataraman, Z. Shriver, I. Fier 3:45 Intermission. 3:55 10. Targeting tumor cells using low affinity multivalent interactions. L. L. Kiessling 4:30 11. Heterobivalent ligands: A versatile approach to ligand induced protein aggre gation and ligand clustering exemplified by the structure-based design of Shiga toxin antagonists. D. R. Bundle, P. I. Kitov 5:05 Concluding Remarks. MONDAY MORNING
TUESDAY AFTERNOON Section A From Lab to Market: Protecting and Commercializing New Knowledge Sponsored by CHAL, Cosponsored with BMGT, and SCHB
McCormick Place North Room N226, Level 2 Organic Chemistry of Carbohydrates: Legacy of Aleksander Zamojski W . Priebe, Z. J . Witczak, and M. C. Chmielewski, Organizers W . A. Szarek, Organizer, 8:30 Introductory Remarks.
Presiding
CARB 8:45 12. Zamojski's total synthesis of racemic monosaccharides as an inspiration to stereoselective transformations of readily available sugar synthons. M. C. Chmielewski 9:15 13. Acetylenic sugars: Versatile synthons for chiral aliènes and C-nucleoside analogs. D. Horion 9:45 14. Exploring carbohydrates to design blood-brain barrier-penetrating, brain tumor-targeting anthracyclines. W. Priebe 10:15 Intermission. 10:30 15. Half of sugar chemistry resides at the anomeric carbon. S. Hanessian 11:00 16. Application of (salen)Cr(lll) and (salen)Co(ll) complexes in the enantioselective synthesis of 3,6-dihydro-2Hpyrans. J. Jurczak, P. Kwiatkowski 11:30 17. Total synthesis of a fully phosphorylated CD52 GPI. Z. Guo MONDAY AFTERNOON Section A McCormick Place North Room N226, Level 2 Organic Chemistry of Carbohydrates: Legacy of Aleksander Zamojski Z. J . Witczak, W . A. Szarek, and M. C. Chmielewski, Organizers W . Priebe, Organizer,
Presiding
1:30 18. Total synthesis of complicated natural products from simple carbohydrates. K. Tatsuta 2:00 19. Monosaccharides to "natural products" to oligosaccharides: A strange route from 2,3-unsaturated sugars. B. Fraser-Reid 2:30 20. From higher carbon sugars to carbocyclic sugar mimics. S. Jarosz 3:00 Intermission. 3:15 21.1,3,2-Oxathiaphospholane approach to the synthesis of biologically relevant oligonucleotide congeners and nucleoside polyphosphates. W. J. Stec, D. Blaziak 3:45 22. Synthesis of oligosaccharide libraries by random glycosylate of unprotected carbohydrates. J. Thiem TUESDAY MORNING Section A McCormick Place North Room N226, Level 2 Organic Chemistry of Carbohydrates: Legacy of Aleksander Zamojski W . Priebe, W. A. Szarek, and M. C. Chmielewski, Organizers Z. J . Witczak, Organizer,
Presiding
8:30 23. New approaches for the synthesis of neoglycoconjugates. F. Nicotra, B. La Ferla, F. Cardona 9:00 24. Biosynthesis and molecular recognition of bacterial heptoses. P. Kosma, H. Wang, A. Zamyatina, H. Amer, A. Graziani, E. Balla, E. Crouch, J. F. Head 9:30 25. Structure and recognition of carbohydrates. J. F. G. Vliegenthart 10:00 Intermission. 10:15 26. Heparan sulfate and amyloidogenesis. W. A. Szarek, R. Kisilevsky 10:45 27. Glycoconjugates: Development of new biologically active compounds. W. Szeja, A. Kasprzycka, G. Pastuch, I. Wandzik, G. Grynkiewicz, B. Szewczyk 11:15 28. Synthesis of L-glycero-D-mannoheptose by A. Zamojski as a trigger for Russian Polish German cooperation in the field of Escherichia coli oligosaccharides. L. V. Backinowsky Sustainability of Food Systems: Carbohydrate Economy Sponsored by SUST, Cosponsored with CARB, and BIOT
TUESDAY AFTERNOON Section A McCormick Place North Room N226, Level 2 Organic Chemistry of Carbohydrates: Legacy of Aleksander Zamojski W . Priebe, Z. J . Witczak, and W . A. Szarek, Organizers M. C. Chmielewski, Organizer,
Presiding
1:30 29. C-Disaccharides and analogs: The search for anticancer agents. P. Vogel, S. Gerber-Lemaire, L Awad, C. Bello, H. Fiaux, L Juillerat-Jeanneret, A. Gillig, M. Kolympadi 2:00 30. Diaminoinositol inhibitors of phospholipase C and phosphatidylinositol 3-kinase. H. Li, C. Mihai, X. Yue, K. S. Bruzik 2:30 3 1 . Synthesis of S-ribosylhomocysteine analogs modified at carbon-3. J. Robert, B. Meyers, A. J. Sobczak, S. F. Wnuk 3:00 Intermission. 3:15 32. Carbohydrate enones. New stereoselective approaches to thiosugars. 3-5 and 5,-5'-thiodisaccharides from L-arabinose enone. Z. J. Witczak 3:45 33. Ruff degradation. J. N. BeMiller, J. A. Stapley 4:15 34. Synthesis and glycosidase inhibitory activities of zwitterionic glycosidase inhibitors. B. M. Pinto 4:45 Concluding Remarks. Section Β Hyatt Regency Chicago Riverside Center General Posters D. P. Arya,
Organizer
6:00-8:00 35. Effect of microwave radiation on the thermal properties of high-amylose maize starches. Z. Luo, X. Fu, F. Luo 36. pH-Dependent swelling properties of hydrophilic biogel with polysaccharide. X. He, Z. Luo 37. Studies on the relationship of structure and properties of konjac glucomannan. L. Pan, J. Ma, Y. Yu, Y. Deng, R. Dai 38. The effect of purification on the dissolution rate of konjac glucomannan. J. Ma, L. Pan, R. Dai, Y. Deng 39. Characterization of acetylated resistant starch for controlled and targeted releasing carriers. X. Li, L Chen, L. Li 40. Synthesis of glycosylamino acid contain ing dipeptides possessing a C-terminal α-ketoacid. A. K. Sanki, R. Talan, H. Zheng, S. J. Sucheck 41. Withdrawn. 42. Characterizations of Salix gordejecii cellu lose isolated from alkaline hydrogen per oxide process. L. Qi, F. Xu, H. Zhao 43. Withdrawn. 44. Recognition of DNA:RNA hybrids by a novel neomycin-methidium derivative. Ν. Ν. Shaw, H. Xi, D. P. Arya 45. Recognition of the DNA duplex with novel neomycin-polyamide conjugates. N. N. Shaw, M. Baker, D. P. Arya 46. Application of plant polyphenols in poly mer materials. L-H. Zhang, Q. Shen 47. Thermodynamics of aminoglycosides binding to AT-rich DNA triple helices. H. Xi, L. Xue, D. K. Gray Jr., D. P. Arya 48. Complexation efficiency of cyclodextrins. T. Loftsson 49. Do cyclodextrins form nanoparticles? T. Loftsson 50. NMR characterization of corn stalk hemicelluloses. X-F. Sun 51. Morphology study of nanoporous xyloglucan matrices on silicon and mica by XPS and AFM. A. F. Lubambo, N. Lucyszyn, J. J. Klein, W. H. Schreiner, P. C. de Camargo, M. R. Sierakowski 52. Identifying RNA structural motifs recog nized by kanamycin A. J. L. Childs-Disney, M. D. Disney
53. Seven-membered iminocyclitols: Synthe sis of 4R,5R,6S-trihydroxydiazapenones. R. M. Moriarty, N. S. Chandrasekera, C. I. Mitan, B. C. Surve, D. A. Parrish 54. Improving aminoglycoside antibiotics by conjugation with tetracyclines. B. L H. Taylor, S. R. Kirk 55. Modulation of innate immune responses with synthetic lipid A derivative with KDO. Y. Zhang, J. Gaekwad, M. A. Wolfert, G-J. Boons 56. Synthesis of novel 2-carboxy-6-hydroxyloctahydroindole analogs from sugars. J. R. Ella-Menye, X. Nie, G. Wang 57. Wettability studies of different carbohy drate polymer derivatives using Wash burn's method. H. Caplan, T. C. Nelson, B. Derecskei 58. Study on structure and biological activity of polysaccharides from seaweed. W. Mao, H. Li 59. Synthesis and characterization of multi functional glycoconjugated Au nanopar ticles. H. Wang, S. Boduroglu, J. Hu 60. Selective mannosidase inhibitors as cancer therapeutics. J . Guo, J. Asong, G-J. Boons 61. Cyclodextrin based artificial oxidases. L. G. Marinescu, M. Bols 62. Microwave synthesizer: A convenient tool for the conjugation of amino acids with sugars and amino sugars. P. Angrish, T. Narindoshvili 63. Synthesis of carbohydrates carrying fluorescent naphthalimide groups. A. M. Dreis, A. J. Wagner, D. E. Lewis 6 4 . 1 3 C NMR studies of RNase glycation using 13 C-labeled aldoses. W. Zhang, Q. Pan, S. Chetyrkin, P. A. Voziyan, B. G. Hudson, A. S. Serianni 65. Withdrawn. 66. Synthesis of β-C-galactosides with fluorine substituents in the methylene linker to the pseudo aglycone. K. A. Tony, R. W. Denton, A. Dilhas, D. R. Mootoo 67. Approaches to novel sialyl Lewis X mimetics: S-Linked fucoside derivatives. I. Robina, A. Moreno-Vargas, A. Carmona, A. Ferrali, L. Molina 68. New synthetic approach to C-S-thiotrisaccharides form C-disaccharide enones. Z. J. Witczak, J. Danowski, J. Dwyer, S. Jarosz, E. Kozlowska 69. Novel synthetic approach to 1,2-thiodisaccharides from 3-nitro-and 3-cyano carbo hydrate enones. C. Cassett, Z. J. Witczak, R. A. Spanevello, M. I. Mangione, A. G. Suarez 70. Total synthesis of OSW-1. J . Xue, P. Liu, Z. Guo 7 1 . Synthesis and immunological character ization of the core oligosaccharide of Francisella tularensis. W. Zhong, T. Buskas, J. H. Kim, J. Park, G-J. Boons 72. Novel cytosine-based fluorescent nucleo sides: Synthesis, characterization, and modeling. V. K. Dunlap, T. I. Kalman 73. Methyl beta-[1- 13 C]GlcNAc-(1,2)-alpha-[213 C]mannopyranoside: Synthesis and conformational studies by NMR, MD, DFT and crystallography. X. Hu, T. Klepach, A. S. Serianni 74. Parameterization of 3 J H C O H
a n d 3
^CCOH
spin-coupling constants in saccharides: Influence of electronegative substituents, and application to experimental studies of Η-bonding in solution. H. Zhao, I. Carmichael, A. S. Serianni 75. 1 3 C-Labeled methyl aldohexopyranuronides: NMR and DFT studies of homoand heteronuclear spin-couplings involving hydrogen and carbon. W. Zhang, T. Klepach, I. Carmichael, A. S. Serianni 76. 1 3 C-Labeled /V-acetylneuraminic (sialic) acid: NMR and DFT studies of J H H. «4DH and JQC spin-couplings in protonated and ionized forms. T. Klepach, I. Carmichael, A. S. Serianni
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
77. On the development of X J C H spin-cou plings as probes of inter-residue H-bond strength in oligosaccharides in solution. H. Zhao, I. Carmichael, A. S. Serianni 78. Detection and quantification of the acyclic keto and eno/forms of 13 C-labeled /\/-acetylneuraminic acid (sialic acid) in aqueous solution. T. Klepach, A. S. Serianni 79. Progress toward scalable syntheses of aminosugars found in S. aureus capsular . polysaccharides. R. Conway, G. A. Cox, P. Norris 80. Application of 4,5 O.N-oxazolidinone protected sialosyl donors to the synthesis of alpha-sialosides. C. De Meo, N. Ginder 81. Synthesis of 5-epi Kdo derivatives as probes for Kdo-specific monoclonal anti bodies. K. Wimmer, P. Kosma 82. Degradation kinetics and its mechanism of potato starch paste under ultrasonic irra diation. J. Li, L Li, B. Li, L Chen, X. Li, X. Zhang 83. Ionic liquid supported oligosaccharide synthesis. A. K. Pathak, C. K. Yemeni, V. Pathak 84. Convenient assembly of anthrax tetrasaccharide antigen using ionic liquid support. A. K. Pathak, Y. N. Timsina, R. Muto 85. Galactofuranose disaccharide analogs for inhibitors of cell wall biosynthesis in Myco bacterium tuberculosis. A. K. Pathak, R. K. Rayala, V. K. Alapati, R. C. Reynolds 86. Structural characterizations of polysaccha rides from Ulva pertusa. W. Mao, X. Zang 87. Study on chemical characteristic and anticoagulant activity of difference molecu lar weight sulfated polysaccharides from Monostroma latissium. W. Mao, H. Zhang 88. Effect of kneading on the structure and digestion resistance ability of starch. L. Chen, H. Xiang, X. Li, L. Li 89. Synthesis of C-linked neuraminic acid disaccharide and larger oligosialic acids. X. Yuan, R. J. Linhardt 90. Efforts toward the isolation and sequence determination of the putative mammalian enzyme carbon-mannosyltransferase. S. M. Chervin, G. A. Garcia 9 1 . Mono-, di-, and trifluoromethyl analogs of S-phenyl 2,3,4-tri-O-benzyl-thiorhamnoside: On the influence of the disarming substituent at 5-position in glycosylate reactions. 0 . Vinogradova, D. Crich 92. Super light thermal insulators from Ceratonia siliqua galactomannan. S. K. Singh, N. Singh, E. Blackfeather 93. Synthesis of methylprednisolone-peptidedextran conjugates. A. Kumar, Ν. Η. Nam, H. K. Agarwal, R. Mehvar, K. Parang 94. Synthesis of nucleoside-succinate-dextran conjugates. H. K. Agarwal, A. Kumar, R. Mehvar, K. Parang 134. Automated iterative solution-phase synthesis of glucose-based immunomodulators. S. M. Brokman, B. Y. M. Collet, A. E. Nielsen, N. L Pohl 135. Biocatalytic esterifications in carbohy drates using CLEC lipases in green reac tion media. N. K. Sharma, N. Owens, P. K. Sharma, V. S. Parmar 136. Exploring the Scope of Oxyamine-Mediated Neoglycosylation. J. M. Langenhan 137. Fluorous-tagged synthesis of capping carbohydrates of parasitic and nonparasitic Leishmania. E. Song, N. L Pohl 138. Incorporation of reducing saccharides into carbohydrate microarrays using syn thetic fluorous tags. G-S. Chen, N. L. Pohl 139. On-Chip synthesis of oligosaccharide and glycopeptide arrays. L. Ban, M. Mrksich 140. Synthesis of building blocks for the automated iterative solution-phase synthe sis of glucans. A. E. Nielsen, B. Y. M. Collet, S. M. Brokman, N. L Pohl 141. Ionic liquid as solvent for biopolymer: acetylation of hemicelluloses. R. Junli, S. Runcang, L Chuanfu 142. Delignification of wheat straw pulp with hydrogen peroxide catalyzed by sodium molybdate under acidic condition. A. Zhang, C. F. Liu, M. H. Qin, R. C. Sun 143. Effect of Microwave Radiation on the Properties of Waxy Maize Starches. Z. Luo, L. Yang 144. Chemical Modification of Native Eucommia Ulmoides Oliver with Succinic Anhy dride. F. Xu, R. Sun, H. Zhao
TECH-13
TECHNICAL PROGRAM
CARB/CELL 145. Homogeneous modification of cellulose with phthalic anhydride in an ionic liquid. C. F. Liu, R. Sun, A. P. Zhang, J. L Ren, X.-A.Wang 146. Effect of Modified Cellulose on Mechani cal Properties of SPI Film. J. Xlong, Z-S. Song, J. Ye, L Li 147. Automated iterative solution-phase synthesis of glycosaminoglycans: Hyaluronan and keratan. Β. Υ. Μ. Collet, M. Schouten, N. L. Pohl
4:10 110. Grignard reagent addition to N-quaternary iminiumcyclitols. R. M. Moriarty, C. I. Mitan, B. Gu, T. Block 4:30 111. S-Thiazolinyl glycosides in the "Inverse Armed-Disarmed Strategy". J. T. Smoot, A. V. Demchenko 4:50 112. Chemoselective synthesis of oligosaccharides of 2-deoxy-2-aminosugars. A. F. G. Bongat, A. V. Demchenko 5:10 113. Determining solution conforma tional entropy of malto- and cellooligosaccharides at quasi-physiological conditions. M. A. Boone, A. M. Striegel
Sustainability of Food Systems: Carbohydrate Economy Sponsored by SUST, Cosponsored with CARB, and BIOT
THURSDAY MORNING
WEDNESDAY MORNING
Section A
Section A
McCormick Place North Room N226, Level 2
McCormick Place North Room N226, Level 2
Biological Applications of Carbohydrates
Nucleic Acid Therapeutics I. Fokt and M. D. Disney,
D. P. Arya, Presiding
9:00 Introductory Remarks. 9:05 95. Sugar moiety-fluorinated anthracyclines. I. Fokt, M. Krawczyk, P. Skibicki, G. Grynkiewicz, W. Priebe 9:25 96. Progress toward a chemical code for recognition of RNA. M. D. Disney 9:45 97. Redesign of aminoglycosides for treatment of human genetic diseases caused by premature stop mutations. I. Nudelman, J. Kondo, A. Rebibo, D. Shallom-Shezifi, M. Hainrichson, T. Ben-Yosef, E. Westhof, T. Baasov 10:05 98. Recognition of duplex DNA by aminoglycoside dimers. S. Kumar, H. Xi, M. Newby, D. P. Arya 10:25 99. Attenuating the solubility of carbo hydrate-based drugs for improved delivery and targeting. T. A. Houston, B. L Wilkinson, S. Quader, L. F. Bornaghi, S. E. Boyd, S-A. Poulsen, I. D. Jenkins 10:45 100. Targeting the HIV-1 TAR stemloop with Hoechst-neomycin conjugates. M. Baker, S. Kumar, M. Newby, D. P. Arya 11:05 101. Oligonucleotide-peptide hybrids with overall positive charge enter efficiently into cells while maintaining hybridization properties and enzymatic recognition. G. F. Zuber, A. Fraley, J-P. Behr, B. Pons 11:25 102. S-Adenosylhomocysteine analogs with carbon-5' and sulfur atoms replaced by halovinyl unit. P. R. Sacasa, D. Andrei, T. P. Dang, S. F. Wnuk WEDNESDAY AFTERNOON Section A McCormick Place North Room N226, Level 2
Organizer
T. J . Tolbert and E. Burton,
Presiding
8:30 Introductory Remarks. 8:35 114. Bioactive properties of pectic oligosaccharides from sugar beet and Valencia oranges. A. T. Hotchkiss Jr., K. Manderson, K. M. Tuohy, W. W. Widmer, A. Nunez, G. R. Gibson, R. A. Rastall 8:55 115. Synthesis the GPI anchor of CD52 and its derivatives. X. Wu, Z. Guo 9:15 116. Carbohydrate microarrays for basic and translational cancer research. J. C. Gildersleeve 9:35 117. Modulation of adhesion by fluorination of eukaryotic cells by biosynthesis. L. Dafik, M. d'Alarcao, K. Kumar 9:55 118. Measurement of noncovalent binding interactions of fluorous sugar substrates. G. Camci-Unal, N. L. Pohl 10:15 119. Role of multivalency in bacterial recognition by CD14 and TLR2 receptors. D. W. Miller, M. Wolfert, G-J. Boons 10:35 Intermission. 10:50 120. Synthesis and antigenic analysis of oligosaccharides derived from bioterrorism agents. A. S. Mehta, E. Saile, W. Zhong, T. Buskas, R. W. Carlson, C. P. Quinn, G-J. Boons 11:10 121. Synthesis and immunological evaluation of a three-component cancer vaccine. S. Ingale, G. J. Boons 11:30 122. Synthesis and characterization of the first antagonist of a periplasmic binding protein. Y. Zhu, J. Barrack, L. L Kiessling 11:50 123. Dissecting the mechanism of the bacterial transglycosylases using synthetic substrate analogs. Y. Zhang, E. J. Fechter, T-S. A. Wang, D. Barrett, S. Walker, D. E. Kahne THURSDAY AFTERNOON
Carbohydrate Synthesis and Mechanism Section A D. P. Arya,
Organizer
A. V. Demchenko,
Presiding
1:30 Introductory Remarks. 1:35 103. Evidence and kinetics of native starch degradation with recombinant human small intestinal maltase-glucoamylase. Z. Ao, R. Quezada-Calvillo, D. R. Rose, B. L Nichols, B. R. Hamaker 1:55 104. Toward the synthesis of side chain Β of rhamnogalacturonan II. S. Nepogodiev, M. T. de Oliveira, R. Field 2:15 105. Kinetic study of the acetolysis of ester protected methyl L-ribofuranosides. J. J. Forsman, M. U. Roslund, R. Leino 2:35 106. Thermochemical properties of glucoseamine. A. Fattahi, M. Ghorat, A. A. Torabi, M. R. Avadi 2:55 107. Sugar folding: A novel structural prediction tool for oligosaccharides and polysaccharides. J . Xia, R. P. Daly, F-C. Chuang, L. Parker, J. H. Jensen, C. J. Margulis 3:15 108. Synthesis of a water-soluble chitosan derivative: Reaction kinetics and mechanism. J . Cho, C. Allen 3:35 Intermission. 3:50 109. Conformational arming of glucosyl donors. C. M. Pedersen, M. Bols
14-TECH
McCormick Place North Room N226, Level 2 Biological Applications of Carbohydrates D. P. Arya,
2:25 Intermission. 2:35 128. Approaches toward the synthesis of QS-21Axyl. K. Deng, D. Y. Gin 2:55 129. Glycoprotein synthesis in the yeast Pichia pastoris. T. J. Tolbert, B. S. Hamilton, A. M. Kukuch, M. Pawlicki 3:15 130. Synthetic saccharides to study the immunological properties of Streptococcus pneumoniae 6A and 6B. A. R. Parameswar, P. Pomsuriyasak, N. A. Lubanowski, A. V. Demchenko 3:35 131. Synthesis of oligomannose clus ters as potential HIV-1 vaccine candidates and their binding to human antibody 2G12. J. Wang, H. Li, L-X. Wang 3:55 132. Role of glycoconjugates in phago cytosis and destruction of B. cereus spores. O. Tarasenko, E. Burton, L. Soderberg, P. Alusta 4:15 133. Glycoconjugates enhanced phago cytosis of B. cereus spores using Dictyostelium discoideum as a model. E. Burton, S. Desikan, J. Bush, P. Alusta, O. Tarasenko
Organizer
T. J . Tolbert and J . C. Gildersleeve, Presiding 1:00 Introductory Remarks. 1:05 124. Synthesis and structural study of isotopically labeled heparin. J . Xie, S. A. McCallum, Z. Zhang, M. Chen, J. Liu, R. J. Linhardt 1:25 125. Dissecting the structural require ments for moenomycin A activity using semisynthetic analogs with modified phosphoglycerate lipids. S. Fuse, Y. Zhang, M. Adachi, D. E. Kahne 1:45 126. Combinatorial biosynthesis of NDP-deoxysugars and spinosyn glyco sides by in vitro recombination of second ary metabolite biosynthetic pathways. H-T. Chiu, Y - L Chen 2:05 127. Synthesis of 2-8 linked Kdo disaccharide analogs as ligands for chlamydiaspecific monoclonal antibodies. G. Sixta, P. Kosma, H. Brade, S. Evans
8:30 8. Characterization and stability of cellulose ester thin films. P. M. Kosaka, D. F. S. Petri 9:00 9. Preparation of regioselectively 6-0alkylated cellulose derivatives and charac terization of their Langmuir-Blodgett films. F. Nakatsubo, S. Ifuku, Y. Tsujii, S. Nakai, H. Kamitakahara, T. Takano 9:30 10. Self-assembled monolayers of carboxymethyl cellulose. G. Wenz 10:00 Intermission. 10:15 11. Multilayered assemblies of cellu lose derivatives and their application as surface modifiers and primers. G. Wegner 10:45 12. Toward the fabrication of photocurrent generation systems with cellulose matrix by the Langmuir-Blodgett technique. K. Sakakibara, Y. Tsujii, T. Takano, H. Kamitakahara, F. Nakatsubo 11:15 13. Oxidized cellulose fibers used for metal chelation. D. Han, G. P. Halada, J. Kubicki Section C McCormick Place East Room E261, Level 2
CELL Division of Cellulose & Renewable Materials O. J. Rojas, Program Chair
Nanotechnology: A Fiber Perspective Nanoscience D. S. Argyropoulos, L. A. Lucia, and O. J . Rojas, Organizers
Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides NMR of Polysaccharides
8:30 14. Decorating fibers with nanoparticles: From hydrophobic to ultrahydrophobic materials. K. Ramaratnam, V. Tsyalkovsky, I. Luzinov 9:00 15. Incorporation of quantum dot taggants into paper and board products. T. Abitbol, D. G. Gray 9:30 16. Epitaxial self assembly of biobased materials on cellulose template. S. Park, J. J. Bozell, N. Labbé, T. G. Rials 10:00 Intermission. 10:15 17. A high throughput and environmentally benign fabrication process of thermoplastic nano-fibers. G. Sun, D. Wang, B-S. Chiou 10:45 18. Effect of reaction conditions on the formation and thermal behavior of cellulose nanocrystals. I. Filpponen, X. Wang, L. A. Lucia, D. S. Argyropoulos 11:15 19. Cellulose nanofibrils: Adsorption with cationic polyelectrolytes and application as a paper strength additive. S. Ahola, M. Ôsterberg, J. Laine
K. J. Edgar,
Organizer
SUNDAY AFTERNOON
D. Lowman,
Presiding
Section A
S O C I A L EVENT: Anselm Payen Award Banquet: Tue BUSINESS M E E T I N G S : Executive Committee Meeting, 5PM: Sat Open Business Meeting, 5PM: Mon Program Meeting, 6PM: Sun SUNDAY MORNING Section A McCormick Place East Room E258, Level 2
8:00 1. What can we learn about the struc ture of cellulose esters from NMR? D. Lowman 8:30 2. Structural and functional properties of NMR J-couplings in simple and complex saccharides. A. S. Serianni 9:00 3. Recent methods for the determina tion of polysaccharide structure: Pulse sequences and high resolution magic angle spinning NMR. J. O. Duus 9:30 4. NMR spectroscopy of polysaccha rides. J. F. Vliegenthart 10:00 Intermission. 10:15 5. HRMAS NMR of polysaccharides in condensed phases. W. T. Winter, D. J. Kiemle 10:45 6. Glycosaminoglycan structure and interactions from 13C enrichment and NMR observation of acetyl groups. J. H. Prestegard, F. Yu 11:15 7. Primary structure determination of oligosaccharides using isotags and highdimensional NMR spectroscopy. B. Bendiak, G. S. Armstrong
McCormick Place East Room E258, Level 2 Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides Synthesis of Polysaccharides K. J . Edgar, T. Shibata,
Organizer Presiding
1:15 20. Utilization and molecular characteristics of cellulosic esters. T. Shibata 1:45 2 1 . Novel concept for structure design of polysaccharide-based nanoparticles. T. Heinze, S. Hornig 2:15 22. Solvent-free process to esterify polysaccharides. A. Biswas, R. L. Shogren, G. W. Selling, J. L. Willett, C. M. Buchanan 2:45 23. Exploiting the unique properties of cellulose esters in contemporary applications. D. Tindall, B. D. Seiler 3:15 Intermission.
Section Β McCormick Place Lakeside Room E257, Level 2 Model Cellulosic Surfaces Derivatized Cellulose Films and Surfaces M. Roman and S. J . Eichhorn, 8:20 Introductory Remarks.
Organizers
Please refrain from using cellular telephones and cameras during technical sessions.
CELL 3:30 24. Synthesis and properties of regiospecifically modified cellulose and cellu lose copolymer brushes. J. F. Kadla, B. Bar-Nir, A. F. Xavier 4:00 25. Synthesis strategy for functional cello-oligosaccharides to develop innova tive cellulosic materials. H. Kamitakahara, A. Yoshinaga, H. Aono, F. Nakatsubo, D. O. Klemm 4:30 26. Synthesis of functional cellulose derivatives. G. Wenz Section Β McCormick Place Lakeside Room E257, Level 2
Organizers
1:15 32. Lateral force microscopy on thin films of cellulose. Y. Li, J. P. Hinestroza, O. J. Rojas 1:45 28. Polyelectrolyte adsorption on cellu lose thin films. 0 . J. Rojas, M. A. Hubbe 2:15 29. Assembling of xyloglucans and lectin onto Si wafers and onto aminoterminated surfaces. D. F. S. Petri, L. B. R. Castro, M. M. Homma, M. R. Sierakowski 2:45 30. Studies of pullulan and pullulan cinnamate self-assembly onto cellulose and self-assembled monolayers via sur face plasmon resonance spectroscopy. A. Kaya, W. G. Glasser, A. R. Esker 3:15 Intermission. 3:30 3 1 . Effect of lignin onto adsorption of xylan rich fractions onto model cellulose surfaces. P. Westbye, T. Kohnke, A. R. Esker, W. G. Glasser, P. Gatenholm 4:00 27. Review of the surface chemistry of lignocellulosics. Y. Li, W. Qin, Q. Shen Section C McCormick Place East RoomE261, Level 2 Nanotechnology: A Fiber Perspective Nanomaterials D. S. Argyropoulos, L. A. Lucia, and O. J. Rojas, Organizers 1:45 33. Toughness enhancement of nanocomposites by chemical treatment of the reinforcing cellulose nanofibers. A. N. Nakagaito, H. Yano 2:15 34. Cellulose fibers with controlled microstructure via electrospinning, with applications in enzymatic hydrolysis. H. J. Park, J. Dingee, S. Fitzgibbon, A. B. Anton, Y. L. Joo 2:45 35. Correlation of rheological properties and "electrospinability" of chitosan. R. R. Klossner, H. A. Queen, A. J. Coughlin, W. E. Krause 3:15 Intermission. 3:30 36. Modified silicone polymers and their interactions with fabric substrates. P. S. Purohit, P. Somasundaran 4:00 37. Heat of vaporization of water asso ciated with cellulose fibers characterized by differential scanning calorimetry. S. Park, R. A. Venditti, H. Jameel, J. J. Pawlak 4:30 38. Surface bonding of metal nanoparticles on cellulose substrates. H. Dong, J. P. Hinestroza Section D Hyatt Regency Chicago Riverside Center General Posters O. J. Rojas,
41. A study on the generation of pyrolytic products derived from sewage sludge using a bubbling fluidized bed reactor. K. S. Yoo, M. S. Eom, N. C. Kim, Ε. Κ. Park, Y. S. Lee 42. Cellulose dissolution in [C4mim]CI. X-F. Zhao, J. Ye, J. Xiong 43. Structure-design and functional-property of biomimetic self-assembly nano-cellulose whiskers. D. Ye 44. Fungal degradation of lignin: Initial proteomic analysis of extracellular protein of fusarium solani f.sp. glycines, grown naturally in the gut of the Asian Longhorned Beetle (ALB). P. A. Springer
Model Cellulosic Surfaces Cellulose Surface Interactions M. Roman and S. J . Eichhorn,
40. Effect of fungal conditioning on ammonia fiber expansion (AFEX) pretreatment of rice straw. V. Balan, S. P. S. Chundawat, Β. Ε. Dale
Organizer
4:00-6:00 39. Effect of Fenton's reaction in the oxidation of a HTMP pulp and in physical properties of adhesive-free MDF boards. F. Pino, J. C. Riquelme, D. Contreras, J. Freer, J. Rodriguez
45. Studies on the properties of quartemary ammonium cation cellulose. S. Yao, W. Shi, X. Chen, Y. Yu 46. Characterization and application of cationic hemicelluloses as wet-end additives in papermaking. R. Junli, S. Runcang, L. Chuanfu 47. Infrared analysis of natural and thermal decomposition of leaf litter from the New Jersey Pinelands. K. Lammers, G. A. Arbuckle-Keil, J. Dighton 48. Plasma grafting of amino compounds enhances transglutaminase mediated cross-linking of wool fibres. J. Cortez, E. Fatarella, L. Lombardi, I. Ciabatti 49. Improving biomass bioconversion through a fundamental understanding of pretreat ment technologies: The case of Ammonia Fiber Expansion (AFEX) pretreatment. S. P. S. Chundawat, V. Balan, Β. Ε. Dale, D. Jones, L. D. Sousa 50. Promotion of stereo complex formation of polylactide with ion complex formation of poly-L-lactide and poly-D-lactide. Y. Tachibana, T. Maeda, Y. Maeda 51. Rheological properties and glucose yield from high solid enzymatic suspensions as a function of enzyme loading and tem perature. B-H. Urn 52. Pyrolysis of cellulose over mesoporous catalysts. S. K. Ahn, M. Yu, J. Y. Koo, S. I. Chang, J. Y. Lee, Y-K. Park 53. Resource utilization of corn plant. A. Singh, A. K. Mohanty 54. Fabrication and characterization of polylactide-microporous zeolite composite films. I. E. Yuzay, R. Auras, S. M. Selke 55. On bleaching as a unit operation. K. R. Sharma 56. Rheology and lubricity of hyaluronic acid in solution. W. E. Krause, J. Liang, R. R. Klossner 57. Self-assembly of cellulose-based trienzyme system for pseudo-reagentless biosensor. M. L. Rabinovich, L. G. Vasilchenko, K. N. Karapetyan, G. P. Shumakovich, O. P. Yershevich, R. Ludwig, D. Haltrich, Y. Hadar, Y. P. Kozlov, A. I. Yaropolov 58. Self-decontaminating cellulose fibers of ΟΡΗ, ΟΡΑΑ and HD enzymes for compre hensive protection against chemical nerve and chemical blister agents. Y. Lee, A. Riecker, T. Mendum, J. P. Puglia 59. Ethoxylated and sugar-based surfactants in recycled paper de-inking. V. Goins, H. Morris, C. Cranford, K. L. Spence, J. Trucker, R. A. Venditti, O. J. Rojas 60. Natural fiber characterization using gener alized 2-D correlation spectroscopy. S. O. Han, Y. M. Jung 61. Synthesis and applications of a novel biocidal polymer. C. Zhu, A. Akdag, J. Liang, S. D. Worley, T. S. Huang 62. Preparation of controllable biotinylated poly(ethylene-co-glycidyl methacrylate) (PE-co-GMA) nanofibers to bind streptavidin-horseradish peroxidase (HRP). D. Wang, G. Sun 63. Structural characterization of the lignin from stone groundwood pulp modified with laccase/mediator system. A. Zhang, M. Qin, R. Sun, Q. Xu, Y. Fu 64. Synthesis and characterization of blue dextrans. D. Viet, S. Beck-Candanedo, D. G. Gray 65. Use of nanofillers as reinforcement agents for biobased composites. O. Sevastyanova, J. F. Kadla
66. Viscoelastic and microstructural properties of cellulose acetate in a mixed solvent system. R. Korehei, J. F. Kadla 67. Adsorption of nonionic and amphoteric polymers on organic thin films. J. Song, O. J. Rojas, M. A. Hubbe, J. P. Hinestroza, W. E. Krause 68. Molecular dynamics simulation during shear in fiber processing. H. Liu, W. E. Krause, J. P. Hinestroza, M. A. Pasquinelli, O. J. Rojas 69. Synthesis and application of a new antimi crobial N-halamine siloxane. L. Kou, J. Liang, A. Akdag, S. D. Worley, H. B. Kocer, R. M. Broughton, T. S. Huang 70. Organosolv pretreatment to enhance bioethanol production from Pinus radiata. E. Araque, C. Parra, J. Freer, J. Rodriguez, R. Mendonça, J. Baeza 71. Xylan self-assembly onto model cellulose surfaces. D. A. Drazenovich, A. Kaya, W. G. Glasser, K. Schwikal, T. Heinze, A. R. Esker 72. Interpretation of XPS (ESCA) spectra of lignocellulosic surfaces. M. Weller, D. G. Gray 73. Isolation of barley arabinoxylans and the effect of structure on material properties. A. Hôije, P. Gatenholm 74. N-Chloramine formation on acyclic amide/ amine monomers grafted cotton cellulose. S. Liu, G. Sun 75. Gelation of cellulose from alkali-urea solvent system. J . Cai, S. Kimura, M. Wada, S. Kuga, L. Zhang 76. Studies on synthesis of quaternary ammonium cationic cellulose. Y. Yu, W. Shi, X. Chen, S. Yao, X. Zhong 77. Effect of pulping conditions and white-rot biodégradation in the content of hexenuronic acids in Eucalyptus globulus kraft pulps. J. Freer, M. Monrroy, C. Salazar, J. Baeza, J. Rodriguez, R. Mendonça 78. Fractional characterization of lignins from perennial ryegrass (L. perenne) and cocksfoot grass (D. glomerata). F. Xu, C. F. Liu, J. L Ren, J. X. Sun, R-C. Sun, S. Curling, P. Fowler, M. S. Baird 79. Algae fiber and its biocomposites. S. Ο. Han, M. W. Lee, Y. B. Seo 80. Analysis of monoglycerides and diglycerides in biodiesel fuel by GC-MS and FTIR. N. S. Chong, S. Ramamoorthy, C. Ashford, A. Buerstetta, K. Donthula, B. G. Ooi 81. Association phenomena of lignin isolated from wood investigated by light scattering. A. R. Gaspar, I. S. Contreras, A. Guerra, L. A. Lucia, D. S. Argyropoulos 82. Cellulose nanocrystals as targeted drug delivery systems. S. Dong, A. A. Hirani, Y. W. Lee, M. Roman 83. Characterization of the noncrystalline regions in the coagulated cellulose film using vapor-phase deuteration and gener alized 2-D correlation infrared spectros copy. Y. Hishikawa, T. Kondo 84. Determination of siringyl/guaiacyl ratio in Eucalyptus spp. decayed by Ceriporiopsis subvermispora. R. Mendonça, C. Puentes, J. P. Elissetche, J. Freer, A. Ferraz 85. Development and validation of an automated microplate method for hydrolysis of AFEX treated lignocellulosics using enzyme mixtures and synergistic additives. S. P. S. Chundawat, V. Balan, Β. Ε. Dale MONDAY MORNING Section A McCormick Place North Room N228, Level 2 Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides Polysaccharides as Sources of Sustainable Materials K. J . Edgar, E. Chiellini,
Organizer Presiding
8:00 86. Starch graft copolymers with con trolled response to environmental changes. J. L Willett
8:30 87. Xylan films and coatings for food packaging applications. M. H. Grôndahl, L. Eriksson, P. Gatenholm 9:00 88. Bioengineering polysaccharide amphiphiles to optimize structure-function relationships. B. Paniliaitis, H. Dams-Kozlowska, M. Mercaldi, M. Curtis, D. L. Kaplan 9:30 89. Cellulose composites prepared using room temperature ionic liquids. R. J. Linhardt, S. Murugesan 10:00 Intermission. 10:15 90. Carbohydrates as feedstocks for the biorefinery: Preparation of new nanostructural materials. J. J. Bozell, S. Park, N. Labbé 10:45 9 1 . Seaweeds and algae as raw materials in the formulation of biobased plastics. E. Chiellini 11:15 92. Modified galactoglucomannan from forestry wastewater utilized for oxygen barrier films and hydrogels. M. S. Lindblad, A-C. Albertsson, O. Dahlman, J. Sjogren Section Β McCormick Place Lakeside Room E257, Level 2 Model Cellulosic Surfaces Native Cellulose Model Surfaces M. Roman and S. J . Eichhorn,
Organizers
8:30 93. Submonolayer films of cellulose nanocrystals on silica, titania and amor phous cellulose. E. Kontturi, L-S. Johansson, J. Laine 9:00 94. Preparation of cellulose model surfaces with different degree of ordering and determination of the interaction between these surfaces with different methods. L. Wâgberg, M. Eriksson, S. Notley 9:30 95. Dependable cellulose I crystallinity determination using near-IR FT-Raman. U. P. Agarwal, R. S. Reiner, S. A. Ralph 10:00 Intermission. 10:15 96. Smooth model films containing nanocrystalline cellulose. E. D. Cranston, D. G. Gray 10:45 97. Application of multiple incident media ellipsometry technique on trimethylsilylcellulose, regenerated cellulose, and cellulose nanocrystals. U. Karabiyik, M. Roman, A. R. Esker 11:15 98. Ink-jet printing of cellulose nanocrystal suspensions. F. Navarro, M. Roman Section C McCormick Place Lakeside Room E352, Level 3 Nanotechnology: A Fiber Perspective Nanocomposites D. S. Argyropoulos, L. A. Lucia, and O. J . Rojas, Organizers 8:30 99. Cellulose-loaded polystyrene composites: Effect of sorbitan monostearate and production of nanofibers and nanostructures for new generation multifunctional materials. J. Kim, G. A. Montera, X. Wang, D. S. Argyropoulos, J. Genzer, J. P. Hinestroza, O. J. Rojas 9:00 100. The use of cellulose nanocrystal for the preparation of inorganic nanocrystals. Y. Shin, B. Arey, C. Wang, I-T. Bae, G. J. Exarhos 9:30 101. Ultra-low thermal expansion composites reinforced by planar orientation of bacterial cellulose. M. Nogi, K. Handa, H. Yano
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-15
CELL
TECHNICAL PROGRAM
10:00 102. Property enhancement of optically transparent composites reinforced with a series of acetylatèd bacterial cellulose nanofibers. S. Ifuku, M. Nogi, K. Abe, K. Handa, F. Nakatsubo, H. Yano 10:30 103. Cellulose nanocomposite barrier films. J. Simonsen, S. Paralikar, J. L. Lombardi MONDAY AFTERNOON Section A McCormick Place North Room N228, Level 2 Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides Polysaccharide Blends and Nanocomposites K. J . Edgar,
Organizer
A-C. Albertsson,
Presiding
1:45 115. Performance of bioactive molecules on cotton textiles. J. V. Edwards, S. C. Goheen, J. Arnold, P. S. Howley 2:15 116. Halamine chemistry and selfdecontaminating textile materials. G. Sun 2:45 117. Flame resistant cotton durability and antimicrobial properties by using a novel epoxy phosphonate monomers. B. Condon, G. R. Siragusa, S. Chang 3:15 Intermission. 3:30 118. Experimental evaluation and modeling of gas permeation through chemical protective materials. T. Turel, E. Shady, Y. Gowayed, G. Buschle-Diller 4:00 119. Antibacterial cellulose surfaces using plasma polymerization. S. N. Jampala, S. Manolache, K. Leonas, F. S. Denes, M. Sarmadi 4:30 120. The bonding of a hydroxyl-functional organophosphorus flame retarding agent to nylon fabric and the flame retardant finishing of cotton/nylon military fabric. C. Q. Yang, H. Yang 5:00 Division Business Meeting. M O N D A Y EVENING
1:45 104. Renewable and/or degradable polymers. A-C. Albertsson 2:15 105. The relationship between corn fiber gum structure and its functional properties. M. P. Yadav, R. A. Moreau, D. B. Johnston, Κ. Β. Hicks 2:45 106. Triphasé equilibria in cellulose nanocrystal suspensions containing neutral and charged dextrans. S. Beck-Candanedo, D. Viet, D. G. Gray 3:15 Intermission. 3:30 107. Nanocellulose as scaffolds for tissue engineering and organ regeneration. A. Bodin, H. Bâckdahl, B. Risberg, P. Gatenhoim 4:00 108. Novel nanocomposites based on renewable resources. K. A. Oksman
Section A Section C Hyatt Regency Chicago Riverside Center
O. J . Rojas,
Organizer
8:00-10:00 80, 82-83, 85, 93,112. See previous listings. 165, 174,176. See subsequent listings.
J. V. Edwards,
TUESDAY MORNING
8:25 Introductory Remarks. 8:30 135. New n-halamine antimicrobial coatings for textiles. S. D. Worley, J. Liang, K. Barnes, J. Lee, R. M. Broughton, T. S. Huang 9:00 136. Electrospun shape memory polyurethane-laponite nanocomposite mats recover intrinsic stretch. S. M. Lift, P. Bhattacharyya, G. H. McKinley 9:30 137. Modification of the NIR signal of textile fabrics via colloidal self-assembly. C. M. Diaz, J. P. Hinestroza 10:00 Intermission. 10:15 138. Carbonized and activated nonwovens as high performance acoustic materials. Y. Chen, N. Jiang 10:45 139. Nanocomposite silk fibers. M. K. Gupta, J. M. Slocik, L. F. Drummy, M. M. Tomczak, R. R. Naik 11:15 140. Catalytic electrospun oxime nanofibers. L. Chen, L. Bromberg, T. A. Hatton, G. C. Rutledge 11:45 Panel Discussion.
McCormick Place Lakeside Room E265, Level 2
M. Roman and S. J . Eichhom,
Organizers
1:15 109. Interactions of cellulose surfaces: Friction, adhesion and polysaccharide adsorption. N. Nordgren, J. Stiernstedt, H. Brumer, L. Wâgberg, D. G. Gray, M. W. Rutland 1:45 110. Cellulose nanofibril films as a model for the cellulose fibre surface: Application in adsorption and surface force studies. M. Ôsterberg, S. Ahola, J. Salmi, J. Laine 2:15 111. Cellulose model surfaces of plant cell wall and their reactivites. A-B. Véronique, H. Youssef, F. Laurence, M. Michael, D. Roger 2:45 112. Studies on dextran and β-cyclodextrin functionalized gold surfaces. S. Hornig, A. R. Esker, T. Heinze 3:15 Intermission. 3:30 113. Model films of cellulose to monitor enzyme activity. X. Turon, O. J. Rojas, J. Song, K. L. Spence, D. S. Argyropoulos, R. Deinhammer 4:00 114. Mode of action of fungal cellulases studied using model cellulose films and a quartz crystal microbalance. P. Josefsson, L. Wâgberg, G. Henriksson Section C McCormick Place Lakeside Room E353 C, Level 3
Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides Polysaccharides in Drug Delivery and Medicine K. J . Edgar,
Organizer
D. O. Thompson,
Presiding
8:00 121. Utility of CAPTISOL® (sulfobutylether beta-cyclodextrin SBE-beta-CD) for delivery of poorly soluble drugs. D. O. Thompson, J. Rodriguez 8:30 122. Noncovalent cyclodextrin polymers and their pharmaceutical uses. L. Szente 9:00 123. Polysaccharides in oral drug delivery: Recent applications and future perspectives. S. Klein 9:30 124. Comparison of cellulose and high-amylose starch as drug delivery excipients. R. H. Marchessault, G. Chauve 10:00 Intermission. 10:15 125. CMCAB for drug delivery: Simple zero order release, and so much more. K. J. Edgar, J. Posey-Dowty, M. C. Shelton, T. L. Watterson, L. Lingerfelt, A. K. Wilson 10:45 126. Influence of polymer type on the crystallization tendency of a model amorphous drug. L. S. Taylor 11:15 127. Microbial cellulose as nanostructured biomaterial for medical implants. D. O. Klemm, D. A. Schumann, F. Kramer, N. HeBler, W. Fried Section Β
Protective Fibers with Military and Medical Applications Fiber Structure/Function Relationships and Properties J. V. Edwards and S. C. Goheen, Organizers S. A. Fossey,
Presiding
1:40 Introductory Remarks.
16-TECH
Protective Fibers with Military and Medical Applications Structure/Function Relationships and Nanofibers
29, 34, 48, 50, 53, 56-58, 64-65, 68, 72-73,
Section A
Model Cellulosic Surfaces Native Cellulose Model Surfaces
McCormick Place East Room E264, Level 2
Sci-Mix
Section Β McCormick Place Lakeside Room E257, Level 2
8:30 128. Learning lessons from nature for fibre bioprocessing and bioengineering. A. Cavaco-Paulo 9:00 129. Designer protein-based perfor- . mance materials. W. A. Cuevas, K. Sanford, K. D. Collier, M. Du, N. Chow, M. Kumar 9:30 130. Isomerases for functional modifica tion of fibrous polymers. T. Tzanov, F-D. Munteanu, A. Cavaco-Paulo 10:00 131. Effect of various pre-treatments on the accessibility of target amino acids in wool fibre proteins to transglutaminase and tyrosinase. J. Cortez, C. Kulik, J. Ellis, G. Freddi, R. Lantto, E. Heine 10:30 132. Enzyme-mediated crosslinking of wool. J. M. Cardamone 11:00 133. Biocatalytic modification of natu rally occurring Iron porphyrin as a renew able catalyst. S. Nagarajan, R. Tyagi, R. Nagarajan, J. Kumar, A. C. Watterson, F. Bruno, L. A. Samuelson 11:30 134. Enzymatic modification of poly mers. S. Heumann, A. Eberl, M. Schroeder, A. Cavaco-Paulo, G. M. Guebitz
Organizer
S. A. Fossey and S. C. Goheen,
Presiding
G. Buschle-Diller, G. M. Guebitz, and A. Cavaco-Paulo, Organizers 8:25 Introductory Remarks.
Section Β McCormick Place Lakeside Room E267, Level 2 Functionalization of Renewable Materials Lignin and Other Natural Compounds G. Buschle-Diller, G. M. Guebitz, and A. Cavaco-Paulo, Organizers 1:30 145. Effect of lignin on the enzymatic synthesis of colorants. R. Stephen, G. Buschle-Diller 2:00 146. Enzymes in functionalization of lignin-rich fibres. A. Suurnàkki, S. Grônqvist, H. Mikkonen, M. Orlandi, L. Viikari 2:30 147. Furfuryl alcohol modified wood. L. G. Thygesen, Τ. Μ. Venaas, S. Barsberg, T. Elder 3:00 151. Carbonation of vernonia oil. J. W. Rawlins, N. Mann, S. K. Mendon, S. F. Thames 3:30 149. A novel solid acid catalysis pre pared from cellulose for the production of biodiesel. G. Chen, Β. Fang 4:00 150. Modified gum acacia: A simple effective method of synthesis. M. L. Akins, N. Naouli 4:30 148. Dynamic dissolution of tea poly phenol in water and DMF and related model. L-H. Zhang, Q. Shen, R-F. Hu 5:00 152. Esterified fructans from tequila agave plant to produce microspheres for drug delivery to the colon. R. Starbird, V. Zuniga, B. Saake, E. Delgado, G. Toriz Agricultural Biomass, Biobased Products, and Biofuels Defining the Challenges Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF WEDNESDAY MORNING Section A McCormick Place Lakeside Room E265, Level 2 Polysaccharide Processing: The Essential Component in a Sustainable Energy Future W. T. Winter,
Organizer
TUESDAY AFTERNOON Section A McCormick Place Lakeside Room E265, Level 2 Anselme Payen Award Symposium: Synthesis and Structure/Property Relationships of Polysaccharides Award Session K. J . Edgar, Organizer,
Presiding
1:15 141. High throughput screening meth ods for determining solubility and dissolu tion profiles. N. L. Buchanan, C. M. Buchanan 1:45 142. On the road to cellulose and chitin nanocomposites from sustainable materi als. J. D. Goodrich, W. T. Winter
McCormick Place Lakeside Room E267, Level 2 Functionalization of Renewable Materials Enzymatic Modifications
2:15 143. Synthesis, properties and their LB film preparation of regioselectively substi tuted cellulose cinnamates. T. Kondo, M. Yamamoto, W. Kasai, K. Tsutsumi, M. Morita 2:45 Intermission. 3:00 144. Building new drug delivery sys tems: In vitro and in vivo studies of drughydroxybutenyl cyclodextrin complexes. C. M. Buchanan
8:25 Introductory Remarks. 8:30 153. Glucanase activity on model thin films of cellulose. X. Turon, K. L. Spence, R. Deinhammer, O. J. Rojas 9:00 154. Enzymatic hydrolysis of lignocellulosic biomass in yellow pine sawdust for production of bioethanol. A. B. Simon, H-D. Shin, R. R. Chen 9:30 155. Changes in cellulose structure during enzymatic hydrolysis. C. Felby, J. B. Kristensen, H. Jorgensen, T. L. Eberhardt, T. Elder 10:00 156. Can cellulose nanocrystals be a cellulosic ethanol coproduct? W. T. Winter 10:30 157. Strain-induced crystallization in solution-spun cellulose triacetate fibers. J. Braun, J. F. Kadla 11:00 Concluding Remarks. Section Β McCormick Place Lakeside Room E267, Level 2
Please refrain from using cellular telephones and cameras during technical sessions.
Functionalization of Renewable Materials Polymers and Composites G. Buschle-Diller, G. M. Guebitz, and A. Cavaco-Paulo, Organizers 8:25 Introductory Remarks.
CELL/CHED
8:30 158. Cellulose nanocrystals as rein forcement for shape memory polyurethanes. M. L Auad, S. R. Nutt, M. I. Aranguren, N. E. Marcovich 9:00 159. Chitosan-PEG-clay nanocomposite: A novel chitosan spongy scaffold. S. Chirachanchai, T. Ponyomma 9:30 160. Composite materials produced by particle-bonding with gliadin as a glue. S. Kim, J. Xu 10:00 161. Modification of wood flour sur faces by esterification with acid chlorides: Use in HDPE/wood flour composites. Y. Zhang, C. U. Pittman Jr., H. Toghiani, Y.Xue 10:30 162. Functional cellulose via RAFT polymerization. S. Perrier, D. Roy, J. T. Guthrie 11:00 163. Polylactide-perfluoropolyether block copolymer. A. Singh, D. Haynes, A. K. Naskar, D. W. Smith Jr., M. J. Drews 11:30 164. Synthesis and characterization of substituted poly(lactic acid) bearing - C F 3 groups. D. Haynes, D. W. Smith Jr. 12:00 165. Surface modification of nanocrystalline chitin. J . D. Goodrich, W. T. Winter Agricultural Biomass, Biobased Products, and Biofuels Process and Product Control Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF WEDNESDAY AFTERNOON Section A McCormick Place East Room E265, Level 2 Cellulose-Based and Other Green Composites J. P. Hinestroza,
Organizer
1:25 Introductory Remarks. 1:30 166. Cellulose microfiber functionalizing through nanocoating with polyelectrolytes, enzymes, and nanoparticles. Y. M. Lvov 2:00 171. Production of biobased composites with nano- and mico-scale dispersion using solid-state shear pulverization. A. M. Walker, Y. Tao, J. R. Dorgan, J. M. Torkelson 2:30 168. Integrating biosynthesis and prop erty design in bacterial cellulose nanocomposites. M-P. Laborie, Ε. Ε. Brown 3:00 Intermission. 3:15 169. Interfacial properties of cellulosic based composites using Raman spectros copy and synchrotron X-ray diffraction. S. J. Eichhorn, B. Mottershead 3:45 170. Study of reactions mechanisms in furfuryl alcohol polymerization. N. Guigo, L. Vincent, A. Mija, N. Sbirrazzuoli, H. Hoydonckx 4:15 167. Determination of the critical con centration for hydroxypropylcellulose solution by Theological method. X-H. Jia, X-Y. Huang, Q. Shen Section Β McCormick Place Lakeside Room E267, Level 2 Functionalization of Renewable Materials Functionalized Films and Coatings G. Buschle-Diller, G. M. Guebitz, and A. Cavaco-Paulo, Organizers 1:30 172. Biobased functional polyesters for coating applications: Synthesis, character ization and application. B. A. J. Noordover, R. Duchateau, C. E. Koning, R. A. T. M. van Benthem, W. Ming, J. van Haveren, D. S. van Es 2:00 173. Surface functionalization of poly meric surfaces. I. Luzinov 2:30 174. Fabrication of honeycomb-pat terned polysaccharides. Y. Uraki, C. Matsumoto, T. Kishimoto, M. Ubukata, H. Yabu, M. Tanaka, M. Shimomura 3:00 175. Mechanical properties of oriented high amylose starch films: Orientation by drawing of starch triacetates followed by deacetylation. R. L. Shogren 3:30 176. Fabrics for VOC capture and conversion. D. Vynias, M. W. Frey
4:00 177. Barrier materials for controlled release of bioactive compounds. G. Buschle-Diller, X. Ren, A. M. Karaaslan, Z. Xie, T-S. Huang 4:30 178. Nonleaching antimicrobial films prepared from surface modified microfibrillated cellulose. M. Andresen, P. Stenstad, T. Mo retro, P. Stenius Agricultural Biomass, Biobased Products, and Biofuels Process Characterization Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF THURSDAY MORNING Section A McCormick Place East Room E265, Level 2 Cellulose-Based and Other Green Composites J. P. Hinestroza,
Organizer
8:55 Introductory Remarks. 9:00 179. Toward advanced green compos ites. A. N. Netravali 9:30 180. Characterization of enzyme-modi fied soy protein isolate. J. N. Shera, J. W. Rawlins, S. F. Thames 10:00 181. Evaluation of wetting in pulpbased composites using pulse NMR relaxometry. J. R. Feldkamp 10:30 Intermission. 10:45 182. Plastics from proteins produced by animal coproduct industry. S. Sharma, I. Luzinov 11:15 183. Synthesis of submicrometric silver crystals using cow bone as template. V. Sânchez-Mendieta, R. A. Morales-Luckie, I. G. Becerril-Juérez, F. Ureha-Nunez, R. Lopez-Castafiares 11:45 184. Anatomy, ultrastructure and lignin distribution in cell wall of Salix psammophila. F. Xu, G. Zhao, R. Sun Section Β McCormick Place Lakeside Room E267, Level 2 Functionalization of Renewable Materials Modification of Fibrous Materials G. Buschle-Diller, G. M. Guebitz, and A. Cavaco-Paulo, Organizers 8:25 Introductory Remarks. 8:30 185. Investigating the mechanism of biobased, formaldehyde-free crosslinkers for cellulosic textiles. Ε. Ν. Johnson, S. K. Mendon, J. W. Rawlins, S. F. Thames 9:00 186. FTIR characterization of biobased, formaldehyde-free crosslinkers for cellulo sic textiles. Ε. Ν. Johnson, S. K. Mendon, J. W. Rawlins, S. F. Thames 9:30 187. New nonformaldehyde durable press finishing agent for cotton by the reactions of maleic acid and sodium hypophosphite on cotton. C. Q. Yang, C. Dongzhong 10:00 188. Applications of non-traditional flame retardant finishing agents to reduce the flammability of cotton fleece. C. Q. Yang, X. Wu 10:30 189. Tactile properties of enzyme treated yarns and fabrics. R. Parachuru, V. Kasi, F. L. Cook, G. Buschle-Diller 11:00 190. Chemical modification of wood by acetic anhydride. Y. Çelen, D. P. Harper, N. Labbé
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
11:30 191. Preparation of succinic derivatives of cellulose in room-temperature ionic liquid 1-allyl-3-methylinidazolium chloride. C. Liu, R. Sun, A. Zhang, J. Ren, X. Wang Agricultural Biomass, Biobased Products, and Biofuels Improving Bioproduct Design Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF THURSDAY AFTERNOON Section A McCormick Place East Room E265, Level 2
10:05 5. Characteristics of successful and unsuccessful students in solving stoichiometric problems. O. Gulacar, H. Fynewever 10:25 6. Learning the language of organic chemistry: How do students develop reaction mechanism problem-solving skills? J. P. Anderson, G. M. Bodner 10:45 Intermission. 10:55 7. Contextualizing chemistry content knowledge for middle and high school teachers: Which chemistry knowledge sticks and how is knowledge impacted by teaching it? H. Sevian 11:15 8. Use and effect of teaching aids in the teaching and learning of chemistry. M. E. Ighedo
Cellulose-Based and Other Green Composites
Section Β
J. P. Hinestroza,
McCormick Place North Room N230A, Level 2
Organizer
1:25 Introductory Remarks. 1:30 192. Effect of compatibilizer blends on mechanical and thermal properties of HDPE/hardwood/organoclay nanocomposites. D. De Kee, M. Hetzer, T. Poloso 2:00 193. Transcrystallization at cellulose surfaces revisited. D. G. Gray 2:30 194. Characterization of acetylated Eucommia ulmoides Oliver hemicelluloses. F. Xu, H. Zhao, R. Sun 3:00 Intermission. 3:15 195. A novel solvent system for cellulose dissolution and spinning. R. Kotek, H. J. Lee, J. A. Cuculo, J. Onori 3:45 196. Starch and alkyl ketene dimer microcellular foam particles. R. A. Venditti, J. J. Pawlak, A. I. Bolivar, K. El-Tahlawy 4:15 197. A review of recent development in lignin-synthetic polymers blends. X-H. Jia, Q. Shen, X-Y. Huang Agricultural Biomass, Biobased Products, and Biofuels The Cellulosic Challenge Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
CHED Division of Chemical Education C. Middlecamp, W. E. Jones Jr., and G. M. Bodner, Program Chairs
Community College Led Advances in Undergraduate Education Cosponsored with CMA, WCC, and YCC T. Higgins, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 9. National Science Foundation: Fund ing opportunities for community colleges. E. L. Lewis 8:55 10. Introducing community college undergraduates to the world of research. S. I. Lall-Ramnarine 9:15 11. Improving organic chemistry stu dents' rotation ability. Η. Μ. Sklenicka 9:35 Intermission. 9:45 12. Learning chemistry through cocurricular activities. Μ. Ε. Ayoub 10:05 13. Challenges of an on-line chemistry class with labs. R. Pankayatselvan 10:25 14. The Numeracy Project: Phase II. C. Geary, T. Neal 10:45 Intermission. 10:55 15. New renewable fuels teaching materials for general chemistry classes of all levels. S. L Britton, K. A. Walz 11:15 16. Community college undergraduate research: You can do it! S. Shih 11:35 17. Establishing an interdisciplinary undergraduate research course at Oakton Community College. M. Graber, G. Mines, C. Ward, T. Trobec, T. Firak, K. Shanahan 11:55 Discussion. Section C McCormick Place North Room N230B, Level 2
SOCIAL EVENTS: Dinner: Sat High School/College Interface Luncheon: Sun Social Hour: Sun
Using Social Networking Tools to Teach Chemistry Cosponsored with CINF H. Pence,
Organizer
A. Gay, Organizer,
Presiding
SUNDAY MORNING Section A McCormick Place North Room N227A, Level 2 Research in Chemical Education Conceptions Research W. J . F. Hunter,
Organizer
D. Mulford, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1. Investigation of the teaching of Lewis dot structures in the first-year chemistry course. R. A. Krystyniak, J. Erickson 8:55 2. Examining general chemistry students' thought processes via interviews. C. G. Shepler, K. D. Schurmeier, C. H. Atwood 9:15 3. Written and pictorial explanations of physical equilibrium generated by experts and novices. S. Akaygun, L. Jones 9:35 Intermission. 9:45 4. Freshman chemistry students' microscopic interpretations of their visible observations of melting and dissolving. K. C. Smith, M. B. Nakhleh
8:30 Introductory Remarks. 8:35 18. Keeping up and staying current: Harnessing the chemical information web with RSS. Τ. Μ. Vogel 8:55 19. Find it, tag it, share it: Social bookmarking in chemistry education. J. N. Currano, A. Day 9:15 20. RSS and social tagging: On the desktop and in the classroom. L. E. Pence, Η. Ε. Pence 9:35 Intermission. 9:45 2 1 . Blogging the culture of chemistry. Μ. Μ. Francl 10:05 22. Video podcasting in an under graduate introductory chemistry course. J. I. Gelder, T. Greenbowe 10:25 23. Experimentation with podcasting in an organic chemistry setting as a second ary tool for students. J. Picione, K. Murphy 10:45 Intermission. 10:55 24. Second Life as a scientific educa tion medium. J. Scott 11:15 25. Teaching organic chemistry with blogs and wikis. J-C. Bradley, B. Ritter-Guth 11:35 26. Wikis, podcasts and screencasts (oh my!) in undergraduate chemistry coursework and research. K. A. Walters
I f!C 1-1-1 /
TECHNICAL PROGRAM
CHED Section D McCormick Place North Room N229, Level 2 Sustainability and Chemical Education: Industry's Perspective Cosponsored with l&EC, CEI, and SUST M. A. Abraham,
Organizer
M. A. Fisher, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 27. The world is changing and students need to be empowered for change. F. K. Wood-Black 9:00 28. Sustainability and the role of the chemist. M. A. Gonzalez 9:25 29. Preparing chemistry students for "sustainable" jobs: The growing need for green chemists, green engineers and sustainable product development experts. L. G. Heine 9:50 Intermission. 10:00 30. Some examples of industrial involvement in green chemistry education. B. W. Cue Jr. 10:25 3 1 . DuPont biorefinery and biobased materials. M. A. Harmer 10:50 32. Approaching a century of sustain ability: The Eastman Chemical Company experience. J. R. Zoeller 11:15 33. Considerations for sustainable material development: Polylactic acid. L. M. Babcock Section Ε McCormick Place North Room N227B, Level 2
Presiding
8:30 Introductory Remarks. 8:35 34. EPA's drinking water regulatory process. J. B. Kempic 9:00 35. Drinking water quality and treatment research at Louisville Water Company. R. Song, J. Wang 9:25 36. Testing residential water treatment technologies for contaminant reduction performance. R. N. Andrew 9:50 Intermission. 10:00 37. Point of use and point of entry technologies. R. P. Regunathan 10:25 38. Microbial filtration utilizing carbon block, reverse osmosis and other point-ofuse membrane technologies. J. Buteyn, G. Hatch, M. Kinsey 10:50 39. Global drinking water issues and solutions. E. Thiers 11:15 Intermission. 11:25 40. Testing the waters: Hands-on water testing for students. D. A. Katz 11:50 Panel Discussion. Section F McCormick Place North Room N231, Level 2 Process-Oriented Guided Inquiry Learning (POGIL) R. S. Moog,
Organizer
A. Silva, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 4 1 . POGIL and the POGIL Project. R. S. Moog 8:55 42. What does a typical implementation of POGIL look like? J. N. Spencer, R. S. Moog 9:15 43. POGIL in the laboratory. F. J. Creegan 9:35 Intermission. 9:45 44. POGIL and the large class: Strate gies and results. S. M. Ruder 10:05 45. POGIL activities in an organic and biochemistry course. C. Conway 10:25 46. Guided inquiry: Intermolecular forces using manipulatives and molecular modeling. E. M. Howson, D. Krone
18-TECH
4:35 60. Correlations between student hyper media navigation strategies and perfor mance. E. M. Epp, K. T. Blaske, G. C. Weaver
Section D
Section G
Section Β
McCormick Place North Room N228, Level 2
McCormick Place North Room N230A, Level 2
George C. Pimentel Award in Chemical Education: Symposium in Honor of A. Truman Schwartz Science Literacy and the Liberal Art of Chemistry
High School Teachers Program: Inquiring Minds Want to Know Cosponsored with WCC
NSF Catalyzed Innovations in the Undergraduate Curriculum
C. L. Stanitski,
S. H. Hixson,
W . C. Wolsey, Organizer,
A. LeFevre,
Organizer
L. R. Marek, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 48. Award Address (James Bryant Conant Award in High School Chemistry Teaching, sponsored by Thermo Electron Corporation). Thirty-nine years of motivat ing and enjoying students. E. W. Siegrist 9:20 49. Demonstrating carbonate chemistry from the pyramids to soda pop. J. J . Fortman 9:50 50. Process oriented guided inquiry learning POGIL. J . N. Spencer, P. L. Daubenmire 10:50 Intermission. 11:00 5 1 . Demonstrations of the dead chem ists society. W. C. Deese Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Sponsored by HIST, Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF SUNDAY AFTERNOON
Educating the Public About the Challenges for Improving the Quality of Drinking Water C. Li, Organizer,
10:45 Intermission. 10:55 47. Lessons learned from 10 years of POGILing. M. D. Perry Jr. 11:15 Panel Discussion.
Section A McCormick Place North Room N227A, Level 2 Research in Chemical Education Programmatic and Curricular Research D. Mulford,
Organizer
W. J . F. Hunter, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 52. Discussion sections for Introductory Chemistry. B. Blake, K. A. Chambers 1:55 53. Effects of a learning assistant on grade improvement and grade distribution. J. T. Engle, W. J. Donovan, P. J. Hollinger, C. B. Monroe 2:15 54. Student success via the 'Two Plus Two" workshop strategy. Y. J . Kim, W. E. Dickson, J. E. Hernandez, O. M. Khateeb, K. A. Loya, J. E. Becvar 2:35 Intermission. 2:45 55. Interventions planned for general chemistry topics based on IRT assess ment. K. D. Schurmeier, C. G. Shepler, C. H. Atwood 3:05 56. How IRT and post test interviews have impacted our teaching. C. H. Atwood, K. D. Schurmeier, C. G. Shepler 3:25 57. ConcepTests using an electronic response system in general chemistry courses. W. J. Donovan 3:45 Intermission. 3:55 58. Analysis and interpretation of the results for case-based CPR assignments at UNH. C. T. Cox Jr., C. F. Bauer, L. S. Langdon, K. Woznack 4:15 59. Use of an organic extraction simula tion to improve students' understanding and develop their mental models. S. Supasorn, J. P. Suits, L. L Jones
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Organizer
P. Varma-Nelson,
Presiding
1:30 Introductory Remarks. 1:35 6 1 . DUE: Supporting undergraduate education at NSF. E. L. Lewis, S. H. Hixson, Η. Η. Richtol, P. Varma-Nelson 1:55 62. Development and assessment of a chemistry-based video game. G. C. Weaver, C. Morales, K. J. Martinez-Hernandez 2:15 63. On-line support for problem solving in introductory chemistry. D. Yaron, M. Karabinos, G. Leinhardt 2:35 Intermission. 2:45 64. Advances in ACE Organic, an on-line organic chemistry homework pro gram. R. B. Grossman, R. A. Finkel, K. Joiner, M. S. Allu 3:05 65. Greener educational materials for undergraduate organic chemistry: Strate gies to catalyze curriculum development and adoption. J. E. Hutchison, K. M. Doxsee, J. A. Haack 3:25 66. Making chemistry relevant to the STEM freshman student: Examples from inter-disciplinary seminar courses devel oped in an NSF-STEP sponsored project. S. Basu-Dutt, V. J. Geisler, D. Otwell 3:45 Intermission. 3:55 67. Successful STEP for science. L. G. Spears, V. Estrera, A. J. Uzman, S. P. Janes 4:15 68. Preparing future faculty to effec tively teach diverse student audiences at the Center for the Integration of Research, Teaching, and Learning. J. N. Burstyn, N. Gunasekera, F. O. Ayorinde Section C McCormick Place North Room N230B, Level 2 Using Social Networking Tools to Teach Chemistry Cosponsored with CINF A. Gay and H. Pence, M. Holman,
Organizers
Presiding
1:30 Introductory Remarks. 1:35 69. Wikis in chemistry and education. M. A. Walker, Τ. Β. Rauchfuss 1:55 70. Using wiki in education: The sci ence of spectroscopy. S. Mader 2:15 7 1 . Wikipedia: A holistic model for the communal creation of chemical course content. H. S. Rzepa, M. E. Cass 2:35 Intermission. 2:45 72. Hierarchical wiki links index. R. E. Belford 3:05 73. Social software: Uses, hopes and dreams at the American Chemical Society. M. Tinnesand, T. Taylor 3:25 74. Effective communication in an on-line environment. M. Towns, R. S. Cole 3:45 Intermission. 3:55 75. Public good: A reverberation under pinning the foundation of academic research? B. A. Greenman 4:15 76. Supranational chemistry, wireless and pocket-sized. W. A. Warr 4:35 77. What is the future of social network ing software in the chemistry classroom? Η. Ε. Pence
McCormick Place North Room N229, Level 2
Presiding Presiding
1:30 Introductory Remarks. 1:35 78. The familiarity of chemistry and the role of chemists in achieving science literacy. Β. Ζ. Shakhashiri 2:00 79. Intellectual kinetics and thermody namics of interdisciplinary research. C. M. Rienstra 2:25 80. Research in high school chemistry. L. Fruen 2:50 8 1 . Scientific literacy: Institutes of tech nology and ninny ideas. C. L. Stanitski 3:15 Intermission. 3:25 82. Understudied science: Challenging the neglect of chemistry by philosophers of science. H. VandeWall 3:50 83. Chemistry at a liberal arts college, in context. W. C. Wolsey 4:15 84. Award Address (George C. Pimen tel Award in Chemical Education, spon sored by Rohm and Haas Company). Chemistry education, science literacy, and the liberal arts. A. T. Schwartz Section Ε McCormick Place North Room N227B, Level 2 Nanotechnology in Undergraduate Education Incorporating Nanoscale Science into Undergraduate Courses K. A. O. Pacheco, Organizer,
Presiding
1:30 Introductory Remarks. 85. Withdrawn. 1:35 86. Development of a nanomaterials one week intersession course at NKU. H. A. Bullen, K. A. Walters 1:55 87. Integration of nanoscale science and technology into undergraduate cur ricula. S. S. Iyer, J. Bickle, T. Mantei, I. Papautsky, M. Schulz, V. Shanov, L. Smith, A. Steckl 2:15 Intermission. 2:25 88. Integration of nanoscience into the undergraduate curriculum: From fabrica tion to practical applications of nanodevices. N. J . Pinto 2:45 89. Introducing nano and society issues into the undergraduate and graduate classrooms. W. C. Crone, G. M. Zenner, C. A. Miller, K. D. Ellison, C. Tahan, R.Leung 3:05 90. Nanotechnology research-based courses for freshmen and sophomores. T. W. Odom 3:25 Intermission. 3:35 9 1 . Nanotechnology class: Principles that reinforce scientific concepts and concepts that involve students. D. Teeters 3:55 92. Nanotechnology undergraduate education: An active learning experience for undergraduates. E. Ferrer, L. Gonzalez, M. E. Castro 4:15 93. Thinking small: Activities to promote visualization at the nanoscale. D. H. Johnston Section F McCormick Place North Room N231, Level 2 Process-Oriented Guided Inquiry Learning (POGIL) Implementing POGIL in the Classroom R. S. Moog and A. Silva, F. J . Creegan, 1:30
Presiding
Introductory Remarks.
Organizers
CHED 1:35 94. Phasing into POGIL: There are many options. R. D. Libby 1:55 95. Incorporation of POGIL into the organic lecture at Arkansas State Univer sity. M. J. Panigot 2:15 96. Scaling up: Strategies for the suc cessful transition from teaching small POGIL classes to the large lecture envi ronment. E. C. Bucholtz 2:35 Intermission. 2:45 97. Implementation of POGIL in an introductory chemistry course. A. S. Silva 3:05 98. POGIL in a one-semester GOB course: How much guidance does a nursing major need? L. D. Frost 3:25 99. Experiences and reflections of a new instructor using POGIL. S. M. Lewis 3:45 Intermission. 3:55 100. POGIL in Physical Chemistry: Getting started. J. M. LoBue 4:15 Discussion. Section G McCormick Place North Room N228, Level 2 High School Teachers Program: Inquiring Minds Want to Know Cosponsored with WCC A. LeFevre,
Organizer
L. R. Marek, Organizer,
Presiding
1:30 101. Eternal verities: How to make your students hate you less if not necessarily love you more. G. M. Bodner 2:20 102. Celebrate Earth Day: Resources from the Journal of Chemical Education. M. E. Harris, L. Fanis 2:50 Intermission. 3:00 103. Redesign of advanced placement chemistry. J. N. Spencer 3:25 104. Lowering students' activation energy for learning chemistry. L. Hogue, A. M. Sarquis Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Sponsored by HIST, Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF Starting a Successful Research Program at a Predominantly Undergraduate Institution Sponsored by YCC, Cosponsored with Council on Undergraduate Research, CHED, and PROF S U N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center General Posters R. W . Schwenz, Organizer,
Presiding
7:30-9:30 105. "Rain Check Network": A national out reach project. M. H. LeFaivre 106. National Chemistry Week: The "Extreme" way to celebrate. W. F. Carroll Jr., T. A. Halmi 107. CHED regional meetings initiative. M. Z. Hoffman 108. Volunteer engagement and recognition opportunities of the Committee on Com munity Activities. C. V. Gauthier, P. G. Fox 109. High school nanoscience outreach program. C. S. Joiner, S. H. Tolbert 110. Making the nanoscale larger than life: University of Wisconsin-Madison NSEC education and outreach. A. E. Greenberg, J. M. H. Tomasik, D. Nutbrown, C. Pharr, K. A. Robertson, J. W. Moore 111. Chemists celebrate Earth Day 2007: Recycling - Chemistry Can! M. A. Fisher, A. Jorgensen, Κ. Μ. Jackson 112. Your home—It's All Built on Chemistry: Highlights from National Chemistry Week 2006. R. M. de Groot, M. Sheets, T. A. Halmi, Κ. Μ. Jackson 113. Cognitive load analysis of tests from the ACS Examinations Institute. K. Knaus, K. Murphy, J. Picione, T. Holme
114. Electronic delivery of ACS exams assessment materials. T. Holme 115. Investigating item order effects in ACS exams. K. Affeldt, T. Holme 116. Looking for persistent misconceptions in multiple choice exams. K. Murphy, J. Picione, K. Knaus, T. A. Holme 117. The construction and implementation of IMMEX problems in organic chemistry. J. Picione, K. Murphy, T. Holme 118. REEL project at Wright State University. S. K. Lunsford, N. L. Speelman 119. Research exposure for undergraduates: Projects in the general chemistry and organic chemistry laboratories. L. A. Scheich, J. S. Russel 120. The impact of GK-12 participation on career choices of chemistry undergradu ate, graduate, and postdoctoral students at UCLA. A. A. Russell, S. Gilboa 121. The application of female design style on chemistry e-learning course in Taiwan. Z. Own 122. Enhancing the Science Resource Cen ter. P. lies, R. Valcarce, L. Giddings, S. Lennberg, J. Brewer, P. Murphy 123. Consensus policy statement on crystal lography education and training. C. L. K. Stevens, K. A. Kantardjieff 124. Cyber-enabled access for high school classrooms into national user facilities: Enhancing education and research in environmental chemistry. M. I. Beg, P. Northrup, S. Branson, K. White, J. Clodius, A. Adler, J. Kaczmarek, R. J. Reeder 125. Experiences from the Merck/AAAS undergraduate science research program award. M. C. Koether, J. L. Powers, H. Sutton, D. Vogelien 126. Girls raised in Tennessee science (GRITS): Planning and preparing the future STEM workforce. J. M. Iriarte-Gross, K. Claud 127. PR2EPS: Preparation, recruitment, retention and excellence in the physical sciences. J. C. Schaumloffel, H. Gallagher, P. Bischoff, S. Labroo, N. Bachman 128. Laboratory modernization initiative at Seton Hill University. S. M. Yochum 129. Chemistry of Percy Lavon Julian. J. A. Hansen, S. S. Rund, A. J. Huhn 130. Programs supporting the advancement of chemistry education. D. R. Eiler, B. J. Scheen 131. Big Red's summer chemistry camp: A summer camp for 5th and 6th grade students. L. L. Pesterfield, A. L. McDaniel 132. GCSU's chemistry construction: 'Your Home—It's All Built on Chemistry". D. Nguyen, J. Owens, L. Peaden, C. Rowell, R. A. Richards, C. H. Lisse 133. Unique educational opportunities in the chemical sciences with Thailand universi ties. G. D. Christian, K. Grudpan 134. Women in Chemistry Alliance. L M. Peaden, C. Rowell, C. H. Lisse, R. A. Richards 135. Evaluation of the "What's Green About Biodiesel?" middle school curricular unit. A. N. French, J. Heppert, C. Bode 136. Promoting conceptual understanding through inquiry-based instruction. A. L. Kern, M. Sande, G. Roehrig 137. Inquiry-based lesson plans: A workshop for middle-school science teachers. W. J. Donovan, K. Calvo, S. Horvath, D. Turner, D. Williams 138. Good, bad, and ugly: Implementing inquiry-based experiments into a nonscience majors chemistry laboratory course. D. K. Howell 139. Inquiry-based teaching: Lessons learned in the laboratory. T. Ewald, W. R. Winchester 140. Inquiry-based learning in the organic chemistry laboratory. A. M. Schoffstall, B. A. Gaddis 141. Sowing the seeds of inquiry: Engaging students in interdisciplinary projects in science and mathematics. L. M. O'Brien, C. Boyd, B. Brown, W. Lammela 142. An early insight into an academic career. Y. Marcano, A. Fraiman 143. Use of retired high school faculty in the college science education curriculum. S. L. McCarthy, R. Koziarski
144. Help! My dog has been dognapped: A fun CSI laboratory for elementary and middle school students. B. A. Hernandez-Sanchez, S. H. King, C. M. Baros, T. J. Boyle, W. H. Hammetter 145. Chemistry of Crime Scene Investigation: A laboratory-intensive course for nonscience majors. R. W. Corbin, B. K. Mohney 146. Whose science is it anyway? Models of science according to chemistry students, faculty, and teachers. L. M. Kennedy, E. J. Yezierski, D. G. Herrington 147. Biochemistry for liberal arts: A personal learning experience. B. Biidy 148. Chemistry of beer and brewing: A labo ratory-based course for non-science majors. P. A. Brletic 149. A freshman course linking biomimetic engineering and biodiversity. G. P. Halada 150. Learning in an organic research group: Nested mentoring in a cognitive appren ticeship setting. R. E. Robinson, J. Bond-Robinson, A. Stucky-Preece 151. Molecular Architecture: A writing-inten sive, non-majors' course focusing on molecular structure and spectroscopy. P. S. Corbin 152. Teaching organic synthesis: A compara tive case study approach. D. A. Vosburg 153. Modeling an SN2 reaction. P. lies, R. Valcarce, L. Giddings, J. A. Brewer, P. Murphy, G. Russell, S. Lennberg, A. Tuckett, J. Williams, A. Harvey, M. Ahem, B. Blake, L. Truong, J. Timothy, M. Fredrickson 154. Which way did they go? Undergraduate students' problem-solving routes in organic synthesis. N. J. Barrows, R. E. Robinson, K. N. Holmes, J. Bond-Robinson 155. Rotation and visualization performance tasks in organic chemistry. P. M. Mayo, D. P. Cartrette 156. Change in structure: Understanding student attrition in a spiral organic chemis try curriculum. N. P. Grove, J. W. Hershberger, S. L. Bretz 157. Undergraduate organic laboratory: Sum mary of current practices. J. A. Moroz, K. W. Field 158. Analysis of 2-D representations of substi tuted methane: Representations from art-related fields of study. D. Hall 159. Can the stylus be mightier than the model set? Using tablet PCs to teach sophomore organic chemistry. C. E. Stilts 160. Visualizing waste: Green chemistry lecture demonstration of e-factor. I. J. Levy 161. Studies of student understandings of solution. D. J. Wink, S. A. Cunningham, S. K. Brennan, M. Bertenthal, S. R. Goldman 162. The alchemist apprentice: Using reality television as a model for teaching GC/MS. K. L. Steelman 163. Considerations for converting a freshman majors lab into a majors/honors lab. N. Flynn 164. Crossing traditional boundaries with an integrated laboratory curriculum. M. J. Schroeder, D. K. Dillner, R. F. Ferrante, J. P. Fitzgerald, W. B. Heuer 165. Patterns in safety programs: Vertical integration and blame game. S. D. Wiediger 166. Strategies for teaching blind students chemistry in a mainstreamed classroom. C. Supalo, D. L A. Rankel 167. Data-driven exercises for chemistry: A new digital collection. W. T. Grubbs 168. Writing as a tool for teaching and learn ing organic chemistry. W. G. Hollis Jr. 169. Development of a rubric for grading essay exam questions in chemistry. H. M. Sklenicka 170. Do high school chemistry students write effective laboratory reports? N. D. Rovira-Figueroa, M. B. Nakhleh 171. Implementing a web-based math tutorial in general chemistry. M. D. Barker, B. A. Barker, J. Heppert 172. Effects of feedback with Online Webbased Learning (OWL) in first semester general chemistry. T. L. Sarvela, V. M. Williamson, R. D. Macfarlane 173. Will large lecture halls "click" in a new science building? G. Wulfsberg
174. Ethics scenarios in the senior seminar. J. M. Purser 175. Chemistry for the community: Lead levels in the city. S. A. Schlipp 176. Investigation of the relationship between student chemistry-related attitudes and other non-cognitive variables with student studying practices. H. C. Robus, L. L. Jones 177. Linked cohort courses: Making academic connections between general chemistry and political science. A. B. Moore 178. Mapping the dimensions of the under graduate chemistry laboratory: Faculty perspectives on curriculum, pedagogy, and assessment. M. Towns, M. E. Fay, S. L. Bretz 179. Reflective learners and student achieve ment. B. P. Tsai 180. Discovering periodicity with a conductiv ity activity. J. C. Easdon, K. E. Garrison 181. Preparation and enzymatic hydrolysis of a library of esters. T. L. Smith, E. M. Sanford 182. Bomb calorimetry of common candy bars: An undergraduate physical chemistry laboratory at Franklin College. L Ward, S. McCoy 183. Carbon dioxide absorbers: An engaging context for stoichiometry in the general chemistry laboratory. T. M. Ticich 184. Integrating spectroscopy, liquid chroma tography and biochemistry in the instru mental analysis laboratory curriculum. M. Koppang, B. Lamprecht, P. Sees, D. Mormann, J. Polreis 185. Integration of NMR spectroscopy throughout the undergraduate chemistry curriculum. D. F. Nogales, D. T. Anstine, J. D. Harris, J. Chase 186. Revisiting the Evelyn effect. J. Currie, M. Fiedler, R. Anderson 187. Ruthenium indenylidene complexes for olefin metathesis: Microscale experiments for the undergraduate inorganic/organometallic laboratories. T. M. Pappenfus, D. L Hermanson, D. P. Ekerholm, S. L. Lilliquist, M. L Mekoli 188. Desktop experiments for a transition metal chemistry course. L. M. Dillenback, K. Cederquist, D. A. Fleming, C. D. Keating 189.1 swear they are not that boring: The rare earth elements and the modern inorganic course. B. L. Westcott 190. Electrochromic prussian blue: Application in display devices. D. Keefer, G. Lisensky 191. Using student laboratory data to discover substitution and elimination mechanisms. F. J. Creegan 192. General strategy for constructing chiral molecules of tetrahedral (T), octahedral (O) or icosahedral (I) symmetry: Solutions for an open problem in stereochemistry. Y-Y. Luk, S. K. Narasimhan, X. Lu, P. Sejwal 193. Materials chemistry projects in the descriptive inorganic chemistry laboratory. K. S. Brewer 194. Nanotechnology in the inorganic chemis try laboratory: Synthesis of inverse opal photonic crystals. L. N. Hamilton, E. J. Voss 195. Design-based development of a bio chemistry laboratory exercise for under graduates. B. Campanaro, S. R. Lefler, J. Bond-Robinson 196. Introducing physical analytical chemistry across the curriculum using fluorescence instrumentation and the case study approach: Nut poisoning (or too much of a good thing); fluorescence determination of Se in Brazil nuts. P. M. Schaber, L. A. Shepherd, H. A. Pines, J. E. Larkin, E. E. Wierchowski 197. Teaching color theory with reflectance curves. M. J. Welsh 198. Neat NMR spectroscopy for large under graduate laboratories. D. E. Alonso, P. A. Wong
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-19
CHED
TECHNICAL PROGRAM
199. Relative reactivity of alkenes and alkynes toward bromination: A project-based first semester organic lab. F. M. Rossi 200. Light in the chemistry laboratory. E. D. Sprague 201. Testing the Boltzmann distribution. R. W. Kugel 202. Isomerization of menthone: An NMR study. D. E. Alonso 203. New bioorganic laboratory experiments: Vancomycin-binding tripeptides and proline-catalyzed asymmetric oxidations. H. L. Fitzmaurice, D. A. Vosburg 204. Semi-quantitative powder X-ray diffrac tion in an instrumental analysis laboratory. I. R. Corn, M. Shabangi, E. J. Voss 205. Decarboxylation of N-carboxy-2-imidazolidone: An organo-physical chemistry experience for the undergraduate labora tory. R. E. Rivera-Hainaj 206. Aldol addition and condensation reac tions: The effect of conditions on reaction pathway. R. D. Crouch, A. M. Richardson, J. L Howard, R. L. Harker, Κ. Η. Barker 207. Effect of tartrazine on Cytochrome P450 isoenzymes present in CHO cells. C. Lugo-Esclavon, L Santos 208. Synthesis of silver and copper nanoparticles. S. Solomon, M. Bahadory 209. Reaction of single-walled carbon nanotubes with singlet oxygen. M. A. Hamon, M. A. Sugar, K. C. Tumminello 210. Adaptation of phase vanishing bromina tion of alkenes and alkynes to undergradu ate organic chemistry laboratory. V. Dragojlovic 211. Raman spectroscopic characterization of gem stones. L M. Pasquini, C. Y. Jones, D. G. Bailey, T. E. Elgren 212. Simple method to generate a theoretical titration curve on a spreadsheet. H. Mukai 1340. Integrating technology in the laboratory: Medicinal chemistry 409. F. M. Burke, K. L. Damm, M. H. Waldman, K. Ghirtis, R. W. Woodard, M. A. Beleh MONDAY MORNING
McCormick Place North Room N230A, Level 2 ACS Award for Achievement in Research for the Teaching and Learning of Chemistry: Symposium in Honor of J. Dudley Herron C. R. W a r d , J. H. Reeves,
Organizer Presiding
8:30 222. Introductory remarks and estab lishing the context. C. R. Ward 8:35 223. Dudley Herron: A case of phytog eny recapitulating ontogeny. G. M. Bodner 8:55 224. Reflections on J. Dudley Herron's contributions to research in chemical education. D. L. Gabel 9:15 Intermission. 9:25 225. J. Dudley Herron: Change agent. S. C. Nurrenbern 9:45 226. Standing on the shoulders of a giant: J. Dudley Herron, Jean Piaget, and beyond. S. L. Bretz 10:05 227. Making the world better: J. Dud ley Herron and pre-college chemistry education. D. V. Frank 10:25 Intermission. 10:35 228. What is learned from laboratory activities. M. R. Abraham 10:55 229. Using clinical interviews to probe students' understanding of chemistry and problem-solving skills. T. J. Greenbowe 11:15 230. Award Address (ACS Award for Achievement in Research for the Teaching and Learning of Chemistry, sponsored by Prentice-Hall Publications). Philosophical ramblings of a has-been or advice to my intellectual grandchildren. J. D. Herron Section C McCormick Place North Room N230B, Level 2 Impending Issues in Chemistry Teacher Education
Section A McCormick Place North Room N227A, Level 2
W . J . F. Hunter, Organizer,
Research in Chemical Education Cognition and Prediction Research W. J. F. Hunter,
Section Β
Organizer
D. Mulford, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 213. Reflections on conceptual change: Views from counseling psychology and organic chemistry. G. Bhattacharyya 8:55 214. Students' categorizations of organic compounds. D. S. Domin 9:15 215. Impact of metacognitive instruction on chemistry problem solving skills. S. Sandi-Urena, M. M. Cooper 9:35 Intermission. 9:45 216. Using cognitive load theory to examine word problem complexity. J. S. Kirk, N. J. Pienta 10:05 217. Metarepresentational compe tence of organic chemistry students. D. S. Domin 10:25 218. A study of the relationship between ability to use higher-order think ing skills and coherence in particulate-level models across contexts. K. Monteyne, G. Avila, E. Lomont 10:45 Intermission. 10:55 219. Predicting student success in general chemistry: A multivariate approach. K. A. Chambers, B. Blake 11:15 220. Analysis of a math diagnostic to help predict introductory chemistry suc cess. C. A. Morse 11:35 221. Student outcomes from a com bined math and chemistry program: Ten year data. J. H. Hwang, D. J. Wink, S. F. Gislason
Section Ε McCormick Place North Room N227B, Level 2 Nanotechnology in Undergraduate Education Nanotechnology in the Undergraduate Laboratory K. A. O. Pacheco, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 247. Active learning experience in nanotechnology: A laboratory experience to bring nanotechnology to students using PC to PC access. E. Ferrer, M. Gonzalez, M. Leon, M. E. Castro 8:55 248. Hands-on powder X-ray diffraction in the general chemistry laboratory: Syn thesis and characterization of a nanocrystalline phosphor. E. J . Voss, M. J. Shaw 9:15 249. Benchtop nanopatteming using soft lithography. Y. Babayan, V. Meenakshi, T. W. Odom 9:35 Intermission. 9:45 250. Incorporation of STM into the undergraduate curriculum using a coadsorbed self-assembled monolayer system. E. V. Iski, M. El-Kouedi, A. E. Baber, S. C. Jensen, E. C. H. Sykes 10:05 251. Laboratory modules on environ mental impacts of nanotechnology. X. Zhang, C. Bruell, M. Hines, A. C. Watterson, C. M. Barry 10:25 252. Low-cost laboratory experiments in nanoscience. D. N. Horoszewski, W. C. Crone, K. L Gentry, S. K. H. Ng, C. Johnson, G. C. Lisensky, J. Marmon, D. Keefer, J. Horger, K. J. Nordell, R. Amankwah 10:45 Intermission. 10:55 253. NanoLab: A hands-on introduc tion to nanoscience for scientists and engineers. L. A. Bumm, M. B. Johnson 11:15 254. Synthesis of CdS nanoparticles for a freshman nanotechnology laboratory. K. Winkelmann, T. Noviello, S. Brooks 11:35 255. Synthesis, characterization, and applications of colloidal gold nanoparticles. P. H. Davis
Section D McCormick Place North Room N229, Level 2 Broadening Participation in Undergraduate Research Cosponsored with CMA, WCC, YCC, SOCED, and COMP M. K. Boyd, Organizer,
Presiding
8:30 Introductory Remarks.
20-TECH
Presiding
8:30 Introductory Remarks. 8:35 231. Incorporating chemistry in the community in a comprehensive curriculum and teacher professional development program. D. J. Wink, S. K. Brennan, S. A. Cunningham, P. L. Daubenmire, S. A. Shippy, R. J. Kassner 8:55 ' 232. Target inquiry: The importance of an authentic science inquiry experience in creating an inquiry-based high school science program. D. G. Herrington, E. J. Yezierski 9:15 233. Effects performing authentic research has on secondary science teach ers' classroom practices. J. D. Weld, D. I. Del Carlo, J. Ophus, A. VanWaardhuizen 9:35 Intermission. 9:45 234. Which comes first, the standards or the curriculum? J. S. Carver 10:05 235. Impact of standards-based grad ing. M. J. Robertson, D. Douthit 10:25 236. Chemistry for elementary teach ers. N. J. Gardner 10:45 Intermission. 10:55 237. Instructional support CD and collaborative website. J. S. Christopherson 11:15 238. Chemistry content transfer from professional development to the K-8 classroom: Teachers' motivations and adaptations. A. Gay 11:35 239. The chemistry module in Texas: No Child Left Behind. B. Blake
8:35 240. Broadening participation in chem istry through undergraduate research at a minority-serving community college. Τ. Β. Higgins 8:55 241. The 2YC-4YC research pipeline: A success story. D. J. Stanford, J. G. Gillmore, C. L. Bodden 9:15 242. Research Internships in Science of the Environment (RISE). R. Hannigan 9:35 Intermission. 9:45 243. Practical strategies for broadening participation: "How". G. Thomas, Z. Wilson 10:0ό 244. Strength in numbers: Broadening participation of underrepresented minori ties in chemistry. L. E. Martinez 10:25 245. Academic success through LSAMP and PUI participation. J. D. Evanseck, E. S. Gawalt, J. D. Madura 10:45 Intermission. 10:55 246. A key element of the HHMI undergraduate program: Broadening access to science for students. P. Soochan 11:15 Panel Discussion.
Please refrain from using cellular telephones and cameras during technical sessions.
Section F McCormick Place North RoomN231, Level 2 Process-Oriented Guided Inquiry Learning (POGIL) Assessing POGIL Implementations A. Silva,
Organizer
R. S. Moog, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 256. Why do students remain first time learners in a general chemistry course? R. S. Lamba 8:55 257. Impact of the Science Writing Heuristic on subsequent laboratory courses. S. J. Gravelle 9:15 258. Using POGIL and Odyssey to encourage student visualization in chemis try. R. S. Cole, K. J. Linenberger, E. M. Maison, B. L. Zernicke 9:35 Intermission. 9:45 259. Developing a plan to evaluate student achievement in POGIL general chemistry. D. M. Bunce 10:05 260. Immediate feedback multiple choice testing format in large lecture POGIL classrooms. J. L. Schneider 10:25 261. Does small group work change students' attitudes and confidence? A. B. Mahoney 10:45 Intermission. 10:55 262. POGIL in college prep chem: A systematic approach to POGIL lesson implementation. J. Picione, K. Murphy, T. A. Holme 11:15 Panel Discussion. Section G Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Analytical Chemistry Cosponsored with SOCED, and ANYL A. T. Bennett,
Organizer
J . L. W e s e m a n n , Organizer,
Presiding
11:00-1:00 263. Dictyostelium discoideum: A platform for the screening of intracellular nanosensor performance. K. M. Rank, M. G. Brasuel 264. A comparison of volatile organic com pounds in new homes, older homes and their outside environment. A. Newman 265. Analysis of commercial products and standards by Direct Analysis-Real Time (DART) time of flight mass spectrometry. J. K. P. Williams, B. L. Vaandering, L. Schumacher, J. A. Clark, J. N. Leibowitz 266. Analysis of common black tea theaflavins using normal-phase high performance liquid chromatography. J. D. Freeman, E. D. Niemeyer 267. Analysis of maned wolf (Chrysocyon brachyurus) urine headspace via auto mated solid phase dynamic extraction (SPDE)/GC-MS: The first report of sulfurcontaining compounds therein. M. E. Weddell, C. J. Chen, S. R. Jackson, T. E. Goodwin, N. Songsasen, J. P. Helsper 268. Analysis of nickel electrodes for residual capacity. C. A. DeFusco, R. Whiteley Jr. 269. Analysis of purity of common solvents using quantitative NMR. P. T. Bell, A. D. Adkins, L D. Schultz 270. Analysis of volatile compounds of diag nostic interest using a microdialysis probe extraction technique. A. M. Kramer, A. Borgerding 271. Analytical method for determination of arsenic in chicken. M. E. Blessinger, B. Hopkins 272. Antioxidant activity in herbal extracts and isolated fractions. M. A. Deibel, J. Colanese, C. Nakata 273. Withdrawn. 274. Antioxidant activity of capsaicinoids in six hot pepper varieties. L. Schuster, J. K. Vohs
CHED 275. Application of an MAE- SPME- GC/MS methodology for identification of fatty acid ethyl ester in sebum as markers of alcohol consumption. G. Ojeda-Torres, F. Gonzalez Ulan, L. Diaz, O. Rosario 276. Bacterial inhibition with liposoluble extracts of red and pardas algae. A. Y. Gonzalez, M. Garcia, G. Peha 277. Binding of novel water-soluble perylene diimides to oppositely charged polyelectrolytes. A. A. Twite, T. A. Everett, D. A. Higgins 278. C-Terminal histidine loss from orcokinin family neuropeptides: Implications for the identification of truncated neuropeptide variants by MALDI-FTMS. C. R. Cashman, P. S. Dickinson, A. E. Christie, E. A. Stemmler 279. Catecholate siderophore complexation on metal oxide surfaces. W. L. Schmidt, H. A. Bullen 280. Characterization of copal incense from Mesoamerica: Identification of residues by GC-MS. J. Van Gemert, R. A. Armitage 281. Chemical warfare agent simulant diisopropylfluoro phosphate (DFP) decontami nation reactions in ionic liquid solvent dimethylpropyl imidazolium bis(trifluoromethyl)sulfonyl imide (DMPITf2N). S-J. L. Adams, P. J. Castle, J. A. Levisky, A. Hermosillo, J. S. Wilkes 282. Chiral platinum (II) extended linear-chain materials: Search for an enantiomeric sensor (Part I). S. M. Drew, Y. Takeshita, I. M. Hill, A. J. Young, A. D. Lackner, C. E. Buss, J. R. Burney, K. R. Mann 283. Chiral platinum (II) extended linear-chain materials: Search for an enantiomeric sensor (Part II). S. M. Drew, I. M. Hill, Y. Takeshita, A. J. Young, A. D. Lackner, C. E. Buss, J. R. Burney, K. R. Mann 284. Colorful chemistry: The spectroscopic analysis of autumn leaves. K. S. Donaldson, S. M. Yochum 285. Comparison of film formation methods using amine-terminated alkyltrialkoxysilane precursors. W. E. Gilson, J. D. Acton, J. W. Cline, G. G. McPherson, A. F. Farmer, A. C. Friedli 286. Constraining the age of the Grizzly Creek Shear Zone, Glenwood Canyon, Colorado. M. L. Mekoli, R. E. Goodfellow 287. Detection of total sulfur and nitrogen compounds in industrial samples and foods. D. J. N. Driscoll, D. R. A. Kipp, D. D. I. Lewis, J. Hamm III, A. Marchetti, N. Liakis 288. Detection of transfer RNAs (tRNAs) by their signature digestion products. C. Cherenfant, M. Hossain, P. Limbach 289. Determination of a method for analysis of p-arsanlic acid. R. N. Kepler 290. Determination of As and Hg using anodic stripping voltammetry with gold film elec trodes. C. Kousok, J. T. Long 291. Determination of osmotic second virial coefficient for acid phosphatase A by self-interaction chromatography. C. K. Strickland, Κ. Ε. Garrison 292. Withdrawn. 293. Determination of the origin of central Texas chardonnay wines using GC-MS. R. Walker, H. Altmiller 294. Development and optimization of a rotating disk enzyme electrode for xan thine. C. Prajapati, N. J. Ronkainen-Matsuno 295. Development of a detection method for fluoroquinolone antibiotics using flow injection analysis with electrochemiluminescent detection. H. Wang, M. Burkhead, E. Gross 296. Development of a fluoroscence titration method to measure the association con stants of small molecule fluorophores with cyclodextrins and fluorophore specific antibodies. J. R. Meyers 297. Development of algorithms to elucidate spectrophotometric titration curves. I. P. Zubkov, J. A. Lynch 298. Development of an entangled polymer solution for improved resolution in DNA analysis using a portable microfluidic instrument. O. G. Cabrices, K. Opel, B. R. McCord 299. Direct sampling mass spectrometry of water in biodiesel. M. S. Todd, T. Peters, D. J. LeCaptain 300. Dissociation constant (pK2) of the buffer CHES from 5 to 55°C. H. M. Hughes, A. Bwashi, N. W. Grove, S. R. LeNoue, B. T. Morris, L. N. Roy, R. N. Roy
301. Dynamic quenching of fluorescence spectra: The kinetics of solution deoxygenation by purging with an inert gas. K. Edenzon, T. Pagano 302. Effects of alkyl side chains on the hydro gen/deuterium exchange kinetics of tripeptides in the gas phase. J. M. Jankolovits, E. M. Marzluff 303. Effects of radiation and cultivar on soy foods. A. L McMillan 304. Efficiency of ionic exchange metathesis in the synthesis of hydrophobic ionic liquids. N. D. Burrows, M. A. Brooks Jr., D. D. W. Blackburn 305. Electrochemical detection of hydrazine using flow injection analysis. K. L. Brown, S. B. Gray 306. Electrosynthesis of surface-bound hydroxylamine linkers for antibody immobi lization. B. M. Prentice, M. C. Rhoten, D. A. Williams, S. M. Ruder, C. D. Crawley 307. Elemental analysis of single-walled carbon nanotubes for cytotoxicity studies. E. K. Walker, M. Daigrepont, R. Azad, P. Pantano 308. Energy dispersive X-ray analysis of a series of Japanese coins of the early nineteenth century. H. Attar, J. Shango, M. A. Benvenuto 309. Ewww . . . gross! What's on your shirt? S. Bacon, R. Miller, L. Buttitta, H. Haramut, A. Huff, D. Nguyen, C. H. Lisse 310. Exploring the BZ reaction. N. Coleman Jr., C. W. Blackledge, M. C. Sostarecz 311. Exploring the interactions between chiral molecules and molecular micelles with NMR spectroscopy. S. A. Kingsbury, K. F. Morris 312. Extraction of cesium from alkaline media utilizing functionalized calix[4]arene-benzocrown ethers. J. L. Smith, J. D. Partridge, D. D. Ensor 313. Extraction of lactic acid from aqueous solution using ionic liquids with trialkylamine and tetraalkylammonium salt based extradants. A. E. Wirtz, P. M. Smith 314. Forensic lipstick analysis using chemical fingerprinting via gas chromatography. A. Engebretson, D. M. Besemann 315. From eye lens crystalline to polylactide star polymers: Multidisciplinary applications of MALDI-TOF mass spectrometry. C. J. Prince, D. L Wagner, R. W. Corbin 316. GC-MS for quantitative analysis of lipids in a coating associated with rock paintings in Little Lost River Cave, Idaho. G. Maxwell, R. A. Armitage 317. GC/MS/MS analysis of atrazine and three metabolites using chemical ionization and multiple reaction monitoring. A. W. Graham, R. E. Stacy, C. C. Deibel 318. Gold nanoparticles as matrices for the MALDI-TOF MS detection of small mol ecules. M. W. Bourassa, P. H. Davis 319. Health hazard or forensic tool? Trihalomethane formation in public drinking water supplies. M. B. McNamara, J. Van Doren, J. Bonofiglio 320. H PLC separation of derivatized {alpha}dicarbonyl compounds: Preliminary stud ies. L. P. Marruffo, J. A. Palasota 321. Identification and isolation of primary fatty acid amides from mammalian tissue. A. C. Bishop, M. E. Johnson, T. Sultana, G. Dent 322. Impact of pyoverdin siderophores extracted from Pseudomonas aeruginosa on bacterial adhesion to metal oxide surfaces. S. M. Proctor, H. A. Barton, H. A. Bullen 323. Withdrawn. 324. Implementation of a new extraction cooler for analysis of volatiles in African elephant urine headspace (and other samples) via automated SPDE/GC-MS: A search for pheromones. S. R. Jackson, T. E. Goodwin, M. E. Weddell, C. J. Chen, I. Christ, K. Chokshi, B. A. Schulte 325. Improved electrochemical biosensor response via metal oxide pre-oxidation of chemical interférants. M. Tapsak, J. G. Houseknecht 326. Improved ultraviolet spectroscopic measurement of rocket motor efficiency. M. W. Teague, J. E. Haley 327. Investigating the absolute charge of transition metal substituted heteropoly tungstates. B. T. Tyler, T. J. Dobmeier, S. H. Szczepankiewicz
328. Investigation of heavy metal ion content in imported green tea using inductivelycoupled plasma-optical emission spectroscopy (ICP-OES). J. F. Curran, D. Y. Mei-Ratliff 329. Investigation of pesticide contamination in imported green tea using gas chromatography-mass spectrometry (GC-MS). E. J. Retter, D. Y. Mei-Ratliff 330. Investigation of the electrochemiluminescent reaction of fluoroquinolone antibiotics withtris(2,2'-bipyridyl)ruthenium(ll). M. Burkhead, H. Wang, E. Gross 331. Investigation of the separation properties of covalently linked vancomycin dimers vs. native vancomycin. T. J. Ward, B. A. Baker, A. C. Gilmore, C. L. Vowell, M. D. Oglesbee 332. Investigation of trace elements in pottery at Adequentaga. E. R. Wojcik, S. M. Young, J. B. Dudek 333. Jet fuel characterization on the battlefield: Method development. J. L Kulevich, J. M. Van Doren, E. J. Soares, R. E. Morris, K. J. Johnson 334. Kinetic investigation of the reaction of a fluorescent label and fatty acids. K. A. Wilson, J. T. Williams, M. E. Johnson 335. Kinetics of trihalomethane formation in public drinking water. J. Van Doren 336. Kinetics of trioctylmethylammonium methyl carbonate. K. Becvar, C. Fry, G. W. Earl, D. E. Weisshaar 337. Langmuir monolayers for the investigation of the interaction of antibacterial molecules with the bacterial membrane in cystic fibrosis airway environment. P. A. Rogers, R. Bucki, P. B. Savage, P. A. Janmey, A. G. Sostarecz 338. Levels of heavy metals concentration in aquatic plants and surface water from the Cano Tiburones wetland. S. J. Cardona, Y. Vega, R. A. Lopez, D. E. Gonzalez, M. Ramos 339. Lipid domains: Existence in the inner leaflet of the plasma membrane? L. Ditzler, K. King, A. G. Sostarecz 340. Lipid monolayers provide insight into lipid-drug interactions in Isotretinoin loaded unilamellar liposomes. A. Magnelli, K. R. Watson, C. P. I. Alves, Ε. Μ. Lima, A. G. Sostarecz 341. Low cost flame emission demonstration apparatus. R. Warren, D. E. McCall, K. C. McGill 342. Mass spectrometric determination of glycation sites in hemoglobins. B. M. Clifford-Nunn, S. Hess 343. Measurement of 1 4 C content in Mexico City atmospheric aerosol. A. C. MacMillan, K. L Steelman, N. A. Marley, J. S. Gaffney, T. P. Guilderson 344. Metal content in printer cartridges. C. J. Boyd III, G. L. Seebach 345. Method development and microfluidic device design for separation and detection of modified nucleosides. C. Sweeney, D. Morris 346. Monitoring conformational rearrange ments in Bacillus anthracis protective antigen using FRET microscopy. S. Madera, K. A. Christensen, T. P. Caldwell 347. Nonlinear fitting to TLC fluorescence data: Quantitative analysis of vitamin Ε components in commercial supplements. X. Jiang, P. J. Ogren 348. pH For the physiological buffer standard AMPSO from 5 to 55°C in an isotonic saline solution. C. E. Denton, S. R. LeNoue, K. Majumder, J. T. Wollen, K. V. Smith, L N. Roy, R. N. Roy 349. Photochemical transformations of 1-Nitropyrene adsorbed on silica gel. O. M. Colon, Z. Garcia, Y. Martinez, R. Arce 350. Photochemistry of sunscreen compo nents in polar and non-polar solvents. C. Watkins, C. Cantrell, K. LaiHing 351. Plasma oxidation and AMS radiocarbon dating for the Chauvet cave multi-labora tory intercomparison. J. DuPriest, K. L. Steelman, M. W. Rowe, T. P. Guilderson, H. Valladas 352. Preparation and characterization of gold-film microelectrodes. R. K. Castleberry, C. Brennan
353. Probing the interactions between enkephalin peptides and beta-cyclodextrin with NMR spectroscopy. A. L. Wingert, K. F. Morris 354. Product analysis of photocatalysis with transition metal substituted heteropoly tungstates in nonpolar solvents. T. J. Dobmeier, Β. Τ. Tyler, S. H. Szczepankiewicz 355. Qualitative determination of fluorescent dyes present in commercial lightsticks. A. E. Comfort, T. S. Kuntzleman 356. Quantification of zinc in metallothionein standards using high pressure size exclu sion chromatography with inductively coupled plasma mass spectrometric detec tion. M. Ly, S. Balram, T. Palermo, D. Cleveland, R. G. Michel 357. Quantitation of gamma-hydroxybutyric acid (GHB) in cellular extracts using gas chromatography/mass spectrometry. E. A. Scott, A. C. Dema, L. A. Wetmore 358. Quantitation of total phenol antioxidants in commercial milk chocolate and dark chocolate. M. J. Motisi, J. A. Vinson 359. Quantitative determination of polyphenol content in whole grain foods. J. Z. Marchegiani, J. A. Vinson 360. Restriction enzyme inhibition to detect sites of DNA-protein cross-linking on DNA. T. Maisonet, C. Ochoa, J. Zelaya, E. D. Stemp 361. Role of metal ion binding in generating 8-hydroxy-2'-deoxyguanosine from the nucleoside 2'-deoxyguanosine and the nucleotide 2'-deoxyguanosine-5'-monophosphate. S. D. Noblitt, A. M. Huehls, D. L. Morris Jr. 362. Size optimization of estragon imprinted polymers in non-fluorinated solvents. B. L. Custer, M. G. Brasuel 363. Spectrophotometric analysis of thiocyanate in saliva and its correlation to tobacco smoking. B. Wahl, D. Gildon, S. M. Diab 364. SPME-GC/MS analysis of fluorotelomer alcohols in environmental matrices. E. C. Panzer, M. M. Schultz 365. Standard buffer solutions of BICINE from 5 to 55°C. E. L. Wunderlich, S. L. Cowherd, S. R. LeNoue, C. H. Grove, M. I. Myers, L N. Roy, R. N. Roy 366. Structural study of FHA domain from guanylate kinase-associated kinesin. C. A. White, Y. Xue, J. Xu, Y. Ryobov, N. Skrynnikov 367. Study of self-assembled monolayers of 4-aminothiolphenol over gold electrodes. A. M. Rios-Pagân, L. Santiago-Rodriguez, C. R. Cabrera 368. Study of TRICINE buffer compound for pH measurements. J. C. Carr, A. S. Foster, S. J. DeArmon, A. Z. Wei, S. Ashkenazi, L. N. Roy, R. N. Roy 369. Studying decontamination reactions with the chemical warfare agent simulant Bis(2-ethylhexyl) phosphate (BIS) in the ionic liquid solvent dimethylpropyl imidazolium bis(trifluoromethyl)sulfonyl imide (DMPITÎ2N). K. A. Sanders, P. J. Castle, J. A. Levisky, A. Hermosillo, J. S. Wilkes 370. Suitability of silica aerogels as platforms for sensors based on phosphorescent probes. J. B. Reichbind, S. W. Bartok, M. K. Passarelli, M. K. Carroll, Α. Μ. Anderson 371. Supercritical fluid chromatography with long packed capillary columns. D. B. O'Brien, D. P. Poe 372. Surface modification of stainless steel medical implants for biofouling prevention. R. A. Wilson, H. A. Bullen 373. The determination of antioxidant and caffeine concentrations in tea: Comparison of HPLC and spectral methods. A. J. Obregon, J. Brown, M. Montoya, B. G. McBurnett
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
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CHED 374. The development of biopolymer coated iron nanoparticles for As(lll) chelation. B. T. Stackhouse, B. R. White, J. A. Holcombe 375. THM-GC-MS analysis of possible bind ers in rock paintings: Comparisons to authentic pictographs and the effect of pretreatment. M. Doolin, R. A. Armitage 376. THM-GC-MS analysis of rock paintings from Casa de Las Golondrinas, Guate mala: Implications for radiocarbon dating. A. Livingston, R. A. Armitage 377. Ultrathin polymer films as fluorescent sensors. K. M. Wentz, C. J. Bardeen 378. Use of a QCM to monitor the interaction of multinuclear platinum complexes to biologically relevant molecules. C. M. Shuford, M. C. Rhoten, J. B. Mangrum, N. P. Farrell 379. Use of automated SPDE/GC-MS, novel macros, and pattern recognition tech niques in a search for African elephant urinary pheromones. T. E. Goodwin, C. J. Chen, M. E. Weddell, S. R. Jackson, C. Drea, B. A. Schulte 380. Variance in capsaicin concentrations of jalapeno peppers. A. Gaydess, J. Stowell, P. Steinbach 381. Voltammetric study of methionine oxida tion in alpha synuclein oligomerization. N. A. Hodges, T. Boyd, L. S. Moses, S.Han 382. Electrochemical immunoassay detection of Cryptosporidium parvum in water. J. C. Gertsch, Z. P. Aguilar, I. Fritsch 383. Endocrine disruption in carp from Lake Erie: Analysis of PCBs, PBDEs and vitello genin. S. L. Morgan, F. Samara, A. Perez-Fuentetaja, M. Clapsadl, D. Aga 384. Exploration of a capillary electrophoresis method combining vacancy separations and sample stacking techniques. M. Sorrell, S. D. Gilman 385. Synthesis and evaluation of new cathepsin Β inhibitors containing argininal-thiosemicarbazones. D. Driver, P. Velusamy, C. J. Trana, K. L. Sayyar, W. E. Godwin, R. M. McConnell Section Η Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Chemical Education Cosponsored with SOCED A. T. Bennett and J. L. W e s e m a n n , Organizers
11:00-1:00 386. A website to complement the laboratory component of the chemistry for health sciences course at Ball State University. M. G. Olds, S. Prescia, T. Bramel, J. W. Ribblett 387. ACS examination studies: Investigation of the conceptual retention of general chemistry topics at Lee University. M. K. Krepps, B. Ferrell 388. Analysis of cucumber plants for use as phytoremediators: An instrumental analysis project. L. D. Riddle, R. E. Farmer, C. M. Shuford, J. M. Joyce, S. L. Hensler, M. R. Edwards, B. M. Prentice, J. A. Mann, M. E. Lehman, M. C. Rhoten 389. Analysis of multivitamin tablets for their mineral content by flame atomic absorp tion spectrophotometry: A quality control experiment. R. E. Deimler, R. Fietkau 390. Casting away the cookbook: Bringing independent experimental design into an organic chemistry laboratory experiment. P. A. Bonvallet, J. C. Amburgey-Peters 391. Computer controlled data collection in the first year general chemistry laboratory. F. M. Hocutt, G. W. Daub, H. Van Ryswyk 392. Dehydration of alcohols using acidic resin catalysis. K. W. Field, J. R. Ludeman 393. Determination of sulfate in pond water. R. Alexandre, K. Sebekos, M. Exposito 394. Determination of sulfide in seawater. N. Salazar, M. Amicarelli, M. Galvez, M. Exposito 395. Development of a powder X-ray diffrac tion laboratory module for the use in honors General Chemistry: Identification of unknown household solids using powder X-ray diffraction. M. L. Gahan, J. Blair, P. Wildfong, J. A. Aitken
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TEC Η ΝIC AL Ρ R OG RAM 396. Development of an interactive spectral problem set for increased understanding of various spectroscopic techniques. D. G. New, A. R. Stephens 397. Development of diffusion NMR physical chemistry experiment. J. G. Longenecker, P. D. Schettler Jr., T.L.Fisher 398. Inquiry-based biochemistry labs in pro tein structure-function of cytochrome b5 at Eastern Michigan University. M. M. McPhail, C. A. Oswald, S. J. Pernecky, L Waskell, S. C. Im, D. Mansuy, D. Mathieu, C. Capeillere-Blandin 399. Investigating color: A guided inquiry experiment for the sophomore organic chemistry laboratory. K. L. Pate, M. B. Carper 400. Invisible ink revealed: Chemistry and secret writing. E. K. Bell, R. D. Sweeder 401. Microwave-assisted reaction series for use in organic teaching laboratories: Application to the formation and Diels- • Alder cycloaddition of tetraphenylcyclopentadienone. S. G. Ballmer, D. M. Ketcha 402. Modeling solid structures with 2-D paper cutouts. K. F. Robinson, P. N. Nguyen, N. D. Applegren, D. J. Campbell 403. Nucleophilic substitution reactions: A guided inquiry experiment. K. L. Pate, K. E. Ryder, K. B. Kephart 404. On-line interactive problems to enhance the domain of General Chemistry concepts of stoichiometry and molecular geometry. C. M. Torres, K. M. Matos, M. A. Fuentes, K. Banhard 405. PocketPC molecular modeling for organic chemistry laboratories. B. Graham, B. Hobbs, M. B. McGinnis 406. Putting it all together: Applying advanced chemical concepts to the culinary world. L. A. Fraser, K. Symcox 407. Rapid chemometric method for analyzing simulated street drug samples. K. Y. Noonan, K. Frederick 408. Surface-enhanced fluorescence. A. Pravitasari, T. Shtoyko, E. G. Matveeva, I. Gryczynski, Z. Gryczynski 409. Synthesis of a bromoether from transcinnanmic acid as a sophomore laboratory procedure. L J. Allen, B. J. Myers 410. Time-resolved fluorescence immunoas say: An experiment for instrumental analy sis. N. L. Ritzert, D. C. Zapien 411. Undergraduate laboratory in hetero geneous catalysis with a computational component. R. A. Grimminger, P. D. Schettler Jr. 412. Understanding keto/enol and enol-a/ enol-b equilibrium: A computational labora tory. J. G. Estevez, Μ. Ε. Maldonado, C. Ospina, Z. Alvarado, L. J. Cotto, Z. Cortes, Μ. Μ. Coronado, T. M. Pacheco, M. Perez, V. Ramos, S. M. Velez 413. A greener approach for esterification reactions. I. Montes, J. Escudero 414. An innovative way to introduce students to discuss ethical misconduct. I. Montes, A. Padilla, A. Maldonado, S. Negretti 415. An inquiry-based lecture approach to SN1, SN2, E1, and E2 chemistry. J. M. Teixeira, R. W. Holman 416. An integrated inquiry-guided approach laboratory experience to teach: Extraction, recrystallization and melting point determi nation. I. Montes, J. Fajardo, L. M. Pruna 417. Applying basic thermodynamics: An analytical approach to understanding Greek fire. L. D. Dye, J. D. Powell 418. Assessing the impact of an integrated physics and chemistry professional devel opment program in improving teacher performances and changing classroom practices in Texas public schools in San Antonio area. G. M. Yale, Ε. Ε. Gonzalez, A. R. Chaudhuri 419. Authentic research in general chemistry lab. K. A. Trick, H. Knachel Jr., S. M. Swavey, D. W. Johnson 420. Connecting science and literacy: Hands-on inquiry in the elementary class room. K. Nafziger, B. M. Motter, N. U. Bautista, J. Winslow, S. L. Bretz 421. Development and application of a stovetop essential oil apparatus. M. R. Miner, S. A. Martin, J. Bennett 422. Development of green chemistry class room and laboratory activities for high school students. A. E. Bentz, C. Fish
423. Development of spatial ability and atti tudes in chemistry courses. K. J. Linenberger, R. S. Cole 424. Development of the lab component for a web-based non-major college chemistry course. S. A. Henrie, A. G. Murray 425. Do student and faculty learning styles differ in the chemistry classroom? H. L. Kolzow, A. B. Mahoney 426. Does yeast matter? A beer chemistry laboratory for liberal arts students. P. A. Brletic, C. L Young, F. P. Smith, J. J. Farrell 427. Fading phenolphthalien kinetics experi ment employing a diode array based spectrometer. N. I. Ifionu, W. L. Sheppard, R. Fietkau 428. Improving experiments through trial and error. M. Exposito, B. Sewerin, L. J. Hernandez 429. Inquiry-based approach to solubility equilibria. K. L. Cacciatore, J. Amado, J. Evans, H. Sevian 430. Integrating lab techniques and Odyssey software using essential oils. D. Dickson, J. Murillo, N. Salazar, M. Exposito 431. Laboratory exercises involving photonic crystal films. K. E. Korte, D. J. Campbell 432. Laboratory simulation of an acid mine drainage system. M. R. Purcell, S. F. Wolf 433. Minority representation in chemical education: Comprehensive comparison to other scientific disciplines. A. Donaldson, C. N. Brammer, D. J. Nelson 435. NMR determination of the kinetics of deuterium exchange in 3-methyl-2-butanone. A. Knutson, G. Toledanes, T. B. Malloy Jr. 436. NMR determination of the kinetics of deuterium exchange in 3-pentanone. G. Toledanes, T. B. Malloy Jr. 437. On-line data collection and database development for survey research in chem istry education. J. Mathew, N. P. Grove, S. L. Bretz 438. Peer led team learning in organic chem istry: A workshop leader perspective. A. Johnson 439. Ring-opening polymerization of lactide to form polylactide: A laboratory for organic chemistry. J. Robert, K. B. Aubrecht 440. Separation of ethanol from fermentation broth during the production of fuel ethanol. R. A. Hill, Ο Ε. George 441. Spectroscopic investigation of an octabrominated porphyrin for application in PDT. J. Owens, R. A. Richards 442. Synthesis of 1,3-bis-(3,5-dimethyl-pyrazol-1-yl)-propane-2-thiol. F. T. Ladipo, N. L. Webb, A. Zazybin 443. Synthesis of ionic liquids in the undergrad organic chemistry laboratory. M. A. Brooks Jr., N. D. Burrows, D. D. W. Blackburn 444. Target inquiry: How does a chemistry research experience impact teachers' perceptions of science inquiry. C. Luxford, D. G. Herrington, E. J. Yezierski 445. Thermodynamic exploration of eosinlysozyme binding: A physical chemistry and biochemistry laboratory experiment. A. J. Huisman, L. R. Hartsell, B. P. Krueger, M. J. Pikaart 446. Using on-line questions database through WebCT to enhance General Chemistry student's learning process of the kinetics and equilibrium concepts. C. M. Torres, S. Negretti, A. L. Freire, K. Bamhard 447. Using the effects of antibiotics on bacte rial growth to demonstrate pharmaceutical concepts. K. M. Kahler, A. L. Miller
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Section I Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Nanotechnology Cosponsored with SOCED A. T. Bennett and J . L. W e s e m a n n , Organizers 11:00-1:00 448. Conformai copper nanolayers over cotton fibers via electroless plating. B. Hekia, H. Dong, J. P. Hinestroza 449. Design and characterization of drug delivery systems across the blood brain barrier. T. Fabre, J. D. Hogan, K. A. Walters, K. H. Martines, D. A. Tomalia, H. A. Bullen 450. Withdrawn. 451. Experimental factors influencing the growth of calcium oxalate monohydrate on coinage metal substrates. C. M. King, S. M. Wong, M. A. McFarland, L. E. Morrell, H. A. Bankowski, R. W. Gurney 452. Influence of ionic strength on brookite content in sol-gel synthesized titanium dioxide before and after hydrothermal aging. E. R. Anderson, S. L. Isley, R. L. Penn 453. Polyetherimide nanofibers: Identifying optimum electrospinning conditions by mapping the dielectric properties of the precursor solutions. E. Franzek, K. C. Mills, J. P. Hinestroza 454. Alterations of the surfaces of gold nanorods with biomolecules. J. L. Hass, S. E. Hitchcock, C. W. Blackledge 455. ATR-FTIR analysis of the interaction of biotinylated dendrimers with blood brain barrier models. J. D. Hogan, T. Fabre, K. A. Walters, Κ. Η. Martines, D. A. Tomalia, H. A. Bullen 456. Claisen-Schmidt and other condensation reactions on the surfaces of nanocrystalline aluminum oxide and titanium oxide. • H. Hussain, R. Narske 457. Controlling flow of water in nanotubes by patterns of charged dopants. P. Krai, K. Sint, B. Wang 458. Coumarin 343 PEBBLEs selectively monitor intracellular magnesium ion con centrations inside Dictyostelium discoideum. E. J. Moding, M. G. Brasuel 459. Degradation of functionalized porous silicon in simulated gastric fluid. H. M. Dam, L A . Porter Jr. 460. Effect of processing parameters on the synthesis of mesoporous MCM-48. B. Boote, H. Subramanian, K. T. Ranjit 461. Effects of SWNT feeding on Drosophila growth, development, and longevity. K. M. Beckingham, R. B. Weisman, R. M. Reith, M. E. Harden 462. Electroless deposition of metals on nanopattems of n-alkylsilane self-as sembled monolayers. L. Brown, J-R. Li, J. C. Garno 463. Electroroughening and functionalization of nanowire arrays for the development of a biosensor. C. M. Flynn, N. Dower, J. Pelliccia, M. J. Cosentino, Y. Habib, L. H. Rickard 464. Europium modified titania aerogels and xerogels as photocatalysts. A. S. Weber, R. J. Psota, N. M. Parker, Κ. Τ. Ranjit 465. Evaluation of dye molecules capable of probing electron transfer in dye-sensitized photovoltaic cells. J. C. Kofford, B. A. Logue, D. W. Galipeau 466. EXAFS analysis of hydrogénation effects on the structure of Pd nanocatalysts. N. Bursky-Tammam, Y. Piatt, A. Bram, L. Kanner, M. Simpser, J. Zhou, S. Zhao, M. Rafailovich, A. Frenkel 467. Withdrawn. 468. Fabrication and characterization of nanobattery arrays. L. K. Hutter, P. L. Johnson, D. Teeters 469. Formation and characterization of silane self-assembled monolayers on mica surfaces using atomic force microscopy. K. Barnes, K. A. O. Pacheco, G. Ting 470. In situ self-assembly of G-DNA molecular scaffolds nucleated by a polymeric template. M. K. Turner, Τ. Ο Marsh 471. Inherent voltages of solution-cast poly ethylene oxide) electrolyte films. M. W. Kennedy, C. Smith, P. L Johnson, D. Teeters
CHED
472. Introduction to the nanosized world: A laboratory studying properties of silane films. D. J. Mack, K. A. O. Pacheco, N. M. Kunze 473. Investigating the electrochemical reduc tion of gold triphenylphosphine chloride: Precursor in the synthesis of gold nanoparticles. C. L. Moy, L. C. McKenzie, J. E. Hutchison 474. Kinetics of the remediation of chromium(VI)-contaminated groundwater using nanoscale iron particles. A. R. Isley, P. Hari, G. H. Purser 475. Manipulating exposed functional groups of self-assembled monolayers on gold surfaces. R. H. Strine II, G. P. Foy 476. Withdrawn. 477. Osteoblast adhesion on nanostructured hydroxyapatite and gelatin scaffolds. M. Georgy, D. Georgy, D. Teeters 478. Probing monolayer stability via deteriora tion of functionalized porous silicon in alkaline environments. W. W. Labaki, L A . Porter Jr. 479. Properties of charged thermoresponsive hydrogels containing gold nanoparticles. K. S. Lee, N. T. Flynn 480. Proteomic analysis of cultured cells in the presence of carbon nanomaterials. K. A. Waterhouse, D. Hammond, A. Jeevarajan, J. Huff, K. Bradley, J. L. Conyers, V. Moore 481. Quantum dot synthesis: Toward versatile purification strategies. L. K. Grigsby, J. N. Bearden, S. T. Oszwaldowski, K. P. Roberts 482. Solid state synthesis of gold nanopar ticles. K. S. Antion, L. M. Leslie, A. Leavitt 483. Stability of functionalized porous silicon in a simulated gastrointestinal track. D. S. Albrecht, H. M. Dam, J. L Siegel, L A . Porter Jr. 484. Stability of nanoparticle thin films on glass substrates. J . Y. Lin, N. Flynn 485. Study of gold CD-Rs as a surface for nanotechnology applications. D. C. Dewey, G. P. Foy 486. Study of the reaction of NO2 with carbon nanotubes. T-H. Chu, H. M. Bevsek 487. Surface modification of G4 and G5 PAMAM dendrimers. C. D. Girten, J. R. Helton, D. A. Tomalia, K. H. Marlines, H. A. Bullen, K. A. Walters 488. Synthesis and characterization of colloi dal magnetic nanoparticles. V. Vu, V. L. Kolesnichenko, G. Goloverda 489. Synthesis and characterization of copper nanowires. R. L. Butt, L. H. Rickard, Y. Habib 490. Synthesis and characterization of silica microspheres. B. S. Lady, L. L. Pesterfield 491. Synthesis and characterization of transi tion metal ion containing mesoporous MCM-48 materials. E. Nettleton, H. Subramanian, K. T. Ranjit 492. Synthesis and surface-plasmon reso nance spectroscopy of silver nanoparticles prepared by gas-phase condensation. A. M. Fry, B. Tissue 493. Synthesis of functionalized carbon nano tubes for polymer strength enhancement. A. L. Shipman, M. R. Kessler, C. J. Peeples, K. P. Roberts, J. C. DiCesare 494. Synthesis of magnetic surface-enhanced Raman scattering substrates. M. Holt, D. Finley, S. R. Emory 495. Thin films of bifunctional gold nanopar ticles. A. J. Bear, Ν. Τ. Flynn 496. Titanium dioxide nanomaterials as advanced oxidation photocatalysts. N. M. Parker, R. J. Psota, A. S. Weber, Κ. Τ. Ranjit 497. Utility of dendrofullerene DF-1 nanopar ticles for radioprotection in cells. J. O. Reynolds, J. Huff, H. Holtorf, R. K. Bradley, A. S. Jeevarajan, V. C. Moore, J. L. Conyers
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
498. Voltage-gating in synthetic nanopores induced by cobalt ions. M. B. Sullivan, Z. S. Siwy, M. R. Powell, E. Kalman Section J Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Organic Chemistry Cosponsored with SOCED A. T. Bennett and J . L W e s e m a n n , Organizers 11:00-1:00 499. Kinetic studies of the addition of thiolate ion nucleophiles to didemethoxycurcumin. M. A. Gudiel, F. X. Flores 500. An anhydrous polymer supported fluoride source. T. M. Palmeri, A. S. Koch, S. G. DiMagno 501. Performance analysis of gasoline from various local retailers. P. lies, R. Valcarce, L. Giddings, J. Brewer, G. Russell, M. Ahrend, A. Harvey, P. Murphy 502. Synthesis of allyl vinyl ketone substrates for electrocyclization reactions. D. R. Jacobsen, N. A. Yakelis 503. Using fluorocarbons to study carbanions. P. lacono, H. Koch 504. β-Linked dipyrroalkanes as potential precursors to conformationally restricted bipyrroles and tetrapyrrolic macrocycles. M. Collins, A. N. Samuels, G. R. Geier III 505. 3+2 Cycloadditions on azomethine ylides. J. P. Backous, C. P. Jasperse 506. In situ generation of borane for the reduction of nitriles to primary amines. J. M. Brunton, S. E. Schmidt, P. R. Porubsky 507. A convenient synthesis of alpha-arylpropanoic acids: Non-steroidal anti-inflamma tory agents. A. R. Cohen, M. S. Ahmad, C. A. Rojahn, M. M. Hossain 508. A model system to study face-to-face and edge-to-face interactions. K. Waggoner, C. Neill, M. Lewis 509. A new synthesis for an isobenzofuran. D. J. Trader, J. R. McClure 510. A novel approach toward the construc tion of spirocyclic amines. R. B. Ahmed-Schofield, T. D. Davis 511. A one-pot condensation reaction between [8]annulyne and N-ethyl isocyanate. S. J. Peters, J. Klen 512. A replication of Victor Meyer's synthesis of benzildioximes (1888-1889). N. Webber, P. J. Ramberg 513. A theoretical examination of the potential energy surface of α-peroxyacetaldehyde in the gas phase and in dichloromethane. A. W. L. Bayci, J. Hofferberth, K. Hofferberth 514. Aerobic oxidation of α-methylpyrroles to οί-formylpyrroles catalyzed by N-hydroxyphthalimide/CuCI. A. A. Rughani, S. H. Leung 515. Almond to mint in two easy steps. C Heuberger, A. Minnock, A. Sy, J. Bennett 516. Amination of cycloalkanes utilizing nitro gen trichloride. B. A. Cunningham, K. W. Field 517. Ammonia borane as a reducing agent for organic functional groups. K. N. Jaegersen, P. L. Gaus 518. Amphiphilic [2]catenanes synthesis. A. M. Middleton, N. P. Henrich, C. K. Benson-Adjei, D. M. Crizer, K. L. Caran 519. An efficient synthesis of tertiary amines from nitriles. J. Shares, A. Kowalsik, P. Byers, M. Haaf 520. An exploration of novel methods for the synthesis of photochromic molecules. M. L. Winkler, C. Coudret, A. Armas 521. Analysis of pyrrolizidine alkaloid in Cacaliopsis nardosmia. D. S. Kelley, B. M. Acton, S. L. Savage, D. W. Erickson, R. B. Kelley 522. Angelic acid esters in the Ireland-Claisen rearrangement. S. Frost, M. J. Campbell 523. Application of Amberlyst® A-26 (OH) ion exchange resin to aqueous-phase, palla dium-catalyzed Suzuki cross-coupling reactions. A. M. Isom, R. DeVasher 524. Asphaltene aggregation behavior in ionic liquids. L. Brents, J. R. Hardee, M. J. Campbell
525. Asymmetric derivatives of 1,10-phenanthroline. T. C Berto, J. R. Lindlof, K. L. H. Cunningham 526. Attachment of tris(pyrazolyl)methane ligands to synthesis beads. A. Phelan, L. Thompson, T. Linz, R. Tarkka 527. Attempted aziridinations and sulfonilimations using simple iron catalysts and hypervalent iodine reagents. S. J. Simmons, A. N. French, R. D. Richardson, T. Wirth 528. Benzylidene cyclopropanes formed during cyclopropanation of aliènes with rhodium carbenoids. M. J. Waitner, A. P. Pendleton, T. M. Gregg 529. Beta-turn peptides as asymmetric catalysts. M. H. Reutershan, B. R. Linton 530. Biotransformation of selenium-containing substrates to produce unnatural selenium containing amino acids. T. King, J. Thompson, L A. Silks III, J. O. Boles 531. Camphoric acid derived organocatalysts: Efforts toward the asymmetric synthesis of the unnatural enantiomer of the taxol C-13 side-chain and the calcium antagonist diltiazem. K. A. Mesch, S. R. Hitchcock 532. Carbocation reactions with tertiary amines. C. Smith, D. P. Predecki 533. Catalytic enantioselective alpha-oxytosylation of propiophenone using chiral hypervalent iodine reagents. S. M. Paradine, A. N. French, T. K. Page, R. D. Richardson, T. Wirth 534. Catalytic ephedra ligands for asymmetric 1,2-additions and conjugate additions: Efforts toward the asymmetric synthesis of tolterodine. M. A. Dean, S. R. Hitchcock 535. Catalytic synthesis of 5-membered carbocycles via the rearrangement of B-alkoxy dienes. B. A. McKeown, K. S. Knight 536. Cation binding of positive quadrupole moment aromatics. P. Disbennett, M. Lewis 537. Characterization of 1-azidoadamantane and related 1,2,3-triazoles by 1- and 2-D NMR. J. T. Yeoman, T. A. Mobley, J. G. Lindberg 538. Charge transfer on the interface of an organic field effect transistor. L. D. DeVries 539. Comparative structural analysis of halomethyltrimethylammonium salts. R. J. Payne III, F. Fronczek, M. O. Fletcher Claville 540. Comparison of a series of 1 ^-naphthoquinone thiosemicarbazide and semicarbazide compounds. B. Robinson, R. Huxford, E. C. Lisic 541. Computational and synthetic investigation of stabilized and nonstabilized azomethine ylides for the generation of azacycles. A. M. Schimpf, A. M. Hibberd, D. L. Warner 542. Concise syntheses of iridodial and actinidine. J. S. Beckett, J. Hofferberth 543. Conformational control for heterotropic cooperativity and fluorescence chemosensing. Y. Hristova, S. A. Van Arman 544. Continued investigative methods of preparing N-arylenamino ketones and N-arylenamino esters. Β. Τ. McKinney, D. G. Watson 545. Conversion of free base octaethylporphyrins to oxypyriporphyrins. N. Morozowich, C. Ryppa, C. Bruckner 546. Copper (l)-catalyzed synthesis of 1,2,3triazoles by cycloaddition. D. E. Anciaux, A. M. Schoffstall 547. Coupling surface groups to dendrimers to enable passage through the blood brain barrier. M. Lauer, A. Saqr, D. Tomalia, K. H. Marlines, K. Russell 548. Cyclization of alkoxy-substituted 1,7 dienes using zirconium catalysts. C. N. Welch, K. S. Knight 549. Cyclotriveratrylene oxime and deriva tives: Synthesis and conformation. L. Hydo, D. French, P. Rehage, D. P. Becker 550. Degradation of RDX by potassium per manganate: Synthesis and identification of 4-NDAB. M. S. Love, C. Chokejaroenrat, C. E. Harris, S. D. Comfort 551. Dehydration of 5-hydroalkyl-2H-tetrazoles as a route to alkylidenecarbenes. J. P. Komenda, D. J. Wardrop 552. Dendritic Diels-Alder reactions of orange. N. E. Hunter, W. A. Feld
553. Deprotection of aryl mesylates: A new method. D. L. Silverio, D. F. Taber 554. Design and synthesis of oxadiazines based on L-valine: Potential tools for asymmetric catalysis. J. D. Sadik, S. R. Hitchcock 555. Determination of the pKa of alphahydrogens in cyclohexanone by deuterium incorporation studies. B. Blank, R. W. Nagorski 556. Development of a novel method for acyloxazolidinone synthesis using mukaiyama's reagent and dimethylaminopyridine. K. Brandvold, C. P. Jasperse 557. Development of novel multicationic triarylmethane chromophores. D. H. Murray, R. Ramlalsingh 558. Development of peptidomimics as sen sors for opiates. T. Binyon, N. Gleason, A. Evans, R. Castleberry, R. Tarkka 559. Development of water soluble reagents for the Mitsunobu reaction. B. Cansler, M. Clements, M. Haltom, H. Rice, J. P. Deville 560. Diels-Alder reactions of styrene deriva tives in high temperature water. C. E. Bagby, L. U. Gron 561. Disulfide-based beta-sheet peptidomimetics. T. J. Cashman, B. R. Linton 562. DNA adduct formation from interaction with pesticides in plants. T. C. Andrade, D.W.Boerth, E. Eder 563. Domino Diels-Alder reactions: The onepot preparation of polycyclic compounds. C. Renson, M. Davis, H. N. Gray 564. Effect of porphyrin structure on binding to HSA (human serum albumin). A. Hannemann, M. Henderson, J. Widin, J. Dicke, O. Rinco 565. Efficient synthesis of a photocleavable amino acid: o-Nitrophenylglycine. M. E. O'Connor, J. T. Ippoliti 566. Efforts toward the synthesis of (+)kalkitoxin. M. T. Corbett, A. A. Oni, R.J. Mullins 567. Efforts toward the synthesis of bis(butyrolactone) natural products. K. J. Quinn, J. B. Ortolani 568. Withdrawn. 569. Encounter complex and transition state searches for the halogen dance reaction. B. A. Suchy, J. E. Elbert 570. Evaluating synthetic fragments of α-synuclein for influence on a-synuclein aggregation behavior. M. Blattner, C. Crosswhite, K. Walsham, J. H. Miwa 571. Evaluation of the mechanism of reaction of isopropenyl chloroformate, a former war gas. M. J. D'Souza, A. Omondi, K. Shuman, D. N. Kevill 572. Evidence of hydrogen bonding in 1,2,4triazolium salts. C. B. Reddy, A. C. Doran, C. I. Worrall, N. Siripong, L M. Wittenhagen, M. Chen, D. R. Haines 573. Experimental and computational investi gations into an electrophilic aromatic addition reaction. M. R. Huehn 574. Exploring GLP-1R activation using a metal chelated nitrilotriacetic acid deriva tive. E. H. Kelley, M. W. Thompson, D. R. Haines, M. Beinbom 575. Factorial design and linear regression used to determine the importance of various factors to the yield of 7,7dichlorobicyclo[4.1.0]heptane. K. A. Shupe, K. M. Czenkusch, J. A. Bohmann 576. Fluorescent properties of substituted 1,4-dimethylbenzenes. L. Cartmill, G. Sereda 577. Fluorogenic 1,3-dipolar cycloaddition reaction between 9-azidomethylanthracenes and acetylenes and fluorescent properties study. B. M. Hodges, F. Xie, Q. Wang 578. Formation of byproducts in the synthesis of (2,6-dimethylphenyl)-triphenylmethane. K. C. Strohl, D. R. Powers 579. Formation of electron deficient α,β oxy genated alkenes. M. J. Caspers, C. P. Jasperse 580. GC/Mass spectral analysis of substituted chalcones. M. Mohammadi, L. Gillette, T. Simon, W. C. Crawford, Τ. Β. Malloy Jr. 581. High-yield one-step synthesis of donor acceptor cyanostilbenes. D. H. Murray, K. B. Fletcher, R. W. Jiyani 582. Hydrogen bond studies in chemically tuned pyrroles. C. M. Baldwin, R. M. Eason
TECH-23
CHED 583. Hydrogen-mediated C-C coupling of enones and imines: The reductive Mannich reaction. J. R. Brown, S. A. Gamer, M. J. Krische 584. Identification and structural determination of cancer chemoprevention agents from a marine streptomyces sp. M. D. Leibrand, J. B. MacMillan, W. Fenical 585. Improved synthesis of meso-tetrarylbenziporphyrins. V. R. Yant, T. D. Lash 586. Inhibition of ABTS radical cation and soybean lipoxygenase: In vitro biological activities of selected plant extracts. J. Gavillân-Suârez, L. Santiago-Capeles, Y. Garay-Cotto, Y. Rivera 587. Intermolecular interactions in benzylideneaniline crystals: Comparison of a fluorobenzylidene-cyanoaniline to a cyanobenzylidene-fluoroaniline. B. Balidemaj, W. H. Ojala 588. Investigating the hydrogénation of unsaturated aldehydes and related compounds. K. J. Temple, M. Railing 589. Investigation into a one-pot synthesis of phenanthrene. S. C. Chesak, S. T. Handy 590. Investigation into the mechanism of the formation of (2S,6R/2R,6S)-1,1,3-triethoxycarbonyl-2,6,-di-(4-methoxyphenyl)cyclohex-3-en-4-ol. K. A. Hill, B. Baeza, J. L. Maxwell 591. Investigation of a novel phthaldialdehyde reaction. K. M. George, R. R. Hark 592. Investigation of cycloaddition reactions of sulfone ketenes. C. Furr, J. Hill, A. T. Beard 593. Investigation of DNA damage induced by the chemotherapeutic drug cyclophosphamide. A. Mehta, J. Smith 594. Investigation of peptide interactions using a synthetic fluorescent amino acid. A. Perez, L. G. Oesterich, D. R. Haines 595. Withdrawn. 596. Investigation of the Horner-WadsworthEmmons reaction for the preparation of a conjugated polymer. B. A. Franks, P. A. Bonvallet 597. Ionic liquid monomers for low-emission polymers. B. D. Echols, M. J. Campbell 598. Ionic reactions of halogens with 4-halo1,1,2-trifluorobut-1-enes. M. P. Herrick, R. N. Jones, R. J. Weiss, D. Shellhamer 599. Ireland-Claisen rearrangements on chiral acids. A. Doty, M. J. Campbell 600. Isolation and structural analysis of compound isolated from Thevetia peruviana (yellow oleander). L. M. Lindsay, G. D. Frederick 601. Isolation of specific proteins via copper-catalyzed alkyne-azide "click" cycloaddition. B. C. Buer, R. V. Rozhkov, G. M. Knudsen, V. J. Davisson 602. Lewis acid impact upon stepwise and concerted Diels-Alder reaction mechanisms. A. J. Ross, J. A. Plumley, J. D. Evanseck 603. Magnetic materials based on indolesubstituted quinones. Κ. Μ. Darmafall, V. P. McCaffrey 604. Maleimide based tethering of a potential tripeptide agonist to GLP-1R. R. Buglione-Corbett, M. B. Scobee, D. R. Haines 605. Mechanism of carbamoyl formation, pyrimidine synthesis and role of methabolic pathways controling nucleotide syn thesis. R. S. Bozov 606. Mechanistic study of PP-1, a catalytically promiscuous enzyme. E. A. Lund, A. C. Hengge, Ν. Η. Williams, C. McWhirter, G. Feng 607. Mechanochemistry and the BaylisHillman reaction. A. J. Hesse, J. Mack, M. Shumba 608. Medicinal chemistry of (+)-kalkitoxin: Derivatives of the aliphatic core. D. M. Makley, M. T. Corbett, R. J. Mullins 609. Medicinal chemistry of (+)-kalkitoxin: Derivatives of the aliphatic core. M. J. Hellmann, N. W. Cammett, A. A. Valdiserri, R. J. Mullins 610. Michael reactions catalyzed by tetrabutylammonium prolinate. A. M. Nolan, T. W. Surber, P. R. LePlae 611. Withdrawn. 612. Microwave-accelerated Suzuki-Miyaura coupling reactions using potassium aryltrifluoroborates. R. L. Harker, R. D. Crouch 613. Microwave-assisted substitution reac tions in ionic liquids. M. W. Thomsen, C. C. Lasota, K-A. Steen
24-TECH
TECHNICAL PROGRAM 614. Microwave-promoted esterification reac tions: Optimization and scale-up. K. M. Amore, N. E. Leadbeater 615. Moebius bond shifting in [14]annulene. J. Moll, R. P. Pemberton, M. G. Gutierrez, C. Castro, W. L. Karney 616. Molecular recognition of Troger's base analogs. M. F. Serafin, K. A. Wheeler 617. Multivalent peptide recognition by a synthetic host in aqueous solution. A. A. Kennedy, Β. Τ. Halbert, A. R. Urbach 618. N-oxidation of 2, 4-bipyridine and 4, 4-bipyridine via dimethyl dioxirane. L W. Maina Sr., S. McKay 619. Naturally derived flavonols as topical antioxidants. M. Miskiv, G. Jones 620. New directions in the synthesis of a vancomycin derivative incorporating an unnatural carbohydrate residue at the vancosamine position. N. L. Snyder, A. M. de Guillebon, A. E. Hewitt, Κ. Υ. Ngai 621. New polyesters from ionic liquids. R. Jackson, M. J. Campbell 622. New porphyrin chromophores with fused heterocyclic rings. M. A. Geiger, C. M. Cillo, T. D. Lash 623. New synthetic route to 4-hydroxyisoquinolines. N. A. Hastings, D. Huang, J. C. DiCesare 624. NMR kinetics of carbocation mediated iminium ion formation. J. DePasquale, D. P. Predecki 625. NMR method to distinguish long range structural effects via a common Diels-Alder reaction. D. J. McLoughlin, E. Portmann 626. Novel approach to guanacastepene A. G. E. Arab, T. V. Ovaska 627. Novel method for the tritiation of photoactivatable ligands. A. E. Starosta, H. M. Boylan 628. Novel substitution reactions involving meso-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin. A. O. Adeyemo, T. A. Adeyemo, O. Olubajo 629. Nucleophilic addition to pyridine deriva tives: Synthesis of azospyrocyclic com pounds. G. S. Gibbons, S. Fang 630. Olefin cross metathesis of enones cata lyzed by ruthenium complexes. L. J. Allen, R. Raju, M. Thakur, A. R. Howell 631. Overview of copper(l) catalysis in cyclopropanation reactions. L. M. Matosziuk, J. D. Evanseck 632. Oxacycle synthesis by tandem olefin metathesis. K. J. Quinn, C. M. Cammarano 633. Oxadiazinanones as chiral auxiliaries: Addressing the structural and electronic limitations of N4-substituted oxadiazi nanones. Ν. Τ. Stewart, S. R. Hitchcock 634. Oxadiazines as chiral auxiliaries: Prepa ration of ephedra based oxadiazines derived from α-amino acids. C. J. Kelley, S. R. Hitchcock 635. Oxidative cross-linking between poly(dGdC) and polylysine: A model system for DNA-protein cross-linking. K. Schaefer, M. Harris, H. Abuershaid, C. Evangelista 636. Palladium ττ-allyl route to the endiandric acid cascade. S. J. Sobelman, K. C. Gray, F. M. Hocutt, D. A. Vosburg 637. Phosphine catalyzed Henry reactions. J. A. Weeden, J. D. Chisholm, R. R. Hark 638. Planar bond shifting in [4n]annulene species. M. G. Gutierrez, M. Braten, C. Castro, W. L. Karney 639. Polymethylhydrosiloxane (PMHS) in Pd catalyzed reactions with acid chlorides. W. Chong, K. Lee, R. E. Maleczka Jr. 640. Polyphenol^ compounds from Hyperi cum punctatum. H. Matta, M. Janssen, J. A. M. McKenzie, G. E. Henry 641. Preparation of 5-aryl-3-oxo-8-lactones by potassium carbonate promoted addition of β-keto esters to substituted benzaldehydes. J. Gereg, D. Baudo, B. Andersh 642. Preparation of a tryptophan hydroxylase activated gadolinium based NMR contrast agent. S. M. Smith, L Cadish, J. You, N. Shin, N. H. Kolodny, D. R. Haines 643. Preparation of polyether substituted poly(phenylenevinylenes) for use in light emitting devices. M. Kryger, J. D. Barms, E. M. Sanford 644. Preparation of tetradentate "click" chela tors and their ruthenium complexes. J. T. Fletcher, B. J. Bumgarner 645. Progress toward the total synthesis of nootkastatin 2. J. D. Carlson, N. A. Yakelis
646. Progress toward the total synthesis of the penarolide sulfate A-|. C. Toh, D. J. Wardrop 647. Progress toward the production of a carbohydrate-based vaccine targeted at galectin-1. N. L. Snyder, H. M. Haines, A. E. Hewitt 648. Purification of chaulmoogric acid featur ing urea complexation. G. D. Stewart, B. W. Baldwin 649. Pursuing 3,3-diphenyl-1,2-bis(diphenylphosphino)propane and 3,3-diphenyl1,2-bis(diphenylphosphino)butane. G. A. Hudson, B. R. Van Ausdall, R. L. Keiter, E. M. Treadwell 650. Quantifying the effects of substituent position on color of mono- and di-methyl substituted indene anions. L. E. Romick, D. W. Carpenetti II 651. Quasiracemate studies of (S)-3-bromophenoxypropionic acid and (R)-3-methoxyphenoxypropionic acid. M. E. Breen, K. A. Wheeler 652. Quenching mechanism of lucigenin fluorescence: Theory and experiment. N. Cristea, M. Chavez, E. F. Healy 653. Quinoline analogs of perimidinespirohexadienone photochromes. R. W. Knoll, J. G. Gillmore 654. Rapid and convenient preparation of MEM ethers from alcohols using reagents of low toxicity. C. M. Maurseth, J. T. Thomas, G. L. Milligan 655. RCM/CM approach to the synthesis of pyranone natural products. K. J. Quinn, N. A. Biddick 656. Reaction of alpha-haloacylals with metal thiocyanates. D. H. Murray, C. A. Roosenberg 657. Reactions of 1,4-dicyclopropyl-1,3butadienes with singlet oxygen and 4-methyl-1,2,4-triazoline-3,5-dione (MTAD). K. O'Shea, C. Gomez 658. Reactions of singlet oxygen and the singlet oxygen mimic, 4-Methyl-1,2,4triazoline-3,5-dione with (Ε,Ε), (Ε,Ζ) and (Z,Z)-1,4-diphenyl-1,3-butadiene. S. Rodriguez, B. Das, K. O'Shea, C. Gomez 659. Reactivity and enantioselectivity of chiral imidazolidinone organocatalysts in asym metric Robinson annulations. C. M. Mascarenhas, K. E. Lazarski, A. A. Rich 660. Recent progress on the synthesis of a symmetrical dihydroxydibenzo-26-crown-8. K. R. Gilbert, J. S. Howard, Z. Amoozgar, L. R. Sousa 661. Reversible homotrimeric and heterotrimeric cucurbit[8]uril-peptide complexes. L. M. Heitmann, A. R. Urbach 662. Rh-Catalyzed transannulation approach toward N-fused imidazoles. F. Hwang, S. N. Chuprakov, V. Gevorgyan 663. Ruthenium complexes of alkyne-functionalized "click" bidentate chelators. J. T. Fletcher, N. D. Engels 664. Selective oxidation of silo-enol ethers. J. Merrill, L. Bordas 665. Solid-phase synthesis of a fluorescent analog of callipeltin Α. Α. Μ. O'Farrell, D. C. Cranfill, M. A. Upton 666. Solid-state comparison of two bridgeflipped benzylideneanilines. M. K. Kuspa, W. H. Ojala 667. Solid-state intermolecular interactions of 1,2-bis(3-iodophenyl)azine and its isomer, 1,2-bis(3-iodophenylimino)ethane. T. M. Arola, W. H. Ojala 668. Solid-supported [2+2+2] cyclotrimerizations in the synthesis of biologically rel evant molecules. A. Cruz-Montanez, D. D. Young, A. Deiters 669. Solvent-free synthesis of monoacylaminals and hydrolysis to form carbinolamides. T. Koyanagi, R. W. Nagorski 670. Stability of 3-O-arenediazoascorbic acids: Cyclic voltammetry and EPR stud ies. A. Giordano, S. Mahapatro 671. Strategies toward the synthesis of the frondosins. R. E. Kyne, T. V. Ovaska 672. Structural determination and chemotaxonomic analysis of pyrrolizidine alkaloids of cynoglossum occidentale. M. J. Bechaver, R. G. Edwards, R. B. Kelley 673. Structural preferences of malic acid and tartaric acid cocrystals. R. C. Grove, K. A. Wheeler 674. Structure activity relationship study of the N-terminal histidine of GLP-1. K. A. Lipford, L W. Marinelli, C. Luiggi, R. Roush, D. R. Haines
675. Studies in preparation of alpha and beta phytanyl mannoside. R. A. Kjonaas, R. C. Galloway, M. L. Schulte, S. K. Ghosh 676. Withdrawn. 677. Studies toward enantioselective sulfurmediated oxidation of alcohols. B. D. White, R. W. Fitch 678. Studies toward rearrangement of aziridines to allylic amines. G. Brown Jr., K. M. Morgan 679. Study of ortho-quinone cycloaddition reactions: Applications to the synthesis of neolignans. C. Taylor, M. U. T. Huynh, J. Zhang 680. Substitution studies on a tetrathiophenebased ligand system. J. S. Kinyon, C. E. Hobbs, D. K. Howell 681. Synthesis and activity of inhibitors of trypanothione reductase. M. H. Duyzend, W. B. Johnson, S. L. Simmons, D. G. Alberg 682. Synthesis and characterization of a dimethyl dibenzo-30-crown-10 ether. Ε. Ε. Fortin, P. A. Bonvallet 683. Synthesis and characterization of a mixed-valence system composed of a binuclear ruthenium complex with bipyridine and heptadione-type ligands. P. M. Valencia, J. Bonvoisin 684. Synthesis and characterization of a modular multivalent peptide receptor. B. T. Halbert, A. A. Kennedy, A. R. Urbach 685. Synthesis and characterization of a new series of isatin thiosemicarbazone and semicarbazone compounds. K. Monteen, E. C. Lisic 686. Synthesis and characterization of iron(ll) and iron(lll) porphyrin complexes. A. O. Adeyemo, D. Butts, J. Baker, O. Olubajo 687. Synthesis and characterization of two new luminescent iridium and platinum complexes containing the 1,3-(di-N-pyrazolyl)benzene tridentate ligand. A. J. Bach 688. Synthesis and evaluation of nitroxyl releasing compounds. J. L. Lubbeck, S. B. King 689. Synthesis and investigation of the bio logical roles of 1,4-disubstituted and 1,2,4trisubstituted cyclohexadienes. J. M. Benson, B. J. Bench, C. M. H. Watanabe 690. Synthesis and polymerization of a polydiacetylene leukocyte esterase enzyme sensor. M. A. Altermatt, J. T. Ippoliti 691. Synthesis and properties of soluble flavobenzocyclynes. M. Seger, K. C. Russell 692. Synthesis and reactions of 4-iodopentacyclo[4.3.0.0 2 ' 4 .0 3 ' 8 .0 5,7 ]nonane. M. A. Forman, A. Pozzessere, L. Lowchyj, C. Kelly 693. Synthesis and reactions of isomeric diones prepared from dibenzothiophene. B. Bogusz, R. R. Hark 694. Synthesis of 1,1,1 -trifluoro-4-trimethylsilyl-2-butanone-3,3-d2. C. C. Rich, L. J. Tilley 695. Synthesis of cyclopropyl and tetrazole peptidomimetics of D-ala-D-ala. N. K. Dunlap, T. A. Pegram, J. Lamb, L. Waldrop 696. Synthesis of 1 -amino-2,3,4-butanetriol. N. K. Dunlap, J. Drake, A. Martin 697. Synthesis of 2,6,9-trisubstituted purines for the eventual use as ligands in coordi nation complexes. C. J. Rosenker, P. Baran, Z. Travnicek 698. Synthesis of 2-nitro-benzylidenes. B. Edwards, J. G. Edusei, P. L Gaus 699. Synthesis of 3-substituted bisindenylideneindenes: Positional selectivity during synthesis. M. H. Hogue, D. J. Swingle, N. S. Mills 700. Synthesis of a chemiluminescent polymerizable compound. J. C. Speros, J. T. Ippoliti
Please refrain from using cellular telephones and cameras during technical sessions.
CHED 701. Synthesis of a new class of solid organic acids and the ability to tune acidity. A. Gorden, M. Kadarkaraisamy, A. G. Sykes 702. Synthesis of a new series of coumarin derivatives as potential cytochrome P450 inhibitors. M. Foroozesh, A. McCall, A. Norris 703. Synthesis of a nitro-substituted crown ether for incorporation into a light-emitting polymer. V. M. Andrus, D. H. Thomas, P. A. Bonvallet 704. Synthesis of a novel oxazolidinone containing a thiadiazole. A. J. Micek, J. T. Ippoliti 705. Synthesis of a perhydroazulene system through a decalin rearrangement. M. A. Drahl, C. E. Schiaffo, Ε. Z. Tucker, L. J. Stephens 706. Synthesis of a spontaneous nitrite donor. A. Feneran, S. B. King 707. Synthesis of a thiadiazole functionalized oxazolidinone antimicrobrial agent. K. A. McGarry, J. T. Ippoliti 708. Synthesis of alkenyl bromides and alkyl dibromides. B. Drake, S. Ramezan, K. L. Evans 709. Synthesis of allyl vinyl ketone substrates for electrocyclization. N. A. Yakelis, D. R. Jacobsen 710. Synthesis of asymmetric hydroxamates. T. E. Thomas, D. D. Dolliver 711. Synthesis of biodiesel from coconut meat. D. L. Sellers, B. W. Baldwin 712. Synthesis of bulky phenoxide and tripodal amine compounds. J. E. Pearl, S. A. Waratuke 713. Synthesis of chalcones containing pyri dine rings and polyquaternary compounds therefrom. W. C. Crawford, L. Gillette, T. Simon 714. Synthesis of cyclohexyl carbobenzyloxyL-serine benzyl ester phosphodiester: A precursor to the phospholipid analog cyclohexyl phosphoserine. A. M. Buytendyk, J. C. Amburgey-Peters 715. Synthesis of diacetyl ferrocene chalcone using green chemistry. L J. O'Dell, B. W. Baldwin 716. Synthesis of diazo dyes. M. J. Harlow, J. L. Ketron, M. Baskett, G. L. Seebach 717. Synthesis of diimino and tetraimino ligands for use in magnetic materials. A. T. Brusoe, V. P. McCaffrey 718. Synthesis of five novel antimicrobial oxazolidinones via click chemistry. T. N. Winkelman, J. T. Ippoliti 719. Synthesis of fluorescent-labeled phytosiderophore analogs. M. G. Stocksdale, M. S. Peoples, A. C. O'Conner, R. J. Kinne, D. A. Hardesty 720. Synthesis of four-membered ring heterocycles by the reaction of 1,3-dipoles with electrophilic carbenes. J. Kahl, A. H. Predecki 721. Synthesis of lasiol via stereoselective 1,4-conjugate addition. J. J. Gregg, R. J. Mullins 722. Synthesis of N-(2-hydroxyphenyl)-N',N'bis-(2-(2-hydroxyphenyl)amino-ethyl)ethane-1,2-diamine for bonding to lanthanide ions. K. G. Schuyler, P. M. Smith 723. Synthesis of N-fused heteroaromatic compounds via transition metal catalalyzed cycloisomerization of propargyl-containing heterocycles. A. W. Schammel, I. V. Seregin, V. Gevorgyan 724. Synthesis of N-pyridyl-alkylamine by a reductive rearrangement of O-silylated oximes using borane/boron trifluoride system. S. E. Rodriguez, C. Torruellas, M. Ortiz, S. Espinosa, M. De Jesus 725. Synthesis of new carbaporphyrin ketals. A. M. Young, T. D. Lash 726. Synthesis of novel porphyrin ethers. B. E. Smith, T. D. Lash 727. Synthesis of novel PPVs via application of "click" chemistry. T. B. Clark, W. H. Wyatt, N. Panday, W. A. Feld
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
728. Synthesis of silane diol histone deacetylase inhibitors. M. Salvaggio, S. M. Ulrich, M. Haaf 729. Synthesis of specifically substituted 3-phenylisoxazoles with structural similari ties to Fipronil. A. E. Ponsot, L. Huber, R. E. Sammelson 730. Synthesis of substituted 1-benzoxepin derivatives from 3-carboxyisoxazoles. M. D. Jackel, M. G. Kociolek 731. Synthesis of substituted ortho-phthalaldehydes for the derivatization of amino acids. D. C. Hawkinson, E. Meier 732. Synthesis of T-06, a reverse agonist of GLP-1R. L. Kim, J. Y. Lin, D. R. Haines 733. Synthesis of tetrahedrane. K. Whitaker, J. Radziewicz 734. Synthesis of thienyl-containing asymmet ric aryldiketones using the Sonogashira reaction. J. F. de Freitas 735. Synthesizing trapped photochromes for the detection of leukocyte esterase. K. J. Robertson, J. T. Ippoliti 736. Synthetic efforts toward isoaltholactone. K. J. Quinn, Ε. Ε. Faherty 737. Tetraphenyldideazaporphyrin, a novel hybrid of the porphyrins and [18]annulene. S. A. Jones, T. D. Lash 738. The preparation of N4-(2-hydroxyethyl) and N4-(2-hydroxy-2-phenylethyl)oxadiazines as tools for the enantioselective addition of diethylzinc to aldehydes and (diphe nylphosphinoyl)imines. G. L. 3 asciak, S. R. Hitchcock 739. The synthesis of 1-hexylcyclobutene for synthetic studies with difluorocarbene. S. B. .ewis, C. Kane 740. The use of hydrogen bonds to control peptic e structure. L. R. Steffel, B. R. Jnton 741. The mochromic polymers: The effect of structure on transition temperature. K. D. Marchuk, J. T. Ippoliti 742. Titanium promoted conversion of aziridines to beta-lactams. F. Bates II, H.LHoltJr. 743. Titanium(IV) trisphenolate characteriza tion. W. S. Mitchell III, E. M. Valkevich, G. E. Hofmeister 744. Titanium(IV) trisphenolate kinetics. E. M. Valkevich, W. S. Mitchell III, C. M. M. Hurd, G. E. Hofmeister 745. Toward the chemical synthesis of an armchair carbon nanotube. R. K. Hughes Jr., T. J. Hill, L. T. Scott 746. Trends in the chemical shifts of 9-hydroxyphenalenone derivatives. D. Jensen Jr., B. Caes, D. Cast, R. Jensen 747. Trite rpenes and other constituents of Hypericum prolificum. R. S. Saing, S. Rathore, G.E.Henry 748. Understanding the mechanisms of reac tion o : arenesulfonyl chlorides. M. J. D'Souza, S. Mlynarski, L. Yaakoubd, D. N. Kevill 749. Using a photolabile precursor to study radies l-mediated protein damage. T. M. Green, Κ. Ν. Carter 750. Virus detection using a chemiluminescent polymer. E. M. Korman, J. T. Ippoliti 751. Whon will symmetric Diels-Alder adducts follow an asymmetric reaction path? P. B. White, S. M. Bachrach 752. X-rey crystallography identification of bis-aninoacid oligomers. C. Preece, C. E. Schafmeister, Z. Brown 753. Development of a branched chiral selec tor adsorbent with (S)-naproxen termini. S. A. Henrie, S. A. Conway 754. Development of highly regioselective bromi nation of substituted aromatic deriva tives. F. N. Ngassa, K. E. Hamilton 755. Does ionic liquid technology address pollution prevention in the Knoevenagel reacti Dn? D. C. Forbes, S. A. Patrawala, A. M. Law 756. Ger eration and reactions of penta=yclo[4.3.0.02l4.03,8.05,7]non-4(5)ene. M. A. Forman, C. Moran, J. Stairs, J. Herres 757. Hydrogen-bonding in ortfto-substituted benzenes. C. M. Baldwin, M. A. Thornhill 758. Hydrogen-bonding in highly substituted pyrrol as. C. M. Baldwin, A. T. Smith 759. Imp-oving aminoglycoside antibiotics: Design, synthesis, and evaluation of a library of neomycin B-amino acid conju gates S. McGuffin 760. Imp-oving the efficiency and selectivity of host-[2]rotaxanes as cellular transport agents. D. B. Smithrud, C. Diallo, A. Ju arez-Garcia
761. Influence of positive charges on the affinity and stoichiometry of viologen*cucurbit[n]uril complexes. G. Vincil, A. R. Urbach 762. Investigation of cyclopropyl carbene formation from bromo-silyl cyclopropane. J. D. Brown 763. Lews acid catalyzed electrophilic carbonyl addition: Synthesis of alpha-haloacylals. D. H. Murray, A. Agnetta 764. Modified selectivity of linear α-olefin dimerization to linear α-olefin products by cobalt catalysis. Ε. Β. Van Arnam, R. D. Broene 765. Organolithium chemistry: Transmetallation, electrophilic substitution, and crosscoupling reactions of organolithium with boron trifluoride. C. J. Trana, R. E. Gawley 766. Overloading of the Ce(IV)/Si02 solidsupported reagent. M. V. Stewart, K. J. Stanislav 767. Palladium-catalyzed coupling of amines and aryl halides using functionalized neopentylphosphines. J. M. Smith, K. H. Shaughnessy 768. Pd-catalyzed arylation of Sp 3 C-H bonds. O. Daugulis, R. K. M. Khan 769. Photoinduced C-N bond cleavage in 1 -azido-1,3-diphenyl-propan-1 -one deriva tives. C. M. Vanos, R. F. Klima, A. V. Jadhav, P. N. Singh, M. Chang, M. Vu, Ν. Ibrahim, J. A. Krause, B. A. Ault, A. D. Gudmundsdottir 770. Photophysical properties of diarylacetylenes. A. E. Brown, Β. Ε. Eichler 771. Sulfur and selenium ylide bond strengths: A computational study. R. D. McCulla, S. A. Stoffregen, R. Wilson, S. Cercone, J. Miller, W. S. Jenks 772. Synthesis and characterization of 2,6dimethyl-4-phenyl-3-cyclohexenecarboxylic acid and its derivatives, unusual enantio meric pairs that differ only in the position of the double bond. C. M. Kenny, S. Xie 773. Synthesis and computer analysis of two related chalcones. J. Kenney, H. D. Kwon, B. W. Baldwin, T. Kuntzleman 774. Synthesis of 5-[5-(5-formyl-2-thienyl)-2furyl]-2-thiophenecarbaldehyde. J. P. Bequette, B. L. Groh, D. R. Quirk Dorr 775. Synthesis of benzoate esters with poten tial biological activities. M. Foroozesh, Q. Nhan, R. Colvin, T. McGee 776. Synthesis of novel resorcinol derivatives via fragmentation of Meldrum's acid adducts. L L. Tomasevich, M. S. Leonard 777. Synthesis of oxacyclic and thiol methylphenidate derivatives and investigation of their binding affinities via fluroescence. K. M. Jaremko, K. L. Hervert 778. Synthesis of yohimbanones and betacarbolines through heterocyclic rearrange ment chemistry. Ν. Μ. Kennedy, S. M. Zitelli, M. S. Leonard 779. Synthetic approaches to 4-(hydroxymethyl)benzoates and cyclophanes. A. D. Carbaugh, M. S. Leonard 780. Synthetic studies for the synthesis of cassine via Pd-catalyzed carboamination. R. Padilla, J. S. Nakhla, J. P. Wolfe 781. The application of vinylogous iminium salts to the synthesis of Lamellarin G trimethyl ether and Ningalin A. J. T. Gupton, J. E. Hempel 782. Toward a biomimetic synthesis of davanone. K. L Poindexter, P. D. Dossa, K. C. Brown, D. A. Vosburg 783. Toward the synthesis of enantioenriched and highly substituted δ-lactones. J. D. Blakemore, F. Guo, Y. Huang, R. K. Dieter Section Κ Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Polymer Chemistry Cosponsored with SOCED, POLY, and PMSE A. T. Bennett and J. L. Wesemann, Organizers 11:00-1:00 784. Alkoxygermanes as possible calcareous stone consolidants and biocides. G. E. A. Rudd, S. Miller, T. R. Metzger
785. An efficient method for the synthesis of nanoparticles with controlled morphology and functionality. B. E. Wertzberger, M. A. Latta, S. M. Gross 786. Anionic synthesis and functionalization of poly(styryl)lithium with chlorodimethylsilane followed by hydrosilation with vinyltrimethoxysilane. R. L. King, R. P. Quirk, M. Ocampo 787. Antimicrobial activity of cationic poly(ethylenimine). S. A. Koplin, S. Lin, T. Domanski 788. Chitosan for application as an organic light-emitting diode. A. Adams, R. A. Richards 789. Comparing absorption of superabsorbent polymers: Laboratory synthesized vs. industrially synthesized. M. K. Krepps, J. C. A. Cope III 790. Diversion of brewery waste to polylactic acid. M. Kamunde, J. B. Klabo, J. Greene, R. M. Miller 791. Effect of copolyether-urethane-urea domain-matrix morphology on protein adsorption. J. Moseley, B. Bacon, R. D. Bonifield, M. Moore, J. Rivera, D. J. Lyman, P. Schofield 792. Electrochemical synthesis and spectro scopic investigation of a polyaniline film for an undergraduate laboratory. M. L. Mekoli, T. M. Pappenfus, D. L. Hermanson 793. Hydroxypropyltrimethylammonium-xylan adsorption studies onto model surfaces via surface plasmon resonance spectroscopy. D. A. Drazenovich, A. Kaya, W. G. Glasser, K. Schwikal, T. Heinze, A. R. Esker 794. Incorporation of alkynes into block copolymers for "click" cross-linking and BODIPY dye attachment. J. A. Caramiciu, K. B. Aubrecht, J. Robert 795. Investigation of poly(3-hexylthiophene) as an undergraduate lab experiment. D. L. Hermanson, M. L Mekoli, J. H. Melby, T. M. Pappenfus 796. Investigations of polymer coatings for armor protection. C. A. Tieman, M. J. Schroeder 797. Laser line deflection to determine the diffusive behavior of methyl methacrylate and poly(methyl methacrylate) for use in isothermal frontal polymerization models. J. R. McPherson, J. S. Hanna, L. L Lewis 798. Macromolecular release from thermoresponsive cationic hydrogels. L. M. Guiney, N. T. Flynn 799. Macromolecular release using thermoresponsive anionic hydrogels. K. Takatori, Ν. Τ. Flynn 800. Marine anti-fouling: /V-lsopropylacrylamide-based polymers on metal surfaces. M. S. Burr, Ν. Τ. Flynn 801. Modification of montmorillonite clays using quaternary ammonium salts. S. A. Sullivan, L. A. Scheich 802. Novel ionic liquid electrolyte materials for dye-sensitized solar cells. E. S. Sterner, S. M. Gross 803. Photocurable polymers through the Diels-Alder trapping of photochemically generated enols. R. J. Wojtecki, D. S. Tyson, F. Ilhan, D. A. Scheiman, M. A. Meador 804. Plasma surface modification of POSS-MA films on Ta-coated Si wafers. A. J. Figueiredo, Β. Η. Augustine, W. C. Hughes, K. A. Zimmerman, C. C. Chusuei 805. Polymerization reactions from emulsions. B. Chhun, D. Franke 806. Preparation of new materials through the inclusion of polyoxometalate anions within a copolymer matrix. M. A. Kramer, M. L. Nagel, W. A. Neiwert 807. Rain repellant interference with automo tive glass filler adhesion. J. M. Wells, D. M.Joseph 808. Sensor-coatings for the detection and removal of surface-borne lead and americium contaminants. H. N. Gray, L. Williams 809. Surface modification of gold with linear /V-isoproplyacrylamide-based polymers. D. D. Draper, Ν. Τ. Flynn 810. Synthesis and characterization of a new class of glycopolymer MRI contrast agents. M. W. Robinson, T. M. Reineke, C. G. Gulgas, R. L Lucas 811. Synthesis and characterization of copoly mers consisting of poly(l-lactide) and polypropylene glycol). A. Y. Goodner, M. L. Gillespie, A. Jones, P. Schofield
TECH-25
TECHNICAL PROGRAM
CHED 812. Synthesis and characterization of resorcinarene-core polylactide star polymers with cleavable arms. B. A. Goudy, R. D. Dria, P. S. Corbin 813. Synthesis and copolymerization of 2-cyano-1 -oxo-3-halophenyl-2-propenyl ethyl urethanes with styrene. S. Behbahani, A. Lorenz, N. Fliman, A. Reznick, V. Salcedo, B. Shepherd, S. Skucha, T. Taylor, N. Du, C. Dittmann, S. Morris, J. Drandakis, G. Kharas 814. Synthesis and copolymerization of diand trialkoxyphenyl-substituted 2-cyano-1oxo-3-phenyl-2-propenyl ethyl urethanes and styrene. S. Russell, T. Couty, V. V. Horin, S. Begani, B. A. Jerke, C. May, K. Takao, M. Dimarco, F. Villasenor, A. Walton, M. Huang, O. Husseini, C. Montemagni, G. B. Kharas 815. Synthesis and copolymerization of dialkyl and dialkoxyphenyl-substituted 2-cyano-1oxo-3-phenyl-2-propenyl ethyl urethanes with styrene. T. Rose, S. Behbahani, N. Bertrand, S. Blank, T. Beckwith, M. L. Boor, M. Davis, A. Stitch, D. Hans, K. Marhaver, N. Martinez, G. B. Kharas 816. Synthesis and copolymerization of dihalogen phenyl-substituted 2-cyano-1-oxo-3phenyl-2-propenyl ethyl urethanes. J. Crespo, J. A. Hsieh, J. Ippolito, J. Juares, S. Kennedy, E. Lesser, R. Tungekar, G. B. Kharas 817. Synthesis and copolymerization of some phenyl-substituted 2-cyano-1 -oxo-3-phenyl-2-propenyl ethyl urethanes and sty rene. M. Damiano, K. Davis, E. Gibbons, K. Debaene, M. Zuniga, K. Monroe, A. Opalka, T. Rose, G. B. Kharas 818. Synthesis and direct fluorination of den dritic monomers. L. A. Read, K. W. Felling 819. Synthesis and properties of metallated porphyrins immobilized in a sol-gel matrix. D. E. McCall, D. Nguyen, P. Simon, R. Warren, C. H. Lisse, R. A. Richards 820. Synthesis and study of calixarene-core polylactide star polymers and related amphiphilic block copolymers. R. D. Dria, B. A. Goudy, P. S. Corbin 821. Synthesis of "ideal" bipyridyl cross-linked poly(dimethylsiloxane) elastomeric net works. M. R. Kincer, A. D. Schwab 822. Synthesis of a partially fluorinated aro matic polymer by Suzuki polycondensation. R. W. Kopitzke, E. R. Anderson 823. Synthesis of a phosphine oxide termi nated dendrimer. S. Ferdous, R. W. Kopitzke 824. Synthesis of a sulfonated monomer to be polymerized into PEM electrolytes for use in fuel cells. G. K. Mbogo, R. W. Kopitzke 825. Synthesis of monomers for radical ring opening polymerization. T. Vo, K. B. Aubrecht 826. Synthesis of polyarylethers using CF 2 as an activating group. R. S. Haroldson, R. W. Kopitzke 827. Synthesis of polybenzoxazole foam. R. P. Smart, K. D. Conkel, B. Murrell, L. Sanford, A. F. Schultz 828. The effects of annealing on the morphol ogy and color tunability of the luminescent polymer layer of polymer light-emitting diodes. A. L. Crotti, S. J. Gravelle 829. The solubility and conductivity of lithium salts in ionic liquid mixtures. J. L. Hamilton, S. M. Gross 830. Toward soy-based dental composite materials. V. E. Kokai, H. M. Boylan 831. Tri-block biodegradable polymers for drug delivery applications. B. A. Muszynski, S. Singh, S. M. Gross 832. Urea and guanidinium-containing supramolecular polymers. H. H. Musa, A. Nelson, N. Phambu 833. [14]Annuldiyne. J. C. Holloway, C. D. Stevenson
This One is Just Right! Information Resources for Small Colleges Sponsored by CINF, Cosponsored with CHED MONDAY AFTERNOON Section A McCormick Place North Room N227A, Level 2 Research in Chemical Education Research on Guided Inquiry and Miscellaneous D. Mulford,
Organizer
W. J. F. Hunter, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 835. Teacher and student reflections on using guided inquiry to teach high school chemistry. R. A. Krystyniak, A. Stacy 1:55 836. A rubric to characterize inquiry in the undergraduate chemistry laboratory. M. E. Fay, M. Towns, S. L. Bretz 2:15 837. Student learning in the context of incremental change in a general chemistry laboratory curriculum. K. L. Cacciatore, H. Sevian 2:35 Intermission. 2:45 838. In-lecture guided inquiry for large organic chemistry classes. A. L. Sauers, R. W. Morrison 3:05 839. "I could see myself as a chemist": A case study on the science identity for mation of nine Mexican American girls in high school chemistry. R. P. Beeton, G. Canales, L. L. Jones 3:25 840. Preparing chemists to excel: Design, implementation, and evaluation of a fourth-year laboratory course constructivist learning environment. L. A. Avila Diaz, L W. Fine 3:45 841. Beliefs and practices of general chemistry students and faculty members regarding knowledge transfer. A. F. Johnson, G. M. Bodner Section Β McCormick Place North Room N230A, Level 2 Exploring and Exploiting Nature with Biomimetics Biomolecular Self-assembly and Biocatalysis Cosponsored with WCC, BIOL, and INOR S. Mitra,
Organizer
N. Dickson,
Presiding
1:30 Introductory Remarks. 1:35 842. Exploring and exploiting self assembly with DNA nanotubes. D. K. Fygenson, K. Chipman, K. Weirich, P. O'Neill 2:00 843. Nothing amuses more harmlessly than computation. M. L. Klein 2:25 844. The structure and function of hierarchically folded molecules. J. R. Parquette 2:50 Intermission. 3:00 845. Biomimetic assembly of nanoscale functional materials from solution. S. Jin 3:25 846. Toward the development of the catalytic wave function of FeFe-hydrogenases. R. K. Szilagyi 3:50 847. Functional polymeric architectures via self-assembly. M. Week 4:15 848. Bioinspired hydrocarbon oxidations by non-heme iron catalysts. L. Que Jr., R. Mas-Balleste, P. D. Oldenburg 4:40 Concluding Remarks.
Section L
1:35 849. Development and impact of the Center for Workshops in the Chemical Sciences. J. C. Smith, D. M. Collard, L. J. Kaplan 1:55 850. Building a community of teacherscholars: Lessons learned from 10 years of NSF-funded workshops. P. S. Hill 2:15 851. The color of minerals and inor ganic pigments: An interdisciplinary course for Chemistry and Art students. C. Achim 2:35 852. An undergraduate course on "Science and Art" at Wesleyan University. M. E. Klaneski, D. L. Beveridge 2:55 Intermission. 3:05 853. Using a guided-inquiry approach in organic chemistry lab. T. A. Davidson, J. R. Mohrig, C. N. Hammond 3:25 854. Nucleophilic aromatic substitution: A laboratory project. L. Winfield 3:45 855. Extending guided-inquiry experi ments to research proposals in general chemistry. M. F. Hall, B. Anzivino 4:05 856. Toward a more inquiry-based and technology-based general chemistry lab program. A. Hazari 4:25 Concluding Remarks. Section D McCormick Place North Room N229, Level 2 Broadening Participation in Undergraduate Research Cosponsored with CMA, WCC, YCC, SOCED, and COMP M. K. Boyd, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 857. Two-year college research experi ence for undergraduates. R. House, T. B. Higgins, T. Dowd, D. J. Stanford 1:55 858. The Northern Plains Undergradu ate Research Center. M. T. Berry 2:15 859. Introduction to research workshops and intensive undergraduate research experiences as part of the NSF-URC Northern Plains Undergraduate Research Center. A. G. Sykes, M. T. Berry 2:35 Intermission. 2:45 860. Deaf students and interpreters in the research laboratory. G. MacDonald, Β. Ο Seal, D. M. Downey 3:05 861. Visibility of early engagement in undergraduate research at DePauw Uni versity increases participation and interest. B. L. Gourley 3:25 862. Wellesley College's Mentoring in Sciences Program: Efforts to increase minority student participation and retention in the sciences. J. H. Miwa 3:45 Intermission. 3:55 863. Challenges and opportunities in growing undergraduate research at a small public Hispanic-serving institution. M. L. Druelinger 4:15 Panel Discussion.
High School Chemistry Research Poster Session Cosponsored with SOCED T. Taylor, Organizer,
Presiding
11:00-12:00 834. 6,7-Dihydroxy-3,4-dihydroisoquinoline: Novel NF-κΒ inhibitor and anti-metastatic agent. F. N. Alvarez, I. Lindner, L. Carlson, K. P. Lee
26-TECH
L. J. Kaplan and J. C. Smith, D. M. Collard, Organizer, 1:30 Introductory Remarks.
Organizers
Presiding
Process-Oriented Guided Inquiry Learning (POGIL) POGIL Throughout the Curriculum R. S. Moog,
Organizer
A. Silva, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 873. Implementation of POGIL tech niques in chemistry courses at a commu nity college. S. Unnithan 1:55 874. Colligative properties: Oriented guided activities. M. R. Soriano, D. A. Barbiric 2:15 875. Integrating technology with POGIL in large general chemistry classes. S. S. Hunnicutt 2:35 Intermission. 2:45 876. POGIL in context. J. A. Goodwin 3:05 877. POGIL in the Chemistry of Color classroom. R. S. Lumpkin 3:25 878. POGIL by Vogel: Introducing the POGIL pedagogy into analytical chemistry. J. G. Vogel 3:45 Intermission. 3:55 879. Guided inquiry activities on pericyclic reactions. K. E. Butler 4:15 Panel Discussion. Section G
McCormick Place North Room N227B, Level 2 Nanotechnology in Undergraduate Education Nanotechnology across the Curriculum K. A. O. Pacheco, R. W. Schwenz,
Organizer Presiding
1:30 Introductory Remarks. 1:35 864. Development of a nanoscience conceptual inventory. R. A. Elgammal, J. S. Krajcik
McCormick Place North Room N230B, Level 2 Center for Workshops in the Chemical Sciences (CWCS) Chemistry of Art; Guided Inquiry Labs
Section F McCormick Place North Room N231, Level 2
Section Ε
Section C Hyatt Regency Chicago Riverside Center
1:55 865. Nanoscience and technology studies as an undergraduate minor. D. M. Berube 2:15 866. Exploiting photochemistry of nanoparticles to enhance curriculum and research opportunities for undergraduates. W. Lynch, D. Nivens 2:35 Intermission. 2:45 867. Nanotechnology in undergraduate education at North Carolina Central Uni versity. B. Vlahovic, M. Wu 3:05 868. Project DUNES: Developing undergraduate nanoscale experiences in the sciences. K. A. 0 . Pacheco, R. W. Schwenz, J. P. Suits, W.E.Jones Jr., C.Willis 3:25 869. Reconciling principles with prac tices in the age of nanotechnology: Explor ing nanoscale science and engineering in undergraduate education. L. W. Fine, L. Avila, S. Brydges 3:45 Intermission. 3:55 870. Seeding nanoscience throughout the undergraduate chemistry curriculum at James Madison University. B. H. Augustine, K. L. Caran, B. A. Reisner, S. L. Torcivia 4:15 871. Upward integration of nanotechnol ogy in the undergraduate curriculum. S. C. Larsen, N. J. Pienta, R. G. Larsen 4:35 872. Nanotechnology items for ACS Exams standardized tests. T. A. Holme 4:55 Concluding Remarks.
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Biochemistry Cosponsored with SOCED, BIOL, and ΒΙΟΤ A. T. Bennett and J. L. W e s e m a n n , Organizers 2:00-4:00 880. (Oligo)ethylene oxide SAMs on Au: A system to understand protein adsorption on surfaces. R. J. Vierling, J. C. DiCesare, D. J. Vanderah 881. Ability of guanidine and guanidinecontaining species to neutralize the reac tive chlorine species, hypochlorous acid. J. S. Morgan, K. J. Brumback, G. H. Purser 882. An investigation into the biology and management of a monogenean trematode parasite {Acolpenteron ureteroceles) infecting the largemouth bass (Micropterus salmoides). J. A. Dill, D. F. Leavitt, S. O'Shea 883. Characterization of microsomal metabo lism of BML-190, a CB2 selective agonist by HPLC-MS/MS. N. Oliver, Q. Zhang, P. Ma, G. Wang
CHED
884. Effect of 1-propyl-3-imidazolium chloride on spermine binding to duplex RNA. S. D. Berry, L. L. Berry, N. F. Campbell 885. Effect of bay laurel on Cytochrome P450 isoenzymes present in CHO cells. N. Torres, M. B. Gonzalez-Hernandez, L. Santos 886. Effects of osmolytes on protein and nucleic acid processes. S. E. Heitkamp, J. G. Cannon, M. Capp, M. T. Record Jr. 887. Expression of m RNA export protein rael from S. pombe in E. coli BL21 cells. E. E. Stoss 888. Isolation and characterization of chromodulin from octopus liver. M. Viera, C. M. Davis-McGibony 889. Synthesis and evalution of new histone deacetylase inhibitors. K. KrennHrubec, S. Ulrich 890. Synthesis of electrophilic inhibitors of LuxS, a quorum sensing enzyme. C. O'Loughlin, S. Ulrich 891. Ultrastructural effects of RNAi-mediated nopp140 knockdown. A. L Joe, P. J. DiMario 892. What role does dad's basic region play in mdia's auto-inhibition mechanism? A computational study. S. K. Munster, M. E. Karpen 893. Metalloproteases involved with teleost hatching. J. L. Holloman, G. L. Seebach, B.Sly 894. Quantitative PCR methods for assessing epichlorohydrin damage within chicken erythroid cells. M. L Watts, J. T. Millard 895. Study of inositol phosphate using changes in fluorescence. J. Corwin, S. E. Pattison 896. Rhodoccocus rhodochrous B-276 grown on propane expresses a unique acetonedegrading enzyme. C. A. Plewik, C. Broberg, D. D. Clark 897. Characterization of West Nile virus RNA dependent RNA polymerase. A. Mattheus, J. S. Temple, M. B. Doughty 898. Comparison of allergen profiles in Alternaria. Ν. Τ. Dahl 899. Copper complexes of alpha and beta amino acids. S. Lawrence, E. Csuhai, G. L. Seebach 900. Dependence of DNA-protein crosslinking on DNA sequence. J . Scala, G. Gonzalez, S. Burton, C. Norashkharyan, J. Palma, A. Madison, E. D. A. Stemp 901. Dependence of oxidative DNA proteincross-linking on GC content. C. E. Ochoa, T. Maisonet, J. Zelaya, M. Alvarez-Montez, E. D. A. Stemp 902. Design and characterization of leucine zipper coiled-coils for use in ordered nanostructures. J. W. Nelson, K. L. Kiick 903. Expression of lipid droplet proteins in macrophages. M. L Hobbs, T. M. Ander, J. T. Tansey 904. Implications.of RNA tertiary structure on double stranded RNA binding proteins. T. D. Wabbersen, D. G. Stoub 905. Induction/activation of phosphotidyl inositol 3-kinase by vanadium-flavonoid complexes. G. A. Legatt, K. G. Fernando, M. Mahroof-Tahir, L. Sreerama 906. Kidney tissue damage during the pro gression of diabetes: Time course study. K. A. Negrin, C. B. Vincent, P. J. Birckbichler 907. Kinetic analysis of nucleosomal DNA repair. M. T. Hoss, K. A. Haushalter 908. Lateral diffusion of the Torpedo and muscle type acetylcholine receptors on oocytes membranes of the Xenopus laevis. I. Rodriguez Nazario, A. Ortiz Acevedo, J. A. Lasalde Dominicci 909. Local sequence effects on the pks of ionizable groups in a small monomeric protein. M. E. Hobbs, R. L. Thurlkill
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
910. Moculation of estrogen receptor ligandbinding domain dimer exchange by small mono functional alcohols. R. J. Waltz, M. E. Brandt, D. M. Knapp 911. Nov5l method for analyzing spectro scopic ligand binding data. A. G. Georgas, M. E. Brandt 912. Oxidation of GMP in the presence of lysine A simple model system for DNAprotein cross-linking. J . D. Ott, K. Rebello, C. B. Evangelista, E. Lee, E. D. A. Stemp 913. ΡΑΊ-1/MLDP increases triacylglycerol stores and changes lipid droplet morphol ogy, ίί. R. Bartholomew, E. M. Hlavin, T. L. Summerfield, W. E. Ackerman, J. T. Tansey 914. Polypeptide cobalt complexes of betaaminc acids. S. D. Westerman, E. Csuhai, G. L. oeebach 915. Qualitative proteomic determination of protei ns differentially expressed by Xanthoba:ter autotrophicus Py2 during growth on propylene or glucose. C. Broberg, D. D. Clark 916. Reconstitution of cytochrome P450 3A4 activit/ in a lipid free system. C. Lindsey, H. Fenando, D. Davydov, J. Halpert 917. Role of Glu68 of the Fe protein of nitrogenai.e from Azotobacter vinelandii in component protein interactions. J. L Prince, J. M. Chan 918. Site-directed mutagenesis of the yeast V-ATPase subunit d. C. Damin, D. L. Pappas Jr., K. J. Parra 919. Structual analysis of Piscidin 1 via high resolition solid-state NMR techniques. R. J. iSaager, M. Cotten, R. Fu 920. Structure and dynamics of the antimicro bial peptide piscidin. B. S. Vollmar, M. Cctten, R. Fu 921. Study of freeze-avoidance in the ooplasm of an Antarctic fish, Gymnodraco acuticeps, using NMR spectroscopy. T. Lirk, M. Marjanovic, B. A. Lawrence 922. Sub-cellular localization of two P-type ATPases, Atp13a1 and Atp13a2. R. Baldridge, A. C. Ketron, J. Walter, J. Leclford, D. L. McGill, P. Schultheis, K. H. Martines 923. Synthesis and analysis of RNA contain ing 2-trifluoromethyl inosine. L A. Taylor, D. G. Stoub 924. Synthesis and characterization of peptide nude c acid for experimental use of direct ing anthrapyrazole intercalation. J. M. Bradley, K. A. Bruns 925. Synthesis of farnesyl pyrophosphate analogs for affinity chromatography and photo labeling. J. J. Stracke, M. D. Distefano, J. Xu 926. The effect of divalent cations (Mg2+, Zn2+ Mn2+, and Ca2+) on the hybridiza tion efficiency of DNA. J. Buthker, J. Nichols, K. Sinniah 927. The use of microfluidic devices for com prehensive multidimensional electrophore sis of fetal calf serum. B. C. Snowden, H. Shadpour, M. A. Witek, S. A. Soper 928. Trapping of a nucleosomal DNA repair intermediate. K. Loh, K. A. Haushalter 929. tRNA identity elements for GatDE. B. Mîirtin, K. Sheppard, L. Sherrer, D. Soil 930. Using capillary electrophoresis to study the RNA-acting adenosine deaminase reaction. J. E. Kusnir, D. G. Stoub 931. Analysis of growth and activity of transformed Escherichia coli cells containing the Entamoeba histolytica enzyme EhADH2 by using metal ions and chelators to confirm the presence of an iron activei center within the ADH domain. M. J. Roberto, D. A. Espinosa 932. Analysis of oxidized fatty acids by HPLC and GC. A. B. Ashton, S. E. Pattison 933. Doe^s gp96 form homooligomers in vivo? M. Biirtik, K. L. McQuade 934. Withdrawn. 935. Effect of trifluoroethanol on the structure and activity of calf intestinal alkaline phosphate se. J. L. Schwartz, E. Csuhai 936. Evaluation of peroxidase activity in natural antioxidants. M. L. Scozio, M. F. Wright, R. B. LaCount 937. Fatiî of creatine in the reaction with hypochlorous acid. K. J. Brumback, M. R. Thomas, J. C. DiCesare, G. H. Purser 938. Ion beam analysis of metalloprotein stoichiometry. L A. Ellsworth, J. D. Warner, M. J. Rycenga, L. M. Kiessel, G. F. Peaslee, P. A. De Young
939. Quantitative mass spectrometry of honey bee venom proteins. J. W. Kleinberger, C. R. Ross, L. M. Mulfinger 940. The purification of the ligand binding domain of the human Androgen Receptor and the analysis of binding of testosterone and mibolerone. M. N. Wells 941. In vitro and in vivo interface studies with genetically incorporated p-benzoyl-Lphenylalanine. R. A. Mehl, D. P. Nguyen 942. Attempted solid phase synthesis of truncated HIV-1 Nucleocapsid protein. M. M. Kelly 943. Covalent trapping of the hOGG1:nucleosomal DNA complex. F-Y. Chang, K. A. Haushalter 944. Effect of sucralose on invertase-catalyzed sucrose hydrolysis. H. H. Tran, P. W. Baures 945. Effects of Valeriana officinalis extracts on [3H]glutamate binding. B. A. Torres Hernânadez, G. Gonzalez-Medina, N. Berrios-Cartagena, J. M. Cordero-Hernândez, J. G. Ortiz 946. Thermal stability of like RNA inter- and intramolecular triple helices. E. Cantu, J. Miriti, D. J. Holland 947. Biochemical analysis of microbial communitites from forest canopy soils of Gifford Pinchot National Forest. E. J. Sloan 948. Cigarette smoke effects on the AKT pathway in normal human lung fibroblasts. A. E. Conway, C. A. Martey-Ochola 949. Citric acid anhydrous disrupts corticosterone levels in Sprague-Dawley rats. J. L. Lasecki, M. G. Baldridge 950. Determination of the postmortem interval by analysis of adipocere using gas chromatography. O. C. Langguth, C. E. Stilts 951. Determining the organization and function of the serine chemoreceptor in Escherichia coli by incorporation of photocrosslinking amino acids site specifically. R. A. Mehl, J. Weinstein 952. Development of an enzyme-linked immunosorbent assay incorporating the enzyme alcohol oxidase and the reporter peroxyfluor-1. K. A. Leehy, L J. Baumgartner, K. Olson 953. Experiment vs. computation: What does nature think of human designed proteins? E. Repasky, C. Fortenberry, L. Mizoue, B. Dorr, J. Meiler 954. Site specific fluorinated unnatural amino acids in proteins probed by 1 9 F NMR as a tool for probing protein conformational changes. R. A. Mehl, J. T. Hammill 955. Structural and mechanistic characterization of a bacterial catalytic riboswitch. J. Soukup, K. Klawuhn 956. Structural and thermodynamic effects of halogen bonds in proteins. R. A. Mehl, S. Miyake-Stoner 957. Studies of the mechanism of microwaveassisted fixation of tissues by formaldehyde. M. L. McCrea-Hendrick, R. T. Giberson, R. M. Miller, C. Gaffney 958. Treating crown gall disease in miniature roses by photodynamic therapy. V. M. Paul, C. E. Stilts 959. Comparison of pH values of two zwitterionic buffers, (DIPSO) and (MES), from 5 to 55°C. J. L. Durden, C. E. Denton, S. R. LeNoue, T. Ghosh, C. N. Roy, L. N. Roy, R. N. Roy 960. Cytotoxicity of functionalized hexagonal mesoporous silicates in IEC-18 and MDCK cells for their use as non-steroidal antiinflammatory drug carriers. D. J. Mayo, M. Zastrow, I. L. Lagadic, R. L. McCann 961. Directed evolution of bacteriorhodopsin for use in optical devices. Κ. Ν. McCleary 962. Effect of organic solvents on alkaline phosphatase enzyme activity. E. Dorfling, G. L Seebach, E. Csuhai 963. Effects of the genetic background of (Na + , K + )-ATPase, a-2 knockout mice on the distribution of a-2 and a-3 isoforms of this enzyme in the brain. A. M. Baran, N. R. Meyer, T. M. Spranger, J. B. Lingrel, A. E. Moseley, M. L. Caspers 964. Expression and purification of a yeast glutaminyl cyclase. A. Dantin, J. S. Temple 965. Importance of loop-loop contacts to guanine riboswitch genetic control. J. Soukup, A. Werth 966. p107 Protein complexes in 3T3L1 preadipocyte differentiation. G. Jackson, S. Hart, R. Ngwanyam, T. E. Hayes
967. Role of an alternative processivity Clamp in DNA damage tolerance in E. coli. M. J. Ordazzo, P. J. Beuning 968. Structural characterization of the S-adenosylmethionine riboswitch. J. Soukup, V. Ward 969. Analysis of total protein in wild type and «2 (Na+ + K+)-ATPase heterozygous FVBN mouse brain sections. R. H. Stevens 970. Characteristics of surface adsorption of leucine enkephalin on fused silica. N. M. Litzie, M-C. Su, J. W. Lillig 971. Withdrawn. 972. Increased S6K1 protein expression confers proliferative advantage and Rapamycin sensitivity to human mammary cancer cells. N. Brodt, R. L Yamnik, J. Blenis, M. K. Holz 973. Stabilty of inter- and intramolecular RNA triple helices and loop size. J . K. Miriti, E. Cantu', D. J. Holland 974. Characterization of chromatin remodeling proteins in Arabidopsis thaliana. R. J. Burgess, X. Yang, C. A. Makaroff 975. Characterization of fathead minnow and frog aldehyde dehydrogenases (ALDHs) with regard to their role in metabolism of ethylene glycol ethers. T. Yanjon, I. Penniston, A. Piotrowski, D. Petersen, T. Schuh, H. Schoenfuss, L Sreerama 976. Dermal accumulation of astaxanthin in the false percula anemonefish, Amphiprion ocellaris, under a diet of varying astaxan thin concentrations. K. G. Jackson, L F. Ho, H. F. Pomeroy, S. K. O'Shea 977. Developing a functional assay to study transport dysfunction across membranes. C. Shacklady 978. DNA's stability: Composition vs. sequence. S. A. Guigui, D. Estes, L. Blau 979. How many ways can you leave your DNA behind, and TWINS: Identical or fraternal? J. M. Ludovici, B. E. Flowers 980. Hybridization of calf thymus DNA in 1 -butyl-3-methylimidazolium chloride. L. L. Berry, S. D. Berry, N. F. Campbell 981. Novel tubulin interacting agents. K. Chastain, M. Gourley 982. Overexpression of serine carboxypeptidase II in a pET 32c vector. L. Abu-Esba, M. A. Kopecki-Fjetland 983. Quantifying RNA and DNA content in Gammarus minus. S. M. Guida, R. Reed, D. Glazier 984. Withdrawn. 985. Synthesis and characterization of pyri dine, pyrrole and anisole containing calixarenes. M. Tincher, A. Gebauer 986. Analysis of tissue transglutaminase and apoptosis in human fibroblasts. R. L Wagner, A. J. Henry, P. J. Birckbichler 987. Anaredoxin as a potential rubredoxin. M. Borck, M. A. Kopecki-Fjetland 988. Capturing AlkA in action: X-ray crystal lography of a glycosylase with unusually broad substrate specificity. B. R. Bowman, S. Lee, S. Wang 989. Characterization of membrane lipid modification as a result of hyperglycemic induced oxidative stress in PC-12 cells. K. Andrews, M. A. Fisher 990. Cloning and expression of a truncated metacaspase from Schizophyllum com mune. B. C. Gulack, K. M. Fox 991. Enzymatic synthesis of dipeptides. A. R. Szklarski, D. P. Kongsaeree 992. Expression of adiponectin membrane receptor 1 in Sf9 cells. S. Kissinger, L. Walker, C. L. Parker 993. Expression, purification, and character ization of two human aldehyde dehydroge nases (ALDH3A1 and ALDH9A1). R. A. Grant, M. A. Salad, L Sreerama 994. Influence of pH and food matrix on protein adsorption by activated charcoal. A. Olena, R. Kopper 995. Native polyacrylamide gel electrophore sis assessment of DNA bending upon diepoxybutane and epihalohydrin crosslinking. E. E. McGowan, J. T. Millard 996. Protease inhibition of oral bacteria S. mutans and A. actinomycetemcomitans by oil-soluble garlic compounds. J. M. Uhrin, M. A. Fisher 997. Quantitative PCR suggests preferential nuclear DNA alkylation by epichlorohydrin in the chicken genome. A. G. Newman, F. J. LaRiviere, J. T. Millard
TECH-27
CHED 998. Quantity of sugars produced from switchgrass hydrolysis by variation of Thermobifida fusca enzyme mixture. C. J. Gillard, J. DeSantis, D. E. Wolfgang 999. Regulation of cell cycle inhibitors by the SCFSkp2 E3 ubiquitin ligase. T. D. Schoedel, R. J. Sheaff 1000. Segmental labeling of proteins via sortase enzyme: Human lysyl aminoacyl tRNA synthetase. S. Dave, P. Kaur, J. M. Sapitro, M. Howell, P. Tsang 1001. Structural and mutation studies on the Rieske protein from Thermus thermophilus. C. Froyd, S. Muellner, R. Pokhrel, L. M. Hunsicker-Wang 1002. Structure-function relationship of Glyceraldehyde-3-phosphate dehydrogenase. A. Easterday, N. Keil, R. Subramaniam 1003. Copper chaperones from Thermus thermophilus: Toward a purification proto col for Sco1. J. Robicheaux, M. Goebel, L. M. Hunsicker-Wang 1004. Determination of OMP expression in ciprofloxacin-resistant Salmonella enterica in varied ionic conditions. W. T. Rundle, M. A. Fisher 1005. Development of affinity chromatography reagents for purification of the class D β-lactamase OXA-1. S. Toman, D. A. Leonard 1006. Investigation of branch points of the biosynthetic pathway of rhodoquinone in Rhodospirillum rubrum via HPLC analysis. L. A. Johnstone, R. K. Morgan, B. N. Marbois, C. F. Clarke, J. N. Shepherd 1007. Synthesis and comparison of a series of N-substituted isatin thiosemicarbazone and semicarbazone compounds. B. Newhouse, K. Ford, K. Monteen, E. C. Lisic 1008. A single molecule study of enzymeinhibitor interactions. S. G. Kamper, L. Porter-Peden, K. Sinniah 1009. Withdrawn. 1010. Applications of stable photoactivatable analogs for the study of farnesyl diphos phate utilizing enzymes. M. L. Hovlid, 0 . Henry, J. Xu, M. D. Distefano 1011. Biophysical study of RNA dimerization in hepatitis C virus. P. E. Lackey, K. A. Ruszkowksi, M. R. Mihailescu 1012. Cellular localization of guanidinium peptide nucleic acid. E. A. Wiltrout, D. H. Ly 1013. Chemical interactions between peanut proteins and activated charcoal. A. Anthony, R. Kopper 1014. Cloning, expression, and initial charac terization of a K. pneumoniae enzyme involved in virulence. C. Hall, L. Beuke, A. E. Zercher, J. L. DuBois 1015. Cloning, purification and characteriza tion of human aldehyde dehydrogenases ALDH5A1 and ALDH7A1 and their ability to catalyze detoxification of certain chemotherapeutics and environmental contami nants. A. A. Pitcher, T. J. Hoffman, L. Sreerama 1016. Conformational dynamics during termi nation of protein synthesis. S. H. Sternberg, R. L. Gonzalez Jr. 1017. Detection and characterization of DNA distortion induced by cation-pi interactions. M. Stewart 1018. Differential regulation of Myosin II during cell spreading. A. V. Shneidman, 1. Spielman, B. J. Dubin-Thaler, V. Cornish, M. P. Sheetz 1019. Downregulation of cohesin protein SYN3 by RNAi in Arabidopsis thaliana. K. Harris, L. Jiang, M. Xia, C. A. Makaroff 1020. Effect of a C-terminal tail truncation in GroEL on protein folding. M. R. Kastner, S. Falke 1021. Effect of the histone deacetylase (HDAC) inhibitor PXD101 on the human colon carcinoma cell line FET. J. K. McArdle, M. Brattain, D. G. Howell 1022. Effects of 3-methyleneoxindole (MOI) on procyclic forms of Trypanosoma brucei: Possible mechanisms of drug toxicity. B. R. Zografos, P. E. Mancini, E. J. Brush 1023. Effects of phosphorylation via cGMP dependent protein kinase on the MaxiK channel in wild type and beta-1 knockout arterial smooth muscle. J. D. Bates, G. J. Peréz, R. Bucciero
28-TECH
TECHNICAL PROGRAM 1024. Elicitation of oxidative stress in vitro on the cytochrome bc^ complex of Rhodospirillum rubrum using rhodoquinone and other synthetic quinone species. R. K. Morgan, J. L. Cape, D. M. Kramer, J. N. Shepherd 1025. Elucidation of the regulation of DNA damage response in Escherichia coli using two-hybrid analysis. C. Kuang, P. Beuning, G. Walker 1026. Epitope mapping anti-ADAMTS13 antibodies. J. A. Thomson 1027. Exploration of a GDP-specific aminotransferase. U. Joshi, N. Beyer 1028. Expression and purification of human arylamine N-acetyltransferase 2. I. Baker, J. Hurlbert, C. L. Parker 1029. Expression of a glycosyltransferase from Streptomyces nodosus. A. Schoofs, N. Beyer 1030. Fatty acid ethyl esters as biological markers for the diagnosis of Fetal Alcohol Syndrome. P-H. Wei, N. McCormick, V. A. Hornik-Rosinski, H. Kim, E. S. Roberts-Kirchhoff 1031. Fluorescence quenching of Green Fluorescent Protein by various metal complexes and flavonoids: Calculation of quenching constants, excited lifetimes and intermolecular distances. B. L. Swartz, D. Snyder, S. Basu 1032. Impact of cysteine carboxymethylation on n-propanol unfolding of yeast cytochrome c. K. D. Clevenger, S. A. Mistry, G. C. Hoops, T. A. Hopkins 1033. Interactions of p107 in 3T3-L1 preadipocyte differentiation. S. Hart, G. Jackson, R. Ngwanyam, T. E. Hayes 1034. Investigating odorant signal attenuation in the cockroach Lucophae maderae. A. E. Thurber, J. Hofferberth 1035. Investigation of abnormal cell cycle progression and cyclin expression in U138MG glioma cells. A. B-l. Popejoy, L. A. Wetmore 1036. Investigation of hydroxyethyl acrylate and hydroxyethyl methacrylate effects on membrane permeability in L929 mouse fibroblast cells. L. Wahl, L. A. Wetmore 1037. Investigation of N-methyl-5H-benzocycloheptanaphthalene-5,12-imine induced cell toxicity. A. J. Boustani, R. J. Sheaff, J. C. DiCesare 1038. Investigation of the cholesterol content distribution within phospholipid bilayer vesicles using fluorescent analysis. K. E. Perko, C. P. Pennell, J. C. Utter, K. Dharmala, L. A. Wetmore, J. E. Code, D. M. Yourtee 1039. Investigation of the effect of cholesterol content on phospholipid bilayer vesicle disruption by common amphipathic solvents. C. P. Pennell, Κ. Ε. Perko, J. C. Utter, K. Dharmala, L. A. Wetmore, J. E. Code, D. M. Yourtee 1040. Investigation of the mechanism of inhibition of the dopamine transporter by modafinil. A. L. Schuh, J. C. Wieting, C. E. Ochsner, J. S. Russel 1041. Isolation and characterization of novel(bis)indole alkaloids from local marine sponges. T. R. McCall, P. C. Pletcher, C. M. Davis-McGibony 1042. Isolation and characterization of pro teins involved with biomineralization in silkworms (Bombyx mori). S. G. Dixon, L. A. Porter Jr., A. J. Wyman 1043. Kinetic characterization of Arylamine N-Acetyltransferase 2 using the substrates sulfamethazine and 5-aminosalicylic acid. R. Glazener, I. Baker, J. Hurlbert, C. L. Parker 1044. Mapping the interaction of the HIV-1 capsid protein and lysyl-tRNA synthetase using covalent cross-linking studies. J. A. Hubers, B. Kovaleski, K. Musier-Forsyth 1045. Mechanistic study of inosine mono phosphate dehydrogenase. S. Braun-Sand, D. Anciaux, A. Cook 1046. Oxidative degradation of anilinic azo dyes by horseradish peroxidase. J. Lokken, H. Patnode, M. A. Miller-Rodeberg 1047. Polypeptide collapse initiates the change in redox potential of Phe-82 iso-1cytochrome c mutants. B. A. Feinberg, S. M. Seefeld, D. Xie 1048. Possible O-linked glycosylation of enamelin 23 kDa cleavage product. M. J. Love
1049. Proteomic analysis of the mid/hindbrain of Pet-1 knockout mice. J. D. Schonhoft, P. Der, E. V. Gilbert, M. Giammo, E. M. Mintz, S. Basu 1050. Purification of cyclohexyl (CBZ-L-SerBzl) phosphodiester: Precursor to a pro posed phospholipid analog (PLA) of phosphatidylserine. N. J. Amato, J. C. Amburgey-Peters 1051. Role of histidine-98 in the enzyme mechanism of methylglyoxal synthase in Escherichia coli. T. M. Emmer, G. Marks 1052. Sensitivity of human breast adenocarci noma cells to Ottelione A and its structural analogs and possible molecular basis for resistance to Ottelione A. S. L. Scully, S. Ghose, S. Marine, K. Islam, T. R. Hoye, G. Mehta, L. Sreerama 1053. Separation and isolation of metabolites of N-(4-hydroxyphenyl) retinamide (4-HPR) after incubation with Sprague-Dawley rat liver microsomes. Ε. Κ. Malcolm, M. D. Kelley 1054. Synthesis and purification of brominated ubiqinone pseudosubtrates for fluorescence studies of electron-transfer flavoprotein: Ubiquinone oxidoreductase (Etf:Qo). A. K. Furdek, W. W. Radford 1055. Synthesis of ethylene glycol ether aldehydes and their enzymatic oxidation by human aldehyde dehydrogenases. A. D. Gross, D. D. Gregory, L. Sreerama 1056. Synthesizing juglone with green chem istry. H. Vo, N. Beyer, R. Eliason 1057. Toward expanding the pool of GDPactivated sugars. D. Scheppmann, N. Beyer 1058. Understanding how the E3 ubiquitin ligase SCFSkp2 targets proteins for degra dation. R. C. Hughes, R. J. Sheaff 1059. Water molecules interact site specifi cally with the conjugated pi systems of DNA bases. T. O'Bannon, G. Holman 1060. Why not silicon? A comparative molecular mechanics and molecular mod eling study of three important biological molecules. J. C. Cooper, M. K. Murphy 1061. 1 9 5 Pt NMR analysis of non-DNA sub strate binding sites to platinum complexes. C. T. Roberge, S. K. O'Shea 1062. Aggregation prevention of amyloid peptide using sugars. J. Gagnon, M. Preimesberger, J. Schwehm 1063. Comparative modeling of plasma mem brane permease Git1 ρ from Saccharomyces cerevisiae. S. Okolo, J. D. Madura, J. L. Patton-Vogt 1064. Deacetylation levels on histones H3 and H4 by Sir2 and Hos1 in Saccharomyces cerevisiae. S. E. McQuate, C. M. Smith 1065. Molecular interactions in binary phos pholipid monolayers. C-F. Chang 1066. A mutation in vesicle-associated mem brane protein 1 causes prewean lethality in the mouse lethal wasting mutant. J. K. Schwendinger, A. J. Sachs, N. B. Haider, A. M. Nystuen 1067. Accurate potentiometric titrations of citric acid and molybdenum in aqueous solutions. T. Greer, Y. Z. Hamada 1068. Amino acid and carbohydrate content of wine cup nectar and pollen. L. Lawdermilk, B. Amos, N. Flynn 1069. Analyzing post-transcriptional modifica tions in the t-RNA like structure (TLS) of the Brome mosaic virus (BMV). D. Y. Adamu, C. C. Kao, K. Gopinath 1070. Aqueous solution chemistry of Zn(ll) and Cd(ll) with L-DOPA. C. Rogers, Y. Z. Hamada 1071. Binding of NCp7 protein with varied stem loops of the HIV-1 genome. N. Atlasevich, M. Ferguson, D. B. Hudson 1072. Cloning and expression of a putative metacaspase from Schizophyllum com mune. M. M. Fox, K. M. Fox 1073. Cloning, expression and purification of human adiponectin receptor AdipoR2. Z. Ghadiyali, C. L Parker 1074. Dependence of DNA-protein crosslinking on guanine radical protonation state. A. J. Estonactoc, J-L. Padigus, J. Scala, J. D. Ott, A. Madison, E. D. A. Stemp 1075. Derivatives of azure Β and toluidine blue as potential photodynamic therapy agents. B. Chee, J. A. Kohlmeier, M. V. Keck
1076. Determination of critical micelle concen tration for the fluorescent phospholipid 2-(6-(7-nitrobenz-2-oxa-1,3-diazol-4yl)amino)hexanoyl-1 -hexadecanoyl-snglycero-3-phosphocholine[NBD-C6-HPC] and its aggregation behavior with bile salts. R. L. Baskin, L. D. Frost 1077. Determining binding of 2,4-Dichlorophenoxyacetic acid to the fibroblast growth factor receptor 2b using computer model ing. D. J. Anton, A. Khandelwal, Η. Ε. van Gijssel 1078. Effect of cooking on the antioxidant level of cabbage. W. M. Vann, J. R. Broughton, G. C. Weaver 1079. Functional reconstitution and 1 H NMR study of recombinant peripheral cannabinoid receptor CB2. S. D. Rhodes, T. Kimura, A. Yeliseev, K. Gawrisch 1080. Gene expression studies of TRP ion channels implicated in cancer. M. Davis, J. Frederick 1081. Human lysyl aminoacyl tRNA synthe tase and tRNA binding. M. K. Bates, R. Kennedy, K. Musier-Forsyth, M. Howell, P. Tsang, M. Marei 1082. Multifaceted study of Glutamic acid with Cu(ll) and Cr(lll) metal ions in aqueous solutions. H. Holeyfield, Y. Z. Hamada 1083. Regulation of the anthocyanin pathway in arabidopsis by MYB transcription factor PAP1. J. M. Leavitt, A. Gonzalez, A. M. Lloyd 1084. RT-PCR experiments to explore TRPlike genes in non-mammals. M. McCabe, J. Frederick 1085. Solid state 31Ρ and 2H NMR of mem brane active peptides in bicelles. N. Gleason, D. Greathouse, C. Mazzanti 1086. Study of endocytosis between DNA and a cancer cell using laser tweezers. J. Askwith, H. Mao 1087. Thermosensitivity of liposomes of varying DPPC and DSPC lipid composi tions. K. C. Peng, L. A. Tai 1088. Utilizing photodynamic therapy to gen erate oxidative stress in C6 astrocytomas. T. Sirivanta, D. P. Kerrigan, J. Haley, S. Young, J. E. Bradshaw, M. F. Roberto Section Η Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Environmental Chemistry Cosponsored with SOCED, and ENVR A. T. Bennett and J . L. W e s e m a n n , Organizers 2:00-4:00 1089. A kinetic study of hydrolysis of micromolar aqueous FeCl3 using a redox analy sis. S. L. Holbrook, H. Zhang 1090. Activity analyses of extracellular laccase enzymes induced by 2,5-xylidine and Kraft lignin. R. C. McDonald, L. R. Eller 1091. Adsorption of molybdate and tetrathiomolybdate onto solid surfaces in the pres ence of organic molecules. J. L. Morford, C. M. Carney, D. S. Kritzer, P. H. Helman 1092. Analysis of ambient air for Chicago by solid-phase microextraction and gas chromatography/mass spectrometry. F. A. Pierri 1093. Analysis of gasolines with low and high octane ratings by gas chromatography/ mass spectroscopy. D. Smiljanic, J. Coffield, M. J. Baird 1094. Analysis of river and wastewater efflu ent for the presence of estrogenic com pounds. A. L. Black, L. M. Ponton 1095. Analysis of two fluoroquinolone antibiot ics and their environmental photochemical degradation. A. R. Korte, K. H. Wammer
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CHED 1096. Assessing the phosphorus sorption capacity of Mollisol soils using the Langmuir isotherm and single-point sorption index techniques. A. Baune, F. V. Schindler 1097. Assessment of arsenic contamination in soil from pressure-treated wooden decks. F. Walker, M. J. Baird 1098. Automating a kinetic study of the degradation of biodegradable and compostable plastics. J. Klabo, J. Greene, R. M. Miller 1099. Carotenoid extraction of Grateloupia doryphora from Mount Hope Bay, Rhode Island. J. Cherny, S. K. O'Shea 1100. Characterization of monorhamnolipid biosurfactants in aqueous solution and at the air-water interface. J. N. Gremaud, A. Lebron-Paler, J. E. Pemberton, R. M. Maier 1101. Characterization of soil-contaminant interaction measuring retention of contaminants by soil column chromatography. A. M. Copenhaver, C. J. Dunlap 1102. Chemical and biological impacts of migratory birds on small pond ecosystems. J. Johnson, A. E. Marteel-Parrish, K. Verville 1103. Comparing the thermal and microwave assisted syntheses of DABCO ionic liquids. K. Kerr, M. Thomas, J. F. Wishart, S. I. Lall-Ramnarine 1104. Competition between dechlorination and hydrogénation reactions in aquatic chemistry: Effects of pH changes and palladium catalyst sources. C. A. Johnson 1105. Copper(l) complexations and their reaction with nitrite ion. S. Meade, S. K. O'Shea 1106. Cu (II) uptake by engineered poly(/Visopropylacrylamide)-based hydrogels. Κ. Ε. Wagner, Ν. T. Flynn 1107. Deciphering the geochemical history of Lake Waban, Wellesley, Massachusetts. R. M. Erdil, N. T. Flynn, D. J. Brabander 1108. Degradation of persistent organic pollut ants (POPs) by laccases isolated from Ganoderma tsugae. J. D. Matakas, L. R. Eller 1109. Degreaser reduction and the creation of an instrumental procedure to test for hydraulic oil on parts. S. A. Henrie, N. L Eckley 1110. Determination of cadmium complexation in zebrafish {Danio rerio) embryos by NMR. C. D. Ridel, S. K. O'Shea, K. S. Warren 1111. Determining the effects of annual burn ing in a grassland restoration on extractable cations and organic matter. C. A. Prior, L. A. Sherman 1112. Developing new heterogeneous cata lysts for the transesterification of biodiesel. Τ. Κ. Morita, J. W. Gohdes 1113. Distribution of copper on model soil constituents. M. Resto-Roldân, N. Martinez-Villegas Jr., C. E. Martinez 1114. Effect of molecular size on the sorption of hydrophobic compounds with dissolved organic matter. J. W. Freiderich, J. D. Thoemke 1115. Enhancement of zinc-mediated dechlorination by cobalt porphyrin complexes. S. E. Page, A. D. Follett, K. McNeill 1116. Establishing a link between the viscosity and 1H-NMR spectra of weathered ATF. K. Sims, N. Lloyd, S. M. Abemathy 1117. Withdrawn. 1118. Evaluating properties of composts containing biodegradable and compostable materials. D. Nayyar, J. Greene, R. M. Miller 1119. Examining the relationship between the 1H-NMR and viscosity of used engine oil. J. R. Speaks, K. Sims, N. Lloyd, S. M. Abernathy 1120. Formic and acetic acids in Antarctica snow. N. A. Morris, J. Cole-Dai 1121. H 2 Oconee and beyond: Canoeing for middle Georgia's water quality. B. Barfield, D. C. Brooks, K. Harper, L Peaden, S. Rowland, D. Wilson, C. H. Lisse 1122. Influence of compound structure on the sorption of cationic amines to mineral surfaces. A. Carrasquillo, D. Vasudevan 1123. Investigating the occurrence of pharmaceutical and personal care products in wastewater. K. J. Knaup, J. J. Piatt
1124. Investigating the physical properties of 4-dimethylaminopyridine containing ionic liquids. J. Hatcher, M. Thomas, R. Engel, S. I. Lall-Ramnarine, J. F. Wishart 1125. Investigation of the synthesis of 2,4,6,6tetrachloro-2-methylcyclohex-4-ene-1,3dione and its reaction with chloramine. L Sator, V. L Heasley, A. M. Fisher 1126. Isolation and photophysical characterization of pyoverdine compounds from Pseudomonas spp. H. Rim, M. M. Baum, J. A. Moss 1127. Mercury analysis of water and fish in northeast Kansas. C. G'Sell, N. Russo, T. Ruskamp, P. Steinbach 1128. Method development for non-invasive analysis of exogenous substances, such as pesticides using sweat as biological matrix. A. Pizarro Rios 1129. Photocatalytic chemical fixation of C 0 2 using the semiconductor cadmium sulfide. P. W. Wang, M. M. Baum, J. A. Moss, M. R. Hoffmann 1130. Photochemical behavior of enrofloxacin, a fluoroquinolone, in the aqueous environment. R. A. Lundeen, K. H. Wammer 1131. Physical and radiolytic properties of boron-containing ionic liquids. A. Castano, S. I. Lall-Ramnarine, J. F. Wishart 1132. Plant uptake of triclosan. S. E. Schostarez, M. M. Schultz 1133. Predicting competitive adsorption on activated carbon using Mathcad with Ideal Absorption Solution Theory. E. Alkhatib, P. Snetsinger, A. Gauthier, J. DePalma 1134. Preparation and properties of phosphate containing ionic liquids. K. Urena, J. F. Wishart, S. I. Lall-Ramnarine, S. Penkhasova, H. R. Walker, R. Engel 1135. Quantification of photochemically produced hydroxyl radical from chlorinated quinone pesticides. P. P. Vaughan, K. Davis, D. An 1136. Reactions of pentachlororesorcinol with chlorinating agents: Identification of the products. A. M. Ramirez, M. D. Alexander, P. E. Baker, R. H. DeBoard, D. C. Madrid, V. Heasley, J. L. Boemeke, T. L. Hartge 1137. Reducing disinfection byproducts using cyanuric acid: Relative reactivity of hypochlorite ion, hypochlorous acid, monochlorocyanuric acid, and dichlorocyanuric acid with dichlorohydroxybenzoic acid. D. M. Robinson, G. H. Purser 1138. Remediation of As ions using zerovalent Fe nanoparticles. W. Davidson, J. C. Schaumloffel 1139. Remediation potential of a reusable solid-phase adsorbant/absorbant. J. Fiori, J. C. Schaumloffel 1140. Removal of heavy metal ions using cassava skin. L. Akinola, N. Phambu 1141. Removal of trichloroethylene from contaminated water using Ambersorb and Dowex polymeric adsorbents. C. A. Bowers, J. M. Olander, A. C. Nichols, D. A. Steffy 1142. Removal of uranyl ions from aqueous solutions using different adsorbents. A. K. Stone, N. Phambu 1143. Removing arsenic from water using a natural, inexpensive filter. T. M. Nagel, J. T. Ippoliti 1144. Search for medicinal or potentially medicinal alkaloids in the plant family Apocynaceae. J. M. Silverman, K. Marino, S. K. O'Shea 1145. Seasonal variation of nitrate loading into the Long Island Sound from the Housatonic River. J. Reynolds, E. A. Alkhatib 1146. Sequestration and remediation of uranium by electrospun silica-based material. A. J. Salter 1147. Significance of highly toxic secondary emissions from on-road vehicles. J. Stihle, M. Burgoyne, R. Latimer, D. Wanger, A. Webster, J. A. Moss, G. A. Poskrebyshev, M. M. Baum 1148. Silica gel pellet development for water purification by use of titania photocatalyst. P. R. Burkholder, V. Mathew, J. C. DiCesare 1149. Source and extent of sediment contamination in Lake Macatawa. D. G. Tobert, J. Pabon, G. F. Peaslee 1150. Stability study of biodiesel using fourier transform infrared spectroscopy. P. Wetzel, D. Groscost, S. Johnson, B. Humberger, A. Aul, A. Stallard, A. Och, T. James, A. Miller, P. Tran, B. Williams, J. Wedin, A. Clement, K. Schreffler, P. Y. Furlan
1151. Synthesis of redox-labeled atrazine conjugates for an electrochemical immunoassay. A. N. Fields, A. E. Beilstein 1152. The cloud condensation nuclei (CCN) activity of anthropogenic aerosol particles. E. F. Gagne, E. S. Cross, B. Wrobel, P. Davidovits, D. K. Lewis 1153. Total phosphorus determination of select Mollisol soils for use in agricultural non-point source (AGNPS) modeling. J. Voelker, F. V. Schindler 1154. Tracing the bioaccumulation pattern of the heavy metals mercury, cadmium, and arsenic in Narragansett Bay, Rhode Island. S. A. Helming, D. L. Taylor, S. K. O'Shea 1155. Understanding the sources of lead in drinking water. M. L. Praamsma, G. F. Peaslee 1156. Use of soybeans in the phytoremediation of lead-contaminated soil. J. J. Hirner, S. M. Wells, S.' E. Bloch, L A. Kopff, Β. Κ. Kramer 1157. Utilizing soybean and rice hulls as activated carbons to remove heavy metals from contaminated water. A. M. Rizzuti, D. D. Nguyen 1158. Variations in transition metal ion speciation due to differences in dissolved organic matter. R. J. Wienhold, J. D. Thoemke 1159. Vitellogenesis in male fish induced by estrogens in wastewater effluent. L A. Gibbons, E. E. Singer, C. M. Babyak, S. R. Tuberty 1160. Voltammetry of atrazine. P. DeVos, J. H. Brown 1161. Voltammetry of propazine. M. Bruzek, J. H. Brown 1162. Voltammetry of simazine. K. M. Henning, J. H. Brown 1163. Water quality monitoring of local water sheds in rural northeast Texas. E. V. Bonilla, D. M. Encino Section I Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Inorganic Chemistry Cosponsored with SOCED A. T. Bennett and J. L. W e s e m a n n , Organizers 2:00-4:00 1164. Withdrawn. 1165. Energy transfer within a ruthenium doped trisbipyridine zinc crystal. K. M. Gallagher-Gonzales, J. N. Demas, W.Xu 1166. Group 13 complexes of highly fluorinated enaminoketones: Synthesis, struc ture and reactivity. T. E. McCord, J. D. Gordon 1167. Investigation of nickel-bromide com plexes with Siwu. M. J. DeVries, D. A. Vander Griend 1168. Withdrawn. 1169. Synthesis and characterization of a copper(ll) oxime tetranuclear ladder. L. M. Grande 1170. Synthesis and characterization of lowmelting salts: O-carborane anions with N-alkyl pyridinium and Ν,Ν-dialkyl imidazolium. R. E. Wibby, A. S. Larsen, J. Heingardner, K. Brown 1171. Synthesis and spectrophotometric analysis of nanoscale structural motifs. D. K. Bediako, D. A. Vander Griend 1172. Synthesis of cis-[i\5(C5H3)C(CH3)2lr(CO)2]2: A dinuclear iridium complex containing a doubly linked cyclopentadienyl ligand. B. A. Brown, D. M. Chin
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
1173. Synthesis of a novel fullerene-bipyridine ligand for photoelectric applications. J. R. Deye 1174. Synthesis, characterization, and photochemically-directed self-assembly of gold nanoparticles. L. E. Goodrich, R. S. Dibbell, J. Nevins, A. Smith 1175. A comparative study of lanthanide oxythiophosphates to the corresponding orthophosphates. L Slomka, N.J. Takas, J. A. Aitken 1176. A series of ruthenium complexes as fluorescent probes of DNA. C. Gagliardi, C. J. Timpson 1177. Amino acid and fatty acid complexes of Re(CO) 3+ . A. de Grève, A. Cetin, R. S. Herrick, C. J. Ziegler 1178. Ammonia controls facile solid-phase halide exchange at nickel(ll). C. A. Sutton, P. J. Desrochers, M. L. Abrams 1179. Antibiotic functionalized calcium aluminate ceramics as biomaterials. B. F. DiSalle, S. Hott, E. S. Gawalt, K. A. McGowan 1180. Attempted attenuation of mediator leakage in biofuel cell polymer modified electrodes: Synthesis and characterization of a perfluoroalkyl-modified 2,2'-bipyridyl ruthenium complex. P. A. Jelliss, M. Patel, S. D. Minteer, M. Watt 1181. Attempted synthesis of 1,2-diamino-4,5bis(dodecoxy)benzene as a precursor to new metallomesogens. A. Bisch, B. A. Frazier, S. M. Malinak 1182. Withdrawn. 1183. Cadmium (II) and mercury (II) complexes with mixed oxathiacrown ligands. J. Hassler, G. J. Grant, D. E. Janzen 1184. Catalytic oxidation of alkenes by (nitro)cobalt porphyrins on Nation films. D. Kavanagh, J. A. Goodwin, T. S. Kurtikyan 1185. Chemical combinations for curing of marine mussel adhesives. L M. Hight, A. B. Moore, J. J. Wilker 1186. Chemical vapor deposited and template synthesized carbon nanotubes for polymer solar cells. J. L. Young, J. D. Harris, R. P. Raffaelle 1187. Chemistry in ceramic glazes. A. L. Keskey, D. Selter, G. L. Seebach 1188. Chemistry of chromium(V): Biological significance-structure and reactivity of chromium (V)-glutathione complex. S. M. Bernard, S. N. Mahapatro 1189. Chemistry of oxovanadyl(IV) and peroxo-vanadium(V) complexes. M. Sanchez, S. N. Mahapatro 1190. Comparison of a series of Ni(L)2 compounds using new alloxan thiosemicarbazone and semicarbazone ligands. E. C. Lisic, R. Huxford, E. C. Lisic 1191. Competitive binding of albumin and fibrinogen on functionalized amorphous carbon surfaces. S. M. Ahmed, P. Colavita, R. J. Hamers 1192. Continued synthesis of symmetric and asymmetric ligation points for organometallic supramolecular systems. S. M. Goins, J. Kareth, K. A. Walters 1193. Continuous process for the microwave synthesis of manganese oxides. R. R. Mitchell III, S. L. Suib, G. Crundwell 1194. Controlling the metal to olefin bond symmetry by ligand substitution at the metal center. S. A. Matchett, A. Putti 1195. Coordination and extraction of Pb(ll) and Cd(ll) by disulfonamide chelates derived from 3,4-dimethoxyphenylsulfonylchloride and o-phenylenediamine. P. Nunez, N. Salazar, R. J. Alvarado, K. Kavallieratos 1196. Copper(l)-arene interactions in the solid state and in solution using an NS 2 -cyclodecane ligand with different pendant aryl groups. C. Owens, R. R. Conry, M. Kim 1197. Detection of anionic arsenic species by surface enhanced Raman spectroscopy. M. C. Lower, D. H. Johnston 1198. Determination of the catalytic activity of a rhenium bisdithiolene complex as a homogeneous and heterogeneous catalyst for oxygen atom transfer. T. H. Zauche, R. L. Johnson, M. R. Meyer, T. P. Schuldes 1199. Developments in fullerene-transition metal supramolecular systems and molecular wire precursors. C. A. Morris, K. A. Walters 1200. Electronic coupling of metalloporphyrin oligomers. A. Hickman, H. Van Ryswyk, R. J. Cave
TECH-29
CHED 1201. Electrospray mass spectroscopy of transition metal chloride clusters in methanol. J. R. Sutton, G. L Seebach, K. D. Cook 1202. Evidence for DNA modification by a novel water-soluble porphyrin derivative. A. M. Berry, J. E. Bradshaw 1203. Ferrocene based molecular wire candidates: Synthesis and characterization. C. R. de Denus, D. Evers, S. Czajkowski 1204. First tetradentate asymmetrical pyridine N-oxide ligand. A. D. Fry 1205. Further 31-P NMR investigation of heteropolytungstate chemistry in nonpolar solvents. J. Arcadi, M. Makar, M. Kozik 1206. Hydroaminations with alkynes, enynes, and dienes using titanium catalysts. T. D. Palluccio, S. A. Waratuke 1207. In situ spectroscopic studies of a heterogeneous system: Palladium-catalyzed hydrodehalogenation of organohalides. T. J. Dunn, J. Marhenke 1208. Interactions between guanine and metal ions: Infrared and Raman spectra. H. Mumini, N. Phambu, B. Kamara 1209. Interactions of Rh(l) and Rh(lll) cationic complexes with simple monosaccharides. S. M. Lane, S. C. Haefner 1210. Intercalations of organic molecules into clay mimics. A. M. Beatty, A. N. Pickett 1211. Investigation of water soluble copper alkoxides. L. A. M. Ottley, T. J. Boyle, R. M. Sewell, R. Raymond, L. J. Tribby, D. Ingersol 1212. Luminescent lanthanide reporters: Characterization of polymetallic dendrimer complexes. S. J. Johnson, G. Filipcyzk, S. Petoud 1213. Mechanistic studies of reductive dehalogenation catalyzed by cobalamin and related cobalt compounds. M. Z. Corliss, J. Marhenke 1214. Metal boron synthesis and coating of metal substrates. L. E. Wager 1215. Metal ligand stretching frequencies in quinoline complexes. K. L. Shaw, G. L. Seebach 1216. Methylation of (2-(dimethylamino)ethyl)cyclopentadienyl group VI metal carbonyl anions. Z. R. Herm, P. J. Fischer, B. E. Kucera 1217. Mimicking metallo-proteins and enzymes: New aminoalcohol ligands prepared by Mannich condensations. J. A. Niconchuk, C. S. Higham, M. V. Andrews Jr., A. Cetin, C. J. Ziegler, J. R. Farrell 1218. Modeling C-H activation in pincerligated iridium complexes. J. Bush, J. Wardrip, A. Ford, J. Robinson, J. Seyler 1219. Modeling enantioselectivity in the chelate-controlled synthesis of ansa-zirconocenes: How accurate are UFF and DFT methods? R. C. Alter, D. C. Wiser 1220. Modeling the active site of protocatechuate dioxygenase using aminoalcohol ligands prepared from Mannich condensations. M. V. Andrews Jr., C. S. Higham, A. Cetin, C. J. Ziegler, J. R. Farrell 1221. New copper(ll) oxidation catalysts: Toward catalytic metal-organic frameworks. K. P. Schultze, J. J. Bodwin 1222. Nitrosyl bipyridyl rhenacarborane complexes: Synthesis, characterization, and prospective uses. P. A. Jelliss, X. Shi, J. H. Orlando, N. P. Rath, M. J. Shaw 1223. Novel bis(pyrazolyl)propionate ligands as models for histidine and carboxylate residues in metalloenzymes. B. D. Klebon, B. P. Smith, E. T. Papish 1224. Optimization of electroyte-MgO powder composite properties. S. J. Widgeon, E. L. Corral, R. E. Loehman, K. E. Waldrip, M. E. Chavez 1225. Oxidation and complexation of benzamide with transition metal ions. J. D. Kromer, G. L. Seebach
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30-TECH
TECHNICAL PROGRAM 1226. Perfluoroalkylation of arènes using iron reagents. A. Hammad, J. A. Jurewicz, M. P. Clark, G. M. Lang, J. D. Lawrence 1227. Peroxynitrite quenching in the biocompatibility of Nation. M. Sabbagh, J. A. Goodwin, L P. Smith 1228. Photophysical properties of a family of molybdenum halide clusters. N. M. Stephens, K. M. Chenault, M. L. Mohler, D. H. Johnston 1229. Platinum(ll) thiacrown complexes with chiral and achiral diphosphine ligands. E. R. Hassler, G. J. Grant, D. E. Janzen 1230. Polyoxometalates as nanoscale building blocks for the design and preparation of new materials. O. M. Boldt, W. A. Neiwert 1231. Preparation of polyelectrolytes via the copolymerization of ionically-functionalized cyclooctene monomers. J. M. Honnold, D. H. Johnston 1232. Progress toward the synthesis of tugsten, rhenium, and molybedenum bisamido complexes using 1,4-di-tert-butyl1,4-diazabuta-1,3-diene (DAD). L. A. Watson, G. Hettiarachchi, J. Concha Urday Zaa 1233. Progress toward self-assembled platinum(ll) and rhodium(lll) molecular squares. R. D. Naik, G. J. Grant, D. E.Janzen 1234. Reactions of the cyanoborane-semicarbazide adduct with protic solvents. Β. Κ. Johnson, G. M. Edvenson 1235. Recovery of gold from scrap. D. E. Berry, G. L Milligan 1236. Relative basicity of porpholactones. M. King, G. Crundwell, C. Bruckner 1237. Reoxidation of transition metal substi tuted heteropoly blues in nonpolar sol vents. A. Rinaldi, M. Kozik 1238. Reversible proton transfer across a metal-oxide interface: Protonation and proton transfer dynamics of the polyoxotungstate proton cryptate, a-[(H x )W 12 O 40 ] (8 - x) - (x=2,3). C R. Sprangers, D. C. Duncan 1239. Rhenium and tungsten oxo and imido complexes with N-heterocyclic carbenes. L. A. Watson, F. Gray, E. Yoder 1240. Rhenium carbonyl compounds with polypyridyl ligands. C. Aquina, C. J. Ziegler, R. S. Herrick, A. Cetin, D. L. Jameson 1241. Selective ligand design and coordina tion for uranium extraction. J . Z. Vilseck, T. H. Bray, A. E. V. Gorden 1242. Shape changing polymers. L. A. Fredin 1243. Solid-state and polyol microwave syn thesis of bulk and nanocrystalline group 15 chalcogenides. C Mastrovito, J. A. Aitken 1244. Spectral and crystallographic studies of seven-coordinated complexes. J. H. Davis, A. E. McBride, M. Bond 1245. Structural and spectroscopic studies on copper(ll) complexes containing sterically demanding carboxylate and aromatic imine ligands. T. J. Smith, K. L. Brodsky, J. C. McClellan, K. M. Schultz, P. E. Fanwick 1246. Surface plasmon resonance studies: A step toward understanding protein-solid interactions. H. Pehratovic, A. Bhambhani, C. V. Kumar 1247. Syntheses of unprecedented low-valent titanium species. E. D. Smolensky, J.E.Ellis, R.Jilek 1248. Synthesis and characterization of {[Co 2 (1,3-ADC) 2 (4,4'-bipy) 4 (N0 3 ) 2 ]*MeOH}n. C Baker, M. Midence, C. V. Gauthier 1249. Synthesis and characterization of a highly fluxional cyano molybdenum dioxolene complex. B. W. Zeiger, M. Wicholas, M. Gleaves 1250. Synthesis and characterization of a mixed valence dinuclear nickel (ll/lll) complex with bis^ 2 -sulfido bridges. B. F. Moore, M. J. Prushan, M. Zeller, A. D. Hunter, S. Lof land 1251. Synthesis and characterization of a novel water-soluble gallium(lll) porphyrin. R. J. Hickerson, J. E. Bradshaw 1252. Synthesis and characterization of a series of new phenanthrenequinone thiosemicarbazone palladium complexes. R. Huxford, E. C. Lisic 1253. Synthesis and characterization of alumi num phosphate nanobuilding-block clus ters. M. C Silva
1254. Synthesis and characterization of chemical analogs of nitrile hydratase: Initial steps in design of a functionalized metalorganic framework. J. J. Smith, J. J. Bodwin 1255. Synthesis and characterization of lumi nescent orthometallated iridium(lll) polypyridine complexes. L. M. Hinkle, K. A. McGee, K. R. Mann 1256. Synthesis and characterization of new chemical precursors for p-type metal oxide semiconductors. J. S. Hyslop, J. L. Young, J. D. Harris, B. J. Frost 1257. Synthesis and characterization of potential carbon dioxide reducing cata lysts. L. Drennan, D. Avondoglio, E. W. Goldman 1258. Synthesis and characterization, with X-ray crystal structure, of Co(acac) 2 (HMTA) 2 . N. A. LaFranzo, P. J. Morrison, Ε. Β. Flint, G. M. Ferrence, M. Zeller 1259. Synthesis and conductivity of organosilicon-based electrolytes for energy storage applications. R. R. Butorac, L. Zhang, R. West 1260. Synthesis and electrochemical studies of homo- and hetero-leptic terpyridine complexes. C. R. de Denus, D. Evers, S. Czajkowski 1261. Synthesis and reactivity of ^ - s y m m e t ric ansa-ytterbocene(ll) complexes derived from the reductive coupling of 1,3,6-trisubstituted fulvenes. A. J . Peloquin, R. L. Stone, S. E. Stampher, J. E. B. Johnson, G. J. Balaich 1262. Synthesis and structural characteriza tion of uranyl complexes containing ferrocene-1,1'-dicarboxylate. P. M. Vogel, R. Sykora 1263. Synthesis and study of a mixed-metal cluster complex. L. F. Szczepura, J. R. Long, H. R. Bowen 1264. Synthesis and study of pyrrole-metallocene as anion receptors and sensors. L. L. Pham, A. Gebauer 1265. Synthesis of a new isocyanide ligand for efficient photo-induced charge transfer processes within an octahedral W(0) compound. R. A. Seger, K. A. Walters 1266. Synthesis of a novel uranyl peroxide material using organic templating agents. J. G. McAlpin, T. Z. Forbes, P. C. Burns 1267. Synthesis of a novel zinc compound for use in molecularly imprinted polymer based catalysis. C T. Gutman, J. W. Gohdes 1268. Synthesis of a ruthenium polypyridyl complex for kinetics studies. J. L. Achtyl, S. Glazier 1269. Synthesis of an isolable and monomeric phosphorus radical that is resonancestabilized by the vanadium(lV/V) redox couple. P. Agarwal, N. A. Piro, K. Meyer, P. Mueller, C. C. Cummins 1270. Synthesis of bi-azulenic pi-bridges for applications in novel charge transport materials. M. V. Barybin, T. R. Maher, C. L. Berrie, A. D. Spaeth 1271. Synthesis of bis(pentachlorocyclopentadienyl)zirconium dichloride. D. G. McGuire, C. Bryan, K. Beacham, J. Wilson, M. Landoll 1272. Synthesis of C 2 -symmetric chiral tetra dentate ligands and complexation reac tions with group 6 carbonyls. J. M. Keane, P. K. B. Palomaki, J. A. Rubin, J. E. Saunders, S. A. Burgess, D. B. Perlow, B. W. Nash, S. V. Scarselletta, R. D. Pike 1273. Synthesis of electro-active PNA oligom ers for electron transfer studies. P. Lund, R. M. Watson, C. Achim, A. Paul, D. Waldeck 1274. Synthesis of inorganic materials using pyridine/thiophene hybrid ligands. R. T. Pennell, D. P. Lavoie, J. L Shaw, C. J. Ziegler, J. R. Farrell 1275. Synthesis of new bridging phenanthroline ligands. D. Orner, D. K. Geiger 1276. Synthesis of polyurethane matrices for polydiacetylene strain sensors. C Pollock, J. Kauffman, W. Pennington, T. Hanks 1277. Synthesis of ruthenium complex with bipyridine ligands featuring aromatic side chains for use in DNA binding. S. R. Walter, S. Glazier 1278. Synthesis of solvated cationic osmium complexes using halide abstraction. I. T. Sines, S. C. Haefner
1279. Synthesis of the methylcyanoborohydride anion. A. L. Goraczkowski, G. M. Edvenson 1280. Synthesis of [16-(2-Hydroxy-benzoyl)2,3,11,12-tetramethyl-5,14-dihydro5,9,14,18-tetraaza-dibenzo[a,h]cyclotetradecene-7-yl]-(2-hydroxy-phenyl)methanone and its metal complexes. P. Goodman, J. O'Brien, R. Miller 1281. Synthesis, characterization, and photochemically-directed self-assembly of Au nanoparticles. L. E. Goodrich, A. Smith, J. Nevins, R. S. Dibbell, D. F. Watson 1282. Synthetic investigation into a doublylinked permethylated cyclopentadienyl ligand. N. D. AI I worth, R. Schwenker, M. J. Parr 1283. The study of hypercoordination using Ge-73 NMR. C. H. Yoder, T. M. Agee 1284. Thermal decomposition of In(lll) dithiocarbamates: A combined GC/MS and TGA study. M. I. Perera, A. F. Hepp, M. J. Baird, S. M. Brothers, E. M. Schierloh, N. V. Duffy 1285. Thermogravimetric analysis studies of iron(lll) dithiocarbamates. M. J. Jose, M. J. Baird, A. F. Hepp, N. V. Duffy 1286. Toward coordination of various transi tion metals to [18] annulene trisulfide. C C Kimme, M. E. Long, D. K. Howell 1287. Toward the synthesis of rhenium imido complexes using 1, 3-diaminobenzene. L. A. Watson, P. D. Durand, L. Giles 1288. Transition metal catalysts for environ mentally benign oxidation of organic sub strates by N 2 0 . J. Erler, D. Foster, M. Fujita 1289. Transition metal complexes of bis (2-ethylpyridyl)hydroxylamine. C W. Belock, A. Cetin, C. J. Ziegler 1290. Transition metal directed supramolecular assemblies: Double helicates. D. A. Habboush, L. Farber, C. M. Aiuto, J. R. Boy, T. O. Lescouflair 1291. Visible spectroscopic study of nitroben zene binding to transition metals: A mimic for possible rohypnol-metal interaction. S. M. Bailey, D. W. Carpenetti II 1292. X-ray absorption and density functional study of the anticancer drug NAMI-A and related compounds. T. V. Harris, K. L. McFarlane Holman, R. K. Szilagyi 1293. Zinc(ll) complexes of pyridyl-substituted mono- and bis(guanidine) ligands. L R. Whiteaker, U. Pal Chaudhuri, R. P. Houser 1294. Aerobic oxidation of benzylamine with poly(oximate)amine Ni(ll) catalysts. S. A. Bragg, E. A. Deters, H. S. Hehemann, J. A. Krause, M. J. Baldwin 1295. Aerobic oxidation of tetrahydrofuran assisted by varied iron (III) chloro-POSS compounds. D. Pettner, M. T. Hay 1296. Oxidative coupling and cluster growth and fragmentation in the highly fluxional platinum derivatives of Sn 9 . Synthesis, characterization and solution dynamics of Pt 2 @Sn 1 7 4 - and Pt@Sn 9 H 3 \ B. Kesanli, J. E. Halsig, P. Y. Zavalij, J. Fettinger, Y-F. Lam, B. W. Eichhorn 1297. Oxidative damage associated with the treatment for iron overload. B. W. Alderman, J. I. Wirgau 1298. Synthesis of cyclic metal bonded olefin to be used in ring opening metathesis polymerization. A. E. Mack 1299. X-Ray crystallographic structure deter mination of Ua{H 2 AI(OC 2 H 4 OMe) 2 } (dmpe) 2 ] 2 . M. E. Carroll, B. M. Foxman Section J Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Medicinal Cosponsored with SOCED, and MEDI A. T. Bennett and J . L. W e s e m a n n , Organizers 2:00-4:00 1300. Dioicine, a novel alkaloid from the Kentucky coffeetree, Gymnocladus dioicus. R. R. Chase, R. W. Fitch 1301. DNA cleavage induced by photoactivated daunomycin and the role of reactive oxygen species. R. Kainthla, M. Zewail-Foote
CHED 1302. Docking studies of the binding mode of dictyostatin and its analogs to the taxoid binding site on β-tubulin. C. B. Hackmeyer, B. W. Day 1303. Energetic analysis of base-pair stability and DNA decamers containing 7,8-dihydro-8-oxoguanine. T. Steele, C. A. Parish, M. Hamm 1304. Extraction and identification of formononetin from black cohosh (Actaea racemosa) utilizing gas-chromatography coupled mass-spectroscopy and ultraviolet detection of high performance thin layer chromatography. E. D. Freeburg, L. Nopo-Olazabal, R. Hannigan, F. Medina-Bolivar 1305. In silico study of Plasmodium falcipa rum proteases Plasmepsin II and IV: Prediction of biological activity of newly designed inhibitors. C. B. Abdul-Wahid, S. Abdul-Wahid, L. Fabry-Asztalos, R. Andonie 1306. Industrial-scale extraction of Taxol® from the soil around Taxus χ media Hicksii. E. J. Davis, D. T. Vo, A. Hoffman 1307. Withdrawn. 1308. Investigation of the effect that different drying methods have on the mechanism of theophylline release from microcrystalline cellulose beads (part III). F. C. Mayville Jr., R. Swoyer, A. Bollinger 1309. Long-term evaluation of nodular and ring enhancing lesion evolution in patients with multiple sclerosis. M. L. Davis, F. Bagnato 1310. Methylation of estrogen receptor-beta promoter ON CpG sites in LNCaP cells. J. B. Elston, X. Zhang, Y-K. Leung, S-M. Ho 1311. Molecular dynamics analysis of poten tial inhibitors of HIV-1 protease. G. Springsted, C. A. Parish 1312. Photochemistry of L-phenylalanine for use in photodynamic therapy. J. Weekes, S. Cooper, R. Hammond, K. LaiHing 1313. Progress on the synthesis and evalua tion of lipid-lowering effects of novel pyr roles. M. Melendez, B. S. Burnham 1314. Progress toward the synthesis of pyrimidodiazepine-based folates as poten tial inhibitors of glycinamide ribonucleotide formyltransferase. J. Lanham, Μ. Μ. Frick, Z. Chinoy, P. S. Ray 1315. Pyrazoline analogs of Combretastatin A-4: Synthesis, biological evaluation and tubulin inhibition. B. Younglove, L. Lee, H. Mackay, S. L. Mooberry, P. Hills, T. Brown, M. Lee 1316. Screening for marine natural products that inhibit the LARG/RhoA signaling pathway. Μ. Ε. Rivera-Quinones, C. Evelyn, R. Neubig, J. C. Carlson, D. H. Sherman 1317. Structure-activity study of the N-terminal histidine of GLP-1. L. W. Marinelli, T. N. Lenton, K. A. Lipford, D. R. Haines 1318. Sustained release of the antimalarial Artemether via polymer coating of drug particles. I. R. Hajjali, M. M. Baum, T. J. Smith 1319. Synthesis and antimicrobial activity of skeletally modified alpha pinene deriva tives. P. Dhar, T. Snyder-Leiby, D. T. Cohen, P. Y. Chan 1320. Synthesis and evaluation of novel hydroquinone analogs as inhibitors of the sarco/endoplasmic reticulum calcium ATPase. M. Versluis, M. Lape, C. Elam, R. Kempton, S. Paula 1321. Synthesis of growth hormone releasing hormone analogs. J. D. Houck, H. M. Geysen, C. Gineste, L. Willingham 1322. Synthesis of novel borinic acids as potential HIV-1 protease inhibitors. Y.'Jia, T. S. Heer, D. V. Nguyen, T. K. O'Connell, L. Fabry-Asztalos 1323. Synthesis of novel polyamide acids as intermediates for anticancer compounds. P. Nolan, K. Mulder, J. Martinez, T. Smith, T. Brown, M. Lee 1324. Toward synthesis of para-alkyl substi tuted alcohols as conformationally con strained fatty alcohols. F. J . Nau Jr., A. Parrill 1325. Characterization of DNA damage formed upon photoactivation of daunomycin. P. Kainthla, R. Kainthla, M. Zewail-Foote 1326. Chemical analysis of medicinal plants used in the treatment of type II diabetes. R. O. Flores, A. R. Chaudhuri, Ε. Ε. Gonzalez
1327. Chemical probes as tools for studying Parkinson's disease. S. A. Hubers, J. D. Hulleman, K. L. Taylor, J-C. Rochet 1328. Concentration and counterion effects on Ac-FRWWHR-NH 2 peptide antimicrobial activity in non-buffered systems. A. R. Alam, J. W. Chan, D. A. Wicks 1329. Conformational analysis of HIV-1 prote ase inhibitors. J. Brown, C. A. Parish 1330. Conformational variations of Kedarcidin and Neocarzinstatin. L. Folgosa, C. A. Parish 1331. Cursory comparison of chemical com ponents in medicinal plants possessing renal activity. A. M. Cavazos, D. L. Kramer, A. J. Obregon, J. E. Gomez, R. O. Flores, A. R. Chaudhuri, Ε. Ε. Gonzalez 1332. Design and synthesis of template competitive reverse transcriptase inhibi tors. T. Lin, M. B. Doughty 1333. Development of a branched chiral selector stationary phase with vancomycin termini. S. A. Henrie, W. H. Stepp 1334. Development of cellular tolerance to racemic buprenorphine. C. V. Subban, M. Wallisch, G. D. Olsen 1335. Effects of oxygenated zinc dialkyldithiocarbamate complexes on glyceraldehyde3-phosphate dehydrogenase (GAPDH): A model system for the elucidation of the mechanism of novel anticancer agents. L. C. Tallorin, N. Franco, T. Miller, B. Lopez, P. Farmer, J. Fukuto 1336. lmidazole-4,5-dicarboxylic acid libraries: Anilines and primary amine substituents. K. Lawson, J. C. DiCesare, P. W. Baures 1337. lmidazole-4,5-dicarboxylic acid libraries: Anilines and secondary amine substitu ents. J. Hinshaw, J. C. DiCesare, P. W. Baures 1338. Inhibition of β-N-acetylglucosaminidase by substituted septanose triazoles. E. Cherney, S. Castro, M. W. Peczuh 1339. Inhibition of nucleic acid polymerases: Template-competitive transcriptase inhibi tors. S. Harris, M. B. Doughty 1341. Peptide mimicry of carbohydrate anti gens. A. Massey, M. D. Perry Jr., T. Kieber-Emmons 1342. Peptide mimicry of carbohydrates on cancer-fighting antibodies. T. C. Ransom, M. D. Perry Jr., T. Kieber-Emmons 1343. Predicting binding interactions of ring substrates with CYP2E1 using homology modeling. R. M. Laddusaw, M.D.Perry Jr., G.P.Miller 1344. Preliminary investigation into the syn thesis of stable-isotope labeled gabapentin. D. J. Swartling, K. S. Taylor 1345. Qualitative chemical analysis of amphipterygium adstringens (Cuachalalate) from Mexico. J. E. Gomez, A. R. Chaudhuri, Ε. Ε. Gonzalez 1346. In silico drug evaluation utilizing FDA consumer drug information files. M. J. D'Souza, F. Koyoshi 1347. A study of the flexibility of Calicheamicin A1 and Esperamicin A 1 . L. Sinanan, C. A. Parish 1348. Alkaloids of Packera glabella. M. A. Miller, R. W. Fitch 1349. Anti-androgen activity of natural product "bizzy" in prostate cancer cells. L. Debose, K. Fontenot, S. Koppula, R. Solipuram, A. Hurst, W. Gray 1350. Assessing protein changes in hypertro phic mouse hearts. K. L. Abels, A. N. Reese, S. A. McDowell 1351. Bioactive constituents from cocoa powder protect cells from toxicity associ ated with mutant polyglutamine expansion. M. J. Czapla, R. B. Williams, W. R. Gutekunst, P. M. Joyner, R. H. Cichewicz 1352. Bypassing β2 adrenergic receptor in isoproterenol desensitized airway smooth muscle with forskolin. J. Hill, C. Pate, S. M. Jones, R. C. Kurten 1353. Characterization of bizzy nut extracts in estrogen responsive MCF-7 breast cancer cells. K. Fontenot, W. Gray, S. Naragoni, M. Claville 1354. 2,2'-Bithiophene-5,5'-dicarbaldehyde: Synthesis and mechanistic evaluation of generating guanine adducts. D. R. Quirk Dorr, J. P. Freund 1355.1H NMR examination of a series of 5-substituted isatin thiosemicarbazone and semicarbazone compounds. M. D. Stone, K. Monteen, K. B. Ford, T. Mathis, E. C. Lisic
Section Κ Hyatt Regency Chicago Riverside Center Undergraduate Research Poster Session: Physical Chemistry Cosponsored with SOCED, and PHYS A. T. Bennett and J. L. W e s e m a n n , Organizers 2:00-4:00 1356. Absolute pKa values: An exercise in physical chemistry. D. Gôtz, B. Tlach, P-P. Ilich 1357. 1 3 C solid state nuclear magnetic resonance (NMR), a powerful analytical tool for photochemical reactions in zeolites. T. T. Nguyen, A. M. Amboya, S. M. Baylon, H. Huynh 1358. A density functional theory study of the gas and condensed phase behavior of donor-acceptor complexes of sulfur dioxide. P. Gorczynski, J. M. Standard 1359. A stochastic approach to elucidating glioblastoma expansion. B. M. Rubenstein, L. J. Kaufman 1360. A systematic study of structure and physical properties of smectogenic 2,7fluorenes. A. A. Pribram-Jones, R. N. Harris, G. R. Van Hecke 1361. Ab initio investigation of the interaction of sulfur trioxide with hydrogen halides. M. C. Cafarelli, J. M. Standard 1362. Adsorption of sarin on α-alumina sur faces. R. Terrio, M. J. Dorko 1363. Allegheny energy: Coal and oil in Greensburg. A. M. Kiral 1364. An inexpensive Raman modular spec trometer for solids. P. N. Larsen, D. Johnson, S. Schaertel 1365. Analysis of a Keggin polyoxometalate on various oxide surfaces. J. Bean, K. Pontarelli, C. M. Teague 1366. Anthrax toxins: Modes of infection and release of the tripartite toxin into the body. M. R. Lacina, A. Loccisano, J. D. Evanseck 1367. Application of Pitzer formalism for thermodynamics of HBr + NdBr 3 + H 2 0 system from 5 to 55°C. L. N. Roy, R. N. Roy, S. Ashkenazi, J. A. Larbey 1368. Attenuated total reflection infrared spectroscopy of ice films. G. M. Riggio, R. R. Michelsen 1369. Bergman, Meyers-Saito and Schmittel cyclization of pyridinium skipped azaenediyne analogs analyzed by DFT method. M. A. Brozier, J. F. Capitani 1370. Calculation of excited vibrational states from quartic potential energy surfaces. J. L. Davisson, N. R. Brinkmann, W. F. Polik 1371. Calculation of melting point of gold by free energy calculations. S. M. King, V. B. Warshavsky, X. Song 1372. Characterization of carbonate environ ments in carbonate apatite. A. Kozlowski, H. Mason, B. L. Phillips 1373. Characterization of silica-based aero gels: Surface area, pore size distribution and infrared spectra. A. E. Reeve, M. K. Carroll, D. C. Korim, A. M. Anderson 1374. Chemical-shift anisotropy measure ments in organic solid-phase materials. R. J. luliucci, C. L. Hoop, C. L. Becker 1375. Computational studies of a series of 1 -phenyl isatin thiosemicarbazone and semicarbazone compounds. Κ. Β. Ford, S. H. Northrup 1376. Computational studies of the interaction between ethers and singlet carbenes in the gas phase and in solution. R. D. Quinn, J. M. Standard 1377. Computational study of methane to methanol conversion on metal oxide clusters. S. M. Braun, A. Arnold, E. D. Glendening 1378. Computational study of the keto/enol equilibrium and enol-a/enol-b equilibrium of trifluormethyl-beta-diketones( R1COCH 2 COR2) with R2 = -CF 3 using semi-empirical method AM1. M. M. Coronado, J. G. Estevez, T. M. Pacheco, V. M. Ramos, S. M. Velez 1379. Computational study of the keto/enol equilibrium in 2-fluoro-beta-diketones, (R1COCHFCOR2) with R= -CH3, using semi-empirical method AM1. M. Perez, S. M. Velez, Z. Alvarado, J. G. Estevez
1380. Computational study to construct mim ics of helical domains in proteins. M. E. Messick, C. K. Wilson, E. A. Woods, E. Csuhai, A. C. Goren 1381. Computer simulations of the kinetics of autocatalytic aggregation of 1,1 '-diethyl3,3'bis(sylfopropyl)-5,5'6,6'-tetrachlorobenzimiadcarbocyanine in water. I. Pazos, I. A. Struganova 1382. Constructing a green alternative to a traditional physical chemistry experiment, the moderate-resolution infrared spectra of carbon dioxide: Analysis of weak absorp tion bands. C. M. Clark, C. R. Braden 1383. Convection roll properties in 3-D vibrofluidized granular systems. N. Petkovich, J. Talbot 1384. Coulombic model of the anomalous conformations of chlorinated acetates. T. A. Barnes, P. J. MacDougall 1385. Deactivation kinetics for the dehydrogenation of cyclohexane and the isomerization of η-octane. A. J. Zoelle, M. J. Baird 1386. Density functional calculations of low temperature CO oxidation on Au(111). N. S. Froemming, G. Henkelman 1387. Describing electronic states in UVinduced excitation of adenine. C. E. Schlosberg 1388. Determination of biologically relevant binary lyotropic liquid crystalline phase diagrams formed by alkyl-glucosides in water. J. R. McDonough, W. C. Duim, K. K. Karukstis, G. R. Van Hecke 1389. Determination of rotational dynamics at the air/ D 2 0 interface by time resolved second harmonic generation. K. Brown, K. B. Eisenthal, E. McArthur 1390. Development and implementation of a frequency-domain fluorescence lifetime instrument using lasers and light-emitting diodes, suitable for an undergraduate institution. A. J. Poncheri, S. Basu 1391. DFT calculations on intramolecular hydrogen bond energies. K. W. Elliott, D. W. Brown, M. Lewis, R. Hansen, W. Richards, J. N. Woodford 1392. Dispersed fluorescence spectroscopy of formaldehyde in a free-jet expansion. K. K. Ellsworth, B. D. Lajiness, W. F. Polik 1393. Displacement of weakly coordinated solvent molecules from transition metal centers. A. A. Bengali, L. Bahorich, A. Grunbeck 1394. Effect of co-solvents on the rate of nucleophilic displacement reaction in a tri-phase catalytic system using modified clay. N. Shabestary, E. Beverlin 1395. Effect of substituents on secondary deuterium isotope effects in the solvolysis of aryl diazonium salts. R. Benning Jr., L. Black, R. Lefkowitz, G. McSurdy, J. E. Sheats 1396. Effect of temperature on photoinduced double proton transfer in the excited state of double hydrogen bonded dimmers of 7-azaindole. N. Shabestary, A. L. Hustedt, D. N. Reed 1397. Electrochemical performance of cobalt and aluminum doped lithium manganese oxide spinel cathode materials. N. Slade, L Kullberg 1398. Electrochemistry and ESR analysis of pristine Y 3 N@C 8 0 and its [6,6] monoadduct derivatives. L. Z. Lugo-Morales, C. Cardona, J. Rivera, L. Echegoyen 1399. Electron transfer in mixed-valence systems: Effects of strong vibronic cou pling. C. C. Ralph, D. G. Evans 1400. Electronic structure studies of a clockreconstructed Al/Pd(100) surface alloy. J. E. Kirsch, C. J. Tainter 1401. Emission spectroscopy of tetraacenaphthoporphyrins. Β. Μ. Bennett, D. L. Cedeho 1402. Encapsulation of fluorescent polymers by cowpea chlorotic mottle virus. J . Lin, W. Molenkamp, B. Ng, S. Tolbert
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-31
CHED 1403. Withdrawn. 1404. Excess thermodynamic functions of alcohol + n-alkane mixtures using viscometry, dilatometry, refractometry, and laser light scattering. M. Jang, C. L. Kalcic, G. R. Van Hecke 1405. Foam stability under pressurized condi tions. C. R. Tryon, R. Ahmed, N. Takach 1406. Formation of ion pairs in cubic arrays. L. A. Schipper, R. L. DeKock 1407. Ground and excited state acidity con stants of indole derivatives. N. Shabestary, D. N. Reed, A. L. Hustedt 1408. Hydrogen bonding to Coumarin-102 in ground and electronically excited states. K. J. Grove, R. A. King 1409. Hydrogen/deuterium exchange of small peptides containing aspartic acid. S. M. Knapp, E. M. Marzluff 1410. Identification of diastereomeric interac tions in zeolites by solid state Nuclear Magnetic Resonance (NMR). H. T. Huynh, M. Park, D. Cizmeciyan 1411. Improvements in a tunable diode laser spectrometer to measure 1 3 C/ 12 C isotope ratios in carbon dioxide. B. L. Brethauer, G. C. McBane, S. A. Schaertel 1412. Increase of permeability in lipid vesicles caused by antimicrobial peptide Protegrin-1. T. A. Siaw, K. L H. Lam, Y. Ishitsuka, A. J. Waring, R. I. Lehrer, K. Y. C. Lee 1413. Infrared optical constants of crystalline and amorphous water ice. M. C. Hooper, J. E. Boulter 1414. Inquiry-based exercises in physical chemistry. M. Boyle, K. White, T. Barstis 1415. Insertion of merocyanine dyes into Silicalite-1 hosts. C. Sheldon, J. S. Holt 1416. Internship at OMNOVA Solutions Inc. J. L. Keith 1417. Investigation of reaction kinetics by 1 H and 2 H NMR Spectroscopy: The kinetics of decompoosition of 2,2'-azo-bis-isobutryonitrile and dimethyl-2-cyano-2-propylketenimine. J. Hilton, T. O'Connor, D. Agins, J. E. Sheats, A. Grushow, I. Pelczer 1418. Investigation of single molecule charge transfer. J. M. Tyler, M. L. Blumenfeld, O. L. A. Monti 1419. Kinetics and mechanism of the reaction of glucose oxidase with a surface tethered N-hydroxysuccinimide ester using SPR. A. R. Bolger, A. A. Deckert 1420. Liquid junction potential and single ion activity coefficient for pH standard buffer TAPSO from 5 to 55°C using Pitzer model and Bates-Guggenheim convention. S. R. LeNoue, C. E. Denton, D. A. Kaufmann, W. D. Bair, L. N. Roy, R. N. Roy 1421. Low-energy electron-induced oligomerization of condensed carbon Tetrachloride. L. D. Weeks, L Zhu, M. Pellon, D. R. Haines, C. R. Arumainayagam 1422. Magnetic resonance study on C-N amide bond rotational barriers. R. B. Lefkowitz, E. J. Choi, A. Grushow 1423. Measurement of the protonation enthalpy of ethanol by variable tempera ture NMR spectroscopy. Κ. Μ. Vernier, R. R. Michelsen 1424. Metal complexation, adsorption onto titanium dioxide and irradiation studies of ethylenediaminetetraacetic acid. C. A. Pitters, E. D. Rames, C. B. Vidican, J. M. Shafer, H-Y. Chen, K. C. Lanigan 1425. Molecular dynamics vs. Monte Carlo: The effects of constant temperature or constant energy on computer simulations of liquid clusters. J . P. Strey, B. G. Moore 1426. Molecular dynamics: A study of density, potential energy, and atom plucking. J. D. Coppock, B. G. Moore 1427. Molecular motions of acetophenone and cyclohexane co-adsorbed in zeolite NaY investigated by solid-state deuterium Nuclear Magnetic Resonance (NMR). S. M. Baylon, A. M. Amboya, T. T. Nguyen, H. Huyn 1428. Particle size of beta amyloid peptide aggregates using dynamic light scattering. K. Centrella, J. Roeklein-Canfield, D. B. Gray, P. Johnson 1429. Photophysical behavior of sunscreen active ingredients: A combined computa tional and spectroscopic study. B. M. Baughman, D. S. Schmidtke
32-TECH
TECHNICAL PROGRAM 1430. Photophysics of cinnamic acid deriva tives. A. F. Fidler, C. Bieler 1431. Polycyclic aromatic hydrocarbon mono layers on gold: Preparation and molecularscale characterization. A. Becker, P. W. Young, S. A. Kandel 1432. Polyoxometalate based composite materials: Structure and interaction. J. Valenstein, M. Tuetken, A. Hauser, C. M. Teague 1433. Praparation, functionalization, charac terization of carbon nanoonions. M. Rivera-De Leon, F. Melin, A. Palkar, L. Echegoyen 1434. Proton-coupled electron transfer kinet ics in tyrosine D of photosystem II. A. Y. Evans, D. L. Jenson, B. A. Barry 1435. Quasiclassical trajectories and the H + CH 4 reaction threshold. J. C. Shearouse, Z. Xie, K. M. Christoffel, J. M. Bowman 1436. Raman and surface enhanced raman spectra of flavone and several hydroxy derivatives. C. Corredor, T. Teslova 1437. Remediation of arsenic from drinking water. L. R. Condon, J. M. Van Doren, J. F. Hauri Jr. 1438. Resonance Raman spectrum of thiirane. K. A. Kane, M. R. Wedlock 1439. Search for organometallic complexes with bishomoaromatic ligands. M. D. Kelly, A. C. Goren 1440. Seeking the most stable isomer of C 1 8 N 1 2 . M.J. Parker, A. Kus, G. Schoendorff, M. Vaziri, J. Song 1441. Simple model for time-dependent vibrational relaxation using MathCad software. K. D. Shah, R. Nanda, T. W. Marin 1442. Solid acid fuel cells. K. D. Eleamos, S. J. Gravelle 1443. Solid state Nuclear Magnetic Reso nance (NMR) as a molecular level probe for the photochemical reaction of cyclohex ane and acetophenone in zeolite Y. A. M. Amboya, T. T. Nguyen, H. Huyn, D. Cizmeciyan 1444. Stability of trisilanolphenyl-POSS on pH buffered subphases. S. M. Huffer, Κ. J. Dawson, J. Deng, A. R. Esker 1445. Storage and generation of H 2 gas from hydrocarbons adsorbed on Pt/Mg alloy surfaces. C. Sandquist, M. J. Dorko 1446. Storage of methane gas in propane hydrate. Y. L. Cazares 1447. Structure and organization of alcohol monolayers at the air-water interface. D. D. Mago, S. Z. Can, R. A. Walker 1448. Substituent effects on O-H stretching bands in substituted phenols. D. Chiluvuri, J. D. Lewis 1449. Supported metal catalysts derived from RF non-thermal plasma for hydrogénation reaction. D. M. Encino, E. V. Bonilla 1450. Surface enhanced photochemistry of p-nitrobenzoic acid on mixed silver-gold nanoparticles. F. Shi, D. B. D. Gilbert, R. K. Kaneta 1451. Surface enhanced Raman spectroscopy using colloidal gold nanoparticle aggregates. C. I. Bingham, P. H. Davis 1452. Withdrawn. 1453. Surface-enhanced Raman scattering of />nitrobenzoic acid on Ag-coated Au nanoparticle slides. R. K. Kaneta, D. B. D. Gilbert, F. Shi 1454. Surface-enhanced Raman spectroscopy in relation to enzyme kinetics. G. E. Turner, J. M. Nichols 1455. Surface-enhanced Raman spectroscopy of kojic acid on colloidal silver. C. D. Deane, B. D. Gilbert 1456. Synthesis of gold nanoparticle aggregates for use as SERS microscopy substrates. C. P. Morrisey, P. H. Davis 1457. Tetraalkylphosphonium ionic liquid dyes. R. I. Garrett, M. Williams, J. S. Wilkes 1458. The characterization of asphaltenes derived from air blown asphalt using diffuse reflectance spectroscopy. C. B. Seevers, J. Hardee Jr. 1459. Theoretical and spectroscopic studies of nitrogen containing bases. E. Hohenstein, J. Johnson, J. Locker 1460. Theoretical investigations on two arginase inhibitors. C. Burrell, C. A. Deakyne, J. Song 1461. Theoretical modeling of biologically and environmentally relevant organic molecules for X-ray absorption studies. A-K. Witt, D. C. Edwards
1462. Theoretical studies of the electronic coupling element for electron transfer in a variety of metalloporphyrin systems. J. A. Kouzelos, H. Van Ryswyk 1463. Thermodynamics of HBr + PrBr3 + H 2 0 from 5 to 55°C. C. N. Roy, S. Ashkenazi, L N. Roy, R. N. Roy 1464. Thermodynamics of HCI + TbCI 3 + H 2 0 system from 5 to 55°C. S. Ashkenazi, A. Bwashi, L. N. Roy, R. N. Roy 1465. Transient absorption spectroscopy for photoinduced electron transfer processes of pyrromethene 546. N. C. Brandt, J. M. Brom 1466. Ultrasensitive chiral measurement of small molecules by second harmonic generation. D. J. Kissick 1467. Up-converted fluorescence kinetics from [Ru(dmb) 3 ] 2+ / 9,10-diphenylanthracene solutions. M. A. Phimister, J. C. Williamson 1468. Using NMR spectroscopy to probe the motional dynamics of chiral molecules bound to molecular micelles. K. D. Pedersen, K. F. Morris 1469. Vector correlation in the photodissociation of o-nitrosotoluene. C. A. Kent 1470. X-ray crystal structures of erbB2 Tyrosine Kinase Inhibitors (TKIs). P. Tran, N. Zhu, C. L. K. Stevens 1471. Infrared-ultraviolet photoionization and photoelectron spectroscopy of group 6 metal bis(benzene) sandwich complexes. D. Hensley, Y. Lei, D-S. Yang 1472. Kinetic measurements for the DielsAlder trapping of bis(o-methylbenzophenones) with maleimides. M. E. Warner 1473. Matrix isolation study of the reaction of chromyl chloride with arsine. J . Morris, B. S. Ault 1474. Molecular dynamics studies of the unusual thresholds for the reaction of A l + and isotopic H 2 . A. D. Daigle, M. R. Salazar 1475. Scanning tunneling microscopy of titanium(IV) phthalocyanine catechol. C. M. L. Pham, U. Mazur 1476. Study of the thermal properties of a binary/eutectic alloy of In-Sn using a differential scanning calorimeter. D. Clark, R. P. D'Amelia Beyond the Bench: Non-Traditional Careers in Chemistry Sponsored by CHAL, Cosponsored with CHED, CINF, SCHB, WCC, and YCC Chemistry Pedagogy 101 Sponsored by YCC, Cosponsored with CHED, and PROF This One is Just Right! Information Resources for Small Colleges Sponsored by CINF, Cosponsored with CHED M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center
Sci-Mix C. Middlecamp, Organizer,
Presiding
8:00-10:00 106-113, 120,124,126,129-130, 132, 134135, 137,143-144, 146-147, 152, 154, 161,164,173,175,183. See previous listings. Section Β Hyatt Regency Chicago Riverside Center
1479. Northeast Texas Community College "Science Road Show'. E. V. Bonilla, D. M. Encino 1480. Schooling at The Chemistry CirCus. R. A. Ashmus, G. Heredia, N. Avila, I. Arrieta, C. Pasillas, W. E. Dickson, J. E. Becvar 1481. Science day on the greenway. N. Evans, L. Huber, T. Evans, C. Suskovich, A. Huff, C. Damin, R. Heim, C. Keyes, J. W. Ribblett 1482. Seventy years of a chemistry club at Hartwick College. A. Luby, E. R. Wojcik, M. Lahr, N. Deal-Laroda, S. M. Young 1483. Sharing chemistry with middle and high school students through interactive and stimulating educational methods. S. Y. Choung 1484. SHU reacts with you. K. Donaldson, A. Kiral, J. Keith, J. Ludovici 1485. Smoking and health: Benz[a}pyrenes and cancer induction. J. Adams, C. Dienes, P. Di Raddo 1486. South Texas College Student Affiliates chapter. J. Hernandez, J. Gonzalez 1487. The University of Texas at Dallas: Model of a successful Student Affiliates chapter. E. K. Walker, M. V. Selvidge, D. Victor, J. Jackson, S. Edgett 1488. Three years of a successful Student Affiliates chapter. S. J. Cardona, A. Y. Gonzalez, I. Fernandez 1489. Universtiy of Texas at Austin Student Affiliates chapter. L. A. Fredin, N. S. Froemming, J. Leavitt 1490. Vitamin C, health and wellness. C. Kuehnl, E. Dittmar, B. Beaver, R. Chellson, P. Di Raddo 1491. Your home: It is all built on chemistry. A. Ayala, E. Rosario, G. Delgado, W. de la Cruz, J. Suârez 1492. Chemistry style at San German. J. Lisboa, C. Troche, M. Plato, H. Rodriguez, Y. Rivera, N. Caraballo, A. M. Gonzalez 1493. GCSU's chemistry club: Building stronger bonds. D. Nguyen, D. E. McCall, K. Harper, J. Proffit, M. McGinnis, C. H. Lisse 1494. Increasing membership and community involvement: The 2006-2007 University of Northern Colorado Student Affiliates of the American Chemical Society activities and accomplishments. R. Miwa, J . Walsh, K. Barnes, K. A. O. Pacheco 1495. Leading our community into chemistry. I. Rivera, A. Dubey, J. Sanchez 1496. A long history made with magic. K. B. Schallies, B. Perez, A. Marchetti, S. Strezsak, C. Guifarro 1497. ACS at Kalamazoo College: Giving chemistry a voice in the liberal arts. H. C. Gillis, A. W. L. Bayci, G. Ettenger, K. Diffenderfer, J. M. Esson, M. Migliore 1498. Activities of SAACS at Lock Haven University of Pennsylvania. J . Wilhelm, J. Freed, D. Hunter, B. D. May, K. Range, J. Whitling 1499. Activities of the Texarkana College chemistry club. Z. Ramsey 1500. Activities: The heartbeat of a successful Student Affiliate chapter. Κ. Ε. Thompson, A. D. Adkins, A. M. Dunson, E. Martinez 1501. Barry University Chemistry Club/ACS Student Affiliates REACT! I. Pazos, S. Thompson, J. Zephirin, S. Gillig, L. Barbera, L. Arencibia, G. Fisher 1502. Bike Day: A campus wide activity to spread environmental awareness. D. G. Watson, A. R. Sedillo 1503. Blown away with chemistry. K. Fallo, C. Aiuto, J. DePalma, T. Lescouflair, R. Leedham, K. Hannigan, J. R. Boy, J. Reynolds, P. Yarincik, C. Fontana, J. Hunter, R. LaTerra, J. Audie, L. Farber, K. Naik
Successful Student Affiliates Chapter Poster Session Cosponsored with SOCED A. T. Bennett and J. L. W e s e m a n n , Organizers 8:00-10:00 1477. Marietta College ACS student affiliates and chemistry club. D. W. Carpenetti II, K. L. Pate 1478. MSCD SAACS: Promoting awareness of chemistry in the community. S. M. Schelble
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
CHED
1504. Celebrating NCW: Chemistry and your home. P. Di Raddo, K. Worth, J. Sullivan, E. Ohaeri 1505. Withdrawn. 434. MSUM chemistry club campus and community activities. K. J. Marthaller, B. D. Madery, A. P. Marasinghe 1506. Chemistry and your community: Educating local youth based on hands-on demonstrations. L. Celeste, J. R. Martin, A. P. Pendleton, M. J. Waitner, T. M. Gregg 1507. Chemistry club on campus and in the community: Activities of the 2006-2007 SIUE student affiliates chapter. L N. Hamilton, R. Harnack, D. Herrmann, C. Hise, D. Powell, J. Redding, M. T. Sydow, S. D. Wiediger 1508. Chemistry connections in the classroom, campus, and community. B. Stroope, M. D. Perry Jr. 1509. Chemistry matters at Washington College. J. Johnson, E. W. Hobbs, S. Moser, E. Jones, A. E. Marteel-Parrish, J. R. Locker 1510. Chemistry, community and children: The Tuskegee University SAACS commitment. T. Farrer-Bradley, B. G. Rackley, A. E. Russell 1511. ChEmory: Emory University's Student Affiliate Chapter. K. A. Rodby, D. L. Gray 1512. Chi epsilon mu: Great things can happen when the chemistry's right. M. Clay, R. K. Castleberry, C. Brennan 1513. Chico State SAACS: 50 years of community, service and celebration. J. Rai, J. Hostetter, C. A. Plewik, M. Kamunde, A. Mull, K. Voigtritter, M. L. McCrea-Hendrick, D. B. Ball, R. M. Miller 1514. Circulo de quimica: Improving chemistry knowledge at UPR-Cayey. E. Reyes 1515. Clemson University SAACS. C. Pollock, A. Dennis, A. Kraft, J. Hodges, J. Kaup 1516. Community outreach through partnership with local schools. J. W. Revels, T. Thurston, J. Massing 1517. Curiosity for science, and inspiration for chemistry. K. Lee 1518. Demos in the dark: A successful NCW activity. A. S. Nunez 1519. Demystifying chemistry for the masses: The Longwood University SAACS chapter's honorable attempt. C. M. Shuford, R. E. Farmer, L D. Riddle, N. K. Porterfield, A. K. Simmons, S. E. Jenkins, L. A. Friedman, M. C. Rhoten 1520. DePauw Univeristy chapter: Part of the community. D. Roberts, S. S. Rund, S. E. Lemons 1521. Development fostered by demonstration. J. Valenstein, T. Beary, L. Griepenstroh, K. Brown, C. M. Teague 1522. Driving force of our science club: Attending ACS national meetings. J. Machado, J. Murillo, A. Castello, N. Salazar, D. Dickson, M. Amicarelli, K. Espino, R. Alexandre, G. Santiesteban, M. Exposito, M. Delgado 1523. Drury University Student Affiliate chapter. S. R. LeNoue, C. E. Denton, S. Ashkenazi 1524. Eastern Oregon University SAACS: Promoting science in the community. M. J. Bechaver, J. C. Deutsch, T. L Boethin, T. Holcomb, A. G. Cavinato 1525. Elements of team work. F. Garcia 1526. Exciting times for the Pacific Lutheran University's Chemistry Club! C. S. Gordon, C. Fryhle 1527. Exploring the field of chemistry through hands-on experiments. D. Groscost, K. Schreffler, B. Humberger, A. Aul, A. Stallard, S. Johnson, P. Wetzel, A. Och, T. James, A. Miller, P. Tran, B. Williams, J. Wedin, A. Clement, C. Tran, P. Y. Furlan 1528. Exploring the world through the eyes of chemistry. W. Beaumont, P. Bobryshev, C. Cole, C. Lemons 1529. Fundraising for the NDSU Student Affiliates chapter of the ACS. A. Baskerville, A. Rassmussen, C. Seth 1530. Getting Florida International University chemistry students involved in the community. O. G. Cabrices, S. Lamar, S. Boulos, S. Brito 1531. Green chemistry at the University of Minnesota-Morris. C. J. Steinbring
1532. Hands-on chemistry for highschool students. S. C. Laustsen, S. K. O'Shea 1533. Hosting activities for large groups of k-6. E. Mclean, A. E. Turner, E. A. Freehauf, C. J. Kalish, T. H. Zauche 1534. Juniata College SAACS: Expect the uncommon. M. C. Kauffman, B. Bogusz, K. M. George, R. A. Grimminger, K. Kratz, J. G. Longenecker, J. M. Mann, T. L. Fisher, R. R. Hark 1535. Learning, teaching, research, and discovery: The UIW chemistry club. J. M. Davis, B. G. McBurnett, E. E. Gonzalez, R. O. Flores, A. J. Obregon, A. M. Cavazos 1536. Millersville University Student Affiliates. R. L Butt, K. M. Kahler, C. M. Flynn, A. J.Jacobs 1537. Morehead State University SAACS. A. Dockery, K. Russell, C. Preece, M. T. Blankenbuehler 1538. MTSU SAACS activities 2007: The name is Bond... as in chemical bond. T. A. Barnes, S. C. Chesak, R. Parsons, G. D. White, A. C. Friedli 1539. Nano chili. L K. Hutter, D. I. Georgy, K. Symcox 1540. Nazareth College outreach program: Bringing science to the community. A. J. Balliano, K. A. MacMaster 1541. NDSU Student Affiliates chapter outreach program. A. Baskerville, A. Rassmussen, C. Seth 1542. New methods of membership recruitment for SAACS at Northern Kentucky University. J. R. Deye, R. A. Wilson, M. Lauer, R. A. Seger, C. A. Morris, H. A. Bullen, K. A. Walters 1543. New traditions for the SAACS chapter at Centenary College of Louisiana. B. Martin, J. Fagan, I. Newton, C. Andrews, T. M. Ticich 1544. Nurturing relationships and building community with chemistry. K. B. Lewoczko, J. R. Barker, C. M. Baldwin, R. F. Johnston 1545. Positive impacts of a student and community centered organization. M. Woods, B. Drake, J. Connolly, B. Gregory, K. L. Evans 1546. Professional development activities and community service in a student affiliate chapter. J. A. Vervynckt, S. A. Bragg, L L Pesterfield, R. Zhang 1547. Reestablishing a SAACS chapter at Miami University. K. Harris, J. Sarquis 1548. Reaching out to the campus and beyond: SAACS events that spark interest. J. M. Fritz, E. Repasky, C. R. Bowman, A. B. Moore 1549. Saint Louis University Chemistry Club: Drop it like it's exothermic. M. Watt, A. Blackwell 1550. Saint Mary's affiliate of the American Chemical Society. M. Boyle, C. Herdman 1551. A history of outstanding activities of the ACS-Student Affiliates Chapter at the University of Puerto Rico, Rio Piedras Campus. A. Pizarro Rios, S. M. Delgado, J. C. Aponte Santini, F. L. Rosario Quinones, R. Rivera Ocasio 1552. ACS demons rock the bayeux. G. E. A. Rudd, J. Brown, I. Jamil, A. Brauer 1553. ACS Student Affiliates, Purdue chapter. C. A. Johnson, M. Trybula 1554. American Chemical Society Student Affiliate chapter, University of Puerto Rico at Arecibo 2005-2006. S. J. Cardona 1555. SMSU chemistry club activities. K. M. Henning, J. H. Brown 1556. Strategies for student recruitment and retention in the Student Affiliate Chapter (SAC) of the ACS at Pontifical Catholic University of Puerto Rico (PUCPR). C. Collazo, C. Rivera, J. Pérez, M. Colon, F. Rodriguez, X. Santiago
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
1557. Student affiliate chapter activities at Angelo State University. C. A. Cozby, L Lawdermilk, D. K. Howell, Ν. Ε. Flynn 1558. Student affiliates activities at Eastern Illinois University. M. E. Breen, K. S. Cagle, M. F. Cuddy II, R. C. Grove, D. S. Schwenk, M. Unterfenger, E. M. Treadwell, S. M. Tremain 1559. Student Affiliates of the American Chemical Society at the University of St. Thomas, Houston, TX. A. Olowu, G. Toledanes, L. P. Marruffo, C. Kelley, S. Metouri, T. B. Malloy Jr. 1560. Successful activities of SAACS at the University of Central Oklahoma. D. G. New, C. M. Lindsey, J. M. Ferguson, P. S. Jordan 1561. Successfully reactivating a dormant student affiliates chapter. L. Thompson, A. Mehta, J. Smith, Ε. Κ. Malcolm, L. A. Read, K. L. Steelman, K. W. Felling 1562. Team Chemistry: A dynamic effort. C. Levy, F. Santory, T. Sirivanta, P. K. Kerrigan 1563. The big bang theory: Public chemistry demonstrations for all ages. B. J. Stockel, T. M. Emmer, M. D. Schuder 1564. The catalyst of our community: W&J SAACS. A. Bisch, M. Samios, F. Smith, C. Hoop 1565. The SAACS Community and the chemical interactions of undergraduate subjects at Cal Poly Pomona. D. Y. Wooten 1566. The Southern Chemical Society at Georgia Southern University. T. R. McCall, M. Viera, P. C. Pletcher, S. Vaughn, K. Deal, C. M. Davis-McGibony 1567. Truman SAACS: What next? D. Stacy, J. Himer, M. Thorstad, B. K. Kramer 1568. University of Michigan-Flint chemistry club: Coordination in chemistry. J. L. Tischler, B. Gorski, B. Yonke, A. Stanczyk, K. Bezemek, M. Qureshi 1569. Waynesburg outstanding chapter strives to promote chemistry education. M. R. Orndoff, M. L. Scozio, A. M. O'Farrell 1570. We may not be part of the solution but we are definitely part of the precipitate. C. L. May 1571. Xavier University of Louisiana SAACS: A post-Katrina success story. T. D. Davis, J. A. Ellis, N. Guillory, T. Ndessoko, P. Tran, C. Gillard 1572. Chemistry at the borders: A student affiliates chapter at the University of Ari zona. N. T. Dahl, T. W. Jones, D. C. Correia, S. D. Gee, L. Hall 1573. A green chemistry poster session among Thanksgiving holiday festivities. B. P. Vos, L R. Cullen, J. A. Heidt, K. C. Lanigan, M. A. Benvenuto, M. J. Mio
10:55 1580. Sensorial chemistry experiments that rely on senses other than eyesight. M. T. Oliver-Hoyo, D. C. Bromfield-Lee 11:15 1581. Organic chemistry for the visu ally impaired. T. Poon, R. Ovadia 11:35 1582. Teaching a blind student organic chemistry and biochemistry. R. L. McCann, A. H. Predecki 11:55 1583. A national clearinghouse for teaching and encouraging blind and low vision students in chemistry and other scientific disciplines: A web portal. M. Riccobono, C. A. Supalo, B. Zaborowski Section Β McCormick Place North Room N230A, Level 2 Exploring and Exploiting Nature with Biomimetics Rational Manipulation of Biomolecular Architecture Cosponsored with WCC, BIOL, and INOR S. Mitra,
Organizer
M. Roettger, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1584. Learning from nature. R. Breslow 9:00 1585. Metal ion recognition and selec tivity using de novo designed peptides. V. L. Pecoraro, D. Touw, O. Iranzo, C. Cabello, M. Luczkowski, K-H. Lee, D. Ghosh, S. Chakraborty, L. Hemmingsen 9:25 1586. Diversifying biosynthetic path ways in engineered cells. C. Schmidt-Dannert 9:50 Intermission. 10:00 1587. Evolutionary changes in protein structure as models for protein design. M. H. Cordes 10:25 1588. Molecular biomimetics: Geneti cally engineered peptide-based materials for technology and medicine. M. Sarikaya 10:50 1589. Novel proteins from designed combinatorial libraries. M. H. Hecht 11:15 1590. Mimicking the functions of DNA and RNA. E. T. Kool 11:40 Concluding Remarks. Section C McCormick Place North Room N230B, Level 2 Center for Workshops in the Chemical Sciences (CWCS) Forensic Science D. M. Collard and J. C. Smith,
TUESDAY MORNING
L. J . Kaplan, Organizer,
Section A McCormick Place North Room N227A, Level 2 Teaching Chemistry to the Visually Impaired D. Wohlers, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1574. Research in Disabilities Educa tion Program at the National Science Foundation. D. Wohlers, M. Leddy 8:55 1575. Independent Laboratory Access for the Blind (ILAB). C. A. Supalo, T. E. Mallouk, D. Wohlers, A. E. Greenberg, A. Roth, D. L. A. Rankel 9:15 1576. Assessment of the impact chem istry text and figures have on visually impaired students' learning. P. M. Mayo, G. Bodner 9:35 Intermission. 9:45 1577. Teaching nanoscience to the blind and visually impaired. A. E. Greenberg, M. Farhoud, L. Goetter 10:05 1578. Access for students with disabili ties to chemistry curricula using Digital Talking Books. D. Schleppenbach 10:25 1579. Teaching chemistry to mainstreamed blind students. D. L. A. Rankel, C. Supalo, D. D. Wohlers 10:45 Intermission.
Organizers
Presiding
8:30 Introductory Remarks. 8:35 1591. Forensic chemistry: A CWCS workshop and the birth of a community of scholars. L. J. Kaplan 8:55 1592. It all started in the Goat Room: Reflections from a forensic science work shop. C. V. Gauthier 9:15 1593. How participation in CWCS contributed to Hofstra University's BS Program in Forensic Science. N. M. Wachter, R. B. Finzel 9:35 Intermission. 9:45 1594. Team teaching forensics: Bridg ing chemistry and physics. S. S. Cady 10:05 1595. "Introduction to Forensic Sci ence" as a temptation into a sciencebased career. J. K. Schoer 10:25 1596. Contemporary identification methods: Bridging forensic science and traditional qualitative analysis. A. Y. Nazarenko 10:45 Intermission. 10:55 1597. Forensic science at St. Olaf College: A CWCS success story. D. J. Beussman 11:15 1598. Forensic science for non-sci ence majors. J. W. Benson 11:35 Concluding Remarks.
TECH-33
TECHNICAL PROGRAM
CHED Section D
Section F
McCormick Place North Room N229, Level 2
McCormick Place North Room N231, Level 2
Developing a Safety Plan for Teaching Chemistry in the Home School Situation Cosponsored with CHAS
Advances in Teaching Chemistry at the Nanoscale at the K-12 Level G. M. Bodner,
F. K. Wood-Black, Organizer,
Organizer
Presiding Κ. Μ. Hutchinson,
8:30 Introductory Remarks. 8:35 1599. Benign by design: Integrating green chemistry into the home school curriculum. Κ. Ε. Parent, M. M. Kirchhoff 8:55 1600. CHO, CHP, EHS, LEPC, MSDS: Too much alphabet soup for the homeschooler? W. C. Penker 9:15 1601. Green clean experiments at the home school. Y. I. Gonzalez 9:35 Intermission. 9:45 1602. Development of chemistry labora tories for home school assignments. F. K. Wood-Black 10:05 1603. Home school instruction from the student's perspective. T. Black, F. K. Wood-Black 10:25 Discussion. 10:30 Concluding Remarks. Section Ε McCormick Place North Room N227B, Level 2 Communicating Chemistry Cosponsored with CINF L. Fine,
Organizer
J. C. Kotz, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1604. Podcasting and general chemis try: What is my chemistry professor doing in my iPod? H. D. Bapat 8:55 1605. Hybrid learning as the bridge between technology and pedagogy in the first and second year chemistry curriculum. T. Poon, T. Morkin 9:15 1606. Chemistry breaks the Top 100: Podcasting quantum mechanics. Μ. Μ. Francl 9:35 Intermission. 9:45 1607. Open notebook chemistry using blogs and wikis. J-C. Bradley, K. Mirza, J. Giammarco, A. Holsey, D. Strumfels, S. Gardner, L Chen 10:05 1608. What role do grades play in communicating chemistry? W. J. Vining 10:25 1609. Improving the communication and efficiency in grading of laboratory reports. M. Hadley, J. R. Pribyl, J. A. Kaliski 10:45 Intermission. 10:55 1610. Enhancing communication in chemistry courses using DyKnow™. B. L. Gourley 11:15 1611. Taking ownership of learning: Can adding technology to the traditional classroom increase the opportunity for students to be more responsible for their own learning? C. M. Turner 11:35 1612. Ε-learning chemistry. J. Reeves, J. Tyrell
Presiding
8:30 Introductory Remarks. 8:35 1613. Using small-group discussions to assess student learning of nanoscale concepts. C. S. Cahill, S. Y. Stevens, N. Shin, C. Delgado, J. S. Krajcik, M. Yunker 8:55 1614. Seeing is believing: Middle school students' engagement and devel opment notions of the particular nature of matter through Microscopy Camp 2005 and 2006. R. L Penn, L. Flynn 9:15 1615. Size and scale curricular activities for middle school. C. Delgado, S. Y. Stevens, J. S. Krajcik 9:35 Intermission. 9:45 1616. Nanoscale science in a wizard's world. J. M. Bortiatynski, A. E. Greenberg, D. G. Sykes, P. C. Eklund, T. E. Mallouk 10:05 1617. Professional development for middle and high school teachers in nano scale science and technology. D. Sederberg, L. Bryan, N. Giordano, S. Daly, W. L. Fornes, K. M. Hutchinson, R. Batchelor, E. Hagedom 10:25 1618. Middle and high school teach ers' conceptions of model-based inquiry and design activities of nanoscale phe nomena. S. Daly, L. Bryan 10:45 Intermission. 10:55 1619. An NCLT nanoscience work shop for science teachers at Fisk Univer sity. W. Lu, D. Thomas, W. E. Collins, E. Tevaarwerk, M. Hsu, M. Wong, R. P. H. Chang 11:15 1620. Introduction to materials science and nanotechnology: A shared teaching/ learning experience. L. A. Avila Diaz, L. W. Fine TUESDAY AFTERNOON
Chemical Evolution, Chemical Change Across Space and Time Chemical Evolution in Astrophysics Cosponsored with GEOC, and NUCL L. Zaikowski and J . M. Friedrich, Organizers, Presiding 1:30 Introductory Remarks. 1:35 1621. Origins of order and the emer gence of complexity. S. A. Kauffman 2:05 1622. Chemical origins: Nuclear chem istry in the early universe. K. A. Olive 2:35 1623. Origin of the elements: Nucleo synthesis in stars. B. S. Meyer 3:05 Intermission. 3:15 1624. Identifying molecules in space. L. M. Ziurys 3:45 1625. Circumstellar chemistry and dust from dead stars in meteorites. K. Lodders 4:15 1626. Chemical evolution in the inter stellar medium. L. J. Allamandola
McCormick Place North Room N230A, Level 2 Exploring and Exploiting Nature with Biomimetics Molecular Recognition and Drug Delivery Cosponsored with WCC, BIOL, and INOR
34-TECH
S. Mitra, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 1627. Biomimetic design of intracellular drug carriers. A. S. Hoffman, P. S. Stayton 2:00 1628. Biomimetic environments for cells: Chemical approaches to controlling human embryonic stem cell fates. L. L. Kiessling
Section Ε McCormick Place North Room N227B, Level 2 Communicating Chemistry Cosponsored with CINF
McCormick Place North Room N230B, Level 2
J. C. Kotz, Center for Workshops in the Chemical Sciences (CWCS) Green Chemistry; General Chemistry J. C. Smith and L. J. Kaplan, D. M. Collard, Organizer,
Organizers
Presiding
1:30 Introductory Remarks. 1:35 1634. Green chemistry in the organic chemistry teaching lab: Workshops to promote curriculum adoption and faculty development. J. E. Hutchison, K. M. Doxsee, J. A. Haack 1:55 1635. Development of a green organic chemistry laboratory program at Hendrix College. T. E. Goodwin 2:15 1636. Green chemistry at St. Olaf College. G. O. Spessard 2:35 1637. Green chemistry education net work (GCEdNet): A collaborative model for curriculum development. J. A. Haack, J. E. Hutchison, Κ. Μ. Doxsee 2:55 Intermission. 3:05 1638. Expanding a CWCS workshop experience: A journey continues for a workshop participant and workshop leader. S. Basu-Dutt, D. J. Wink 3:25 1639. Modified general chemistry labo ratory activities for the enhancement of critical thinking. C. Kim 3:45 Discussion: Building learning communi ties to foster curriculum development. Section D
McCormick Place North Room N227A, Level 2
3:55 1648. Student experiences in informal science education: Science in the City. R. A. Morgan Theall 4:10 Intermission. 4:20 1649. Musical science: Integrating undergraduate education into a Discovery Corps project. C. M. Oertel 4:35 1650. Integrating materials chemistry and art for metallic art conservation and chemical education. T. L. Clare, B. A. Bassett, B. A. Price, P. A. Lins
Section C
Section A
Section Β
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
2:25 1629. Mimicking and expanding biologi cal assembly and function. D. Trauner 2:50 Intermission. 3:00 1630. Inner space of molecules. J. Rebek Jr. 3:25 1631. Parsing the specificity-activity relationship in transcriptional regulation. A. K. Mapp 3:50 1632. Nature as a teacher: New drug leads, drug delivery systems, and real time in vivo imaging methods. P. A. Wender 4:15 1633. Natural products: From practical chemical synthesis to elucidation of the cellular mode of action. S. A. Kozmin 4:40 Concluding Remarks.
Presiding
1:30 Introductory Remarks. 1:35 1651. Visualizing acid/base chemistry: Using electostatic potential surfaces to teach acid/base strengths. R. W. Morrison, R. Hubbard IV, K. Soncha 1:55 1652. Open access peer reviewed portal for communicating chemistry: Ana lytical Sciences Digital Library. H. A. Bullen 2:15 1653. Comparison of student discourse in on-line and face-to-face environments. G. C. Weaver, K. F. Green 2:35 Intermission. 2:45 1654. Chemical Eye on ears tuned to public radio. P. J. MacDougall 3:05 1655. Science outreach in the city of Chicago. M. C. Lach, M. Davis 3:25 1656. "Smart Cities': Summer science in the mean streets of France. G. P. Niccolai 3:45 Intermission. 3:55 1657. Collaborative efforts by Illinois local American Chemical Society sections to promote chemistry at the Illinois State Fair. H. D. Bapat 4:15 1658. Analysis of how scientists explain their research and parallels to how science teachers explain science. H. Sevian, L. Gonsalves 4:35 1659. Service-learning with a general chemistry lab: Communicating chemistry through application. M. J. Harvey Section F
McCormick Place North Room N229, Level 2 Bridging Research and Service: The Discovery Corps Experience Post Doctoral Fellows R. Theall,
Organizer
L. Fine, Organizer,
McCormick Place North Room N231, Level 2 Advances in Teaching Chemistry at the Nanoscale at the K-12 Level
Organizer G. M. Bodner,
G. D. Bothun and A. K. Bentley,
Organizer
Presiding S. Daly,
1:30 Introductory Remarks. 1:35 1640. Bringing authentic science to the undergraduate lab experience. A. K. Bentley, G. C. Weaver, K-S. Choi 1:50 1641. Discovery Corps Postdoctoral Fellowship: Developing an innovative program for undergraduate research and education. G. D. Bothun 2:05 1642. Continuation and institutionaliza tion of an undergraduate research and development program. J. R. Ingle, L. Uitenham, E. Baucom, J. M. DeSimone 2:20 Intermission. 2:30 1643. Developing a new generation for organic electronics. J. M. Léger, D. Rodovsky, G. Bartholomew 2:45 1644. NSF Discovery Corps Postdoctoral Fellowship: Development of an afterschool science program - combining outreach, education, and professional development. C. L. Stoffel 3:00 1645. Alternative energy in the research lab and chemistry classroom. P. D. Weyman, T. Thiel 3:15 Intermission. 3:25 1646. Greener approaches to chemistry through research and education. S. L. Gould, M. A. Garcia-Garibay, A. A. Russell 3:40 1647. Using molecular animation to visualize the chemical origins of life. J. H. Iwasa, M. Morse, J. W. Szostak
Presiding
1:30 Introductory Remarks. 1:35 1660. Nanoscale science: A tool to excite middle school students in chemistry. S. O. Obare 1:55 1661. On-line nanoscience course for teachers: Design, implementation, and evaluation. J. M. H. Tomasik, J. W. Moore 2:15 1662. The nanoworld: Research-driven design process. N. Shin, C. Quintana, C. Delgado, S. Y. Stevens, J. S. Krajcik 2:35 Intermission. 2:45 1663. Developing and validating a learning progression for the nature of matter. S. Y. Stevens, C. Delgado, N. Shin, J. S. Krajcik 3:05 1664. Development of an inventory of student nanoscience concepts. N. A. Unterman, M. Grdinic, L. J. Lauhon 3:25 1665. Identification of the big ideas in nanoscience. S. Y. Stevens, J. S. Krajcik, C. Delgado, R. A. Elgammal, C. Quintana, A. Rosenquist, N. Sabelli, T. Sanford, P. Schank, M. Yunker 3:45 Intermission. 3:55 1666. Secondary students' interests in nanoscience concepts and phenomena. K. M. Hutchinson, S. Y. Stevens, N. Shin, C. Delgado, M. Yunker, G. M. Bodner, N. Giordano, J. S. Krajcik 4:15 1667. Students' conceptions of size. C. Delgado, S. Y. Stevens, J. S. Krajcik
CHED 4:35 1668. The chemistry of metal and semiconductor nanoparticles. L. M. Goh, J. Pazmino, J. A. Washington, M. Fujiwara, R. D. Braatz Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Sponsored by PRES, Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT WEDNESDAY MORNING Section A McCormick Place North Room N227A, Level 2 Chemical Evolution, Chemical Change Across Space and Time Geochemical Evolution of the Solar System and Earth Cosponsored with GEOC, and NUCL L Zaikowski and J. M. Friedrich, Organizers, Presiding 9:00 Introductory Remarks. 9:05 1669. Photochemistry in the early solar system. R. N. Clayton 9:35 1670. Lessons from meteorites. M. E. Lipschutz 10:05 1671. Chemical diversity and abun dances across the solar system. J. S. Lewis 10:35 Intermission. 10:45 1672. Planetary volatile inventories and atmospheres. B. Fegley Jr. 11:15 1673. Formation of the Earth and Moon: Geochemical and isotopic con straints. T. Kleine 11:45 Discussion. Section Β McCormick Place North Room N230A, Level 2 Building Connections to Non-Major's Chemistry K. Anderson, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1674. Description of a molecule portfo lio project for health-occupations students. W. F. Huntsman 8:55 1675. Creating an active learning envi ronment to facilitate the meaningful learn ing of biochemistry by allied health stu dents. D. W. Parkin, R. Lippman 9:15 1676. Making the chemistry connection: Integrating mini-reviews and case studies to teach biochemistry to senior level biol ogy students. M. D. Kelley 9:35 Intermission. 9:45 1677. Fire and ice: Student inquiry into heat. C. F. Bauer 10:05 1678. Chemistry in context: Global issues that connect. C. Middlecamp, L. P. Eubanks 10:25 1679. Project-based modules for teaching materials chemistry. E. P. Douglas, O. Graeve, S. Gleixner 10:45 Intermission. 10:55 1680. Teaching forensic science using a science-in-fiction approach. K. McMahon 11:15 1681. Using forensic science to teach non-majors about science and chemical principles. C. M. Teague, C. A. Liberko, J. C. Kolowski Section C
D. M. Collard and J . C. Smith,
Organizers
Presiding
8:30 Introductory Remarks. 8:35 1682. Development of a forensic chem istry course for non-science majors at Ursinus College. V. J. Tortorelli
Section F McCormick Place North RoomN231, Level 2 Bringing Authentic Research into the Undergraduate Laboratory D. J . Wink,
McCormick Place North Room N229, Level 2
G. C. Weaver, Organizer,
Bridging Research and Service: The Discovery Corps Experience Senior Fellows R. Theall, S. L. Gould,
Organizer Presiding
8:30 Introductory Remarks. 8:35 1690. Seniors in service: Project SERVE (Science Enrichment using Retired Volunteer Educators), an intergenerational program for improving the quality of chemistry education in the EC-12 class room. D. J. Casadonte Jr. 8:55 1691. Career success in science and engineering: A Discovery Corps project. Ε. Η. Wagener 9:15 1692. Professor-in-Residence at Clark Atlanta University. L. M. Tolbert 9:35 Intermission. 9:45 1693. How a Discovery Corps Fellow ship can take over your life: Great Lakes Intercontinental Instrumentation Collaboratory. A. Fitch, W. Mavura, G. Thiruvathukal 10:05 1694. Development of marine and seawater pollution database across conti nents. O. A. Sadik 10:25 1695. Coffee for justice: An interna tional collaboration for research and ser vice with small-holder coffee farmers of Nicaragua. S. C. Jackels, C. F. Jackels, C. Vallejos, S. Kleven, R. Rivas, S. Fraser-Dauphinee 10:45 Intermission. 10:55 1696. Sustainable energy and chemi cal sciences collaboration in biomass conversion research between the US and Brazil. B. Miller 11:15 1697. Discovery Corps: Assessing the program. M. J. Kenney Section Ε McCormick Place North Room N227B, Level 2
L. Fine,
Center for Workshops in the Chemical Sciences (CWCS) Forensic Science
9:35 Intermission. 9:45 1701. Investigational writing exercises to complement undergraduate biochemis try experiments. P. J. Higgins 10:05 1702. Readability levels of college chemistry textbooks from introductory chemistry to physical chemistry. E. A. Drommerhausen, J. R. Pribyl 10:25 1703. Student opinions of writing assignments in organic chemistry courses for majors. D. P. Cartrette 10:45 Intermission. 10:55 1704. How to think logically about organic chemistry. Ε. Τ. Papish 11:15 1705. Communicating the concepts of resonance and conjugation. J. J. Mullins 11:35 1706. Use of humor and illustrations in organic chemistry lectures. V. Dragojlovic
Section D
Communicating Chemistry Cosponsored with CINF
McCormick Place North Room N230B, Level 2
L. J. Kaplan, Organizer,
8:55 1683. An interdisciplinary undergradu ate "Science of Forensics" course. S. Kaur, D. Jemiolo 9:15 1684. Development of the forensic science and forensic chemistry programs at Sam Houston State University. P. A. Loeffler, M. F. Plishker, R. E. Norman 9:35 Intermission. 9:45 1685. Empowered learning. L. Bordas 10:05 1686. Enlisting university and commu nity resources in support of a forensic science program. J. M. Postma 10:25 1687. Implementation of forensic science course: Incorporation of mockcrime and mock-trial scenarios with foren sic science and computer forensics ele ments. R. Ganaganur 10:45 Intermission. 10:55 1688. Multiple-discipline, team-taught forensic science course. J. Bartlett, B. Gay, T. Metz, M. B. Wells 11:15 1689. Progression of biology and chemistry education using a criminalistics matrix at Greenville College. E. A. Dunkley Jr. 11:35 Discussion. 11:50 Concluding Remarks.
Organizer
J. C. Kotz, Organizer,
Organizer Presiding
8:30 Introductory Remarks. 8:35 1707. Developing a new model to provide first- and second-year undergradu ates with chemistry research experience: The Center for Authentic Science Practice in Education (CASPiE). W. L. Fornes, G. C. Weaver, D. J. Wink, F. E. Lytle, S. Shih, R. J. Morris, W. J. Boone, P. Varma-Nelson, A. K. Bentley, C. B. Russell 8:55 1708. Peer-Led Team Learning (PLTL) in a research based laboratory course. P. Varma-Nelson, A. K. Bentley, G. C. Weaver 9:15 1709. Training undergraduate team leaders for a research-based laboratory course. A. K. Bentley, M. A. Hoch, P. Varma-Nelson, G. C. Weaver 9:35 Intermission. 9:45 1710. CASPiE module development: From the cradle to the lab. C. B. Russell, G. C. Weaver 10:05 1711. Development of an old reagent for the reduction of solid-supported alkenes: A research-based laboratory module. D. J. Wardrop 10:25 1712. Evaluation of student perfor mance in authentic research experiences. W. R. Robinson, C. B. Russell, G. C. Weaver 10:45 Intermission. 10:55 1713. About a student's perspective on CASPiE at Purdue University. K. M. Sinak, M. A. Hoch, A. K. Bentley, G. C. Weaver 11:15 1714. Undergraduate participation in the development and implementation of a CASPiE lab module for the organic labora tory. C. Toh, M. Lunda, D. J. Wardrop, D. J. Wink 11:35 1715. CASPiE research for high school students. N. Hike-Teague, D. Wink, M. Dianovsky 11:55 1716. CASPiE at College of DuPage: Undergraduate research at a two-year institution. S. Shih, C. Dockus, M. Newberg 12:15 Concluding Remarks. ACS Award for Encouraging Women into Careers in the Chemical Sciences: Symposium in Honor of Bojan H. Jennings Sponsored by WCC, Cosponsored with CHED
Presiding
8:30 Introductory Remarks. 8:35 1698. Teaching chemical information: Tips and techniques from the Division of Chemical Information Education Commit tee. S. Cardinal, S. Yu 8:55 1699. Communicating the chemistry behind issues. B. Venkataraman 9:15 1700. Teaching chemistry majors to write like chemists. M. S. Robinson, F. L. Stoller
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
On Beyond Keyword Searching: Advanced Instruction in Chemical Information Sponsored by CINF, Cosponsored with CHED WEDNESDAY AFTERNOON Section A McCormick Place North Room N227A, Level 2 Chemical Evolution, Chemical Change Across Space and Time Prebiotic Chemistry Cosponsored with GEOC, and NUCL L. Zaikowski and J. M. Friedrich, Organizers, Presiding 1:30 Introductory Remarks. 1:35 1717. Cosmic carbon chemistry. P. Ehrenfreund, O. Botta 2:05 1718. Extraterrestrial organic chemistry as recorded in carbonaceous chondrites. O. Botta 2:35 1719. Interactions: Earth's early atmo sphere, lithosphère, and hydrosphere. D. Rumble III 3:05 Intermission. 3:15 1720. Prebiotic organic synthesis in neutral planetary atmospheres. J. L. Bada, J. Cleaves, J. H. Chalmers, A. Lazcano 3:45 1721. Prebiotic synthesis: Organic chemistry and catalysis. J. P. Ferris, G. J. Gluszak, J. W. Delano, P. C. Joshi, M. F. Aldersley, J. D. Price 4:15 Discussion. Section Β McCormick Place North Room N230A, Level 2 Building Connections to Non-Major's Chemistry K. Anderson, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 1722. Nanotechnology for non-science majors. R. D. Crouch 1:55 1723. Topics and activities for contex tual chemistry courses. D. A. Katz 2:15 1724. Chemistry in context: Lab projects that connect. S. W. Keller 2:35 Intermission. 2:45 1725. How to connect with pre-service elementary teachers in the chemistry classroom: Reflective action research. M. L. Grunert, G. M. Bodner 3:05 1726. Lab for non-science majors: Chemistry of the environment. M. W. Teague, J. R. Merritt 3:25 1727. Quantifying lead in soils and dust: A field portable XRF lab. S. J. Bachofer 3:45 1728. Teaching principles of color theory with commercial paint chips. M. J. Welsh Section C McCormick Place North Room N230B, Level 2 Center for Workshops in the Chemical Sciences (CWCS) Green Chemistry; General Chemistry J. C. Smith and L. J . Kaplan, D. M. Collard, Organizer,
Organizers
Presiding
1:30 Introductory Remarks. 1:35 1729. Opening the black box of compu tational chemistry. R. Hernandez, T. D. Shepherd, C. D. Sherrill 1:55 1730. Development of a class in com putational chemistry. L. M. Pratt 2:15 1731. Collaboration strengthens chem istry program, a win-win strategy. H. Fan, A. Vivoni 2:35 Intermission. 2:45 1732. Innovations in nanotechnology and chemistry laboratory courses. K. Winkelmann, Μ. Η. Baloga, J. C. Baum, T. Noviello, S. Brooks 3:05 1733. Powder X-ray diffraction in under graduate inorganic and physical chemistry. J. Gryko
TECH-35
TECHNICAL PROGRAM
CHED 3:25 1734. Participating in CWCS workshops in the core of one's discipline vs. the periphery: A comparison of benefits. A. Pavlick 3:45 1735. Implementation of course mod ules: From pilot labs to study abroad. D. M. Norton 4:05 Concluding Remarks.
Bringing Authentic Research into the Undergraduate Laboratory
10:45 1767. Science and the concept of evolution. L. Zaikowski, K. Fisher, R. T. Wilkens 11:15 1768. Time-evolution of wavepackets as a means to bridge quantum and classi cal concepts. G. J. Simpson 11:45 Concluding Remarks.
G. C. Weaver,
Section Β
S. S. Hunnicutt, Organizer,
McCormick Place North Room N230A, Level 2
8:00 Introductory Remarks. 8:05 1786. Grade a set (1 - *>) of chemistry labs in minutes: On-line submission of data and calculations. E. L. Brown 8:25 1787. Development of LON-CAPA problems for pre-lab assignments to accompany an on-line laboratory manual in general chemistry. R. J. Light, S. R. Dillon 8:45 1788. LON-CAPA lab reports. J. Topich 9:05 Intermission. 9:15 1789. DyKnow™ as a mechanism for sharing student work among peers and more effective note taking. B. L. Gourley 9:35 1790. Electronic homework system in an organic chemistry distance education course: It's not just for homework any more! K. A. Sandberg 9:55 1791. On-line homework for organic chemistry. S. M. Ruder 10:15 Intermission. 10:25 1792. Synthesis Explorer: Dynamically generated reaction and synthesis prob lems for organic chemistry education. J. Chen, P. Phung, P. F. Baldi 10:45 1793. ACE organic on-line homework. L. Farber 11:05 1794. Incorporating the OWL on-line homework system in the teaching of organic chemistry at VCU. Q. Zhou 11:25 Panel Discussion.
Section F McCormick Place North RoomN231, Level 2
Organizer
Section D McCormick Place North Room N229, Level 2 Applications of Electronic Homework Systems Presiding
Section D D. Wink, Organizer, McCormick Place North Room N229, Level 2 Applications of Electronic Homework Systems S. S. Hunnicutt, S. M. Ruder,
Organizer
Presiding
1:30 Introductory Remarks. 1:35 1736. Designing homework for learning first and assessment second. W. J. Vining, B. Botch, R. O. Day 1:55 1737. Using ARIS to boost student performance. J. S. Overby 2:15 1738. Electronic homework and student achievement in large enrollment general chemistry courses. R. D. Arasasingham 2:35 Intermission. 2:45 1739. Online Web-based Learning (OWL) assignments vs. written homework assignments. D. R. Neu 3:05 1740. Use of ChemSkill Builder in a large general chemistry classroom. W. L. Keeney-Kennicutt 3:25 1741. LON-CAPA for general and physical chemistry classes. S. S. Hunnicutt 3:45 Intermission. 3:55 1742. Dimensional analysis 101. E. L. Brown 4:15 1743. Does the use of an electronic homework system help students to learn? L G. Hartshorn 4:35 1744. Learning gains through the use of an on-line homework system. P. A. Wegner 4:55 Panel Discussion.
Section Ε McCormick Place North Room N227B, Level 2 Broadening Participation in Undergraduate Research Cosponsored with CMA, WCC, YCC, SOCED, and COMP M. K. Boyd, B. L. Gourley,
Organizer Presiding
1:30 Introductory Remarks. 1:35 1745. Collaborative study between chemistry and art of environmental consid erations in art preservation. J. A. Ganske, J. Piasentin, M. Roosa, C. Tinsley, J. Laubacher, J. Dildine 1:55 1746. Pedagogical advantages of coupling interactive multimedia simulation and microcomputer-based science labora tory. M. Diack 2:15 1747. Porous stainless steel anode support layers for solid oxide fuel cells by tape casting. R. H. Jarman, L. J. Elgass, M. Hamedani, J. D. Carter 2:35 Intermission. 2:45 1748. Retention through research: Maximizing undergraduate involvement in a research laboratory. C. H. Lisse 3:05 1749. When small schools lack the resources. S. Gupta 3:25 1750. What....publish with freshman undergraduate research students?!? D. C. Forbes, P. M. Davis 3:45 1751. Building excellence in science and technology. D. H. Murray
36-TECH
Presiding
1:30 Introductory Remarks. 1:35 1752. Using CASPiE as an introduction to research for pre-college students. M. Dianovsky, S. A. Cunningham, D. J. Wink 1:55 1753. Implementation of CASPiE in the community college classroom. M. Davis 2:15 1754. Undergraduate research in a rural community college. J. A. Bardole 2:35 Intermission. 2:45 1755. CASPiE experience at Northeast ern Illinois University. A. Fraiman, V. Curtis-Palmer 3:05 1756. On the implementation of the CASPiE program in the Department of Chemistry at Ball State University. R. J. Morris, P. S. Coan, R. E. Sammelson, J. Dunham, S. Chung, M. Towns, D. Smith 3:25 1757. Working toward unattended student access to remote instrumentation. F. E. Lytle, G. C. Weaver, D. Steffen, P. J. Wyss 3:45 1758. Development of the DECRE (Device to Evaluate Chemistry Reform) instrument and its use in CASPiE evalua tion. W. J. Boone, D. Wink, G. C. Weaver 4:05 Intermission. 4:15 1759. General description of CASPiE. D. Wink, G. C. Weaver 4:20 1760. Bringing authentic research into the general chemistry laboratory curricu lum: Northern Plains Undergraduate Research Center. M. Koppang, M. T. Berry, A. G. Sykes, G. W. Earl, D. Weisshaar, B. G. Moore, K. DeWitt 4:25 1761. About the Ohio REEL project: Research experiences to enhance learn ing. P. M. Woodward, P. K. Dutta, V. Subramaniam, R. T. Taylor, T. Clark, S. J. Olesik, C. Callam, W. Mathews, R. Spinney, W. J. Donovan, J. W. Francis 4:30 1762. About a two-year college based undergraduate research collaborative. T. B. Higgins, T. Dowd, G. M. Ferrence, Y. Harris, R. House 4:35 1763. Teaching through research: The Undergraduate Research Center at The University of Texas at Austin. S. L. Simmons, A. D. Ellington, R. I. Shear, S. W. Stevens, M. A. Rankin 4:40 Panel Discussion. 5:10 Concluding Remarks.
General Papers T. A. Miller, Organizer,
Section C McCormick Place North Room N230B, Level 2 Development and Implementation of Learning Objectives in Chemistry Departments: A View of Progress at a Myriad of Institutions Cosponsored with CPT M. Towns, Organizer,
Educating the Laughing, Stormy, Husky Youth of the Midwest: Chicago-Area Colleges and Universities Sponsored by HIST, Cosponsored with ACS Chicago Section, PROF, and CHED THURSDAY MORNING Section A McCormick Place North Room N227A, Level 2 Chemical Evolution, Chemical Change Across Space and Time Teaching Chemical Evolution Cosponsored with GEOC, and NUCL L. Zaikowski and J. M. Friedrich, Organizers, Presiding 9:00 Introductory Remarks. 9:05 1764. On-line tools for understanding the chemical evolution of the galaxy. A. Parker, B. S. Meyer 9:35 1765. Development of laboratories for teaching basic chemical principles using techniques of radio astronomy. D. T. Halfen, A. J. Apponi, L. M. Ziurys 10:05 1766. Chemistry of Life: A course on chemical evolution for non-science majors. B. Venkataraman 10:35 Intermission.
Presiding
8:00 Introductory Remarks. 8:05 1769. Get students thinking in class: Concept tests in thermodynamics. E. D. Cranston, W. C. Galley, H-W. Li 8:25 1770. Writing component for a secondsemester, physical chemistry curriculum. J. T. Reilly, M. Strickland 8:45 1771. Discovering Markovnikov's rule. F. J. Creegan 9:05 Intermission. 9:15 1772. Asymmetric catalysis in the undergraduate research and teaching curriculum. C. M. Mascarenhas, Κ. Ε. Lazarski, A. A. Rich, Ν. Τ. Rebeck, C. T. Check, Κ. Κ. Bartgen 9:35 1773. Phenomenological explanation of metallic bonding and electrical conductiv ity. Y. Gankin, V. Gankin 9:55 1774. Chemical bath deposition of bismuth oxychloride: An experimental introduction to thin-film materials at the undergraduate and high school levels. C. L. Exstrom, J. Lahners 10:15 Intermission. 10:25 1775. Using a computer game model for teaching chemistry. K. J. Martinez-Hernandez, G. C. Weaver, C. Morales 10:45 1776. What are the effective aspects of multiple visualizations for students in learning chemistry? B. Postek, M. B. Nakhleh 11:05 1777. Molecular modeling vs. VSEPR: New trends in teaching chemical bonding and molecular geometry. Μ. Ε. Ayoub
Presiding
8:00 Introductory Remarks. 8:05 1778. Learning objectives and assess ment in chemistry and biochemistry at Utah State University. D. Farrelly 8:25 1779. Examining a chemistry major's curriculum from a learning objectives viewpoint. G. C. Weaver 8:45 1780. Developing learning goals for a chemistry program. R. M. Kelly 9:05 Intermission. 9:15 1781. Collecting data on student learn ing and using it to improve a chemistry program. J. E. Mihalick 9:35 1782. Department mission statements and assessment plans: Lessons from the trenches at an undergraduate liberal arts college. K. J. C. Muyskens 9:55 1783. Department assessment of learn ing objectives at a liberal arts college. J. L. Stewart 10:15 Intermission. 10:25 1784. Progress in developing a webbased database-driven curriculum assess ment tool. D. A. Kofke, J. R. Errington, A. Schultz 10:45 1785. ACS Exams and programmatic assessment. T. A. Holme, K. Murphy 11:05 Discussion.
Section Ε McCormick Place North Room N227B, Level 2 Bringing Research to the Undergraduate Course Curriculum N. Jacob,
Organizer
S. Lutz, Organizer,
Presiding
8:00 1795. Research experiences to enhance learning (Reel) initiative. W. J. Boone, V. Subramaniam, P. K. Dutta, P. M. Woodward 8:20 1796. Stimulating undergraduate pas sion for research. D. H. Murray 8:40 1797. Bringing research level comput ing to the undergraduate chemistry cur riculum. H.Jonsson 9:00 Intermission. 9:10 1798. Guided-inquiry-based design and construction of instrumentation in the analytical curriculum. D. Sykes 9:30 1799. Incorporation of current research in the general and organic chemistry courses and laboratories. P-T. Pham 9:50 1800. First principles determination of the formaldehyde photoelectron spectrum: A physical chemistry laboratory. E. L. Millam, R. Lord, L. Davis, S. M. E. Green, E. Brown, C. Offerman, P. Wray 10:10 Intermission. 10:20 1801. Bridging the gap: Evolving ORDER in graduate and undergraduate education. D. Lynn, D. Comeau, J. Sales 10:40 1802. Student-designed research projects in the biochemistry laboratory. D. G. Stoub 11:00 1803. Using undergraduate student research to enhance the chemistry labora tory curriculum. A. F. Charlebois
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
CHED/CHAS/CINF THURSDAY AFTERNOON
Section C
Section A
McCormick Place North Room N230B, Level 2
McCormick Place North Room N227A, Level 2
Chemical Sensors in Undergraduate and Graduate Education
Modernizing the Undergraduate Laboratory with Research and Instrumentation A. Grushow, Organizer,
Presiding
1:00 Introductory Remarks. 1:05 1804. Designing a chemistry building to increase student performance in the labo ratory. B. P. Tsai 1:25 1805. Modern chemical instrumentation in the introductory chemistry laboratory: Examples of multi-week inquiry-based projects that illustrate the power of advanced instrumentation. S. M. Drew 1:45 1806. Penn State's advanced synthetic organic and inorganic lab course. Κ. Μ. Masters 2:05 Intermission. 2:15 1807. Incorporation of authentic chemi cal separation research. Y. Zuo 2:35 1808. Organic chemistry lab at Penn State (main campus). Κ. Μ. Masters 2:55 1809. Modernizing the undergraduate laboratory with instrumentation: How much is too much? J. C. Schaumloffel 3:15 Intermission. 3:25 1810. Acquisition of instrumentation at a PUI: The story of successful back-to-back NSF MRI grants at CCSU. G. Crundwell, B. L. Westcott, N. M. Glagovich, T. R. Burkholder 3:45 1811. Meeting the state-of-the-practice in chemical instrumentation. A. Grushow Section Β McCormick Place North Room N230A, Level 2
Organizer,
1:00 Introductory Remarks. 1:05 1822. Integrating sensors into the undergraduate chemistry curriculum. C. M. Cutcher 1:25 1823. Authentic science in the under graduate laboratory: Surface attachments for biosensors. C. B. Russell, J. W. J. Slavin, J. M. Kinsella, A. Ivanisevic, G. C. Weaver 1:45 1824. Linking a gas pressure sensor to a computer simulation depicting gas behavior at the particulate level. J. I. Gelder, M. R. Abraham, K. A. Haines, K. Hammett 2:05 Intermission. 2:15 1825. Chemical sensor research at the Illinois Institute of Technology International Center for Sensor Science and Engineer ing (ICSSE). W. J. Buttner, J. R. Stetter, M. W. Findlay 2:35 1826. Design of an emission ratiometric biosensor from MerR family proteins: A sensitive and selective sensor for Hg(ll). S. V. Wegner, A. Okesli, P. Chen, C. He 2:55 1827. Ten years of an undergraduate course in chemical and biological sensors. D. C. Stone 3:15 1828. Development and optimization of rotating disk enzyme electrodes: Under graduate research projects in chemical sensors. N. J. Ronkainen-Matsuno, S. Karimi, A. Peverly, C. Prajapati, K. D. Shah, D. Wang 3:35 Concluding Remarks.
Presiding Synthesizing New Chemists: A Discussion in Practitioner Development G. Bhattacharyya, Organizer,
Section Ε McCormick Place North Room N227B, Level 2
S. Lutz,
Hyatt Regency Chicago Riverside Center
R. W . Phifer and F. K. Wood-Black, Organizers 8:00-10:00 7. Did you just see that? F. K. Wood-Black 8. Egg-ceptional safety. T. Black, F. K. Wood-Black 9. Spot the hazard: Examples of improper safety protection in common print media. F. K. Wood-Black TUESDAY MORNING Developing a Safety Plan for Teaching Chemistry in the Home School Situation Sponsored by CHED, Cosponsored with CHAS Safety and Health Issues at Small Chemical Businesses Sponsored by SCHB, Cosponsored with Chemical Safety Board, and CHAS
CHAS Division of Chemical Health and Safety D. M. Decker and S. Wawzyniecki Jr., Program Chairs
CINF Division of Chemical Information L. R. Solla, Program Chair
Organizer
N. Jacob, Organizer,
Developing a Safety Plan for Teaching Chemistry in the Home School Situa tion (see CHED, Tue)
Educating for Sustainability (see SUST, Mon)
Safety and Health Issues at Small Chemical Businesses (see SCHB, Tue)
Sustainability: A World View (see SUST, Sun)
S O C I A L EVENT: Programming Luncheon: Mon
Pressing Challenges and Technology Opportunities for a Sustainable Future (see SUST, Mon)
Presiding
1:00 Introductory Remarks. 1:05 1829. Value of research: A framework for assessing professional growth. W. J. F. Hunter, T. Higgins, G. M. Ferrence, R. House 1:30 1830. Research-enhanced vs. tradi tional courses: A comparison. W. S. Harwood 1:55 1831. Learning in the lab: What gradu ate students learn during the research phase of the Ph.D. G. Bhattacharyya 2:20 Intermission. 2:30 1832. Holistic approaches to planning undergraduate research experiences. M. L. Miller, D. Cartrette 2:55 1833. Effects of research participation on preconceptions of science practice. D. P. Cartrette, Β. Μ. Melroe 3:20 1834. Roles social factors play in undergraduate research experiences. J. J. Humston, D. I. Del Carlo 3:45 1835. Predicting products in main-group inorganic chemistry: Results of introducing a learning scheme into a descriptive inor ganic chemistry course. E. C. Gustafson, G. M. Bodner 4:10 Concluding Remarks.
Bringing Research to the Undergraduate Course Curriculum
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section A
O T H E R S Y M P O S I A O F INTEREST:
McCormick Place North Room N229, Level 2
1:00 Introductory Remarks. 1:05 1812. Advice for international faculty to teach American students chemistry. S. Xie 1:25 1813. Mexico-US collaborations in chemical education. H. Palencia, L. C. Hall 1:45 1814. Undergraduate chemistry courses at US and Middle Eastern universities: A comparative study. M. M. Bader 2:05 Intermission. 2:15 1815. Improving pedagogic strategies in analytical chemistry: Applying the action, process, object, schema theory (APOS theory) to chemical education efforts. M. Rodriguez-Lopez, A. Carrasquillo Jr. 2:35 1816. Invisible ink revealed: Chemistry and history in a chemistry lab. R. D. Sweeder, K. Macrakis, Ε. Κ. Bell 2:55 1817. Creating a customized, relevant, and engaging laboratory safety video. S. Lin, M. L. Matson, J. P. Fitzgerald 3:15 Intermission. 3:25 1818. Chemistry for students with learning disabilities. N. Sanyal 3:45 1819. Impacting the mathematics and science learning of students in New York City public schools (MSPinNYC). W. J. Boone, P. Mills, W. Sweeney 4:05 1820. Multidisciplinary engineering: A new paradigm in engineering education. J. P. Youngblood, P. C. Wankat 4:25 1821. Multistep synthesis of carboxylic acid derivatives of diphenyl ethers. M. H. Silveira, M. Q. Clark, J. V. Galloway, E. N. Konieczka, R. L. McDaniels, A. I. Paul, J. J. Petrella, G. M. Ripoll 4:45 Concluding Remarks.
M O N D A Y EVENING
OTHER SYMPOSIA O F INTEREST:
Section D
General Papers T. A. Miller, Organizer,
N. J. Ronkainen-Matsuno, Presiding
1:25 1837. Integrating authentic research into the general chem lab: Ionic liquids module. G. W. Earl, B. G. Moore, D. E. Weisshaar, M. Koppang, K. DeWitt 1:45 1838. Integrating authentic research on ionic liquids into the general chemistry laboratory at a small liberal arts college and a public university. M. Koppang, J. Meyer, J. D. Hoefelmeyer, L. Riley, M. T. Berry, K. DeWitt 2:05 Intermission. 2:15 1839. Metagenomics in the classroom: An undergraduate research laboratory. S. Lutz 2:35 1840. Development of a research seminar chemistry course to support undergraduate research at Bridgewater State College. S. A. Waratuke 2:55 1841. Special topics lab course in general chemistry: An introduction to research in materials and nanotechnology. D. M. Norton 3:15 Intermission. 3:25 1842. Application of scientific research to undergraduate lab of physical chemis try. D. He, Y. Ma 3:45 1843. Regioselective bromination of aromatic ketones: Discovery in the organic chemistry laboratory. C. E. Ballard, J. A. Struss, S. E. Allen, L. M. Carastro
Presiding
1:00 Introductory Remarks. 1:05 1836. Coherent scientific research integration into all segments of under graduate learning: A paradigm of national interest. K. Rupnik
BUSINESS M E E T I N G : Executive Committee Meeting: Sun MONDAY MORNING Section A Hyatt Regency McCormick 22C Teaching Safety: Learning By Accident G. H. Wahl Jr. and T. O. Murdock, Organizers 9:00 Introductory Remarks. 9:10 1 . Hurt egos, injured bodies, damaged laboratories: How many times does this have to happen? R. H. Hill Jr. 9:30 2. Applying human performance factors to investigations of laboratory accidents. K. B. Jeskie 9:50 3. Case histories in chemical burns. S. Wawzyniecki Jr. 10:10 Intermission. 10:25 4. Explosion in a refrigerator results in college laboratory fire. M. Metcalfe, L. Stephens 10:45 5. Perchlorates, love them, hate them: A case study. W. C. Wolsey 11:05 6. This CAT has more than nine lives. T. O. Murdock 11:25 Discussion. 11:40 Concluding Remarks.
BMGT Presents an Executive Over view of Energy Programming for the Chicago ACS Meeting (see BMGT, Sun) S O C I A L EVENTS: Luncheon: Tue Reception: Sun, Tue BUSINESS M E E T I N G S : Open Meeting. CINF Division: Mon Open Meeting. Committees on Publi cations and Chemical Abstracts: Mon SUNDAY MORNING Section A Hyatt Regency McCormick 12C/D Symposium in Honor of Gary Wiggins M. Trimarchi and A. Twiss-Brooks, Organizers 8:40 Introductory Remarks. 8:45 1 . Fanfare for an uncommon man: A tribute to Gary Wiggins' contributions to the chemical information profession. F. B. Culp 9:30 2. Changing nature of academic librarianship: Implementing a distributed institu tional repository. J. R. Garritano 10:00 3. Hands-on learning: Developing a creativity collection. T. Baldwin 10:30 4. Challenges in developing a global alerting system. L. Sandvoss 11:00 5. Corporate libraries: Evolving as the electronic resources evolve. M. J. Dunker
TECH-37
TECHNICAL PROGRAM
CINF Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin Sponsored by COMP, Cosponsored with CINF, and WCC Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Sponsored by HIST, Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF Using Social Networking Tools to Teach Chemistry Sponsored by CHED, Cosponsored with CINF SUNDAY AFTERNOON
9:30 18. Characterization of spectra and other analytical data via combination of two methods: Multivariate processing and overlap density heatmap visualization. G. M. Banik, M. D'Souza, M. Scandone 10:00 19. Novel visualization techniques for the analysis of molecular properties. J. Corkery, B. Kelley, K. Schmidt, M. McGann, R. Tolbert, A. Nicholls 10:30 20. Spectral clustering of chemical datasets. R. Guha, D. J. Wild 11:00 2 1 . Data analysis and visualization: Some case studies. D. Walter
Section Β Hyatt Regency McCormick 12B
Section A Hyatt Regency McCormick 12C/D
This One is Just Right! Information Resources for Small Colleges Cosponsored with CHED
Symposium in Honor of Gary Wiggins
A. B. Twiss-Brooks,
M. Trimarchi and A. Twiss-Brooks, Organizers
8:25 Introductory Remarks. 8:30 22. Right now, approximating just right! Chemical information resources for small/ all (Canadian) colleges and universities. L. I. Lancaster, Β. Μ. Lynch 9:00 23. Information literacy in the chemistry major: Stretching our money at Augustana College. C. Ghinazzi, D. Jensen Jr., R. Narske 9:30 24. Delivering chemical information in the age of tight budgets: Faculty and librarian cooperation at Trinity University. S. M. Bachrach, B. MacAlpine 10:00 25. SciFinder Scholar, Chemical Abstracts Student Edition or General Science Abstracts: Which should you ask your library to purchase? P. Kirkwood 10:30 26. Make the most of what you have: Use Scifinder Scholar as a collection development tool. D. R. Resetar 11:00 27. Meeting the challenge of 'The New Biology" for college libraries and librarians in the post-genomic era. F. Stoss
2:00 6. Toward a global chemical knowledge base. P. Murray-Rust 2:30 7. Integrating text and literature sources with traditional chemoinformatics tools. D. J. Wild 3:00 8. When will the evolution of chemical information on the Internet turn into a revolution? S. R. Heller 3:30 9. Promise and reality of turning chemi cal literature into information. T. N. Doman 4:00 10. Present and future of informatics in chemistry. T. W. Heritage, P. McHale, T. Hoctor 4:30 Concluding Remarks. Section Β Hyatt Regency McCormick 12 Β Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin
Organizer
MONDAY AFTERNOON Cosponsored with COMP, and WCC Section A A. Tropsha,
Organizer
O. F. Gtiner, Organizer,
Presiding
2:00 11. Bibliometric analysis of chemoinfor matics. P. Willett 2:30 12. Still searching for the perfect finger print. R. D. Brown 3:00 13. Virtual screening for new chemotypes using compound similarity mea sures. I. A. Muegge 3:30 Intermission. 3:50 14. Lead-like, drug-like or "pub-like": How different are they? T. I. Oprea 4:20 15. Computer-aided drug design: The next twenty-five years. J. Van Drie 4:50 16. What I learned from a career in computer-assisted molecular design. Y. Martin Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Sponsored by HIST, Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF Using Social Networking Tools to Teach Chemistry Sponsored by CHED, Cosponsored with CINF MONDAY MORNING
Hyatt Regency McCormick 12C/D Chemistry Applications Involving Data Analysis and Visualization Cosponsored with COMP A. J. Trippe,
Organizer
1:30 28. Analysis of documents pertaining to the phenomena of RNA interference. B. Sweet 2:00 29. Uncovering competitive technology intelligence from chemical information in patent databases. B. Stewart 2:30 30. Text visualization in chemistry: Roadblocks and rewards. J. D. Saffer 3:00 3 1 . New key-based molecular fingerprinter for visualization and data analysis in compound clustering, similarity search ing, and substructure commonality analy sis. N. E. MacCuish, J. D. MacCuish 3:30 32. Selection of commercially available lead discovery compounds potentially active against P. falciparum methionine aminopeptidase by substance analysis and clustering. A. J. Trippe 4:00 Intermission. 4:30 Open Meeting. CINF Division. 5:00 Open Meeting. Committees on Publica tions and Chemical Abstracts Service.
Hyatt Regency McCormick 12C/D Chemistry Applications Involving Data Analysis and Visualization Cosponsored with COMP A. J. Trippe,
Organizer
9:00 17. ChemDB: A public database of small molecules and related chemoinfor matics resources. J. Chen, E. Linstead, S. J. Swamidass, D. Wang, Y. Dou, P. F. Baldi
38-TECH
Section Β
TUESDAY MORNING
Hyatt Regency McCormick 12 Β
Section A
This One is Just Right! Information Resources for Small Colleges Cosponsored with CHED A. B. Twiss-Brooks,
The Evolving Network of Scientific Communication Cosponsored with COMSCI
Organizer D. P. Martinsen,
1:55 Introductory Remarks. 2:00 33. Effective teaching requires compre hensive reaction databases. V. Eigner Pitto, J. Eiblmaier, H. Kraut, H. Sailer, P. Loew 2:30 34. ChemgaPedia Enzyclopedia: A new electronic visualization program for teach ing and learning organic chemistry. G. Grethe 3:00 35. Creation of an instructional module for small college science librarians high lighting free chemistry resources and their use in undergraduate instruction. S. K. Cardinal, C. L. Newsom 3:30 36. One answer: On-line access to chemical information at community col leges, but what are the questions? R. G. Landolt Beyond the Bench: Non-Traditional Careers in Chemistry Sponsored by CHAL, Cosponsored with CHED, CINF, SCHB, WCC, and YCC M O N D A Y EVENING
Section A Hyatt Regency Chicago Riverside Center
L. R. Solla,
Organizer
8:30 Introductory Remarks. 8:35 48. Implementation of scientific "blogging" into chemical laboratory research. A. C. Fahrenbach, A. H. Flood 9:00 49. Filling the void: Organizations and social networking. D. S. Loney 9:25 50. New global communication process in thermodynamics and its impact on quality of published experimental data. M. Frenkel, R. D. Chirico, V. V. Diky, C. D. Muzny, Q. Dong, Κ. Ν. Marsh, J. H. Dymond, W. A. Wakeham, S. E. Stein, E. Koenigsberger, A. R. H. Goodwin, J. W. Magee, M. S. Thijssen, W. M. Haynes, S. Watanasiri, M. Satyro, M. Schmidt, A. I. Johns, G. R. Hardin 9:50 51. Semantic chemical publishing. N. E. Day, P. T. Corbett, P. Murray-Rust 10:15 52. Data lifecycle and curation of laboratory experimental data. T. Hey 10:40 53. Semantic wiki as a model for an intelligent chemistry journal. H. S. Rzepa 11:05 54. Standard domain ontologies: The rate limiting step for the "Next Big Change" in scientific communication. A. Renear Section Β Hyatt Regency McCormick 12B
Sci-Mix Organizer
8:00-10:00 17-18, 35. See previous listings. 37. Novel cheminformatics study of non-peptidic HIV protease inhibitors using machine learning and statistical tools. B. Bhhatarai, S. Alla, C. R. Bernier, R. Garg, S. Kumar 38. Pharmacokinetic modeling of anti-HIV protease ritonavir analogs. R. C. Kasara, B. Bhhatarai, R. Garg 39. Understanding the effect of benchmark dataset composition on the validation and optimization of ligand based virtual screen ing using self-organizing maps. S. G. Rohrer, K. Baumann 40. Data mining of NIH DTP human tumor cell line screen data for anticancer drug discovery. H. Wang, D. J. Wild 41. Method for calculating the pKa values of small and large molecules. J. Szegezdi, F. Csizmadia 42. NCL-3D: A 3-D natural compound library for computer-aided anticancer drug discov ery. Z. Hu, W. M. Southerland 43. Classification of proteomics data by kernel methods. K. Tang, T. Li 44. Fabrication of chemical and engineering devices. K. Choi 45. Gas chromatography determining 2-methylnaphthalene and 2-methylnaphthoquinone-1,4 in electrosynthesis reaction solution. S. Chengying, L. Zhisheng, W. Liucheng, Z. Jianhong, Z. Mingxing 46. Loop fitting with a combined force field and shape potential. B. P. Kelley, G. Skillman, M. Stahl, S. Wlodek, A. Nicholls 47. Optimization of LC/APCI-MS quinone isomer separation. A. Gonzalez, K. L. Foster, G. Hanrahan 48. 68, 73, 79, 8 1 . See subsequent listings.
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Hyatt Regency McCormick 12C/D
Sustainable Resources: Science and Information Sources Cosponsored with AGRO, FUEL, and SUST B. Town, L. R. Solla, and S. Swann, Organizers 8:30 Introductory Remarks. 8:35 55. Designing a new industry for sustainability: Life cycle analysis for the emerging bioeconomy. Β. Ε. Dale 9:15 56. Emerging technologies for renew able materials in the UK and EU. J. Tomkinson, A. Hamer 9:45 57. Biofuels: From an information per spective. K. Sands 10:15 58. Survey of information resources covering renewable fuels, chemicals and energy. S. Swann 10:45 Discussion. Communicating Chemistry Sponsored by CHED, Cosponsored with CINF TUESDAY AFTERNOON Section A Hyatt Regency McCormick 12C/D The Evolving Network of Scientific Communication Cosponsored with COMSCI D. P. Martinsen,
Organizer
2:00 59. Enhancing the web experience with ACS journals. E. Jabri, S. Tegen 2:25 60. Podcasting and social bookmarking at Nature. J. C. Scott, T. Hannay 2:50 6 1 . Beyond searching: Adding increased value to today's scientific data bases. M. Dennis 3:15 62. Google Scholar: The adventure continues. A. Acharya 3:40 63. Recommendation systems for research. M. F. Krellenstein 4:05 64. Collaborative filtering in a scholarly context. G. Papadopoulos 4:30 65. Modeling the scholarly community from usage data. J. Bollen
CINF/TECH/CHAL Section Β Hyatt Regency McCormick 12B Advances in 3-D Pharmacaphores and 3-D Searching O. F. Guner,
Organizer
2:00 66. Ligand binding and circular permu tation modify residue interaction network in DHFR. Z. Hu, D. Bowen, W. M. Southerland, Y. Pan, A. del Sol, R. Nussinov, B. Ma 2:30 67. Chemical superposition and phar macophore elucidation by SCAPFOId: Self-consistent atomic property field optimi zation. M. Totrov 3:00 68. Surface interaction property based similarity searching with the eHiTS Filter. D. Reid, Z. Zsoldos, B. Sadjad, A. Simon 3:30 69. Effect of query structure on specific ity for flexible 3-D searching. P. R. Wolohan, R. D. Clark 4:00 70. Adventures in shape space. P. Hawkins 4:30 7 1 . New self-organizing algorithm for molecular alignment and pharmacophore development. D. Bandyopadhyay, D. K. Agrafiotis 5:00 72. Analyzing docking results by sub structure search in euklidean space. T. Zuhl, M. Gastreich, C. Lemmen, H. ClauBen
8:30 8 1 . Something old, something new: Creating an undergraduate chemical information seminar. Τ. Μ. Vogel, B. A. Sawrey 9:00 82. Mmm...vanillin: Reaching graduate students through ice cream seminars. J. R. Garritano 9:30 83. Hands-on remote training in chemi cal information. P. Renery 10:00 Intermission. 10:10 84. Taking the graduate classroom teaching a step further. M. Shokeen, K. T. Powell, K. L. Wooley, C. J. Anderson 10:40 85. Educating graduate students in chemical information. E. Zass, M. P. Braendle 11:10 86. Librarian office hours: An old tool with a new use to improve graduate edu cation. B. Wang 11:40 87. Deconstructing molecules in an organic information course. J. N. Currano Agricultural Biomass, Biobased Products, and Biofuels Process and Product Control Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Communicating Chemistry Sponsored by CHED, Cosponsored with CINF High Throughput Screening and Drug Discovery Sponsored by MEDI, Cosponsored with CINF WEDNESDAY AFTERNOON
Agricultural Biomass, Biobased Products, and Biofuels Defining the Challenges Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Communicating Chemistry Sponsored by CHED, Cosponsored with CINF
Section A McCormick Place North Room Ν134, Level 1
Advanced Mining and Use of Life Science Information Cosponsored with CSA Trust, BIOT, BTEC, MEDI, and COMP D. J . Wild,
Organizer
8:25 Introductory Remarks. 8:30 73. Using text mining software to iden tify drug, compound, and disease relation ships in the literature. D. A. Leon 8:55 74. Descriptive and predictive models for in-vitro human cancer cell growth screens. R. Kho, M. Correll, J. Ratcliffe 9:20 75. Toward linking small molecules to biological processes in RSC publications. C. R. Batchelor 9:45 76. Applying data mining approaches to further understanding chemical effects on biological systems. C. Yang, A. M. Richard 10:10 77. Pharmaceutical^ intuitive chemical space visualization: Enabling the discovery of structural relationships and associated biologically relevant properties between substances. A. J. Trippe 10:35 Intermission. 10:45 78. Mining and visualizing the chemi cal content of large databases. H. O. Villar, M. R. Hansen, J. Hodges 11:10 79. Developing semantic web service for chemical informatics. X. Dong, D. J. Wild 11:35 80. Tiered screening protocol for the discovery of structurally diverse HIV Integrase inhibitors. R. Guha, D. Dutta, D. J. Wild, T. Chen
Agricultural Biomass, Biobased Products, and Biofuels Process Characterization Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF THURSDAY MORNING Section A McCormick Place North Room Ν134, Level 1
L. R. Solla,
Organizers
L. R. Solla,
Organizer
1:00 97. Information content in organic molecules: Brownian processing of ribonucleases. D. J. Graham, J. L. Greminger 1:30 98. Chemical Terms, a language for cheminformatics. G. Pirok, N. Maté, J. Szegezdi, Z. Mohacsi, S. Csepregi, I. Cseh, A. Szabo, M. Vargyas, F. Csizmadia 2:00 99. Accounting for 3-D descriptors of conformers in QSAR modeling. S. K. Dogra, A. Das, K. Subramanian
SOCIAL EVENT: Social Hour: Mon BUSINESS M E E T I N G : Executive Committee Meeting: Sun SUNDAY AFTERNOON Section A McCormick Place South Room S504A, Level 5 The Many Faces of CHAL: Where Chemistry Meets the Law J. J . Hasford, X. Pillai,
Agricultural Biomass, Biobased Products, and Biofuels The Cellulosic Challenge Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
TECH
Organizer
Presiding
2:00 Introductory Remarks. 2:05 1 . Can you comply with patent laws while designing new molecules to beat the competition? X. Pillai 2:35 2. Driving innovation through green chemistry legislation. J. B. Manley, P. T. Anastas, K. P. O'Brien, B. W. Cue Jr. 3:05 3. Sad aspects of Canada's war on drugs of abuse. M. Grossman 3:35 4. The Patent Register: Canada's version of the Orange Book. T. Fauconnier 4:05 Discussion. MONDAY MORNING
SOCIAL EVENTS: Dinner: Sun Social Hour: Sat, Tue BUSINESS MEETINGS: Executive Business Meeting: Mon
Strategic Planning Meeting: Mon
TECH Open Meeting: Mon M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Sci-Mix S. Bloxom,
Organizer
1. Analysis for polychlorinated biphenyls and persistent organochlorine pesticides in meconium. W. Roman, M. D. Davis, P. Morales-Α, L. Needham, D. B. Barr 2. Determination of dithiodiglycolic acid in the electroreduction process. Z. Jian-hong, Z. Zhan, W. Liu-Cheng, S. Cheng-ying, C.Jie 3. Simultaneous determination of 2-methylnaphthalene and 2-methylnaphthoquinone1,4 in reaction solution by UV spectropho tometry. S. Chengying, L. Zhisheng, W. Liucheng, Z. Jianhong, Z. Mingxing
General Papers Scientific Information Resources
9:30 94. Index to physical, chemical and other property data: What's next? Ο. Β. Sparks, L. Shackle 10:00 95. Open software and open stan dards may help cease the fire. T. Helmus, S. Kuhn, P. Murray-Rust, M. Rojas Cherto, H. S. Rzepa, O. Spjuth, C. Steinbeck, J. E. S. Wikberg, E. Willighagen 10:30 96. IUPAC name generation: Chal lenges and evaluation. D. Bonniot
F. B. Culp and L. R. Solla,
General Papers New Developments in Chemical Information
8:00-10:00
McCormick Place North Room N135, Level 1
8:25 Introductory Remarks.
McCormick Place North Room Ν134, Level 1
L. R. Dillard, Program Chair
Organizer
Section Β
On Beyond Keyword Searching: Advanced Instruction in Chemical Information Cosponsored with CHED
J. J. Hasford, Program Chair
A. B. Twiss-Brooks,
1:25 Introductory Remarks. 1:30 88. Fifty years of the International Association for Great Lakes Research. M. F. Simcik 2:00 89. Mass balance models for persistent, bioaccumulative, toxic chemicals (PBTs) in the Great Lakes: Application to Lake Ontario. J. V. DePinto, R. G. Kreis Jr. 2:30 90. Contaminant mass balance model applications in the Great Lakes: Lower Fox River/Green Bay and Lake Michigan. R. G. Kreis Jr., J. V. DePinto 3:00 Intermission. 3:10 9 1 . PBDEs and PCBs in the sediments of the Great Lakes: Distributions, trends, influencing factors, and implications. A. Li, K. Rockne, N. C. Sturchio, W. Song, J. C. Ford, D. R. Buckley, W. J. Mills 3:40 92. Great Lakes offshore biological dessert and the nearshore slime around the tub. D. C. Rockwell 4:10 93. Moving the region toward meaning ful Great Lakes restoration. K. Meyer
Division of Chemistry & the Law
Section A
Division of Chemical Technicians
Section A
CHAL I
THURSDAY AFTERNOON
Great Lakes Research: Environmental Issues for a Freshwater Ecosystem Cosponsored with ENVR, and SUST
WEDNESDAY MORNING
McCormick Place North Room Ν134, Level 1
Agricultural Biomass, Biobased Products, and Biofuels Improving Bioproduct Design Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
Section A McCormick Place South Room S504A, Level 5 Intellectual Property Issues in Solid Forms: Polymorphs, Amorphous Materials, Cocrystals and Beyond Ε. Η. Barash, Organizer,
MONDAY AFTERNOON Section A McCormick Place South Room S504A, Level 5 Beyond the Bench: Non-Traditional Careers in Chemistry Cosponsored with CHED, CINF, SCHB, WCC, and YCC J. J . Hasford, Organizer,
Organizer
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Presiding
9:00 Introductory Remarks. 9:05 5. Inventor due diligence: Preparing to talk to a patent attorney. L. A. Villanueva 9:35 6. Avoiding inequitable conduct when pursuing pharmaceutical patents. L. A. Villanueva 10:05 7. Solid form patents: Not just poly morphs anymore. Ε. Η. Barash 10:35 8. Enablement requirement for biotech and pharmaceutical patents. B. S. Gibbs 11:05 Discussion.
Presiding
1:30 Introductory Remarks. 1:35 9. Technical communication: Nontraditional career for a chemist. L. M. Balbes 2:05 10. Combining science writing and technical consulting: A satisfying career choice. J. K. Borchardt 2:35 11. Lab to lobbyist and everything in between. W. F. Carroll Jr. 3:05 12. Who wants to be a patent litigator? J. J. Hasford 3:35 13. Law student's perspective on careers in patent law. S. E. Perlinger 4:05 Discussion.
TECH-39
TECHNICAL PROGRAM
CHAL/COLL M O N D A Y EVENING
WEDNESDAY AFTERNOON
Section A
Section A
Division of Colloid & Surface Chemistry
Hyatt Regency Chicago Riverside Center
McCormick Place South Room S403B, Level 4
Sci-Mix
New Rules From the United States Patent and Trademark Office and Basic Questions of Patentability
H. M. Peters, Organizer,
Presiding
8:00-10:00
D. M. Benner, Organizer,
14. Chocolate: Food of the gods. H. M. Peters, S. Peters 15. The Lawyer Is In: CHAL's Legal Assis tance Network. C. Lippenberger TUESDAY MORNING Section A McCormick Place South Room S403B, Level 4 From Lab to Market: Protecting and Commercializing New Knowledge
OTHER SYMPOSIA OF INTEREST: 2:00 Introductory Remarks. 2:05 27. What can I patent? R. M. Schulman 2:35 28. How do I get a patent (in addition to contacting a patent attorney)? R. C. Lampe III 3:05 29. Avoiding patent unenforceability: Understanding changes to the information disclosure requirements. D. M. Benner 3:35 Discussion. THURSDAY MORNING
McCormick Place South Room S403B, Level 4
J. D. Goldhar, Organizer,
Presiding
9:00 Introductory Remarks. 9:15 16. What a chemist needs to know about patents. E. B. Flom, E. P. Gamson 10:45 Intermission. 11:00 17.1 am from Washington and I am here to help you. A. M. Ehrlich 11:30 18. From innovation to application: Marketing university technologies. L. Millar TUESDAY AFTERNOON
Section A McCormick Place South Room S403B, Level 4 From Lab to Market: Protecting and Commercializing New Knowledge Cosponsored with BMGT, and SCHB J. D. Goldhar,
Organizer
A. M. Ehrlich, Organizer,
Presiding
1:30 19. State assistance in technology transfer. J. Noel 2:00 20. An academic reports from "real world" experience: I don't wanna talk to nobody nobody sent. J. D. Goldhar 2:30 Intermission. 2:40 2 1 . Reprise: Inventing, protecting, developing, and commercializing new technology. A. M. Ehrlich
The Many Faces of CHAL: Where Chemistry Meets the Law J. J. Hasford, Organizer,
Catalysts for Biorenewable Energy Applications (see CATL, Mon) Micro/Nano Encapsulation of Active Food Ingredients (see AGFD, Mon, Tue, Wed) Nanotechnology: A Fiber Perspective (see CELL, Sun, Mon) Barry Honig 65th Birthday Sympo sium: Biological Applications of Implicit-Solvent Models (see COMP, Sun, Mon, Tue, Wed, Thu)
Cosponsored with BMGT, and SCHB Organizer
P. S. Cremer and R. Nagarajan, Program Chairs
Presiding
Section A
A. M. Ehrlich,
COLL
Presiding
9:00 Introductory Remarks. 9:05 30. Novel analytical procedures on golf patent examples: Explanation during patent prosecution. T. J. Kennedy III, M. Catania 9:35 3 1 . Will you lose your invention to the competition for failing to proofread the patent? X. Pillai 10:05 32. Lipitor: Pfizer's potential multibillion-dollar loss at the Federal Circuit. J. J. Hasford 10:35 33. Strategic use of printed publica tions for patent protection. S. P. Thompson 11:05 34. Picking a strategy for your career in business as a patent attorney. J. M. Brown 11:35 Discussion.
Environmental Characterization, Impacts and Applications of Nanocarbons (see ENVR, Sun) Carbon Nanoparticles and Nanotubes (see FUEL, Mon, Tue) Nanotechnology and the Environ ment: Focus on Green Nanotechnol ogy (see l&EC, Sun, Tue) Nanotechnology for Contaminated Site Remediation (see l&EC, Wed) Nanoscale Inorganic Catalysis (see INOR, Sun, Mon, Tue) One-dimensional Nanomaterials (see INOR, Tue, Wed) Advances in Selective Heterogeneous Catalytic Oxidation (see PETR, Tue) Dynamics on the Nanoscale (see PHYS, Tue, Wed, Thu) ACS National Awards in Physical Chemistry: Symposium in Honor of Rodney J. Bartlett, Michael D. Fayer, Jean H Futrell, Keith E. Gubbins, John T. Yates, Xiaowei Zhuang (see PHYS, Tue)
McCormick Place South Room S403B, Level 4 The Many Faces of CHAL: Where Chemistry Meets the Law J. J . Hasford, Organizer,
Presiding
ACS Award in Polymer Chemistry: Symposium in Honor of Ludwik Leibler (see POLY, Sun)
Section A McCormick Place South Room S403B, Level 4 Ensuring the Effective Patent Protection of Innovative Molecular Technology J. M. Brown, Organizer,
Presiding
8:00 Introductory Remarks. 8:05 22. Patent law basics for the molecular business. X. Pillai 8:45 23. Strategic alliances: Creating, devel oping and licensing. G. Arnold 9:25 24. 2007 Federal Circuit update: Cur rent developments in patent prosecution law—what scientists need to know. J. M. Brown 10:05 25. International patent protection and strategy. B. W. Crawford 10:45 26. Threshold intellectual property issues for the V.P. of R&D at small phar maceutical companies. S. J. Sarussi 11:25 Discussion.
40-TECH
General Papers and Segmented Block Copolymers (see POLY, Tue) Polymer Surfaces and Interfaces (see POLY, Sun, Mon, Tue, Wed, Thu) Segmented Block Copolymers (see POLY, Mon, Tue) Unconventional Processes for Nanostructured and Microstructured Poly mer Systems (see POLY, Sun, Mon, Tue, Wed) Nanostructures from Block Copoly mers and Supramolecular Polymers (see PMSE, Sun, Mon, Tue, Wed) Polymer-Based Nanoparticles and Nanostructures (see PMSE, Wed, Thu)
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
SUNDAY MORNING Section A McCormick Place South Room S404A, Level 4 Biological Surface Chemistry Lipid Bilayers Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
Organizers
8:30 1. Do proteins induce lipid domain organization? E. D. Sheets, K. Vats, A. Elegbede, A. Hinderliter 9:05 2. Controlling the shape and organiza tion of phosphatidylcholine/phosphatidic acid membranes. L. R. Cambrea, J. S. Hovis 9:25 3. Atomic force microscopy study of DPPC morphology on metal oxides. M. J. Stevens, N. Sahai 9:45 4. Pattern formation in lipid bilayers. J. S. Hovis, K. Seu, E. Lamberson, L. R. Cambrea 10:20 5. Effects of membrane associated polymers on membrane organization and dynamics in polymer sandwiched bilayers. S. Garg, J. X. Tang, R. Jordan, K. Ludtke, C. A. Naumann 10:40 6. Probing the interaction of Α β 4 0 with phospholipid/dihydrocholesterol mixed monolayers. S. M. Danauskas, E. Y. Chi, K. Y. C. Lee 11:00 7. Mineral specificity of DPPC adsorp tion on oxide surfaces. T. A. Oleson, N. Sahai 11:20 8. Reactions between vesicles observed one at a time. S. G. Boxer
McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Biomolecules T. A. Hatton,
Organizer
R. Nagarajan, Organizer,
WEDNESDAY MORNING 1:30 Introductory Remarks. 1:35 35. ACS short course: Practical approaches to patents and other forms of intellectual property. F. J. Waller 2:05 36. Overview of pharmaceutical patentANDA litigation under the Hatch-Waxman Act. J. J. Hasford 2:35 37. Worldwide inventorship issues. S. P. Thompson 3:05 38. Really crummy deals: Language surprises to avoid. P. L. Cox 3:35 Discussion.
BUSINESS MEETINGS: Executive Committee Meeting 5:00-7:00 PM: Sat Open Business Meeting 5:30-6:00 PM: Mon Program Committee Meeting 4:00-5:00 PM: Sat
Section Β
THURSDAY AFTERNOON Section A
SOCIAL EVENTS: Luncheon Noon-1:45 PM: Tue Social Hour/Poster Session 6:00-8:00 PM: Mon
Nanoscience: Characterization and Application (see INOR, Sun, Mon, Tue, Wed, Thu) Nanoscience: Synthesis (see INOR, Sun, Tue, Wed, Thu)
Presiding
8:30 9. Nanoparticle-based electrochemical DNA hybridization detection. H. S. Zhou, K. Dang 8:50 10. Maximizing DNA loading on a range of gold nanoparticle sizes. S. J. Hurst, A. K. R. Lytton-Jean, C. A. Mirkin 9:10 11. Nanoparticle-DNA conjugates bear ing defined number of short DNA strands for detection and quantitative analysis. W. Qin, L-Y. L Yung 9:30 12. Viruses: The "Whitesides-polyhedrons" from Nature's own design. Q. Wang 9:50 13. Importance of nanoparticle surface charge density for templating Brome mosaic virus capsids. L. M. Bronstein, X. Huang, J. R. Retrum, A. L. Schmucker, T. Budreau, B. D. Stein, B. Dragnea 10:10 14. Antibody conjugation to PRINT nanoparticles as a cellular targeting strat egy. R. A. Petros, A. Buntzman, L. E. Euliss, J. A. DuPont, J. A. Frelinger, J. M. DeSimone 10:30 15. Solid lipid nanoparticles of amphiphilic calixarenes: Structure, phase transi tions, loading. G. Ananchenko, M. Pojarova, M. Tomietto, K. Udachin, A. Coleman, J. Ripmeester
COLL 10:50 16. Nanopattern-directed crystallization of aspirin. G. Mao, H. Handa, D. Chen, W. Dong, D. G. Kurth, H. Mohwald 11:10 17. Bioengineered mesosphilic bacterial flagella as a toolkit for nanofabrication. M. T. Kumara, B. C. Tripp, S. Muralidharan
SUNDAY AFTERNOON
Section C
Section A
McCormick Place South Room S404D, Level 4
McCormick Place South Room S404A, Level 4
Section C
Biological Surface Chemistry Lipid Bilayers Cosponsored with PHYS
McCormick Place South Room S404D, Level 4
P. S. Cremer and G-Y. Liu,
D. Velegol and S. C. Glotzer, M. J . Solomon, Organizer,
Organizers
Structure and Dynamics at the Liquid-Liquid Interface Structuring of Water Sponsored by PHYS, Cosponsored with COLL
Presiding MONDAY MORNING
Fabrication of "Colloidal Atoms and Molecules" Assembly of Unmodified Particles S. C. Glotzer and M. J . Solomon, Organizers D. Velegol, Organizer,
Organizers
Fabrication of "Colloidal Atoms and Molecules" Assembly of Modified or Patchy Particles
4:20 67. Fundamental studies of CH 3 OH oxidation over well-defined supported V 2 0 5 catalysts. I. E. Wachs, T. J. Kim 4:50 68. Operando kinetics for designing improved catalysts. A. Corma 5:20 Concluding Remarks.
Presiding
8:30 18. Colloids in electric fields. A. van Blaaderen 9:10 19. Fabrication and packing of colloidal tetrahedra. M. T. Elsesser, A. D. Hollingsworth, D. J. Pine 9:30 20. Pyramidal nanoparticles: Fabrication, characterization, and functionalization. T. W. Odom 9:50 2 1 . In-suspension fabrication of colloidal doublets by a salting out/quenching/fusing technique. A. Yake, D. Velegol 10:10 22. The breaking of chiral symmetry using long-range electrostatic forces. K. L. Kohlstedt, G. Vernizzi, F. J. Solis, M. Olvera de la Cruz 10:30 23. Nanofluids wetting solids: Effect of structural disjoining pressure on wedge film profile. A. Nikolov, D. Wasan, K. P. Kondiparty 10:50 24. Self-assembly of metal soap molecular patterns on graphite. R. Wang, W. Dong, H. Môhwald, G. Mao 11:10 25. Assembly of colloidal spheres into well-defined and controllable structures. Y.Xia Section D
2:00 49. Gel-forming patchy colloids and network glass formers: Thermodynamic and dynamic analogies. F. Sciortino 2:40 50. Colloidal lithiography and particle decoration metrology. T. T. Chastek, S. D. Hudson 3:00 5 1 . Self-assembly of patchy particles into terminal and bulk structures. S. C. Glotzer, Z. Zhang, T. Chen 3:20 52. Janus colloids assemble into cluster shapes. L. Hong, A. Cacciuto, E. Luijten, S. Granick 3:40 53. Self-assembly of CdTe nanoparticles into sheets and wires: Role of anisotropy. Z. Zhang, Z. Tang, N. A. Kotov, S. C. Glotzer 4:00 54. Stability and self-assembly studies of a thermostable flagellin protein from Aquifex pyrophilus. S. V. Mukkamala, V. R. R. Malapaka, N. Srividya, S. Muralidharan, B. C. Tripp 4:20 55. In-solution directed assembly of heterogeneous colloidal aggregates. C. E. Snyder, A. Yake, D. Velegol 4:40 56. Step toward colloidal "molecules". D. Wang
Section Β
McCormick Place South Room S405A, Level 4
McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Quantum Dots
Section D
Nanoscience Fostered Advances in Sustainability Green Chemistry and Nanoparticle Reactivity Cosponsored with SUST S. O. Obare and J . J. Lenhart,
T. A. Hatton and R. Nagarajan, Organizers
McCormick Place South Room S405A, Level 4 Nanoscience Fostered Advances in Sustainability Sustainability in Energy Cosponsored with SUST S. O. Obare and J. J. Lenhart,
2:00 33. PCB and fullerene-decorated supported lipid bilayers. A. A. Gewirth, T. A. Spurlin, A. S. Campbell 2:35 34. Mechanism of membrane disruption by antimicrobial peptide Protegrin-1. K. L H. Lam, Y. Ishitsuka, A. J. Waring, R. I. Lehrer, K. Y. C. Lee 2:55 35. Polymer-induced flip-flop in biomembranes. A. A. Yaroslavov, N. S. Melik-Nubarov, F. M. Menger 3:15 36. Cell membrane-mediated amyloid-β fibrillogenesis and membrane disruption. E. Y. Chi, S. L. Frey, A. M. Winans, J. Majeswki, K. Kjaer, K. Y. C. Lee 3:35 37. Protein interactions on supported lipid bilayers. P. S. Cremer, S. Daniel 4:10 38. Reconstitution of bacteriorhodopsin into artificial cyclic lipid membranes. M. Shibakami, M. Nakamura, S. Miyoshi, R. Goto, M. Sonoyama, S. Mitaku 4:30 39. Developing reagents for the stabili zation of membrane proteins. Q. Zhang 4:50 40. Microstructure, phase, nucleation, and growth of lipid domains in model cell membranes. C. D. Blanchette, W-C. Lin, C. A. Orme, T. V. Ratto, M. L. Longo
Organizers
8:30 Introductory Remarks. 8:35 26. Meeting clean energy demand with nanostructure architectures. P. V. Kamat 9:05 27. Unidirectional photo-induced charge transport in templated nanostructures. T. Sehayek, A. Vaskevich, I. Rubinstein, D. Meisel 9:35 28. Enhancing sustainability with graphitic carbon nanofiber materials. C. M. Lukehart, J. Li, L Li, J. A. Michel, E. S. Steigerwalt 10:05 29. Multifunctional mesoporous nanoparticle-based catalysts and controlled release delivery systems for bioenergy applications. V. S-Y. Lin 10:35 30. Exploring nanoparticles as building blocks toward catalytic and sensing materials. C-J. Zhong 11:05 3 1 . Electron and energy transfers between nanoparticles. D. Lee, J. Kim, M. Kondon, P. M. Cox 11:35 32. Integrated, nanoarchitectured proton-exchange fuel-cell electrodes— without ionomer or carbon. C. N. Chervin, J. W. Long, K. A. Pettigrew, D. R. Rolison
R. M. Leblanc,
Presiding
2:00 4 1 . Live cell imaging with semiconduc tor and magnetic quantum dots. S. T. Selvan, P. K. Patra, G. C. Papaefthymiou, J. Y. Ying 2:20 42. Aptamer-capped nanocrystal quan tum dots: A new method for label free protein detection. J. H. Choi, Κ. Η. Chen, M. S. Strano 2:40 43. Design of quantum dot-conjugated phospholipids and membrane proteins for single molecule tracking studies. D. E. Minner, M. J. Murcia, K. Oh, K. Ritchie, C. A. Naumann 3:00 44. Aqueous synthesis of glutathionecapped ZnSe and Zn1-xCdxSe alloyed quantum dots. Y. Zheng, Z. Yang, J. Y. Ying 3:20 45. Hybrid metal/dielectric/semiconduc tor-quantum-dot nanostructures: Synthesis and characterization of semiconductormetal interactions. N. Liu, B. S. Prall, V. I. Klimov 3:40 46. Langmuir and Langmuir-Blodgett films of quantum dots. R. M. Leblanc, K. M. Gattâs-Asfura, X. Ji, J. Xu 4:00 47. Optical properties of charged quantum dots. P. P. Jha, P. Guyot-Sionnest 4:20 48. Synthesis of InP quantum dot and its surface functionalization for nanostructured solar cells. T. Zeng, J. E. Norris, T. W. Veatch
Structure and Dynamics at the Liquid-Liquid Interface Transport/Reactivity Sponsored by PHYS, Cosponsored with COLL
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizers
2:00 Introductory Remarks. 2:05 57. Green and biosafe metal nanoparticles. C. J. Murphy 2:30 58. Investigation of enhanced photocatalytic reduction and oxidation of titanium oxide nanotubes. H. Xu, H. Konishi, R. R. Yeredla, Y. Wang 2:55 59. Synthesis and aqueous-phase chemical transformations of monodisperse metallic nanoparticles in the 1-4 nm size. R. Freemantle, S. O. Obare 3:20 60. Fundamental characterization of nanoparticles and their interactions by capillary electrophoresis. S. Muralidharan, K. Du, P. Amaratunga 3:45 6 1 . Role of sulfide in aqueous solutionbased synthesis of ZnS and CdS quantum dots. N. Udawatte, S. Muralidharan 4:05 62. Green methods for synthesis of ZnS:Mn/CdS core/shell quantum dots and their characterization. K. Babcock, E. J. Sodt, S. Muralidharan Section Ε McCormick Place South Room S405B, Level 4 Gabor A. Somorjai Award for Creative Research in Catalysis: Symposium in Honor of Hans J. Freund P. C. Stair and R. J. Meyer,
Organizers
2:00 Introductory Remarks. 2:05 63. Novel catalytic materials: From nanoporous foams to nanoparticles. M. Baeumer 2:35 64. Distance dependence of the corelevel binding energy shifts in pure and mixed metal nanoparticles. P. S. Bagus, S. Yockel 3:05 65. Oxide nanostructures on metal surfaces. F. P. Netzer 3:35 Intermission. 3:50 66. High pressure studies of real and model Pd-alumina catalysts under oxida tive conditions. G. Rupprechter
Section A McCormick Place South Room S404A, Level 4 Biological Surface Chemistry Lipid Bilayers Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
Organizers
8:30 69. Evidence for condensed lipid/cholesterol complexes in lipid membranes. M. Ratajczak, S. L. Frey, E. Y. Chi, C. Ege, J. Majewski, K. Kjaer, T. Steck, Y. Lange, K. Y. C. Lee 9:05 70. Development of robust hydrogel encapsulated membranes for channel protein science and sensing. T-J. Jeon, N. Malmstadt, J. Schmidt 9:25 7 1 . Directed self-assembly of lipid bilayer membranes within a microfluidic device. N. Malmstadt, J. Poulos, J. Schmidt 9:40 72. Beta-sheet templating of amyloidbeta protein by anionic phosphatidylglycerol membranes. A. M. Winans, Ε. Υ. Chi, C. Ege, J. Majewski, K. Kjaer, K. Y. C. Lee 10:00 73. Dried foam films: Free-standing, water-free, reversed bilayers. J . Jin, I. Ichinose Sr. 10:20 74. Antimicrobial peptoid interactions with model membrane mimics at an airliquid interface. M. T. Dohm, A. Ivankin, N. P. Chongsiriwatana, C. Liu, A. E. Barron, D. Gidalevitz 10:40 75. Membrane self-assembly at struc tured surfaces. M. C. Howland, B. Sanii, A. W. Szmodis, A. M. Smith, A. N. Parikh 11:15 76. Membrane bending mechanics and cellular signal transduction. J. T. Groves Section Β McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Gold Nanoparticles R. Nagarajan,
Organizer
T. A. Hatton, Organizer,
Presiding
8:30 77. Electrospray ionization mass spec trometry for analysis of gold monolayer protected clusters with atomic precision. J. B. Tracy, M. C. Crowe, C. A. Fields-Zinna, J. F. Parker, G. Kalyuzhny, L. D. Menard, R. Balasubramanian, J-P. Choi, R. G. Nuzzo, R. W. Murray 8:50 78. Synthesis and stabilization of colloi dal gold nanoparticle suspensions for SERS. S. M. V. Tuley, C. P. Morrisey, P. H. Davis 9:10 79. Controlled chemical functionalization of gold nanoparticles. Q. Huo, Q. Dai, J. Zou, X. Liu 9:30 80. Gold nanoparticles functionalized with the tunable length thiol surfactants. Q. Li, J. M. El Khoury, X. Zhou 9:50 8 1 . Kinetic trends in triazole formation at the surface of Au nanoparticles. C. J. Thode, M. E. Williams 10:10 82. Synthesis and behavior of oligonucleotide-functionalized anisotropic gold nanostructures. J. E. Millstone, E. K. Payne, D. S. Seferos, X. Xu, C. A. Mirkin 10:30 83. Light-induced self-assembly of gold nanoparticles. R. Klajn, K. Bishop, M. Fialkowski, B. A. Grzybowski 10:50 84. Rayleigh instability in gold nanorods. C. Novo
TECH-41
TECHNICAL PROGRAM
COLL 11:10 85. Synthesis of stable, water soluble gold nanoclusters. L. L. Rouhana, J. A. Jaber, J. B. Schlenoff 11:30 86. Mechanism of place exchange reactions. A. S. Kassam, E. Fuller, G. Bremner, R. B. Lennox Section C
11:10 105. Mechanical and optical highfrequency rheology of wormlike micellar solutions. N. Willenbacher, C. Oelschlaeger, M. Schopferer, F. Scheffold, F. Cardinaux 11:30 106. Withdrawn. Section Ε
McCormick Place South Room S404D, Level 4
McCormick Place South Room S405B, Level 4
Fabrication of "Colloidal Atoms and Molecules" Fabrication of Complex Single Particle Assemblies
D. Velegol and M. J. Solomon, Organizers S. C. Glotzer, Organizer, Presiding 8:30 87. Strategies for making multicomponent, nonspherosymmetric micro-and nanostructures. B. A. Grzybowski 9:10 88. Candle and sand: Simple method to produce Janus colloidal particles with different geometry in large quantity. S. Jiang, L. Hong, S. Granick 9:30 89. Synthesis of patchy colloids: New particles with reversible, directional interac tions. D. R. Breed, V. N. Manoharan, D. J. Pine 9:50 90. Microfluidic synthesis and assembly of complex microparticles. D. Dendukuri, T. A. Hatton, P. S. Doyle 10:10 9 1 . Ultra-large scale and green syn thesis of monodisperse magnetite nanocrystals. C. T. Yavuz, J. A. Cox, C. R. Suchecki, A. A. Tran, V. L Colvin 10:30 92. Anisotropic microparticle synthesis by fluidic processing. K. Sung, D. Mukhija, S. Vanapalli, H. McHugh, J. Millunchick, M. A. Burns, M. Solomon 10:50 93. Controlling interparticle forces to guide colloidal assembly. D. Velegol 11:10 94. Shape selectivity in the assembly of lithographically-designed particles. S. Badaire, C. Cottin-Bizonne, J. W. Woody, A. D. Stroock 11:30 95. Molecular dynamics simulation of Langmuir Monolayer at air/water interface and Langmuir-Blodgett film on H-Si (111) surface of amphiphilic bistable [2]Rotaxane. S. S. Jang, W. A. Goddard 11:50 96. Ultra-sensitive chiral specific detec tion of small molecule assemblies. G. S. Goeken, N. Ingram, D. J. Kissick, A. Moad, N. Begue, R. D. Wampler, G. J. Simpson
Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Cosponsored with PHYS M. Batzill, J. G. Chen, K-H. Ernst, D. W. Goodman, R. J. Meyer, J. A. Rodriguez, P. C. Stair, and W. T. Tysoe, Organizers 8:30 Introductory Remarks. 8:40 107. Transition of metal single crystals to nanodispersed nanoparticles (1-10 nm) as model catalyst systems. G. A. Somorjai 9:10 108. Understanding trends in surface reactivity. J. K. Norskov 9:40 109. Metal atom interaction with reac tive intermediates on single crystal sur faces. R. J. Madix 10:10 Intermission. 10:25 110. Electron-stimulated processes in monolayers and condensed films. T. E. Madey 10:55 111. General trends in the electronic and chemical properties of bimetallic surfaces. J. G. Chen 11:25 112. Surface chemistry of C2 mol ecules on the Pt(111) surface. R. Deng, M. Trenary 11:55 113. Regioselectivity, stereoselectivity, and enantioselectivity in hydrocarbon conversion catalysis. F. Zaera Structure and Dynamics at the Liquid-Liquid Interface Nanoparticles Sponsored by PHYS, Cosponsored with COLL MONDAY AFTERNOON
Section A McCormick Place South Room S404A, Level 4
Section D Biological Surface Chemistry Protein Adsorption and AFM Cosponsored with PHYS
McCormick Place South Room S405A, Level 4 ACS Award in Colloid and Surface Chemistry: Symposium in Honor of William B. Russel N. J . Wagner,
Organizer
M. M. Santore, Organizer,
Presiding
8:30 97. Molecular aspects of latex film formation. M. A. Winnik, Y. Liu, J. C. Haley, W. Lau 8:50 98. Directed assembly of colloidal films, granules, and 3-D periodic structures. J. A. Lewis 9:10 99. Particle adhesion and motion on nanotextured surfaces. M. M. Santore, S. Kalasin, R. Duffadar, J. M. Davis 9:30 100. Interactions between polyelectrolyte brushes in various ionic environments. M. Tirrell 9:50 101. Microflow control strategies based on thermally-responsive triblock copoly mers. S. J. Muller, B. Stoeber, D. Liepmann 10:10 102. Spatially resolved microrheology through a liquid/liquid interface. R. Rajagopalan 10:30 103. Friction characteristics of clean hydrophilic silica surfaces in solutions of normal and high pH's. E. Taran, B. C. Donose, I. U. Vakarelski, H. Shinto, Y. Kanda, K. Higashitani 10:50 104. Diffusive permeability and selec tivity of polymeric nano-composite mem branes. R. J. Hill
42-TECH
P. S. Cremer and G-Y. Liu,
Organizers
2:00 114. Atomic force microscopy-based single cell mechanics. V. Lulevich, T. Zink, H-Y. Chen, F-T. Liu, G-Y. Liu 2:35 115. AFM study of immobilized bacte riophage and its interactions with bacteria. H. Handa, S. Gurczynski, M. Jackson, G. Auner, G. Mao 2:55 116. Bacterial surface properties of Shewanella spp. as probed by force spec troscopy and microelectrophoresis. E. Dague, J. F. Duval, M. L. Gee, J. A. Holden, R. Strugnell, F. Gaboriaud 3:15 117. A nanotumbleweed: Breaking away a covalently tethered polymer mol ecule by non-covalent interactions. Y. Deng, X. Zhu 3:35 118. Conformational changes of DNA polymerases on a microcantilever. S. L. Biswal
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
3:55 119. Guided protein delivery via two-tier AFM. R. Wang 4:15 120. Protein-mixed polymer brush interactions measured by atomic force microscopy. R. Burtovyy, O. Hoy, B. Zdyrko, R. Lupitskyy, S. Minko, I. Luzinov 4:35 121. Controlling the assembly of biologi cal nanoarrays using metal ion affinity templates and dip-pen nanolithography. R. A. Vega, C. A. Mirkin 4:55 122. Formation and characterization of homogeneous and mixed self-assembled monolayers of peptides and alkanethiols on indium phosphide surfaces. Η. Η. Park, A. Ivanisevic Section Β
Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Polymer R. Nagarajan and T. A. Hatton, Organizers Presiding
2:00 123. Preparation and controlled selfassembly of Janus magnetic nanopar ticles. M. Lattuada, T. Isojima, T. A. Hatton 2:20 124. Epoxidized nanoparticles for poly mer grafting. V. Klep, V. Tsyalkovsky, R. Lupitskyy, S. Minko, I. Luzinov 2:40 125. Functionalization of ferromagnetic nanoparticles using polymeric surfactants and assembly into 1-D mesostructures. J. Pyun 3:00 126. LCST phenomena of amphipolar copolymers in nanoparticle surface modifi cation. C. D. Eisenbach, N. Bulychev, F. Wurst, T. Schauer 3:20 127. Structural characterization of glassy and rubbery anionic amphiphilic model conetworks. G. Kali, Τ. Κ. Georgiou, B. Ivân, C. S. Patrickios, E. Loizou, Y. Thomann, J. C. Tiller 3:40 128. Polymer-inorganic nanocomposites from Si-based substrates: Applications of surface-initiated ring-opening metathesis polymerization (SI-ROMP). J-H. Kim, S. T. Nguyen 4:00 129. Polysaccharide-stabilized dispersions for nanoparticle preparation. A. Durand, E. Marie, M. Léonard, E. Dellacherie, T. A. Camesano 4:20 130. Synthesis and characterization of novel electro-active PBA-b-PSS/PEDOT nanoparticles. L. Wang, Y-W. Wang 4:40 131. Novel synthesis of nanocapsules from chitooligosaccharides and low molecular weight alginate. T. Wang, Z. Feng, N. He 5:00 132. "Frozen" block copolymer micelles as stable nanoparticles: Size and shape control via self-assembly. R. Nagarajan Section C McCormick Place South Room S404D, Level 4 Nanoscience Fostered Advances in Sustainability Environmental Remediation Cosponsored with SUST S. O. Obare and J. J. Lenhart,
Section D McCormick Place South Room S405A, Level 4 ACS Award in Colloid and Surface Chemistry: Symposium in Honor of William B. Russel M. M. Santore and N. J. Wagner, Organizers
McCormick Place South Room S404B/C, Level 4
C. S. Patrickios,
4:35 138. Organic-inorganic hybrid catalysts for environmental remediation. C. G. E. Ciptadjaya, S. O. Obare 5:05 139. Porewater velocity and collector grain size affects the mobility of surfacemodified nanoiron in water-saturated porous media. N. B. Saleh, T. Phenrat, R. D. Tilton, G. V. Lowry
Organizers
2:00 Introductory Remarks. 2:05 133. Doped metal oxide nanoparticles for environmental remediation. C. Burda 2:35 134. Electrolytic recovery of nanosized crystalline brucite from membrane residuals. J. J. Lenhart, K. Raman 3:05 135. Surfactant template-based sol-gel synthesis of mesoporous nanocrystalline T i 0 2 photocatalytic materials immobilized on supports for environmental applications. H. Choi, Y. Chen, D. D. Dionysiou 3:35 136. Nanoparticle size effects on the microbial iron reduction. B. Yan, D. E. Giammar, B. Wrenn, B. Pratim 4:05 137. Sequestration of metal cations with nanoscale zero-valent iron (nZVI). X-Q. Li, W.Zhang
H. J. Ploehn,
Presiding
2:00 140. Structure, rheology, and migration in concentrated suspensions. D. T. Leighton Jr., A. Ramachandran 2:20 141. Granular matter and complex systems. J. M. Ottino 2:40 142. The three viscosities. A. Khair, J. F. Brady 3:00 143. Microstructure and rheology of shear thinning and thickening near hard sphere colloidal suspensions. N. Wagner, D. Kalman, L. Porcar 3:20 144. Yielding and aging of soft colloidal glasses. E. Stiakakis, M. E. Helgeson, G. Petekidis, N. J. Wagner, C. N. Likos, D. Vlassopoulos 3:40 145. From attractive glasses to lowdensity gels in colloidal dispersions with short-range attractive interactions. J. Bergenholtz 4:00 146. Withdrawn. 4:20 147. Effects of interparticle interactions and applied fields on colloidal gel. M. J. Solomon, C. Dibble, M. Kogan 4:40 148. Colloidal crystal nucleation rate measurements. Z. Cheng 5:00 149. Electrostatic patterns in particles, films and monoliths: Effect on particle adhesion. F. Galembeck, L. F. Valadares, F. C. Bragança, C. Silva, R. F. Gouveia, C. Rezende Section Ε McCormick Place South Room S405B, Level 4 Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Cosponsored with PHYS M. Batzill, J. G. Chen, K-H. Ernst, D. W. Goodman, R. J. Meyer, J. A. Rodriguez, P. C. Stair, and W. T. Tysoe, Organizers 2:00 150. Probing reaction pathways on model catalyst surfaces: Vinyl acetate synthesis and olefin metathesis. W. T. Tysoe, F. Gao, Y. Wang, F. C. Calaza, D. Stacchiola 2:30 151. Composition of, and reaction chemistry at, aqueous solution surfaces. J. C. Hemminger 3:00 152. Functionalization of hydrocarbons promoted by oxidized Au(111) and Ag(110). C M . Friend, X.Deng, T. A. Baker, X. Liu 3:30 Intermission. 3:45 153. Diffusion of species on Ti02(110). J. M. White, Z. Dohnâlek, B. D. Kay, Z. Zhang, Q. Ge, S-C. Li 4:15 154. Role of DFT calculations for the design of new catalytic materials: From oxide thin films to doped photoactive oxides. G. Pacchioni 4:45 155. Nature of supported vanadium oxide. P. C. Stair, M. J. Bedzyk, Z. Wu, H-S. Kim, C. Y. Kim
COLL M O N D A Y EVENING Section A Sheraton Chicago River Exhibit Hall Fundamental Research in Colloid and Surface Chemistry Posters R. Nagarajan,
Organizer
6:00-8:00 156. Polymer-micelle complex as an aid to electrospinning nanofibers from aqueous solutions. R. Nagarajan, C. Drew, C. M. Mello 157. Cell-penetrating quantum dots based on multivalent and endosomolytic surface coatings. H. Duan, S. Nie 158. Highly selective anthrax sniffer for homeland security and public safety. Y. Zhou, K.M. Levon 159. Surface plasmon resonance sensing based on nanometric holes in thin gold films. A. Gunnarsson, T. Rindzevicius, Y. Alaverdyan, B. Sepulveda, M. Kail 160. Microfluidic platforms for membrane protein crystallization. S. L. Perry, G. Roberts, J. Tice, P. J. A. Kenis 161. Real time qualitative and quantitative evaluations of the adsorbed Concanavalin A layer on polymeric and functionalized surfaces. J. Dong, E. Mielczarski, J. Rybka, J. A. Mielczarski 162. 2-D Molecular imprinting of proteins via polymer brush approach. O. Hoy, B. Zdyrko, I. Luzinov 163. 3-Dim. growth of well-ordered cubic (RSÎ01.5)8 silsesquioxane powders from 0-dim. nanosized spherical particles. C. Y. Jung, C. G. Kim, S. M. Koo 164. A branched hybrid: Inducing fatty acid nanorods from nanoparticles. R. Wang, I. U. Arachchige, S. L. Brock 165. A comparison of cholesterol and 7-ketocholesterol's packing behavior in phospholipid monolayers at the air-water interface. L. Burkemper, A. B. Serfis 166. A novel method in the investigation of the interaction of Glutathione and Glutathione-S-transferase with surface plasmon resonance. L. Chen 167. A study of interactions between blood composition and heparinized polyethersulfone biomembrane surfaces: Characteristics of protein adsorption and platelet adhesion. D. Huo, C. Hou, D. Zhan, Q. Yuan 168. Adlayer structure and copper deposition of a Au(111 ) electrode modified by bis(3sulfopropyl) disfulride and mercaptopropylsulfonic acid. T-Y. Cheng, Y-C. Yang, W-P. Dow, Y-L. Lee 169. Adsorption of nitrogen oxide on immersion modified activated carbon fiber felt. X. Song Sr., C. Wang 170. Adsorption of polyelectrolyte single molecules vs. surface charge: Intact AFM study under liquid. Y. Roiter, S. Minko 171. Adsorption studies of cytochrome c to a silica nanoparticle surface. C. A. Hedge, T. A. Hopkins, G. C. Hoops, M-C. Su 172. An oil in surfactant emulsion and waterless emulsions. A. AI Bawab 173. Analysis of colloid nanoparticle suspensions via acoustic method. B. B. Damdinov, T. S. Dembelova, B. B. Badmaev 174. Analysis of the effect of nonpolar lipids on the milk fat globule membrane. C. R. Cabrai, P. J. Krommenhoek, D. E. Gragson, J. P. Hagen III, R. Jimenez-Flores 175. Barcoded nanowires: Surface chemistry for pathogen detection. S. E. Brunker, C. D. Keating 176. Cellular uptake of neutral, anionic, cationic, and targeted PRINT hydrogel nanoparticles. P. D. Pohlhaus, S. E. A. Gratton, J. DeSimone 177. Characterization of alkyne-functionalized silicon surfaces. K. E. Plass, P. T. Hurley, E. J. Nemanick, B. B. Brunschwig, N. S. Lewis 178. Characterization of Langmuir monolayers of phospolipids and oxysterol. J. Fraser, A. Serfis
179. Charge effects on gold nanoparticlebased drug delivery. G. Han, B-J. Kim, A. Chompoosor, N. S. Forbes, V. Rotello 180. Chemically modified AFM tips for distinguishing nanoscale drug and block copolymer domains in biomedical coatings. J. Dong, G. D. Haugstad 181. Click chemistry as an efficient method for chemoselective modification of tobacco mosaic virus. M. A. Bruckman, G. Kaur, M. Joralemon, T. Emrick, Q. Wang 182. Clouding feature for water + betaine + polyethylene glycol) + Salt) quaternary mixtures. X. You, W. Qin, Y. Ding, Y. Dai 183. CO adsorption on hydrated Ru catalysts. K. A. Layman, D. Gottschalk, E. A. Hinson, N. Wood 184. Complexation of fullerenes on a pentacene-modified Au(111) surface. Y-C. Yang, Y-L. Lee 185. Conducting probe atomic force microscopy measurements of 1, 4 phenyldiisocyanide based molecular wires. Z. Habeeb, J. A. Boscoboinik, T. A. Siddiquee, D. W. Bennett, W. T. Tysoe 186. Controlled nanoparticle assemblies for modulating optical and magnetic properties. S. Srivastava, A. Verma, B. L. Frankamp, V. Rotello 187. Critical brush density and critical salt concentration for polyelectrolyte brush at the air/water interface. H. Matsuoka, P. Kaewsaiha, Y. Suetomi, T. Yamada 188. Crown-ether films as sensors for ions in solution. L. E. Russell, A. A. Galyean, M. C. Leopold 189. Delivery of proteins to a protein-patterned surface. D. Qiu, R. Wang 190. Density functional theory calculations for the hydrogen evolution reaction in an electrochemical double layer on the Pt(111) electrode. E. Skulason, G. Karlberg, J. Rossmeisl, T. Bligaard, J. P. Greeley, H. Jonsson, J. K. Norskov 191. Deposition and aggregation of aspirin on lipid bilayer. H. Handa, G. Mao, H. Mohwald 192. Design and fabrication of size-tunable porous electrode nanoarchitectures for energy storage. A. J. Barrow, J. C. Lytle, A. N. Capecelatro, A. E. Fischer, J. W. Long, D. R. Rolison 193. Determination of the structures and protonation states of surface phosphate complexes formed on aluminum oxides from their characteristic adsorption behaviors. X. Huang, G. D. Foster, R. V. Honeychuck, J. A. Schriefels 194. Developing chemically modified electrodes for bioelectrocatalysis. M. Watt, S. D. Minteer 195. Development of microemulsion templates for formation of metal microstructures. R. L. Woo, J. Manning, B. O'Neal, L. MacKenzie, R. Campbell, M. G. Bakker 196. Effect of drug solubilized in a novel cubic nanostructure. R. Efrat, A. Aserin, D. E. Shalev, R. E. Hoffman, N. Garti 197. Effect of potassium perfluorooctanesulfonate, perfluorooctanoate and octanesulfonate on the phase transition of dipalmitoylphosphatidylcholine (DPPC) bilayers. W. Xie, H-J. Lehmler 198. Effects of additives on the behaviors of viscoelastic surfactant systems. S. Lu, Ζ. Wei, P. Somasundaran 199. Electrochemical and optical spectro scopic characterization of two-component self-assembled monolayers on gold sur faces. H. Liu, T. Ugur, C. Shannon 200. Electrochemical DNA biosensor arrays using functionalized polystyrene films. M. Diaz-Serrano, K. Rivero-Rodriguez, A. Rosado-Gomez, E. Vega-Bermudez, A. R. Guadalupe 201. Electron transport in gold nanoparticle films investigated by scanning electro chemical microscopy. V. Stoycheva, D.Lee 202. Encapsulation using hybrid nanoparticlebionanoparticle assemblies. R. Tangirala, Y. Hu, M. Joralemon, T. P. Russell, T. Emrick 203. Engineering structure and function of polymeric nanocomposites. H. Xu, Y. Ofir, T. Lu, V. M. Rotello
204. Enzymatically synthesized polyaniline and polypyrrole colloids: An XPS, FTIR, and TEM study. R. Cruz-Silva, M. E. Nicho, J. Romero-Garcia, S. Sepulveda-Guzman, F. F. Castillon, M. H. Farias 205. Fabrication and design of multifunctional nanoparticles. W. Hasan, J. Lee, T. W. Odom 206. Facile fabrication of polymeric nanohair structures with high aspect ratio. D. Y. Lee, D. J. Ok, D. H. Lee, K. Cho 207. Formation and decomposition of C-3 metallacycles from ethylene and methy lene on MoAl alloy thin films. F. Gao, Y. Wang, W. T. Tysoe 208. Formation of gradient morphology in emulsifier-free latex blend films of fluorinated ant fluorine-free acrylate. Y. Chen, C. Zhang 209. Functionalization of calcium aluminate ceramic surface with biologically active molecules. B. F. DiSalle, S. Hott, E. S. Gawalt, K. A. McGowan 210. Gemini surfactant capped CdSe/ZnS quantum dots as a bioprobe for cell imag ing. H. Li 211. Generation and characterization of multi-component protein patterns. T. Kim, R. Wang 212. Growth and surface modification of silicon-filled nanopits on highly oriented pyrolytic graphite (HOPG): Parallels with surface chemistry of single crystalline silicon. T. R. Leftwich, S. P. Sullivan, X. C. Zhang, T. P. Beebe Jr., A. V. Teplyakov 213. High-throughput synthesis of colloidal particles with anisotropic properties and their DNA directed assembly. J. H. Moon, A. J. Kim, J. C. Crocker, S. Yang 214. Horizontal opals and vertical substrates: The role of the liquid-air interface in verti cal deposition. R. G. Shimmin, A. J. DiMauro, P. V. Braun 215. Hyperthermal 0 + induced etching of polyhedral oligosilsequioxane (POSS) monolayer and multilayer on Au(111). X. Liu, T. Tzvetkov, D. C. Jacobs 216. I am GaN. GaN I am. Will I form a stable SAM? C. Arisio, M. Lieberman 217. Immobilization of enzymes in porous gold. O. V. Shulga, K. Jefferson, M. C. Parlato, A. V. Demchenko, J. Liu, K. J. Stine 218. Imparting size control on materials for nanomedicine: An assessment of the effect of PRINT particle size on in vivo biodistribution. S. E. A. Gratton, P. D. Pohlhaus, J. Lee, M. J. Cho, J. M. DeSimone 219. In situ monitoring of salt-induced disas sembly of redox-sensitive DNA/poypeptide polyplexes. L. Wan, D. S. Mannickam, G.Mao 220. Influence of surface hydrophobicity on immobilized lipase activity. J. A. Laszlo, K. Evans 221. Influence of the atom-surface potential for stability of commensurate monolayers on well-ordered surfaces. A. Tkatchenko, N. Batina, M. Galvân 222. Influence of the shape of silver and gold nanoparticles on the surface-enhanced Raman scattering detection limit of biomolecules. A. Ray, G. K. Darbha, P. Ray 223. Interaction of potassium perfluorooctanesulfonate and perfluorooctanoate with phosphatidylcholine vesicle membranes: Fluorescence anisotropy study. W. Xie, H-J. Lehmler 224. Interaction of the disease-associated prion protein with quartz surfaces. X. Ma, D. I. McKenzie, J. M. Aiken, J. A. Pedersen 225. Intracellular delivery of siRNA with PRINT nanoparticles. A. J. Murphy, J. An, A. L. Galloway, M. J. Cho, J. DeSimone
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
226. Kinetic investigation of glucose oxidase reaction with a surface tethered N-hydroxysuccinimide ester using surface plasmon resonance. A. A. Deckert, H. Carlberg 227. Label-free DNA detection using polydiacetylene-based fluorescent sensors. G. S. Lee, E. J. Kim, D. H. Yang, J-M. Kim, D.J. Ann 228. Lateral distribution of surfactants in waterborne pressure sensitive adhesive films: Theory and experiment. C-H. Lei, K. Ouzineb, O. Dupont, A. F. Routh, V. Gundabala, S. Hinder, J. Keddie 229. Light-induced charge separation across bioinorganic interface. N. M. Dimitrijevic, Z. V. Saponjic, T. Rajh 230. Liposomes with crosslinked polymer shells: A highly stable drug-delivery system. S-M. Lee, T. V. O'Halloran, S. T. Nguyen 231. Low-energy electron-induced oligomerization of condensed carbon tetrachloride. L. D. Weeks, L. Zhu, M. Pellon, D. R. Haines, C. R. Arumainayagam 232. Mechanism and growth kinetic study of gold nanoparticles. X. Liu, Q. Huo, Q. Dai, J. Zou 233. Microwave-assisted rapid preparation of V-MCM-41 materials by hydrothermal synthesis. J. Q. Xu, W. Chu, S. Z. Luo 234. Modification of the NIR signal of textile fabrics via colloidal self-assembly. C. M. Diaz 235. Monolayer-protected nanoparticle film assemblies as platforms for protein monolayer electrochemistry: Interfacial adsorption considerations. A. Loftus, M. C. Leopold 236. Monolayer-protected nanoparticle film assemblies as platforms for protein monolayer electrochemistry: Signal-to-noise considerations. K. P. Reighard, M. C. Leopold 237. Monte Carlo simulation of microstructure of polyelectrolyte around oppositely charged macroions. D. Cao, R. Ni 238. Multi-dimensional nanoparticle assembly through supramolecular hydrogen-bonded scaffolds. S. Kinge, M. Crego-Calama, D. Reinhoudt 239. Nanoengineered halloysite tubules for controlled release of drugs and proteins. A. A. Darrat, N. G. Veerabadran, S. S. Balkundi, Y. M. Lvov 240. Nanoparticle interfacial assembly using PEGylated gold nanoparticles. E. Glogowski, R. Tangirala, J. He, T. P. Russell, T. Emrick 241. Nanoparticle synthesis using porous polyelectrolyte thin films. H-J. Jeong, S. Y. Yang 242. Nanoparticle-based optical probes for · chemical imaging. C. Thompson, D. Finley, M. Holt, C. J. A. Daley, S. R. Emory 243. Nanoparticle-mediated refolding of thermally denatured proteins. M. De, V. M. Rotello 244. Nanotechnology for colloidal chemistry. Κ. Μ. Choi 245. Novel anionic gemini surfactants with sulfonic groups: Synthesis, surface proper ties, and application. C. Li, J. Yang, Y. Ding, G. Chen 246. Novel synthesis of nanospheres by self-assembly of random copolymers in supercritical carbon dioxide. E. Yoshida, A. Nagakubo 247. Original height and compression elastic ity of chloroplast DNA with contact and tapping atomic force microscope. J. Zhu, G. Wang, B. Zhang, D. He 248. pH Dependent clustering of PAA coated gold nanoparticles. T. Isojima, A. Hatton 249. Physiochemical properties of magnetic iron oxide composites. A. M. Jones, K. A. Layman 250. Polydiacetylene vesicle application for cell detection on chip. H. Choi, K. W. Kim, J. E. Sohn, M. K. Oh, G. S. Lee, J-M. Kim, D. J. Ahn 251. Polymer electrolytes confined in nanoporous membranes: Mixed ionic electronic conductor composites. N. H. Truong, P. L. Johnson, D. Teeters 252. Polymer nanoparticles synthesized from amphiphilic block copolymers as probes for DNA detection. B. R. Stepp, M. Boyle, S. Srinivasan, D. Smith, J. G. Davis, S. T. Nguyen
TECH-43
COLL 253. Preparation and characterization of conjugated organic molecules on H-passivated silicon surfaces. J-H. Kim, J. Kellar, J-C. Lin, R. Verma, M. J. Bedzyk, M. C. Hersam, S. T. Nguyen 254. Preparation and characterization of nitrogen-doped. B-C. Hsu, Y-T. Liu, S-S. Chen, C. Su 255. Preparation and characterization of polyelectrolyte-coated gold nanoparticles. A. C. Dorris, S. Rucareanu, C. J. Barrett, L. Reven, R. B. Lennox 256. Preparation of hollow cobalt ferrite nano particles. Q. K. Ong, C. Kuebel, A. L. Oldenburg, A. Wei 257. Preparation, characterization and proper ties of Au/Pd surface alloy on Pd (111). Z. Li, F. Gao, F. C. Calaza, L. A. Burkholder, W. Tysoe 258. Pressure tuning the optical transmission properties of photonic bandgap compos ites. Y. Ying, J. Xia, P. Rungta, S. Foulger 259. Protein adsorption and cell attachment/ spreading on gradient surfaces of polyeth ylene glycol) generated by the contact printing approach. Y. Cai, Y. H. Yun, B. M. Zhang Newby 260. Protein-resistant surfaces based on dithiocarbamate assembly. H. Zhu, A. Wei, J. Irudayaraj 261. Quasielastic neutron scattering and molecular dynamics studies of structure and dynamics of surface water on nanopowder rutile and cassiterite. E. Mamontov, L. Vlcek, D. J. Wesolowski, P. T. Cummings, W. Wang, J. Rosenqvist, C. M. Brown, V. Garcia Sakai, D. R. Cole 262. Recent advances in the studies of CdSe magic clusters. Y. A. Barnakov, C. E. Bonner Jr., A. Kasuya, Y. Noda, R. Sivamohan, R. Belosludov, Y. Kawazoe, I. Dmitruk, V. Romanyuk 263. Redox-assisted flavin motion of FMNfunctionalized single walled carbon nanotubes. S-Y. Ju, F. Papadimitrakopoulos 264. Refractive index engineering of the transparent film based on siloxane poly mer-dispersed Zr02 nanoparticle. H-J. Shin, S. J. Choi, S-M. Yoon, D. Yi, J-Y. Choi 265. Restoring gene expression with PRINT nanoparticles. A. L. Galloway, A. J. Murphy, P. L. Sazani, R. Kole, J. M. DeSimone 266. Salt-dependent adsorption of pectin on bovine serum albumin surface studied by quartz crystal microbalance with dissipa tion monitoring. X. Wang, Y-W. Wang, Q. Huang 267. SAM derivatization with a fluorescent ruthenium complex by topotactic photopolymerization. B. Wetmore, L. L. Wright, T. Hanks 268. SAXS/GISAXS study on nanobio par ticles: Structural deformations induced by interactions with solid substrates. B. Lee, Z. Niu, Q. Wang, C-T. Lo, P. Thiyagarajan 269. Scanning tunneling microscopy and spectroscopy studies of dinuclear organometallic molecules. S. Guo, Z. Wei, S. A. Kandel 270. Selective colloidal stabilization of doped single wall carbon nanotubes. S. N. Kim, Z. Luo, F. Papadimitrakopoulos 271. Self-assembled monolayers of alkyl tethered π moieties. L. C. Teague, E. Hinson, W. R. Kwochka, J. G. Kushmerick 272. Self-assembled pentammine cobaltterminated monolayers with two types of scissile bonds: Characterization and litho graphic processing. K. Sarveswaran, M. Lieberman 273. Self-assembly and controlled assembly of nanoparticles. L. M. Dillenback, A. Yake, D. Triplett, D. Velegol, K. A. Fichthorn, C. D. Keating
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44-TECH
TECHNICAL PROGRAM 274. Self-assembly properties of pore-forming amphiphilic peptides. L. You, G. W. Gokel 275. Self-induced 1-D molecular chain growth of thiophene on Ge(100). S. M. Jeon, H. Lee, S. J. Jung, D. K. Lim, S. I. Kim, S.Kim 276. Single liposome tracking in dense sus pensions of stabilized liposomes. Y. Yu, S. M. Anthony, L. Zhang, S. Granick 277. Spatially-resolved product formation in the reaction of formic acid with singlecrystal calcium carbonate: The role of step density and adsorbed water-assisted ion mobility. C. R. Usher, J. Baltrusaitis, V. H. Grassian 278. Stimuli responsive drug-conjugated polymer nanoparticles via ring-opening metathesis polymerization. D. Smith, S. Clark, T. R. Holden, P. A. Bertin, C. K-F. Shen, B. Mirkin, S. T. Nguyen 279. Structural evolution and shear banding in self-assembled worm-like micellar solu tions. M. E. Helgeson, P. A. Vasquez, N. J. Wagner, E. W. Kaler, P. L. Cook, L. Porcar 280. Structure and phase behavior of mixed alkanethiol and biphenylthiol self-as sembled monolayers on gold films. J. W. Rivard III, D. A. Hall, E. L Bullock 281. Studies on the self-assembled mono layer of 2-(terthienyl)phosphonic acid on Ti02 thin film. C. W. Hsu 282. Study of conjugation of proteins with gold colloidal nanoparticles. K. Yokoyama, D. Sri Hartati, W. S. M. Tsang 283. Study of gold colloidal nanoparticles embedded in a silica-based sol-gel. P. Kogan, T. M. Gilbert, J. R. Swana, K. Yokoyama 284. Study of mechanical properties of insulin amyloid fibrils and crystals by AFM nanoindentation. S. Guo, B. B. Akhremitchev 285. Study of the formation of self-assembled monolayers on nitinol. R. Quinones, E. S. Gawalt 286. Surface enhancement of Raman scatter ing using substrates patterned by nanopar ticle assembly and e-beam lithography. S. I. Kim, J-H. Kang, Y-H. Lee, S. Kim 287. Surface modification and characterization of POSS-based acrylic thin films. K. Zimmermann, Β. Η. Augustine, W. C. Hughes, A. J. Figueiredo, C. C. Chusuei 288. Surface modification as a means to alter adsorption and decomposition mecha nisms of metallorganic compounds on semiconductors: Tetrakis-(dimethylamino)-titanium on clean and ammoniamodified silicon surfaces. J. C. F. Rodriguez-Reyes, A. V. Teplyakov 289. Surface modifications for biosensor applications. F. Shen, J. Genzer, O. J. Rojas, P. V. Gurgel, R. G. Carbonell 290. Withdrawn. 291. Surfaces and interfaces of high explo sives probed by nonlinear optical spectros copy. S. E. Surber, A. Lozano, A. Lagutchev, D. D. Dlott 292. Suspended self-assembled opal mem branes. A. K. Bohaty, I. Zharov 293. Synergistic effects in antimicrobial poly mers: Synthesis, characterization, and antimicrobial testing. K. R. Keller 294. Synthesis and characterization of ω-func tional alkylphosphonic acids to be used as self-assembling monolayers on titanium dioxide. V. Dougherty, D. Johnson 295. Synthesis and characterization of alkanethiolate monolayer-protected Au38 clusters. J . Kim, K. Lema, M. Ukaigwe, D. Lee 296. Synthesis of responsive fluorescent nanoparticles. V. Tsyalkovsky, V. Klep, R. Lupitskyy, S. Minko, I. Luzinov 297. Synthesis of thiophene derivatives and their applications in developing tobacco mosaic virus composite fibers. S. Li, Z. Niu, M. Bruckman, Q. Wang 298. Synthesis, characterization and optical spectroscopy of silver nanoprisms. G. K. Darbha, A. Ray, P. Ray 299. Templated synthesis of cobalt nanopar ticles from a Co16-resorcinarene complex. J. Liu, A. Wei
300. The deposition morphology of Brownian/ non-Brownian particles within a constricted tube. Y-l. Chang 301. The effects of including N-terminally alkylated peptoid mimics of lung surfactant protein C on the in vitro surface activity of mixed lipid-peptoid films. Μ. Τ. Dohm, A. Ivankin, N. J. Brown, C. Liu, D. Gidalevitz, A. E. Barron 302. The use of artificial neural network (ANN) as well as various mathematically formulae to rank the applicability of pro posed models for attaining the surface free energy of powders. S. Ahadian, S. Moradian, M. Mohseni 303. Toxic metal ion removal by coated acti vated carbon. C Burrel, A. Omoike 304. Unusual magnetic properties of PbS nanoparticles bound via 1,8-octanedithiol to a p-type of GaAs surface. A. Zakrassov, G. Leitus, S. Cohen, R. Naaman 305. Vesicle-forming iodine contrast agents. D. B. Elrod, R. Partha, D. Danila, S. W. Casscells, J. L. Conyers 306. Waterborne nanocomposite pressuresensitive adhesives: Achieving enhanced adhesion combined with electrical conduc tivity. T. Wang, C-H. Lei, A. B. Dalton, M. Manea, J. Asua, J. L. Keddie 307. Improved nanodiamond solvent formula tions. S. C. Hens, S. L. Wallen, V. Grichko, G. B. Cunningham, M. Casulli, O. Shenderova Section Β Sheraton Chicago River Exhibit Hall Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Posters R. Nagarajan and T. A. Hatton, Organizers 6:00-8:00 308. Protein capture and detection with bioconjugate nanodiamond probes. S. C. Hens, G. B. Cunningham, V. Grichko, O. Shenderova 309. "Hairy" magnetic micro and nanoparticles for diagnostic applications. V. Audonnet, L. Koreckâ, B. De Lambert, Z. Bilkova, J-L. Viovy 310. Core-shell nanostructures: Titanium on silica. L. Zhou, M. Ramirez-Huerta, M. D. Soucek 311. Micron-sized crystallites from Ag nanocrystals embedded in a film. D. D. Johnson Jr., B. C. Tway, W. Sohn, J. L. Vigorita, E. M. Spain 312. Study on copper-cobalt-based catalysts promoted by plasma for higher alcohols synthesis. L. Huang, J. Li, J. Liu, W. Chu 313. Dendrimer-mediated synthesis of magnetic nanoparticles: CoPt. H. Wan, L. Bai, G. Β. Thompson, M. Shamsuzzoha, S. C. Street Section C Sheraton Chicago River Exhibit Hall Biological Surface Chemistry Posters Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
Organizers
6:00-8:00 314. Cellular interactions on nanostructured polyelectrolyte multilayers. J-Y. Seo, W-H. Pyun, S. Y. Yang 315. Exchange reactions in lipid vesiclepolyelectrolyte system. E. G. Yaroslavova, A. V. Sybachin, E. A. Litmanovich, A. A. Yaroslavov 316. Exploring chemistry of bacterial prédation using external measurements of bdelloplasts formed from heat-killed and UVkilled Escherichia coli. J. Schmitt, M. A. Ferguson, Ε. Μ. Spain 317. Molecular recognition of chromophore molecules. R. Flores, A. Ivanisevic 318. Multiple cleavages of metal-coated DNA on a surface. A. Ivanisevic, J. W. J. Slavin 319. On-chip synthesis, assay, and label-free detection of peptide arrays. A. H. Eisenberg, S. Kigar, M. Mrksich
320. Protein recruitment to raft domains: A planar model membrane study. A. C. Kimble-Hill, C. A. Naumann 321. Research of neutral deinking agents. W. Liucheng, C. Jie, Z. Jianhong, S. Chengying, Z. Zhan 322. Supported planar lipid bilayers on T i 0 2 and S i 0 2 surfaces: Effects of surface atomic structures and chemical species. R. Tero, T. Ujihara, H. Watanabe, T. Urisu Section D Sheraton Chicago River Exhibit Hall Catalysis Posters Cosponsored with CATL R. Nagarajan,
Presiding
6:00-8:00 323. A novel catalyst for liquid phase oxida tion of glyoxal to glyoxylic acid. Y. Niu, R.Li 324. A theoretical study of the Heck Reaction: N-heterocyclic carbene vs. phosphine ligands. C-H. Hu 325. FT-Raman spectroscopy quantification of biodiesel in a progressive transesterification reaction and its correlation with 1H NMR spectroscopy methods. G. F. Ghesti, J. L. D. Macedo, I. S. Resck, S. C. L Dias, J. A. Dias 326. Metalloporphyrins catalysts anchored on MCM-41 for the selective oxidation of cycloexene. A. A. Costa, J. L. D. Macedo, V. S. Braga, J. A. Dias, S. C. L. Dias, M. M. Santos 327. Molecular beam scattering of alkanes on carbon nanotubes. S. Funk, U. Burghaus, B. White, S. O'Brien, N. Turro 328. Withdrawn. 329. Selective oxidation of cyclohexene over reaction-controlled phase-transfer catalyst with hydrogen peroxide. Z. Weng, X. Jian, J. Wang 330. Study on the interaction between ten kinds of proteins and biomembrane. J. Jiang 331. Synthesis and application of CuO/ Nb205/Si02-AI203 on elimination of diesel soot particulates. J . A. Dias, F. A. C. Garcia, V. S. Braga 332. The effect of reduction properties of sepiolite-supported ruthenium catalysts for ammonia synthesis. Z. Le, R. Ruan, Y. Huang, K. Wei 333. Withdrawn. 334. Trireforming of methane to syngas over supported carbide catalysts. H. Jiang, H. Li, Y. Zhang 335. Trypsin inhibitors screening by biologi cally functionalized chromatography with on-line immobilized enzyme. Y. Y. Liu, R. Dai, F. Qu, L Geng, Y. Deng 336. Adsorption of CO on Ge(100) at room temperature. J. Choi, J. Ryou, Y. S. Youn, S. Hong, S. Kim 337. C 0 2 adsorption on Cr2O3(0001)/ Cr(110). S. Funk, B. Hokkanen, T. Nurkic, U. Burghaus 338. Enantioselectivity and structure of a chiraly templated surface: 2-Butanol on Pd(111). L. A. Burkholder, W. T. Tysoe 339. Formation and dissociation of isocyanate on Pt(111). J. Jones, M. Trenary 340. Kinetics of NH formation and dissociation on Pt(111). K. Mudiyanselage, M. Trenary, R. J. Meyer 341. Vinyl acetate synthesis on Au/Pd(111) alloys. F. C. Calaza, D. J. Stacchiola, Z. Li, W. T. Tysoe 342. Catalytic reduction of uranium(VI) by surface immobilized cytochrome C of Saccharomyces cerevisiae on ITO elec trode. T. Nankawa, Y. Suzuki, T. Ozaki, A. J. Francis, T. Ohnuki
COLL Section Ε Sheraton Chicago River Exhibit Hall Nanoscience Fostered Advances in Sustainability Poster Cosponsored with SUST S. O. Obare and J. J. Lenhart,
Organizers
6:00-8:00 343. Vesicles as green nanoreactors: Charac terization of their formation by self-assem bly of lipids. S. Patel, N. Srividya, S. Mural id ha ran 344. Electrokinetic properties and aggregation kinetics of cerium oxide nanoparticles: An intercomparison across particle size. S. E. Mylon, K. Buettner 345. Self-assembly of phospholipids by dynamic light scattering studies for appli cations in green synthesis of nanomaterials. A. Towlerton, N. Srividya, S. Muralidharan 346. Molecular modeling of vesicles for appli cations as nanoreactors for green synthe sis. K. Dorrance, N. Srividya, B. C. Tripp, S. Muralidharan 347. Optical properties of novel quantum dot composites of nanoscale self-assemblies of amphiphilic molecules. E. J. Sanchez, G. V. Reddy, S. Muralidharan TUESDAY MORNING
8:50 356. Palladium seeded synthesis of iron nanoparticles via chemical reduction. S. H. Ehrman, K. C. Huang 9:10 357. Growth and properties of super conducting anisotropic lead nanoprisms. X-M. Lin, H. Claus, U. Welp, I. Beloborodov, W. K. Kwok, G. Crabtree, H.Jaeger 9:30 358. Preparation of metal foams from spherical nanoparticle aggregates. R. Klajn, T. P. Gray, M. Paszewski, P. Wesson, B. A. Grzybowski 9:50 359. Shape-controlled synthesis of Pd nanostructures. Y. Xiong, Y. Xia 10:10 360. Size control in the synthesis of iron nanoparticles. D. L. Huber, E. L. Venturini, B. L. Frankamp, T. C. Monson, J. E. Martin 10:30 361. Synthesis and characterization of single-crystalline Pd, Au, Ag and Pt nanocubes. F. Fan, J. Sheng, Z. Yang, Y. Zhang, H. Zhou, L. Cui, B. Ren, Z. Tian 10:50 362. Shape-controlled platinum nano particles as catalysts: Synthesis, reaction studies, and support effects. H. Lee, K. M. Bratlie, G. A. Somorjai, P. Yang 11:10 363. The photochemical reduction of dendrimer-mediated metal ions. H. Wan, S. Shuler, T. Konovalova, K. Belmore, D. A. Dixion, J. S. Thrasher, S. C. Street 11:30 364. Time-dependent density func tional theory examination of the effects of ligand adsorption on metal nanoparticles. C. M. Aikens, G. C. Schatz
Section A
Section C
McCormick Place South Room S404A, Level 4
McCormick Place South Room S404D, Level 4
The Priestley Medal: Symposium in Honor of George M. Whitesides Cosponsored with MTLS
Nanoscience Fostered Advances in Sustainability Bio-inspired Nanosystems Cosponsored with SUST
Y. Xia,
Organizer
8:30 Introductory Remarks. 8:35 348. The architecture and evolution of organic chemistry. B. Grzybowski 9:05 349. Label-free detection of proteinprotein interactions on biochips. M. Mrksich 9:35 350. Organizing structure and function at all scales. R. G. Nuzzo 10:05 351. Hybrid organic-organometallicinorganic electronic circuitry. T. J. Marks 10:35 352. Nanostructural design of photocatalysts and photoelectrochemical cells. N. M. Abrams, P. G. Hoertz, G. D. Barber, A. P. Goodey, S. Dilts, S. A. Lee, E. A. Hernandez-Pagan, W. J. Youngblood, J. M. Redwing, T. S. Mayer, Τ. Ε. Mallouk 11:05 353. Soft lithography with hard materi als for flexible electronics. J. A. Rogers 11:35 354. Lessons from biomineralization. J. Aizenberg 12:05 Concluding Remarks. Section Β McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Metal Nanoparticles R. Nagarajan and T. A. Hatton, Organizers S. H. Ehrman,
Presiding
8:30 355. Controlling the assembly of silver atoms into nanostructures with defined shapes and properties. B, Wiley, Y. Xia
S. O. Obare and J. J. Lenhart,
8:30 365. DNA-mediated assembly of FePt nanoparticles to control magnetic behavior. S. Srivastava, B. Samanta, P. Arumugam, G. Han, V. M. Rotello 8:55 366. Characterization of the bilayer region of vesicles of dimyristoylphosphatidylcholine (DMPC) for green approaches to synthesis of nanomaterials. W. Okumu, N. Srividya, B. C. Tripp, S. Muralidharan 9:20 367. Vesicles of natural phospholipids as model systems for green nanoreactors. J. Whitlock, N. Srividya, B. C. Tripp, S. Muralidharan 9:45 368. Fundamental investigation of the vesicles of dimyristoylphosphatidylserine (DMPS) as nanoreactors for green synthe sis. K. McPherson, N. Srividya, S. Muralidharan 10:10 369. Pore formation dynamics and line tension determination on vesicles for green approaches to nanoscale material synthesis. N. Srividya, W. Okumu, B. C. Tripp, S. Muralidharan 10:35 370. Nanoparticle-vesicle interactions as model studies to discern the environ mental impact of nanoscale materials. P. Amaratunga, N. Srividya, S. Muralidharan
McCormick Place South Room S405A, Level 4
McCormick Piace South Room S405B, Level 4 Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Cosponsored with PHYS M. Batzill, J. G. Chen, K-H. Ernst, D. W. Goodman, R. J. Meyer, J. A. Rodriguez, P. C. Stair, and W. T. Tysoe, Organizers 8:30 381. Elaboration of supported model catalysts: Controlling shape, size, spatial distribution and chemical composition of metal nanoparticles on oxide surfaces. C. R. Henry 9:00 382. Use of density functional theory to explore catalysts consisting of an atomic active center. S. Chrétien, R. Pala, V. Shapovalov, H. Metiu 9:30 383. Photodesorption of organic radicals during photocatalysis on T i 0 2 . M. A. Henderson 10:00 Intermission. 10:20 384. Surface investigations of semiconducting metal oxides. U. Diebold 10:50 385. Microscopic insight into the function of heterogeneous catalysts from first-principles statistical mechanics. K. Reuter 11:20 386. Active phases of palladium catalysts for CO oxidation. Y. Cai, M. Chen, Z. Yan, K. K. Gath, D. W. Goodman 11:50 Concluding Remarks.
Organizer Presiding
8:30 371. Colloidal and surface phenomena in DNA-protein interactions. R. Larson, W. Shi, J. H. Kim 8:50 372. Influence of protein on surfactant self-assembly in oil/water mixtures. S. R. Dungan 9:10 373. Bridging of colloidal particles across oil/water interfaces. G. G. Fuller, H. Xu, J. Kirkwood
4:25 392. Nonlinear optical studies of sup ported bilayer membranes: Phospholipid organization and transmembrane polypep tide incorporation. D. Levy, K. A. Briggman 4:45 393. Small molecule and peptide pertur bations of phospholipid bilayer structure and dynamics. J. C. Conboy, T. C. Anglin, J. Liu, H. Li Section Β McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Carbon, Organics R. Nagarajan and T. A. Hatton, Organizers S. S. W o n g ,
Presiding
2:00 394. Investigation of the interaction between SWCNT and 7-cyclodextrin using AFM. S. Ravi, M. P. Kujawski, L Rakesh, M. Chai 2:20 395. "Know your onions": Reactivity and potential uses of carbon nano-onions. A. Palkar, F. Melin, A. K. Naskar, A. Kumbhar, D. D. Edie, L Echegoyen 2:40 396. Silicon-inspired functionalization of carbon nanotubes. T. Hemraj-Benny, S. S. Wong 3:00 397. Strategies for the preparation of small carbon nano-onions (CNOs). F. Melin, A. Palkar, A. K. Naskar, A. Kumbhar, D. D. Edie, L. Echegoyen 3:20 398. Synthesis and characterization of magnetite nanoparticles on DNA wrapped single-walled carbon nanotubes. G. N. Ostojic, M. C. Hersam 3:40 399. Synthesis and characterization of tannic acid functionalized magnetic nano particles. A. Omoike 4:00 400. Synthesis and characterization of the single-point substituted fullerene bisadduct: C60[CMe(CO2Et)2]2. H-L Wang, C-C. Wang, Y. Gao, L. Chiang, L. Y. Chiang 4:20 401. Influence of free surfactant and surfactant surface coverage on the rheol ogy and mesoscale structure of organoclay dispersions. J. Li, J. M. Fitz-Gerald, J. P. Oberhauser 4:40 402. Nanocrytalline cation exchanger derived from beta-chitin. D. Sawada, M. Wu, S. Kimura, M. Wada, S. Kuga 5:00 403. Nanoparticles as seeds for organic crystallization. R. Wang, I. U. Arachchige, S. L. Brock, G. Mao Section C McCormick Place South Room S404D, Level 4 ACS Awards Lectures R. Nagarajan,
Organizer
TUESDAY AFTERNOON F. Zaera,
Presiding
Section A McCormick Place South Room S404A, Level 4
P. S. Cremer and G-Y. Liu,
ACS Award in Colloid and Surface Chemistry: Symposium in Honor of William B. Russel M. M. Santore,
Section Ε
Biological Surface Chemistry Nonlinear Optics Cosponsored with PHYS
Section D
N. J. Wagner, Organizer,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizers
9:30 374. Using stereochemistry to control structure and rheology in associative polymer gels. S. R. Bhatia, S. Agrawal, N. Sanabria-DeLong, G. N. Tew 9:50 375. Polymeric nanoparticles for drug delivery by reactive impingement mixing. J. L Anacker, S. Ji, Z. Zhu, T. R. Hoye, C. W. Macosko, R. K. Prud'homme 10:10 376. Microgel particles: The thermody namics, structure and dynamics of swell ing. A. F. Routh 10:30 377. Dendrimer-stablized metal nano particles: Synthesis mechanisms and catalytic applications. H. J. Ploehn, Y. Gu, H. Xie, P. Sanders, X. Hu, O. S. Alexeev, M. D. Amiridis, D. A. Chen 10:50 378. Charged, water-soluble triblock copolymers with polyether end groups: Steric stabilization of magnetite nanopar ticles and novel micelles for biomedical applications. R. M. Davis 11:10 379. Polarization of electrodes by doped nonpolar media. D. C. Prieve, R. Fu 11:30 380. Dielectric spectroscopy as a probe of colloidal surface structure. A. D. Hollingsworth, Β. Κ. Hamilton, R. J. Hill, W. B. Russel, D. A. Saville
Organizers
2:00 387. Amino acid- and dna-functionalized fused quartz/water interfaces studied by second harmonic and sum frequency generation. F. M. Geiger 2:35 388. Determining the absolute orientation of membrane-bound water. M. Smits, M. Sovago, G. W. H. Wurpel, A. Ghosh, J. Bredenbeck, E.'M. Vartiainen, M. Miiller, M. Bonn 2:55 389. Dielectric spectroscopy and noncontact imaging of single cells using AC electrokinetics. G. J. Simpson 3:30 390. Doubly-resonant sum-frequency generation spectroscopy of retinal-phospholipid films. L. K. Wolf, K. Briggman 3:50 391. Molecular structures of biological molecules at interfaces: Proteins, peptides, and lipids. Z. Chen
2:00 Introduction of William B. Russel. Pablo Debenedetti. 2:05 404. Award Address (ACS Award in Colloid and Surface Chemistry, sponsored by Procter & Gamble Company). Colloidal dispersions: Controlling interactions and understanding the'consequences. W. B. Russel 2:45 Introduction of Hans-Joachim Freund. Peter Stair. 2:50 405. Award Address (Gabor A. Somorjai Award for Creative Research in Catalysis, sponsored by The Gabor A. and Judith K. Somorjai Endowment Fund). The surface science of metal and oxide cata lysts: Model systems at the atomic level. H-J. Freund 3:30 Introduction of Chales T. Campbell. D. Wayne Goodman. 3:35 406. Award Address (Arthur W. Adamson Award for Distinguished Service in the Advancement of Surface Chemistry, spon sored by Occidental Petroleum Corpora tion). Thermodynamics and kinetics of surface chemical reactions: From ratedetermining steps in catalysis to protein adsorption. C. T. Campbell
TECH-45
TECHNICAL PROGRAM
COLL 4:15 Introduction of Bruce Koel. John L. Falconer. 4:20 407. Award Address (George A. Olah Award in Hydrocarbon or Petroleum Chemistry, sponsored by George A. Olah Award Endowment). Site-directed hydro carbon chemistry and catalysis at Pt-Sn alloy surfaces. Β. Ε. Koel Section D McCormick Place South Room S405A, Level 4 The Science of Electrocatalysis: From Extended Surfaces to Nanoscale Catalysts (i)Challenges in Catalysts Design and (ii) Oxygen Reduction Reaction N. Markovic and V. Stamenkovic, Organizers 2:00 408. The role of alloying in catalytic properties: Pd-Au bimetals for vinyl acetate synthesis. M. Chen, P. Han, F. Yang, D. W. Goodman 2:20 409. Electrocatalytic properties of Pt single crystal surfaces vs. nanoparticle surfaces: Similarities and differences. P. N. Ross 2:40 410. Relevance of fundamental cataly sis studies to proton exchange membrane fuel cell applications. H. A. Gasteiger, W. Gu, R. Makharia, K. C. Neyerlin, F. T. Wagner, S. G. Yan, P. T. Yu 3:00 411. Density functional theory calcula tions for the hydrogen evolution reaction. J. K. Norskov, E. Skulasson, J. Rossmeisl, T. Bligaard, G. Karlberg, J. P. Greeley, H. Jonsson 3:20 Intermission. 3:35 412. Gold-modified platinum surfaces in electrocatalysis of oxygen reduction. R. R. Adzic, J. Zhang, K. Sasaki, E. Sutter 3:55 413. Peroxide and oxygen reduction on electrode surfaces. A. A. Gewirth, E. E. Eibergen, K. L. Stewart 4:15 414. Analysis of oxygen reduction reaction by using X-ray photoelectron spectroscopy combined with electrochemi cal cell: Potential-dependence of oxygen species adsorbed on Pt-based electrocatalysts. M. Watanabe, M. Wakisaka, H. Uchida 4:35 415. Oxygen reduction electrocatalysis on non-precious metal nanocomposites. R. Bashyam, C. M. Johnston, S. D. Conradson, P. Zelenay 4:55 416. Oxygen reduction measurements in alkaline solution. M. Arenz, K. J. Mayrhofer, G. Wiberg 5:15 417. Electroreduction of oxygen at uniform arrays of Pt nanoparticles: Role of particle size and interparticle distance. S. Kumar, S. Zou Section Ε McCormick Place South Room S405B, Level 4
4:00 424. Synthesis and fundamental char acterization of patchy CdS:Mn/CdS core/ shell quantum dots. E. J. Sodt, S. Muralidharan 4:20 425. "Switch on" and "Switch off' nano sensors for the detection of nerve gas agents. S. Varanganti, S. Muralidharan 4:40 426. Highly fluorescent stilbene based monomers for the design and construction of nanosensors for chemical and biotoxins. C. Wang, S. Muralidharan 5:00 427. Nanosensors for the detection of explosive compounds. D. Thimmaraju, S. Muralidharan Structure and Dynamics at the Liquid-Liquid Interface Nanoparticles Sponsored by PHYS, Cosponsored with COLL
10:50 445. Preparation, physico-chemical characterisation and applications of colloi dal microgel particles. M. J. Snowden 11:10 446. Synthesis, passivation and stabili zation of nanorods and nanowires by microwave irradiation. A. B. Panda, G. P. Glaspell II, M. S. El-Shall 11:30 447. Using particle lithography to form nanopattems of n-alkylsilanes: The role of surface hydrolysis. J. C. Garno, J-R. Li
WEDNESDAY MORNING
Section C
Section A
McCormick Place South Room S404D, Level 4
McCormick Place South Room S405A, Level 4 Biological Surface Chemistry Polymer Interfaces Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
McCormick Place South Room S404B/C, Level 4
S. O. Obare and J. J. Lenhart,
Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Synthesis and Processing
t6-TECH
R. Nagarajan and T. A. Hatton, Organizers M. E. Castro,
Section Ε McCormick Place South Room S405B, Level 4 George A. Olah Award in Hydrocarbon or Petroleum Chemistry: Symposium in Honor of Bruce E. Koel M. Batzill,
Arthur W. Adamson Award for Distinguished Service in the Advancement of Surface Chemistry: Symposium in Honor of Charles T. Campbell Cosponsored with PHYS
Organizers
8:30 428. Ideal chemical environment for optimal protein activity on surfaces. X-Y. Zhu, A. Guo 9:05 429. Controlling the morphology of 1-D tobacco mosaic virus assembly assisted by aniline polymerization. M. A. Bruckman, Z. Niu, L. A. Lee, B. Lee, Q. Wang 9:25 430. Fabrication of nanostructured biomimetic interfaces. D. Srivastava, N. Kohli, M. Worden, I. Lee 9:45 431. Polyelectrolyte multilayers control ling fibronectin and A7r5 cytoskeletal rearrangements. M. D. Moussallem, J. B. Schlenoff, S. G. Olenych, T. C. S. Keller 10:05 432. Self-assembled monolayers of polyethylene glycol) silane as resists for electron beam lithography. B. Gao, G. Bernstein, M. Lieberman 10:25 433. Surface properties and interac tions between charged polymer brushes: Effects of charges and electrostatic screening. B. Liberelle, S. Giasson 10:45 434. The growth of individual particles in clouding process. H. Mao, P. Luchette, N. Abiy 11:05 435. Volumetric interpretation of com petitive protein adsorption to sepharose. H.Noh 11:25 436. Electron transfer of myoglobin entrapped in polyethylene glycol diacrylate hydro gel formed by photo polymerization. A. Mugweru 11:45 437. Azobenzene polyelectrolytes for photoreversible bioactive surfaces. C. J. Barrett
Nanoscience Fostered Advances in Sustainability Sensors Cosponsored with SUST
2:00 418. Formation of viologen-functionalized monolayers in nanoporous anodic alumina for reagentless multiplexing biosensing. J . Yan, R. D. Long 2:20 419. Aqueous nanoscale self-assem blies of amphiphilic acylpyrazolones and acylisoxazolones for lanthanide metal ion recognition. G. V. Reddy, H. Ma, S. Muralidharan 2:40 420. Nanoscale sensor consisting of nanoparticle, fluorescent stilbene, and receptor for nerve gas analogs. Y. Datar, S. Muralidharan 3:00 421. Multifunctional receptors for the generation of nanosensors for nerve gas toxins. W. Lizik, S. Muralidharan 3:20 422. Novel Ru(ll) complexes bearing receptors for the construction of nerve gas sensors. A. Weerasinghe, S. Muralidharan 3:40 423. Nitrogen heterocyclic compounds as receptors in nanosensors for nerve gas agents. S. Katram, S. Muralidharan
10:25 462. Hydrogen adsorption and hydrogen evolution reaction on a polycrystalline Pt electrode studied by surface-enhanced infrared absorption spectroscopy. K. Kunimatsu, T. Senzaki, G. Samjeské, M. Tsushima, M. Osawa 10:45 463. Bimetallic catalysts composition effect on the ammonia electrooxidation. G. M. Brisard, T. Jiang, P. Dube 11:05 464. Toward a more realistic modeling of electrochemical systems. T. Jacob, M. Scheffler
Organizer
W . T. Tysoe, Organizer,
Section Β
Organizers
10:10 443. Synthesis of high-quality ll-VI nanocrystals without precursor injection. Y. C. Cao 10:30 444. Hydrodynamic focusing-based nanoreactor for preparation of morphologycontrolled and mono-dispersed nanopar ticles. K. K. Coti, W. Lu, Y. Wang, H-R. Tseng, M. Selke, J. F. Stoddart
Presiding
8:30 438. Aerosol-based processing as an approach to nanoparticle surface function alization. J. T. Roberts, J. Holm 8:50 439. Synthesis of novel materials for 3-D nanostructured assemblies. D. S. Pradhan-Kadam, D. U. Jonas 9:10 440. Convectional, sedimentation and drying dissipative patterns of colloidal dispersions and solutions. T. Okubo 9:30 441. Fabrication of shape-controlled multivalent particles via interference lithog raphy. J-H. Jang, C. Ullal, S. Kooi, C. Koh, E. L. Thomas 9:50 442. Functional nanostructures by wet chemistry: A tool to ordered 1 - and 3-D structures. M. E. Castro, R. Irizarry, L. Gonzalez
D. W . Goodman and J. A. Rodriguez, Organizers K-H. Ernst and C. H. F. Peden,
Presiding
8:30 Introductory Remarks. 8:40 448. Model studies of BaO/AI 2 0 3 NO x storage materials. C. H. F. Peden, C. W. Yi, E. Ozensoy, J. Szanyi 9:00 449. The interaction of H 2 0 and N 0 2 with thin MgO(100) films grown on Ag(100) as studied with ambient pressure photoemission spectroscopy. D. E. Starr, C. D. Weiss, S. Yamamoto, A. Nilsson, M. Salmeron, H. Bluhm 9:20 450. CO adsorption on the model catalyst Pd/Ce02-x(111). G. Thornton 9:40 451. Water-gas shift reaction on Cu and Au nanoparticles supported on Ce02 and ZnO: Intrinsic activity and importance of support interactions. J. A. Rodriguez, X. Wang, P. Liu, J. C. Hanson, J. Hrbek 10:00 452. Novel catalytic phenomena and mechanisms for formic acid decomposition on Ti02(110) and NO reduction on Co2/ AI2O3(110). Y.lwasawa 10:20 Intermission. 10:35 453. Sintering of supported metal particles: Au on Ti0 2 (110). S. C. Parker, C. T. Campbell 10:55 454. Reactivity of Pd-0 surface phases. J. Wang, Y-R. Yen, E. I. Altman 11:15 455. Bridging material and pressure gaps in heterogeneous catalysis by using environmental-HRTEM. S. Giorgio, M. Cabié, C. R. Henry 11:35 456. Tribology of interfacial water under nanometer level confinement. J. E. Houston Section D McCormick Place South Room S405A, Level 4 The Science of Electrocatalysis: From Extended Surfaces to Nanoscale Catalysts Challenges in Catalysts Design N. Markovic and V. Stamenkovic, Organizers 8:30 457. Processes at metal/electrolyte interfaces: Influence of surface structure. K. Wandelt 8:50 458. Single particles and extended surface measurements. U. Stimming 9:10 459. In-situ characterization of temperature controlled electrified solid-liquid interfaces. V. Stamenkovic, C. A. Lucas, D. Tripkovic, D. Strmcnik, K-C. Chang, H. You, N. Markovic 9:30 460. What we (I) don't understand about the Tafel slope in electrocatalysis. M. T. Koper 9:50 Intermission. 10:05 461. Materials advances for fuel cell applications. H. D. Abrufia
Presiding
8:30 465. CO and H2S chemistry on and in Fe and Fe alloys from first principles. E. A. Carter 9:00 466. Studies of catalysis using a combi nation of quantum mechanics and reactive force fields. W. A. Goddard III 9:30 467. Structure sensitivity and stability of oxygen reduction reaction catalysts from first principles. J. P. Greeley, J. Rossmeisl, J. K. Norskov 9:50 468. A "trifunctional mechanism" to model ethanol electrooxidation on Sn/Rh modified Pt(110) electrodes. M. Lave, M. Sells, A. Hightower 10:10 469. Segregation at CuxPd^x alloy hydrogen purification membranes. A. Gellman, P. Ye, J. Miller, C. Matranga 10:30 470. Photoelectron diffraction via ARXPS and ARUPS. K. Klier 10:50 471. Surface properties of SnO2(101). M. Batzill 11:10 472. Catalytic properties of binary alloy surfaces. K. Wandelt 11:40 473. Surface chemistry of confined nanostructures and disordered substrates. A. V. Teplyakov Structure and Dynamics at the Liquid-Liquid Interface Ionic and Electrical Phenomena Sponsored by PHYS, Cosponsored with COLL WEDNESDAY AFTERNOON Section A McCormick Place South Room S404A, Level 4 Biological Surface Chemistry Fluidics, Patterning, and Biofilms Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
Organizers
2:00 474. Microfluidic tools to probe the spatiotemporal dynamics of complex biological networks. R. F. Ismagilov, C. Kastrup, M. Runyon, F. Shen 2:35 475. Development of self-assembled monolayer-based cell culture platforms for tissue engineering. R. Aithal 2:50 476. Formation of size-controlled pro tein crystals in microwell arrays. L. Wang, J. Barton, M. H. Lee, L. Hughes, T. W. Odom 3:05 477. Self-assembled monolayer based cell culture platforms for tissue engineer ing. R. K. Aithal, D. P. Kumaraswamy, V. Shanigaram, A. T. Doss, C. Watson, D. K. Mills, D. Kuila
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
COLL 3:20 478. Nanoscale patterning of arginineglycine-aspartate (RGD) cell adhesion ligands to understand cell adhesion at molecular level. T. Huynh, N. Huebsch, D. J. Mooney, C. Cai 3:35 479. Resistance of cellular adhesion to modified SS316L substrates. E. S. Gawalt, A. Raman, K. A. Pappariella 3:50 480. Spontaneous DNA pattern forma tion via confinement and evaporation. L. Zhang, S. Maheshwari, H-C. Chang, Y. E. Zhu 4:05 481. Biocompatibility of microcapsules: An in vitro investigation of a potential novel drug delivery system. Z. An, M. Choy, L. Kaufman 4:20 482. Study of bacteria adhesion onto carbohydrate-presenting surfaces. G. Qin, W. Zhang, A. Kumar, C. Cai 4:35 483. Studying integrin-extracellular matrix interactions using self-assembled monolayers. J. L. Case, M. Mrksich 4:50 484. Surface modifications by covalent printing. D. I. Rozkiewicz, B. J. Ravoo, D. N. Reinhoudt 5:05 485. Using quantitative force measure ments to examine chemical and biophysi cal changes at a native bacterial surface. M. A. Ferguson, Ε. Μ. Spain Section Β McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Metal Oxides R. Nagarajan and T. A. Hatton, Organizers M. D. Soucek,
Presiding
2:00 486. Dispersion of super paramagnetic iron oxide nanoparticles in poly(D,L-lactide-co-glycolide) microparticles. B. P. Grady, R. A. Wassel, R. D. Kopke, K. D. Dormer 2:20 487. Evaluation of surface coverage and influence of linker lengths on loading of magnetic iron oxide nanoparticles. B. Srinivasan, X. Huang 2:40 488. Facile preparation of partially reduced V205 high-aspect-ratio nanowire sheet. C. Xiong, A. E. Aliev, G. Pant, B. Gnade, K. J. Balkus Jr. 3:00 489. Ionic monolayer-protected metal clusters (IMPCs): Effects of counter anions. Y-S. Shon 3:20 490. Low temperature synthesis of rutile nanorods in ionic liquids. H. Kaper, B. Smarsly, M. Antonietti 3:40 491. Preparation and characterization of monodisperse cerium oxide nanoparticles in hydrocarbon solvents. H. Gu, M. D. Soucek 4:00 492. Synthesis and optical properties of 1-D metal and core/shell colloidal nanostructures. M. Liu, P. Guyot-Sionnest 4:20 493. Surfactant effects on the particle size and formation of sol-gel iron(lll) oxides. E. Camponeschi, J. D. Walker, R. Tannenbaum 4:40 494. Polyelectrolyte-modified nanoscale zerovalent iron: Characteristics of the adsorbed polyelectrolyte layer and disper sion stability. T. Phenrat, N. B. Saleh, K. Sirk, H-J. Kim, Y. Liu, R. D. Tilton, G. V. Lowry 5:00 495. Vanadia nanoparticles grown on thin ice films: Structure and reactivity. S. K. Shaikhutdinov, S. Kaya, H-J. Freund
Please refrain from using cellular telephones and cameras during technical sessions.
Section C
Section Ε
McCormick Place South Room S404D, Level 4
McCormick Place South Room S405B, Level 4
Arthur W. Adamson Award for Distinguished Service in the Advancement of Surface Chemistry: Symposium in Honor of Charles T. Campbell Cosponsored with PHYS
George A. Olah Award in Hydrocarbon or Petroleum Chemistry: Symposium in Honor of Bruce E. Koel
D. W. Goodman, H. Jonsson,
Organizer Section Β
M. Batzill, Organizer,
Organizer
Presiding
J. A. Rodriguez, Organizer,
W. T. Tysoe,
Presiding
2:00 496. Moving beyond the printed page in teaching physical chemistry. T. Engel, P. J. Reid 2:20 497. MoS 2 nanoparticles for hydrogen evolution: A combined UHV/STM and electrochemical study. J. H. Nielsen 2:40 498. Butandioic acid derivatives on Cu(110): Sergeants and soldiers, 2-D enantiomorphism and surface explosion. K-H. Ernst, M. Parschau, C. Roth 3:00 499. Calculations of dissociative sticking of molecules: Statistical vs. dynamical approaches. H. Jonsson 3:20 Intermission. 3:35 500. Surface-confined coordination chemistry with metalloporphyrins: ln-situ metalation and competitive axial coordina tion. J. M. Gottfried 3:55 501. Surface science study of fuel cell electrode catalysts. J. Nakamura 4:15 502. The next generation nuclear plant: Materials issues and needs. J. W. Rogers Jr. 4:35 503. Designer plasmonic structures with tunable optical properties. J. Shumaker-Parry 4:55 504. Studies of host-to-activator energy transfer in luminescent materials. A. L. Diaz 5:15 Concluding Remarks. Section D McCormick Place South Room S405A, Level 4 The Science of Electrocatalysis: From Extended Surfaces to Nanoscale Catalysts ln-situ Solid-Liquid Interfaces and Electrooxidation of CO N. Markovic and V. Stamenkovic, Organizers 2:00 505. Vibrational sum frequency genera tion studies of phase transition of CO on Pt(111) and Pt(111)/Ru electrodes. A. Lagutchev, G. Q. Lu, T. Takeshita, D. D. Dlott, A. Wieckowski 2:20 506. Electrochemical oxidation of CO: A spectroscopic point of view. K. C. Chou 2:40 507. Dewetting at the aqueous-hydrophobic interface. S. K. Shaw, A. A. Gewirth 3:00 508. Sum frequency generation study on potential and time dependent structures of electrochemical interfaces. K. Uosaki, H. Noguchi, T. Okada, M. Ito 3:20 509. Surface-enhanced Raman spectro scopic studies of CO and methanol oxida tion on Ru-decorated Pt surfaces. H. Yang, S. Zou 3:40 Intermission. 3:55 510. Particle size and substrate effects in electrocatalysis: Carbon and titania supported gold particles. Β. Ε. Hayden, D. Pletcher, J-P. Suchsland 4:15 511. Characterisation and reactivity of novel thin metallic films supported on single crystal electrodes. G. A. Attard, S. Smale, S. Huxter, F. Vidal, A. Al-Akl, L. Fang, E. Wright, A. Pratt 4:35 512. Oxidation of carbon monoxide, formic acid and methanol on platinum: A hardy perennial. A. Cuesta, M. D. C. Perez, A. Rincon, C. Gutierrez 4:55 513. Electroanalysis for electrocatalysis: What can we learn? R. J. Behm, Z. Jusys, M. Heinen, Y-X. Chen, L. Colmenares
11:20 534. Separation of PCR products using alkane-tagged primers in micellar electrokinetic chromatography. S. T. Grosser, J. M. Savard, J. W. Schneider 11:35 535. An in-situ spectroscopic ellipsometry study of the effects of potential on fibrinogen/thrombin. M. L. Walker, J. T. Elliot, V. Reipa
Presiding
2:00 514. Novel nanodispersed early transi tion oxide catalysts on mesoporous silica. C. H. F. Peden, J. E. Herrera, J. H. Kwak, J. Hu, X. She, Y. Wang 2:30 515. The E2V story: Novel catalysts enable the Dow ethane-to-vinyl process. M. E. Jones, D. A. Hickman, M. M. Olken 2:50 516. Selective catalytic reduction of NOx over Ag/AI203 catalyst by hydrocar bons. H. He 3:10 517. Role of mono-atomic steps in catalytic reactions. I. Chorkendorff 3:40 518. Reactivity of oxygen adatoms on gold single crystal surfaces. J. Kim, D. Syomin, E. C. Samano, B. E. Koel 4:00 519. Selective chemistry on metal surfaces: Stereoselection on Pt(111) and metathesis on Mo2C. P. H. McBreen 4:20 520. Thermal and radiation induced chemistry of water on U02 surfaces. M. T. Paffett, J. Stultz, S. A. Joyce 4:40 521. Adsorption-activated nanovalve. J. L Falconer, M. Yu, R. D. Noble 5:00 522. Formation mechanism of crystal nitrate and sulfate salts in coarse and fine particulate matter in the atmosphere. N. A. Saliba, H. Kouyoumdjian, G. AI Kadamany 5:20 523. Oxidation of organic films by beams of hydroxyl radicals. B. Ellison Structure and Dynamics at the Liquid-Liquid Interface Surfactants Sponsored by PHYS, Cosponsored with COLL THURSDAY MORNING Section A McCormick Place South Room S404A, Level 4 Biological Surface Chemistry Biosensors Cosponsored with PHYS P. S. Cremer and G-Y. Liu,
Organizers
8:30 524. Utilizing surface enzyme chemistry and nanoparticles to detect surface bioaffinity interactions. R. M. Corn, H. J. Lee, A. Wark 9:05 525. Growth of metal nanostructures on templates of RNA-aptamer catalysts formed by scanned probe nanolithography (SPN). S. Chung, J. V. LaTour, S. S. Hah, T. M. Tarasow, J. J. De Yoreo, L. A. Gugliotti, D. L. Feldheim, B. E. Eaton 9:20 526. Renewable bioelectronic interfaces for biosensor applications. B. L. Hassler, N. Kohli, I. Lee, R. M. Worden 9:35 527. Surface plasmon resonance com patible carbon thin films. M. R. Lockett, M. F. Phillips, M. R. Shortreed, S. C. Weibel, L. M. Smith 9:50 528. Thermodynamical analysis of the gold surface recognition by a gold binding peptide. U. O. S. Seker, B. R. Wilson, C. Tamerler, M. Sarikaya 10:05 529. Functionalization and character ization of amorphous carbon thin film for real-time biosensing with high chemical stability. B. Sun, J. Beck, P. Colavita, H. Kim, M. R. Lockett, M. S. Marcus, L M. Smith, R. J. Hamers 10:20 530. Virus-assembled metallodielectric plasmonic materials. B. Dragnea 10:35 531. Enhanced fluorescent immunoas say on silver fractal-like structures. E. G. Matveeva, T. Shtoyko, I-F. Chang, Z. Gryczynski, I. Gryczynski 10:50 532. Electrochemical study of interfacial enzymatic reactions. S. Nayak, M. Mrksich 11:05 533. Identification of metastatic subpopulations of breast cancer progenitor cells using gold nanorod probes. C. Yu, H. Nakshatri, J. Irudayaraj
McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Passivation and Functionalization R. Nagarajan and T. A. Hatton, Organizers I. Sokolov,
Presiding
8:30 536. Functionalized core-shell nanopar ticles as optical probes for chemical imag ing. A. Anderson, D. Finley, M. Holt, C. Thompson, C. J. A. Daley, S. R. Emory 8:50 537. Metal-enhanced fluorescence in metal-core silica-shell nanoparticles. M. L. Viger, O. Dupont-Therrien, D. Boudreau 9:10 538. Immobilization of siloxane elas tomer on GaAs surfaces using dopaminetreated MPt (M = Fe, Ni) nanoparticles as crosslinkers. A. Ivanisevic, H. M. Song, P. Ye 9:30 539. Reactivity of Ti02 nanotubes toward oxygen and alkane adsorption: Structure activity relationship. S. Funk, B. Hokkanen, T. Nurkic, U. Burghaus, A. Ghicov, P. Schmuki, L. Saraf 9:50 540. Solubility in novel mixed mono layer protected nanoparticles. S. Chen, A. M. Jackson, O. Uzun, F. Stellacci 10:10 541. Synthesis and application of fluoroalkyl end-capped oligomers/silica. H. Kakehi, M. Miura, N. Isu, H. Sawada 10:30 542. The electrical conduction of semiconductor nanoparticles in solution: A kinetic-conductivity study of semiconductor nanoparticle formation. M. Leon, R. Irizarry, M. E. Castro 10:50 543. Ultra-bright fluorescent silica particles. I. Sokolov, S. Naik 11:10 544. Ion and molecular transport through surface-modified silica colloidal crystals. I. Zharov Section C McCormick Place South Room S404D, Level 4 Basic Research in Surface and Colloid Science R. Nagarajan, S. O. Obare,
Organizer Presiding
8:30 545. Amino acid-functionalized fused quartz/water interfaces studied by nonlin ear optics. J. M. Gibbs-Davis, C. T. Konek, K. A. Scheldt, F. M. Geiger 8:50 546. Mild methods to assemble and pattern monolayers on Si(111) using soft lithography. M. Perring, N. B. Bowden 9:10 547. Generation of gradient surfaces via contact printing based approach. B-M. Zhang Newby, Y. Cai, F. Song, S-H. Choi 9:30 548. Soft interference lithography: A large-scale platform for nanophotonics. J. Henzie, M. H. Lee, T. W. Odom 9:50 549. Encapsulation of dextran coated superparamagnetic particles and drugs in liposomes for controlled release. J-H. Lee, J. A. Frank 10:10 550. Molecular self-assembly in the presence of nanoparticles. R. Wang, I. U. Arachchige, S. L. Brock, G. Mao 10:30 551. Manipulating assembly properties in DNA-nanoparticle systems. M. M. Maye, D. Nykypanchuk, D. van der Lelie, O. Gang 10:50 552. In situ growth and characteriza tion of reducible ceria thin films and ceriasupported metal nanoparticles. J. Zhou, S. D. Senanayake, A. P. Baddorf, S. V. Kalinin, S. H. Overbury, D. R. Mullins
TECH-47
COLL/COMP
TEGHNICAL PROGRAM
11:10 553. Micellar effect on the kinetics of oxidation of hydroxy acids by N-bromophthalimide in presence of acidic medium. Y. R. Katre, S. Patil, A. K. Singh 11:30 554. Influence of the degree of deacetylation and molecular weights on the surface properties of chitosan. L. Zhang, Z-D. Zhang, Q. Shen Section D
4:20 571. Biofunctionalizing nitride surfaces without silanes. R. Stine, Κ. Μ. McCoy, S. P. Mulvaney, L. J. Whitman 4:40 572. Selective nesting and deactivation of small proteins on substrates designed on nanoscale material surfaces. P. Krai, Y. Chen, B. Wang 5:00 573. Transport and reaction in electrocatalytic processes. R. J. Behm Section Β
McCormick Place South Room S405A, Level 4 The Science of Electrocatalysis: From Extended Surfaces to Nanoscale Catalysts (i) ln-situ Solid-Liquid Interfaces and (ii) Recent Progress in Catalyst Design N. Markovic and V. Stamenkovic, Organizers 8:30 555. Surface structure and electro chemistry of model electrocatalysts. C. A. Lucas 8:50 556. Establishing structure property relationships for fuel cell electrocatalysts. A. E. Russell 9:10 557. X-ray in-situ investigation of inter faces relevant to electrocatalysis. H. You, N. Markovic, K-C. Chang, V. Stamenkovic 9:30 558. Single Pt atoms to clusters: Their electronic structure and electrocatalytic activity. Y-T. Kim, D. H. Chi, T. Mitani, Y. Shao-Hom 9:50 559. Size and composition distribution dynamics of Pt alloy nanoparticle electro catalysts probed by anomalous small angle X-ray scattering . S. Koh, C. Yu, J. Leisch, M. F. Toney, P. Strasser 10:10 Intermission. 10:25 560. Electrocatalysis from first prin ciples. M. Neurock 10:45 561. Electrodeposition of Pt on a RuO 2 (110) single-crystal surface. M. B. Vukmirovic, P. Liu, J. T. Muckerman, R. R. Adzic 11:05 562. Copper ultra thin films growth on Au(111) by surface limited redox replace ment. L. T. Viyannalage, N. Dimitrov 11:25 563. Hydrogen-assisted and COassisted reductive desorption of hydroquinone-derived adlayers from Pt(111) single crystal electrodes. M. Rodriguez-Lopez, E. Herrero, J. M. Feliu, P. Tuhon, A. Aldaz, A. Carrasquillo Jr.
McCormick Place South Room S404B/C, Level 4 Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization Functionalization and Applications R. Nagarajan and T. A. Hatton, Organizers H. S. Zhou,
Presiding
2:00 574. Synthesis and polymer functional ization of metallic and bimetallic nanorods. E. R. Zubarev 2:20 575. Sensitivity and selectivity of multi plex nanoSPR biosensor assays. C. Yu, J. Irudayaraj 2:40 576. Amplified detection of protein cancer markers and oligonucleotide tar gets through the nanoparticle-based biobarcode assay. S. I. Stoeva, J-S. Lee, R. Elghanian, S. T. Rosen, C. A. Mirkin 3:00 577. Effects of drying condition on inkjet printed conducting line. Y. A. Baik, M. J. Jang, H. C. Jung, J. Joung 3:20 578. Metal nanoparticle-embeded polyelectrolyte multilayers for biosensor application. H-J. Jeong, H-C. Kim, S. W. Jeong, S. Y. Yang 3:40 579. Nanoparticle decoration for enhanced Raman spectroscopy of pre existing polymer surfaces. B. Roan, T. E. Furtak 4:00 580. Polymer nanoparticles for emul sion stabilization. W. Richtering, B. Brugger 4:20 581. Synthesis and characterization of nanoparticle assemblies for electronic applications. J. A. Ayres, K. L. Chandra, C. B. Gorman Section C
Structure and Dynamics at the Liquid-Liquid Interface Interfacial Structure and Surfactants Sponsored by PHYS, Cosponsored with COLL THURSDAY AFTERNOON
S. O. Obare,
McCormick Place South Room S404A, Level 4 Biological Surface Chemistry Nanomaterials and Thin Films Cosponsored with PHYS Organizers
2:00 564. Interaction of the engineered chaperonin proteins with water-soluble quantum dots. H. Xie, Y-F. Li, J. D. Trent, B. I. Swanson 2:20 565. Interaction between nanoparticles and liquid crystal supported phospholipid monolayer. D. Hartono, K-L. Yang, L-Y. L Yung 2:40 566. Surface properties of tea polyphe nols. L-H. Zhang, R-F. Hu, Q. Shen 3:00 567. DNA/Drug delivery into cells using multifunctional gold nanoparticles. G. Han, B-J. Kim, N. S. Forbes, C. T. Martin, V. M. Rotello 3:20 568. Design, synthesis and fabrication of a biomolecular nanovalve. B. Reiss, O. Auciello, L. E. Ocola, M. A. Firestone 3:40 569. Directed evolution of hydroxyapatite-associated protein. S-W. Lee, J. H. Huh, Y. Zhao 4:00 570. Functionalization of gallium nitride thin films with molecular and biomolecular layers. H. Kim, P. Colavita, B. Sun, P. Paoprasert, J. J. Uhlrich, P. Gopalan, T. F. Kuech, R. J. Hamers
48-TECH
Basic Research in Surface and Colloid Science R. Nagarajan,
Section A
P. S. Cremer and G-Y. Liu,
McCormick Place South Room S404D, Level 4
Organizer Presiding
2:00 582. Rapid assembly of organic mono layers on hydrogen terminated silicon surfaces by application of living radical polymerization systems. I. W. Moran, K. R. Carter 2:20 583. Modulating stress relaxation in lipid monolayers: Effects of surface composition and subphase viscosity. L. Pocivavsek, S. L. Frey, A. J. Waring, K. Y. C. Lee 584. Withdrawn. 2:40 585. Thermal stability in air of hydrocar bon monolayers on porous silicon. S. R. Coon, R. S. Cunningham, A. N. Simonson, D. L. Mavour 3:00 586. Bond character of thiophene on Ge(100): Effects of coverage and tem perature. H. Lee, S. M. Jeon, S. J. Jung, D. K. Lim, J. H. Choi, S. Kim 3:20 587. Formation of concentric nanorings by fatty acids. L. Wan, G. Mao 3:40 588. Jamming of confined colloids in aqueous and non-polar media. P. S. Sarangapani, P. Hoffmann, Y. E. Zhu 4:00 589. Dynamic instability of a sol-gelderived thin film: Dewetting and dynamics. S. J. Kwon, J-G. Park
11:40 6. Modeling protein-protein interactions with continuum electrostatics. E. G. Alexov
Section D McCormick Place South Room S405A, Level 4
Section Β The Science of Electrocatalysis: From Extended Surfaces to Nanoscale Catalysts (i) Electrooxidation of CO and (ii) Future Directions in Catalyst Design N. Markovic and V. Stamenkovic, Organizers 2:00 590. Coverage dependence of CO surface diffusion on Pt nanoparticles: An EC-NMR study. P. K. Babu, T. Kobayashi, H. Chung, E. Oldfield, A. Wieckowski 2:20 591. An X-ray absorption study of Pt-Ru electrocatalysts subjected to different atmospheres. C. Roth, M. Mazurek, F. Scheiba, N. Benker, H. Fuess 2:40 592. Adsorptive interactions and sur face mobility of COaCj on supported afunc tional catalyst nanoparticles. M. Hepel, K. Moot, l. Delà, J. Luo, C-J. Zhong 3:00 593. A new PROX reaction of CO on the FeOx/Pt/Ti02 catalyst. K-l. Tanaka, H. He, X. Shi 3:20 Intermission. 3:35 594. Chemical approach to electrocatalysis: When should complexity be introduced? A. B. Anderson 3:55 595. Aspects of alloy electrocatalysis. M. Mavrikakis, A. U. Nilekar, D. C. Ford, Y. Xu, K. Sasaki, J. Zhang, M. B. Vukmirovic, R. R. Adzic 4:15 596. Toward the nanoscale design of catalysts for fuel cells: A computational approach. G. Wang 4:35 597. Combinatorial first-principles screening of alloys for electrocatalysis: The hydrogen evolution reaction. J. P. Greeley, T. F. Jaramillo, J. Bonde, I. Chorkendorff, J. K. Norskov Structure and Dynamics at the Liquid-Liquid Interface Micelles and Aggregates Sponsored by PHYS, Cosponsored with COLL
COMP Division of Computers on Chemistry J. D. Madura and E. X. Esposito, Program Chairs SUNDAY MORNING Section A Hyatt Regency McCormick 10A/B Barry Honig 65th Birthday Symposium: Biological Applications of Implicit-Solvent Models C. F. W o n g and R. A. Friesner, Organizers D. Murray, Organizer,
Presiding
8:30 Introductory Remarks. 8:40 1. Reminiscing about chemical and biological applications of continuum electrostatics. Β. Η. Honig 9:25 2. Proton and chloride pumping in bacterio- and halo-rhodopsin. M. R. Gunner, Y. Song 9:55 3. Binding entropies and free energies. M. K. Gilson 10:25 Intermission. 10:40 4. A modest proposal for the use of physical quantities in continuum electro statics. A. Nicholls 11:10 5. Interactions of cationic-hydrophobic peptides with lipid bilayers: A coarse grained Monte Carlo simulation method. N. Ben-Tal
Hyatt Regency McCormick 10C/D Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin Cosponsored with CINF, and WCC O. F. Guner,
Presiding
A. Tropsha, Organizer,
Presiding
8:15 Introductory Remarks. 8:30 7. Using knowledge on chemical reac tions for drug design. J. Gasteiger 9:00 8. Experimental and computational approaches to measuring compound reactivity. P. Hajduk 9:30 9. Drug Guru: A new kind of computa tional tool for medicinal chemists. K. Stewart 10:00 Intermission. 10:20 10. Pushing the boundaries of 3-DQSAR. R. D. Cramer 10:50 11. Outliers in SAR and QSAR: What are the possible sources? Κ. Η. Kim 11:20 12. Do multiconformer queries enhance 3-D lead hopping? S. W. Muchmore, Y. C. Martin 11:50 13. Advances in conformational sam pling. D. K. Agrafiotis, F. Zhu, S. Izrailev, A. Gibbs, E. Martin Section C Hyatt Regency McCormick 12A General Oral: Quantum Chemistry A. E. Roitberg, G. D. M. Seabra,
Organizer Presiding
8:30 14. Coupled-cluster and explicitlycorrelated perturbation-theory calculations of the uracil anion. M. S. J. Gutowski, R. Bachorz, W. Klopper 9:00 15. Ab initio study of the interaction of the phospholipid head-group with repre sentative quartz and aluminosilicate struc tures. J. Snyder 9:30 16. Quantum chemistry calculations of the methane dimer potentials. S. D. Chao, A. H-T. Li 10:00 17. Density functionals for noncovalent interaction energies of biological impor tance. Y. Zhao, D. G. Truhlar 10:30 Intermission. 10:45 18. Validation of density functionals, semiempirical methods, and SCC-DFTB for Zn coordination chemistry. E. A. Amin, D. G. Truhlar 11:15 19. TDDFT studies of 3-hydroxykynurenine and its photoproducts in primate eyes. B. C. Dutmer, T. M. Gilbert 11:45 20. Accurate quantum chemical calcu lations of NMR chemical shifts and appli cation to protein structure refinement. Y. Zhang, E. Oldfield Measures of Accuracy and Reliability in Molecular Simulation Materials Simulation Sponsored by PHYS, Cosponsored with COMP
Please refrain from using cellular telephones and cameras during technical sessions.
COMP
SUNDAY AFTERNOON Section A Hyatt Regency McCormick 10A/B Barry Honig 65th Birthday Symposium: Biological Applications of Implicit-Solvent Models C. F. W o n g , R. A. Friesner, and D. Murray, Organizers M. Gunner,
Presiding
1:30 2 1 . Probing pH dependent conforma tional landscapes. C. L. Brooks III 2:00 22. Prediction of long loops in proteins: Improved sampling and continuum solva tion model. R. Friesner 2:30 23. Macromolecular simulations using continuum solvent models. D. A. Case 3:00 Intermission. 3:15 24. Protein folding using mechanismbased searching and implicit solvent models. K. A. Dill 3:45 25. Implicit modeling of complex cellular environments. M. Feig 4:15 26. Hybrid solvation model for MM-PB/SA free energy calculations. H. Gohlke, A. Metz Section Β Hyatt Regency McCormick 10C/D ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Cosponsored with WCC J. D. Madura,
Organizer
T. M. Chang,
Presiding
1:30 27. A new paradigm for high-tempera ture superconductors. W. A. Goddard III, J. Tahir-Kheli 2:00 28. How ab initio calculations can help in the microscopic understanding of sen sors and charge transport through mol ecules. A. J. R. da Silva 2:30 29. Dopants in engineering materials: Atomic effects on stability and structure. Κ. Μ. Carling 3:00 30. First principles calculations of the widths of atomic resonances near sur faces. P. Nordlander, K. Niedfeldt, E. A. Carter 3:30 Intermission. 3:45 3 1 . Embedded configuration interaction theory view of the many-body Kondo state. P. Huang, E. A. Carter 4:15 32. The chemical reactivity of a nano graphene ribbon's zigzag edge. D-E. Jiang, B. G. Sumpter, S. Dai 4:45 33. Insights into high temperature evolution of thermal barrier coatings from first principles. B. Hinnemann, E. A. Carter Section C Hyatt Regency McCormick 12A De Novo Design Coupled to Synthetic Feasibility D. F. Ortwine,
Organizer
1:20 Introductory Remarks. 1:30 34. Form follows function: The de novo design of pharmaceutical^ active com pounds. G. Schneider 2:05 35. De novo design revisited: Algorithm design, validation and qualification. J. Wang, I. A. Watson, M. A. Bell, Y. W. Webster, R. E. Higgs Jr., M. Vieth 2:40 Intermission. 3:00 36. De novo design of enzyme inhibi tors by growing and scoring with BOMB. W. L. Jorgensen 3:35 37. SynSPROUT and SPROUTLeadOpt: De novo ligand design and optimization guided by virtual synthesis. A. P. Johnson, V. Valko, A. Valko, Z. Zsoldos, K. Boda, D. Reid
4:10 38. Fragment based docking combined with synthetic planning: De novo eHiTS. Z. Zsoldos, A. Simon, D. Reid
Section Β Hyatt Regency McCormick 10C/D
MONDAY AFTERNOON
Section D ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Cosponsored with WCC
Hyatt Regency McCormick 11 A/B Thomas Kuhn Paradigm Shift Award Competition
J. D. Madura,
A. Nicholls and A. G. Skillman,
A. Venkatnathan,
Organizers
2:00 39. Massive, accurate empirical datasets: New tools for drug discovery and computational chemistry. C. N. Hodge 2:40 40. Bridge chemistry and biology through HTS. S. F. Yan, F. J. King, Y. He, J. S. Caldwell, Y. Zhou 3:20 Intermission. 3:40 4 1 . ADME modeling using structural data: Structure guided elimination of PXR activity. Y. Gao, S. H. Olson, J. Balkovec, Y. Zhu, I. Royo, J. Yabut, R. Evers, E. Y. Tan, W. Tang, D. P. Hartley, R. T. Mosley 4:20 42. COSMO-RS: The novel bridge from quantum chemistry to fluid phase thermo dynamics. A. Klamt Capturing Complexity in Physical Sciences Simulation Chemical Kinetics and Dynamics Sponsored by PHYS, Cosponsored with COMP Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin Sponsored by CINF, Cosponsored with COMP, and WCC Measures of Accuracy and Reliability in Molecular Simulation Enzyme and Ribozyme Function Sponsored by PHYS, Cosponsored with COMP MONDAY MORNING Section A Hyatt Regency McCormick 10 A/B Barry Honig 65th Birthday Symposium: Biological Applications of Implicit-Solvent Models C. F. W o n g , R. A. Friesner, and D. Murray, Organizers N. Ben-Tal,
Simulation Methods/Force Fields Sponsored by PHYS, Cosponsored with COMP
Presiding
8:45 43. Applications of Poisson-Boltzmann and generalized Born methods to protein solubility and protein folding and binding stability and kinetics. H-X. Zhou 9:15 44. Calculating ion permeation through biological channel proteins. R. D. Coalson 9:45 45. Challenges in calculations of elec trostatic energies in macromolecules. A. Warshel 10:15 Intermission. 10:30 46. Biological macromolecules inter acting with mixed fluid lipid membranes. A. Ben-Shaul 11:00 47. Modeling ion transport pathways through the bacterial chloride transporter. Z. Kuang, U. Mahankali, G. Feng, T. Beck 11:30 48. Continuum electrostatic models of protein-membrane interactions. D. Murray, A. Mulgrew-Nesbitt
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizer Presiding
8:30 49. Dynamics in the first hydration shell of anions. J. T. Hynes 9:00 50. Efficient global optimization: From cluster structures to protein folding. B. Hartke 9:30 51. Para-selective nitration of toluene in beta zeolite: A computational study. A. Andersen, N. Govind, L. Subramanian 10:00 52. Minimum free energy paths and isocommittor surfaces. G. Ciccotti 10:30 Intermission. 10:45 53. Role of surface dynamics in designing ordered organic nanostructures on Si and SiC dimerized surfaces via Car-Parrinello molecular dynamics. R. L. Hayes, M. E. Tuckerman 11:15 54. From first-principles to the proper ties of ionic materials, via transferable interaction potentials. P. A. Madden 11:45 55. First principles molecular dynamics of electronically excited DNA and RNA bases. T. J. Martinez, H. R. Hudock, A. Virshup, S. Yang Section C Hyatt Regency McCormick 12A
Section A Hyatt Regency McCormick 10 A/B Barry Honig 65th Birthday Symposium: Biological Applications of Implicit-Solvent Models C. F. Wong, R. A. Friesner, and D. Murray, Organizers F. Sheinerman,
Presiding
1:30 63. Implicit solvent effective potentials for simulations of protein structure and dynamics: The AGBNP effective potential with applications to protein-ligand binding, and crystallographic refinement. R. M. Levy, A. K. Felts, E. Gallicchio, J. Knight, Z. Zhou 2:00 64. Computed electrostatic properties of proteins: A powerful tool for annotation in the post-genomic age. M. J. Ondrechen 2:30 65. Electrostatics in ligand binding and design. B. Tidor 3:00 Intermission. 3:15 66. Modeling membrane potentials: When does discreteness matter? B. Olsen, Y. Song, S. Lee, D. P. Tieleman, N. A. Baker 3:45 67. Scaling in biomolecular hydration: A critical analysis of implicit solvents. C. Tan, R. Luo 4:15 68. Membrane-mediated helix-helix interactions studied by potentials of mean force calculations in explicit and implicit membrane models. W. Im, J. Lee
General Oral: Quantum Chemistry A. E. Roitberg, A. Okur,
Organizer
Presiding
8:30 56. DFT solvation studies of carbohy drates: The effect of different hydration models on the internal coordinates and alpha/beta anomeric ratios of epimers of glucose. U. Schnupf, J. L. Willett, F. A. Momany 9:00 57. Analysis of OH stretching frequen cies in glucose and glucose monohydrates calculated by DFT: Rotomer and water placement effects on the calculated spec trum. W. B. Bosma, U. Schnupf, J. L. Willett, F. A. Momany 9:30 58. DFT optimization studies of alphaMaltose: Iso-energetic and internal coordi nate contour maps upon rotation about the glycosidic bonds. F. A. Momany, J. L. Willett, W. B. Bosma, U. Schnupf 10:00 59. Coupled-cluster property calcula tions of aromatic molecules. J. R. Hammond, K. Kowalski, W. A. deJong 10:30 Intermission. 10:45 60. Topological investigation of strong intramolecular hydrogen bonding systems. J. N. Woodford 11:15 61. Nucleophilic substitution at silicon (SN2@Si) via a central barrier: Evidence for the steric nature of the SN2 reaction barrier. A. P. Bento 11:45 62. Stability of metallic nanoclusters and negative differential resistance in organic molecules. S. K. Pati
Section Β Hyatt Regency McCormick 10C/D De Novo Design Coupled to Synthetic Feasibility D. F. Ortwine,
Section C Hyatt Regency McCormick 12A General Oral: Molecular Mechanics E. X. Esposito,
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP Capturing Complexity in Physical Sciences Simulation Condensed Matter Sponsored by PHYS, Cosponsored with COMP Chemistry Applications Involving Data Analysis and Visualization Sponsored by CINF, Cosponsored with COMP Measures of Accuracy and Reliability in Molecular Simulation
Organizer
2:00 69. Practical synthetic accessibility: Can we make that compound we just designed? J. C. Baber 2:30 70. BIBuilder: A computational tool for receptor-based de novo design of drug-like molecules. M. L. Teodoro, I. A. Muegge 3:00 7 1 . Fragment-based de novo design. C. Lemmen, H. ClauBen, M. Gastreich, J. Paern, J. Degen, M. Rarey 3:30 Intermission. 3:45 72. Withdrawn. 4:15 73. Collaborative chemistry with rapid ligand prototyping: The MindRocket. C. M. Ho 4:45 74. AHChem: Generating, searching, and manipulating 10 2 0 synthetically acces sible structures. R. D. Cramer, F. Soltanshahi, R. Jilek, B. Campbell
J. A. Plumley,
Organizer Presiding
1:00 75. Ab initio molecular dynamics simu lations of shock properties of water. N. Goldman, C. J. Mundy, I. F. W. Kuo, E. J. Reed, L. E. Fried, A. Curioni 1:30 76. Medium effects on organic reactions featuring elimination mechanisms in pure and mixed solvents from QM/MM simula tions. O. Acevedo 2:00 77. Computational studies of the [Ca 3 P2] n η = 1, 2 . . . cluster systems. C. S. Palehepitiya Gamage, D. S. Marynick, K. Ueno-Noto
TECH-49
TECHNICAL PROGRAM
COMP 2:30 78. Modeling phase equilibria and transport in carbon dioxide expanded solvents. K. Kuczera, Β. Β. Laird, Y. Houndonougbo 3:00 Intermission. 3:15 79. Force dependence of phosphoryl transfer during DNA synthesis/repair by a high fidelity polymerase from Bacillus stearothermophilus (BF). R. Venkatramani, R. Radhakrishnan 3:45 80. Long timescale dynamics of shocked nitromethane. E. J. Reed, L. E. Fried, M. R. Manaa, K. R. Glaesemann, J. Joannopoulos 4:15 8 1 . Atomistic simulation of a bound + mobile lubricant. D. L. Irving, D. W. Brenner 4:45 82. Molecular dynamics simulation study of conformational and dynamic properties of self-assembled thiol monolay ers on Au. T. E. Dirama, J. A. Johnson Section D Hyatt Regency McCormick 11 A/B Rational Drug Design M. R. Reddy,
Organizer
2:00 83. New developments in the Glide XP docking and scoring methodology. R. Friesner 2:30 84. Comparative modeling and ligand binding of the dopamine transporter. J. D. Madura, M. Indarte, C. Surratt 3:00 85. Accelerating lead discovery using structure-based paradigm: Genes to Leads®. K. Ramnarayan 3:30 86. Progress in the development of an electron density enhanced scoring function in assessing ligand-receptor complexes. M. D. Ryan, M. J. Embrechts, C. M. Breneman 4:00 87. CAESAR: A super fast conforma tion generation algorithm in Discovery Studio. J. Li, K. Raghavan, J. Sutter, A. Kulkami 4:30 88. Generalized knowledge-based approach to quickly generating diverse but energetically representative ensembles of ligand conformers. R. D. Clark, R. Dorfman, Β. Β. Masek Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP Capturing Complexity in Physical Sciences Simulation Catalysis and Surfaces Sponsored by PHYS, Cosponsored with COMP Chemistry Applications Involving Data Analysis and Visualization Sponsored by CINF, Cosponsored with COMP Measures of Accuracy and Reliability in Molecular Simulation Protein-Ligand Interactions Sponsored by PHYS, Cosponsored with COMP
TUESDAY MORNING
Section C
Section A
Hyatt Regency McCormick 11 A/B
Hyatt Regency McCormick 10 A/B Barry Honig 65th Birthday Symposium: Biological Applications of Implicit-Solvent Models C. F. W o n g , R. A. Friesner, and D. Murray, Organizers E. G. Alexov,
Presiding
8:45 89. Universal solvation models and their applications. D. G. Truhlar, C. P. Kelly, A. V. Marenich, A. Chamberlin, J. M. Smith, P. Jaque, Ν. Elmasry, C. J. Cramer 9:15 90. Biomolecules and interfaces in solution. Β. Μ. Pettitt 9:45 9 1 . Implicit solvent modeling of peptidemembrane interactions. T. Lazaridis 10:15 Intermission. 10:30 92. Implicit electrostatics in molecular docking. R. Abagyan, M. Totrov 11:00 93. Reduction potentials of iron-sulfur proteins: From atomistic to continuum electrostatics. T. Ichiye 11:30 94. Simple electrostatic models for fast protein docking. D. Kozakov, R. Brenke, S. Vajda Section Β Hyatt Regency McCormick 10C/D
General Oral: Quantum Chemistry A. E. Roitberg, D. R. Roe,
Organizer
Presiding
8:30 102. Deamidation of asparaginyl resi dues in peptides and proteins. S. Catak, G. Monard, V. Aviyente, M. F. Ruiz-Lopez 9:00 103. Rationalization of the polymeriza tion of acrylates. V. Aviyente, I. Degirmenci Jr., D. Avci Sr., V. Van Speybroeck Sr., K. K. Van Cauter Jr., M. Waroquier Sr. 9:30 104. Angelis' Salt decomposition, a multiscale study. G. D. M. Seabra, J. Torras-Costa, E. Deumens, S. Trickey, A. Roitberg 10:00 105. Origin of high energy phosphoryl bonds. J. D. Evanseck, E. A. Ruben, M. S. Chapman 10:30 Intermission. 10:45 106. Stereoelectronic and steric fac tors in boron Lewis acid adducts of alpha,beta-enal compounds. J. D. Evanseck, J. A. Plumley 11:15 107. Archetypal backside SN2 reac tions: Effects of nucleophilicity and leavinggroup ability. A. P. Bento, F. M. Bickelhaupt 11:45 108. An in silico study of solvent effects on the Kolbe-Schmitt reaction kinetics. L. E. Achenie, I. Stanescu TUESDAY AFTERNOON
ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Cosponsored with WCC
Section A
J. D. Madura,
General Oral: Drug Discovery Ligands: They're Good For You!
N. Govind,
Organizer
Hyatt Regency McCormick 10 A/B
Presiding I. Visiers,
8:30 95. Importance of shear in the b c c - t o hcp transformation in iron. M. Ortiz 9:00 96. Orbital-corrected orbital-free density functional theory. Y. A. Wang, B. Zhou 9:30 97. Unraveling chemistry under extreme conditions by atomistic simulations. C. J. Wu 10:00 98. Multiscale simulations of complex materials for engineering and biological applications. E. Kaxiras 10:30 Intermission. 10:45 99. First-principles study of the effect of helium on the onset of dissociation in liquid hydrogen. K. J. Caspersen, F. Gygi, E. Schwegler 11:15 100. Impact of local bonding interac tions on condensed phase structure and reactivity. E. A. A. Jarvis, O. Coskuner, T. C. Allison, J. N. Crain, J. A. Stroscio, A. M. Chaka, M. D. Stiles 11:45 101. Award Address (ACS Award for Computers in Chemical and Pharmaceuti cal Research, sponsored by Accelrys Inc). Synergy in computational science and engineering. E. A. Carter
M O N D A Y EVENING Section A
Organizer
1:30 Introductory Remarks. 1:35 109. Opening the "black box": Interpret ing in silico models to guide compound design. E. J. Champness 2:05 110. Weighted lingos for fast similarity searching. R. Sayle, J. A. Haigh, J. A. Grant 2:35 111. Active algorithm training: A key to accurate physicochemical property predic tion. G. Pearl, K. Kassam, E. Kolovanov, S. Bhal 3:05 112. Inverse design of quinoids-based inhibitors for redox regulation of Cdc25B. S. Keinan, D. N. Beratan, W. Yang, P. Wipf 3:35 Intermission. 3:50 113. Analysis and optimization of con formational search parameters for identify ing bioactive conformations of drug-like molecules. B. W. Sherman, P. Dalai, J. C. Shelley 4:20 114. Molecular grand-canonical ensemble theory and rational drug design. O. A. von Lilienfeld, M. E. Tuckerman 4:50 115. Rational design of broad spectrum therapeutics using signature graph ker nels. J-L. Faulon, S. Martin, J. Joo
Hyatt Regency Chicago Riverside Center
Section Β
Sci-Mix
Hyatt Regency McCormick 10C/D
E. X. Esposito,
Organizer
General Oral: Molecular Mechanics
8:00-10:00 135, 142, 151, 153, 155, 159-161, 163-164, 167-168, 174-178, 180, 182-184, 188-189, 191, 193-194, 200-201, 203, 205-206, 208, 211-213, 216-217, 221, 225, 227, 229-230. See subsequent listings.
50-TECH
E. X. Esposito, E. A. Ruben,
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Organizer Presiding
1:00 116. Possible roles of mg2+ in ham merhead ribozyme catalysis from X-ray crystallography and molecular dynamics simulation. T-S. Lee, D. M. York 1:30 117. Modeling G protein-coupled recep tors for structure-based drug discovery using low-frequency normal modes for refinement of homology models. B. K. Rai, G. J. Tawa, A. H. Katz, C. Humblet
2:00 118. Characterizing the interactions between the antimicrobial peptide buforin II and nucleic acids with molecular dynam ics simulations. D. E. Elmore, E. T. Uyterhoeven, D. Ko, C. H. Butler 2:30 119. Dynamics of the interaction between factor Va and asymmetric mixed phospholipids. T. Orban, M. Kalafatis 3:00 Intermission. 3:15 120. Computational analysis of the searching and recognizing oxidative DNA lesion 8-oxo-guanine by formamido-pyrimidine DNA glycosylase. K. Song, C. De los santos, A. P. Grollman, C. Simmerling 3:45 121. Quantitative in silico analysis of enzyme reactions: Comparison of D-amino acid oxidase and monoamine oxidaze. T. Hanai 4:15 122. Multiscale molecular modeling of biomembrane heterogeneities. S. V. Bennun, M. I. Hoopes, M. L. Longo, R. Faller Section C Hyatt Regency McCormick 11 A/B Rational Drug Design M. R. Reddy,
Organizer
2:00 123. FEP-Guided lead optimization for anti-HIV agents. W. L. Jorgensen 2:30 124. Use of computer-assisted drug design in drug discovery: Limitations and advantages of available computational methods. M. R. Reddy, M. D. Erion, Q. Dang, P. D. van Poelje 3:00 125. End-point binding free energy calculations with the LIE approach. J. Carlsson, M. Almlôf, M. Andér, J. Aqvist 3:30 126. New tools for computer-aided drug-discovery. M. K. Gilson 4:00 127. Accommodating receptor flexibility in structure based drug design. R. E. Amaro, J. A. McCammon 4:30 128. In silico lead optimzation: Results for a test set of Hsp90 ligands. M. Brunsteiner, P. A. Petukhov, N. Foloppe, C. Richardson Capturing Complexity in Physical Sciences Simulation Oxides and Hydrides Sponsored by PHYS, Cosponsored with COMP Measures of Accuracy and Reliability in Molecular Simulation Protein Dynamics, Solvation, and Association Sponsored by PHYS, Cosponsored with COMP T U E S D A Y EVENING
Sheraton Chicago River Exhibit Hall General Posters J. D. Madura,
Organizer
6:00-8:00 129. A basis set perspective on density functional performance. B. P. Prascher, B. Wilson, A. K. Wilson 130. Automated pharmacophore query optimization with genetic algorithms: Case study of MC4R. L. Jia, J. Zou, H. Sun 131. Ab initio calculations on the intramolecular Schmidt reaction. J. M. Cannone, J. L. Poutsma 132. Genetic function approximation insights into Plasmodium falciparum dihydrofolate reductase and famesyltransferase inhibition. P. Sivaprakasam, A. Xie, P. N. Tosso, R. J. Doerksen 133. Hydrolysis in pure water: Car-Parrinello metadynamics on the hydrolysis of esters at pH7. H. Gunaydin, K. N. Houk 134. Modified effective core potentials for the efficient modeling of metallocenes. J. L. Lewin, C. J. Cramer 135. Molecular dynamics simulations of R67 dihydrofolate reductase: Investigation into the cooperative binding. C. Shi, J. L. Poutsma
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A
n»rC60) analysis and interaction with wastewater biomass. P. K. Westerhoff 9:50 Intermission. 10:10 5. Behavior and removal of multiwalled carbon nanotubes during simulated drink ing water treatment processes. C. B. Mansfeldt, C. B. Bott, R. D. Holbrook 10:30 6. Transport and retention of C 6 Q fullerene in water-saturated soils. Y. Wang, Y. Li, J. D. Fortner, J. B. Hughes, L M. Abriola, K. D. Pennell 10:50 7. Characterization of the size, shape, crystallinity and surface charge of Ceo aggregates formed in aqueous systems. L. K. Duncan, P. J. Vikesland 11:10 8. Dispersion and disaggregation of fullerene aggregates in the aqueous phase induced by natural organic matter. B. Xie, Q.Li Section Β McCormick Place South Room S403B, Level 4 Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Organics and Nanoparticle Reactivity Cosponsored with GEOC
Environmental Characterization, Impacts and Applications of Nanocarbons S. Agnihotri and B. Kura, Presiding
Organizers,
1:30 16. Effect of water vapor adsorption on surface functionality of single-walled car bon nanotubes. P. Kim, Y. Zheng, L. N. Vadlamani, S. Agnihotri 1:50 17. Photochemical production of reac tive oxygen species (ROS) by aqueous C60 colloids during the UV illumination. J . Lee, J. D. Fortner, J. B. Hughes, J-H. Kim 2:10 18. Uptake and depuration behaviors of carbon-14 single- and multi-walled carbon nanotubes by L. variegatus. E. J. Petersen, Q. Huang, W. J. Weber Jr. 2:30 19. Influence of surface chemistry on the aquatic stability of carbon nanotubes. B. Smith, H. Fairbrother, W. P. Ball 2:50 20. Interactions of water soluble fullerene with model cell membranes probed by atomic force microscopy. T. A. Spurlin, A. A. Gewirth 3:10 Intermission. 3:30 2 1 . Solubility of buckminsterfullerene (Ceo) ' n organic solvent mixtures. P. P. Kulkarni, C. T. Jafvert 3:50 22. Influence of surface oxides on the adsorption of hydrophobic organic chemi cals and heavy metals onto carbon nano tubes. B. Smith, H-H. Cho, W. P. Ball, H. Fairbrother 4:10 23. Microbial interactions of carbon nanomaterials. P. M. V. Raja, G. P. Ganesan, P. M. Ajayan, O. Nalamasu, A. Sharma 4:30 24. Ozonation of C 6 0 in water. J. D. Fortner, D-l. Kim, A. M. Boyd, J. C. Falkner, S. Moran, J. B. Hughes, J-H. Kim Section Β
Nanoparticles: Synthesis, Passivation, Stabilization, and Functionalization (see COLL, Sun, Mon, Tue, Wed, Thu)
D. E. Giammar and E. J. O'Loughlin, Organizers D. M. Cwiertny,
Estimation of Environmental Expo sure to Agrochemicals Using Spatial Data Analysis and Geographic Infor mation Systems (see AGRO, Tue, Wed, Thu) Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse (see SUST, Tue, Wed) Micro/Nano Encapsulation of Active Food Ingredients (see AGFD, Mon, Tue, Wed) Polymer-Based Nanoparticles and Nanostructures (see PMSE, Wed, Thu) SOCIAL E V E N T S : Dinner: Tue Social Hour: Tue BUSINESS M E E T I N G : Executive Committee Meeting: Sun
McCormick Place South Room S403B, Level 4
Presiding
M. L. McCormick, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 9. Probing oxide surface reactivity with organic contaminants: From kinetic and product studies to stable isotope fraction ation. M. Eisner, D. M. Cwiertny, M. M. G. Chartrand, G. Lacrampe-Couloume, A. L. Roberts, B. Sherwood Lollar 9:20 10. Kinetic and microscopic studies of reductive transformations of organic con taminants on synthetic goethite and natu ral sediments. C. L. Chun, G. Commellas, W. A. Arnold, R. L. Penn 9:45 11. Degradation of trichloroethylene by pyrite-goethite at elevated temperatures. J. Costanza, K. D. Pennell 10:10 Intermission. 10:30 12. Loss of reactivity of magnetite (Fe 3 0 4 ) due to particle aggregation induced by the presence of electrolytes. R. F. Rebodos, J. A. Templeton, P. J. Vikesland 10:55 13. Effect of aging on the structure and reactivity of nanoparticles of iron/iron oxides. V. Sarathy, J. T. Nurmi, P. G. Tratnyek, J. E. Amonette, D. R. Baer, C. L Chun 11:20 14. Reduction of trichloroethylene as a dense non-aqeous phase by surfactantmodified bimetallic nanoscale zero-valent iron. A. Ryu, H. Choi
Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Organics and Nanoparticle Reactivity Cosponsored with GEOC D. E. Giammar,
Organizer
M. L McCormick and E. J . O'Loughlin, Organizers, Presiding 1:20 Introductory Remarks. 1:25 25. Effect of groundwater constituents on H 2 evolution and TCE reduction by reactive Fe(0)/Fe-oxide nanoparticles. Y. Liu, T. Phenrat, G. V. Lowry 1:50 26. Fe(ll) sorption on nanoscale goethite. D. M. Cwiertny, R. M. Handler, M. V. Schaefer, V. H. Grassian, Μ. Μ. Scherer 2:15 27. Characterizations and reactivity of metal-doped iron and magnetite nanopar ticles. C. L. Chun, D. R. Baer, D. Matson, J. E. Amonette, R. L. Penn
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-53
TECHNICAL PROGRAM
ENVR 2:40 28. Tunable synthesis and immobiliza tion of iron nanoparticles for environmental applications. Q. Huang, X. Shi, R. Pinto, E. J. Petersen, W. J. Weber Jr. 3:05 Intermission. 3:25 29. Reduction of polyhalogenated alkanes by iron(ll)-organic complexes. A. L. Bussan, T. J. Strathmann 3:50 30. Abiotic reduction of nitroaromatic contaminants by organothiol-complexed iron(ll) species. D. Naka, T. J. Strathmann 4:15 3 1 . Oxidative mechanisms and kinetics of aqueous organics' removal in hydrogen peroxide-enhanced iron-mediated aeration treatment of refractory organic wastewater. Y. Deng, J. D. Englehardt 4:40 32. Process fundamentals on the elec trolytic oxidation of iron and its effects on electrocoagulation. D. Lakshmanan, D. Clifford Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR MONDAY MORNING
9:45 43. Effect of uranium complexation on aging of iron oxyhydroxides. G. P. Halada, M. Cuiffo, A. J. Francis, C. J. Dodge 10:10 Intermission. 10:30 44. Coupled processes involved in the heterogeneous reduction of U(VI) by Fe(ll) at Fe(lll)-oxide surfaces. W. D. Burgos, J-H. Jang, B. A. Dempsey 11:15 45. Reduction of uranium under abiotic iron reducing conditions: A macroscopic and spectroscopic study. V. G. Alexandratos, T. Behrends, P. Van Cappellen 11:40 46. X-ray micro(spectro)scopy investi gations of transformations at the mineralmetal-microbe interface. Κ. Μ. Kemner, T. J. Beveridge, M. I. Boyanov, R. E. Cook, A. Dohnalkova, J. K. Fredrickson, S. Glasauer, S. D. Kelly, B. Lai, M. J. Marshall, E. J. O'Loughlin, B. D. Ravel, D. Sholto-Douglas 12:05 47. Geochemical and mineralogical controls on the oxidation of biogenic uraninite by ferrihydrite. M. Ginder-Vogel, S. Fendorf Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR
Section A McCormick Place South Room S403A, Level 4
MONDAY AFTERNOON Environmental Transport, Fate, Effects and Models of Atmospheric Pollutants H. A. Khwaja and X. Zhou,
Organizers
8:30 Introductory Remarks. 8:35 33. Succession of biogenic VOC emis sions in northern Michigan. B. Gannon, S. B. Bertman, B. V. Barnes 9:05 34. Enhancement of atmospheric mer cury deposition by plants within a northern forest landscape, USA. J. T. Bushey, A. G. Nallana, C. T. Driscoll, H-D. Choi, T. Holsen 9:25 36. Characteristics of PM2.5 carbon aceous aerosol in urban New York State. H. A. Khwaja, V. Dutkiewicz, R. Briggs 9:45 Intermission. 10:05 37. Charring of organic compounds during thermal-optical analysis: What can we learn about the carbonaceous aerosol? R. Subramanian, P. Boparai, T. Bond 10:25 38. Chemical speciation of chromium in ambient aerosol particles. P. S. Nico, M. Werner, C. Anastasio, M. A. Marcus 10:45 39. Trace metals and Pb isotopic signatures of aerosols in the Pearl River Delta, South China: Influences of the long-range transport of air contaminants. C. S. L. Lee, X-D. Li, G. Zhang, J. Li, A-J. Ding, T. Wang 11:05 40. Characterization of polycyclic aromatic hydrocarbons of TSP in Beijing, China for a three-year record. K. He, Y. Jia, Y. Ma, Y. Lei, D. Zhang, S. Tanaka, T. Okuda Section Β McCormick Place South Room S403B, Level 4 Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Green Rusts and Uranium Complexation/ Reduction Cosponsored with GEOC M. L. McCormick,
Section A McCormick Place South Room S403A, Level 4 Environmental Transport, Fate, Effects and Models of Atmospheric Pollutants H. A. Khwaja and X. Zhou,
Organizers
1:30 Introductory Remarks. 1:35 48. Evidence of nitric acid photolysis on surfaces as a Re-NOx-ification pathway. X. Zhou, H. Gao, Y. He 2:05 49. Adsorption and photochemical reactions of PAHs at the air-water inter face of fog droplets. Κ. Τ. Valsaraj, J. Chen 2:25 50. Chemical ionization mass spectrom etry as a tool for studying the surface interactions of the air pollutant acetone with Degussa P25 T i 0 2 . C. M. Schmidt, A. Savara, E. Weitz, F. M. Geiger 2:45 5 1 . Regiochemistry of the N0 3 -promoted gas phase nitration of toluene and phenol with N 0 2 . E. Bolzacchini, M. Bruschi, G. Galliani, J. Hjorth, M. Orlandi, B. Rindone 3:05 Intermission. 3:25 52. Soil-air exchange: From the labora tory to the field experiments. J. Klanova, P. Ruzickova, M. Koblizkova, I. Holoubek 3:45 53. Assessing the feasibility of employ ing passive air samplers for long-term air quality monitoring programs. J. Klanova, P. Cupr, J. Kohoutek, I. Holoubek 4:05 54. Pollutant formation in a near stoi chiometric gasoline flame as a function of fuel structural composition. H. R. Zhang, E. G. Eddings, A. F. Sarofim 4:25 55. Atmospheric corrosion of Al-oxyhydroxide films by NaCI droplets. L. J. Criscenti, H. Finley-Jones, H. Moffat, R. Cygan 4:45 Concluding Remarks.
54-TECH
McCormick Place South Room S403B, Level 4 Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Biotic Processes, Uranium, Arsenic Cosponsored with GEOC M. L. McCormick, M. I. Boyanov,
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Organizer
Presiding
D. E. Giammar, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 56. Redox transformations of metals and radionuclides: Unraveling biotic and abiotic mechanisms through geomicrobiological studies. J. R. Lloyd 2:20 57. Quantitatively describing and pre dicting electron balance between competi tive iron and uranium reduction. B. D. Stewart, P. S. Nico, R. Amos, S. Fendorf 2:45 58. Comparison of arsenic removal from groundwater by iron oxide coated sand: Mechanisms, kinetics and influence of anions. S. R. Kanel, Ο. Κ. Hartzog, V. A. Loganathan, M. O. Barnett, T. P. Clement 3:10 Intermission. 3:30 59. Transformation and mobilization of arsenic adsorbed on granular ferric hydroxide under bioreductive conditions. S. R. ΑΙ-Abed, G. Jegadeesan, P. Pinto 3:55 60. Catalytic effect of arsenic on iron reduction in freshwater sediments. S. Chow, M. Taillefert 4:20 6 1 . Biologically-enhanced sequestration of phosphate in iron-enriched sediments. L. Sandersfeld, M. Clayton, E. J. Brown 4:45 62. How the oxidation of Fe(ll) affects cadmium immobilization by bacterial sur faces. X. Châtellier, M. Fakih, C. J. Daughney Undergraduate Research Poster Session: Environmental Chemistry Sponsored by CHED, Cosponsored with SOCED, and ENVR M O N D A Y EVENING
Section A Hyatt Regency Chicago Riverside Center
Sci-Mix G. Coimbatore,
Organizer
8:00-10:00 66, 68, 133, 143, 145, 148, 151, 167, 169, 173, 175, 178, 182, 189, 191, 195, 201202. See subsequent listings. TUESDAY MORNING
Section A McCormick Place South Room S100B/C, Level 1
9:55 67. Comparison of the photocatalytic properties of T i 0 2 nanoparticles prepared by sol-gel and ultrasonic assisted sol-gel methods. B. Neppolian, Q. Wang, H. Choi 10:15 Intermission. 10:30 68. Imprinted polymers for heavy metal ion removal from water. S. A. Ashraf, A. Mueller 10:50 69. Oxidation of selected organophosphate pesticides during chlorination of drinking water. C. Byrne, A. Kamel, C. Vigo, J. Ferrario, C. Stafford, G. Verdin, F. Siegelman, S. Knizner, J. Hetrick 11:10 70. Drive to produce evenly-distributed coatings of reagents in the equatorial plane of 37-mm glass fiber membrane filters. S. P. Tucker 11:30 7 1 . QSAR model for absorption rate constant of drugs in humans. S. K. Dogra, J. B. Dikshit, N. Gupta, K. Subramanian Section Β McCormick Place South RoomS105A, Level 1 Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Health and Regulatory Concerns of DBPs and Analytical Methods Cosponsored with CEI, and SUST T. Karanfil, P. K. Westerhoff, and Y. F. Xie, Organizers S. W. Krasner, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 72. Evolution of DBP regulations. J. A. Roberson 9:00 73. Comparative mammalian cell toxic ity of N-DBPs and C-DBPs. M. J. Plewa, E. D. Wagner, M. G. Muellner, K. M. Hsu, S. D. Richardson 9:25 74. Use of chemical models and struc ture-activity relationships to identify novel disinfection by-products of potential toxicological concern. R. J. Bull, D. A. Reckhow 9:50 75. Chlorinated vs. chloraminated drinking water: Toxicity-based identification of disinfection by-products using ESI-MS and ESI-MS/MS. S. D. Richardson, F. G. Crumley, M. J. Plewa, E. D. Wagner, T. Mize, P. Angel, R. Orlando, L. Williamson, M. G. Bartlett 10:15 Intermission. 10:30 76. Contribution of organic bromines to the mutagenicity of chlorinated water. S. Echigo, S. Itoh, R. Ando 10:55 77. 2-D Matrix diversion method for improved bromate analysis in drinking waters by suppressed ion chromatography with conductivity detection. R. Lin, H. Wagner, K. Srinivasan, S. Bhardwaj, C. Pohl 11:20 78. Overview and strategies for con ducting real-time monitoring studies.for THMs and HAAs. G. L. Emmert, M. A. Brown, P. Simone Jr., G. Geme, L. J. Thurston 11:45 79. Determination of haloacetic acids and dalapon via ion chromatography and tandem mass spectrometry. A. Zaffiro, R. Al-Horr, D. J. Munch, B. Pepich Going with the Flow: Water Sustainability Past, Present, Future Sponsored by HIST, Cosponsored with PRES, SUST, and ENVR
General Topics G. Coimbatore,
Organizer
D. E. Giammar and E. J. O'Loughlin, Organizers, Presiding 8:30 Introductory Remarks. 8:35 4 1 . Contaminant interactions with green rusts: Abiotic and biotic pathways. M. M. Scherer, H. Ali, M. I. Boyanov, J. D. Coates, C. A. Gorski, K. M. Kemner, P. Larese-Casanova, D. E. Latta, E. J. O'Loughlin, S. L. Smith, M. St. Clair, K. A. Weber 9:20 42. Mechanisms of U(VI) uptake and reduction by carbonate, sulfate and chlo ride green rusts studied by XAFS. M. I. Boyanov, E. J. O'Loughlin, S. L. Smith, S. D. Kelly, D. E. Latta, B. D. Ravel, M. St. Clair, M. M. Scherer, Κ. Μ. Kemner
Section Β
Organizer
8:30 Introductory Remarks. 8:35 63. Correlation of atmospheric ultrafine particle iron and mitochondrial toxicity. C. Thomas, S. L. Bryner, E. L. Bullock, A. M. Johansen, J. M. Johnston, J. K. Wells 8:55 64. Electrochemical detection of parts per billion lead via an electrode-bound DNAzyme assembly. Y. Xiao, A. A. Rowe, K. W. Plaxco, A. J. Heeger 9:15 65. Electrochemical reduction of perchlorate ions on pitting corrosion developed titanium surface. C. Lee, T. A. Kramer 9:35 66. Fluorescence-based organophosphorus pesticide detection. T. Haywood, B. J. Engelmann, D. S. Beaudoin, W. Guo, S. O. Obare
Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Catalytic Control of Emerging Micropollutants Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Sponsored by SUST, Cosponsored with ENVR
ENVR
TUESDAY AFTERNOON Section A McCormick Place South Room S100B/C, Level 1 ACS Award for Creative Advances in Environmental Science and Technology (in Memory of Joseph J. Breen): Symposium in Honor of Richard C. Flagan Cosponsored with Air Products and Chemicals R. A. Hathaway, Β. Ε. Wyslouzil,
Organizer Presiding
1:00 Introductory Remarks. 1:05 80. Award Address (ACS Award for Creative Advances in Environmental Science and Technology, sponsored by Air Products and Chemicals, Inc). Toward ubiquitous aerosol monitoring. R. C. Flagan 1:35 8 1 . Aerosol-cloud interactions: Recent advances in measurements and modeling. S. M. Kreidenweis 1:55 82. Collection of ultrafine aerosols by electrostatic classification for size-resolved chemical analysis. D. J. Phares 2:15 83. Factors affecting indoor exposure to carbonaceous aerosols. M. M. Lunden 2:35 84. Characterizing the interactions of water vapor with carbonaceous aerosol. A. Nenes, A. Asa-Awuku, L. T. Padro 2:55 Intermission. 3:10 85. Predicting nanoparticle interfaces with molecular dynamics. L. Russell, R. Bahadur 3:30 86. Isothermal nucleation rates in supersonic nozzles and the properties of small water clusters. Β. Ε. Wyslouzil, G. Wilemski, R. Strey, J. Wôlk, Y. J. Kim 3:50 87. Applications of nanoparticles and nanostructured films synthesized by aerosol routes for environmental and renewable energy technologies. P. Biswas 4:10 88. Development and application of a high-resolution time-of-flight aerosol mass spectrometer. J . L. Jimenez, P. Decarlo, J. R. Kimmel, J. A. Huffman, I. Ulbrich, E. Dunlea, A. Trimbom, M. J. Northway, J. T. Jayne, A. C. Aiken, M. Gonin, K. Fuhrer, T. Horvath, K. S. Docherty, D. R. Worsnop 4:30 Concluding Remarks. Section Β McCormick Place South Room S105A, Level 1 Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Reactivity of NOM toward DBP Formation Cosponsored with CEI, and SUST S. W. Krasner, P. K. Westerhoff, and Y. F. Xie, Organizers T. Karanfil, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 89. Disinfection by-product precursor content of natural organic matter extracts. D. A. Reckhow, G. Makdissy, P. S. Rees 2:00 90. Precursor identification of haloacetic acids (HAAs) and trihalomethanes (THMs): A UK perspective. C. Bougeard, E. H. Goslan, B. Jefferson, S. A. Parsons 2:25 9 1 . Characterization of by-products of isolated fractions of natural organic mat ters by chlorination. J . Lu, J . Ma, T. Zhang, Z. Chen, Q. Wang 2:50 92. Relationship between brominated THMs, HAAs and total organic bromine during drinking water chlorination. G. Hua, D. A. Reckhow 3:15 Intermission. 3:30 93. Correlations among DBP formation and NOM properties during chloramination. X. Yang, C. Shang, W. Lee, P. Westerhoff, C. Fan 3:55 94. Formation of haloacetic acids from dissolved organic matter and its fractions during chloramination. Y. Hong, H. Song, T. Karanfil
4:20 95. Pre-chlorination-induced DOC and DBPs' formation from M. aeruginosa in water treatment processes. C-A. Chiu, G-S. Wang 4:45 96. Impact of pre-ozonation on the formation of haloacetic acids and trihalomathanes from algae cells and extracellu lar organic matter. J. Fang, J. Ma Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Sponsored by SUST, Cosponsored with ENVR WEDNESDAY MORNING Section A McCormick Place South Room S100B/C, Level 1 Remediation Technologies for Chromium J. L. Gardea-Torresdey,
Organizer
8:30 Introductory Remarks. 8:35 97. Using infrared imaging to determine changes in plant structure due to chromium(VI) exposure. K. M. Dokken, M. O. Montes-Holguin, J. R. Peralta-Videa, J. L. Gardea-Torresdey 8:55 98. Soil amendments for in situ immobi lization of chromium. A. P. Schwab, M. Banks, C. Henderson 9:15 99. X-ray and vibrational spectroscopic tools for investigating Cr(VI) reduction by Fe(ll) and Fe(0) materials. B. A. Manning, J. Kiser, J. Hatch 9:35 100. Cr(VI) reduction using fructose, glucose and sucrose. B. Bilyeu, P. Balderas-Hernândez, G. Roa-Morales, C. Barrera-Diaz 9:55 101. Evolved high activity enzymes for enhancing combined bacterial chromate and uranyl bioremediation. A. C. Matin, Y. Barak, D. Ackerley, Y. Nov, A. J. Francis, C. Dodge 10:15 Intermission. 10:45 102. Chromium uptake and speciation by both desert and non-desert plant species. J. G. Parsons, G. de la Rosa, J. R. Peralta-Videa, M. V. Aldrich, J. L. Gardea-Torresdey 11:05 103. Remediation of Cr(VI) using zero-valent iron nanoparticles: Kinetics and stoichiometry. J . Cao, X-Q. Li, W. X. Zhang 11:25 104. Chemical and spectroscopic approaches to determine the adsorption of chromium species to saltbush (Atriplex canescens) biomass. M. F. Sawalha, J. R. Peralta-Videa, J. Parsons, J. L. Gardea-Torresdey 11:45 105. Monitoring fate and transport of chromium using stable isotopes. A. S. Ellis, T. M. Johnson, T. D. Bullen, E. Sikora, J. Kitchen 12:05 106. Effect of the growth stage and sulfate concentration on Cr(VI) uptake and tolerance by Helianthus annuus. G. de la Rosa, R. Lopez-Camargo, G. Cruz-Jimenez, I. Cano-Rodriguez, M. P. Gutierrez-Valtierra, J. R. Peralta-Videa, J. L. Gardea-Torresdey
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section Β McCormick Place South Room S105A, Level 1 Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Probing Formation of DBPs Cosponsored with CEI, and SUST T. Karanfil, S. W . Krasner, P. K. Westerhoff, and Y. F. Xie, Organizers D. A. Reckhow,
Presiding
8:30 Introductory Remarks. 8:35 107. Scaled-up chlorination of surface water using reverse osmosis concentrates for detection of priority DBPs in drinking waters. N. Bodin, H. S. Weinberg, S. W. Krasner, S. D. Richardson, J. E. Simmons 9:00 108. Examination of contributions of kinetically distinct chromophores in NOM chlorination: Results of conventional and stop-flow differential absorbance spectros copy. G. V. Korshin, M. M. Benjamin, H-S. Chang, H. Gallard 9:25 109. Formation of chlorination by products in low-SUVA surface waters: Correlations with SUVA and differential UV spectroscopy. N. Ates, M. Kitis, U. Yetis 9:50 110. Probing the formation of individual chlorinated and brominated disinfection by-products using fluorescence indices. P. Roccaro, F. Vagliasindi, G. Korshin 10:15 Intermission. 10:30 111. Volatile by-product formation resulting from chlorination of organic-N precursors in recreational water. C. Blatchley, J. Li 10:55 112. Reactivity of bromine-substituted haloamines in forming haloacetic acids. P. G. Pope, G. E. Speitel Jr. 11:20 113. Tracking total organic halide formation and transformation during chlori nation. Q. Zhao, C. Shang 11:45 114. Comparison of the performance of absorbance-based indices developed to quantify the halogenation of natural organic matter at varying chlorine concen trations. P. Roccaro, F. Vagliasindi, G. Korshin Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Sponsored by SUST, Cosponsored with ENVR WEDNESDAY AFTERNOON Section A McCormick Place South Room S100B/C, Level 1
2:05 118. Removal of heavy metals, microbial organisms and particulates from drinking water using a natural material. N. Alcantar, P. Stroot, T. Pichler 2:25 119. Screening of toxic elements in pineapples from plantations located in Vieques and Barceloneta, Puerto Rico, using ICP-OES. J. L. Lopez-Morales, F. R. Roman 2:45 Intermission. 3:15 120. Chromium uptake by mesquite (Prosopis spp.) exposed to Cr(lll) and Cr(VI) in hydroponics. J. A. Arias, J. R. Peralta-Videa, N. S. Mokgalaka, H. A. Castillo-Michel, J. L. Gardea-Torresdey 3:35 121. Design of chemically-activated materials for improved removal of Cr(VI) from water. Z. Yue, J. Wang, S. E. Bender, J. Economy 3:55 122. Bioaccumulation of chromium from mine tailings to a desert plant, desert broom (Baccharis sarothroides). M. D. N. Haque, J. L. Gardea-Torresday, J. R. Peralta-Videa 4:15 123. Reduction of chromium(VI) for the treatment of model wastewater using copper nitrate catalyst. Y. W. Goshu, Y. V. Tsaryov, V. V. Kostrov 4:35 124. Chromium accumulation and its influence on growth and the antioxidative system in Sesbania drummondii. M. Israr, J. L. Gardea-Torresdey, S. Sahi Section Β McCormick Place South Room S105A, Level 1 Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation and Control of Regulated DBPs Cosponsored with CEI, and SUST T. Karanfil, S. W. Krasner, P. K. Westerhoff, and Y. F. Xie, Organizers P. C. Singer,
Presiding
1:30 Introductory Remarks. 1:35 125. Use of multiple linear regression models to examine impacts of water quality and treatment on DBP formation using the ICR database. A. Obolensky, P. C. Singer 2:00 126. Evaluating GAC performance on preformed HAA removal using ICR data base. H-H. Tung, Y. F. Xie 2:25 127. MWRAs experience with disinfec tion by-products. W. Sung 2:50 128. Bromine incorporation down under. P. C. Singer, T. H. Boyer, C. Chow, M. Holmes, R. Trolio, K. G. Xanthis, R. Walker 3:15 Intermission. 3:30 129. Combined treatments for enhanced reduction of trihalomethane precursors. R. B. Fabris, C. W. K. Chow, M. Drikas 3:55 130. Removal of DBP precursors using the MIEX process in combination with granular activated carbon. M. Drikas, M. Dixon, J. Morran 4:20 131. Disinfection by-product (DBP) formation and speciation in chlorinated waters after anion exchange treatment. Y. Tan, J. Kilduff, T. Karanfil 4:45 132. Biodégradation and photolysis of disinfection by-products. P. K. Westerhoff
Remediation Technologies for Chromium J. L. Gardea-Torresdey and J. R. Peralta-Videa, Organizers 1:00 Introductory Remarks. 1:05 115. Spectroscopic studies of Cr(VI) absorption and reduction by Convolvulus arvensis and Medicago truncatula. M. O. Montes-Holguin, J. R. Peralta-Videa, J. L. Gardea-Torresdey 1:25 116. First field study demonstrating stable chromium isotopes as a quantifier of Cr(VI) reduction. E. Berna, T. M.Johnson 1:45 117. Orange peels as an effective Cr(VI) biosorbent. B. Bilyeu, P. Balderas-Hernândez, G. Roa-Morales, C. Barrera-Diaz
Great Lakes Research: Environmental Issues for a Freshwater Ecosystem Sponsored by CINF, Cosponsored with ENVR, and SUST Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Sponsored by SUST, Cosponsored with ENVR
TECH-55
TECHNICAL PROGRAM
ENVR W E D N E S D A Y EVENING
Section A Hyatt Regency Chicago Riverside Center General Papers G. Coimbatore, Organizer,
Presiding
6:00-8:00 133. The Division of Environmental Chemis-' try. G. Coimbatore 134. Environmental analytical chemist and technician certification. R. A. Hathaway 135. Bioaccumulation and oxidative stress induced by polynuclear aromatic hydrocar bons (PAHs) in Ceratophyllum demersum L. X. Wang 136. Effect of rare Earth cerium on the photocatalytic behavior of semiconductor TiC^. X. Rui-Fen, L. Kun, L. Xiao-ling, L. Li-min 137. Degradation of rhodamine Β by a sonoFenton process using Fe@Fe 2 0 3 coreshell nanowires as the iron reagent. Z. Ai, L. Lu, J. Li, L. Zhang 138. Visible light degradation of Rhodamine Β by a photo-electrochemical process based on a B i 2 W 0 6 nanoplates film electrode. J. Li, Z. Ai, X. Zhang, L. Zhang 139. Analysjs of pesticides in breast milk using stir bar sorptive extraction. A. T. Awad, B. A. Rocha-Gutierrez, W-Y. Lee 140. Analysis of petroleum hydrocarbons and trace metals in highway runoff. F. Jackson, R. Hannigan 141. Correlating the viscosity of oxidized motor oil with its 1 H-NMR. N. Lloyd, S. M. Abernathy, K. Sims, J. R. Speaks 142. Amination of activated carbons for the removal of natural organic matter from freshwater supplies. Y. Guo, T. Karanfil 143. Analysis of polarity fractionated dissolved organic matter using 3-D fluorescence excitation-emission matrix spectroscopy. F. L. Rosario-Ortiz, S. Snyder, I. H. Suffet 144. Arsenic removal and stabilization by synthesized pyrite. J. Song, B. Batchelor 145. Baseline toxicity assessment by an alternative method of Pseudomonas initial oxygen uptake assay. C-W. Tseng, M-S. Ling, T-J. Whang, D-S. Huang 146. Characteristics of heavy metal removal using magnetically modified alginic acid. C. Jeon, S. Y. Shim, H. S. Kim, K-H. Park 147. Characterizing the adsorption of triethylamine on zirconium silicate and polyethyl ene surfaces. X. Guo, C. C. Chusuei, M. Ongwandee, G. C. Morrison 148. Chemical and ecotoxicity assessment of aerobically biotreated residual fish fat. A. Selberg, T. Tenno 149. Chlorination of organophosphorus pesti cides in natural waters. J. L. Acero, F. J. Benitez, F. J. Real, A. I. Leal, T. Fernandez 150. Comparative study of chemical species of mercury in tailings exposed to repro cessing activities in Mexico. I. G. Gavilan, E. S. Santos, M. Yarto, A. Gavilân-Garcia, R. Rosiles, S. T. Suarez, J. Esquivel 151. Comparison of the urinary metabolites of rats, mice and humans after oral arsenic exposure focusing on thioarsenicals. S. D. Conklin, Β. Μ. Adair, P. A. Creed, J. T. Creed, M. F. Hughes, D. J. Thomas 152. Copper speciation and teachability from an industrial sludge. J. Xu, S. Dai, S. Sun, X.Han 153. Degradative solidification/stabilization of liquid wastes containing trichloroethylene using cement/steel slag/Fe(ll). W-H. Kang, I. Hwang, J-Y. Park 154. Determination of alkaloid diversity within the Solanacae family using GC-MS. T. A. Moss, J. Jelesko, S. Hildreth, J. Sandoe, I. Gartner, R. Hannigan 155. Determination of chlorinated pesticides and PCBs in the lagoon "La Escondida" in Reynosa, Mexico, by chromatography with electron-capture detection (GCED). J. E. Castrejon, I. Palos, C. Meza 156. Determination of polybrominated diphenyl ethers in sediments using pressurized liquid extraction and gas chromatographymass spectrometry. W-H. Ding 157. Effect of As(lll) exposure on the activity of starch degrading enzymes in pea leaf. H. A. Castillo-Michel, J. Peralta-Videa, K. M. Dokken, J. L. Gardea-Torresdey
56-TECH
158. Effect of pH on the dissolution kinetics of zero-valent iron in the presence of EDDHA and EDTA. A. Lodge, Ε. Μ. Pierce, D. M. Wellman, E. A. Rodriguez 159. Advanced treatment of textile wastewater with combined media biological aerated filter (CMBAF). F. Liu, C. Zhao, D. Zhao, G.Liu 160. Effect of phosphate on arsenite adsorp tion by mesoporous adsorbents impregnat ing nanostructured titania. D. Han, B. Batchelor 161. Electrocatalytic oxidation of £>efa-nicotinamide adenine dinucleotide at a poly(2,2bithiophene)-coated glassy carbon elec trode. J . Stinson, S. Lunsford, J. Widera, H. Choi, D. D. Dionysiou 162. Electron transfer mediator effects on the bioreduction of lepidocrocite by Shewanella putrefaciens CN32. E. J. O'Loughlin 163. Evaluation of solution composition on aluminoborosilicate waste glass dissolution at 40°C. E. L. Richards, A. Davis, Ε. Μ. Pierce 164. Flora and fauna on the "La Escondida" lagoon in Reynosa, Tamaulipas, Mexico. I. Palos, J. E. Castrejon, J. C. Gutierrez 165. Global gene expression profiling by pesticide endosulfan in human HepG2 cells. H-Y. Sohn, H-E. Kim, M-J. Jang, M-H. Park, J-S. Kim, Y-H. Kim, J-B. Lee, G-S. Kwon 166. Greenhouse gas flux at Halfway Creek Marsh. M. Karpinsky, M. A. Engen 167. Heterogeneous catalytic reduction of perchlorate using molecular rhenium(V) precursors. K. D. Hurley, J. J. Daleiden, J. R. Shapley 168. High throughput discovery of low-tem perature water-gas-shift catalysts. K. Yaccato, A. Hagemeyer, A. Lesik, A. F. Volpe Jr., C. J. Brooks 169. Impact of wastewater discharge on water quality and challenge in drinking water treatment. H. Lei, S. Snyder 170. Metal and organic sediment contami nants from homes in New Orleans, Louisi ana, following Hurricane Katrina: Longterm environmental and human health implications. N. Ashley, K. T. Valsaraj, L. Thibodeaux 171. Microbiologic study of the lagoon "La Escondida" in Reynosa City, Mexcio, in four seasons of the year. I. Palos, J. E. Castrejon, B. Juarez 172. Mn02-mediated transformation of oxytetracycline and chlortetracycline: Character ization of transformation products. K. F. Rubert IV, C. J. Hedman, J. A. Pedersen 173. Modeling of the system of calcium sul fide and water. K. Hellat, A. Mashirin, T. Tenno 174. Pesticide measurement using a tyrosi nase electrode improved by gold nanoparticles. S-H. Moon, G-Y. Kim 175. pH profiles for catalytic nitrite reduction with Pd/Cu/PVP nanoparticles. K. A. Guy, J. R. Shapley 176. Photochemical reduction of iron(oxy)hydroxides in the presence of dimethyl sulfide-derived electron donors. A. M. Johansen, B. Affholter, A. Nieber, N. Paulk, J. M. Key 177. Withdrawn. 178. Polybrominated diphenyl ether (PBDE) levels, signatures and sources in the lower Hudson River basin. L. A. Benedict, R. F. Bopp, S. N. Chillrud, D. A. Chaky, J. P. Smith, C. R. Olsen 179. Polycyclic aromatic hydrocarbon concen trations in wood smoke from prescribed fires of the Southwest. M. S. Robinson, X. Nelson, P. Herckes 180. Preconcentration of trace arsenite and arsenate with titanium dioxide nanopar ticles and subsequent determination by the silver diethyldithiocarbamate spectrophotometric method. Y. Xiao, J. Ling, A. Lin, W. Zheng, W. Xu
Please refrain from using cellular telephones and cameras during technical sessions.
181. Preparation of polymer-based ion-ex change capable modified electrodes: Monomer synthesis, electrode character ization and performance evaluation. A. R. Knauff, M. J. Samide 182. Profiling dioxin in salmon oil and bacon using a high-sensitivity 1 mm capillary microprobe via 1 H-NMR. S. M. Abernathy, R. Gil, A. Akinyemi 183. Reductive dechlorination of tetrachloroethylene by GRs with platinum. J. Choi, S. G. Shim, B. Batchelor, W. Lee 184. Reductive removal of naphthalene using bimetal catalyst and hydrogen. Y. H. Kim, Y-S. Jeong, W. T. Lim, W. S. Shin, M-C. Kim, Y. J. Oh, T. W. Ha 185. Response of phytoplankton communities to phosphorus addition in urban shallow lake enclosures. C. Liu, X. Jin, H. Sun, L. Sun, S. Dai, Y. Zhuang 186. Response of the freshwater alga Chlorella vulgaris to trichloroisocyanuric acid and ciprofloxacin. N. Xiangping 187. Risk identification on mercury contami nated sites of Mexico using two chemical speciation methods. I. G. Gavilan, E. S. Santos, M. Yarto, A. Gavilân-Garcia, R. Rosiles, S. T. Suarez, J. Esquivel 188. Roles of oxidation and coagulation in removal of organics during Fenton treatment of high strength recalcitrant organic wastewater. Y. Deng 189. Short-chain peptide sensors utilizing fluorescence resonance energy transfer for the selective detection of heavy metals. B. R. White, J. A. Holcombe 190. Stimulation and toxicity assessment of short-chain alcohols by a Pseudomonas initial oxygen uptake assay. D-S. Huang, C-W. Tseng, W-T. Su 191. Survival of pathological prion protein during simulated wastewater treatment processes. G. T. Hinckley, C. Bartholomay, J. A. Pedersen, D. I. McKenzie, J. M. Aiken, K. McMahon 192. Synthesis of periodic mesoporous T i 0 2 thin film and powder. Y-K. Park, J. Y. Hur, M. Yu, S. K. Ahn, J. M. Kim, H. I. Lee, S. S. Kim 193. Toxicity study of methoxyethyl methyl imidazolium-based ionic liquids. H. Wang, S. V. Malhotra, A. J. Francis 194. Transformation of sertraline, a selective serotonin reuptake inhibitor, during chlorination of drinking water and wastewater. J-W. Kwon, K. Xia, K. L. Armbrust 195. Use of colloid-enhanced ultrafiltration for the removal of perchlorate from aqueous solutions. D. Tush, J. D. Roach 196. Voltammetric determination of catechol at a sonogel-carbon electrode in the presence of common interferents. A. Yeary, J. Stinson, H. Choi, S. K. Lunsford, D. D. Dionysiou 197. Water quality changes in the Valparaiso Chain of Lakes Watershed. J. K. Schoer, A. Coulter, S. Schmeltz 198. Water remediation of volatile organic compounds. A. B. Helms 199. Accumulation of dibutyltin in human natural killer cells. M. M. Whalen, R. W. Luebke Section Β Hyatt Regency Chicago Riverside Center
203. Transformation of uranium by biogenic Fe(ll) phases resulting from the bioreduc tion of Fe(lll) oxides by Shewanella putre faciens CN32. E. J. O'Loughlin, S. D. Kelly, M. I. Boyanov, Μ. Μ. Scherer, Κ. Μ. Kemner 204. Nanoscale size effects on uranium(VI) adsorption and reduction by iron(ll) on hematite nanoparticles. H. Zeng, S. Basak, P. Biswas, D. E. Giammar 205. Size-dependent reactions between Fe(ll) and goethite. R. M. Handler, D. M. Cwiertny, C. B. Kennedy, C. M. Johnson, M. M. Scherer 206. Oxidation of Fe(ll) by Mn-oxides: Char acterization of Fe(lll) reaction products. M. V. Schaefer, R. M. Handler, D. M. Cwiertny, M. M. Scherer 207. Môssbauer study of Fe(ll) reacted with environmentally relevant surfaces. C. A. Gorski, P. Larese-Casanova, A. G. B. Williams, M. M. Scherer 208. Bioavailability of iron arsenate phases leading to metal release. C. G. Weisener, M. Babechuk, E. Baun 209. Effects of particle aggregation mechanisms on metal uptake to nanoscale goethite. R. Ono, K. Ching, B. Gilbert, C. S. Kim 210. Enhanced adsorption of natural organic matter (NOM) on quaternary ammonium cationic-modified iron oxide-coated sand (IOCS). C. Ding, C. Shang, Y. Chang 211. Adsorption and surface precipitation of uranyl phosphate on goethite. A. Singh, D. E. Giammar 212. Effect of pre-reduction of aquifer material on PCE reductive dehalogenation in a continuous-flow column study. M. F. Azizian, M. E. Dolan, J. D. Ingle, L. Semprini Section C Hyatt Regency Chicago Riverside Center Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Poster Session Cosponsored with CEI, and SUST T. Karanfil, S. W. Krasner, P. K. Westerhoff, and Y. F. Xie, Organizers 6:00-8:00 213. Determining haloacetic acid levels influenced by typical residential water usage patterns. B. Jay, R. Aranda-Rodriguez 214. Automated on-line monitoring of haloacetic acid concentrations using ion chromatography with the nicotinamide post-column reaction. P. Simone Jr., M. A. Brown, G. Geme, L. J. Thurston, G. L Emmert 215. Miniaturized FIA analyzer with LED spectrophotometer for monitoring disinfectants in drinking water based on colorimetric methods. L. J. Thurston, P. Simone Jr., M. A. Brown, G. Geme, G. L. Emmert 216. On-line monitoring of trihalomethane concentrations in drinking water distribution systems using membrane-based on-line purge-and-trap gas chromatography. M. A. Brown, G. Geme, S. Miller, P. Simone Jr., L. J. Thurston, G. L. Emmert
Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Poster Session Cosponsored with GEOC
Section D
D. E. Giammar, M. L. McCormick, and E. J. O'Loughlin, Organizers
Remediation Technologies for Chromium Poster Session
6:00-8:00 200. Influence of temperature on the transfor mation of metals onto/into nanoscale iron oxyhydroxides. B. C. Reinsch, C. J. Lentini, B. Gilbert, C. S. Kim 201. Experimental studies of Fe(lll) mineral reduction by Geobacter. R. S. Cutting, V. S. Coker, P. L Wincott, D. J. Vaughan, J. R. Lloyd 202. Solid-state biotechnology: Nanospinel synthesis from waste materials by Fe(lll)reducing bacteria. V. S. Coker, C. I. Pearce, R. A. D. Pattrick, G. van der Laan, N. D. Telling, J. M. Charnock, E. Arenholz, J. R. Lloyd
J. L. Gardea-Torresdey,
Hyatt Regency Chicago Riverside Center
Organizer
6:00-8:00 217. Chromium-induced oxidative stress in pea chloroplasts. V. Pandey, V. Dixit, R. Shyam Sustainability in Water Supply: Advanced Membrane Technology for Water Reuse Posters Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment
ENVR/FLUO Posters Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Posters Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Drinking Water Disinfection Processes Posters Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Posters Sponsored by SUST, Cosponsored with ENVR Sustainability in Water Supply: Catalytic Control of Emerging Micropollutants Posters Sponsored by SUST, Cosponsored with ENVR
10:30 228. Mechanistic insight for the N-nitrosodimethylamine (NDMA) formation potential of amine-based water treatment polymers. S-H. Park, S. Wei, B. Mizaikoff, A. E. Taylor, M. Aral, C-H. Huang 10:55 229. Potential transformation by product and associated risk of diuron in the disinfection process. W-H. Chen, T. M. Young 11:20 230. Degradation of NDMA in an open reservoir. D. J. Cook, R. Daly, J. Morran, M. Drikas, G. Kilmore 11:45 231. Free radical chemistry of advanced oxidation process removal of nitrosamines from waters. S. P. Mezyk, N. A. Landsmann, K. L. Swancutt, C. N. Bradford, C. R. Cox, J. J. Kiddle, T. J. Clore Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Sponsored by SUST, Cosponsored with ENVR
Sustainability in Water Supply: How Pure is our Drinking Water: Advances in Detection and Quantification of Water Contaminants Posters Sponsored by SUST, Cosponsored with ENVR
Sustainability in Water Supply: Advances in Desalination of Sea and Brackish Water Sponsored by SUST, Cosponsored with ENVR
THURSDAY MORNING
Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Sponsored by SUST, Cosponsored with ENVR
Section A
THURSDAY AFTERNOON
McCormick Place South Room S106B, Level 1
McCormick Place South Room S106B, Level 1
J. Marwan,
New Energy Technology Cosponsored with CEI
Organizer
McCormick Place South RoomS105A, Level 1 Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation, Fate, and Control of Nitrosamines Cosponsored with CEI, and SUST
Organizer
T. Karanfil, S. W. Krasner, and Y. F. Xie, Organizers Presiding
8:30 Introductory Remarks. 8:35 224. Organic nitrogen occurrence and characterization. P. K. Westerhoff 9:00 225. Occurrence and formation of N-nitrosamines as disinfection by-products during water disinfection. Y. Y. Zhao, J. Boyd, M. Woodbeck, R. Andrews, Xing-F. Li 9:25 226. Formation of nitrosamines in effluent-impacted drinking waters. S. W. Krasner, M. J. Sclimenti 9:50 227. Investigation of NDMA formation pathways: Impact of breakpoint chlorination. I. M. Schreiber, W. A. Mitch 10:15 Intermission.
FLUO 1
Section Β McCormick Place South RoomS105A, Level 1
T. Karanfil, S. W . Krasner, and P. K. Westerhoff, Organizers Presiding
1:30 Introductory Remarks. 1:35 237. Formation and distribution of disinfection by-products in drinking water distribution systems. Z. Tang, Y. F. Xie 2:00 238. Formation of DBP variations in Istanbul, Turkey, drinking water. V. Uyak, I. Toroz, O. Ozkan 2:25 239. Biotic and abiotic degradation of halogenated disinfection by-products in distribution systems. R. M. Hozalski 2:50 Intermission. 2:55 240. Impact of point-of-use treatment on disinfection by-product levels in ingested drinking water. H. S. Weinberg, S. Eslinger, P. C. Singer
MONDAY MORNING Section A Holiday Inn City Centre Lasalle Blrm I ACS Award for Creative Work in Fluorine Chemistry: Symposium in Honor of Kenji Uneyama W . Dolbier Jr. and T. Itoh,
Organizers
P. V. Ramachandran and G. K. S. Prakash, Organizers,
Presiding
8:30 8. Gas phase fluorination of aromatics by copper aluminum fluoride. W. Dolbier Jr., K. M. Janmanchi 8:55 9. Control of physical properties of ionic liquids by point-difluorination. T. Itoh, A. Iwai, S-S. Tamura, S. Hayase, M. Kawatsura 9:20 10. New aspects of fluorine-containing insecticides. T. Mori 9:45 11. Fluoroorganic synthesis via boranes. P. V. Ramachandran 10:10 Intermission. 10:30 12. Recent chemistry of compounds containing -SF 5 and -OSF 5 functional groups. R. G. Syvret, G. S. Lai 10:55 13. Practical synthesis of optically active fluorinated amines as intermediates for pharmaceutical compounds. M. Kanai, Y. Katsuhara, A. Ishii 11:20 14. Synthesis and in vivo evaluation of [18F]labeled COX-2 inhibitors. J. S. D. Kumar, J. J. Mann MONDAY AFTERNOON Section A
SUNDAY AFTERNOON Holiday Inn City Centre Lasalle Blrm I
Section A
1:30 232. Pd/D CO-deposition: Excess power generation and its origin. P. A. Mosier-Boss, S. Szpak, F. E. Gordon 1:55 233. Study of the nanostructured palla dium hydride system. J . Marwan 2:20 234. Miniature microbial fuel cells incor porating nanoporous sterilization mem branes. J. C. Biffinger, R. Ray, B. Little, B. R. Ringeisen 2:40 235. Pressure pulsing: A dynamic method for enhancing environmental remediation. T. J. T. Spanos 3:00 236. Withdrawn.
Y. F. Xie, Organizer,
Sustainability in Water Supply: Advances in Oxidation Processes for Water Treatment Sponsored by SUST, Cosponsored with ENVR
S. G. K. Prakash, Program Chair
Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water DBP Issues in Distribution Systems Cosponsored with CEI, and SUST
Section Β
P. K. Westerhoff, Organizer,
J. Marwan,
Sustainability in Water Supply: Advances in Adsorption Processes for Drinking Water Treatment Sponsored by SUST, Cosponsored with ENVR
Division of Fluorine Chemistry
Section A New Energy Technology Low Energy Nuclear Transmutation Cosponsored with CEI
8:30 218. From cold fusion to low energy nuclear reactions: 2007 Update. S. B. Krivit 8:55 219. Experimental observation of reac tor 1 3 7 Cs isotope deactivation and 5 5 Mn isotope transmutation in biological cells. V. Vysotskii, A. Tashirev, A. Kornilova 9:20 220. Precision and accuracy of cold fusion calorimetry. M. H. Miles, M. Fleischmann 9:45 221. Resonance transfer of neutron from deuteron: Mechanism of low energy nucleus reactions in metals. D. D. Afonichev II 10:10 222. On the energetics of deuterium palladium cluster reactions in LENR elec trolytic experiments. G. H. Miley, H. Hora 10:35 223. Quantization of atomic and nuclear rest masses and stimulation mechanisms of low energy nuclear reac tions using super low energy external fields. F. Gareev
3:20 241. Disinfection by-product formation resulting from chlorination of antimicrobial personal care products. P. J. Vikesland, E. M. Fiss, K. Rule, A. Greyshock 3:45 242. Understanding the chemistry that is applied in the detection of DBPs by the capillary membrane sampling-flow injec tion analysis method. G. Geme, M. A. Brown, P. Simone Jr., L. J. Thurston, G. L Emmert 4:10 243. Using capillary membrane sam pling-gas chromatography for on-line monitoring of trihalomethane concentra tions in drinking water distribution systems. M. A. Brown, G. Geme, P. Simone Jr., L. J. Thurston, G. L. Emmert 4:35 244. Unusual interactions in the NOM/ chlorine/Pb0 2 system and their relation ships to control disinfection by-products and lead release. G. V. Korshin, D. Dryer, H. Liu, J. Ferguson
Holiday Inn City Centre Lasalle Blrm I
ACS Award for Creative Work in Fluorine Chemistry: Symposium in Honor of Kenji Uneyama
ACS Award for Creative Work in Fluorine Chemistry: Symposium in Honor of Kenji Uneyama
W. Dolbier Jr., G. K. S. Prakash, and P. V. Ramachandran, Organizers
T. Itoh, G. K. S. Prakash, and P. V. Ramachandran, Organizers W. Dolbier Jr., Organizer,
Presiding
1:30 Introductory Remarks. 1:40 1. The preparation of CF 2 HCdX and CF 2 HZnX via direct insertion of Cd° or Zn° into the carbon halogen bond of CF 2 HY (Y = Br, I). D. J. Burton, G. A. Hartgraves 2:05 2. Pentafluoroethylation: New aspects. G-V. Roeschenthaler 2:30 3. Preparation and characterization of pentafluorosulfanyl containing amino acids and peptides. J. T. Welch, D. S. Lim, S. C. Ngo, S. Higashiya, A. Shekhtman 2:55 4. Adventures with difluoroenols and their derivatives. J. M. Percy 3:20 Intermission. 3:40 5. Fluorine introduction in organic com pounds using a crystallographically char acterized organoindium reagent. G. B. Hammond, B. Xu 4:05 6. Recent studies on fluorinated prosta noids as therapeutic agents. Y. Matsumura 4:30 7. New fluoroalkylation chemistry. G. K. S. Prakash
T. Itoh, Organizer,
Presiding
1:30 15. New fluorinated sulfonates and sulfonimides for lithium batteries and fuel cells. B. R. Langlois, F. Toulgoat, M. Medebielle, J-Y. Sanchez 1:55 16. Synthesis and properties of fluoroalkyl end-capped oligomers/silica nanoparticles. H. Sawada 2:20 17. Stereoselective generation of 2-fluoroalkylidene-type carbenoids and their application for stereoselective synthesis of fluoroalkenes. S. Hara 2:45 18. Intrinsic(gas phase) acidity of 1 H-perfluoroadamantane and some related compounds. T. Sonoda, M. Pasikowska, M. Mishima, T. Ono, H. Fukaya, J-L. M. Abboud 3:10 Intermission. 3:30 19. Introduction to and effects of fluori nated alkyl groups on small peptides. C. Lu, D. D. DesMarteau 3:55 20. Fluorination of phenyl sulfide deriva tives by IF5/Et3N-3HF. K. Adachi, Y. Sakamaki 4:20 2 1 . New approach to fluorinated com pounds via fluoroacetylene derivatives. T. Hanamoto 4:45 22. Niobium-catalyzed C-F bond activa tion and C-C bond formation. T. Akiyama, K. Fuchibe TUESDAY MORNING Section A
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Holiday Inn City Centre Lasalle Blrm I Fluorine and Energy Cosponsored with SUST P. V. Ramachandran,
Presiding
9:00 Introductory Remarks.
TECH-57
TECHNICAL PROGRAM
FLUO/FUEL 9:10 23. Fluoroalkyl sulfonimides as electro lytes for PEM fuel cells and lithium batter ies. D. D. DesMarteau, S. Creager, R. Rajagopal, P. B. Hallac, Ο. Ε. Geiculescu, I. Sharif, A. Rettenbacher, H. Mei 9:40 24. Low crossover membranes for direct oxidation methanol fuel cells. G. K. S. Prakash 10:10 Intermission. 10:30 25. The development of improved lithium-ion battery electrolytes containing fluorinated cosolvents. M. C. Smart, K. Smith, P. Bhalla, J. Hu, G. K. S. Prakash, J. F. Whitacre, R. V. Bugga 11:00 26. The use of nanocomposite CFx cathode materials in Li-CFx batteries for low temperature application. J. F. Whitacre, M. C. Smart, W. C. West, R. V. Bugga, R. Yazami, A. Hamwi, G. K. S. Prakash TUESDAY AFTERNOON Section A Holiday Inn City Centre Lasalle Blrm I Fluorine and Energy Cosponsored with SUST P. V. Ramachandran,
Presiding
1:30 27. Structure and properties of perfluorinated ionomers in PEM fuel cells. T. Berta, W. E. Delaney, C. W. Martin 2:00 28. Preparation of functionalized fluori nated monomers for polymer synthesis. P. V. Ramachandran 2:30 Intermission. 2:50 29. Modification and characterization of Nation® for direct methanol fuel cells (DMFCs) applications. H. Zhu, L Sun, R. E. Fernandez, J. S. Thrasher 3:20 30. Synthesis of fluoro-terpolymers with high dielectric constant and low loss for high energy density capacitors: Using control borane/oxygen radical polymeriza tion. T. C. M. Chung, Z. Zhang
FUEL Division of Fuel Chemistry J. J. Helble, Program Chair
SOCIAL EVENT: Dinner: Tue BUSINESS M E E T I N G S : Business Meeting: Tue Executive Committee Meeting: Sun Program Chairs Meeting: Sun SUNDAY MORNING Section A McCormick Place North Room N426B, Level 4
Chemistry of HAP (PAH) Formation Organizers
8:55 Introductory Remarks. 9:05 5. Formation of polycyclic aromatic hydrocarbons from pyrolysis and combus tion of plant materials. M. R. Hajaligol 9:50 6. Effects of acetylene addition on the formation of polycyclic aromatic hydrocar bons during the pyrolysis of catechol. M. J. Wornat, S. Thomas 10:15 Intermission. 10:30 7. Role of 1,3-butadiene in the forma tion of polycyclic aromatic hydrocarbons during the pyrolysis of catechol. M. J. Wornat, S. Thomas 10:55 8. Using a multi-sample micro-pellet reactor with laser pyrolysis-molecular beam mass spectrometry to detect the reactive intermediates in PAH formation from biomass. A. M. Herring, E-J. Shin, J. T. Mckinnon, M. Carey
Greenhouse Gas Capture and Sequestration Capture Cosponsored with SUST T. P. Filburn and H. W. Pennline, Presiding 8:55 Introductory Remarks. 9:00 1. Reaction kinetics of carbon dioxide with the supported amine tetraethylenepentamine in ethanol. M. J. Schladt, T. Filburn, J. J. Helble 9:25 2. Regeneration and lifetime of polyethylenimine based C 0 2 adsorbents. T. C. Drage, K. Smith, A. Arenillas, C. Snape 9:50 3. Solid sorbents for C 0 2 capture from post-combustion and pre-combustion gas streams. R. V. Siriwardane, C. Robinson, R. W. Stevens Jr.
Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST SUNDAY AFTERNOON Section A McCormick Place North Room N426B, Level 4 Greenhouse Gas Capture and Sequestration Carbon Sequestration Cosponsored with SUST T. P. Filburn and H. W. Pennline, Presiding 1:25 Introductory Remarks. 1:30 9. Influence of a typical host rock on brine pH as applied to carbon sequestra tion. M. A. Hill, Μ. Μ. Maroto-Valer, H. H. Schobert 1:55 10. Thermodynamical studies of adsorption/desorption of C 0 2 on Wyodak coal at different pressures. M. Mirzaeian, P. J. Hall 2:20 11. Toward the development of a single-stage mineral carbonation process. G. W. Alexander, M. M. Maroto-Valer, Η. Η. Schobert 2:45 12. Using electrolysis of NaCI to pro mote C 0 2 sequestration by mineral car bonation. B. Li, W. Li, W. Li Section Β McCormick Place North Room N426C, Level 4 Chemistry of HAP (PAH) Formation E-J. Shin and R. Evans,
MONDAY AFTERNOON Section A McCormick Place North Room N426B, Level 4
Section A
McCormick Place North Room N426C, Level 4
E-J. Shin and R. Evans,
Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST MONDAY MORNING
Section Β
Organizer
G. K. S. Prakash, Organizer,
58-TECH
10:15 4. Templated polymeric materials as adsorbents for the post-combustion cap ture of C 0 2 . T. C. Drage, C. Pevida, C. Snape
Organizers
1:25 Introductory Remarks. 1:30 13. Vapor pressures and enthalpies of sublimation of several polycyclic aromatic compounds as determined via the Knudsen effusion method. J. L. Goldfarb, Ε. Μ. Suuberg 1:55 14. Reversed-phase sample clean up for analysis of benzo[a]pyrene by gas chromatography/mass spectrometry. C. T. Wilkinson, C. A. Chwojdak 2:20 15. Polynuclear aromatic hydrocarbon formation during biomass gasification. E-J. Shin, M. R. Nimlos, R. J. Evans 2:45 16. Direct formation of polynuclear aromatic hydrocarbons during biomass pyrolysis. R. J. Evans, H. M. Pilath, M. R. Nimlos Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR
Carbon Nanoparticles and Nanotubes Formation Mechanisms
McCormick Place North Room N426B, Level 4
H. Richter and M. Kraft, Carbon Nanoparticles and Nanotubes Synthesis and Characterization H. Richter and M. Kraft,
Organizers
8:55 Introductory Remarks. 9:05 17. Review of flame (combustion) synthesis of carbon nanotubes and nanofibers. R. L. Vander Wal, G. M. Berger 9:50 18. Flame synthesis of carbon nano tubes using electric field control. W. E. Merchan-Merchan, A. V. Saveliev, L. A. Kennedy 10:15 Intermission. 10:30 19. Fluorescence characterization of narrowly diameter distributed Co-MCM-41 single-walled carbon nanotubes. Z. Luo, F. Papadimitrakopoulos, L. Pfefferle, G. L Haller 10:55 20. Characterization of single-walled carbon nanotubes produced by a scalable combustion process. M. Treska, S. B. Thomasson, A. H. Reading, H. Richter, J. B. Vander Sande 11:20 2 1 . Reconstructing the near infrared absorption spectra of single-walled carbon nanotubes. Z. Luo, F. Papadimitrakopoulos
Organizers
1:25 Introductory Remarks. 1:30 28. Prospect of detailed size distribution and composition measurements for nanoparticles formed in highly reacting flows. H. Wang 2:10 29. Two variable representations of soot particles. R. I. A. Patterson, M. Kraft 2:35 Intermission. 2:45 30. Carbon nanotube nucleation and growth in gas phase. A. M. Moisala, A. G. Nasibulin, E. I. Kauppinen, M. Motta, A. H. Windle 3:25 31. Modeling gas-phase carbon nanotube synthesis on iron particles from carbon monoxide. M. S. Celnik, R. H. West, N. M. Morgan, M. Kraft, A. M. Moisala, W. H. Green Jr., H. Richter, J. Z. Wen 3:50 32. Structure of carbon nanotube forming premixed methane/oxygen/argon low pressure flames. J . Z. Wen, H. Richter, W. H. Green Jr., J. B. Howard, M. Treska, P. M. Jardim, J. B. Vander Sande Section Β McCormick Place North Room N426C, Level 4
Section Β
Clean Coal Cosponsored with SUST
McCormick Place North Room N426C, Level 4
T. H. Fletcher, M. A. Wojtowicz, H. Moritomi, and Y. Ohtsuka, Organizers
Optical Diagnostics in Reacting Fuel Systems
1:25 Introductory Remarks. 1:30 33. Chlorine functional forms of Argonne Premium coal samples and their changes with water washing and in slow heating rate pyrolysis. Y. Ohtsuka, N. Tsubouchi, T. Saito, N. Suzuki, M. Sato 1:55 34. Transformation of inorganic ele ments into coal extracts (HyperCoals). L. Zhang 2:20 35. Experimental and modeling of chromium speciation in Australian coals and combustion products. P. Shah, V. Strezov, P. F. Nelson 2:45 36. Partitioning behavior of boron in a coal fired power plant. S. Kambara, H. Moritomi 3:10 Intermission. 3:25 37. Fractionation of Brown Coal by sequential solvent extraction. K. Miura, R. Ashida, Y. Makino Jr., M. Oga, M. Morimoto, H. Nakagawa 3:50 38. Upgrading of peat to gas/liquid fuels in supercritical water with catalysts. C. Xu, J. Donald 4:15 39. Determination of 13 kinds of alde hyde and ketone pollutants in emission from biodiesel engine by HPLC with SPD. F. Guoliang II, Z. Ruifen
T. Parker and R. A. Walker,
Organizers
8:25 Introductory Remarks. 8:30 22. Imaging radical species in reacting flows using picosecond two-photon laserinduced fluorescence spectroscopy. T. B. Settersten 9:10 23. Rare-earth-doped fiber lasers for spectroscopic trace-gas detection. D. A. V. Kliner, J. P. Koplow, R. L. Farrow, P. E. S. Schrader, S. W. Moore, T. A. Reichardt, A. A. Hoops, T. J. Kulp, K. M. Armstrong, R. L. Sommers, L. Goldberg, J-P. Fève 9:50 24. Anomalies in picosecond laserinduced incandescence of soot. H. A. Michelsen 10:15 Intermission. 10:30 25. Probing and mapping SOFC anode reactions using in situ raman spectroscopy. H. Abernathy, Z. Cheng, X. Lou, M.Liu 11:10 26. Single-shot raman measurements in diesel spray systems as a tool to differentiate two-stage ignition from single stage ignition. C. Dreyer, J. Labs, T. Parker 11:50 27. Potential dependence of carbon growth with small hydrocarbon fuels in solid oxide fuel cells. M. B. Pomfret, R. A. Walker Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR
Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Developing Issues in Energy and Fuels Cosponsored with SUST
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
J. J . Helble,
Presiding
8:00-10:00 4-5, 8 , 1 3 , 1 9 , 3 1 , 33. See previous listings. 43, 60, 7 1 , 74, 79, 89. See subsequent listings.
FUEL TUESDAY MORNING Section A McCormick Place North Room N426B, Level 4 Carbon Nanoparticles and Nanotubes From Synthesis to Applications H. Richter and M. Kraft,
Organizers
9:00 Introductory Remarks. 9:05 40. Carbon nanotubes: From synthesis to biomaterial applications. I. A. Kinloch, D. Eder, K. Prehn, K. Schulte, M. Motta, A. Moisala, Y-L. Li, S. Zhang, S. Roberts, J. Geng, B. Johnson, C. Singh, M. Shaffer, A. White, O. Emohare, R. Brooks, S. Best, D. Walter, G. Walker, C. Scotchford, D. Brown, V. Stone, A. H. Windle 9:50 4 1 . Flame synthesis of tungsten-oxide carbon nanowires. W. E. Merchan-Merchan, A. M. Taylor, A. V. Saveliev 10:15 Intermission. 10:30 42. Comparison of carbon surface modification chemistries for nanoparticle based cell delivery. A. Yan, B. Lau, A. B. Kane 10:55 43. Properties of aggregates of anionic-cationic porphyrins: TCPP and TPPS with TAP. M. T. Oztek, M. Hampton, D. K. Slattery, S. Loucks 11:20 44. Carbon nanoparticles as a vehicle for cell delivery of nano selenium. L. Sarin, A. Yan, V. Sanchez, A. Kane, R. H. Hurt Section Β McCormick Place North Room N426C, Level 4
2:40 Intermission. 2:55 52. Application of lithium nanotube salts in organic syntheses: Water-soluble PEGylated single walled carbon nano tubes. J. Chattopadhyay, F. de Jesus Cortez, S. Chakraborty, N. K. H. Slater, W. E. Billups 3:20 53. Covalent functionalization of single walled carbon nanotubes and fullerenes via a Zwitterion approach. W. Zhang, T. M. Swager Section Β McCormick Place North Room N426C, Level 4 Storch Award Symposium R. Pugmire,
Presiding
1:25 Introductory Remarks. 1:30 54. Characterization of nitrogen and sulfur forms in kerogen by X-ray methods. S. R. Kelemen, M. Sansone, P. J. Kwiatek, M. L. Gorbaty 2:00 55. High temperature high pressure 0 2 reactivities of coal char. T. H. Fletcher, D. Zheng 2:30 56. Aromaticity in polycyclic aromatic hydrocarbons: Clar structures revealed by magnetic susceptibility and nuclear shield ing. D. M. Grant, M. D. Hailing 3:00 Intermission. 3:15 57. In situ pressure studies of coal and oil shale by small angle and high energy, wide angle X-ray scattering. R. E. Winans, P. J. Chupas, K. W. Chapman, A. H. Clemens, R. J. Pugmire, S. Seifert 3:45 58. 13C NMR Spectroscopy: A key contributor for development of the molecu lar structure of coal and other kerogens. R. Pugmire, M. S. Solum
Clean Coal Cosponsored with SUST T. H. Fletcher, M. A. Wojtowicz, H. Moritomi, and Y. Ohtsuka, Organizers 9:00 45. Numerical simulation of the best mixture ratio of the secondary air in air staging combustion. X. Du, M-Y. Hu, L-L. Zhang, X-J. Sun 9:25 46. Numerical simulation of the best mixture ratio of the coal and air in fuel staging combustion. L-L. Zhang, M-Y. Hu, X. Du, D-D. Li 9:50 47. Effects of inherent metal cations on the fate of the nitrogen in coal in the fixed bed pyrolysis of twenty five coals. Y. Ohtsuka, N. Tsubouchi, Z. Wu 10:15 Intermission. 10:30 48. Desulfurization mechanism of barium-based additives at high tempera ture during high-sulfur coal combustion. H. Liu, J . Qiu, B. Cheng, F. Kong, H. Zeng 10:55 49. Removal of organic sulfur from hydrocarbon resources. Y. Mochizuki, K. Sugawara Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST Sustainable Resources: Science and Information Sources Sponsored by CINF, Cosponsored with AGRO, FUEL, and SUST TUESDAY AFTERNOON Section A McCormick Place North Room N426B, Level 4 Carbon Nanoparticles and Nanotubes Chemistry of Carbon Nanotubes and Fullerenes H. Richter and M. Kraft,
Organizers
1:30 50. Chemistry of single walled carbon nanotubes: Applications to biomolecule detection, nanotube separation, and elec tronic networks. M. S. Strano 2:15 51. Polyacylation of single- and multiwall carbon nanotubes under FriedelCrafts conditions. T. S. Balaban, M. C. Balaban, S. Malik, F. Hennrich, R. Fischer, M. M. Kappes
Agricultural Biomass, Biobased Products, and Biofuels Defining the Challenges Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
1:30 77. Effect of biodiesel composition on the formation of particulate matter exhaust emissions and comparison to petrodiesel components. G. Knothe, C. A. Sharp, T. W. Ryan
Section Β McCormick Place North Room N426C, Level 4 Clean Coal Cosponsored with SUST T. H. Fletcher, M. A. Wojtowicz, H. Moritomi, and Y. Ohtsuka, Organizers 9:00 64. Development and validation of a method for prediction of the ash split in a CFB boiler using fuel and sorbent proper ties to improve the energy efficiency. N. Soundarrajan, P. L. Rozelle, S. V. Pisupati 9:25 65. Whole-of-life costing of technology options for lignite enhancement for power generation. B. Young, G. Whitfield 9:50 66. Mercury removal from coal-combus tion flue gas using activated carbon derived from waste tires. M. A. Wojtowicz, E. Florczak, E. Kroo, T. Kroo, M. A. Serio, K. Dombrowski 10:15 Intermission. 10:40 67. Investigation of mercury distribu tion behavior in ash-free coal manufactur ing process. R. Yoshiie, H. Watanabe, S. Uemiya, A. Furuya, N. Okuyama, N. Komatsu 11:05 68. Simultaneous H2 purification and C 0 2 capture in a post-gasifier membrane reactor. B. M. Morreale, B. Howard, R. P. Killmeyer, C. Taylor, O. lyoha, M. V. Ciocco 11:30 69. Control of catalytic hydrogen combustion by fluidized bed. T. Osakabe, H. Moritomi Agricultural Biomass, Biobased Products, and Biofuels Process and Product Control Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST WEDNESDAY AFTERNOON
Catalysis Relevant to Energy and Sustainability Sponsored by INOR, Cosponsored with FUEL, and SUST WEDNESDAY MORNING Section A
McCormick Place North Room N426B, Level 4 Environmental Issues in Energy and Fuels Cosponsored with SUST
McCormick Place North Room N426B, Level 4 Pollutant Formation from Mobile Sources B. A. Holmen,
Section A
Organizer
8:55 Introductory Remarks. 9:00 59. Characteristics of driving and onroad emissions of light-duty gasoline vehicles in Chinese cities. K. He, Z. Yao, H. Huo, Q. Wang, Y. Ma, Q. Zhang 9:25 60. Pollutant formation in premixed and diffusion flames of paraffinic fuels using the reduced Utah Surrogate Mechanisms. H. R. Zhang, Z. Yang, E. G. Eddings, A. F. Sarofim 9:50 61. Tracking personal exposure to diesel exhaust in a diesel freight terminal using organic tracer analysis by thermal desorption GCMS. R. J. Sheesley, J. J. Schauer, T. J. Smith, E. Garshick, F. Laden, D. Blicharz, J. DeMinter 10:15 Intermission. 10:40 62. Diesel advancement of the U.S. auto industry in tandem with global warm ing reduction. M. S. 0 Conaire 11:05 63. Ultralow sulfur fuel and ultrafine particle number emissions fromdiesel transit buses: Evaluating fuel composition as an emissions control measure. B. A. Holmén 11:30 Concluding Remarks.
J. J. Helble,
Organizer
1:25 Introductory Remarks. 1:30 70. Effect of loss on ignition and particle size on the concentration of trace ele ments in fly ash. J. A. Vervynckt, B. Casenas, J. Cheng, B. Chen, W. P. Pan 1:55 7 1 . Effects of flue gas constituents on mercury adsorption by activated carbon fiber(Acf). J. Qiu, H. Wu, X. Wang, H. Zeng 2:20 72. Mercury behavior in FGD sulfite-rich scrubber materials at elevated tempera tures and pressures. G. Markevicius, R. D. West, V. M. Malhotra, F. Botha, C. E. Miller 2:45 73. The effect of selenite and selenate on Hg capture on carbon. E. S. Olson 3:10 Intermission. 3:25 74. Using glycerol as fuel in biofuel cells. R. L. Arechederra, S. D. Minteer 3:50 75. Investigation of reaction networks and active sites in bioethanol steam reforming over Co-based catalysts. H. Song, L Zhang, U. S. Ozkan 4:15 76. Steam reforming of glycerin for hydrogen production over Ni catalyst. S. Adhikari, S. Fernando, A. Haryanto
1:55 78. Nanoparticle emission from biomass burning? L-W. A. Chen, R. K. Chakrabarty, H. Moosmuller, W. P. Arnott, J. C. Chow, J. G. Watson 2:20 79. Heavy metal formation in munition waste incinerators and nanostructured sorbents for their control. X. Chen, P. Biswas, S-K. Jeong, M. Lee, S-B. Kim, A. Suriyawong, K. Higginson, A. Shah 2:45 80. Nature and causes of visible light absorption by primary organic aerosol from solid fuel combustion. T. Bond, A. M. Kanu, Y. Chen, H. Sun 3:10 Intermission. 3:25 8 1 . Properties of inorganic PM emitted from incineration of sewage sludge: Speciation in individual elements and their water solubility. L. Zhang 3:50 82. Particulate matter, mercury and trace metals emissions in oxy-coal com bustion. J. Qiu, H. Liu, C. Wen, H. Zeng, H.Wu 4:15 83. Studies on formation pathways of inhalable particulate matter during pulver ized coal combustion. J. Y. Lu, D. K. Li Agricultural Biomass, Biobased Products, and Biofuels Process Characterization Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF THURSDAY MORNING Section A McCormick Place North Room N426B, Level 4 Environmental Issues in Energy and Fuels Cosponsored with SUST J. J. Helble,
Organizer
8:55 Introductory Remarks. 9:00 84. MTBE contamination of gasoline in the midwest II: Effects of legislation in Indiana. R. D. Barreto 9:25 85. Completion of ultrasound assisted oxidative desulfurization process through catalyst polishing or ionic liquid extraction. S-S. Chen, T. F. Yen 9:50 86. Oxidative desulfurization of diesel fractions in a fixed bed reactor under mild condiditons. A. Wang, X. Han, X. Wang, J. Zhang, C. Chen, G. Qi, X. Li, Y. Chen, Y. Hu 10:15 Intermission. 10:30 87. Effect of Na2C03 additives on direct sulfation of limestone under high C 0 2 concentration in 0 2 / C 0 2 coal com bustion. C. Chuanmin, Z. Yi, W. Lidong 10:55 88. Kinetics of the semi-dry desulfu rization reaction with calcium hydroxide reagent. W. Lidong, Z. Yi 11:20 89. Experimental study on flue gas desulfurization and denitrification simulta neously by calcium peroxide. Z. Yi Section Β McCormick Place North Room N426C, Level 4 Environmental Challenges of Fuel Utilization in the Developing World Cosponsored with SUST R. E. Hall,
Organizer
8:55 Introductory Remarks.
Section Β McCormick Place North Room N426C, Level 4 PM Formation in Fuel Combustion S. H. Ehrman and C-Y. W u , 1:25
Organizers
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Introductory Remarks.
Tcru
co
TECHNICAL PROGRAM
FUEL/GEOC 9:05 90. Environmental challenges of energy utilization in China. M. Ni 9:50 9 1 . Mercury control technology: A summary. R. E. Hall, C. W. Lee, R. K. Srivastava, N. Hutson 10:15 Intermission. 10:30 92. Study on the simultaneous flue gas desulfurization and denitrification over activated carbon using microwave irradiation. M. Shuangchen, Z. Yi, M. Xiaoying 10:55 93. Plasma-enhanced preparation of nickel-based catalyst for carbon dioxide methanation. W. Chu, F. Guo, S. Z. Luo 11:20 94. Immobilization of lipase and its application in biodiesel production. N-W. Li, H. Wu, W-Y. Lou, M-H. Zong 11:45 95. Thermodynamics characteristics of C 0 2 reforming via corona plasma reaction. M-W. Li, M-W. Li, J-O. Chae, S-L. Kim, C-M. Lee, E-J. Kim
Environmental Challenges of Fuel Utilization in the Developing World (see FUEL, Thu) Environmental Issues in Energy and Fuels (see FUEL, Wed, Thu)
Nuclear Waste Forms: Current Solutions and Future Challenges (see NUCL, Mon)
Complementary Techniques for Resolving the Structure of Environmentally-Significant Poorly Crystalline and Polycrystalline Materials
Chemistry of Sulfur and Desulfurization (see PETR, Sun, Mon) SOCIAL EVENT: Reception: Tue BUSINESS MEETINGS: Division Business Meeting: Tue Executive Meeting: Sun
THURSDAY AFTERNOON
Section A
Section A
McCormick Place North Room N427A, Level 4
J. J. Helble,
Organizer
1:30 96. Studies on emission features of inhalable particulate matter at different conditions during pulverized coal combustion. J. Y. Lu, D. K. Li 1:55 97. Experimental study on removal of dioxin-like chemicals by "oxygen-enriched" highly reactive absorbent. Z. Yi 2:20 98. Pervaporation and its applications in dehydration of hydrazine fuels. Z. Li, X. Wang, Y. Zhang Agricultural Biomass, Biobased Products, and Biofuels The Cellulosic Challenge Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
GEOC Division of Geochemistry M. A. A. Schoonen, Program Chair
O T H E R S Y M P O S I A O F INTEREST: Estimation of Environmental Exposure to Agrochemicals Using Spatial Data Analysis and Geographic Information Systems (see AGRO, Tue, Wed, Thu) Pesticide Runoff/Leaching Mitigation by Riparian Buffers: Application of the REMM (see AGRO, Thu)
Complementary Techniques for Resolving the Structure of Environmentally-Significant Poorly Crystalline and Polycrystalline Materials F. M. Michel, L G. Benning, and S. M. Antao, Organizers 8:15 Introductory Remarks. 8:30 1. Strengths and weaknesses of structure probes for poorly crystalline and nanocrystalline minerals. G. Waychunas, B. Gilbert, C. S. Kim 9:05 2. First steps in the formation of silica nanoparticles. D. Tobler, L. G. Benning, S. Shaw 9:30 3. STXM, NEXAFS, and HRTEM characterization of FeS nanoparticles formed by the metabolic activity of two different sulfate-reducing bacteria. L. MacLean, S. Wirick, C. Jacobsen, B. D. Ravel, G. Southam 9:55 4. Pair distribution function studies of geologically relevant materials for application in the hydrogen economy. P. J. Chupas, K. W. Chapman, R. E. Winans 10:20 Intermission. 10:35 5. Qualitative assessment of organic macromolecules in soil. D. C. Edwards 11:00 6. Aging and transformation of chromium hydroxide phases: Structural investigations and environmental implications. J. Frommer, M. Nachtegaal, R. Kretzschmar 11:25 7. Structural relaxation in the MnC03CaC03 solid solutions using diffuse scattering. S. M. Antao, R. J. Reeder 11:50 8. Raman spectroscopic studies of manganese oxides: Structure and reactivity. O. F. Oyerinde, G. Balakrishnan, T. G. Spiro Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces
Environmental Transport, Fate, Effects and Models of Atmospheric Pollutants (see ENVR, Mon) Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water (see ENVR, Tue, Wed, Thu) Remediation Technologies for Chromium (see ENVR, Wed) Chemistry of HAP (PAH) Formation (see FUEL, Sun) Clean Coal (see FUEL, Mon, Tue, Wed)
60-TECH
Section A McCormick Place North Room N427A, Level 4
SUNDAY MORNING
Environmental Issues in Energy and Fuels Cosponsored with SUST
SUNDAY AFTERNOON
Greenhouse Gas Capture and Sequestration (see FUEL, Sun)
Agricultural Biomass, Biobased Products, and Biofuels Improving Bioproduct Design Sponsored by AGRO, Cosponsored with FUEL, SUST, CELL, and CINF
McCormick Place North Room N426B, Level 4
Organics and Nanoparticle Reactivity Sponsored by ENVR, Cosponsored with GEOC
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
F. M. Michel, L. G. Benning, P. J. Chupas, and S. M. Antao, Organizers 1:30 9. Chemical, physical, and structural properties of iron oxide nanoparticles. R. L. Penn, S. Banerjee, T. S. Berquo, J . J . Erbs, T. L. Jentzsch, K. Tanaka 2:05 10. Structural changes in oxide nanoparticles associated with surface reduction. B. Gilbert, G. A. Waychunas, J-Y. Chane-Ching 2:30 1 1 . An easier method for evaluating the valence state of Fe oxides from Fe-K XANES. M. A. Marcus 2:55 12. Morphological characterization of environmental oxide nanoparticles on mineral surfaces using grazing incidence small angle X-ray scattering. Y-S. Jun, G. A. Waychunas, M. F. Toney 3:20 Intermission. 3:35 13. Asymptotically approaching the truth: A new single-phase structure model for ferrihydrite. F. M. Michel, L. Ehm, S. M. Antao, P. J. Chupas, J. B. Parise 4:00 14. Investigating the properties of nanoparticles of iron phosphate. X. Châtellier, M. Abdelmoula, K. M. Kemner, G. G. Leppard, C. Mustin, B. D. Ravel, M. Reid 4:25 15. Structural and chemical investigation of clay minerals and poorly crystalline Fe-oxides from a coastal plain aquifer using high-resolution TEM and associated techniques. H. Xu, T. Wu, E. E. Roden 4:50 16. Prediction of the surface properties of poorly crystalline oxyhydroxides at the solid-electrolyte-water interface. D. A. Sverjensky, K. Fukushi Section Β Hyatt Regency Chicago Riverside Center General Posters M. A. A. Schoonen,
Organizer
12:00-2:00 17. Occurrence and distribution of mercury in Mammoth Cave National Park. L. Clark, C. Webb 18. Photochemical production of micromolar superoxide standards in aqueous solution. T-C. Ong, D. W. King 19. Adsorption of domoic acid to sediment surfaces. J. M. Burns, J. L. Ferry 20. Development of singlet oxygen quantita tion methods by flow injection analysis with chemiluminescent detection. E. Bast, B. L. Edhlund, M. Grandbois, K. McNeill, D. W. King 2 1 . DNA profiling of microbial communities as a geochemical tool. M. Ashby, K. Nelson, E. Mongodin, T. Lorenson, D. Dimster-Denk 22. Elucidating the emission of chemical compounds from terrestrial fungal-fungal interactions through chromatographic techniques. A. P. Chin, G. Arbuckle-Keil, J. Dighton, C. Rodriguez-Saona 23. Environmental pollutants derived from plastics. K. Amamiya, T. Itagaki, Y. Kodera, S-Y. Chung, O. Abe, N. Ogawa, K. Miyashita, K. Saido 24. Fungal uptake of C60 fullerenes. K. M. Schreiner, T. R. Filley, R. Blanchette 25. Withdrawn. 26. Identification of polycyclic aromatic hydro carbons (PAHs) in the sediment samples collected from the Rouge River, Michigan. Y. Deng, K. Douglas, J. E. Tarrant, L Kappler, A. Ekstrom, K. Murray
27. Identification of stable organic phospho rous compounds in Florida Everglades sediments using 31Ρ NMR spectroscopy and high resolution mass spectrometry. H. M. El-Rifai, M. S. Heerboth, S. Newman, W. T. Cooper 28. Ion dynamics at the quartz-water and clay-water interfaces. G. M. Bowers, R. J. Kirkpatrick 29. Mercury mobilization in estuarine sedi ment porewaters: A diffusive gel timeseries study. K. A. Merritt, A. Amirbahman 30. Metastability of nanosized MCM-41 in hydrogeochemical systems. C. P. Guthrie, E. J. Reardon 31. Seasonal change of geochemistry in the metal mine drainage in the Okdong Mine, South Korea. J . J . Kim, G. C. Jeong, Y. H. Kim, Y. D. Jang, W. T. Lim, U. J. Lee, H. H. Kwon, H. Kang, S. M. Park 32. Soil pH and nutrient changes after pre scribed burning of a grassland restoration on the Mid-Atlantic Coastal Plain. L. A. Sherman, K. R. Brye 33. Stable isotopes as indicators of contami nant reduction by wetland sediments: Effective fractionation factors and the role of diffusion. S. K. Clark, T. M. Johnson 34. Testing multiparametric models of Fe(ll) oxidation by comparison with natural waters. P. S. Craig, T. J. Shaw, J. L. Ferry 35. Reactions of singlet oxygen with dissolved organic matter. R. M. Cory, K. McNeill Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Organics and Nanoparticle Reactivity Sponsored by ENVR, Cosponsored with GEOC MONDAY MORNING
McCormick Place North Room N427A, Level 4 Formation and Fate of Reactive Oxygen Species in Aquatic Environments M. A. A. Schoonen, K. McNeill, and W . J. Cooper, Organizers 8:15 Introductory Remarks. 8:30 36. Reactive oxygen species generation on photolysis of natural organic matter. S. Garg, A. L. Rose, T. D. Waite 9:00 37. Depth dependence on the produc tion of singlet oxygen in natural waters. B. L. Edhlund, K. McNeill 9:20 38. Electron pirates of the Caribbean: Sources, sinks and steady-state concen trations of superoxide in the ocean. A. L Rose, T. D. Waite, J. W. Moffett 9:40 39. CDOM-sensitized singlet oxygen production: Correlation with CDOM excita tion-emission spectral components. J. D. Thoemke, R. M. Cory, K. McNeill 10:00 40. Ibuprofen direct photolysis and in the presence of Pony Lake, Antarctica, fulvic acid and Old Woman Creek Natural Estuarine Research Reserve water. L. E. Jacobs, L. Weavers, Y-P. Chin 10:20 Intermission. 10:35 4 1 . Modeling long term trends in hydrogen peroxide concentration in rela tion to solar radiation in the Water of Leith, Dunedin, New Zealand. S. A. Rusak, L. E. Richard, B. M. Peake, W. J. Cooper, G. E. Bodeker 10:55 42. Simultaneous photochemical production of superoxide and hydrogen peroxide in natural waters. D. W. King, T-C. Ong, A. C. Fulreader 11:15 43. Sulfate radical: Kinetics and prod ucts of organic contaminant oxidation. P. G. Tratnyek, R. H. Waldemer 11:35 44. Formation of hydrogen peroxide in Ojo Caliente, Yellowstone National Park. M. A. Schoonen, M. Borda, B. mathon Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Green Rusts and Uranium Complexation/ Reduction Sponsored by ENVR, Cosponsored with GEOC
GEOC/HIST MONDAY AFTERNOON Section A McCormick Place North Room N427A, Level 4 Formation and Fate of Reactive Oxygen Species in Aquatic Environments M. A. A. Schoonen, K. McNeill, and W. J . Cooper, Organizers 1:00 45. Multiparametric designs for ranking the impact of cosolutes on Fe(ll) oxidation. P. S. Craig, T. J. Shaw, J. L. Ferry 1:30 46. Iron-cyclodextrin complexes for targeted Fenton oxidation. M. A. Tarr, C. W. Jarand, D-T. Pham, S. F. Lincoln 1:50 47. Photo-Fenton reaction at neutral pH in a fulvic acid solution. A. Vermilyea, B. Voelker 2:10 48. Development of a fluorescent probe for peroxyl radical detection in environmental and biological systems. M. Jia, Y. Tang, S. A. Green, N. V. Blough 2:30 49. Measurement and implications of extracellular generation of superoxide by marine phytoplankton. S. Garg, A. L. Rose, A. Godrant, T. D. Waite 2:50 50. Association with natural organic matter enhances the sunlight-mediated inactivation of MS2 coliphage by singlet oxygen. T. Kohn, M. Grandbois, K. McNeill, K. L. Nelson 3:10 Intermission. 3:25 5 1 . Predicting the public health impact of oxidative toxins using a bacterial glutathione-gated potassium efflux stress response biosensor. K. Ikuma, B. A. Rzigalinski, N. G. Love 3:45 52. Photodegradation of antibiotics used in aquaculture. J. Guerard, Y. P. Chin 4:05 53. Formation of reactive oxygen species in human lung cells exposed to earth materials. S. N. Hylton, M. Schoonen, S. R. Simon, C. A. Cohn, E. Roemer 4:25 54. Pyrite-induced oxidation of adenine through hydroxyl radical formation. S. C. Fisher, B. J. Brownawell, C. A. Cohn, M. A. Schoonen 4:45 55. Hydroxyl radical production by reaction of zero-valent iron nanoparticles with oxygen: Mass balances and yields. C. R. Keenan, C. Duesterberg, T. D. Waite, D. L. Sedlak Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces Biotic Processes, Uranium, Arsenic Sponsored by ENVR, Cosponsored with GEOC M O N D A Y EVENING
9:20 58. Calorimetric measurement of adsorption on bacterial surfaces. M. P. Jensen, D. Gorman-Lewis, J. B. Fein 9:40 59. Spectroscopic parameters and thermodynamics of U and Cd bonding to extracellular bacterial polymers via computational chemistry. J. D. Kubicki, X. Châtellier, P. Selvarengan 10:00 Intermission. 10:20 60. Metal binding mechanism on bacterial cell walls: Using Cd as a model. B. Mishra, J. B. Fein, M. I. Boyanov, S. D. Kelly, K. M. Kemner, B. A. Bunker 10:40 61. Experimental measurement of monovalent cation adsorption onto Bacillus subtilis cells. D. S. Alessi, J. B. Fein 11:00 62. Important selected questions related to metal complexation onto bacterial cells. X. Châtellier, R. Martinez, D. Fortin 11:20 63. A combined titration, structure and metal reactivity study to evaluate Cd and Zn location in bacterial cells and model biopolymers. V. Guiné, L. Spadini, B. Causse, J. Gury, G. Sarret, C. Delolme, A. Heyraud, R. Geremia, J. M. F. Martins 11:40 64. XAFS of U(VI)-Fe(ll) sorption to carboxyl surfaces as a model for redox interactions at the cell wall. M. I. Boyanov, E. J. O'Loughlin, E. E. Roden, S. D. Kelly, B. D. Ravel, J. B. Fein, Κ. Μ. Kemner
McCormick Place North Room N427A, Level 4 Geochemistry Medal Award Symposium G. W. Luther III,
Organizer
1:30 Introductory Remarks. 1:45 65. Application of the bedrock to burial model to the interpretation of organic geochemical stratigraphies on river-domi nated margins. N. E. Blair, E. L. Leithold, C. E. Thompson, R. C. Aller 2:30 66. Dynamic, high-resolution imaging of solute distributions in marine sediments. S. Hulth 3:15 Intermission. 3:30 67. Modelling microbial diagenesis. B. P. Boudreau 4:15 68. Influence of unsteady diagenetic processes on the sulfur cycle in tropical deltaic muds: Implications for biogeochemical cycling and the sedimentary record. R. C. Aller, V. M. Madrid, A. Y. Chistoserdov, J. Y. Aller
Sci-Mix Presiding
TUESDAY MORNING
Section A McCormick Place North Room N427A, Level 4 Mechanisms of Metal Binding onto Microbial Cell Walls J. B. Fein, R. T. Cygan, and K. Kemner, Organizers 8:30 56. Recent advances in understanding metal adsorption onto bacterial cell walls. J. B. Fein, K. M. Kemner, R. T. Cygan 9:00 57. Mechanisms of uranium association with microorganisms and in the presence of clay. T. Ohnuki, T. Ozaki, T. Yoshida, T. Nankawa, N. Kozai, F. Sakamoto, Y. Suzuki, A. J. Francis
WEDNESDAY AFTERNOON
THURSDAY MORNING Chemical Evolution, Chemical Change Across Space and Time Teaching Chemical Evolution Sponsored by CHED, Cosponsored with GEOC, and NUCL Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Sponsored by NUCL, Cosponsored with GEOC THURSDAY AFTERNOON Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Sponsored by NUCL, Cosponsored with GEOC
HIST Division of The History of Chemistry J. S. Jeffers, Program Chair
Section A
WEDNESDAY MORNING
M. A. A. Schoonen,
Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Sponsored by NUCL, Cosponsored with GEOC
Section A
Hyatt Regency Chicago Riverside Center
8:00-10:00 2, 4,13, 15, 39-40, 48, 55. See previous listings.
Chemical Evolution, Chemical Change Across Space and Time Geochemical Evolution of the Solar System and Earth Sponsored by CHED, Cosponsored with GEOC, and NUCL
Poster Session Sponsored by ENVR, Cosponsored with GEOC
TUESDAY AFTERNOON
Chemical Evolution, Chemical Change Across Space and Time Chemical Evolution in Astrophysics Sponsored by CHED, Cosponsored with GEOC, and NUCL
Section A
10:40 74. Interactions of Mn 2 + and V 4 + with the surface of Shewanella putrefaciens CN32: Impacts on membrane structure. S. French, S. Fakra, S. Glasauer 11:00 75. Hexavalent chromium at amino acid-functionalized aqueous/solid interfaces studied by resonantly enhanced second harmonic generation. J. M. Gibbs-Davis, P. L. Hayes, K. A. Scheldt, F. M. Geiger 11:20 76. Identification and isolation of gene clusters involved in iron acquisition by Pseudomonas mendocina ymp. J. D. Awaya, J. L. DuBois 11:40 77. Biotoxicity of zinc oxide nanoparticles on model bacteria, Escherichia coli. V. Siron, R. Iliou-Ferrari, R. Brayner, N. Menguy, F. Fiévet, M. F. Benedetti
Section A McCormick Place North Room N427A, Level 4 Mechanisms of Metal Binding onto Microbial Cell Walls J. B. Fein, R. T. Cygan, and K. Kemner, Organizers
McCormick Place North Room N427A, Level 4 ACS Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences: Symposium in Honor of Robyn E. Hannigan Cosponsored with WCC C. Dowling,
Organizer
1:30 Introductory Remarks. 1:40 78. How do you do that with undergrade? A DIY guide to developing a successful undergraduate research program. S. Lev 2:05 79. RISE REU: Increasing diversity in environmental sciences. C. Dowling 2:30 80. Linking a diverse community of undergraduate students to environmental research. B. Cuker 2:55 Intermission. 3:20 8 1 . Chemistry of ancient paints used in rock art found in the Lower Pecos River region, SW Texas. J. Russ 3:45 82. Award Address (ACS Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences, sponsored by The Camille and Henry Dreyfus Foundation, Inc). Mentor: Someone whose hindsight can become your foresight. R. Hannigan Chemical Evolution, Chemical Change Across Space and Time Prebiotic Chemistry Sponsored by CHED, Cosponsored with GEOC, and NUCL Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Sponsored by NUCL, Cosponsored with GEOC W E D N E S D A Y EVENING
8:30 69. Metal interactions with bacterial surfaces. T. J. Beveridge 9:00 70. Cd and Zn binding onto bacterial cell walls and its implication for acceler ated transport in porous media. V. Guiné, J. M. F. Martins, L. Spadini, J-P. Gaudet 9:20 7 1 . Effects of extracellular polymeric substances on potentiometric titrations of bacteria. B. Ginn, J. B. Fein 9:40 72. Multiligand model systems for Cm(lll)/Eu(lll) binding on microbial surfaces. M. G. Calvert, H. Nitsche, A. Hui 10:00 Intermission. 10:20 73. Mn(ll) sorption by live and dead cells of Shewanella putrefaciens. N. Chubar, T. Behrends, P. Van Cappellen
Abiotic and Biotic Factors Affecting Contaminant Transformation at Iron Oxide Surfaces
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
SOCIAL EVENT: HIST 85th Birthday Dinner, $45 per ticket, 7:00: Tue S U N D A Y MORNING Section A Hyatt Regency McCormick 20C General Papers J. S. Jeffers, Organizer,
Presiding
8:30 1. Sweet beginnings of oxyallyl. D. H. Murray 8:55 2. 75 years of chemistry in the mountains: Virginia Blue Ridge's 75th anniversary "Big Bash". A. K. Addington 9:20 3. Chemical education in nineteenth century Germany: Case of the Franckesche Stiftungen in Halle. P. J. Ramberg 9:45 4. Theodor von Grotthuss (1775-1822): Trail Blazer. B. Jaselskis, C. E. Moore, A. V. Smolinski 10:10 5. ACS Petroleum Research Fund with thanks to Dr. Thomas Midgley as ACS President. H. M. Peters, D. T. Smorodin Section Β Hyatt Regency McCormick 20C Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF V. V. Mainz, Organizer,
Presiding
10:50 6. Books by R. C. Fuson. P. R. Jones 11:20 7. Organic Syntheses: Past and pre sent. J. P. Freeman 11:40 8. Inorganic Syntheses: Classic series of chemistry books with strong connec tions to the University of Illinois. J. P. Fackler Jr. Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN
TECH-61
HIST/I&EC
TECHNICAL PROGRAM
SUNDAY AFTERNOON
4:00 29. Do historians or chemists write better history of chemistry? S. Mauskopf
Section A
WEDNESDAY MORNING
I&EC
Section A
Section A
Hyatt Regency McCormick 20C
Division of Industrial & Engineering Chemistry
Hyatt Regency Chicago Riverside Center
General Papers
M. A. Gonzalez, Program Chair
M O N D A Y EVENING Hyatt Regency McCormick 20C Landmark Chemistry Books of the Twentieth Century: Authors from the University of Illinois Cosponsored with Bolton Society, ACS East Central Illinois Section, CHED, and CINF V. V. Mainz, Organizer,
Presiding
1:30 9. Chemistry of the Coordination Com pounds: J. C. Bailar, Jr. monograph. R. D. Archer 1:50 10. Continuing the renaissance in inorganic chemistry: Drago's Physical Methods in Inorganic Chemistry. C. E. Webster 2:10 11. Forging the "key to the world's chemical literature": Origins of CA. J. E. Mears 2:30 12. Impacts of Bard and Faulkner's Electrochemical Methods. J. Leddy 2:50 Intermission. 3:05 13. Malmstadt, Enke, and Crouch texts in electronics for scientists. C. G. Enke 3:25 14. Marion Sparks' Chemical Literature and Its Use: First chemical information text. T. E. Chrzastowski, F. B. Culp 3:45 15. Molecular Structure and Dynamics: Legacy of Willis H. Flygare. J. M. Lisy 4:05 16. Therald Mueller's Inorganic Chemis try, an Advanced Text Book. D. H. Busch 4:25 17. Organic Reactions: Enduring clas sic. S. E. Denmark Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN MONDAY MORNING Section A Hyatt Regency McCormick 20C Landmark Stable Free Radicals of the 20th Century Cosponsored with ORGN Ε. Τ. Strom, Organizer,
Presiding
8:30 Introductory Remarks. 8:40 18. Gomberg's free radical: Triphenylmethyl. P. R. Jones 9:10 19. Nitroxides: Wieland, Lebedev, Rozantsev, Hoffman, and Rassat. S. C. Rasmussen, G. R. A. Wyllie 9:50 20. Stefan Goldschmidt and DPPH. G. D. Mendenhall 10:20 Intermission. 10:35 2 1 . C. Frederick Koelsch and his radical: A case of premature discovery? Ε. Τ. Strom 11:05 22. Glen A. Russell and semidiones. K. M. Trahanovsky 11:35 23. First organic ferromagnet: Minoru Takahashi and the p-nitrophenyl nitronyl nitroxide radical. J. K. Borchardt MONDAY AFTERNOON Section A Hyatt Regency McCormick 20C ACS Chemical Landmarks Program: Celebrating the History of Chemistry J. B. Ginsberg, Organizer,
Presiding
1:30 24. Overview of the National Historic Chemical Landmarks Program. J. B. Ginsberg 2:00 25. From Belmont to Bakélite: Recollections of the (pre)history of the National Historic Chemical Landmarks Program. J. L. Sturchio 2:30 26. Landmark designation: Recipient's view. V. V. Mainz 3:00 27. International Landmarks. E. Wasserman 3:30 28. IEEE's history programs. M. N. Geselowitz
62-TECH
J. S. Jeffers, Organizer,
Presiding
Sci-Mix
8:00-10:00 2. See previous listings. 44, 52, 58. See subsequent listings.
8:30 45. New developments in the history and philosophy of the periodic system. E. Scerri 8:55 46. Joint papers of Alfred Werner and Paul Karrer. D. F. Martin, B. B. Martin 9:20 47. Xenon: Strange one. K. Kostecka
TUESDAY MORNING
Section Β
Section A
Hyatt Regency McCormick 20C
J. S. Jeffers,
Organizer
Hyatt Regency McCormick 20C
Hog Butchers, Tool Makers, and Stackers of Wheat: Chicago-Area Chemical Industry and Government-Sponsored Laboratories Cosponsored with ACS Chicago Section, l&EC, PROF, and SCHB
M. V. Orna, Organizer,
K. P. Fivizzani,
8:30 Introductory Remarks. M. V. Orna. 8:35 30. Water, water, everywhere: Will there be a drop to drink? C. P. Casey 8:50 3 1 . Waters at the intersection of chemistry and culture. C. Hamlin 9:15 32. Water, water everywhere: Role of the water analyst in 19th century England. H. Goldwhite 9:40 33. Clean water for all: Progress of water treatment technology in the 20th century. D. A. Dzombak, J. M. VanBriesen, J. A. Tarr 10:05 Intermission. 10:20 34. Porous polymers via macroreticular synthesis: Nature and applications. R. Albright 10:45 35. Historical perspective on ion exchange resin technology for water purification. R. Banavali, S. Boyce 11:10 36. Arsenic, nitrate, and perchlorate in water: Dangers, distribution, and removal. D. F. Martin, B. B. Martin, R. Alldredge 11:35 37. Arsenic crisis on the Indian subcontinent: A sustainable solution and the role of chemistry. A. K. SenGupta 12:00 Closing Remarks. T. Hunt.
10:00 48. Obiter Research LLC: Six years down the road. W. A. Boulanger 10:20 49. Carbohydrate research at the USDA Laboratory in Peoria, Illinois. G. L. Côté, V. L. Finkenstadt 10:40 50. USDA, Agricultural Research Service: Research for the growing world. R. M. Wagner, Κ. Μ. O'Hara 11:00 5 1 . DSM Desotech: Pioneer in radia tion curing technology. A. J. Tortorello, T. E. Bishop 11:20 52. Rise and fall of the Chicago white lead industry. A. Fitch 11:40 53. Still Nalco after all these years. K. P. Fivizzani WEDNESDAY AFTERNOON Section A
Educating the Laughing, Stormy, Husky Youth of the Midwest: Chicago-Area Colleges and Universities Cosponsored with ACS Chicago Section, PROF, and CHED K. P. Fivizzani, Organizer,
J. J . Bohning,
Organizer
J. I. Seeman, Organizer,
Presiding
1:30 Introductory Remarks. R. Egolf. 1:35 38. Looking back: Eighty-five years of chemists and their history. J. J. Bohning 2:00 39. Communicating the history of chemistry. P. R.Jones 2:30 40. What's history got to do with a newsmagazine? R. M. Baum 3:00 4 1 . Role of HIST in the history of chemistry. J . I. Seeman 3:25 Intermission. 3:40 42. Role of history and the Division of the History of Chemistry in the American Chemical Society. D. Creech 4:10 43. Future of the past: Intellectual and structural issues. A. W. Thackray 4:40 44. Looking ahead: Keeping history of chemistry relevant to the future of chemistry. C. J. Giunta 5:10 Concluding Remarks. R. Egolf.
Sustainable Resources: Science and Information Sources (see CINF, Tue) New Rules From the United States Patent and Trademark Office and Basic Questions of Patentability (see CHAL, Wed) ACS Award for Creative Advances in Environmental Science and Technol ogy (in Memory of Joseph J. Breen): Symposium in Honor of Richard C. Flagan (see ENVR, Tue) Environmental Challenges of Fuel Utilization in the Developing World (see FUEL, Thu) Catalysis Relevant to Energy and Sustainability (see INOR, Sun, Mon, Tue, Wed) Advances in Selective Heterogeneous Catalytic Oxidation (see PETR, Tue)
Hyatt Regency McCormick 20C
Presiding
Section A
HIST at 85: Looking Back and Looking Ahead
Nanotechnology: A Fiber Perspective (see CELL, Sun, Mon)
Organizer
TUESDAY AFTERNOON
Hyatt Regency McCormick 20C
Pressing Challenges and Technology Opportunities for a Sustainable Future (see SUST, Mon) ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu (see BMGT, Mon)
Going with the Flow: Water Sustainability Past, Present, Future Cosponsored with PRES, SUST, and ENVR Presiding
OTHER S Y M P O S I A O F INTEREST: Catalysts for Biorenewable Energy Applications (see CATL, Mon)
1:30 54. College of DuPage: Chemistry at a premier community college. S. Shih 1:55 55. Founding of the Loyola University Chicago Chemistry Department. C. E. Moore 2:20 56. Chemistry in an arts, media, and communications environment. C. E. Cannon 2:45 Intermission. 3:00 57. IMSA: A unique experience for Illinois high school students. C. E. Cannon 3:25 58. Learning and lecturing preferences: Description of an incoming PharmD class. R. M. Zavod, D. P. Zgarrick, C. Duong 3:50 59. Martin Kilpatrick's chemistry legacy at I IT. P. Lykos
Chemistry of Petroleum and Emerg ing Technologies (see PETR, Wed, Thu) Ethics for the Chemical Professional (see PROF, Tue) Benchmarking the Research Competi tiveness of U.S. Chemistry and Chemical Engineering (see PRES, Tue) Sustainability and Chemistry: Tomor row's Challenge for Today's Students (see SOCED, Mon) S O C I A L EVENT: Social Hour: Tue BUSINESS M E E T I N G S : Business Meeting: Tue
Executive Committee Meeting: Mon
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Organizer
8:30 Introductory Remarks. 8:35 1. Advanced membranes for water treatment. Ν. Ν. Li 9:05 2. Are SMBs better that chromatogra phy? Revisiting the comparisons. P. C. Wankat, N. J. Abunasser, J. S. Hur
I&EC
9:35 3. Can we use atmospheric carbon dioxide as an energy efficient carbon source for hydrocarbon fuels produced from renewable energy sources? P. Scovazzo 10:05 Intermission. 10:20 4. Defective MFI zeolite membranes with high selectivities. J. L Falconer, R. D. Noble, M. Yu 10:50 5. Chemistry, chemical engineering, and membrane science: 20+ Years of collaboration. C. Koval 11:20 6. Novel materials for chemical sepa rations. R. D. Noble Section Β McCormick Place North Room N427D, Level 4 Nanotechnology and the Environment: Focus on Green Nanotechnology Green Synthesis of Inorganic Nanomaterials Cosponsored with INOR T. E. Mallouk,
Presiding
8:30 Introductory Remarks. 8:35 7. Environmentally-friendly methodolo gies of fabricating non-carbonaceous nanostructures. S. S. Wong 9:05 8. Greener approaches to the synthesis and functionalization of metal nanoparticles. J. E. Hutchison 9:35 9. Kinetic and morphologic aspects of the nucleating effect of expanded graphite nanoplatelets on two bio-based polymers poly(3-hydroxybutyrate) and poly(L-lactide). D. G. Miloaga, L. T. Drzal, H. A. Hosein, K. Kjoller, M. Misra 10:05 10. Multifunctional nanocomposites from bioplastics. M. Misra, L. T. Drzal 10:35 1 1 . Nanostructure controlled biological polyesters: New opportunities in green materials research. A. K. Mohanty, R. Bhardwaj 11:05 12. Rapid, low temperature microwave synthesis of novel carbon nanotube com posites. S. Chowdhury, Y. Wang, Y. Chen, Z. Iqbal Sustainability and Chemical Education: Industry's Perspective Sponsored by CHED, Cosponsored with l&EC, CEI, and SUST SUNDAY AFTERNOON Section A McCormick Place North Room N427 B/C, Level 4 l&EC Division Fellow Award: Symposium in Honor of Richard Noble J. D. Way,
Organizer
P. Scovazzo, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 13. Effect of sorbed water and tempera ture on the optical properties and density of thin glassy polymer films on a silicon substrate. B. W. Rowe, B. D. Freeman, D. R. Paul 2:05 14. Sulfur resistant palladium-gold composite membranes for hydrogen separations. J . D. Way, P. M. Thoen, S. K. Gade 2:35 15. Gasification of biomass model compounds and biomass in supercritical water. J. Hahn, L. Cernohlavek, W. A. Jacoby 3:05 Intermission. 3:20 16. Desalination properties of sulfo nated polysulfones. H. B. Park, J. McGrath 3:50 17. Metal ion affinities of coordinating polymers: The auxiliary group effect. S. D. Alexandratos, X. Zhu 4:20 18. Supported lyotropic liquid crystal polymer membranes: New materials for size-selective aqueous nanofiltration and desalination. D. L. Gin, M. Zhou, T. J. Kidd, X. Lu, X. Zeng, P. R. Nemade, R. D. Noble
Section Β
Section Β
McCormick Place North Room N427D, Level 4
McCormick Place North Room N427D, Level 4
Nanotechnology and the Environment: Focus on Green Nanotechnology Green Synthesis of Inorganic Nanomaterials Cosponsored with INOR
ACS and AlChE Symposium on Applied Chemistry and Engineering Advanced Oxidation Processes Cosponsored with American Institute of Chemical Engineers
S. S. Wong,
Presiding
D. Ollis and P. Pichat,
1:30 Introductory Remarks. 1:35 19. Metallurgy in a beaker: Toward greener routes for the synthesis of nanocrystalline alloys. R. E. Schaak 2:05 20. Molecular nanocrystals: An ideal vehicle for large scale solid-to-solid photo chemical reactions. M. A. Garcia-Garibay 2:35 21. Novel physical and chemical prop erties of zeolitic nanomaterials. M. A. White, B-Z. Zhan, Μ. Β. Jakubinek, T. K. Sham, J. Pincock, T. S. Cameron 3:05 22. Preparation and characterization of water-soluble, monolayer-protected quan tum dots. S. A. Owens, M. C. Carpenter, J. W. H. Sonne, D. T. Miles 3:35 23. The second generation of quantum dots. X. Peng 4:05 24. Truly green nanotechnology for water purification. A. W. Apblett, S. I. Kuriyavar, T. M. Trad
Presiding
8:30 Intermission. 8:55 33. Sonochemical transformation of perfluorooctane derivatives PFOS and PFOA into primary inorganic constituents. M. R. Hoffmann, C. D. Vecitis, B. Mader, H. Park, J. Cheng 9:20 34. Kinetics and mechanism in the advanced oxidations processes. G. R. Peyton 9:45 35. Sulfate radical-based advanced oxidation processes. D. D. Dionysiou 10:10 Introductory Remarks. 10:20 36. A view on heterogeneous photocatalysis based on some fundamental aspects and application-related studies. P. Pichat 10:45 37. Materials for photocatalysis. M. A. Anderson 11:10 38. Kinetics of photocatalyzed film removal. D. Ollis
2:15 48. Liquid-liquid equilibria of ionic liquid systems: How good are conventional gE models? L D. Simoni, J. F. Brennecke, M. A. Stadtherr 2:35 49. Superacids of the type 1,1,2,2,tetrafluoroethanesulfonic acids and ionic liquid applications. M. A. Harmer, C. Junk, S. Jackson, D. Confer, C. Hoffman, J. Vickery, Z. Schnepp 2:55 Intermission. 3:05 50. Controlling the size, shape and surface morphology, agglomeration, phases and defect of inorganic nanoparticles under continuous flow conditions. C. L. Raston, K. S. Iyer, M. Saunders 3:25 5 1 . Continuous process for esterification of citric acid: Formation of triethyl citrate. N. S. Asthana, A. Kolah, D. Miller, D. Vu, C. Lira 3:45 52. Reinventing metalworking fluids: A case study in greening the U.S. manufac turing sector. A. F. Clarens, D. Maclean, K. F. Hayes, S. J. Skerlos 4:05 53. Economics of sustainable chemis try: The business case for sustainability. C. A. Bradlee M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center
MONDAY AFTERNOON Sci-Mix
MONDAY MORNING Section A Section A McCormick Place North Room N427 B/C, Level 4
8:00-10:00
Calixarenes: State of the Art and Perspectives Cosponsored with NUCL L. H. Delmau,
Organizer
D. R. Peterman, Organizer,
H. K. Jacobs and M. A. Gonzalez, Organizers
McCormick Place North Room N427 B/C, Level 4 Calixarenes: State of the Art and Perspectives Cosponsored with NUCL D. R. Peterman,
Organizer
L. H. Delmau, Organizer, Presiding
8:30 Introductory Remarks. 8:35 25. Taking inspiration from calixarene chemistry. P. A. Gale 9:00 26. Di-ionizable calix[4]arene-1,2-crown ligands for metal ion separations. R. A. Bartsch, C. Tu, D. Zhang, K. Surowiec, X. Cao 9:25 27. Functionalized calix[4]arene-benzocrown-6 ethers for the extraction of cesium. D. D. Ensor, V. M. Meadors, L. H. Delmau, B. A. Moyer, R. A. Bartsch, H. Zhou 9:50 28. Crosslinking and functionalization of resorcinarene-encapsulated gold nanoparticles. B. Ramjee, Y-G. Kwon, A. Wei 10:15 Intermission. 10:30 29. Optical sensing of TI+ and Cs+ by a fluorogenic 1,3-altemate calix[4]arenebis(crown-6 ether) containing one pendant dansyl group. G. G. Talanova, E. D. Roper, V. S. Talanov, M. G. Gorbunova, R. A. Bartsch 10:55 30. Calixarene crown-6 and calixpyrrole: A fundamental study of cation and anion receptors combination. L. H. Delmau, M. P. Wintergerst, J. L. Sessler, B. A. Moyer 11:20 3 1 . Elaborated calixpyrroles: From chromogenic anion sensing to ion-pair recognition. C-H. Lee, M-J. Lee, M-S. Kim, H. Miyaji, S-J. Hong, S-D. Jeong, H. K. Na, J. L. Sessler 11:45 32. New calixpyrrole and calixpyrroleinspired pyrrole-based anion receptors. J. L. Sessler, D. Gross, W-S. Cho, G. D. Pantos, E. Katayev, N. Barkey, K. A. Nielsen, J. O. Jeppesen, H. Miyaji, D-W. Yoon, S-J. Hong, C-H. Lee
Presiding
1:30 Introductory Remarks. 1:35 39. Metal ion separations with di-ioniz able calix[4]arene-1,3-crown ligands. R. A. Bartsch, H. Zhou, K. Surowiec 2:00 40. Development of a novel solvent for the simultaneous separation of cesium and strontium from acidic solutions. C. L. Riddle, J. D. Law, D. H. Meikrantz, B. J. Mincher, D. R. Peterman, R. D. Tillotson, T. A. Todd 2:25 4 1 . Para-acyl calix[4]arenes: Inclusion abilities and applications. G. Ananchenko, M. Pojarova, K. Udachin, A. Coleman, J. Ripmeester 2:50 42. New platforms for immobilization of calixarenes for gas-sensing and trapping. R. Rogers, J. H. Poplin, D. M. Rudkevich 3:15 Intermission. 3:30 43. Separation and preconcentration of cesium from acidic media by extraction chromatography. M. L. Dietz, D. D. Ensor, B. W. Harmon, S. Seekamp 3:55 44. Gamma radiolysis of the FPEX solvent. B. J. Mincher, S. P. Mezyk, D. R. Peterman, C. L. Riddle, J. D. Law, T. A. Todd 4:20 45. Flowsheet testing of the Fission Product Extraction Process for the separa tion of cesium and strontium from spent nuclear fuel. J. D. Law, D. R. Peterman, T. A. Todd, D. H. Meikrantz, C. L. Riddle
95, 97-100, 104, 107-109, 117, 120-121, 123, 125, 127, 135, 137-138, 141, 145-146, 148,150-151,154. See subsequent list ings. TUESDAY MORNING Section A McCormick Place North Room N427 B/C, Level 4 E. V. Murphree Award in Industrial and Engineering Chemistry: Symposium in Honor of Wolfgang F. Holderich W. Holderich, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 54. Award Address (E. V. Murphree Award in Industrial and Engineering Chemistry, sponsored by ExxonMobil Research and Engineering Company). The impact of weakly acidic catalysts on the commercialization of chemical pro cesses. W. Holderich 9:15 55. Catalysis—breakthrough innova tions for vitamins and fine chemicals. M. Eggersdorfer 9:55 Intermission. 10:10 56. The impact of zoelitic catalysts on the commercialization of chemical pro cesses. T. F. Degnan 10:50 57. The impact of surface science on the commercialization of chemical pro cesses. G. A. Somorjai 11:30 Concluding Remarks. Section Β
Section Β McCormick Place North Room N427D, Level 4 ACS and AlChE Symposium on Applied Chemistry and Engineering Green Chemistry and Engineering, Cosponsored by the Green Chemistry and Engineering Subdivision Cosponsored with American Institute of Chemical Engineers
McCormick Place North Room N427D, Level 4 ACS and AlChE Symposium on Applied Chemistry and Engineering Gas Separations, Cosponsored by Separation Science and Technology Subdivision Cosponsored with American Institute of Chemical Engineers W. J . Koros and M. D. Guiver,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
M. A. Abraham and R. D. Rogers, Organizers 1:30 Introductory Remarks. 1:35 46. A "Green" industrial revolution is in our future. R. D. Rogers, M. A. Abraham 1:55 47. Developing green chemistry for chemical synthesis. C-J. Li
Organizers
8:30 Introductory Remarks. 8:35 58. Developments in commercial mem branes for natural gas purification. L. S. Lloyd S. White, C. Wildemuth 9:05 59. C02-selective membranes: Water gas shift reaction for hydrogen purification. J. Zou, J. Huang, W. W. Ho
TECH-63
TECHNICAL PROGRAM
I&EC 9:35 60. Novel carbon fiber composite materials for gas separations. E. Vogel, G. Lipscomb, M. Coleman 10:05 6 1 . Effect of nanoparticles on structure and gas transport properties in polymers. S. Matteucci, B. Freeman, S. Kalakkunnath, D. S. Kalika, A. Hill 10:35 62. Gas transport and physical aging of a highly microporous polymer as probed by positron annihilation lifetime spectroscopy. C. Cornelius, A. J. Hill, S. Pas, C. L. Staiger 11:05 63. A general strategy for adhesion enhancement in mixed matrix membranes by formation of nanostructured particle surfaces. S. Shu, W. J. Koros
1:35 74. Single-site catalysts as models for the exploration of catalyst structure-func tion relationships. A. Bell 2:05 75. Structure and reactivity of model cluster-derived PtFe/Si02 catalysts. M. D. Amiridis, A. Siani, O. S. Alexeev, B. Captain, R. D. Adams 2:35 76. Manipulating heterogeneous cata lytic activity for design of high temperature total NOx sensors. J-C. Yang, P. K. Dutta 3:05 77. Fluorene oxidation using manga nese oxide octahedral molecular sieves (Oms-2). N. Opembe, Y-C. Son, S. L. Suib 3:35 Concluding Remarks.
Section C
McCormick Place North Room N227B, Level 2
McCormick Place North Room N227B, Level 2
l&EC Division Fellow Award: Symposium in Honor of H.S. Muralidhara
Nanotechnology and the Environment: Focus on Green Nanotechnology Applications of Nanomaterials for a Greener Environment Cosponsored with INOR N. F. Savage,
Section C
Presiding
8:30 Introductory Remarks. 8:35 64. Assessing environmental exposure to engineered nanoparticles. A. B. A. Boxall, K. Tiède, S. Tear, Q. Chaudhry, J. Lewis, H. David 9:05 65. Nanoscale zero-valent iron for environmental remediation: Materials and engineering aspects. W-X. Zhang 9:35 66. Self-assembly of carbon nanotubes to serve as nanosorbents. R. Brukh, M. Karwa, C. Saridara 10:05 67. Targeted removal of bioavailable metal in carbon nanotubes. D. G. Morris, L Guo, X. Liu, V. Gurel, D. Murray, C. Vaslet, A. Zhitkovich, A. B. Kane, R. H. Hurt 10:35 68. Visible light-activated mesoporous titanium dioxide photocatalysts synthesized via sol-gel method employing nitrogen-containing surfactant templates. H. Choi, M. G. Antoniou, D. D. Dionysiou 11:05 69. Effects of fullerenes (nC60 or C60) on soil microbiological functions. R. F. Turco, Z. Tong, M. Bischoff, L. M. Nyberg, L. F. Nies, P. P. Kulkarni, C. T. Jafvert, B. Applegate
M. Ramesh,
Organizer
1:30 Introductory Remarks. 1:35 78. Novel fluid-particle interaction mechanisms in dispersions. D. Wassan, A. Nikolov 2:00 79. Contributions of Dr Muralidhara and other distinguished alumni to capstone projects at West Virginia University. D. Dadyburjor, R. Turton, J. A. Shaeiwitz 2:25 80. Protein fractionation using ultrafiltra tion. Z. Cui 2:50 8 1 . New solutions for the management of system dynamics in industrial water systems. D. A. Johnson, G. Townsend, T. Abraham 3:15 82. Enzymatic esterification of lactic acid coupled to pervaporation: Challenges and opportunities of a hybrid reactionseparation process. S. Luque 3:40 Intermission. 3:55 83. Growth through Innovation at Air Liquide. C. Shetty 4:20 84. Fiber Additives in Food and Indus trial Applications. J. Satyavolu 4:45 85. Organic delivery vehicles for prob ing and treating biological systems: Adapt ing fabrication processes from the elec tronics industry for use in nanomedicine. J. M. DeSimone 5:10 86. Award lecture. H. S. Muralidhara 5:35 Concluding Remarks. T U E S D A Y EVENING
TUESDAY AFTERNOON Section A Section A Hyatt Regency Chicago Riverside Center
McCormick Place North Room N427 B/C, Level 4
General Posters E. V. Murphree Award in Industrial and Engineering Chemistry: Symposium in Honor of Wolfgang F. Holderich W. Holderich, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 70. Trends in catalysis for the chemical industry. C. T. Kresge 2:15 7 1 . The impact of alkanes as feedstocks on the commercialization of chemical processes. S. Han 2:55 Intermission. 3:10 72. The impact of renewable feedstocks on the commercialization of chemical processes. L. E. Manzer 3:50 73. Alternative routes to the production of hydrogen. J. N. Armor 4:30 Concluding Remarks. Section Β McCormick Place North Room N427D, Level 4 ACS and AlChE Symposium on Applied Chemistry and Engineering Molecular Design in Catalysis Cosponsored with American Institute of Chemical Engineers S. L. Suib,
Organizer
P. Smirniotis, Organizer, 1:30
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Introductory Remarks.
Presiding
H. K. Jacobs and M. A. Gonzalez, Organizers 8:00-10:00 87. Join the green chemistry and engineering subdivision. M. Grossner 88. Energy transfer in molecular layer-by-layer films of water soluble perylene diimides. T. Tang, K. Peneva, K. Mullen, S. E. Webber 89. Low temperature copper deposition using copper (II) aminoalkoxide precursor for direct metal printing of microelectronics. P. Majumder, M. Tiwari, C. Megaridis, M. Xu, J. McAndrew, C. G. Takoudis 90. Hydration of industrially obtained magne sium oxide. E. M. van der Merwe, C. A. Strydom, M. E. Aphane, K. P. Matabola 91. Guest encapsulation behavior of a dodecanuclear metalladiazamacrocyclic host. R. P. John, D. Moon, M. S. Lah 92. Neutral and cationic octanuclear gallium metallamacrocycles with two different topological connectivities. M. Park, R. P. John, D. Moon, K. Lee, M. S. Lah 93. Nickel-iridium bimetallic catalysts for ammonia decomposition. X. Han, W. Chu, Z. Zhai, S. Luo, X. Wang, T. Zhang 94. Novel manganese based 48-membered hexadecanuclear metallamacrocycle and its comparison with related structures. K. Lee, R. P. John, D. Moon, M. Park, M. S. Lah
95. Tuning the properties of 2-D gold nanoparticle arrays. M. L. Jespersen, J. E. Hutchison 97. Oxidative degradation of nitrophenols and nitroanilines using Fe(lll)-TAML activated H 2 0 2 . A. Chanda, G. J . Diabes, A. D. Ryabov, S. K. Khetan, T. J. Collins 98. A new, mild catalytic system for the 0 2 oxidation of /^xylene uses a cobalt/initiator catalyst in C 0 2 expanded solutions (CXLs). C. Ma, R. S. Givens, D. H. Busch, B. Subramaniam 99. Application of immobilized T i 0 2 photocatalysts for the on-board treatment of NASA's wastestreams. M. G. Antoniou, U. Nambiar, D. D. Dionysiou 100. Arsenic in alkaline coal fly ash: Column leaching vs. batch sequential leaching. P. Naithani, A. P. Khodadoust, T. Theis, I. Murarka 101. Attrition characteristics in a modified attrition tester with swirl injection. S. H. Lee, J. M. Lee, J. S. Kim, D. W. Kim 102. Combustion of LPG in microreactor with exchangeable sheet-type catalysts. K. Kusakabe, M. Tanaka, Y. Okada, M. Taneda 103. Withdrawn. 104. Comparisons of silica polyamine com posites and crosslinked polystyrene resins. M. A. Hughes, J. Wood, O. Wong, T. Sardot, E. Rosenberg 105. Effect of crosslink density of poly(methyl methacrylate) upon laser irradiation. C. T. Lloyd, J. H. Wynne, R. F. Cozzens 106. Effect of initial COD concentration, nutri ent addition and microbial acclimation on anaerobic digestion of cattle manure. Z. Xiang, L Jindun 107. Effect of ionic liquid hydrophobicity on the enzyme activity. H. Zhao, S. Campbell, Z. Song, O. Olubajo 108. Fate of mercury beneath a sediment cap. L. E. Katz, N. W. Johnson, D. D. Reible, J. Liu 109. Effect of natural organic matter on aque ous Cr'" oxidation by Mn(hydr)oxides. A. R. Wadhawan, A. T. Stone, E. J. Bouwer 110. Flame spray production of three way catalyst for automobile emission control. P.Zhang 111. Investigation of the fracture appearance transition temperature for CrMoV steel by electrochemical process. Y. Chen 112. Method for the rapid analysis of polychlorinated-p-dibenzodioxins and furans in soil and sediment. D. R. McAlister, M. J. Fern 113. Morphology and structure of polyaniline/ starch nanocomposites. Q. Zhang, W. Li, D. Chen, M. Zhu 114. On-line estimation of biomass and intra cellular protein for recombinant Esch erichia coli. C-L. Ko, F-S. Wang 115. Optimization of parameters of single walled carbon nanotube bundles for hydro gen storage. D. Cao 116. Particle size-dependent partitioning behaviors of pesticides in soil-watersurfactant systems. P. Wang, A. A. Keller 117. Progress in process intensification: Synthesis of imines using a spinning tube-in-tube reactor. J . T. Ciszewski, M. A. Gonzalez 118. Refining properties of bleached kraft pulp pretreated with Pulpzyme HC. A. Zhang, M. Qin, Y. Fu, R. Sun 119. Sampling techniques and application of · the USEPA's Equilibrium Partitioning Sediment Benchmark (ESB) methods for evaluating metal bioavailability and toxicity in Lower Hudson River sediments. K. D. Jenkins, C. E. Kiehl-Simpson, S. L Huntley
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
120. Separation of cyclohexanone from cyclohexane using selected alkyl-imidazolium ionic liquids. S. A. Morton III, D. Shlossman, G. Rossi 121. Sorption of ethylbenzene, toluene and xylene onto crumb rubber from aqueous solutions. L. A. Alamo-Nole, F. R. Roman, O. Perales-Perez 122. Study on the phase behavior of carbon dioxide in activated carbon fiber by density functional theory and Yukawa potential. D.Fu 123. Synthesis of magnetic ion exchange resin beads for uranium and dye removal from aqueous waste streams. S. I. Kuriyavar, A. W. Apblett 124. Synthesis of mesoporous Ti0 2 -P25 composite films using polysorbate 20 (Tween 20) as template and evaluation for the destruction of creatinine in water. Y. Chen, D. D. Dionysiou 125. The effect of solution and processing variables on the morphology of multifunc tional electrospun nanofibers. S. Nartker, L T. Drzal, M. Misra 126. The effect of surfactant concentrations on rheological properties of HEC. J . Ye, W-J. Zheng, J. Xiong 127. Thermal analysis of polymers and poly mer bionanocomposites. H. A. Hosein, D. G. Miloaga, L T. Drzal, K. Kjoller, M. J. Rich 128. QSPR Models for predicting extraction equilibrium of dicarboxylic acids with tertiary amine. X. Shan, W. Qin, Y. Dai 129. The characteristics of biomass gasifica tion with steam reforming. J. G. Lee, S. J. Yoon, Y. C. Choi, J. H. Kim, S. H. Lee 130. A useful and green procedure for the synthesis of fatty ester derivatives of ara-cytidine through an enzymatic acylation reaction in ionic liquid-containing system. X-F. Li, M-H. Zong 131. Increase of viscosities of aqueous CaCI 2 solutions under the influence of magnetic field. S. A. Ghauri, M. Afzal, M. Zakaullah 132. Determination of effective diffusivity and tortuosity factors in LB WGS catalyst. L. Wei, F. Wang 133. Investigation on the removal characteris tics of elemental mercury using atmo spheric pressure non-thermal plasma. D. N. Shin, D. J. Koh, K. T. Kim, Y. Byun, K. B. Ko, W. Namkung, M. H. Cho Section Β Hyatt Regency Chicago Riverside Center Joe Breen Student Poster Session in Green Chemistry Cosponsored with the Green Chemistry and Engineering Sub-Division Μ. Μ. Kirchhoff and Κ. Ε. Parent, Organizers 8:00-10:00 134. Joe Breen: The heart and soul of green chemistry. Μ. Μ. Kirchhoff, Κ. Ε. Parent 135. Triethyl citrate: An environmentally benign plasticizer from biorenewable resources. N. S. Asthana, A. Kolah, D. Vu, C. Lira, D. Miller 136. Developing a green physical chemistry experiment. C. R. Braden, C. M. Clark, J. Diamond 137. Commercially viable resolution of (S)ibuprofen. D. Chavez-Flores, J. M. Salvador 138. Green generation of hydrogen peroxide from oxygen and hydrogen using com pressed carbon dioxide as the solvent. Q. Chen, E. J. Beckman 139. Graphite-sensitized microwave flash pyrolysis. H. Y. Cho, R. P. Johnson 140. Evaluation of ionic liquids for applications in the separation of butanol and water. S. E. Davis, S. A. Morton III 141. Investigation of ionic liquids as green separation agents for gas stream purifica tion. K. M. Henry, S. A. Morton III 142. Cyclohexane-1,2,5-triol interaction with metal catalysts in aqueous solutions. T. Kasputis, D. G. Kovacs 143. Preparation of a novel UV curable epoxy methacrylate resin containing phthalazione coating. Y. Kou, J. Wang, X. Jian
I&EC/INOR 144. Solvent-free synthesis of monoacylaminals as precursors in the synthesis of carbinolamides. T. Koyanagi, R. W. Nagorski 145. Solubility of lubricant compounds in SCCO2 for use in MWF applications. D. Maclean, A. F. Clarens, K. F. Hayes, S. J. Skerlos 146. Degradation of Fluoxetine using Fe'"TAML activated hydrogen peroxide. P. J . Madsen, D-L. Popescu, M. A. Vrabel, C. P. Horwitz, T. J. Collins 147. Oxidative degradation of bisphenol A using an Fe-TAML® catalyst and hydro gen peroxide. R. T. Malecky, E. S. Beach, C. P. Horwitz, T. J. Collins 148. Challenge and change: Exploring the barriers to the implementation of green chemistry in the United States. K. J. Matus, P. T. Anastas 149. A safer and greener preparation of MEM ethers from alcohols. C. M. Maurseth, J. T. Thomas, G. L. Milligan 150. Synthesis of ionic liquids and their use as replacement solvents in oxidation reactions. F. C. Mayville Jr., M. Allen, J. Sparks 151. Development of an undergraduate green organic chemistry laboratory experiment: Reduction chemistry involving polymethylhydrosiloxane (PMHS). Κ. Ε. O'Brien, D. K. Wicht 152. Synthesis of diacetyl ferrocene chalcone using green chemistry. L. J. O'Dell, B. W. Baldwin 153. Homogenous catalytic oxidations in dense C 0 2 as a benign reaction medium. B. Rajagopalan, D. H. Busch, B. Subramaniam 154. Nanocomposite materials for clean energy applications. T. Sanders, T. Liu, G. Veser 155. Aromatization of pyrimido fused 1,4dihydropyridine derivatives using ammo nium salts: A green synthesis. M. Kidwai, K. Singhal 156. Direct aerobic oxidation of alcohols to methyl esters. E. Taarning, I. S. Nielsen, K. Egeblad, C. H. Christensen, R. Madsen 157. Green Diels-Alder reactions: 9-Methylanthracene and N-ethylmaleimide in high temperature water. S. M. Tauer, L U. Gron 158. Degradation of triclosan using Fe'"TAML activated hydrogen peroxide. J. L Tehranchi, D-L. Popescu, C. P. Horwitz, T. J. Collins 159. 1 H-NMR quantitative analysis method for one-step synthesis of quaternary ammo nium salts from ammonium salts and carbonate. T. Wu, Z. Zheng, Y. Wu, R. Zheng, Q. Zhang, D. Lin, X. Zhou 160. Selective oxidation of glyoxal with maleic acid hydroperoxide to prepare glyoxylic acid. Y. Zhang, Z. Sun, T. Xu, W. Eli WEDNESDAY MORNING Section A McCormick Place North Room N427 B/C, Level 4 Nanotechnology for Contaminated Site Remediation K. R. Reddy and A. P. Khodadoust, Organizers 9:00 Introductory Remarks. 9:10 161. Synthesis and evaluation of diphosphonic acid functionalized mesoporous silica for actinide sorption. R. J . Wiacek, M. J. O'Hara, O. Egorov, G. E. Fryxell, R. S. Addleman 9:30 162. Yoctowells of various diameters with beta-tetracarboxylate and meso-tetra biphenylcarboxylate porphyrin bottom. V. Meggyes 9:50 163. Arsenic sorption and redox trans formation by modified nanostructured ordered mesoporous carbon. Z. Gu, B. Deng 10:10 164. Palladium doped magnesium bimetallics for dechlorinating PCB contami nated matrices. S. Agarwal, S. R. Al-Abed, D. D. Dionysiou 10:30 165. Membrane-supported palladium nanoparticles as catalysts for reductive dechlorination. K. Venkatachalam, N. Chopra, V. G. Gavalas, D. Bhattacharyya, L. G. Bâchas
10:50 166. Anaerobic corrosion behavior of nanosized iron. E. J. Reardon, R. Fagan, J. L. Vogan, A. Przepiora 11:10 167. Nano ZVI vs. conventional ZVI: The effect of particle size. P. G. Tratnyek, V. Sarathy, J. T. Nurmi, R. L. Johnson 11:30 Concluding Remarks.
McCormick Place North Room N427D, Level 4 ACS and AlChE Symposium on Applied Chemistry and Engineering Novel Catalytic Methods and Reactor Design Cosponsored with American Institute of Chemical Engineers P. Smirniotis,
Section Β McCormick Place North Room N427D, Level 4 ACS and AlChE Symposium on Applied Chemistry and Engineering Separations and Metal-Interactions Cosponsored with American Institute of Chemical Engineers
Section Β
Organizer
S. L. Suib, Organizer,
4:20 Concluding Remarks.
Presiding
9:00 Introductory Remarks. 9:05 168. Fe-TAML/hydrogen peroxide catalysis in strongly alkaline aqueous solution: Applications in the aluminum industry. E. S. Beach, J. L. Henry, C. P. Horwitz, T. J. Collins 9:35 169. Kinetics of hydrogen peroxide reduction as part of the overall kinetics of hydrogen peroxide formation by direct combination in a microreactor. Y. Voloshin, R. Haider, A. Lawal 10:05 170. MicroChannel reactor system for catalytic hydrogénation of aromatic nitro compound. S. Tadepalli, A. Lawal, J. Muslehiddinoglu, D. Kientzler 10:35 171. Microwave-assisted chemical processes in ionic liquids: Toward depletion of emissions and energy savings. C. Guerrero-Sanchez, M. Lobert, T. Erdmenger, R. Hoogenboom, U. S. Schubert 11:05 Concluding Remarks. Hog Butchers, Tool Makers, and Stackers of Wheat: Chicago-Area Chemical Industry and Government-Sponsored Laboratories Sponsored by HIST, Cosponsored with ACS Chicago Section, l&EC, PROF, and SCHB
S. D. Alexandratos,
Organizer
1:30 Introductory Remarks. 1:35 180. Antibacterial mechanisms of silver nanoparticles and nanowires. A. Sharma, D. Ferrer, M. Demers, S. Sepulveda-Guzman, A. Torres, G. Georgiou, M. Jose-Yacaman 2:05 181. Calixarene-encapsulated nanopar ticles: Self-assembly into functional nanomaterials. A. Wei 2:35 182. Acetate modified silica polyamine composite materials for heavy metal removal from aqueous media. M. A. Hughes, E. Rosenberg, J. Wood 3:05 183. Bifunctional chelating fiber contain ing aminomethylphosphonate and sulfo nate. A. Jyo, Y. Shibata, Y. Fujii, M. Tamada, A. Katakai 3:35 184. Transfer printing of femto-liter volumes of liquids on a polymer substrate. C. Gupta, G. A. Mensing, M. A. Shannon, P. J. A. Kenis 4:05 185. Hydrodynamic diffusion system for molecular separations. S. S. Mamidi, T. R. Farhat THURSDAY MORNING
McCormick Place North Room N427 B/C, Level 4 Nanotechnology for Contaminated Site Remediation K. R. Reddy and A. P. Khodadoust, Organizers 1:30 Introductory Remarks. 1:40 172. Functionalized FeO nanoparticles for targeted in situ degradation of entrapped DNAPL. G. V. Lowry, N. B. Saleh, Y. Liu, H-J. Kim, K. Sirk, K. Matyjaszewski, R. D. Tilton 2:00 173. Nanotechnology for chromate remediation in groundwater. A. W. Apblett, K. Barber, A. P. Piquette, Ν. Materer, J. Flaming 2:20 174. Enhancement of nano-iron disper sion and reactivity for degradation of trichloroethylene. B. J. Shiau, T-P. Hsu, J. H. Harwell, D. A. Sabatini, A. D. Jazdanian 2:40 175. Transport of reactive nanoscale iron particles in subsurface soils. A. P. Khodadoust, K. Reddy, S. Varadhan 3:00 176. Use of nanoscale zero-valent iron for groundwater remediation from theory to technical maturity. R. Baig, F. Gheorghiu, C. Mace 3:20 177. TCA remediation using nanoscale zero-valent iron at a former manufacturing facility located in central Ohio. R. C. Hendricks, M. J. Valentine 3:40 178. Field-scale application of emulsi fied, zero-valent, nanoscale iron for reme diation of DNAPL. C. L. Geiger, C. A. Clausen, J. Quinn, S. O'Hara, T. A. Krug, J. Wolters, M. Corbin 4:00 179. In situ treatment of trichloroethene with reactive nanoscale iron particles. A. D. Jazdanian, K. Kakuya, K. Okinaka, M. Lagarrigue
[NOR Division of Inorganic Chemistry D. C. Crans and Β. Τ. Donovan-Merkert, Program Chairs
Section A SUNDAY MORNING McCormick Place North Room N427 B/C, Level 4 Remediation of Contaminated Sediments: Challenges and Opportunities Cosponsored with the Separation Science and Technology Sub-Division
WEDNESDAY AFTERNOON Section A
1:40 193. Velsicol chemical/Pine River cleanup - 640,000 cubic yards, 7 years, and 4400 gallons of DNAPL later. G. C. Bayer, R. Stryker, S. Linebaugh 2:00 194. Practical approaches to remedia tion of polychlorinated biphenyls in sedi ments. Y. Fang, S. R. Al-Abed 2:20 195. Enhanced reductive dechlorination of PCBs in contaminated sediments using iron. R. Srirangam, S. Ramamurthy, A. P. Khodadoust, R. C. Brenner 2:40 196. Evaluation of PCB transport from contaminated sediments during in situ capping. Y. S. Hwang, J. Lee, J. J. Lenhart, P. J. Fox, M. C. Scullion 3:00 197. Performance of activated carbon amended sediment caps for PCB seques tration. J. L. Fairey, K. M. McDonough, G. V. Lowry 3:20 198. Immobilization of Hg in sediment caps and inhibition of Hg methylation by FeS amendment. J . Liu, K. Valsaraj, D. D. Reible, I. Devai, R. D. Delaune 3:40 199. Composite reactive membranes for remediation of contaminated sediments. E. M. Surdo, E. L. Cussler, W. A. Arnold 4:00 200. Active capping project in the Chicago River. P. Z. Viana, K. Yin, X. Zhao, K. Rockne 4:20 Concluding Remarks.
K. Reddy and A. P. Khodadoust, Organizers 9:00 Introductory Remarks. 9:10 186. Great Lakes Legacy Act program for remediation of contaminated sedi ments. A. Vaidya 9:30 187. Quantifying spatial and temporal contaminant loading through sediment core analyses. B. E. Johnson, J. R. Hunt 9:50 188. A novel volume and mass estima tion methodology to support iterative sediment remedial scenarios using data of known quality. D. Callaghan, J. Kraycik, K. Frysinger, R. Vitale, D. Kalet 10:10 189. Building a sediment model for dynamic updating and remediation plan ning. G. R. Eykholt, S. G. Lehrke, S. J. Laszewski 10:30 190. Hydrologie conditions around and in coal tar impacted river sediment at a former MGP site. C. T. Jafvert, S. Hyun, B. Jenkinson, C. Enfield 10:50 191. Remedial options for contami nated sediments. K. R. Reddy 11:10 192. Chromium occurrence and Cr(VI) attenuation in Baltimore Harbor sediments, Baltimore, MD. A. M. Graham, E. J. Bouwer 11:30 Concluding Remarks. THURSDAY AFTERNOON
Section A McCormick Place East Room E270, Level 2 Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST T. D. Tilley, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1. The molecular chemistry of renew able energy. D. G. Nocera 9:05 2. Water oxidation catalyzed by oxobridged dinuclear Mn complexes sup ported on high surface area silica. E. M. W. Rumberger, A. T. Bell, T. D. Tilley 9:35 3. Water oxidation catalysis induced by hybridization of multi-nuclear metal com plexes and solid materials. M. Yagi 10:05 Intermission. 10:20 4. Water oxidation from the blue dimer to Photosystem II. T. J. Meyer, T. Cardolaccia, F. Liu, J. Jurss 10:50 5. Water oxidation by Ru-based multielectron catalysts: A theoretical and experimental approach. J. T. Muckerman, E. Fujita, D. Polyansky, K. Tanaka 11:20 6. Reactivity of Ru naphthyridyl-pyridine complexes toward water oxidation. D. Polyansky, E. Fujita, J. T. Muckerman, R. P. Thummel 11:50 7. Metal ion catalysis of water oxida tion: What we can learn from ruthenium μ-οχο dimers. J. K. Hurst, J. Cape, A. Clark, S. Das, C. Qin
Section A McCormick Place North Room N427 B/C, Level 4 Remediation of Contaminated Sediments: Challenges and Opportunities Cosponsored with the Separation Science and Technology Sub-Division K. Reddy and A. P. Khodadoust, Organizers
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
1:30 Introductory Remarks.
TECH-65
TECHNICAL PROGRAM
1N0R Section Β McCormick Place East Room E271B, Level 2 F. Albert Cotton Award in Synthetic Inorganic Chemistry: Symposium in Honor of Christopher C. Cummins D. G. Nocera, G. L Hillhouse,
Organizer Presiding
8:30 Introductory Remarks. 8:40 8. New developments in coordination and surface chemistry of the 2,6-functionalized azulenic framework. M. V. Barybin, C. L. Berrie, T. C. Holovics, T. R. Maher, R. E. Robinson 9:05 9. Hydrogen storage in chemical bonds: Dehydrogenation of ammonia-borane. F. H. Stephens, R. J. Keaton, R. T. Baker 9:30 10. Radical chemistry of C-C bonds in a redox active ligand: A diazenide/diazoalkane redox couple. J. J. Curley, T. Murahashi, C. C. Cummins 9:55 11. (CO)5W-P2-eliminating niobium complex as a P 2 synthon, and its use in the synthesis of cyclo-P3 complexes. N. A. Piro, C. C. Cummins 10:20 12. Ligand control of the stability, volatility and reactivity of copper (I) amide ALD/CVD precursors. J. M. Blackwell, D. J. Morrison 10:45 13. On the olefin trimerization reaction with chromium catalysts: Ligand effects, deuterium labeling, and studies of regiochemistry using a model chromacyclopentane complex. T. Agapie, J. A. Labinger, J. E. Bercaw 11:10 14. Development of a scaleable syn thesis for DPP-IV inhibitor ABT-279. M. G. Fickes, L. Bhagavatula, K. M. Engstrom, J. Gandarilla, A. W. Kruger, T. S. McDermott, M. J. Rozema, S. H. Wagaw, S. J. Wittenberger 11:35 15. Ferrocene diamide complexes of d°f n elements. P. L. Diaconescu Section C McCormick Place East RoomE271A, Level 2 Nanoscale Inorganic Catalysis P. Balbuena, D. A. Chen, and R. E. Schaak, Organizers, Presiding 8:30 16. Bulk and supported model catalysts: Selectivity at the atomic scale. H-J. Freund 9:15 17. Catalytically active gold: From nanoparticles to ultra-thin films. D. W. Goodman, M. Chen 10:00 Intermission. 10:15 18. Structure and growth of alloy nanoclusters. R. Ferrando 11:00 19. Selective oxidation catalysis using supported gold and gold palladium nano particles. G. J. Hutchings Section D McCormick Place Lakeside Room E253A, Level 2 Nanoscience: Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers C. Papadopoulos,
Presiding
8:30 20. Shell-crosslinked siloxane nanocages: Synthesis, metal binding and nanoparticle preparation. J. Henao, Y-W. Suh, M. Kung, H. Kung 8:50 2 1 . Synthesis and characterization of covalently attached polyethyleneimine functionalized single-wall carbon nanotubes. C. A. Crouse, E. Dillon, R. Colorado Jr., A. R. Barron 9:10 22. Synthesis of aligned single-walled carbon nanotube networks. C. Papadopoulos, B. Omrane
66-TECH
9:30 23. Substrate effects on the growth of single-walled carbon nanotubes (SWNTs) from iron complexes, clusters, and colloids on surfaces. R. Colorado Jr., C. A. Crouse, C. C. Gallaway, A. Orbaek, A. R. Barron 9:50 24. Microwave-assisted synthesis of cage-like mesoporous ordered silicas. E. B. Celer, M. Jaroniec 10:10 25. One-step synthesis of large-as pect-ratio gold nanostructures using cetyltrialkylammonium bromide surfactants. C-K. Tsung, X. Kou, J. Wang, G. Stucky 10:30 Intermission. 10:40 26. Synthesis of small diameter car bon nanotubes by catalytic decomposition of methane. X-J. Xu, S-M. Huang 11:00 27. "Green" approach for fabrication of conducting polymer nanocomposite: The catalytic role of carbon nanotubes. Y. Ma, P. L. Chiu, A. Serrano, A. Chen, H. He 11:20 28. Photocatalytic nanofibers and nanotubes made by atomic layer deposi tion. M. Leskela, M. Kemell, V. Pore, E. Santala, M. Ritala 11:40 29. Carbon dioxide as a carbon source for synthesis of carbon nanotubes by chemical vapor deposition. X-J. Xu 12:00 30. Controlling the anatase/brookite ratio in sol-gel synthesized titanium dioxide nanoparticles. S. L. Isley, R. L. Penn Section Ε McCormick Place Lakeside Room E253B, Level 2 Materials Chemistry D. C. Crans,
Organizer
A. E. Stiegman,
Presiding
8:30 3 1 . Characterization of porous catalysts by N2 sorption and small angle neutron scattering (SANS) studies. S. R. Kirumakki, H. P. Perry, A. Clearfield, S. V. Pingali, P. Thiyagarajan 8:50 32. Synthesis and structures of bis(2dimethylaminoethyl)amine adducts of strontium bis(2,2,6,6-tetramethylheptane3,5-dionate) and their use in the chemical vapor deposition of cubic strontium-doped hafnium dioxides. W. L. Gladfelter, B. Luo, D. Yu, B. E. Kucera, S. A. Campbell 9:10 33. Nanoparticle research at the Air Force Research Laboratory: New develop ments and applications. J. M. Mabry 9:30 34. Acid/base sandwich complexes of trimeric silver(l) pyrazolates. C. S. Palehepitiya Gamage, H. V. R. Dias 9:50 35. Hybrid silica-polymer composites for radiation detection applications. B. Kesanli, S. Dai 10:10 36. Bifunctional mesoporous nanocatalysts by solvent-assisted postgrafting synthesis. T. Asefa, K. K. Sharma 10:30 37. From platinum and [Ge2Se6]4and [GeSe4]4- precursors to hexagonal mesostructured chalcogenides: Detailed investigation of the solution behavior. S. Bag, M. G. Kanatzidis 10:50 38. New tetrazole based energetic materials. T. M. Klapotke, P. Mayer, C. Miro, A. Penger, J. M. Welch 11:10 39. Magnetic dispersions based on ionic liquids: Next generation of magnetic fluids. C. Guerrero-Sanchez, T. Lara-Ceniceros, E. Jimenez-Regalado, M. Rasa, U. S. Schubert 11:30 40. Molecular magnets based on lanthanide ions and the TCNQF 4 radical. N. Lopez, H. Zhao, A. V. Prosvirin, A. Chouai, K. R. Dunbar 11:50 4 1 . Triplet valence states and atomicscale p-n junctions in manganese perovskite oxides from hydrothermal systems. S. Feng, H. Yuan, Z. Shi, Y. Chen, K. Huang, G. Pang, J. Li, Y. Hou 12:10 42. Direct synthesis of monolayerproctected silver nanocrystals: Effect of capping molecules. K. J. Lee, Y. I. Lee, I. K. Shim, B. H. Jun, J. Joung
Section F McCormick Place Lakeside Room E253C, Level 2 Coordination Chemistry: Characterization and Application D. C. Crans and K. J . Franz, J. R. Farrell,
Organizers
Presiding
8:30 43. Application of DFT to charge distri bution and electrochemistry. A. B. P. Lever 8:50 44. Differential polarization of spin and charge density in metal-organic radical complexes. R. J. Fehir Jr., J. K. McCusker 9:10 45. Solution as well as solid NMR studies on 1:1 and 2:1 adducts of silver(l) cyanide with alkanediamine ligands. A. A. Isab, M. I. M. Wazeer, B. A. Al-Mayt 9:30 46. Metalloporphyrins as molecular actuators characterized through allosteric ligation. D. Khvostichenko, R. Boulatov, Q-Z. Yang, J. D. Atkinson 9:50 47. Oxidation of benzylic alcohols in aqueous media with in situ made Cucomplexes. P. J. Figiel, P. Lahtinen, M. Leskelâ, T. Repo 10:10 48. Anion sensing metalloporphyrins. D. P. Cormode, S. S. Murray, A. R. Cowley, P. D. Beer 10:30 49. Evaluation of manganese (III) Schiff base complexes for the copolymerization of carbon dioxide and cyclohexene oxide. E. B. Frantz, D. J. Darensbourg 10:50 50. Facile synthesis of terdentate ligands using click chemistry and the physical properties of the iron(ll), ruthenium(ll) and europium(ll) complexes. A. H. Flood, Y. Li 11:10 5 1 . Influence of ligand modification on the structure and nuclearity of metalladiazamacrocycles and selective encapsulation behavior by a metallamacrocyclic host. R. P. John, D. Moon, K. Lee, M. Park, M. S. Lah 11:30 52. Hydrogen atom transfer reactions of Ru acetylacetonato pyridine-imidazole complexes with large kHlkQ values. A. Wu, J. Masland, J. M. Mayer 11:50 53. Phenanthrenediamide titanium(IV) complexes: Synthesis and reactivity of mixed alkyl, aryl, amido, and imido derivatives. N. A. Ketterer, A. F. Heyduk Section G McCormick Place Lakeside Room E253D, Level 2 Organometallic Catalysts B. T. Donovan-Merkert and D. C. Crans, Organizers T. B. Gunnoe,
Presiding
8:30 54. Synthesis of organoboronic compounds by C-H activation of alkanes and arènes. J. M. Murphy, J. F. Hartwig 8:50 55. Directed C-H functionalization with ruthenium boron analogs of the Shvo hydrogénation catalyst. C. P. Casey, T. B. Clark 9:10 56. Stoichiometric and catalytic activation of carbon-hydrogen bonds using TpRu(L)(NCMe)R (Tp = hydridotris(pyrazolyl)borate; R = alkyl or aryl; L = neutral two-electron donor) complexes: Impact of ancillary ligand "L'. T. B. Gunnoe, N. A. Foley, M. Lail, K. A. Pittard, J. P. Lee, T. Cundari, J. L. Petersen 9:30 57. A combined theoretical and experimental study of CO hydrogénation with Co carbonyl catalysts. R. J . Meyer, J. Rathke, R. J. Klingler 9:50 58. Moving toward olefin cross metathesis involving vinyl halides. M. L. Macnaughtan, M. J. A. Johnson, J. W. Kampf 10:10 59. Ligand steric and electronic effects on catalyst activity in cross-coupling reactions. K. H. Shaughnessy 10:30 Intermission.
10:40 60. Formation of C-N, C-0 and C-S bonds catalyzed by monomeric N-heterocyclic carbene supported Cu complexes with amido, alkoxo, aryloxo and sulfido ligands. T. B. Gunnoe, C. Munro-Leighton, S. A. Delp, E. D. Blue, J. L Petersen 11:00 6 1 . Triazacyclohexane complexes of chromium as catalysts for selective alpha olefin trimerization. R. Kohn, D. Smith, G. Kociok-Kohn, G. Nawn 11:20 62. Insertion copolymerization of olefins with vinyl ethers by Pd(ll) catalysts. S. Luo, R. F. Jordan 11:40 63. Polymerization of 1,3-dienes catalyzed by (iT-allyl)Ni(ll) complexes. A. R. O'Connor, M. Brookhart 12:00 64. Axially chiral 7-membered N-heterocyclic carbenes and their applications. C. C. Scarborough, G. T. Sazama, S. S. Stahl Section H McCormick Place Lakeside Room E255, Level 2 Organometallic Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers F. T. Ladipo,
Presiding
8:30 65. Photochemical route to unusual ferrocenyl containing ligand systems. P. Mathur, A. K. Singh, S. Chatterjee, A. Das, S. M. Mobin 8:50 66. Production of multimeric prostatespecific membrane antigen small molecule radiotracers using a solid-phase 99mTc pre-loading strategy. P. Misra, V. Humblet, N. Pannier, W. Maison, J. Frangioni 9:10 67. Synthesis and reactivity of rhodium compounds with butadienesulfonyl ligands. B. A. Paz-Michel, M. A. Paz-Sandoval 9:30 68. DFT-based discovery of a new binding mode of N 2 0 to metals. K. G. Caulton, H. Fan, A. Walstrom 9:50 69. (2-(Trimethylammonium)ethyl)cyclopentadienyltricarbonylmetalates: Group VI metal zwitterions. P. J. Fischer, Z. R. Herm, B. E. Kucera 10:10 70. Chemistry of iridium complexes and silane compounds. T. Thananatthanachon, J. R. Bleeke, N. P. Rath 10:30 Intermission. 10:50 7 1 . Intramolecular arene coordination in cationic titanium (IV) and (II) complexes: /Ansa-metallocene analogs of the type [Cp-arene]TiX 2 + . E. Otten, A. Meetsma, B. Hessen 11:10 72. Epimerization of non-racemic chiral zirconocenes. R. M. Buck, R. F. Jordan 11:30 73. Selective bromination of platinum complexes of corannulene, phenanthrene and naphthalene via Pt(IV) intermediates. H. B. Lee, P. R. Sharp 11:50 74. Synthesis and reactivity of ruthenium carbynes. S. R. Caskey, M. J. A. Johnson, J. W. Kampf 12:10 75. Synthesis of functional siloxane oligomers on solid phase. Μ. Ν. Missaghi, M. C. Kung, H. H. Kung Section I McCormick Place Lakeside Room E256, Level 2 Bioinorganic: DNA and RNA D. C. Crans,
Organizer
J. C. Dabrowiak, Organizer,
Presiding
8:30 76. Mechanism of guanine binding to dirhodium tetracarboxylate anticancer complexes. D. V. Deubel, H. Chifotides
Please refrain from using cellular telephones and cameras during technical sessions.
INOR
8:50 77. Role of carbonate in the mechanism of action of platinum anticancer drugs. J. C. Dabrowiak, C. R. Centerwall, A. Di Pasqua, J. Goodisman, R. L. Dubowy, Β. Β. Toms 9:10 78. Concurrent pathways of DNA oxida tion and hydrolysis by chromium(V) com plexes. L. Maurmann, R. M. Cordoba, R. N. Bose, L. Joudah 9:30 79. Determination of intermediate and mechanism of DNA cleavage caused by dinuclear copper (II) complexes. Q. Zhu, S. Thyagarajan, S. E. Rokita, K. D. Karlin, N. V. Blough 9:50 80. Long range charge transfer through DNA. F. Shao, K. Augustyn, J. K. Barton 10:10 8 1 . Photobinding and photocleavage studies of mixed-metal supramolecules. D. F. Zigler, J. Brown, A. J. Prussin, B. S. J. Winkel, K. J. Brewer 10:30 82. Synthesis, characterization and biological activity of the stereoisomers of a redox active Ruthenium polypyridyl com plex. A. Yadav, F. M. MacDonnell 10:50 83. Synthesis, characterization, and DNA binding of novel intercalative Cr(diimine) 3 3+ complexes capable of H-bonding to DNA. D. C. Sibley, S. C. Keane, C. J. Priedemann, E. P. Bridges, J. F. Wheeler, N. A. P. Kane-Maguire 11:10 84. Contributions of methyl groups on the stability of DNA triplexes and G-quadruplexes. C. M. Olsen, I. Khutsishvili, H-T. Lee, R. Shikiya, A. M. Soto, L. A. Marky 11:30 85. The use of single walled carbon nanotubes for detection of DNA hybridiza tion: Kinetics, thermodynamics, and appli cations. E. S. Jeng, M. S. Strano 11:50 86. Tracing the metal specificity of a family of Co 2+ -dependent DNAzymes: Structure/function relationships and impli cations for DNA/RNAzyme biosensors and therapeutics. K. E. Nelson, D. Mazumdar, P. J. Bruesehoff, Y. Lu 12:10 87. Unusual periphery modified chlorin molecules and their potential as phototherapeutic agents for hypoxic environ ments. T. Koepke, M. Pink, J. M. Zaleski Nanotechnology and the Environment: Focus on Green Nanotechnology Green Synthesis of Inorganic Nanomaterials Sponsored by l&EC, Cosponsored with INOR SUNDAY AFTERNOON
4:45 94. Nanoporous semiconductors for photocatalytic applications. P. Feng 5:15 95. Development of H2 evolution sites for overall water splitting on particulate photocatalysts. K. Domen
McCormick Place Lakeside Room E253A, Level 2 Nanoscience: Characterization and Application
Section Β
B. T. Donovan-Merkert and D. C. Crans, Organizers
McCormick Place East RoomE271B, Level 2 F. Albert Cotton Award in Synthetic Inorganic Chemistry: Symposium in Honor of Christopher C. Cummins D. G. Nocera, Organizer,
Section D
Presiding
1:30 96. Syntheses and structures of lowcoordinate and multiply-bonded M-M complexes. Y-C. Tsai, Y-M. Lin, J-S. K. Yu, J-K. Hwang 1:55 97. Carbides, carbynes and carbenes: Reaction products of Ru-based olefin metathesis catalysts with vinyl halides and other troublesome substrates. M. J. À. Johnson, S. R. Caskey, M. L. Macnaughtan, M. H. Stewart, J. W. Kampf 2:20 98. Synthesis of and asymmetric catalysis with titanium amino-alcohol complexes. A. R.Johnson 2:45 99. N-Substituted imidazolyl disulfides and diselenides: Coordination chemistry and reactivity. J. S. Figueroa, G. Parkin 3:10 100. Mechanistic studies pertinent to intermolecular CX (X = H, O, F, N) bond activation reactions. D. J. Mindiola, B. C. Bailey, A. R. Fout, J. C. Huffman 3:35 101. Titanium metal-ligand multiple bonds in catalytic synthesis of nitrogen heterocycles. A. L. Odom 4:00 102. Catalysis with iron: The importance of coordination chemistry. P. J. Chirik 4:25 103. Small molecule activation chemistry with low valent iron. J. C. Peters, N. P. Mankad, M. T. Whited, C. Saouma 4:50 104. Small molecule activation at uranium complexes leading to charge-separation and chemical transformation. O. P. Lam, P. Feng, I. Castro-Rodriguez, K. Meyer Section C McCormick Place East RoomE271A, Level 2
T. A. Schmedake,
Presiding
1:30 111. Biofunctional subwavelength optical waveguides for chemical detection. D. J. Sirbuly, O. Bakajin, A. Noy 1:50 112. Mass limited gradients: Applica tions in protein crystallization. J. Barton, L. Wang, T. W. Odom 2:10 113. Tuning of luminescence intensity of manganese doped cadmium sulfide quantum dots by controlling surface passi vation. S. K. Sabui, S. Kar, S. Santra 2:30 114. Monodisperse, mesoporous silica spheres as a sensor substrate. T. A. Schmedake, R. B. Soriano, A. M.Jakob 2:50 115. Incorporation of niobium into cage-like silica mesostructures. I. Nowak, M. Jaroniec 3:10 116. Ratiometric quantum dot chemosensors based on modulation of Fluores cence Resonance Energy Transfer. R. C. Somers, P. T. Snee, A. B. Greytak, M. G. Bawendi, D. G. Nocera 3:30 Intermission. 3:40 117. Optical properties of nanoparticles with hollow structures: A single nanoparticle spectroscopy study. M. Hu, J. Chen, Y. Xia, G. V. Hartland, M. Marquez 4:00 118. Long-range electronic energy transfer in quantum dot nanocomposites: Toward lowering the optical gain threshold of quantum dots. M. Emara, S. Burya, P. G. Van Patten 4:20 119. High-efficiency carrier multiplication and ultrafast charge separation in semi conductor nanocrystals. R. D. Schaller, M. Sykora, S. Jeong, V. I. Klimov 4:40 120. All monolayers are not created equal: Functionlized porous silicon stability studies. L A. Porter Jr. 5:00 121. A novel silver nanostructure with fluorescence and giant Raman enhance ment. J. Zheng, Y. Ding, B. Tian, Z. Wang, C. M. Lieber, X. Zhuang Section Ε
Section A McCormick Place Lakeside Room E270, Level 2
Nanoscale Inorganic Catalysis Understanding Nanoscale Catalysis via Theoretical Modeling and Modern Surface Science Techniques
Coordination Chemistry: Synthesis
Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST
R. E. Schaak and D. A. Chen,
D. C. Crans,
P. Balbuena, Organizer, T. D. Tilley, C. J. Chang,
Organizer Presiding
1:30 88. Bioinspired energy conversion schemes. A. L. Moore, G. F. Moore, M. Hambourger, G. Kodis, M. Gervaldo, P. A. Liddell, D. Gust, T. A. Moore 2:00 89. Biomimetic approaches to artificial photosynthesis. L. Hammarstrom, S. Styring 2:30 90. Light driven generation of hydrogen from water using molecular photochemical devices based on platinum terpyridyl and diimine complexes as chromophores. P. Du, J. Zhang, P. R. Jarosz, J. Schneider, S. Chakraborty, R. Eisenberg 3:00 9 1 . Photoinduced dihydrogen produc tion catalyzed by cobalt(ll) complexes in acidic solutions. J. L. Dempsey, H. B. Gray, J . R. Winkler 3:30 Intermission. 3:45 92. Photochemical and radiolytic pro duction of organic hydride donor with Ru(ll) complexes with an NAD + model ligand. E. Fujita, D. Polyansky, D. Cabelli, J. T. Muckerman, K. Tanaka 4:15 93. Designing strong red-absorbing photosensitizers for use in dye sensitized sqlar cells. A. Kukrek, D. Wang, B. Zhou, Y. Hou, R. Zong, R. P. Thummel
Organizers
Presiding
2:00 105. High-resolution scanning tunneling microscopy studies of surface reactions on rutile TiO 2 (110). F. Besenbacher 2:30 106. Surface chemistry of gold nanostructures deposited on oxides: Oxidespecific 0 2 interactions with supported gold. S. Linic, S. Laursen 3:00 107. Catalytic CO oxidation at 70 Κ on an extended Au/Ni surface alloy. S. T. Ceyer, D. L. Lahr 3:30 Intermission. 3:45 108. How do we achieve nanocatalysis by design? A. M. Chaka 4:15 109. Metal clusters supported on TiO 2 (110): Growth, sintering and chemical activity. D. A. Chen, J. B. Park 4:45 110. Structure and reactivity of vana dium oxide thin film surfaces. M. Li, W. Gao, E. I. Altman
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogranV.
McCormick Place Lakeside Room E253B, Level 2
D. C. Duncan,
Organizer Presiding
1:30 122. Recent advances in the examina tion of Pt/Au metallophilic interactions. C. S. Angle, M. Ghanzi, K. J. Woolard, D. K. Zhong, J. S. Alexander, L. H. Doerrer 1:50 123. Synthesis and characterization of transition metal complexes of the sterically bulky di(tert-butyl)amide ligand. C. W. Spicer, G. R. Potratz, W. M. Reiff, G. S. Girolami 2:10 124. New observations for an 18 th century anion: The lability of ferrocyanide in non-protic solvents. G. M. Chiarella, D. Y. Melgarejo, S. A. Koch 2:30 125. Nickel(ll) homoleptic fluorinated phenolate compounds and their ligand fields. M. V. Childress, B. Zheng, L. H. Doerrer 2:50 126. Novel oligomeric antennae for luminescent lanthanide cations. D. S. Oxley, J. E. Copenhafer, H. M. Edenbom, T. Y. Meyer, S. Petoud 3:10 127. Molecular pairs containing quadruply bonded dimolybdenum units linked by unsubstituted oxamidate and dithiooxamidate ligands. Z. Li, C. Y. Liu, C. A. Murillo, F. A. Cotton 3:30 128. Arylimido functionalization of polyoxotungstates: New redox-active components for supramolecular construc tion. J. C. Duhacek, D. C. Duncan
3:50 129. Cadmium, lead and ruthenium complexes of new chelating anthraquinone ligands. A. G. Sykes, M. Kadarkaraisamy, C. C. Soh, D. Mukherjee 4:10 130. Withdrawn. 4:30 131. Copper(l) complexes of tripodal amine-trithioether ligands. I. Castillo, R. Huerta 4:50 132. Synthesis and characterization of quadruply bonded technetium(lll) dimers. F. Poineau, A. P. Sattelberger, K. Czerwinski 5:10 133. Convergent syntheses of metalloporphyrin-core dendrimers. X. Wang, L. Vigderman, D. W. Silverstein Section F McCormick Place Lakeside Room E253C, Level 2 Structural, Functional and Biomimetic Modeling in Bioinorganic Chemistry D. C. Crans and K. J. Franz, D. Rabinovich,
Organizers
Presiding
1:30 134. The reactions of copper(l) com plexes with NO/02. D. Subramanian, S. C. Puiu, D-H. Lee, B. Mondai, Κ. D. Karlin 1:50 135. Modeling NO reduction activity of nitric oxide reductase and cytochrome c oxidase. J. Wang, S. C. Puiu, K. D. Karlin 2:10 136. Polynuclear copper(ll) and mixedvalence copper complexes: Progress toward models of the C u z catalytic cluster in nitrous oxide reductase. R. P. Houser, L. Yang, Z. Wang 2:30 137. Trinuclear copper complexes of cryptands as biomimetic models for multicopper oxidases. Y. Funahashi, K. Fukui, T. Ozawa, H. Masuda 2:50 138. Comparison of copper binding characteristics of a His-Gly repeat dinucleating pentadecapeptide and a mononucleating tridecapeptide designed as copper binding mimics for the active sites of oxyhemocyanin and oxytyrosinase. D. A. Rockcliffe, A. Cammers, A. Murali, W. K. Russell, V. J. DeRose 3:10 139. Probing structure and reactivity of Cu(l) bound by histidyl-histidine. R. A. Himes, G. Y. Park, N. J. Blackburn, K. D. Karlin 3:30 140. Formation of organized peptide assemblies through metal coordination. M. V. Tsurkan, M. Y. Ogawa 3:50 141. Copper(l) bis(mercaptoimidazolyl)methane complexes as methanobactin analogs. L. A. Graham, K. A. Kreisel, G. P. A. Yap, D. Rabinovich 4:10 142. Sterically bulky tris(triazolyl)borate ligands as water-soluble analogs of tris(pyrazolyl)borate. F. E. Jernigan III, N. A. Sieracki, M. T. Taylor, A. S. Jenkins, S. E. Engel, B. W. Rowe, F. A. Jove, G. P. A. Yap, E. T. PaDish, G. M. Ferrence 4:30 143. Triangular Cu^-pyrazolato com plexes and trigonal prismatic Cu" 6 -pyrazolato cages: Structural and electrochemi cal study. M. Rivera-Carrillo, G. Mezei, R. G. Raptis 4:50 144. Ternary complexes of copper(ll) with potential pharmacological applica tions: Syntheses and physicochemical properties. M. S. Shongwe, Z. Afrasiabi, L. K. Al-Moqbali, D. Matoga, J. Szklarzewicz, M. Mikuriya, E. Sinn Section G McCormick Place Lakeside Room E253D, Level 2 Spectroscopy in Inorganic Chemistry D. C. Crans and S. L. Michel, J. Telser,
Organizers
Presiding
1:30 Introductory Remarks. 1:50 145. NMR Spectroscopy of paramag netic triazacyclohexane complexes. R. Kohn, M. Haute, G. Nawn, G. Kociok-Kohn
TECH-67
TECHNICAL PROGRAM
INOR 2:10 146. EPR as a measure of hydrogen bonding in low-spin heme-thiolate proteins. S. Pazicni, A. Dey, R. C. Linck, E. I. Solomon, J. N. Burstyn 2:30 147. Photoinduced carbon monoxide and nitric oxide migration in synthetic heme-copper complex systems. H. R. Lucas, J. P. Toscano, G. J. Meyer, K. D. Karlin 2:50 148. Electronic structure characteriza tion of dinitrogen-reducing molybdenum triamidoamine complexes by EPR and ENDOR studies. R. L. McNaughton, J. M. Chin, W. W. Weare, R. R. Schrock, Β. Μ. Hoffman 3:10 149. Electron transfer and protein dynamics in cytochrome c. J. S. Magyar, J. R. Winkler, H. B. Gray 3:30 150. Matrix isolation studies of photo chemical reactions of 5-membered rings with chromyl chloride. M. D. Hoops, B. S. Ault 3:50 151. Wavelength dependent photofrag mentation patterns of tris(2,2,6,6-tetramethyl-3,5-heptanedionato)l_n (III) (Ln = Eu, Tb, Gd) in a molecular beam. F. P. Ow, M. T. Berry, P. S. May, J. I. Zink 4:10 152. Spectroscopic characterization of diazo-oxo chlorin photochemical intermedi ates: Elucidating diradical reaction path ways. D. F. Dye, T. Koepke, J. M. Zaleski 4:30 153. V-51 solid state NMR spectros copy of polyoxoanionic solids. W. Huang, L. C. Francesconi, T. Polenova 4:50 154. P-31 solid state NMR spectros copy as a probe of local environments in paramagnetic rare earths polyoxoanionic solids. W. Huang, C. Zhang, R. C. Howell, B. A. Gee, L. C. Francesconi, T. Polenova 5:10 155. Nuclear resonance vibrational spectroscopy: A novel technique to study heme iron vibrational modes and the effect of binding small molecules. N. J. Silvernail, W. R. Scheldt, Β. Μ. Leu, A. Barabanschikov, J. T. Sage, J. Zhao, W. Sturhahn, E. E. Alp 5:30 156. Energy transfer in multinuclear Re/Fe assemblies. T. E. Knight, J. K. McCusker Section H McCormick Place Lakeside Room E255, Level 2 Applications of Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers R. Waterman,
Presiding
1:30 157. Enantioselective iridium-catalyzed allylic amination with ammonia and ammo nia surrogates. M. J. Pouy, J. F. Hartwig 1:50 158. Zr imido mediated cyclohydroamination of alkenes. R. K. Thomson, L. L. Schafer 2:10 159. Advances in titanium catalyzed hydrohydrazination. S. Banerjee, E. Barnea, A. L. Odom 2:30 160. Mechanistic studies of Cu-catalyzed oxidative coupling reactions between aryl boronic acids and heteroatom nucleophiles. A. E. King, T. C. Brunold, S. S. Stahl 2:50 161. Catalytic P-P and P-E bond forma tion via zirconium-mediated phosphine dehydrocoupling. R. Waterman 3:10 Intermission. 3:15 162. Stereospecific ring opening me tathesis polymerization of 3-Methyl-3phenylcylopropene using well-defined molybdenum alkylidene catalysts. R. Singh, R. R. Schrock 3:35 163. Remarkable ancillary ligand effect on ethylene polymerization behavior of titanium(IV) precatalysts. R. Eaves, A. Zazybin, J. An, S. R. Parkin, F. T. Ladipo 3:55 164. Host-Guest chemistry of a-, b-, and g-cyclodextrins with antitumor Cp2MCI2 (M = Nb, V, Mo) complexes: Solution and solid state characterization. E. Meléndez, A. Morales 4:15 165. Synthesis, characterization, and reactivity of Iridium(lll) dithiolate complexes. R. R. Ketcham, S. R. Parkin, F. T. Ladipo
68-TECH
4:35 166. Visible light photochromism of bis(ferrocenylethynyl)ethenes to switch electronic communication between ferrocene sites. H. Nishihara, R. Sakamoto, S. Kume 4:55 167. New bis(fluoro-ponytailed) bipyridine ligands for the Pd-catalyzed Hecktype reactions under fluorous biphasic and thermomorphic conditions. N. Lu, Y-C. Lin, S-C. Chen, W-S. Chen
S U N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Applications of Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers
Section I McCormick Place Lakeside Room E256, Level 2 Solid State Chemistry D. C. Crans,
Organizer
J. D. Corbett,
Presiding
1:30 168. Crystal growth of lanthanidecontaining iridates and palladates from hydroxide fluxes. S. J. Mugavero III, M. D. Smith, H-C. zur Loye 1:50 169. RE7Co4lnGe12 (Re= Dy, Ho, Yb), Dy4ColnGe4 & Yb3AuGe2ln3 flux grown quaternary intermetallic phases. M. Chondroudi, M. G. Kanatzidis 2:10 170. Quantum dot light emitting diodes using sputtered resistive inorganic charge transport layers. J-M. Caruge, J. E. Halpert, V. Wood, M. G. Bawendi, V. Bulovic 2:30 171. Negative thermal expansion in cyanide-based framework materials and the impact of pressure. K. W. Chapman, P. J. Chupas, J. B. Parise 2:50 172. How to control the stress optic response of optical glass. J. W. Zwanziger 3:10 173. Synthesis and characterization of technetium oxides. Ε. Ε. Rodriguez, F. Poineau, A. P. Sattelberger, A. Llobet, K. Czerwinski, A. K. Cheetham 3:30 174. Synthesis of La2KNb06: A novel lanthanide containing niobate. I. V. Puzdrjakova, M. D. Smith, H-C. zur Loye 3:50 175. Synthesis, characterization and solid state reactions of the layered solids composed of {V4012} and {M(C5H5N)4}(M = Co, Cu) motifs. R. C. Nome, R. J. Doedens, M. I. Khan 4:10 176. Decomposition studies of thermitebased energetic materials using MALDITOF mass spectrometry. A. E. Stiegman, M. L. Mileham, M. P. Kramer 4:30 177. Three new intermetallics in the Ca-Au-ln system: Structural diversity controlled by valence electron counts. Q. Lin, J. D. Corbett 4:50 178. Coordination-driven self-assembly based on polyfunctional ligands derived from hydrogen-bonded-directed syntheses in the solid state. D-K. Bucar, T. D. Hamilton, L. R. MacGillivray 5:10 179. Crystal growth and characteriza tion of novel lanthanide containing platinates. T. J. Hansen, S. J. Mugavero III, M. D. Smith, H-C. zur Loye Nanotechnology and the Environment: Focus on Green Nanotechnology Green Synthesis of Inorganic Nanomaterials Sponsored by l&EC, Cosponsored with INOR
7:00-10:00 180. The dielectric profiles of three polarized hybrids modified with tetraethoxysilicate. C. Li, L. Hu 181. Synthesis and reactivity of titanium alkylidene-fluoride complex: A product resulting from a C-H/C-F activation reac tion. D. L. Miller, A. R. Fout, B. C. Bailey, J. C. Huffman, D. J. Mindiola 182. Synthesis of 7- and 8-membered lac tones via ring-closing metathesis. E. Pentzer, M. J. McCullagh, G. C. Schatz, S. T. Nguyen 183. Synthesis, structures, and luminescence and cytotoxic properties of rhenium(l) alkylcarbonato complexes. S. K. Pramanik, D. A. Hill, A. L. Williams, M. K. Mbagu, D. K. Orsa, G. K. Haynes, M. O. Iwunze, G. E. Greco, D. M. Ho, J. A. Krause, S. K. Mandai 184. Theoretical analysis of the first linear iron amide complex. C. Flener, G. S. Girolami 185. Toxicity and QSAR studies of a series of triorganotin 2,2,3,3-tetramethylcyclopropanecarboxylates. G. Eng, X. Song, A. Zapata, O. Atchade 186. Transition metal-catalyzed hydrostannations: Bu3SnCI/PMHS/KF (or Bu3SnF/ PMHS) as in situ organotin hydride source. B. Ghosh, W. P. Gallagher, A. L. Szymanski, J. L. Weeks, R. E. Maleczka Jr. 187. Mechanism and applications of lr-catalyzed C-H activation/borylation of indoles. S. Paul, R. E. Maleczka Jr., M. R. Smith III 188. Syntheses and catalytic activity of tris boryl iridium complexes. G. A. Chotana, R. E. Maleczka Jr., M. R. Smith III 189. Synthesis and characterization of functionalized cyclopentadienyl ligands and their titanocene dichloride derivatives. L. M. Gao, E. Melendez 190. Synthesis and characterization of group 5 pentahaptocyclopentadienyl-transition metal compounds. W. Tikkanen, J. B. Lepe, D. T. Barrios, T. C. Kwong 191. Heterogeneous and homogeneous Mo catalysts with silanol based ligands for synthetic applications of alkyne metathe sis. H. M. Cho, H. Weissman, K. Plunkett, J. S. Moore 192. Hydroboration of allylic alcohols and other unsaturated alcohols. V. A. Kallepalli, R. E. Maleczka Jr., M. R. Smith III Section Β Hyatt Regency Chicago Riverside Center The Bioinorganic Chemistry Relating to Enzymes and Proteins D. C. Crans and S. L. Michel,
Organizers
7:00-10:00
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193. Structrual and functional studies of nickel superoxide dismutase. R. W. Herbst, P. A. Bryngelson, M. J. Maroney 194. Acid-induced conformational changes in calcium-depleted horseradish peroxidase. J. A. Pfammatter, S. M. Tremain 195. BHK-21 cells transfected with full length human transferrin: Expression and charac terization. D. Acevedo-Acevedo, M. Martinez-Torres, E. Meléndez 196. Central ligand X of the nitrogenase FeMo-cofactor: Revealing recipe from theoretical chemistry. V. Pelmenschikov, D. A. Case, L. Noodleman
197. Comparison of the formal reduction potential of acellular Lumbricus terrestris hemoglobin and Arenicola marina hemoglobin to intracellular human hemoglobin. S. C. Dorman, S. L. Zito, J. P. Harrington 198. Copper complexes of sparfloxacin as antiproliferative agents against hormone independent breast cancer. D. Shingnapurkar, S. Padhye, Z. Afrasiabi, E. Sinn, F. Ahmed, F. Sarkar 199. Developing a multi-lateral approach to piece together a mechanism for the multiheme enzyme hydroxylamine oxidoreductase. J. Kostera, A. A. Pacheco 200. Effect of surface mutations on heme ligation in cytochrome c peroxidase. N. M. Pearl, L. B. Vitello, J. E. Erman 201. Gd(lUnconjugates of ribonuclease A for in vivo transport studies. M. J. Allen, T. J. Rutkoski, W. F. Block, L L. Kiessling, R. T. Raines 202. Heme regulates mammalian BK channels. R. Mark, M. Pace, J. Patterson 203. Hydrothermal biochemistry: From formaldehyde to oligopeptides. S. Feng, G. Tian, C. He, H. Yuan, Y. Wang, Y. Wang, L. Han 204. Important HisE7 in the formation of sulhemeproteins. Ε. Μ. Roman-Morales, J. Lopez-Garriga 205. Laser photoinitiated nitrosylation of N. europaea hydroxylamine oxidoreductase in various stages of reduction: Mechanistic implications for the enzyme. A. A. Pacheco, M. Z. Cabail 206. Probing halogenase and dehalogenase activities of sol-gel encapsulated peroxi dases. H. M. Gamble, M. A. Matthews, K. R. Hansen, T. E. Elgren 207. Purification and characterization of perchlorate reductase from Dechloromonas aromatica RCB. J. L. DuBois, J. M. Sexton 208. Rates of iron release from transferrin by low concentrations of phosphonocarboxylate ligands. R. Sharma, W. R. Harris 209. Reaction of N. europaea Cytochrome c554 with nitric oxide: A kinetic study using laser photoinitiated NO. M. D. Youngblut, A. A. Pacheco 210. Copper conjugates of Schiff bases of 3,5-di-tert-butyl phenols as cyclooxygenase enzyme inhibitors for anticancer activ ity. A. P. Zambre, S. Adsule, V. M. Kulkarni, F. Sarkar, E. Sinn, S. Padhye 211. The characterization of the membranebound redox-active decaheme OmcA from S. oneidensis. G. Bodemer, A. A. Pacheco, D. Saffarini Section C Hyatt Regency Chicago Riverside Center Structural, Functional and Biomimetic Modeling in Bioinorganic Chemistry D. C. Crans and K. J. Franz,
Organizers
7:00-10:00 212. Straightforward synthesis of unsymmetric compartmental "end-off' Schiff-base ligands and their homo- and heterobimetallic metal complexes. A. Roth, W. Plass 213. The synthesis and characterization of a novel water-soluble porphyrin series, H2TPPPipOH. J. E. Bradshaw, A. M. Berry, R. J. Hickerson, P. Kerrigan, D. J. Haley, T. Sirivanta, S. Young, M. F. Roberto 214. Designed coiled coil peptides that bind Cd(ll) and Pb(ll) site selectively. D. Touw, M. Matzapetakis, T. L. Stemmler, V. L. Pecoraro 215. Design of a thiolate rich metal binding site in a peptidic framework. M. Luczkowski, B. Demeler, V. L. Pecoraro 216. Potential insulin enhancers: Phosphatase inhibiting vanadium complexes. L. M. Manus, B. A. Greiner, M. A. Jones, C. C. McLauchlan 217. A trinuclear Ni(ll) enediolate complex: Relevance to the chemistry of acireductone dioxygenase. K. Rudzka, A. M. Arif, L. M. Berreau 218. Chemical modeling of alcohol metabo lism using mononuclear copper II com plexes. T. N. Banaszek, L. Wang, E. Sinn
INOR
219. Copper complexes of a new family of alkylguanidine derivatives of 2-(aminomethyl)pyridine and 2-methyl-2-(2-pyridinyl)-1,3-propanediamine. U. Pal Chaudhuri, L R. Whiteaker, R. P. Houser 220. Cobalt(ll) substitution of zinc(ll)-model complexes and metalloproteins toward inhibitor design. F. E. Jacobsen, R. M. Breece, W. K. Myers, D. L. Tierney, S. M. Cohen 221. Lipoxygenase model complex. J. H. Volkman, K. M. Nicholas 222. Photoproperties of de novo designed metalloproteins with variant hydrophobic cores. F. Xie, M. Y. Ogawa 223. Theoretical study of the active site and mechanism of β-phosphoglucomutase. C. E. Webster Section D Hyatt Regency Chicago Riverside Center Coordination Chemistry: Characterization and Application D. C. Crans and K. J . Franz,
Organizers
7:00-10:00 224. Preparation, characterization, asymmet ric catalysis, and molecular recognition of chiral substrates with enantiomerically pure phthalocyanine dimers. V. N. Nemykin, R. Subbotin, S. Sharma, A. Y. Koposov 225. Side-by-side iron phthalocyanine dimer. W. He, M. Lieberman 226. Tuning the redox potentials and reactivi ties of two-electron platinum reagents using modified pincer ligands. M. Ronnie, S. Tastan, J. A. Krause, W. B. Connick 227. Use of symmetry to clarify solution state structures of zinc triad metal complexes. D. C. Bebout, B. J. Carra, R. D. Pike 228. Vanadium complexes possessing N202S2 based ligands as highly active pro-catalysts for the homo-polymerization of ethylene and co-polymerization of ethylene/1 -hexene. D. M. Homden, C. Redshaw, D. L. Hughes 229. Synthesis, structures, and magnetic properties of tetranuclear, tetradecanuclear, and polynuclear azido/acetate bridged copper(ll) complexes of macrocyclic and noncyclic ligands. S. S. Tandon, S. D. Bunge, L. K. Thompson 230. Synthesis, X-ray diffraction, and photoluminescence properties of several lanthanide tetracyanoplatinates. R. Sykora, Z. Assefa, B. Maynard 231. Systematic synthesis of dithiolenebridged complexes: Synthesis and charac terization of transition metal complexes of 1,3,5,7-tetrathia-s-indacene-2,6-dione. K. Arumugam, J. P. Donahue 232. Temperature dependence of the crystal structure of Cu(acac) 2 4,4'bipy. Ε. Β. Flint, G. M. Ferrence, B. A. Howe, P. J. Morrison, D. C. Swenson 233. Trans-dibenzotetraaza[14]annulene macrocycles. R. P. Hotz, E. Sinn 234. Synthesis and spectrophotometric analy sis of nanoscale structural motifs. D. K. Bediako, D. A. Vander Griend 235. Synthesis and structure of a self-as sembled platinum(ll) molecular square incorporating four fluxional thiacrown ligands. G. J. Grant, D. E. Janzen, K. N. Patel 236. Synthesis of Gd(lll) labeled cyclodextrin complexes via click chemistry. Y. Song, D. Ballweg, T. Meade 237. Synthesis, crystal structure and lumines cence property of a novel 4f-3d heterometallic 2-D coordination polymers. Y. X. Chi, S. Y. Niu, J. Jin
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
238. Synthesis, photophysical characterization and DFT calculations of pyridyl-carotenoid ligands coordinated to rhenium(l) and platinum(ll). A. J. F. Cruz, K. Siam, M. E. Islam, R. Kirgan, C. E. Moore, D. P. Rillema 239. Withdrawn. 240. Synthesis and characterization of molybdenum(VI) imido complexes with salicylidene-2-aminophenol. L. A. Arizpe, M. Minelli, Z. Hu, I. A. Guzei 241. Synthesis and photophysics of platinum(ll) complexes bearing acetylenic terpyridines. M. L. Muro, F. N. Castellano 242. Synthesis and crystal structure of 2,2,binaphthyl crown ether complex: [K(BN20C6)]2[Pd(i-mnt)2]. T. Lan, C. Li, J. Dou, D. Li, D. Wang 243. Solution phase behavior of Ph2PCH2CH2P(0)Ph2 with lanthanide(lll) and late transition metal ions using Electrospray Ionization Mass Spectroscopy. J. Gilje, D. S. Amenta, M. Moyer, T. N. Gallaher 244. Squarato-bridged nickel(ll) and copper(ll) complexes. S. S. Massoud, F. A. Mautner, R. Vicente, K. T. Broussard, K. N. Landry 245. Structures and photophysical properties of platinum(ll) biphenyl phenanthroline complexes. W. Huang, K. Siam, T. Nguyen, R. Kirgan, C. E. Moore, D. P. Rillema 246. Orthometallated thiacrown complexes of Pt" and Pd": Electronic structure insights through DFT calculations, electronic spec troscopy, electrochemistry, and X-ray crystal structures. D. E. Janzen, D. A. da Silva Filho, L F. Mehne, D. G. VanDerveer, J-L Brédas, G. J. Grant 247. Polyelectrochromic Re(l) and Pt(ll) polymers from pyridine/thiophene hybrid ligands. J. R. Farrell, D. P. Lavoie, R. T. Pennell, C. J. Ziegler, J. L Shaw 248. Quantification of small molecule and peptide-modified intracellular MRI contrast agents. P. J. Endres, K. W. Macrenaris, T. J. Meade 249. Reduction of ruthenium(lll) complexes to promote reaction with proteins. S. C. Gibson, Κ. Μ. Williams 250. Self-assembly of Co(ll)-meso-mono-4(3)pyridyl-tri-phenyl porphyrins in sublimed layers: Interaction with nitrogen dioxide and N 0 2 gas sensing properties. T. S. Kurtikyan, A. A. Hovhannisyan, H. M. Nazaryan, R. K. Ghazaryan, J. A. Goodwin 251. Metal-metal interactions in ferrocenyldiketonate titanium complexes. L. T. Dulatas, P. V. Kamat, B. C. Noll, S. N. Brown 252. Metal-site controlled arene coordination in heterobimetallic Bi-Rh pyrene complex. B. Li, E. V. Dikarev, A. Y. Rogachev, M. A. Petrukhina 253. Complexes with triaminoguanidine ligands as building blocks for magnetic molecules and coordination polymers. A. Zharkouskaya, A. Ion, Ε. Τ. Spielberg, J. Bauer, A. Roth, A. Buchholz, W. Plass 254. Luminescent N-heterocyclic carbene complexes of silver(l) and gold(l). A. F. Samin, V. J. Catalano 255. Engineering discrete coordination units by organic coupling reactions. S. Han, R. Hopson, B. Luisi, Z. Ma, B. Moulton 256. Interactions of transition metals with cysteine-containing peptides. Y. Ahmadibeni, K. Parang 257. Lead-transition metal heterometallic β-diketonates. H. Zhang, B. Li, L. Huynh, A. Schaffer, E. V. Dikarev 258. A zinc-activated MRI contrast agent. J. L. Major, T. J. Meade 259. Structural and photochemical relationship of ZnL: A fluorescent sensor of nitro com pounds. M. E. Germain, M. J. Knapp 260. Biologically important compounds: Syn thesis of thiolate, arylcarboxylate and amino carboxylate complexes of manga nese. A. Rahman, D. Powell, A. Tran, J. Choi 261. Complexation and catalytic studies using Schiff base ligands. A. L. Wadler, C. G. Hamaker 262. Copper (II) complexes of novel octadentate ligands: DFT and experimental inter pretations. P. Thangarasu, J. Cruz, S. Bernes, R. Alvarez-ldaboy
263. Copper containing surfactants: Synthe sis, characterization and LangmuirBlodgett film formation. J. Driscoll, C. N. Verani 264. Crystal-engineering studies of coordina tion polymers and a molecular-looped complex containing dipyridyl-amide ligands. B-C. Tzeng 265. Design and synthesis of an interweaving MOF possessing Pt304-net constructed from metal-coordination-supported organic ligand. D. Sun, H-C. Zhou 266. Development of oxovanadium biomimetic oxidation catalysts as asymmetric oxi dants. C. J. Schneider, J. W. Kampf, V. L. Pecoraro 267. Effect of pH on the excited state proper ties of two ruthenium complexes. A. Baba, S. Timm, A. Jackson 268. Electronic dissymmetry in 1,3-propanediolate complexes of bis(diketonato)titanium(IV). L Zakko, K. L Hull, B. C. Noll, S. N. Brown 269. Interaction of hydrotris(3,5-methylphenylpyazole-1-yl)borate anion with metal ions: Structural and magnetic studies of copper (II) complexes. H. He, M. Bremer, A. Caruso 270. Synthesis and crystal structure of a 3-D trinuclear manganese complex: [Mn3(OOCCH3)4(py)8](CI04)2. H. Li, J. Dou, D. Li, D. Wang 271. Syntheses and crystal structures of two 1,3-Diamino-2-propanol Schiff-base tetra nuclear nickel complexes: [Ni4(L1)2(CH30)2(CH30H)2] . 3CH30H and [Ni4(L2)2(CH30)2(CH30H)2]. H. Fu, J. Dou, D. Li, D. Wang Section Ε Hyatt Regency Chicago Riverside Center Coordination Chemistry: Synthesis D. C. Crans,
Organizer
7:00-10:00 272. Trans-P, Ρ -diphenyl-1,4-diphosphacyclohexane (dpdpc), a rigid cyclic diphosphine: The crystal structure of [Cp*RhCI2]2(dpdpc). T. S. Morey, M. L. Helm 273. Coordination polymers and networks of P-N cage ligands with Cu(l). R. D. Sommer, B. C. Noll 274. Structures of double stranded mono nuclear Fe(ll), Co(ll), Ni(ll), Cu(ll) and Zn(ll) complexes of (R,R)- 2-[3N-iminosalicylic acid] cyclohexylamine. A. Lalehzari, C. J. Levy 275. Controlled condensation of solvated molybdenum clusters via direct comproportionation reactions. S. C. Haefner, L. T. McDonald, T. R. Pribusauskas 276. Coordination chemistry analogs of Troger's base. A. Craig, D. L. Jameson 277. Different and unusual coordination modes of bis(imine-pyridine) ligands. D. Prema, C. J. Levy 278. Dinuclear and trinuclear Pt"- and Pt m pyrazolate complexes. H. Zhao, R. G. Raptis 279. Diverse coordination chemistry resulting from lithiated heteroarenes and group VII transition metals. S. Lotz, M. Landman, D. Liles 280. Dynamic combinatorial libraries of histidine-based ligands. M. Matsumoto, Κ. Μ. Nicholas 281. Metal carboxylate formation using 2,6bis(2-hydroxyethoxy)-4-methylbenzoicacid and related compounds. E. K. Haub 282. Metallocage coordination complexes from dipyridine ligands possessing a carbazole nucleus. E. Podlesny, D. L. Jameson 283. New metal complexes of o-vanillin tetradentates. F. Liu, E. Sinn 284. Redox electroactive asymmetrical N 2 0 3 type complexes with selected first row transition metals. M. Allard, C. N. Verani 285. Ruthenium oxime complexes: Models to study the kinetics of proton-coupled elec tron transfer. E. T. Bell-Loncella 286. Synthesis and characterization of an anionic (cyclopentadienyl)vanadium nitride complex featuring a terminal VsN bond. C. D. Abernethy, J. P. Jasinski, C. E. Johnson, A. S. Metell, J. W. Queen
287. Synthesis and characterization of asym metric bimetallic ruthenium (II) complexes. M. T. Mongelli, C. Hicks, J. Friga, E. Friga 288. Synthesis and characterization of metallocene salts of tetracyanotetraazanaphthalene. A. C. Dunbar, W. W. Lai, P. G. Rasmussen, G. S. Girolami 289. Synthesis and luminescence study of a series of Cu(ll) halide ligand coordination solids. L. M. Grande, S. L. Stoll, E. VanKeuren, A. Bone 290. Synthesis and reactivity of 3-iminophosphine palladium complexes. A. R. Shaffer, J. A. R. Schmidt 291. Transition metal thiocarboxylate com plexes. M. Landman, M. S. Thomas, R. G. Bokretsion, A. Twala, S. Lotz 292. Wurster's thiacrown ethers and related acyclic ligands. J. W. Sibert, S. C. Dodani, P. B. Forshee 293. Controlled synthesis and structure modi fications in metal alkoxides for directed assembly in inorganic thin films. R. M. Sewell, T. J. Boyle, L. A. M. Ottley, H. D. Pratt III, B. Potter, J. D. Musgraves 294. Coordination chemistry of high-valent transition metals. J. F. Berry 295. Group 6 metal carbonyl complexes of a bulky phosphine: The crystal structures of bis(trimethylsilyl)phenylphosphine -M(0)pentacarbonyl: M(0)= chromium, molybdenum and tungsten. C. P. Rooney, A. C. Hinkle, M. L. Helm 296. Molecular and electronic structure of several 2,3-dithienylquinoxalines and their 2:1 complexes with silver(l) nitrate. G. Crundwell, B. L. Westcott, T. R. Burkholder, A. D. Hunter, M. Zeller, A. Pierpont, P. Foss, S. Cantalupo, K. Kopp, B. McBumey, N. E. Gruhn, J. C. Durivage 297. Synthesis of peptide-bridged macrocycles as bioactivatable magnetic reso nance imaging contrast agents. B. D. Ulrich, T. J. Meade 298. Synthesis, X-ray crystallography, and photoluminescence studies of gold(l) complexes with tri-2-furyl phosphine ligand. D. E. Jenkins, Z. Assefa, A. Kebede, R. Sykora 299. Synthesis of a series of novel bis-bidentate ligands utilizing 2,6-diaminotoluene. S. Padi, J. Cebulski, B. Korfel, M. A. Benvenuto Section F Hyatt Regency Chicago Riverside Center Energy and Environmental Inorganic Chemistry Cosponsored with SUST D. C. Crans and D. J . Nelson,
Organizers
7:00-10:00 300. Polyelectrolytes-organometallic multilay ers for efficient photocurrent generation: [polypropylviologen/RuL2(NCS)2/ (PEDOT;PSS)]n on ITO. M. Park, W. J. Lee, S. K. Min, G. Cai, S. H. Han 301. Catalysts for biofuel synthesis. H. M. Cowing, J. Gryko 302. Photocatalytic water splitting using plati num and metal oxide decorated niobate nanosheets. O. C. Compton, J. Y. Kim, F. E. Osterloh 303. Synthesis of higher alcohol mixtures from syngas over modified copper cata lysts. Y-G. Bai, S. Ge, L. Ma, D. He, B. Xu 304. Cooperative reactivity of phosphines and boranes: The reversible metal free activa tion of dihydrogen. G. C. Welch, D. W. Stephan 305. Designing mixed-metal supramolecular assemblies as photochemical molecular devices: Applications in solar hydrogen production. S. M. Arachchige, M. Elvington, J. Brown, K. J. Brewer 306. Porphyrin-based hydrogen storage materials. E. Y. Choi, R. W. Novotny, W. Choe 307. SiC nanoporous membrane derived from polycarbosilane for hydrogen separation at high temperature. Y. Kim, S. R. Kim, W. T. Kwon, V. Dabhade 308. Thiol group sidewall functionalization of single walled carbon nanotubes. H. L. Rhoads, C. N. Brammer, D. J. Nelson, R. Li
TECH-69
TECHNICAL PROGRAM
INOR 309. Effect of dye-semiconductor electronic coupling on solar energy conversion efficiency in dye sensitized solar cells. A. O. Ramirez, C. She, K-T. Youm, T. Lian, J. T. Hupp 310. Fragile-free ZnO micro-cone flower-like architecture based 2.21% efficient dyesensitized solar cells. J . H. Ahn, S. H. Han, J-H. Chang, H-Y. Ko
Section I Hyatt Regency Chicago Riverside Center Materials Synthesis D. C. Crans,
Organizer
7:00-10:00 Section G Hyatt Regency Chicago Riverside Center Development and Studies with Inorganic Catalysts K. Kustin,
Organizer
7:00-10:00 311. Catalytic combustion of methane over nano Zr02 supported copper-based catalysts. F. Qu, W. Chu, L. Shi, M. Chen, J. Hu, S. Luo 312. Synthesis of mesoporous titanium dioxide without using organic templates and their photocatalytic activities under visible light. J. Shen, Z. Zhang, M. Zhang, N. Lou 313. Mediation of living radical polymerization by cobalt (II) métallo radicals and organocobalt complexes. C-H. Peng, M. Fryd, B. B. Wayland 314. New improved hydrogen chloride oxidation process. K. Iwamoto, K. Seki, T. Hibi, K. Iwanaga 315. Oxygen atom transfer from a cationic rhenium(VII) oxo imido complex to silanes. N. E. Travia, M. M. Abu-Omar 316. Platinum catalyzed reactions in a microwave reactor. F. A. Fullilove 317. Polymer-supported zinc tetrahalide catalysts for the coupling reaction of carbon dioxide and propylene oxide. B. Lee, H. W. Bae, J. M. Hwang, M. Cheong, H. S. Kim 318. Withdrawn. 319. Synthesis of cationic rhenium(VII) oxo imido complexes and their tunability toward oxygen atom transfer. E. A. Ison, J. E. Cessarich, N. E. Travia, P. E. Fanwick, M. M. Abu-Omar 320. Thermocatalytic sensors for monitoring of sulphur hydrogen and fluorine hydrogen in air. D. Kurbanova 321. Use of transition metal diimine complexes as cyclopropanation catalysts. S. I. M. Paris, O. M. Pavlyuk, J. L. Petersen, M. C. McMills, M. Jensen Section H Hyatt Regency Chicago Riverside Center Inorganic Chemistry in Water Cosponsored with SUST D. C. Crans,
Organizer
7:00-10:00 322. Photochemistry of (bpy)2Ru(ll)LCI2 in aqueous solutions (bpy = bipyridine, L = 1,2-bis[4-(4'-2,2'-bipyridyl)] ethene ). H. Zhang, C. S. Rajesh, P. K. Dutta 323. Substrate reactions of rhodium tetrakis(3,5-disulfonatomesityl)porphyrin in water. S. Li, X. Fu, Β. Β. Wayland 324. Aerobic oxidation of alcohols with an aqueous-phase palladium catalyst. B. P. Buffin, N. L. Belitz 325. Ligand exchange kinetics of Ni(tren) and bipyridine. L. Kolopajlo, M. Kallio 326. Relative energies of alpha and beta isomers of Keggin dodecatungstogallates. K. Sundaram, W. A. Neiwert, I. A. Weinstock, C. L. Hill
70-TECH
327. Novel ligands for structural control of photogenerated nanoscale materials. C. De, S. O. Obare 328. Sol-gel synthesis of aluminosilicate glasses. S. Ndegwa, E. J. Voss 329. Study phase formations of zinc titanate nanocrystal powders via sonochemical synthesis. F. Chen, M. Hilton, B. Manhat 330. Synthesis and characterization of Mg doped lithium ion-sieve adsorbent derived from LiMn204. Q. Dong, X. Piao, S. Zhu 331. Synthesis and post-synthetic elaboration of metal-organic frameworks.
T. Gadzikwa, B-S. Zeng, S. T. Nguyen, J. T. Hupp 332. Synthesis of metal-organic-, covalentorganic-, and zeolitic imidazolate frame works (MOFs, COFs, and ZIFs). A. P. Côté, O. M. Yaghi 333. Assembly of nickel tetraphenylporphyrin and DABCO on a metal surface. C. Iverson, L. Teugels, S. J. Sibener, M. D. Hopkins 334. Biomimetic synthesis of hierachical CaC03 multilayer assemblies in P123 aqueous solutions. J . Cao, X. Jiang, J. Guo, M. Zheng, J. Liu, H. Zhao 335. Electrochemical morphogenesis of micron-size C u 2 0 crystals. M. J. Siegfried, K-S. Choi 336. Facile solvothermal routes to main-group and transition metal nitrides, oxides and phosphides. B. M. Barry, E. Gillan, J. L. Choi 337. Influence of microwave irradiation on the reaction of MgO and AI203 slurries to form layered double hydroxide. S. J. Mitchell, I. R. Baxendale, W. Jones 338. Ionic liquids for materials synthesis: Preparation and characterization of [EMIM] 7 [Ni 4 P 1 3S 36 ] (EMIM = 1-ethyl-3methylimidazolium). J. A. Cody, K. B. Finch, C. Nâther, W. Bensch 339. Potassium intercalation of graphitic nanofibers. J. A. Michel, C. M. Lukehart 340. Silicon clathrates - aluminum alloys. G. C. Naughton, J. Gryko 341. Sol-gel synthesis of silicate glasses using DCCAs. J. C. Tarrant, E. J . Voss 342. Synthesize functionally porous silica nanoparticles for heavy metal removal. T. Zeng, W. Li 343. Ultrasonic nozzle and microwave-assisted preparation of mixed metal oxide nanoparticles. E. K. Nyutu, S. L. Suib Section J Hyatt Regency Chicago Riverside Center Nanoscience: Characterization and Applications B. T. Donovan-Merkert and D. C. Crans, Organizers
7:00-10:00 344. Fluorescence enhancement of ruthenium complex on silver nanoparticles coated with different chain length carboxylic acid terminated thiols as spacers. J-S. Yu, N. Chaudhari, M. S. Kim, J. H. Kim 345. Large-area patterning of nanoscale transition metal chalcogenides. C. L. Stender, T. Odom 346. Silicon elastomers designed for advanced soft lithography. Κ. Μ. Choi 347. Electrodeposited electrochromic W 0 3 . x films with reduced lattice deformation stress and fast response time. H. Redmond, M. Hepel 348. In situ nanoparticle synthesis on mono layer templates. I. Pala, K. Bandyopadhyay 349. Nanostructured ceramic thin films for photocatalytic applications. Y. Zhao, X. Xiaofeng Qiu, C. Burda 350. Palladium nanoclusters on carbon nanotubes for flexible hydrogen sensors. Y. Sun, H. H. Wang, Q. Cao, J. A. Rogers
351. Palladium nanoparticles supported on polyaniline nanofibers as catalysts for the formation of C-C bonds. B. Gallon, R. W. Kojima, R. B. Kaner, P. L. Diaconescu 352. Photoactive Ti02 modified with monolayer-protected gold clusters. P. M. Cox, D. Lee 353. Solid-state NMR and FTIR studies of CdS nanoparticle/polymer composites. S. Y. Ortiz-Colon, M. Espe, R. F. Ziolo, F. S. Manciu 354. The electrical and thermal properties of kaolinite/polyaniline hybrid nanocomposite. B-X. Wang, Y. Shi, D-F. Xue 355. A bioinspired synthesis of barium titanate nanoparticles for use in positive tempera ture coefficient of resistivity (PTCR) appli cations. R. L. Brutchey, G. Cheng, E. S. Yoo, D. E. Morse 356. Application of metal chalcogenide aero gels to gas sensing. Q. Yao, S. L. Brock 357. Carbon nanotube contrast agents for MRI and CT. V. C. Moore, P. Joshi, J. L. Conyers 358. Excited-state deactivation of CdSe quan tum dots by gold nanoparticles. M. Kondon, D. Lee 359. Fabrication of multi-functional AFM tips. C. M. Sweeney, J. Henzie, T. W. Odom 360. Luminescent colloidal silica. R. B. Soriano, E. Kpatcha, A. M. Jakob, T. A. Schmedake 361. Multifunctional mesoporous nanomaterials for drug delivery. T. Asefa, E. Blair, A. Di Pasqua, J. C. Dabrowiak 362. Nano- and microparticles from infinite coordination polymers of salen-based homochiral building blocks and late transi tion metal ions. Y-M. Jeon, J. Heo, C. A. Mirkin Section Κ Hyatt Regency Chicago Riverside Center Nanoscience: Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers
7:00-10:00 363. Microwave-assisted synthesis of periodic mesoporous ethane-silica. B. E. Grabicka, M. Jaroniec 364. One-step synthesis of core-shell meso porous carbon nanofibers using anodic alumina membranes as template. M. Zheng, J . Cao, X. Ke, G. Ji, Y. Chen, J. Tao 365. Synthesis of La203 nanorob. Z. Le, W. Liu, R. Ruan, L. Dai 366. Synthesis of L 1 0 FePt, CoPt, and FePd magnetic nanoparticles via single-source precursors. M. S. Wellons, W. H. Morris III, Z. Gai, J. Shen, J. Bentley, J. E. Wittig, C. M. Lukehart 367. Zinc oxide nanoparticles from amido zinc precursors. B. Luo, W. L. Gladfelter 368. Synthesis of colloidal ll-VI and IV-VI metal sulfide semiconductor nanowires by the solution-liquid-solid growth mechanism. J. Sun, W. E. Buhro 369. Synthesis of silicon carbide nanotubes by chemical vapor deposition. N. He, D. Tao, Z. Xie, S. Li 370. Nanoparticle size and self-assembly within nanoclay hybrid films. M. Nolan Jr., M. E. Hagerman 371. Naturally occurring fluorescent (NOF) mineral inspired luminescent colloidal nanocrystals. T. N. Lambert, B. A. Hernandez-Sanchez, T. J. Boyle, H. D. Pratt III, N. L Andrews, D. S. Lidke, J. M. Oliver, B. S. Wilson 372. Synthesis and characterization of mono and multi-element (Nb.Ru)-MSU molecular sieves. I. Nowak, A. Feliczak, M. Jaroniec 373. Effect of synthesis method on the physi cal and catalytic property of nanosized NiO. F. Yang, Y. Wu, T. Wu, H. Wan 374. Effects of solvent on properties of Ti02 porous films prepared by a sol-gel method from the system containing PEG. J. Luo, X.Liu 375. Gold nanoparticles coated with redoxactive transition metals. A. A. Ramirez, I. Cruz-Campa, J. C. Noveron
376. Growth of carbon nanotubes from nanoparticulate catalysts generated by in situ laser ablation of metal targets. B. D. Fahlman, L. A. Nezeritis 377. Sacrificial DNA templates for highly parallel nanolithography. H. A. Becerril, A. T. Woolley 378. Shaped core-shell nanostructures: Shaped synthesis of gold nanoshells with tunable optical properties on silica nanospheres. Y-L. Shi, T. Asefa 379. Difluoroboron dibenzoylmethane-polylactide materials displaying fluorescence and unusual room temperature oxygen sensi tive phosphorescence. G. Zhang, J. Chen, S. J. Payne, J. N. Demas, A. Pfister, C. L. Fraser Section L Hyatt Regency Chicago Riverside Center Organometallic Catalysts B. T. Donovan-Merkert and D. C. Crans, Organizers
7:00-10:00 380. Salicylaldimine ruthenium alkylidene complexes: Metathesis catalysts tuned for protic solvents. J. B. Binder, I. A. Guzei, R. T. Raines 381. Synthesis and characterization of a new Ruthenium(ll) catalyst for asymmetric transfer hydrogénation of acetophenone derivatives. G. J. Uc, S. Attar 382. Investigations into the mechanism of the rhodium catalyzed asymmetric hydroformylation of styrene. A. Watkins, C. R. Landis 383. Metal salen derivatives as catalysts for the copolymerization of oxetane and carbon dioxide to afford polycarbonates. A. I. Moncada, D. J. Darensbourg, W. Choi 384. Pincer-ligated iridium complexes stereospecifically designed for alkane dehydrogenation. S. Kundu, Z. Gao, R. Warmuth, A. S. Goldman 385. Synthesis and reactivity of Group 4 amidate complexes and their applications in hydroamination catalysis. R. K. Thomson, L. L. Schafer 386. Gold-catalyzed intermolecular nitrene transfer into C-H bonds. D. A. Capretto, Z. Li, C. He 387. Insertion of olefins into Ir-H bonds: Experimental and computational studies of a model system. A. Ray, S. Kundu, Y. Choliy, K. Krogh-Jespersen, A. S. Goldman 388. A new planar chiral ferrocenyl-aminophosphine ligand for Ru(ll)-catalyzed asymmetric transfer hydrogénation of acetophenone derivatives. F. R. Perez, S. Attar 389. A study of Schiff base Cobalt(lll)/Lewis base catalyst systems for the cycloaddition of C 0 2 and epoxides and their reaction mechanisms. A. Sibaouih, P. Ryan, M. Leskelâ, T. Repo 390. Aldol condensations mediated by bis(diketonate)titanium(IV) triflates. J. P. Bigi, L. Zakko, V. Ugrinova, B. C. Noll, S. N. Brown 391. Catalytic phosphorus-phosphorus bond activation. S. J. Geier, D. W. Stephan 392. Equlibrium studies of [CpRu(-rf-DBT)] + with various aromatic ligands: Models for adsorption of aromatics on hydrodesulfurization catalysts. M-G. Choi, R. J. Angelici 393. Modular ligand design for electrophilic platinum(ll) catalysts: Improved catalysis and unique reactivity. A. N. Campbell, J. Feducia, M. R. Gagné
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INOR 394. Silver-catalyzed amidation of saturated C-H bonds. Z. Li, D. A. Capretto, R. O. Rahaman, C. He 395. (t-Bu)2PN=P(i-BuNCH2CH2)3N: New efficient ligand for palladium-assisted C-N couplings of aryl bromides and chlorides, and for vinyl bromides at room temperature. V. R. Chinta Reddy, J. V. Kingston, J. G. Verkade Section M Hyatt Regency Chicago Riverside Center Organometallic Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 396. Cycloheptatrienyl tantalum compounds and their EPR spectra. W. Noh, G. S. Girolami 397. Synthesis and spectroelectrochemistry of manganese and rhenium complexes of acetylenic ketones. J . R. Crisman, M. J. Shaw 398. Synthesis, characterization and spectroelectrochemistry of Mn and Re carbonyl complexes which bear scorpionate ligands based on N-heterocyclic carbenes. J. A. Heafner, M. J. Shaw 399. Synthesis and characterization of cyclopropylalkyne complexes of manganese. N. E. Motl, M. J. Shaw 400. Synthesis and characterization of acetylenic ketone complexes of iron porphyrins. J. P. Kistner, M. J. Shaw 401. Reactions of CH 3 Mn(CO) 5 with alkynes revisited: New reactivity from an old system. M. J . Shaw, A. J. Warhausen, L. Mitchell, N. P. Rath 402. Electrochemical effects of pi-coordination of d-6-metal fragments on pi-conjugated molecular wires. S. Osiohwo, M. J. Shaw 403. Silver(l) carbonyl complexes supported by tris(pyrazolyl)borates. H. V. R. Dias, M. Fianchini 404. Silver(l) ethylene complexes based on fluorinated tris(pyrazolyl)borates. H. V. R. Dias, J. Wu, K. Rangan 405. Synthesis and characterization of tartaric acid-derived (bis)phosphite ligands for asymmetric catalysis. S. B. Owens Jr., G. M. Gray 406. Synthesis and structures of molybdenum germylene complexes. A. Shinohara, J. Mcbee, T. D. Tilley 407. The use of a boryl anion for the synthesis and characterization of new low-coordination transition metal compounds. C. Stanciu, N. Travia, P. E. Fanwick, M. M. Abu-Omar 408. Toward the synthesis of a transition metal-alkane complex. R. L Jew, G. S. Girolami 409. Synthesis and characterization of Ferrocene derivatives. M. L. Rivera-Claudio, J. Castillo-Ramirez, T. L. Diaz, M. M. Malavé, L. Diaz 410. Preparation of half-metallocene catalysts for biomedical applications. T. Hilliard, L. Jones II 411. Room temperature dehydrogenation of ethers and alkanes by reaction of β-enamineimine ligands with Me 4 Pt 2 (pSMe 2 ) 2 . N. M. West, J. L. Templeton 412. Heteropentadienyl/alkyne coupling reac tions in half-open ruthenocenes. A. Ramirez-Monroy, J. M. Stryker, M. A. Paz-Sandoval 413. Isolation of a platinum C-C sigma-complex. B. L Madison, B. S. Williams 414. Activation of silicon-aryl and germaniumaryl bonds by transition metals. Q. D. Shelby, B. J. Bellott, G. S. Girolami 415. Equilibrium studies on ligand-substitution reactions of neutral and unipositive Pd(ll) pincer complexes of K 3 -(PO A C A OP)Pd, K 3 -(PN A C A NP)Pd, and ^ - ( P O ^ N P J P d systems. N. W. Hoffman, R. Traylor, B. Wicker, C. N. Henderson, R. Sykora, J. H. Davis Jr., O. V. Ozerov, F. Lei, M. L Kwan, J. Marshall, K. M. Poleski
Section Ν Hyatt Regency Chicago Riverside Center Organometallic: General B. T. Donovan-Merkert and D. C. Crans, Organizers
7:00-10:00 416. Withdrawn. 417. Contact ion "triad" involving diisocyanoarene-linked pentacarbonylvanadates(l-) and cobalticeniums: A facile access from V(CO) 6 . T. R. Maher, M. V. Barybin 418. Development and application of homochiral magnesium amide bases. E. R. Hurley, J. F. Allan, K. Henderson 419. Effect of chelating phosphine ligands on SiH bond activation reactions at platinum. J. Braddock-Wilking, N. Praingam, N. P. Rath 420. Experimental and theoretical interpreta tion of C—C and C—H bond activations of acetonitrile using zerovalent nickel. W. D. Jones, T. A. Atesin, T. Li, W. W. Brennessel 421. Geometrically spin frustrated trinuclear Mn 2 + plaquettes and their diamagnetic Mg 2 + analogs: Building blocks for molecu lar magnetic materials. J. A. Hatnean, R. Raturi, S. A. Johnson 422. Neutral and cationic Palladium(ll) (3,5Me2-pyrazolyl)2CH(Si(p-tolyl)3) complexes. M. P. Conley, C. T. Burns, R. F. Jordan 423. Oxidative electrochemistry of chiral bis(phosphino)ferrocenes. A. Maddox, A. L. Rheingold, J. A. Golen, C. Nataro 424. Preparation and reactivities of TaL(NMe 2 ) 4 (L = Tp*, Tp) complexes. S-J. Chen, T. N. Williams, G. P. A. Yap, Z-L. Xue 425. Stereospecific addition of HCI across an iridium carbon double bond. C. J. Bourgeois, R. P. Hughes, J. Yuan 426. Synthesis and chemistry of bis(perfluoroalkyl)carbene complexes of iridium. R. P. Hughes, J. Yuan 427. Synthesis of ruthenium-olefin complexes as models of olefin metathesis reaction intermediates. D. R. Anderson, D. D. Hickstein, L N. Ciardulli, D. J. O'Leary, R. H. Grubbs 428. Synthesis, characterization, and reactivity of main group elements bearing a PNP pincer ligand. J. H. Orlando, D. J. Mindiola Section Ο Hyatt Regency Chicago Riverside Center Spectroscopy - Electronic Structure - Reactivity S. DeBeer George and K. D. Karlin, Organizers 7:00-10:00 429. Advances in synthetic copper-sulfide chemistry relevant to the CuZ site of nitrous oxide reductase. J. T. York, I. Bar-Nahum, W. B. Tolman 430. Altering the electronic structure of transi tion metal carbides. S. V. Didziulis, H. I. Kim 431. FeMoco biosynthesis as studied by EXAFS. B. Hedman, K. O. Hodgson, M. C. Corbett, A. W. Fay, J. A. Webber, Y. Hu, M. W. Ribbe 432. Bioinorganic chemistry on a singlemolecule basis. P. Chen, Ν. Μ. Andoy, J. Benitez, S. Sarkar 433. Brilliant red crystals from colorless solu tion: Re-examination of the cause of the solid-state effect in bis(dimethylglyoximato)nickel(ll). R. L. Musselman, A. A. Miller 434. Characterization of metal structure of calcium- and zinc-dependent neutral protease from Bacillus amyloliquefaciens. S-K. Lee, L. Wallace, S. DeBeer-George 435. Chemistry and spectroscopy of arsenitethiol interactions relevant to arsenic toxic ity. D. E. Wilcox, B. C. Bostick, G. E. Gehrke, A. M. Spuches, C. F. Quinn
436. Characterization of molecular excited states by light-induced time resolved X-ray absorption spectroscopy (LITR-XAS). E. C. Wasinger, X. Zhang, A. Z. Muresan, K. Attenkofer, G. Jennings, J. S. Lindsay, L X. Chen 437. Understanding how the thiolate sulfur contributes to the function of the nonheme iron enzyme superoxide reductase (SOR). J. A. Kovacs, T. Kitagawa, E. Nam, A. Dey, P. Lugo-Mas, L. M. Brines, G. Villar, P. Alokolaro, E. I. Solomon 438. Differential sensing of protein influences by NO and CO vibrations in heme adducts. M. Ibrahim, C. Xu, T. G. Spiro 439. Development of Pd L-edge X-ray absorption spectroscopy and its applica tion to chloropalladium complexes. R. K. Szilagyi 440. Electrocatalysis of copper-containing oxidases and their electrocatalytic applica tions. W. Shin, Y. Kim, A. Koh 441. Electronic structure contributions to catalysis in pyranopterin molybdenum enzymes. M. L. Kirk, C. G. Young, C. Gourlay, S. Z. Knottenbelt 442. Electronic structure of cationic porphyrazines. A. B. P. Lever 443. Electronic structure of ferric heme nitrosyl complexes with thiolate coordination. N. Lehnert, F. Paulat 444. New mononuclear copper(ll)-superoxo or copper(ll)-hydroperoxo complexes and investigation of their substrate reactivity. K. D. Karlin, D. Maiti 445. Biferrous methodology and its applica tions to the ferroxidase sites in m-Ferritin, Bacterioferritin, and related systems. J. K. Schwartz, P-P. Wei, X. Liu, V. Huang, D. Kurtz, E. Theil, E. I. Solomon 446. Geometric and electronic studies of toluene-4-monooxygenase and component D effector protein. P-P. Wei, J. K. Schwartz, K. H. Mitchell, B. G. Fox, E. I. Solomon 447. High resolution core and valence band XPS of non-conductor silicates. G. M. Bancroft, V. Zakaznova-Herzog, H. W. Nesbitt, J. S. Tse 448. Kinetic and spectroscopic characteriza tion of de novo designed binuclear iron active sites. C. B. Bell III, P-P. Wei, J. R. Calhoun, W. F. DeGrado, E. I. Solomon 449. Molecular mechanisms of manganese neurotoxicity: A bioinorganic chemist's perspective. L. Quintanar, T. Montiel, L. Massieu 450. Exploring the role of sulfur radicals in oxidative neurodegeneration and other biological redox processes. A. Karunakaran, V. Martin-Diaconescu, P. Kennepohl 451. Overcoming the spin forbidden nature in the 0 2 reaction of the intradiol dioxygenases. M. Y. M. Pau, J. D. Lipscomb, E. I. Solomon 452. Photoelectron spectroscopy of first-row transition metal complexes of octaethylporphyrin. D. L. Lichtenberger, N. E. Gruhn, F. A. Walker 453. Oxygen activation by the non-coupled binuclear copper enzymes. J. S. Woertink, E. I. Solomon 454. Photophysical properties of mer and fac isomers of homo- and hetero-leptic triscyclometalated iridium(lll) complexes. J. C. Deaton, S. Huo, D. J. Giesen 455. Pre-steady state kinetic studies (on the microsecond time scale) of the Laccase from Trametes versicolor. S. de Vries, I. Matijosyte, R. A. Sheldon, I. W. Arends 456. Probing the chemical origins of physical properties of metallomesogens via Raman spectroscopy. D. F. Dye, J. M. Zaleski 457. Reaction of iron(lll) polyaminocarboxylate complexes with hydrogen peroxide: Correlation between ligand structure and reactivity. S. Fujii, C. Tsueda, K. Yamabe, K. Nakajima, H. Sakai 458. Reactive complexes in myoglobin and nitric oxide synthase. K. K. Andersson, A. V. Agasoester, E. Harbitz, A. K. Roehr, M. Sorlie, C-H. Gorbitz, S. Marchai, R. Lange, A. C. F. Gorren, T. Shimizu, A. X. Trautwein, B. Mayer, H-P. Hersleth
459. S K-edge XAS and DFT calculations on Fe(lll) and Ni(ll) thiolate complexes: Effects of Η-bonding on metal-sulfur Bond covalency. A. Dey, S. P. Jefferey, M. Y. Darensbourg, T-A. Okamura, N. Ueyama, B. Hedman, E. I. Solomon 460. Structural and spectroscopic comparison of the five-coordinate cobalt(ll) and nick el^!) thiolato complexes with the related four-coordinate complexes. K. Fujisawa, T. Kakizaki, Y. Matsunaga, Y. Miyashita, K-l. Okamoto 461. Structure/function correlations of mono nuclear non-heme ferrous enzymes: Spec troscopic and DFT studies of pterin-dependent hydroxylases. M. S. Chow, S. Wilson, G. Anarat, S. Datta, B. Eser, A. Lee, M. M. Abu-Omar, J. P. Caradonna, P. F. Fitzpatrick, E. I. Solomon 462. The liposome binding nitrophorin 7 from the blood sucking bug Rhodnius prolixus: Spectroscopic and functional studies compared to the well-established NP1-4. M. Knipp, R. E. Berry, T. K. Shokhireva, H. Zhang, M. N. Shokhirev, F. A. Walker 463. The CuZ active site of nitrous oxide reductase: Geometric and electronic structure and role in N 2 0 reduction. S. Ghosh, S. I. Gorelsky, S. DeBeer George, I. Cabrito, J. Chan, D. M. Dooley, I. Moura, J. J. G. Moura, E. I. Solomon 464. The nonheme oxoiron(IV) reaction land scape. L. Que Jr., M. R. Bukowski, T. A. Jackson, E. J. Klinker, R. Mas-Balleste, O. Pokutsa, K. Ray, X. Shan, G. Xue, Y. Zhou 465. Withdrawn. 466. The structural basis of the ferrous iron specificity of the yeast ferroxidase, Fet3p. D. Kosman, C. S. Stoj, L. Quintanar, E. I. Solomon 467. The two state issue and electron dereal ization in the mixed-valence binuclear C u A center in cytochrome c oxidase and N 2 0 reductase. X. Xie, S. I. Serge, Y. Chen, J. A. Fee, E. I. Solomon 468. Comprehensive study of electronic properties of the OH-functionalized single walled carbon nanotubes. S. Lim, J . Lin 469. Variable frequency pulsed EPR studies of oxo-molybdenum centers in enzymes and model compounds. J. H. Enemark, A. V. Astashkin, A. M. Raitsimring, E. L. Klein, K. Johnson-Winters, C. Feng 470. XAS and NRVS of high-valent Fe com plexes: Spectroscopic characterization of Fe(V) and Fe(VI). S. DeBeer George, J. F. Berry, N. Aliaga-Alcalde, T. Petrenko, E. Bill, B. Mienert, W. Sturhahn, K. Wieghardt, F. Neese 471. Mechanisms of peroxide and oxygen reduction on electrode surfaces. A. A. Gewirth, K. Stewart, Ε. Ε. Eibergen, M. S. Thorum 472. Copper(ll) binding to alpha-synuclein, the Parkinson's protein. H. B. Gray, J. R. Winkler, J. C. Lee 473. Density functional theory (DFT) studies of structures and properties for high-valent intermediates Q in methane monooxygenase (MMO) and X in ribonucleotide reduc tase (RNR). L. Noodleman, W-G. Han, E. M. Sproviero, V. S. Batista 474. {FeNO} 7 complexes of mononuclear non-heme iron enzymes: Exploring reac tion pathways in aKG-dependent and related enzymes. C. D. Brown, M. L Neidig, M. B. Neibergall, J. D. Lipscomb, E. I. Solomon 475. Reactivity of aqua ferrate(VI, V, and IV) with inorganic and organic substrates. V. K. Sharma, D. Cabelli 476. Role of inner and outer coordination sphere residues in the structure and oxy gen reactivity of the trinuclear copper cluster in the multicopper oxidases. A. J. Augustine, C. Stoj, D. Kosman, E. I. Solomon
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-71
TECHNICAL PROGRAM
INOR 477. V-51 solid state NMR spectroscopy of vanadium (V) complexes with dipicolinic acid. S. Boite, B. Baruah, J. J. Smee, D. C. Crans, T. Polenova MONDAY MORNING Section A McCormick Place Lakeside Room E253, Level 2 ACS National Awards in Inorganic Chemistry: Plenary Session
4:45 488. The role of the second coordina tion sphere in hydrogen oxidation cata lyzed by nickel complexes. M. Rakowski DuBois, D. L. DuBois, A. D. Wilson, R. K. Shoemaker, J. T. Muckerman 5:15 489. Bioinspired chemistry of energy consequence: First- and second-sphere coordination approaches. C. J. Chang, W. H. Harman, H. S. Soo 5:45 490. Electrocatalytic hydrogen evolution at positive potentials. J. C. Peters, X. Hu, B. S. Brunschwig Section Β
D. C. Crans,
Organizer
K. R. Dunbar,
Presiding
9:00 478. Award Address (ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry, sponsored by Strem Chemicals, Inc). Coordination chemistry and catalysis on two surfaces: Curved carbon and gold metal. R. J. Angelici 9:50 479. Award Address (ACS Award in Inorganic Chemistry, sponsored by Aldrich Chemical Company, Inc). A journey through the periodic table: From boron to transition metals to lanthanides. S. G. Shore 10:40 480. Award Address (Alfred Bader Award in Bioinorganic and Bioorganic Chemistry, sponsored by Alfred Bader). Observing molecules from the inside out(ward): Mossbauer spectroscopy. E. Munck 11:30 481. Award Address (F. Albert Cotton Award in Synthetic Inorganic Chemistry, sponsored by the F. Albert Cotton Endow ment Fund). Synthetic cycles for smallmolecule activation, atom transfer, and reactive metal complex regeneration. C. C. Cummins MONDAY AFTERNOON
McCormick Place Lakeside Room E271B, Level 2 The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Cosponsored with PHYS C. A. Reed,
Organizer
M. Johnson, Organizer,
Presiding
2:00 491. Acidity: It's all about the anion. C. A. Reed 2:30 492. Role of HF in noble gas cation chemistry. K. Seppelt 3:00 493. Perfluoralky sulfonimides as useful strong protic acids and weak conjugate base anions. D. D. DesMarteau 3:30 Intermission. 4:00 494. Structural studies of liquid super acids. J. F. C. Turner, S. E. McLain, J. E. Siewenie, J. J. Molaison, C. J. Benmore 4:30 495. Coordination of Lewis acids to transition metals and the analogy to proto nation. V. Κ. Landry, J. S. Figueroa, K. Pang, G. Parkin Section C McCormick Place Lakeside RoomE271A, Level 2
Section A McCormick Place East Room E270, Level 2 Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST T. D. Tilley, H. M. Frei,
Organizer Presiding
1:30 482. Hydrogenases as catalysts for renewable hydrogen production. M. Ghirardi 2:00 483. Chemistry and iron-only hydrogenase. C. J. Pickett 2:30 484. Hydrogenases: Electrocatalysis, reactions and inspiration. F. Armstrong 3:00 485. Synthetic iron hydrogenase active site mimics as homogenous proton reduc tion catalysts. S. Ott 3:30 486. Biomimetics of the 2Fe2S subsite of the [FeFe]Hydrogenase H cluster con taining redox active ligands. M. Y. Darensbourg, C. W. Thomas, O. Rudinger, K. N. Green, T. B. Liu, J. W. Tye, M. B. Hall 4:00 Intermission. 4:15 487. Inorganic chemistry and the puzzle of the Fe-only hydrogenases. T. B. Rauchfuss, A. K. Justice, J. L. Stanley
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72-TECH
Nanoscale Inorganic Catalysis Innovative Synthetic Strategies in Nanoscale Catalysis P. Balbuena and D. A. Chen, R. E. Schaak, Organizer,
Organizers
Presiding
1:30 496. Synthesis of nanoparticles of ordered intermetallic compounds: The search for improved fuel cell catalysts. F. J. Di Salvo Jr 2:15 497. Solution chemistry toolkit for the design of multi-metal nanoparticle cata lysts. R. E. Schaak 2:45 498. Architectural control in bimetallic nanoparticles for heterogeneous catalysis. B. W. Eichhom, S. Alayoglu, S. Zhou, G. S.Jackson 3:15 Intermission. 3:30 499. Colloidal nanocatalysis: The good and the bad. M. El-Sayed 4:00 500. Autonomous nanoscale motion through catalysis. A. Sen 4:30 501. Varying oxygen ion transport in doped ceria nanoarchitectures: Effect on catalysis of the water-gas shift reaction. D. R. Rolison, C. N. Chervin, K. A. Pettigrew, J. W. Long 5:00 502. Low platinum and non-precious metal catalysts for PEM fuel cell applica tion. R. Atanasoski
1:55 504. Structure function studies on stearoyl-acyl carrier protein desaturase: Characterization of 18:0-ACP binding site and the mechanism of ferredoxin activa tion. P. Sorado, B. Pierce, S. P. Kaul, B. G. Fox 2:20 505. Structural studies of bacterial multicomponent monooxygenases: Hydroxylases and component complexes. M. S. McCormick, Μ. Η. Sazinsky, K. L. Condon, S. J. Lippard 2:45 506. Generation and characterization of novel intermediates in the hydroxylase component of bacterial multicomponent monooxygenases. L. J. Murray, R. Garcia-Serres, V. Izzo, S. Naik, C. E. Tinberg, B. H. Huynh, S. J. Lippard 3:10 507. New features of the nonheme oxoiron(lV) landscape. L. Que Jr., G. Xue, D. Wang 3:35 508. Hydrogen atom transfer and elec tron transfer in the oxidation of nitroxyl radicals and transition metal hydroperox ides by superoxo and oxo metal com plexes. A. Bakac, M. J. Vasbinder 4:00 509. On the mechanisms of function of Fe-TAML oxidant activators. T. J. Collins, A. Chanda, D-L. Popescu, A. D. Ryabov, V. Polshin 4:25 510. Mossbauer, DFT and high-valent iron. E. L. Bominaar 4:50 511. 0 2 and N20 activation by binuclear, trinuclear, and tetranuclear copper clusters. E. I. Solomon
2:50 522. Aromaticity and antiaromaticity in main group porphyrin complexes. T. P. Vaid, J. A. Cissell, A. L. Rheingold, G. P. A. Yap 3:10 523. Arylation reactions of bismuth carboyxlates. Κ. Η. Whitmire, J. H. Thurston, V. Stavila, D. Prieto-Centurion 3:30 524. Beta-diketiminate supported phos phorus complexes. Z. Lu, A. H. Cowley 3:50 525. Ketone deprotonation mediated by calcium amide bases. X. He, B. C. Noll, K. W. Henderson 4:10 526. Molecular alkane-soluble alkalineearth metal fluorides as precursors for nanostructed inorganic-organic hybride particles. M. Niemeyer, H. S. Lee 4:30 527. Novel inorganic synthetic route toward the M{N(2,4,6Me 3 C 6 H 2 )(SiMe 3 )}2(thf) n (M = Ca, Sr, η = 2; M = Ba, η = 3) and the well known heavier alkaline earth bis(bistrimethylsilyl) amides. M. M. Gillett-Kunnath, J. G. MacLellan, C. C. Forsyth, W. Teng, K. Ruhlandt-Senge, P. Andrews, G. B. Deacon 4:50 528. Reactivity of [c/oso-1-CB9H9-I-N2]: Functional group interconversion at the carbon atom. P. Kaszynski, B. S. Ringstrand, A. Franken, M. J. Carr, J. D. Kennedy 5:10 529. Reduction of a cationic borane into a neutral radical. C-W. Chiu, F. P. Gabbaï
Section Ε
Section G
McCormick Place Lakeside Room E253B, Level 2
McCormick Place Lakeside Room E253D, Level 2
ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry: Symposium in Honor of Robert J. Angelici
Nanoscience: Characterization and Application
J. R. Sowa Jr., Organizer,
B. T. Donovan-Merkert and D. C. Crans, Organizers
Presiding
2:00 512. Binding of bis(phosphino)metallocenes: Amazing, novel, grand, electrochemically lively inorganic complexes investigated. C. Nataro 2:30 513. Synthesis and reactivity of the thiapentadienyl ligand and its correspond ing oxidized derivatives with transition metal complexes. M. A. Paz-Sandoval, P. Gamero-Melo, A. P. Melo-Trejo, B. A. Paz-Michel 3:00 514. Beryllium environmental and biological chemistry. N. N. Sauer, E. R. Birnbaum, T. M. McCleskey, B. L. Duran, D. S. Ehler, B. L. Scott, T. P. Taylor, G. Gupta, B. L. Marrone 3:30 515. Tungsten(ll) monocarbonyl bis(acetylacetonate): A docking site for four-electron donor ligands. J. L. Templeton, A. B. Jackson 4:00 516. Organometallic quinonoid com plexes in supramolecular self-assembly and multifunctional catalysis. D. A. Sweigart, G. B. Carpenter, J. A. Reingold, S. B. Kim, M. Oh, S. U. Son 4:30 517. New metallaborane chemistry and superconformai deposition of metal borides by CVD. G. S. Girolami, D. Y. Kim, S. Jayaraman, Y. Yang, J. R. Abelson Section F McCormick Place Lakeside Room E253C, Level 2 Main Group Chemistry D. C. Crans,
Organizer
Section D
Κ. Η. Whitmire,
McCormick Place Lakeside Room E253A, Level 2
1:30 518. Synthesis and characterization of imidazole-silane complexes. T. V. Eliseeva, M. J. Panzner, W. L. Lewis, V. R. Dudipala, M. P. Espe, W. J. Youngs, C. A. Tessier 1:50 519. Carborane-containing dendrons. I. Zharov 2:10 520. Self-healing composite materials for inorganic films. H. A. Liu, K. Balkus Jr. 2:30 521. A closer look at di- and triphenylmethanide alkaline earth metal chemistry. M. A. Guino-o, J. S. Alexander, W. Teng, K. Ruhlandt-Senge
Alfred Bader Award in Bioinorganic and Bioorganic Chemistry: Symposium in Honor of Eckard Munck C. Achim, Organizer,
Presiding
1:30 503. Regulation and reactive intermedi ates of Rieske dioxygenases. S. Chakrabarty, M. B. Neibergall, J. D. Lipscomb
Presiding
T. Asefa,
Presiding
1:30 530. Pore enlarged mesoporous silica nanoparticles for intracellular delivery of membrane impermeable proteins. 1.1. Slowing, V. S-Y. Lin 1:50 531. The effect of physical characteristics on biocompatibility and cellular internalization of carbon nanotubes. V. C. Moore, A. Leonard, Β. Κ. Price, J. L. Conyers, J. M. Tour 2:10 532. INOR 000: Adsorption and con trolled release of chemicals and drug molecules by functionalized mesoporous nanospheres. T. Asefa, E. Blair, A. Di Pasqua, J. C. Dabrowiak 2:30 533. Reversible doping for nanotubes and biosensor applications. S. B. Chikkannanavar, Y. Gao, H-L Wang, S. K. Doom 2:50 534. Upconverting sub-10 nm sized nanophosphors in bioimaging. S. F. Lim, R. Riehn, C-K. Tung, D. Tank, W. S. Ryu, N. Yao, R. H. Austin 3:10 535. Mesoporous silica nanoparticlebased system with chemically removable β-cyclodextrin caps for stimuli-responsive controlled release of drugs. J. L. Vivero-Escoto, V. S-Y. Lin 3:30 Intermission. 3:50 536. Impact of carbon nanomaterial size regimes on smooth muscle cell growth. P. M. V. Raja, J. Connolley, G. P. Ganesan, L. Ci, P. M. Ajayan, O. Nalamasu, D. M. Thompson 4:10 537. Endocytosis and drug release of mesoporous silica nanoparticles within mammalian cells and plant cells. B. G. Trewyn, V. S-Y. Lin 4:30 538. Covalently bound biopolymers within mesoporous silicon as improved substrates for optical detection of enzyme activity. K. A. Kilian, L M. H. Lai, T. Boecking, S. Ilyas, K. Gaus, M. Gal, J. J. Gooding 4:50 539. Selective enrichment of phosphorylated peptides by magnetic nanopar ticles and mesoporous magnetic submicron particles. Y. Huang, C-K. Tsung, Q. Shi, P. Yang, G. Stucky, X. Chen
INOR
Section H McCormick Place Lakeside Room E255, Level 2 Materials Synthesis D. C. Crans,
Organizer
L. C. Francesconi,
Presiding
1:30 540. Rapid synthesis of crystalline, photocatalytically active titania and layered metal oxyhalides. S. Perera, N. Zelenski, R. Pho, E. G. Gillan 1:50 541. Synthesis, photophysics, and optical limiting of a trinuclear cyclometalated Pt(ll) complex. P. Shao, W. Sun 2:10 542. Alternative syntheses and utility of platinum(ll) terpyridyl acetonitrile com plexes. T. M. Pappenfus, G. G. W. Lee, L. R. Davisson, D. P. Ekerholm, J. R. Bumey, K. R. Mann 2:30 543. Novel preparation method for Keggin Type molybdophosphoric heteropoly blues. Y. Li, W. Chu, M. Chen 2:50 544. Pyrolytic formation of Fe5Si3 nanoparticles from a diacetylene-ferrocenyl-containing siloxane. M. K. Kolel-Veetil, T. M. Keller, S. B. Qadri 3:10 545. Radial nanowire growth from Au/Fe core/shell nanoparticles. N. Dahal, V. Chikan 3:30 546. Siloxy-functional polybutadienes and their self-assembly into nanostructures. B. P. S. Chauhan, B. Balagam, A. Sarkar 3:50 547. Coarsened T i 0 2 nanoparticles generated from basic titanate precursors. J. R. S. Brownson, E. Tsang, M. A. Anderson 4:10 548. Substrate-induced growth of nanostructured zinc oxide films from aqueous solution at room temperature using con cepts of biomimetic catalysis: A step toward low-cost solar cells. B. Schwenzer, J. R. Gomm, D. E. Morse 4:30 549. Effect of niobium addition on structural properties of mesoporous organosilicas. I. Nowak 4:50 550. Novel strategies in the crystal engineering of lanthanide coordination polymers: Harnessing structure-directing agents and monodentate linkages. D. T. de Lill, C. L. Cahill 5:10 551. Biomimetic synthesis of bone minerals on spider dragline silks. C. Mao, B. Cao Section I McCormick Place Lakeside Room E256, Level 2 General Inorganic and Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers M. J. Shaw,
Presiding
1:30 552. Ion-pairing and ligand exchange behavior of Lindqvist ions in aqueous solution. M. Nyman, T. M. Anderson, M. R. Antonio, W. H. Casey, J. R. Black, E. Balogh 1:50 553. Surface electrochemistry: Examples of an under-utilized technique. A. B. P. Lever, J. Chen, Y-H. Tse, P. Janda, J. Zhang, D. Christendat, Y. Ma, S. Stefan, M. Qi 2:10 554. Quantitative photochemistry of ring opening polymerization in a silicon-bridged [1]ferrocenophane. C. Kutal, M. J. Morgan 2:30 555. Relativistic protons: Carbon-gold bond formation. T. G. Gray 2:50 556. Ultrafast infrared studies of cobalt tricarbonyl nitrosyl: An investigation of doublet and triplet reactivity in solution. K. R. Sawyer, E. A. Glascoe, J. F. Cahoon, J. P. Schlegel, R. P. Steele, C. B. Harris 3:10 557. Connecting transition metals to the aromatic core of perylene diimide chromophores: Novel photofunctional systems with tunable properties. B. Rybtchinski, H. Weissman, E. Shirman, T. Ben-Moshe, L J. W. Shimon, G. Leitus, R. Cohen
3:30 Intermission. 3:40 558. NMR shifts, orbitals, and M...H-X bonding in d8 square planar metal com plexes. Y. Zhang, E. Oldfield 4:00 559. Probing mechanisms of sitespecific heterogeneous nucleation and directional nanobranch growth. T. Zhang, Z. R. Tian, W. Dong, R. N. Njabon, Q. Anderson, V. K. Varadan 4:20 560. Bismuth-based intermetalloid clusters. M. W. Hull, J. M. Goicoechea, S. C. Sevov 4:40 561. Reactions of d° Ta amide and silyl amide complexes with 0 2 : Mechanistic studies of metal oxide formation. S-J. Chen, H. Qiu, X. Yu, G. P. A. Yap, I. A. Guzei, Z - L Xue Exploring and Exploiting Nature with Biomimetics Biomolecular Self-assembly and Biocatalysis Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR
10:00 565. Role of the first coordination sphere in hydrogen oxidation/production, hydrogen storage, and carbon dioxide reduction catalysts. D. L. DuBois, M. C. Rakowski DuBois, C. Curtis, J. A. Franz, J. C. Linehan 10:30 Intermission. 10:45 566. Polynuclear metal oxide photocatalysts in mesoporous silica for C 0 2 reduction and H 2 0 oxidation. H. M. Frei 11:15 567. Photochemical splitting of carbon dioxide. C. P. Kubiak, A. Sathrum 11:45 568. Photocatalytic reduction of C 0 2 in supercritical C 0 2 . D. C. Grills, K-W. Huang, E. Fujita Section Β McCormick Place East RoomE271B, Level 2 The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Cosponsored with PHYS
9:25 582. Exploiting the versatility of Fe-S proteins in biological sensing and tran scriptional regulation. P. J. Kiley 9:50 583. Connecting nitrogenase intermedi ates with the catalytic mechanism: A relaxation protocol identifies the N 2 -binding (E 4 ) state. D. Lukoyanov, B. Barney, D. R. Dean, L. Seefeldt, B. M. Hoffman 10:15 584. Hubbard theory of polynuclear complexes. J-J. Girerd 10:40 585. Spin transitions in polynuclear iron complexes. C. Achim, A. Dragulescu-Andrasi, M. Pascu, F. Tuna, M. J. Hannon, M. Shatruk, K. R. Dunbar 11:05 586. Mapping helical bundle heme protein folding landscapes. Η. Β. Gray, T. Kimura, J. C. Lee, J. R. Winkler 11:30 587. Toward the function of heme c n in the cytochrome b6f complex: EPR spectroscopy and correlation with struc ture. A. Zatsman, H. Zhang, B. Cramer, M. Hendrich 11:55 588. Iron metabolism in yeast mito chondria. P. A. Lindahl
M O N D A Y EVENING M. Johnson,
Section Ε
Organizer
Section A C. A. Reed, Organizer, Hyatt Regency Chicago Riverside Center Sci-Mix D. C. Crans and Β. Τ. Donovan-Merkert, Organizers 8:00-10:00 181-182, 186-187, 193-196, 201-202, 204, 206, 209, 211, 213, 215, 217, 222-224, 226, 231-232, 235, 238, 247, 252-254, 257, 259, 266, 270, 277, 281, 286, 288, 292, 296, 299-300, 303-305, 308-309, 319, 321, 324, 326-327, 329, 332, 335, 337, 340, 343, 351, 360, 362, 371, 375, 379-380, 384, 387, 390, 392-393, 412, 426, 433, 439, 443, 446, 454, 462, 469, 474. See previous listings. 726, 728, 730, 732, 737, 7 4 1 , 747, 751-752, 754, 759, 762, 773, 775-776, 790, 793, 801-802, 808, 813-816, 818-819, 822823, 831, 833, 841-842, 848, 852, 854, 857, 860, 862-866, 868-871, 874, 878, 880, 882, 884, 886-888, 890, 892, 9 0 1 , 903, 905, 910, 913, 922-924, 9 3 1 , 9 4 1 , 957, 960, 976, 979-980, 982, 986-987, 991-992, 997, 1004, 1011, 1018, 10231026, 1028, 1033-1034, 1036, 1041, 1043, 1047, 1051. See subsequent listings. TUESDAY MORNING Section A McCormick Place East Room E270, Level 2 Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST T. D. Tilley, C. P. Kubiak,
Organizer Presiding
8:30 562. Progress and challenges in solar energy conversion using semiconductor/ liquid junctions. N. S. Lewis 9:00 563. Oxidation of alcohols aimed at power generation from chemical energy in homogeneous reactions. K. Tanaka 9:30 564. Nickel enzymes involved in cata lyzing the reduction of C 0 2 to methane and acetic acid. S. W. Ragsdale, R. C. Kunz, M. Dey, J. Seravalli, B. Brabec, T. I. Doukov, C. L. Drennan
Presiding
9:00 569. Hydrogen bonding: Acidity, basic ity, and effects on reactivity. J. I. Brauman, X. Chen 9:30 570. Weak hydrogen bonds: From crystal engineering to virtual screening. G. R. Desiraju 10:00 571. Superacidity and superbasicity of neutral Bronsted acids and bases: The limits of growth. I. A. Koppel, I. Leito, I. Koppel, L. Lipping, A. Trummal, P. Burk 10:30 Intermission. 11:00 572. Proton as Dr. Jekyll and Mr. Hyde: FTMS and ion-ion studies of the puniest of acids to the strongest of ones. S. R. Kass, M. M. Meyer 11:30 573. Roles of Η-bonding and the proton in coupled electron proton transfer (EPT). T. J. Meyer, M. H. V. Huynh, H. H. Thorp, C. J. Fecenko, J. Concepcion, J. Paul, K. Brennaman, J. Deyton Section C McCormick Place East RoomE271A, Level 2 ACS Award in Inorganic Chemistry: Symposium in Honor of Sheldon Shore T. P. Fehlner, L. Barton,
Organizer
Presiding
8:30 Introductory Remarks. 8:35 574. Structural chemistry of tetrahydroborates of the alkalimetals, titanium and zirconium. H. Noeth, M. Schmidt-Amelunxen, J. C. Galvez-Ruiz 9:05 575. Synthesis and structures of unusual borate anions. D. M. Schubert, M. Z. Visi, S. I. Khan, C. B. Knobler 9:35 576. Robust and recyclable BBD reagents for asymmetric synthesis. J. A. Soderquist 10:05 577. Small cage metallaborane chem istry and the influence of Sheldon Shore. L. Barton 10:35 578. Partially ligated clusters: Role of external lone pairs in bonding. T. P. Fehlner 11:05 579. Transition metal cluster-sup ported supramolecular construction. Z. Zheng 11:35 580. Metal-monocarbollide com plexes: No longer the poor cousins of the metal-dicarbollides. T. D. McGrath, F. G. A. Stone Section D McCormick Place Lakeside Room E253A, Level 2
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Alfred Bader Award in Bioinorganic and Bioorganic Chemistry: Symposium in Honor of Eckard Munck C. Achim, Organizer,
Presiding
McCormick Place Lakeside Room E253B, Level 2 One-dimensional Nanomaterials Solution Synthesis and Physical Properties S. Jin,
Organizer
Y. Cui and L. J. Lauhon,
Presiding
8:30 589. Colloidal semiconductor quantum wires. W. E. Buhro 9:10 590. Morphology-controlled synthesis of 1 -D nanostructures in micellar systems.
L.Qi 9:30 591. Colloidal synthesis of metallic nanorods and nanowires in water. C. J. Murphy 10:10 592. Parallel Pd nanoribbons by spon taneous organization of Pd nanoparticles. O. Taratula, A. Chen, J. M. Zhang, J. Chaudry, I. A. Banerjee, H. He 10:30 Intermission. 10:40 593. Solution-based semiconductor nanowires: New opportunités in one dimension. M. Kuno 11:10 594. Non-local blinking of CdSe nanowires induced by mobile charges. V. Protasenko, S. Gordeyev, M. Kuno 11:30 595. Assymetric, 1-D growth of CdSe quantum dots to quantum rods. J. D. Doll, R. Li, F. Papadimitrakopoulos 11:50 596. Microwave-assisted synthesis of 1-D nanostructures. L Gou, J. M. Zaleski 12:10 597. Room-temperature synthesis of PbCr04 nanorods and SrCr04 nanowires by an aqueous solution route. C-Y. Xu, W-S. Wang, L. Zhen, W-Z. Shao Section F McCormick Place Lakeside Room E253C, Level 2 Development and Studies with Inorganic Catalysts K. Kustin,
Organizer
C. C. McLauchlan,
Presiding
8:30 598. Catalytic dioxygen activation by (nitro)cobalt porphyrins on Nation films. J. A. Goodwin, T. S. Kurtikyan, J. L. Coor 8:50 599. Coordination chemistry with versatile vanadium: Synthesis, characterization, and reactivity of several new complexes with tridentate ligands. C. C. McLauchlan, M. P. Weberski Jr. 9:10 600. Withdrawn. 9:30 601. Effect of organic group addition on catalytic activity of niobosilicas: Friend or foe? I. Nowak 9:50 602. Improved methanol-tolerant performance by PtFe/C electrocatalysts for oxygen reduction reaction. Y. Gong, Y. Yeboah, S. Lvov, V. Balashov, Z. Wang
9:00 581. Weak-field, heterometal iron-sulfur clusters of biological relevance. R. H. Holm
TECH-73
TECHNICAL PROGRAM
INOR 10:10 603. In-situ photoelectrochemical study of adsorption of phthalate and water on titania. S. Zhang, W. Wen, H. Zhao 10:30 604. Investigations of alcoholysis, chain exchange, trans-esterification, and the initial ring-opening event in the ringopening of lactide by chiral salen aluminum initiators. K. T. Quisenberry, M. H. Chisholm, Z. Zhou 10:50 605. Mechanistic studies of catalytic reduction of carbonyls with multiply bonded rhenium(V) complexes. G. Du, P. E. Fanwick, M. M. Abu-Omar 11:10 606. Mesoporous zeolite single crystal catalysts: Tailored hierarchical catalysts. C. H. Christensen, M. Kustova, K. Egeblad, C. H. Christensen 11:30 607. On the mechanism of transition metal dinaphthotetraazafj 4lannulenecatalyzed reduction of S 0 3 . J. P. Muena, M. Villagran, A. G. Lappin, G. J. Ferraudi, J. A. Costamagna 11:50 608. Poisoning of the Au/Ti0 2 active site for CO oxidation by NaBr. S. M. Oxford, J. Henao, J. H. Yang, J. T. Miller, M. C. Kung, H. H. Kung Section G McCormick Place Lakeside Room E253D, Level 2 Organometallic Catalysts B. T. Donovan-Merkert and D. C. Crans, Organizers K. P. Gable,
9:10 621. Hierarchical assembly in silicon zeptoliter beakers. J. Barton, T. W. Odom 9:30 622. Nanostructured catalysts: Where materials science meets catalysis. C. Barnes, R. T. Mayes, J. Clark, M-Y. Lee, G. T. Eldridge 9:50 623. Effects of residual surfactants on the chemistry of nanostructured barium hexaaluminate type catalysts. N. A. Khan, S. Natesakhawat, C. Matranga, T. Sanders, G. Veser 10:10 Intermission. 10:20 624. One-pot reaction cascades cata lyzed by acid and base-functionalized mesoporous silica nanoparticles. Y. Huang, H-T. Chen, B. G. Trewyn, S. Xu, V. S-Y. Lin 10:40 625. Mechanisms governing interfacial behavior of organic/inorganic silicone microemulsions. P. S. Purohit, P. Somasundaran 11:00 626. Gold nanoparticle aggregates for SERS. C. I. Bingham, C. P. Morrisey, S. M. V. Tuley, P. H. Davis 11:20 627. Temperature and length depen dence of charge transport in redox-active molecular wires incorporating ruthenium (II) bis (σ-arylacetylide) complexes. B. Kim, J. M. Beebe, C. Olivier, S. Rigaut, D. Touchard, J. G. Kushmerick, C. D. Frisbie 11:40 628. Structure, shape, and chromato graphic retention behavior of trimetallic nitride endohedral metallofullerenes, M3N@C2n (40 {le} n {le} 44). T. Zuo, L Xu, W. Fu, J. C. Duchamp, A. L. Balch, M. M. Olmstead, H. C. Dom
Presiding Section I
8:30 609. Synthesis and hydroamination kinetics of titanium dipyrrolylmethane derivaties. D. L. Swartz II, A. L. Odom 8:50 610. Reactions of a low-coordinate titanium fragment'with pyridines and nitriles. A. R. Fout, B. C. Bailey, H. Fan, M-H. Baik, J. C. Huffman, D. J. Mindiola 9:10 611. New developments in catalytic nitrile-alkyne cross-metathesis. M. J. A. Johnson, A. M. Geyer, E. S. Wiedner, R. L. Gdula, J. B. Gary, J. W. Kampf 9:30 612. Mechanistic insight into the rhodium/phosphine catalyzed coupling of aldehydes and phenylboronic acid derivatives. W. S. Brown, K. H. Shaughnessy 9:50 613. Electrochemically-promoted catalytic asymmetric hydrogénation of prochiral olefins using Rh(DuPHOS). B. T. Donovan-Merkert, R. P. Cope 10:10 Intermission. 10:20 614. Ligand-based control of thermodynamics in alkene/diolate interconversion. Κ. P. Gable, A. Joyce, J. Albus 10:40 615. Synthesis, resolution, and devel opment of a mixed 3,4-diazaphospholanephosphite ligand set for use in asymmetric hydroformylation. B. G. Hashiguchi, C. R. Landis 11:00 616. Supramolecular phosphines: Rational design, self-assembly and cataly sis. S. H. Chikkali, D. Gudat, M. Niemeyer, M. Nieger 11:20 617. Application of BINOL based pincer-complexes for palladium-catalyzed transformations. J. Aydin, O. A. Wallner, V. J. Olsson, K. J. Szabo 11:40 618. Synthesis of catalytically active group 6 metal alkylidyne complexes from their corresponding nitride precursors. A. M. Geyer, E. S. Wiedner, R. L. Gdula, M. J. A. Johnson, J. W. Kampf Section H McCormick Place Lakeside Room E255, Level 2 Nanoscience: Characterization and Application B. T. Donovan-Merkert and D. C. Crans, Organizers P. H. Davis,
Presiding
8:30 619. 3-D hierarchical nanomaterials mimicking lotus leaves. J. Li, W. Lu, C. M. Lukehart 8:50 620. Self-assembly of hybrid organicinorganic nanostructures. E. R. Zubarev
74-TECH
McCormick Place Lakeside Room E256, Level 2 Nanoscience: Synthesis Β. Τ. Donovan-Merkert and D. C. Crans, Organizers M. E. Hagerman,
Presiding
8:30 629. Synthesis of nanocrystalline AuCuSn 2 : Mechanistic insights for the low-temperature solution synthesis of intermetallic compounds. Β. Μ. Leonard, R. E. Schaak 8:50 630. Intermetallic nanoparticles for fuel cell applications: Synthesis and character ization studies. C. Roychowdhury, F. J. DiSalvo 9:10 631. Photochemically-directed selfassembly: Site-selective deposition of inorganic nanoparticles onto metal oxide surfaces. G. R. Soja, R. S. Dibbell, R. M. Hoth, D. F. Watson 9:30 632. Inorganic seeds for the preparation of nanosilver. M. Leon, P. Santiago, R. Irizarry, M. E. Castro 9:50 633. Molecular precursors for the for mation of iron phosphide nanoparticles. K. H. Whitmire, A. Kelly, I. Rusakova 10:10 634. Self-assembly of monodisperse nanoparticle superlattices mediated by non-local dipole-dipole interactions. P. Krai, A. Titov 10:30 Intermission. 10:40 635. Laponite/quantum dot nanomate rials for light emitting diodes. M. E. Hagerman, A. E. Toney, J. D. Kehlbeck, B. D. Cohen 11:00 636. Sequential growth of CdTe quan tum dots: Observation of magic sized CdTe quantum dots. P. Dagtepe, V. Chikan, J. Jasinski 11:20 637. Preparation and characterization of bismuth ferrite nanostructures by a coordination precursor. K. Su, l-W. Chu, N-L. Yang 11:40 638. Following the formation of gold nanoparticles atom by atom: Photochemi cal molecular mechanism for the formation of gold nanoparticles by disproportionation. S. Eustis, M. A. El-Sayed 12:00 639. Design and synthesis of a nanosized porphyrin hexamer. M. Vinodu, C. M. Drain ACS Award in Organometallic Chemistry: Symposium in Honor of David Milstein Sponsored by ORGN, Cosponsored with INOR
Exploring and Exploiting Nature with Biomimetics Rational Manipulation of Biomolecular Architecture Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR
4:30 654. Using spin-spin coupling constants to probe hydrogen bonds in proton-bound complexes. J. E. Del Bene
Nanotechnology and the Environment: Focus on Green Nanotechnology Applications of Nanomaterials for a Greener Environment Sponsored by l&EC, Cosponsored with INOR
McCormick Place Lakeside RoomE271A, Level 2
TUESDAY AFTERNOON Section A
D. A. Chen, Organizer,
Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST Organizer
D. W. Stephan,
Nanoscale Inorganic Catalysis Understanding Nanoscale Catalysis via Theoretical Modeling and Modern Surface Science Techniques R. E. Schaak and P. Balbuena, Organizers
McCormick Place Lakeside Room E270, Level 2
T. D. Tilley,
Section C
Presiding
1:30 640. A nanoparticle catalyzed efficient route for polyolefin modification. B. P. S. Chauhan, B. Balagam, M. Raghunath 1:50 641. Development of robust Group 4 initiators for the stereoselective ring-open ing polymerization of lactide. M. G. Davidson, M. D. Jones, A. J. Chmura, M. D. Lunn 2:10 642. Iron tris(dibenzoylmethane-polylactide) grows itself: Benefits of incorporating the catalyst into degradable polyester materials. C. L. Fraser, J. Chen, J. L. Gorczynski 2:30 643. Activation of dihydrogen and olefins by sterically demanding phosphines and boranes. D. W. Stephan, G. C. Welch, J. S. J. McCahill, P. A. Chase, A. Das 2:50 644. Ligand effects on the stability of the insertion products: A DFT study of oxidative addition of ammonia to iridium (I) complex. S. Chen, B. E. Bursten, M. H. Chisholm 3:10 Intermission. 3:30 645. Supported organoiridium catalysts for alkane dehydrogenation. H. Li, · B. L Duran, M. T. Janicke, D. Kelly, R. T. Baker, A. P. Sattelberger 3:50 646. Orchestrating electron transfer toward solar energy conversion. L L Tinker, N. D. McDaniel, E. D. Cline, P. N. Curtin, C. K. Smith, S. Bemhard 4:10 647. In situ XANES and EXAFS of catalysts for the 4e reduction of oxygen. G. M. Brown, D. R. Mullins, P. V. Bonnesen, M. G. Gorbunova, F. V. Sloop Jr., S. Dai, J-F. Huang, V. Schwartz 4:30 648. Model studies of electrocatalytic reactions. J. W. Medlin, M. P. Hyman 4:50 649. The use of heteropoly acids in PEM fuel cell relevant catalysis. A. M. Herring, R. J. Stanis, J. R. Ferrell III, M. C. Kuo
Section Β McCormick Place Lakeside Room E271B, Level 2 The Proton: New Physical and Structural Aspects of Acidity and H-Bonding
Presiding
2:00 655. Probing adsorption behavior and reactions at low-coordinated sites. J. N. Andersen 2:30 656. Adsorbate-induced faceting of metal surfaces: A form of nanoscale self-replication. T. E. Madey 3:00 657. Theory and experiments for improved electrocatalysis. M. Mavrikakis, A. U. Nilekar, D. C. Ford, Y. Xu, J. Zhang, K. Sasaki, M. B. Vukmirovic, R. R. Adzic 3:30 Intermission. 3:45 658. Reactivity and stability against dissolution of bimetallic nanocatalysts. P. B. Balbuena 4:15 659. Properties of supported metallic nanoparticles: Adsorbate stabilized shear instabilities. D. D. Johnson, L. Wang 4:45 660. Theoretical insights into the cata lytic activity of nanostructured polyoxometalates. M. Neurock, M. Janik, R. J. Davis Section D McCormick Place Lakeside Room E253A, Level 2 ACS Award in Inorganic Chemistry: Symposium in Honor of Sheldon Shore T. P. Fehlner, Organizer,
Presiding
1:30 661. Medical applications of polyhedral boranes. M. F. Hawthorne 2:00 662. Reaction of the [trans-B20H18]2anion with sterically demanding nucleophiles. D. A. Feakes 2:30 663. Aerosol routes to main group nitrides. R. T. Paine, G. Wood, J. F. Janik 3:00 664. Amineborane based chemical hydrogen storage. L. G. Sneddon, M. E. Bluhm, C. W. Yoon, L Alden, D. W. Himmelberger, M. G. Bradley 3:30 665. Homogeneous catalysts and cocatalysts for new materials. T. J. Marks 4:00 666. Rapid changes in the nature of f element reduction chemistry. W. J. Evans 4:30 667. Coordination chemistry of a trispyrazolylborate ligand having hemilabile ether groups with thalium and the group 1 and 2 metals. M. H. Chisholm, J. Gallucci, G. Yaman 5:00 668. Development of new synthetic methodology for emitting materials using hydroboration and synthesis of lumines cent borole in a fully conjugated electronrich system. S. O. Kang, J. Ko 5:30 Concluding Remarks.
Cosponsored with PHYS M. Johnson and C. A. Reed, E. Pines,
Organizers
Presiding
2:00 650. Understanding proton hydrates H+.nH 2 0 using IR spectra. E. S. Stoyanov 2:30 651. Vibrational signatures of the shared proton. J. R. Roscioli, M. A. Johnson 3:00 652. The peripatetic proton: High reso lution spectroscopy and large amplitude tunneling dynamics in jet cooled molecular ions. D. J. Nesbitt, F. Dong, C. Savage 3:30 Intermission. 4:00 653. Hydrogen-bond symmetry in solution: Symmetry breaking by solvation. C. L Perrin
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INOR Section E McCormick Place Lakeside Room E253B, Level 2 One-dimensional Nanomateriais Characterization, Properties and Applications S. Jin,
Organizer
Y. W u and Y. Cui,
Presiding
2:00 Introductory Remarks. 2:05 669. Synthesis of graphite nanorods by CVD method. X-J. Xu 2:25 670. Epitaxial semiconductor nanowires: From materials science to quantum physics and devices. L. Samuelson 3:05 671. Manganese mediated germanium nanowire growth. J. Lensch Falk, E. R. Hemesath, L. J. Lauhon 3:25 672. Synthesis and properties of FeSi and Fe1-xCoxSi alloy nanowires. A. Schmitt, L. Zhu, S. Jin 3:45 Intermission. 3:55 673. Visualizing silicon nanowire com position and carrier transport. L. J. Lauhon 4:25 674. Withdrawn. 4:45 675. Synthesis and physical properties of ferromagnetic semiconducting EuO nanorods. M. J. Bierman, K. M. Van Heuvelen, T. C. Brunold, D. SchmieBer, S. Jin 5:05 676. Optical sensors for DNA-drug interactions: An application of single-walled carbon nanotubes. D. A. Heller, D. Patel, B. M. Martinez, J. H. Choi, M. S. Strano 5:25 677. Core-shell structured silicongermanium nanowires: Charge distribution and band offsets. R. N. Musin, X-Q. Wang Section F McCormick Place Lakeside Room E253C, Level 2 Organometallic Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers S. A. Johnson,
Presiding
1:30 678. Reactions of Ni(l) trialkyl phosphine and NHC complexes with lithium amides. C. A. Laskowski, D. J. Mindiola, V. M. Hue, G. L. Hillhouse 1:50 679. A mechanistic study of C-H bond activation in Ni(l) complexes. S. A. Johnson 2:10 680. Rapid injection NMR: Observation and characterization of Cu (III) intermedi ates in the reaction of lithium dimethylcuprate with alkyl iodides. S. K. Cope, M. D. Murphy, S. H. Bertz, C. A. Ogle 2:30 681. Synthesis and properties of the first characterized vanadium silyl com plexes. A. Shinohara, J. Mcbee, R. Waterman, T. D. Tilley 2:50 682. New group transfer reactions of nickel-carbene and nickel-imido com plexes. N. D. Harrold, R. Waterman, G. L Hillhouse 3:10 683. 3-Coordinate T-shaped Rh(l) complex. K. G. Caulton, A. Verat, H. Fan, M. Pink 3:30 Intermission. 3:40 684. Chemistry of iridium complexes with N-metalated imine reagents. P. Putprasert, J. R. Bleeke 4:00 685. Coordination and reactivity of pyridines bound to a ττ-basic metal frag ment. K. D. Welch, R. C. Klet, W. D. Harman 4:20 686. Design, synthesis and character ization of novel binuclear Ni(ll) complexes with inherent helical chirality. H. Ueki, V. A. Soloshonok 4:40 687. Multiply-bonded functional groups on nickel supported by chelating bisphosphine ligands. V. M. Iluc, G. L Hillhouse 5:00 688. C-H cleavage by a (PNP)lr spe cies. N. P. Tsvetkov, K. G. Caulton
5:20 689. Oxidative addition of C—H and C—S bonds of substituted thiophenes to Cp*RhPMe3 fragment: Experimental and theoretical study. T. A. Atesin, A. W. Myers, K. E. Skugrud, R. Skugrud, W. D. Jones Section G McCormick Place Lakeside Room E253D, Level 2 Structural, Functional and Biomimetic Modeling in Bioinorganic Chemistry K. J. Franz,
Organizer
J. I. Wirgau,
Presiding
1:50 690. Synthesis, characterization, DNA binding and in vivo activity of Ru(ll)/Pt(ll) complexes. A. Jain, B. S. J. Winkel, K. J. Brewer 2:10 691. Novel ligands for metal ion chela tion. Y. Z. Hamada, W. R. Harris 2:30 692. A mechanistic study of ferrioxamine Β reduction by the biological reduc ing agent ascorbate in the presence of an iron(ll) chelator. J . I. Wirgau, B. W. Alderman 2:50 693. Iron coordination chemistry of curcumin and derivatives. D. P. Kennedy, J. Cho, F. Bou-Abdallah, N. D. Chasteen, R. P. Planalp 3:10 694. Macrocylization, sulfenation, and computation explorations of the thiolate carboxyamido NiN2S2 complex Ni(ema)2-. Κ. Ν. Green, S. M. Brothers, C. W. Thomas, Μ. Υ. Darensbourg 3:30 695. N 2 S 3 FeX model complexes of nitrile hydratase: Substrate binding and spin state dependent oxygen reactivity. C. A. Grapperhaus, M. G. O'Toole, M. S. Mashuta 3:50 696. Structural and functional model of the Rieske dioxygenase enzymes. P. D. Oldenburg, C-Y. Ke, L. Que Jr. 4:10 697. Reactivity of synthetic nonheme oxoiron(IV) compounds with hydrocarbon substrates. E. J. Klinker, L. Que Jr. 4:30 698. Accurate quantum chemical calcu lations of Mossbauer isomer shifts and quadrupole splittings and applications to protein structure refinement. Y. Zhang, E. Oldfield 4:50 699. Protein effects on the mechanism of a non-heme iron enzyme: An ONIOM study of isopenicillin Ν synthase. M. Lundberg, T. Vreven, K. Morokuma 5:10 700. DFT Modeling of glutathione peroxidase mimics using solvent-assisted proton exchange. C. A. Bayse 5:30 701. Bis(tert-butylisocyanide) complex of diazaporphyrin showing a unique (d xy ) 2 (d xz , d y 2 ) 3 ground state. Y. Ohgo, S. Neya, H. Uekusa, M. Nakamura Section Η McCormick Place Lakeside Room E255, Level 2 Coordination Chemistry: Characterization and Application D. C. Crans and K. J. Franz, T. Polenova,
Organizers
Presiding
1:30 702. Electronic localization vs. dereal ization exemplified by an isomer pair that contains two dimolybdenum units linked by an oxamidate anion. Q. Zhao, C. Y. Liu, C. A. Murillo, F. A. Cotton 1:50 703. Inorganic-organic materials based on Mn-12. S. L. Stoll, J. E. Mertzman 2:10 704. High-connectivity networks through alkali metal aggregate assemblies. J. J. Morris, B. C. Noll, K. W. Henderson 2:30 705. Mesomorphic and amphiphilic properties of a new class of soft materials bearing carboxylate-supported μ4-οχο tetracupric clusters. R. Shakya, C. N. Verani 2:50 706. Spin exchange effects on the physicochemical properties of tetraoxalene-bridged bimetallic complexes. D. Guo, J. K. McCusker
3:10 707. Ruthenium(ll)bis(terpyridinecarboxylate) linked dimolybdenum paddlewheel compound. N. Singh, M. H. Chisholm, K. Heinze, K. Hempel 3:30 708. Supramolecular allosteric cofacial porphyrin complexes. C. G. Oliveri, N. C. Gianneschi, S. T. Nguyen, C. A. Mirkin, C. L. Stern, Z. Wawrzak, M. Pink 3:50 709. On the challenge of understanding metal-containing amphiphiles with asym metric ligands: The cobalt and the iron cases. C. N. Verani 4:10 710. Preliminary research in Co"/Au and Co"/Pt metallophilic interactions. L. H. Doerrer, R. J. Allenbaugh, A. G. DiPasquale, A. L. Rheingold 4:30 711. Spectroscopic characterization of competitive coordination interactions between liquid crystals, metal salts and dimethyl methylphosphonate that lead to ordering transitions in liquid crystal thin films. K. D. Cadwell, M. E. Alf, N. L. Abbott 4:50 712. Synthesis and study of the mixedmetal supramolecular complexes of Ru(ll) and Pt(ll). S. Zhao, R. Miao, M. Elvington, K. J. Brewer 5:10 713. The use of molecular precursors for the preparation of Pd/Co-alloy nanoparticles. R. Montano-Serrano, R. G. Raptis, M. Charalampos Section I McCormick Place Lakeside Room E256, Level 2 Energy Research in Inorganic Chemistry Cosponsored with SUST D. C. Crans,
Organizer
D. J. Nelson, Organizer,
Presiding
2:00 714. A novel composite of lead oxide/ active carbon for electrochemical supercapacitor. Y-Z. Zheng, M-L. Zhang 2:20 715. Tuning the electronic energies of novel p-benzenedithiol-bis(triimineplatinum(ll)) complexes. B. W. Smucker, R. J. Batrice, W-H. Chen, J. L. Menke, M. Omary 2:40 716. Solubilization of single-walled carbon nanotubes for nanostructure solar cells. T. Zeng, J. Geng 3:00 717. Ti02 nanoparticle/nanowire com posites for dye-sensitized solar cells. Y. Wu, B. Tan 3:20 718. Tailoring the interface to improve VQC in dye-sensitized solar cells. N. R. Neale 3:40 719. Preparation of new photosensitive compounds that link aniline oligomers to tetraphenylporphyrin. P. Spellane, T. E. Nicolas, M. Chan 4:00 720. Silicon nanoparticles: A new hydrogen storage material. D. Neiner, S. M. Kauzlarich 4:20 721. High-P/low-T neutron scattering of hydrogen inclusion compounds. J . Luo, Y. Zhao, H. Xu, L L. Daemen, W. L Mao, R. P. Currier 4:40 722. High pressure gas sorption studies on covalent organic frameworks. H. M. El-Kaderi, Ο. Μ. Yaghi 5:00 723. Comparative evaluation of Ni-, Cu-, and Fe-based oxygen carriers for chemical looping combustion. T. Liu, T. Simonyi, T. Sanders, R. Siriwardane, G. Veser 5:20 724. Improving the sulfur and coke tolerance of Ni cermet materials. J. Kuhn, N. Lakshminarayanan, U. S. Ozkan
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Exploring and Exploiting Nature with
Biomimetics Molecular Recognition and Drug Delivery Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR T U E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Bioinorganic: DNA and RNA D. C. Crans and J. C. Dabrowiak, Organizers 7:00-10:00 725. Synthesis, structural, and biological activities of Phenanthrenequinone deriva tives and their metal complexes. D. Xiao, Z. Afrasiabi, F. Liu, E. Sinn 726. Validation of an LED array for use in DNA photocleavage assays. A. J. Prussin, D. F. Zigler, J. Brown, A. Jain, B. S. J. Winkel, K. J. Brewer 727. Synthesis and spectral studies of new dicationic porphyrins. B. N. Briggs, D. R. McMillin 728. Synthesis of an extended structure porphyrin via Bergman cyclization. L J. K. Boerner, M. Nath, M. Pink, J. M. Zaleski 729. Spectroscopic investigation of metal ion binding to DNA hairpin loops. C. M. Lemon, R. A. Mathews, J. R. Morrow, B. Switala 730. Structure, spectroscopy, and DNA bind ing of a novel molecular light switch, [Ru(phen) 2 (bptt)] 2+ . B. R. Robinson, B. J. Kraft, C. G. Hughes, J. M. Zaleski 731. Platinum phosphato complexes: How they might work as anticancer agents. R. J. Mishur, R. N. Bose 732. Primary investigation of peptide nucleic acid (PNA) duplex structure by NMR spectroscopy. W. He, M. Madrid, R. Gil, C. Achim 733. Incorporation of chelating ligands into nucleic acids backbones. M. M. Rodriguez, M. Knagge, J. Wilker 734. Hydrolysis mechanism and cytotoxicity of NAMI-A derivatives. L. K. Stultz, J. P. Ellison, A. W. Mincher, P. K. Hanson, G. A. Repasky 735. Factors affecting the rate of reaction of platinum(ll) complexes with DNA and protein targets. B. M. Sandlin, Κ. Μ. Williams 736. Ga(lll), In(lll) and Fe(lll) complexes of a new Ν -functionalized macrocyclic chelator with 3-hydroxy-4-pyrone chelating arms. S. G. Sreerama, W-Y. Hsieh, S. Liu 737. Ground state electron transfer in ruthe nium-modified oligonucleotides. P. Wang, T. J. Meade 738. Withdrawn. 739. DNA damage by peroxo-chromium(IV) complexes. R. M. Cordoba, Y. Ahuja, R. N. Bose Section Β Hyatt Regency Chicago Riverside Center Structural, Functional and Biomimetic Modeling in Bioinorganic Chemistry K. J . Franz,
Organizer
7:00-10:00 740. Interaction of nitrogen bases with ironporphyrins' nitrito complexes Fe(Por)(ONO). T. S. Kurtikyan, A. A. Hovhannisyan, G. M. Gulyan, P. C. Ford 741. Palladium conjugates of bis[N-(2,6diisopropylphenyl)imino] acenaphthene ligands against hormone independent breast and prostate cancer cell line. E. Sinn, V. V. Kulkami, F. Ahmed, S. Padhye, F. Sarkar
TECH-75
1N0R
TECHNICAL PROGRAM
742. Novel spin transition between S=5/2 and S=3/2 in highly saddled iron(lll) porphyrin complexes. Y. Ohgo, D. Hashizume, H. Uekusa, T. Ozeki, M. Nakamura 743. Reactions of thioether ligated ferrous porphyrins with diatomic molecules. G. G. Martirosyan, V. H. Chinaryan, A. M. Dalaloyan, T. S. Kurtikyan, P. C. Ford 744. Study of heme-peroxynitrite formation and reactivity. M. P. Schopfer, S. C. Puiu, D. H. Lee, B. Mondai, Κ. D. Karlin 745. Condensation routes to the probably dithiolate cofactor in the Fe-only hydrogenases. J. L. Stanley, T. B. Rauchfuss, S. R. Wilson 746. Mechanism of hydrogen production in [Fe-Fe]-hydrogenase: A density functional theory study. S. Trohalaki, R. Pachter 747. Iron(ll) tetraanthracenylporphyrazine: A sterically hindered complex binds CO but not 0 2 . J. R. Lebenson, J. P. Fitzgerald 748. Control of the Cd(ll) coordination number and geometry in de novo designed pep tides. O. Iranzo, C. Cabello, S. Chakraborty, V. L. Pecoraro 749. Metal complexes with thiolate and imide/ amide coordination using disulfide reactants. C. E. Moore, D. M. Eichhorn 750. Model complexes for mononuclear manganese enzymes with N3 and N 3 0 environments. C. S. Mullins, V. L. Pecoraro, M. Scarpellini, J. Gaetjens, J. W. Kampf 751. The effect of protein structure in regulat ing bimolecular photoinduced electrontransfer rates in designed metalloproteins. J. Fan, M. Y. Ogawa 752. Theoretical investigation of the reduction of (chlorovinyl)cobaloxime complexes and the effects of substitution at the pyridine ligand. J. D. Scanlon, C. J. Cramer, A. D. Follet, Κ. A. McNabb, A. A. Peterson, Κ. McNeill
Section C Hyatt Regency Chicago Riverside Center Coordination Chemistry: Characterization and Application D. C. Crans and K. J . Franz,
Organizers
7:00-10:00 753. Vanadium(lll) scorpionate complexes: Synthesis and reactivity. M. P. Weberski Jr., A. W. Scott, C. C. McLauchlan 754. [ M n 3 0 ] 7 + trianglar core as a building unit for new molecular magnets. C-l. Yang, W. Wemsdorfer, G. Chung, Y-J. Tsai, G-H. Lee, H-L. Tsai 755. Triarylboron adducts of "magic" carboxylic acids: Structures and luminescent properties. A. Arbaoui, C. Redshaw, M. R. J. Elsegood, D. L. Hughes, M. Green 756. TTDA-like Gd(lll) complexes: Syntheses, physicochemical characterization, water exchange dynamics, and their interaction with human serum albumin. Y-M. Wang, M-H. Ou, Y-M. Chen, Y-H. Chang, X-Y. Huang 757. Synthesis, characterization, and enzyme inhibition studies of vanadium coordination complexes containing heterocyclic tridentate ligands. B. A. Greiner, L. M. Manus, C. C. McLauchlan 758. Synthesis, crystal structure and surface photovoltage of a series of Mn(ll) coordi nation supramolecules. L. Zhang, S. Y. Niu, J. Jin 759. Synthesis, structure and surface photovoltage of two manganese coordination polymers. L. P. Sun, S. Y. Niu, J. Jin 760. Structure and mechanism of β-galactosidase-activated MR contrast agents. L. M. Urbanczyk-Pearson, T. J. Meade 761. Synthèse, crystal structures and photophysical properties of three Cd(ll) coordination polymers. Y. X. Chi, S. Y. Niu, J. Jin 762. Phototriggered S - 0 isomerization of a ruthenium-bound chelating sulfoxide. D. P. Butcher Jr., A. A. Rachford, J. L. Petersen, J. J. Rack 763. Platinum(ll) alkoxyterpyridine salts as vapochromic sensors: Synthesis, photophysics and sensing properties. S. Kinayyigit, F. N. Castellano
76-TECH
764. Platinum(ll) diimine diacetylides. F. Hua, S. Kinayyigit, F. N. Castellano 765. Reactions of metal oxo compounds with alkylating agents: Carcinogen interception and implications for cancer prevention. J. M. Fautch, S. M. Gentry, Ε. Ε. Hamilton, J. J. Wilker 766. Magnetic and structural properties of a heteronuclear uranyl core with salicylidenimine ligands. C. Schmiesing, F. Liu, E. Sinn 767. Metal-containing surfactants and func tional materials as precursors for Langmuir-Blodgett and self-assembled mono layers. S. Hindo, C. N. Verani 768. Metallocomplexes of photoactive ligands for photodynamic therapy. T. G. Gray 769. Mixed-ligand coordination species: A promising approach for "second genera tion" drug development. Z. Ma, B. Moulton 770. Niobium and tantalum based ethylene polymerization catalysts bearing methylene or dimethyleneoxa bridged calixarene ligands. C. Redshaw, M. Rowan, D. M. Homden, M. R. J. Elsegood, T. Yamato, C. P. Casas 771. NMR and X-ray crystallographic studies of divalent zinc triad metal ions coordi nated with multidentate ligand 2,6-bis[((2pyridylmethyl)oxy)methyl]pyridine. D. B. Tice, D. C. Bebout, R. D. Pike 772. pH-Controlled assembly of copper(ll) complexes with ω-hydroxy-functionalized /V-salicylidenehydrazides: Switching between dimers and 1-D coordination polymers. A. Roth, A. Buchholz, W. Plass 773. Ligand substitution on hexamolybdenum clusters and characterization using MALDITOF mass spectrometry. J. W. Guernsey, V. F. Scalfani, C. C. Raymond 774. Mer-[MCI 3 (Me 2 pzH) 3 ] (M = Rh, Ir; Me 2 pzH = 3,5-dimethylpyrazole): X-ray structures, spectroscopic properties, and density functional theory (DFT) calcula tions. W. A. Howard, G. W. Cushing, K. Pang 775. Investigation of nickel-bromide com plexes with Siwu. M. J. DeVries, D. A. Vander Griend 776. A tripodal ferrocenesulfonamide anion sensor derived from 1,3,5-tris(aminomethyl)-2,4,6-triethylbenzene. T. Lopez, K. Kavallieratos 777. Anion assisted supramolecular selfassembly using pyridine-4-acetamide (PAT) as a high yielding reagent. Z. Ma, B. Moulton 778. Arylimido tungsten tetrachloride com plexes: Preparation, characterization, and assessment of bonding and charge distri butions supported by DFT calculations. J. C. Duhacek, T. A. Siddiquee, R. Sniatynsky, D. C. Duncan 779. Autoxidation of a zwitterionic cobalt (II) pincer ligand complex: A hydrogen atom transfer oxidation pathway. C. A. Campbell, M. Wicholas 780. Carbon-sulfur bond formation via alkene addition to an oxidized ruthenium-thiolate. K. B. Venna, C. A. Grapperhaus, M. S. Mashuta, S. Poturovic, P. M. Kozlowski 781. Chloro and pyridine derivatives of rhenium(l) bipyrazine tricarbonyl complexes. R. Kirgan, M. Simpson, C. E. Moore, D. P. Rillema 782. Coordination compounds of the late first row transition metal ions with a ir/s-pyrazolylborate ligand having ether appendages. J. M. Brenneman, M. H. Chisholm, J. Gallucci, G. Yaman 783. Degradation of β-carotene catalyzed by vanadium(V)-comp!exes. T. Jakusch, V. L. Pecoraro 784. Development of iron-based MRI contrast agents. L. Rivera-Millan, K. Gonzâlez-Nieves, A. Lugo-Quintero, R. Gonzalez, R. G. Raptis 785. Effects of neighboring substituents on the acid-base properties of ruthenium complexes. A. Baba, S. Timm, E. Sueva, S. Baker, S. Jolley 786. Electron and energy transfer in platinum(ll) polyimine complexes bearing aryland ferrocenylacetylide units. S. Kinayyigit, D. V. Kozlov, F. N. Castellano 787. Withdrawn.
788. Influence of ligand structure on Fe(ll) spin-state and redox rate in cytotoxic tripodal chelators. J . Cho, M. Childers, C. A. Regino, M. W. Brechbiel, A. G. DiPasquale, A. L. Rheingold, S. V. Torti, F. M. Torti, R. P. Planalp 789. Influence of second-sphere coordination on the properties of metal complex: Inclusion complex of cyclodextrin derivatives with Fe(lll) centered functional model of catechol dioxygenase. H. Park 790. Interactions between cortisone and metal ions: Infrared and Raman spectra. B. Kamara, N. Phambu 791. Synthesis and crystal structure of one 1,3-Diamino-2-propanol Schiff-base binuclear cooper complex: [Cu2L(N03)2]. H. Fu, J . Dou, D. Li, D. Wang 792. Synthèse and crystal structure of novel 2-D nickel N-(2-carboxyphenyl)iminodiacetate polymer: [K2Ni2(cipda)2(H20)4] n. H. Li, J . Dou, D. Li, D. Wang
Coordination Chemistry: Synthesis
810. Synthesis, characterization and comparison of ruthenium(ll) complexes of tetradentate thioether- and pyridine-containing ligands and bidentate nitrogen coligands. A. W. Addison, G. T. Reeves, R. J. Butcher, A. D. Hunter, V. V. Pavlishchuk, M. Zeller 811. Synthesis, characterization and coordination chemistry of 1,3-Bis-(3,5-dibutylpyrazol-1-yl)-propan-2-olate. R. Littich, R. Eaves, F. T. Ladipo 812. Synthesis.structures and thermal property of the Cucunbituril[6] based polyrotaxanes assisted by metal ions. H. Chen, M. Zhao, Z. Wang 813. The metal binding chemistry of the carbahemiporphyrazines. S. Sripothongnak, A. Cetin, W. S. Durfee, C. J. Ziegler 814. Water ligated Iron(lll) bis-pocket siloxylporphyrin. M. Fang, K. S. Suslick 815. Early-late transition heterometallic compounds based on the tripodal-amido phosphine ligands . H. Han 816. Synthesis of novel bis-bidentate ligands that include methylene dianiline. C. Hsu, A. E. Gibbs, M. A. Benvenuto 817. Complexes of pyridine /V-oxide multidentate ligands as promising catalysts. J. G. Leasure, A. Loveitt, P. Baran
D. C. Crans,
Section Ε
Section D Hyatt Regency Chicago Riverside Center
Organizer
7:00-10:00 793. Troge^s base: A versatile platform for assembling novel coordination complexes. C. Hoffman, D. L. Jameson 794. A new family of tripodal amine-based ligands. M. B. Jones, C. E. MacBeth 795. Assessing guest selectivity within metallacrown host compartments. C. Lim, A. Cutland Van Noord, J. W. Kampf, V. L. Pecoraro 796. Cation-guest induced alteration of the spectroscopic properties of picolinehydroxamate-based 15-metallacrown-5 host-complexes. G. Mezei, J. W. Kampf, V. L. Pecoraro 797. Chiral copper(l) phenanthroline derivatives. K. L. Cunningham, T. C. Berto 798. Conformational preference of enterobactin and derivatives. C. E. Godinez, A. Oganesyan, R. Amador, A. Garcia, C. G. Gutierrez 799. Coordination chemistry of diterpyridine ligands bridged by a Troger's base platform. M. Belowich, D. L. Jameson 800. Crystallographic and spectroscopic studies of [Re(CO) 3 L 3 ] + compounds. C. J. Ziegler, R. S. Herrick, A. Cetin, B. R. Franklin 801. Designing ditopic ligand systems for heterobimetallic complex formation. E. J. Brown, S. Lense, C. E. MacBeth 802. Group 6 metal carbonyl complexes of a family of bulky phosphines: Spectroscopic and structural studies of (CO) 5 M[RP(SiMe 3 ) 2 ] (M = Cr(0), Mo(0), W(0); R = H, Ph, SiMe 3 ). A. C. Hinkle, C. P. Rooney, J. L. Wade, M. L. Helm 803. Hydrothermal synthesis and structure characterization of the organic templated metal iodates. X. Liu, G. Li, M. Bi, L Gao, Z. Shi, S. Feng 804. New bis(pyridyl) ligands and their metal complexes with transition metal salts. C. J. Rissing, D. Y. Son, H. Zhang 805. Ortho-metallated nitrogen bases at rhenium polyhydride centers. G. A. Moehring, K. Blaskie, D. Chalsani, J. Plucinski, A. Strepka 806. Reactions of carbon dioxide and carbon disulfide with dtbpe complexes of Ni(0) and Ni(l). J. S. Anderson, V. M. Hue, G. L Hillhouse 807. Structure, properties, and reactivity of the first hexanuclear copper(l) planar ring complex. Y. Sevryugina, D. D. Vaughn II, A. Y. Rogachev, M. A. Petrukhina 808. Synthesis and coordination chemistry of a chiral guanidinate ligand. A. Mohammad, L. Messerle 809. Synthesis and coordination chemistry of novel multidentate Fe(ll) phosphine complexes. A. S. Kirk, A. D. Burrows, M. K. Whittlesey, M. F. Mahon, G. Kociok-Kohn
Hyatt Regency Chicago Riverside Center Electrochemistry in Inorganic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 818. What plays a stronger role on the redox properties of Fe 8 (p 4 -0)4(p-4-RPyrazolate)-|2L4 clusters: Pyrazole sub stituents (R) or change on peripheral ligands (L)? D. M. Pinero, I. Chakraborty, P. Baran, R. G. Raptis 819. Redox-induced reversible solid-solid phase transformation of microcrystalline TCNQ into semiconducting Co[TCNQ]2(H20)2 nanowires network. A. Nafady, A. M. Bond 820. Room temperature synthesis of Pt-Ru/ CMK-3 catalyst with high alloying for the methanol oxidation. W. Wu, J . Cao, G. Ji, F. Zhang, J. Tao, T. Lu 821. Study on Ni-Cr alloy electrodepositing technology on Fe substrate and coating performance. L. Xu, J. Du, Q. He, J. Tang, N. He, S. Li 822. Tuning the potential for electron transfer: Polypyridyl ruthenium complexes with oxime ligands. E. T. Bell-Loncella 823. Electrochemical studies of ruthenium ammine complexes attached via short dithiocarbamates to gold electrodes. A. L. Eckermann, T. J. Meade 824. Influences of complexant on electro chemical behaviors of Fe-Ni-Cr codeposition. J. Du, L Xu, N. He, H. Chen, S. Li 825. Preparation of new molecular wires for photovoltaic cell using photosystem I. M. Miyachi, Y. Yamanoi, H. Nishihara 826. Studies of graphitic mesoporous carbon in electrochemical capacitor application. W. Xing, S. Zhuo, H. Cui 827. Study on the electrochemical behaviors of electrodepositing Ni-Cr alloy. L. Xu, J. Du, Ν. He, Q. He, J. Tang, S. Li 828. Surface-enhanced Raman studies of the oxygen reduction reaction on platinum and silver surfaces. E. E. Eibergen, A. Gewirth 829. Electrochemical probes of weak interac tions in ligand-receptor pairs. K. D. Barker, A. L Eckermann, D. Georganopoulou, T. J. Meade
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INOR
830. Electrochemical sensing of Pb(ll) by small ferrocenylated peptide analogs containing cysteine (C) and glutamic acid (E). P-G. Samuda, F. Ros, K. Kavallieratos 831. Electrochemistry in deep eutectic solvents. R. J. LeSuer, C. A. Nkuku 832. 4-Oxocyclohexadienylidene-substitued porphyrinogen as an electrochemical anion receptor. A. Schumacher, F. D'Souza, M. E. Zandler, P. A. Karr, J. P. Hill, K. Ariga 833. Electrocatalytic oxidation of tyrosine: Rate-limiting PT and MS-EPT. C. J. Fecenko, T. J. Meyer, H. H. Thorp 834. Electrochemical and spectrophotometric characterization of novel ferrocene derivatives. R. D. A. Cardona, A. R. Guadalupe, I. Montes, M. D. M. Garcia-Maldonado, L. E. Pedro, T. L. Diaz, L. I. Vargas, C. M. Rivera, C. Acosta 835. Electrochemical behavior of copper in the presence of benzotriazole and sulfide ions. F. M. AI Kharafi, A. M. Abdullah, B. G. Ateya 836. Electrochemical oxidation of disilver(l) complexes. R. J. LeSuer, B. Davis, C. He, Z.Li
General Inorganic Chemistry
848. High-valent ruthenium oxides: Toward the development of light-driven oxidation catalysts. J. M. Butler, J. R. Schoonover, T. J. Meyer 849. Hydrogen atom transfer to high valent manganese(V) imido corroie. J. L. Dexheimer, M. J. Zdilla, M. M. Abu-Omar 850. Hydrolysis and alcoholysis of silanes catalyzed by oxorhenium(V) oxazoline. R. A. Corbin, E. A. Ison, M. M. Abu-Omar 851. Inherent pitfalls in the simplified evalua tion of kinetic curves. I. Nagypâl, B. Kormânyos, G. Peintler, A. K. Horvâth 852. Low-temperature catalytic combustion of trichloroethene over cerium oxide. X. Wang 853. Model complexes for the Α-cluster of CODH/ACS. D. M. Eichhorn, J. R. Zimmerman 854. Oxidation of cyclopentene to glutaric acid by H202 over ammonium tungstate. M-H. Ji, H-M. Shu, Z-A. Liu, F-Y. Guo, H-M. Li 855. Rational organization of nanoscale catalysts for advanced chemical transfor mations. C. G. E. Ciptadjaya, S. O. Obare 856. Synthesis, structure and reactivity of a C3-trinuclear zinc(ll) hydroxide catalyst efficient at phosphate diester transesterification. R. Mitra, M. W. Peters, M. J. Scott 857. The bleaching effects of seven-coordi nate compound catalysts on pinacyanol chloride dye. J. H. Davis, K. L. Tate
D. C. Crans,
Section H
Section F Hyatt Regency Chicago Riverside Center
Organizer
7:00-10:00 837. Withdrawn. 838. Comparative study of the Mn(ll) zerofield interaction parameters of structural models for mononuclear manganese containing enzymes. G. Jessica, V. L. Pecoraro, L. Tabares, S. Un, P. Thuéry 839. Inorganic nitrite: Metamorphosis from villain to benefactor. B. O. Fernandez, N. S. Bryan, M. F. Garcia-Saura, D. R. Janero, J. Rodriguez, M. Feelisch 840. Organophosphines bearing pendant acetylenes. S. Greenberg, D. W. Stephan Section G Hyatt Regency Chicago Riverside Center Development and Studies with Inorganic Catalysts K. Kustin,
Organizer
7:00-10:00 841. Ti02-Ce02 mixed oxide catalysts for iso-C4 hydrocarbon synthesis from syngas. Z. Zhu, D. He 842. Characterization of 7-alumina supported manganese oxides prepared by grafting and impregnation. D. P. Eyman, N. J. Schoenfeldt 843. Characterization of grafted vanadium and zirconium oxides on -γ-alumina sur face. D. P. Eyman, A. Saha 844. Chromophoric and catalytic supramolecular assemblies of conjugated porphy rins. R. A. Jensen 845. Effect of catalysts on reduction of ilmenite. W. Li, Z. Yuan 846. Factors affecting the reactivities of fer rous porphyrins. K. C. Shaw, S. O. Obare 847. Green process for alkene epoxidation: Catalysis by N a 2 W 0 4 / H 2 W 0 4 under mild conditions. M. H. Repollet-Pedrosa, H-J. Lee, B. Subramaniam, D. H. Busch
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Hyatt Regency Chicago Riverside Center Energy and Environmental Inorganic Chemistry Cosponsored with SUST D. C. Crans and D. J. Nelson,
Organizers
7:00-10:00 858. Dependence of rates of interfacial elec tron transfer on anchoring group and dye MLCT state energy. R. Gadziala, D. L. Mohler 859. Distance dependence of photoinduced interfacial electron transfer. M. Alvey, K. A. Moler, D. L. Mohler 860. Heteroleptic ruthenium(ll) terpyridyl complexes for dye-sensitized solar cells. Y. Sun, F. N. Castellano 861. Ordered uniform macroporous carbons with mesoporous walls as catalyst support in PEM fuel cell. J-S. Yu, J. H. Kim, M. S. Kim, Y. A. Song, B. Fang, S. B. Yoon 862. Plasmon amplified absorption in dyesensitized solar cells. S. D. Standridge, G. C. Schatz, J. T. Hupp 863. Binding of tetrahedral anions with native and derivatized a-cyclodextrins. S. Harwani, J. R. Telford 864. Carbon dioxide fixation by a cadmium(ll) macrocyclic complex. M. E. Botros, G. J. Grant, D. E. Janzen 865. Determination contents of hydrogen sulfide in gas medium. D. Kurbanova, Z. Normurodov 866. Kinetic and mechanistic studies of an iron(O) model complex with halogenated hydrocarbons. K. A. Thoreson, A. D. Follett, K. McNeill 867. Lung edema caused by brief inhalation of high concentration nitrogen dioxide in awake rats. Z. Gu, A. J. Januszkiewicz, T. I. Atkin, V. I. Morthole, G. D. Coleman 868. Metal ion adsorption on functionalized nanocrystalline zeolitie materials. K. N. Barquist, S. C. Larsen 869. Photocatalytic degradation of organic pollutants by monovacant phosphotungstate under visible-light irradiation. H. Shu, S-X. Luo, M-H. Ji, J-M. Xie 870. The sensor for determination of concen tration gas component in the mixture of gases. N. Hamraev, Z. Normuradov
Section I Hyatt Regency Chicago Riverside Center Chemistry of Lanthanide and Actinide Systems S. Liu,
Organizer
7:00-10:00 871. 155Gd, 166Er and 237Np Mossbauer spectroscopic studies on the structure and bonding of lanthanoide and actinoide compounds. J. Wang Sr. 872. A structurally characterized family of hetero-ligated lanthanide guanidinate compounds. T. L Cleland, S. D. Bunge, J. A. Bertke 873. Cerium complexes supported by fer rocene diamide ligands. E. M. Broderick, P. L. Diaconescu 874. Characterization of Group 3 and lan thanide oxide powders formed via precipi tation stripping. P. M. Smith 875. Diamide-pyridine bearing nonadentate ligand systems for the acid extraction of Ln(lll)/An(lll) systems. O. Ozbek, M. J. Scott 876. Exploratory solvatothermal synthesis of lanthanide carboxyborate complexes. G. C. Schaub, C. C. Raymond 877. Exploring the reactivity of ferrocene diamide uranium alkyl compounds. N. P. Gutzwiller, P. L Diaconescu 878. Lanthanide alkoxide complexes sup ported by rigid multidentate nitrogen ligands. M. J. Monreal, P. L. Diaconescu 879. New pathway for through-space metalmetal interaction in heterobimetallic com plexes. R. Raturi, S. A. Johnson 880. One-pot synthesis of imaging agents by multicomponent reactions. M. Jauregui, S. Faulkner 881. Optically active cerium complexes for the asymmetric α-hydroxylation of β-dicarbonyl compounds. M. Niemeyer, J. W. Seo, C. von Biihler, J. Christoffers 882. Polymer-bound Gd(lll)-chelates as con trast agents for magnetic resonance imag ing. M. J. Allen, W. F. Block, R. T. Raines, L. L. Kiessling 883. Pu(IV) complexes with N-hydroxy-2pyridinone, maltol, and bromomaltol: Synthesis and structure. G. Szigethy, A. E. V. Gorden, J. Xu, D. K. Shuh, Κ. Ν. Raymond 884. Structural, spectroscopic and computa tional study of monoporphyrinate lan thanide complexes. H. He 885. Structure-relaxivity study of glycopolymers containing gadolinium(lll) chelates as MRI contrast agents. R. L. Lucas, T. M. Reineke 886. Syntheses and characterization of mac rocyclic lanthanide complexes. P. K. Yuen 887. Synthesis and characterization of a series of novel lanthanide guanidinate complexes. J. A. Bertke, S. D. Bunge 888. Unusual metal-metal interactions in lanthanide(lll) complexes. T. N. Dawkins, I. A. Kahwa 889. X-ray crystal structure of tetrakis(?ertbutyl)erbate(lll) and attempts to oxidize tetrakis(tert-butyl)terbate(lll). W. Noh, G. S. Girolami Section J Hyatt Regency Chicago Riverside Center Main Group Chemistry D. C. Crans,
Organizer
7:00-10:00 890. Heavy alkaline earth metal tetraphenylborate complexes: From solvated ion triples to ττ-bonded contact molecule. J. Hitzbleck, M. A. Guino-o, A. Verma, K. Ruhlandt-Senge 891. Olefin activation by sterically demanding phosphines and boranes. J. S. J. McCahill, D. W. Stephan 892. Reactions of small molecules with main group metal bis(silylamides). B. Boro, J. Saria, A. M. Felix, Y. Tang, B. J. Frost, R. A. Kemp
893. Synthesis of nitrogen-boron ambiphilic ligands. M. A. Pudenz, J. D. Hoefelmeyer 894. Di(3-methylindolyl)methane complexes of aluminum and gallium. A. Das, B. N. Fneich, N. Kingsley, K. Kirschbaum, M. R. Mason 895. Halonium cations stabilized by carborane anions. C. A. Reed, E. J. Stoebenau III, K-C. Kim 896. Heavy alkaline earth metal amides as precursors for CVD: Effects of ligand size. A. Torvisco, K. Decker, M. M. Gillett-Kunnath, K. Ruhlandt-Senge 897. Ionic liquids: Novel solvents in alkaline earth metal chemistry? M. A. Guino-o, J-C. Leye, K. Ruhlandt-Senge 898. Low oxidation state Group 15 com pounds: Approaches to new P-containing polymers. E. L. Norton, B. D. Ellis, C. L. B. Macdonald 899. Magnesiates: An examination of ligandsize and donor effects. M. F. Zuniga, G. B. Deacon, K. Ruhlandt-Senge 900. Small peptides containing cysteine (C) and glutamic acid (E) residues as Pb(ll) fluorescent sensors. F. Ros, P-G. Samuda, K. Kavallieratos 901. The reaction of Li 2 S with unsaturated carbonyls: A safe alternative to H 2 S. R. J. Zimny, M. J. Prushan 902. Toward transition-metal free hydrogénation of organic substrates: Utility of dihydrogen activating phosphine-boranes in catalysis. P. A. Chase, G. C. Welch, D. W. Stephan 903. Weakly coordinating funtionalized carborane anions via hydroboration. E. Molinos, A. S. Weller Section Κ Hyatt Regency Chicago Riverside Center Materials Chemistry D. C. Crans,
Organizer
7:00-10:00 904. Influence of buffer layer on the morphol ogy of ZnO films deposited from aqueous solution. J. Luo, X. Liu 905. Selective detection of trace nitroaromatic, nitramine and nitrate ester explosive particulates using a three-step fluorimetric sensing process. J. C. Sanchez, S. J. Toal, Z. Wang, W. C. Trogler 906. Structures of vinyl polyhedral oligomeric silsesquioxanes (ViSi0 1 5 ) n with n = 8, 10, 12 and 14. Τ. Ν. Lenton, A. Vij, W. Grabow, J. M. Mabry, T. S. Haddad 907. True blue: A series of blue-emitting AI3+ quinolinolate complexes. P. Anzenbacher Jr., C. Pérez-Bolivar 908. Resonance states and nanostructuring in thermoelectric compounds PbxCd1-xTe and SnxCd1-xTe (x = 0.01-0.03). M-K. Han, S. Ahmad, S. D. Mahanti, M. G. Kanatzidis 909. Self-assembled porphyrin monolayers at metal and metal oxide nanoparticle interfaces: Effect of nanoparticle size on the reactivities. A. M. Leonard, S. O. Obare 910. Solid state ionic conductivity of derivatives of polyhedral borane anions. D. Stasko, S. Grecenko, J. Swenton 911. Sonochemical synthesis of nanosized hollow hematite. J. H. Bang, K. S. Suslick 912. Structures and magnetic properties of frameworks made of transition metals and benzenepentacarboxylate linkers. X. Wang, M. Scancella, S. C. Sevov 913. Synthesis, photophysics and gel formation of terpyridyl Pt(ll) complexes covalently linked to a naphthalene diimide. D. Kumaresan, K. Lebkowski, R. H. Schmehl 914. Thioantimonates with permeable and impermeable [M 2 Sb 2 Q 7 ] 2 " (M = Ga, In; Q = S, Se) layers. N. Ding, M. G. Kanatzidis 915. Halogen bonding involving sulfur-based donors. H. D. Arman, J. J. Kimrey, J. D. Buck, S. H. Dunaway, S. C. Hill, L. L Glish, T. W. Hanks, W. T. Pennington 916. Metal-organic and covalent organic frameworks (MOFs and COFs) as adsorbents for environmentally significant gases (H2, C02, and CH4). H. Furukawa, H. M. El-Kaderi, K. S. Park, J. R. Hunt, J. L. Mendoza-Cortés, A. P. Côté, O. M. Yaghi
TECH-77
TECHNICAL PROGRAM
INOR 917. Novel metallic and bimetallic crosslinked poly (vinyl alcohol) nanocomposites pre pared under microwave irradiation. R. S. Varma, M. N. Nadagouda 918. PL properties of [Eu(bpy) 2 ]CI 3 doped mesoporous materials. N. He, S. Ge, J. Wang, S. Li 919. Recent progress in carbon nitride struc tural analysis and investigation of its utility as a metal coordination material. J. R. Hoist, E. Gillan 920. Removal of polymeric template from cage-like mesoporous silica (SBA-16) with incorporated isocyanurate rings. R. M. Grudzien, M. Jaroniec 921. Design, synthesis, and characterization of electrochemically-active metal-organic frameworks for hydrogen storage applica tions. K. L Mulfort, J. T. Hupp 922. Development of polymerizable lyotropic liquid crystal (LLC) compounds with fluo rescent chemical sensing capabilities. K. L. Klinkel, W. Seo, D. L. Gin 923. Efficient acid-base bifunctional meso porous catalysts for Henry reaction or nitroaldol condensation. T. Asefa, K. K. Sharma 924. Fabrication and characterization of new photovoltaic materials: Culn x B-|. x Se 2 (CIBS) and CuBSe 2 (CBS). S. A. Darveau, J. Olejnicek, C. L. Exstrom, R. J. Soukup, N. lanno 925. Isostructural dopants for tetraarylporphyrin molecular semiconductors. D. L. Turner, T. P. Vaid 926. Mesoporous structures based on germa nium. G. S. Armatas, M. G. Kanatzidis 927. Use of luminescent probes for compari son of supercritical extraction techniques in silica aerogel preparation. M. K. Carroll, A. J. Barrow, J. R. Ferrarone, S. G. Gorman, A. F. Phillips, A. M. Anderson 928. Using supercritical drying to prepare evacuated, microporous metal-organic frameworks. A. P. Nelson, J. T. Hupp 929. Zwitterionic mesogens derived from the [closo-λ -CB 9 H 10 ]" and [c/oso-1-CBnH^]". P. Kaszynski, B. S. Ringstrand, A. Januszko, S. Pakhomow 930. Microwave-assisted synthesis of phase pure YFe03 nanocrystalline. L. Xiaomeng, X. Jimin, L. Jun Section L Hyatt Regency Chicago Riverside Center Nanoscience: Characterization and Applications B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 931. Superparamagnetic multimodal probes for magnetic resonance imaging. E. A. Schultz, E. K. Kohlmeir, P. J. Endres, J-H. Lee, M. Aslam, J. Cheon, V. P. Dravid, T. J. Meade 932. Phototransformation and relaxation dynamics of Ti02/Ag nanocomposites dispersed in water. M. R. Kim, W. I. Lee, D-J. Jang 933. Preparation and characterization of platinum binary and ternary alloy nanoparticles. E. Ding, L. Xiong, T. He 934. Reversible carbon nanotube gas sensor and its application. C. Y. Lee, R. Sharma, M. S. Strano 935. Nanostructured alloy catalysts for oxygen electroreduction in PEMFC. L. Xiong, T. He 936. On-wire lithography. L. Qin, C. A. Mirkin 937. Synthesis and characterization of novel nanostructured thermoelectric materials. X. Qiu, C. Burda 938. Synthesis of rutile (α-ΊΠ02) nanorods with controlled size and morphology by forced hydrolysis of TiCI 4 : Effects of tem perature and acidity. W. Wang, B. Gu, D. J. Wesolowski, J. Rosenqvist, L. M. Anovitz 939. The effect of rare earth doping on titania nanoparticles. P. Lin, L. Zheng 940. Size-dependent magnetic properties of single-crystalline multiferroic BiFe0 3 nano particles. T-J. Park, G. C. Papaefthymiou, A. J. Viescas, A. Moodenbaugh, S. S. Wong
78-TECH
941. Thermal and catalytic degradation of stabilizing polymers on nanoparticles and films investigated by Raman spectroscopy and TGA. A. G. Dylla, B. W. Eichhom, R. A. Walker 942. Application of microarray for methylenetetrahydrofolate reductase (MTHFR) poly morphisms in the risk of gastric carcinoma of east China population. N. He, S. Li,
M.Ji 943. Selective functionalization of metallic single-walled carbon nanotubes with triazene. W-J. Kim, M. L. Usrey, M. S. Strano 944. Ion and thermally induced DNA confor mational polymorphism on single-walled carbon nanotubes. H. Jin 945. Novel nanoarchitectures for high perfor mance Grâtzel solar cells. J. E. Norris, T. W. Veatch, C. D. Poteet, T. Zeng Section M Hyatt Regency Chicago Riverside Center Organometallic Catalysts B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 946. Thoretical investigation of C8-selective chromium catalysts for ethylene tetramerization. B. Lee, H. W. Bae, H. S. Kim, T. K. Han, M-A. Ok, M. Cheong 947. Redox reactivity of amine-hydrides of iridium. Z. M. Heiden, T. B. Rauchfuss 948. Stopped-flow NMR investigations of catalytic alkene polymerization. M. D. Christianson, C. R. Landis 949. Synthesis and characterization of new palladium complexes containing neopentyl phosphine ligands. L. L. Hill, K. H. Shaughnessy 950. Iridium-catalyzed reduction of organic halides by trialkylsilanes. J. Yang, M. Brookhart 951. Novel rhodium complexes containing arylspiroborate esters as catalyst precursors for the borylation of vinylarenes. N. Halcovitch, R. Burford, M. Geier, S. Geier, D. Kanas, C. Vogels, A. Decken, S. Westcott 952. Progress toward the synthesis of [(Me 2 Si)(PhC=CPh)^ 5 -C 5 H 2 -4-fBu} 2 ]ZrCI 2 . S. D. Thai, N. S. Daundikhed, D. L. Zubris 953. Synthesis, reactivity and structural studies of arylamido titanium complexes. M. A. Blanchard, J. F. C. Turner 954. Asymmetric hydroformylation of enamides and allyl ethers with diazaphospholane-based ligands. R. I. McDonald, R. P. Neupane, C. R. Landis 955. Highly active palladium complexes of O-functionalized N-heterocyclic carbenes (NHC) for Suzuki-Miyaura cross-coupling reaction. L. Ray, P. Ghosh 956. /V-heterocyclic carbene-substituted rhodium and iridium complexes: Structural investigations and their catalytic properties in borylation and hydrosilylation reactions. G. D. Frey, S. C. Zinner, D. von Preysing, E. Herdtweck, W. A. Herrmann 957. A possible homogeneous route to epoxides. R. Lansing, B. Bora, A. Mrutu, K. I. Goldberg, R. A. Kemp 958. Advances in the synthesis of group 4 catalysts for single site olefin polymerization reactions. C. Stanciu, N. Travia, K. Novstrup, W. N. Delgass, J. M. Caruthers, M. M. Abu-Omar 959. Catalytic aziridination of olefins by nonheme iron(ll) complexes. J. A. Halfen, K. L. Klotz, L. M. Slominski, A. V. Hull 960. Chiral cationic Ir(lll) R-BINAP complexes, and their use as catalysts for tandem Nazarov cyclization-Michael addition and Diels-Alder cycloaddition chemistry. A. C. Atesin, B. P. Gilmartin, W. He, A. J. Frontier, R. Eisenberg 961. Ring-opening polymerization of cyclic monomers by biocompatible metal complexes: Production of poly(lactide) and polycarbonates. W. Choi, D. J. Darensbourg 962. Synthesis and characterization of PhP(Ti 5 -i-BuCp) 2 ZrCI 2 : A novel ansazirconocene with a phosphine linker. L. A. Morton, D. L. Zubris
Section Ν Hyatt Regency Chicago Riverside Center Organometallic Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers
7:00-10:00 963. Synthesis of ruthenium bidentate Schiffbase complexes via microwave irradiation. P. E. Guzman, L. Jones II 964. Synthesis and reactivity of paramagnetic, 14-e (PNP)OsX. N. P.Tsvetkov, J-H. Lee, K. G. Caulton 965. Synthesis, NMR spectroscopy, and ligand-substitution equilibria of a set of carbon/nitrogen palladacycles. C. N. Henderson, B. Wicker, M. Stojanovic, N. W. Hoffman 966. Preparation of new mono- and dinuclear platinum complexes. S. C. Borowski, S. Schreiner 967. Mechanisms of competing C-C reductive eliminations from platinum. M. L. Scheuermann, B. S. Williams 968. New reactions of alkynylsubstituted zirconocenes. G. Erker, P. Spies, G. Kehr, R. Frôhlich, C. Muck-Lichtenfeld 969. Nitrile reactivity in tungsten(ll) bis(acetylacetonate) complexes. A. B. Jackson, J. L. Templeton 970. CH Activation reactions at late transition metal half-sandwich complexes. G. Erker, C. Herrmann, G. Kehr, R. Frôhlich 971. Chiral sulfonamide-amino complexes of Ni, Pd, and Pt. A. M. Royer, T. B. Rauchfuss 972. Extension of sweetener-anion coordination chemistry from fluorinated Pd(ll)pincer systems to nonfluorinated Pd(ll) pincers and Pd(ll) palladacycles. B. Wicker, R. Traylor, C. N. Henderson, N. W. Hoffman, R. Sykora, J. H. Davis Jr., B. Jordan, J. Abemethy, O. V. Ozerov, C. Fafard, F. Lei, M. L. Kwan, K. M. Poleski 973. {alpha}-Methylene-{gamma}-butyrolactone synthesis using the hetero-PausonKhand reaction. S. Lawrence, W. E. Crowe 974. Activation of covalent molecules by a water-soluble transition metal complex. E. M. Spero, S. Schreiner 975. Bis(dimethylphosphino)methane synthesis from reaction with aluminum. J. M. Creamean, G. S. Girolami 976. Design of early transition metal hemilabile systems. K. Yadav, D. W. Stephan 977. Design, synthesis, and reactivity of orthometallated acetophenone imine ligands and their niobium (V) complexes. C. L. Seambos, J. A. R. Schmidt 978. Development of new group IV complexes employing bidentate orthometallated acetophenone imine ligands. T. I. Baiz, J. A. R. Schmidt 979. Electrophilic scandium alkyl complexes supported by 1,1' bis-amidoferrocene ligands. C. T. Carver, P. L. Diaconescu Section Ο Hyatt Regency Chicago Riverside Center Solid State Chemistry D. C. Crans,
Organizer
984. Chiral metal organic frameworks. X. Bu, J. Zhang 985. Influenced by the fabricated two-layer structure of silsesquioxanes and titanium tetrabutoxide. L. Hu 986. Mild hydrothermal synthesis and magnetic properties of the manganates Pr1-xCaxMn03 with adjustable dopingrate. Y. Chen, H. Yuan, G. Tian, G. Zhang, S. Feng 987. Polymer-induced heteronucleation for the selection and discovery of polymorphs of platinum complexes. A. L. Grzesiak, A. J. Matzger 988. Preparation and photocatalytic activity of YFe03-Ti02/N nanojunction system. L. Jun, X. Jimin, L. Xiaomeng 989. Recent advances in the fabrication of transparent ceramics. Y. A. Barnakov, Z. W. Kabato, G. Zhu, M. Bahoura 990. Withdrawn. 991. Synthesis and magnetic characterization of ll-V diluted magnetic semiconductors: C d ^ x S b (M = Mn and Co). J. L. Harris, L. V. Shapoval, L. H. Strauss, P. M. Shand, A. J. Van Waardhuizen, J. T. Kirner 992. The selenophosphate quaternaries TI3Sn0.5P2Se6, NaSn1.5P2Se6 and K10Sn3P8Se24. I.Chung, M. G. Kanatzidis Section Ρ Hyatt Regency Chicago Riverside Center Organometallic: General B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 993. Withdrawn. 994. Cationic titanium and aluminum com plexes with hemilabile ligands. M. A. Dureen, D. W. Stephan 995. Detection and alkyne insertion kinetics of a d° Cp 2 Zr(aryl)(alkyne) + complex. S. M. Kilyanek, R. F. Jordan 996. Diethynyldialkylsilanes as starting materi als for new conjugated polymers. C. Rim, D. Y. Son 997. Examining the redox properties of metal carbonyl complexes containing bidentate phosphines with metallocene backbones. J. Berstler, M. J. Shaw, C. Nataro 998. Further studies of the N-C oxidative addition reaction in (PNP)RhCI complexes. A. L. Fernandez, O. V. Ozerov, B. M. Foxman 999. In search of the elusive IT isomers for the N-coordinated pyridine complex TpW(NO)(PMe 3 )(pyridine). R. C. Klet, K. D. Welch, W. H. Myers, W. D. Harman 1000. Preparation and reactivities of a tanta lum alkyl amide imide complex. S-J. Chen, G. P. A. Yap, Z-L. Xue 1001. Preparation of ruthenium hydride hydro génation catalysts. D. A. Jarem, C. Nataro 1002. Withdrawn. 1003. Synthesis and conformational analysis of Cp 2 WHSn(CN)Ph 2 . T. A. Mobley, S. E. Parker 1004. Synthesis, characterization and reactivity of transition metals bearing a new NNN pincer ligand. C. Schâdle, D. J. Mindiola 1005. Time-resolved and chemical trapping determination of singlet oxygen quantum yield generated by metallo-phthalocyanine photosensitization. N. Gandra, R. Gao
7:00-10:00 980. Ln 3 TW0 6 S 3 (Ln = La, Ce; T = Cr, Μη, Fe, Co): Quinary rare earth transition metal oxysulfides - synthesis, structure and physical properties. C. Zheng, K. Klimaszewski, D. N. Bryhan, N. Govani, J. J. Bohac, R. K. Kremer 981. Substitutions in the homologous family CsPb m Bi 3 Te 5 m + 1 . A. Guéguen, M. G. Kanatzidis 982. A microporous metal-organic framework with high hydrogen uptake. X-S. Wang, W. C. Cole, H-C. Zhou 983. Chalcogenides as clay analogs: Layered quaternary chalcogenide materials with exceptional ion-exchange properties. M. J. Manos, N. Ding, M. G. Kanatzidis
Please refrain from using cellular telephones and cameras during technical sessions.
Section Q Hyatt Regency Chicago Riverside Center Nanoscience: Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers 7:00-10:00 1006. Synthesis of Ti02 nanowires for Grâtzel solar cells. C. D. Poteet, J. E. Norris, T. Zeng 1007. Synthesis of hollow zeolite tubes with encapsulated transition metals. R. Kanthasamy, S. C. Larsen 1008. Oxide semiconductor nanorods. C. R. King, A. A. Gewirth 1009. Photogeneration of silver nanoparticle polyoxotungstate hybrid materials. C. Gu, C. Shannon 1010. Synthesis and characterizations of CulnSe2 microspheres composed of the nanosize particles. H-K. Yoon, H-J. Lee, M-S. Seong, J-S. Seol, H. Pak, T-M. Kim 1011. Synthesis and application of functional graphitic carbon nanofiber/polymer brush hybrid materials. L. Li, C. M. Lukehart 1012. Synthesis and characterization of lyotropic platinum complexes. F. A. Cruz Sanchez, J. C. Noveron 1013. Electrochemical deposition of zinc oxide with ordered nanoporous structures. E. M. P. Steinmiller, K-S. Choi 1014. A novel approach of preparation of (Fe 3 04/PVA-DVB)/Si0 2 magnetic nanocompositions. Y. Guo, N. He, Z. Wang, S. Li 1015. Assembly of vanadium oxide nanorod film for integrated nanosystems. L. Mai, W. Guo, W. Jin, Y. Dai, B. Hu, E. Gu, Y. Gao, W. Chen 1016. Novel heterometallic 3d-4f singlemolecule magnets: Synthesis, structure and magnetic properties of [Mnlll10Lnlll2] complexes. R. Bagai, K. A. Abboud, G. Christou 1017. A green chemistry approach to preparation of core (Fe or Cu)-shell (noble metals) nanocomposites using aqueous ascorbic acid. R. S. Varma, M. N. Nadagouda Section R Hyatt Regency Chicago Riverside Center Spectroscopy in Inorganic Chemistry D. C. Crans and S. L. Michel,
Organizers
7:00-10:00 1018. 13C DOSY studies of solution structures of lithium diisopropylamide and alkali hexamethyldisilazides. D. Li, J. Liu, P. G. Williard 1019. 2-D and computational analysis of the 1 H NMR spectrum of the bis(2,2'-bipyridine)carbonatocobalt(lll) ion: Elucidation of cisltrans influences. S. E. Schmidt, S. A. Angel, A. Keller, Z. Kramer 1020. 35 GHz CW and pulsed ENDOR spectroscopy of a novel diiron imide-hydride complex. R. A. Kinney, C. Saouma, J. C. Peters, Β. Μ. Hoffman 1021. 1 1 9 Sn relayed 1 H-X correlation spec troscopy. T. A. Mobley, E. G. Tennyson, B. N. Williams, K. H. Pannell 1022. A structure-reactivity relationship for single walled carbon nanotubes reacting with 4-hydroxybenzene diazonium salt. N. Nair, W-J. Kim, M. L. Usrey, M. S. Strano 1023. Axial shielded platinum(ll) charge transfer complexes: An excited state absorption study. E. Shikhova, F. N. Castellano 1024. Effect of the E11 amino acid on the ligand binding in Hbl from Lucina pectinata. L B. Granell, R. Pietri, A. Cruz, C. L. Cadilla, J. Lopez 1025. ENDOR spectroscopy of a low coordi nate iron model of nitrogenase. N. S. Lees, W. Vargas, J. Vela, C. Flaschenriem, P. L. Holland, Β. Μ. Hoffman 1026. Fractional bond order of 1/2 in Pd25+ formamidinate species: The value of very high field EPR spectra. S. Ibragimov, F. A. Cotton, C. Murillo, N. Dalai
1070. Theoretical identification of the interme diates and the reaction mechanism in the carbon-hydrogen bond activation by the photochemically generated hydrotris(3,5dimethylpyrazol-1-yl)borato carbonyl rho dium. M. B. Hall, C. E. Webster, S. D. Zaric 1071. Theoretical structural and electrical analysis of 7-coordinate and octahedral systems using GAMESS. J. R. Barker, J. Davis, M. Salazar 1072. 1 H-NMR investigations of paramagnetic Quinolyl-Cp-Chromium(lll)-complexes: Prediction of hyperfine shifts by hybrid density functional calculations. M. Enders, P. Fernandez, P. Hofmann, J. J. Carbo
1027. Interaction of a negatively charged molecular probe with a positively charged reverse micellar interface. J. B. Saeger, B. Barauh, D. Crans, N. E. Levinger 1028. Properties of reverse micelles made with AOT with different cations. M. L Stahla, B. Baruah, M. Sedwick, D. Crans, N. E. Levinger 1029. Proton transfer in the charge-transfer state dynamics of Ru" polypyridyl com plexes. D. J. Dupuis, J. K. McCusker 1030. Spectroscopic investigations of diiron model complexes. J. Tate, M. D. Edington, T. Word 1031. Spectroscopic studies of the active-site electronic structure of the dioxygen-transport protein hemerythrin. G. Lalanne, C. D. Stafford II, M. D. Edington 1032. Surface enhanced Raman spectros copy applied to inorganic compounds. J. E. Tylko, M. L McCormick, T. E. Elgren 1033. Synthesis and photophysical properties from tungsten-alkylidyne/zinc-porphyrin dyads. B. W. Cohen, S. D. Cummings, R. F. Dallinger, M. D. Hopkins
1046. Quantum/classical dynamics of nuclei and electrons in large systems. S. S. Iyengar 1047. Short O-H-N hydrogen bonding: Quantum mechanical investigation of the isotope and temperature dependence of the hydrogen bonded complex 4-methylpyridine:pentachlorophenol (D0/D1). S. A. Rivera, B. S. Hudson 1048. Structure and hydrogen bonding of monocarboxylic acids intercalated in layered double hydroxides. P. Kumar P, A. G. Kalinichev, R. J. Kirkpatrick 1049. Thermochemical analysis of histidine and its metal and anion complexes. E. Tavasoli, A. Fattahi 1050. Thermochemical properties of the anticancer drug fluorouracil and its derivatives. Z. Rezania, A. Fattahi 1051. Experimental and computational investigations of the photophysical properties of UV-absorbers in sunscreens. S. J. Schmidtke
Section S
Hyatt Regency Chicago Riverside Center
Catalysis Relevant to Energy and Sustainability Cosponsored with FUEL, and SUST
Hyatt Regency Chicago Riverside Center
Theoretical and Computational Chemistry
T. D. Tilley,
D. C. Crans,
B. D. Chandler,
The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Cosponsored with PHYS M. Johnson,
Organizer
C. A. Reed, Organizer,
Presiding
7:00-10:00 1034. Vanadium compounds as probes for studies of protons near lipid-water inter faces. D. C. Crans, N. E. Levinger 1035. 3 5 CI Nuclear quadrupole resonance (NQR) studies of chlorinated weakly coor dinating anions. G. P. Wulfsberg 1036. Bronsted acidity of neutral and cationic acids in nonaqueous solvents: Recent developments. I. Leito, A. Kutt, I. Kaljurand, E-l. Rôôm, T. Rodima, I. A. Koppel 1037. Feasibility of the spontaneous gasphase proton transfer equilibria between neutral Bronsted acids and bases. P. Burk, I. A. Koppel, I. Koppel, A. Trummal 1038. Gas phase hydration, deprotonation of ionized aromatics and the generation of protonated water clusters. R. M. Mabrouki, E. Xie, M. S. El-Shall 1039. Generation of protonated carbonyl groups stabilized by intramolecular hydrogen bonding: A new class of organic solid acids? A. G. Sykes, M. Kadarkaraisamy 1040. The second proton: Unraveling the secrets of proton pumps with computer simulations. J. M. Swanson, G. A. Voth 1041. A charged ring model for hydroxide ion (aq) simulation. I. S. Ufimtsev, A. G. Kalinichev, T. J. Martinez, R. J. Kirkpatrick 1042. Proton momentum distributions in water: A path integral molecular dynamics study. J. A. Morrone, V. Srinivasan, D. Sebastiani, R. Car 1043. A comparative study for dehydrogenation and dissociation of B 2 H 6 , AI 2 H 6 , and Ga 2 H 6 . C. Che, L. Rajan, J. Aeschleman, J. Liu, Q. Ge 1044. Comparison of thermochemical properties of aspartame and glucose. A. Fattahi, M. Rashidian, S. Balalaie 1045. Effect of non-covalent interactions on a redox-active tyrosine in a designed beta hairpin peptide. R. S. Sibert, F. Porcelli, G. Veglia, B. A. Barry, R. Kevin, M. Josowicz
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
W E D N E S D A Y MORNING Section A. McCormick Place Lakeside Room E270, Level 2
Section Τ
Organizer
7:00-10:00 1052. Density functional study of propane oxidative dehydrogenation by V 0 4 H 3 and V 2 0 7 H 4 molecules in the gas phase and supported on T i 0 2 . S. A. Zygmunt, J. W. Friedhoff, P. C. Redfern, P. Zapol, M. Sternberg, S. P. Adiga, L A. Curtiss 1053. Electronic properties of the ternary rare-earth polychalcogenide, NdSeTe2. H-J. Koo 1054. Computational study of group 14 ansametallocenes. J. S. Overby, J. C. Johnston, W. J. Rieter 1055. Density functional study of the complete pathway for the Heck reaction with palla dium diphosphines. P. Surawatanawong, Y. Fan, M. B. Hall 1056. DFT calculations of EPR parameters for Cu containing proteins and model com plexes. W. M. Ames, S. C. Larsen 1057. DFT studies of allosteric interactions between remote sites in Fe(ll) porphyrin dimers. D. Khvostichenko, R. Boulatov 1058. Kinetic C-H oxidative addition vs. ther modynamic C-X oxidative addition to lr(l) and Rh(l) systems: A density functional theory study. H. Wu, M. B. Hall 1059. Pseudo Jahn-Teller model for alternat ing bond distortions in [Mo6019]2-. D. C. Duncan 1060. Theoretical studies of the mechanism of reduction of N 2 by an iron-phosphine complex. R. B. Yelle, J. L. Crossland, N. K. Szymczak, D. R. Tyler 1061. A computaional study of the extrusion mechanism for singlet carbene analogs from 1,1-dimethyl-metalla-cyclopent-3-enes [MMe 2 (C 4 H 6 ), M= Si, Ge, Sn]. M. Nag, P. P. Gaspar 1062. Analysis of bonding in alumoxane cages. C. W. Earley 1063. Comparison of Fenske-Hall and density functional calculations on polyoxometalate anion. S. D. Zaric, M. Milcic, M. Stevic, I. Holclajtner-Antunovic, M. B. Hall 1064. Comparison of Pitzer's theory and Meissner's arithmetic on calculating activity coefficients for single and multicomponent. F. Liu, Z. Zhang 1065. Computational study of ansa-beryllocenes. J. S. Overby, J. C. Johnston 1066. Coordination properties of C 20 H-| 0 corannulene vs. C 60 -fullerene: Direct DFT and X-ray structural comparison. A. Y. Rogachev, Y. Sevryugina, A. S. Filatov, M. A. Petrukhina 1067. DFT modeling of Mossbauer spectra parameters and absorption properties in organometallic and macrocyclic com pounds. V. N. Nemykin, R. Hadt, R. Belosludov 1068. Mechanism of water activation by lr(l) complexes: A DFT study. R. Cohen, D. Milstein 1069. Ring strain energies of three-membered silicon, germanium, and tin pnictogenide rings. C. L. Allard, T. M. Gilbert
Organizer Presiding
8:30 1073. Nanocatalysis on tailored shape supports for CO oxidation. G. P. Glaspell II, M. S. El-Shall 8:50 1074. Controlling carbon surface chem istry on Ni by alloying: Carbon-tolerant hydrocarbon reforming alloy catalysts. S. Linic, E. Nikolla 9:10 1075. Partial oxidation of methane to syngas over Ni-based catalysts. Y. Song, D.He 9:30 Intermission. 9:50 1076. Flame aerosol reactor (FLAR) fabrication of doped and pristine nanostructured metal-oxide films for solarhydrogen production. E. Thimsen, H-E. Song, C. Kirmaier, D. Holten, P. Biswas 10:10 1077. Investigation of solid base catalysts for biodiesel production. S. L. Britton, T. W. Root 10:30 1078. Reduction of N H 4 N 0 3 by NO to N 2 : Effects of the substrate, and implica tions for low temperature deNOx catalysis. A. Savara, W. M. Sachtler, E. Weitz 10:50 1079. Low temperature CO oxidation kinetics by dendrimer templated supported Au catalysts. B. D. Chandler, C. G. Long, J. D. Gilbertson Section Β McCormick Place Lakeside Room E271B, Level 2 The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Cosponsored with PHYS C. A. Reed,
Organizer
M. Johnson, Organizer,
Presiding
9:00 1080. Neutron scattering and theoretical studies of Zundel cations in crystalline solids. B. S. Hudson 9:30 1081. Spectroscopy of protonated water in condensed phases. V. Buch, J. P. Devlin, F. Mohamed, M. Parrinello 10:00 1082. Infrared spectroscopy of proto nated water clusters: The effects of argon tagging and deuteration. M. A. Duncan 10:30 Intermission. 11:00 1083. Proton solvation and transport in aqueous systems. G. A. Voth 11:30 1084. Puzzling protons: Investigations of the spectroscopic signatures of hydro gen bonding in water-ion complexes. A. B. McCoy, S. Horvath
TECHNICAL PROGRAM
INOR Section C
Section Ε
McCormick Place Lakeside RoomE271A, Level 2
McCormick Place Lakeside Room E253B, Level 2
One-dimensional Nanomaterials Complex Nanostructures and Assembly
Materials Chemistry
S. Jin,
M. Kuno and H. He,
Section D McCormick Place Lakeside Room E253A, Level 2 Chemistry of Lanthanide and Actinide Systems Organizer
P. M. Smith,
Presiding
8:30 1093. Assembly of d-f hybrids on potential multimodal imaging agents. T. Koullourou, L. S. Natrajan, H. Bhavsar, S. J. Pope, J. Feng, J. Narvainen, R. Kauppinen, A. M. Kenwright, S. Faulkner 8:50 1094. Behavior of the uranyl ion in strongly acidic media. X. Sun 9:10 1095. Luminescence of tripodal amine and aminophenol complexes of europiumOil). P. M. Smith 9:30 1096. Nanoparticles of lanthanide sulfide materials. S. L. Stoll, M. D. Regulacio 9:50 1097. Organophosphine oxide/sulfidesubstituted lanthanide binaphtholate catalysts for enantioselective hydroamination/ cyclization. X. Yu, T. J. Marks 10:10 1098. Plutonium coordination chemistry and relative covalency in An(lll)/Ln(lll) complexes. A. J. Gaunt, S. D. Reilly, A. E. Enriquez, B. L Scott, M. P. Neu 10:30 1099. Reactivity of small molecules with bis- and tris-(polymethylcyclopentadienyl) lanthanide complexes including the utility of the LnZ3/M and LnZ2Z7M reduction systems. D. B. Rego, J. W. Ziller, W. J. Evans
Please refrain from using cellular telephones and cameras during technical sessions.
80-TECH
Organizer Presiding
Presiding
8:30 1085. Engineering the morphology of 1-D ZnO nanostructures from nanorods to nanotubes to nanotube based paintbrush by a solvothermal approach. S. Kar, S. Santra, S. Chaudhuri 8:50 1086. Partial cation exchange as a means of creating nanorod superlattices. A. P. Alivisatos 9:30 1087. Designing PbSe nanowires and nanorings through oriented attachment of nanoparticles. D. V. Talapin, C. B. Murray 9:50 1088. Nanorods and multipods of platinum and its alloys: Synthesis, formation mechanism and property. S. M. Maksimuk, Y. Wang, H. Yang 10:10 Intermission. 10:30 1089. Inorganic nanotubes and nanofluidic transistors. P. Yang, J. Goldberger, R. Fan 11:10 1090. General approaches to controlled organization of nanowires and carbon nanotubes. G. Yu, A. Cao, C. M. Lieber 11:30 1091. Branching and radial siliconsilicide nanowire heterostructures. J. M. Higgins, L Zhu, A. Schmitt, S. Jin 11:50 1092. 1-D functional nanostructures. M. Leon, P. Santiago, R. Irizarry, E. A. Hernandez, M. E. Castro
S. Liu,
D. C. Crans, J. M. Mabry,
Organizer
8:30 1100. Photophysical and optical limiting properties of silicon naphthalocyanines with peripheral bromo-substituents. Y. Li, W. Sun, D. Dini, M. Hanack 8:50 1101. Strontium and rubidium ion exchange in zirconium trisilicate. C S. Fewox, A. Clearfield 9:10 1102. A new cyclometalated Pt(ll) complex with strong optical limiting effect. W. Sun, P. Shao 9:30 1103. Spin frustration on S = 1/2 kagomé antiferromagnets. E. A. Nytko, M. P. Shores, B. M. Bartlett, D. G. Nocera 9:50 1104. Nanostructured PbTe: Reactive displacement of Pb atoms by Eu. P. F. Poudeu Poudeu, H. Kong, R. Pcionek, X. Shi, C. Uher, M. G. Kanatzidis 10:10 1105. Concentration and conversion of polyaluminum chloride solutions by membrane distillation. B. Fan, Y. Guo, Z. Luan, X. Peng 10:30 1106. Synthesis of indium doped cadmium selenide quantum dots. C. J. Tuinenga 10:50 1107. Enhanced functionalization of trimetallic nitride template endohedral metallofullerenes (TNT EMFs) via a manganese (III) acetate dihydrate catalyst. C. Shu, T. Cai, T. Zuo, K. Harich, R. Jonathan, H. W. Gibson, H. C. Dorn 11:10 1108. Synthesis and characterization of pyrene-capped oligothiophenes for use as organic semiconductors. C. M. Halsey, J. N. Bohnsack, M. W. Burand, K. R. Mann 11:30 1109. Matrix encapsulation as a method for the synthesis of nanostructured thermoelectric materials. J. R. Sootsman, H. Kong, C. Uher, M. G. Kanatzidis 11:50 1110. Microwave synthesis of functional materials by novel semiconductor ΗΡΑ microwave chemical reactor. T. Matsumura-lnoue, T. Fukuoka 12:10 1111. Growth of ultra-thin films of amorphous ruthenium-phosphorus alloys using a single source CVD precursor. J. Shin, A. Waheed, R. A. Jones, K. Agapiou, W. A. Winkenwerder, H-W. Kim, G. S. Hwang, J. G. Ekerdt Section F McCormick Place Lakeside Room E253C, Level 2 Coordination Chemistry: Synthesis D. C. Crans, M. Nyman,
Organizer Presiding
8:30 1112. Metal-dicarboxylate networks. D. M. Kandiah, A. D. Burrows, C. Richardson 8:50 1113. Exploring mixed alkoxide [M(OR)x(OR*)y] chemistry of magnesium, zinc and titanium: Heteroatom, denticity and steric influences. T. N. Lambert, T. J. Boyle, L. A. M. Ottley, H. D. Pratt III, R. M. Sewell 9:10 1114. Stable, water-soluble metal alkoxides. T. J. Boyle, R. M. Sewell, L. A. M. Ottley, H. D. Pratt III 9:30 1115. Pi-basic group 6 metal fragments based on chiral C 2 -symmetric tetraamine ligands. J. M. Keane, P. K. B. Palomaki, J. A. Rubin, J. E. Saunders, D. B. Perlow, S. A. Burgess, R. R. Bennov, J. M. Ludlum, B. W. Nash, S. V. Scarselletta, R. D. Pike 9:50 1116. Bis(mercaptoimidazolyl)borate complexes of indium and bismuth. S. C. Hill, S. N. Sims, K. A. Kreisel, G. P. A. Yap, D. S. Jones, L N. Zakharov, A. L Rheingold, D. Rabinovich 10:10 1117. Microwave-assisted syntheses of soft scorpionates. L. S. Maffett, D. Rabinovich 10:30 1118. Coordination chemistry of calix[6 and 8]arenes. C. Redshaw, M. R. J. Elsegood
10:50 1119. Polydentate chelating and macrocyclic pyridine N-oxide ligands. P. Baran 11:10 1120. Exploring the coordination chemistry of a new family of tetralkylguanidinate ligands. S. D. Bunge, J. A. Bertke, J. M. Lance, T. L. Cleland 11:30 1121. Synthesis and structural charac terization of metal-organophosphonate hybrid frameworks. S. Konar, A. Clearfield, J. Zon 11:50 1122. Highly tailorable coordination polymer micro- and nanoparticles. A. Sumrein, M. Oh, C. A. Mirkin 12:10 1123. Triangular transition metal clusters supported by bridging triazacyclohexanes. R. Kohn, G. Kociok-Kohn, Z. Pan, L. Tomas Laudo Section G McCormick Place Lakeside Room E253D, Level 2 Nanoscience: Synthesis B. T. Donovan-Merkert and D. C. Crans, Organizers C. L. Mertzenich,
9:40 1137. Allylpalladium(IV) intermediate in the synthesis of highly substituted benzoxepines and benzopyrans via reactions of stable pallada(ll)cycles with allyl bromides. H. C. Malinakova, R. Guo, V. W. Day, P. Datta-Chaudhuri, J. L. Portscheller 10:00 1138. Iridium-catalyzed dimerization of alkynes: A mechanistic study revealing factors governing the energetics of C-C reductive elimination. A. S. Goldman, R. Ghosh, T. J. Emge, P. D. Achord, X. Zhang, K. Krogh-Jespersen 10:20 Intermission. 10:40 1139. Cyclometalated iridium and platinum metal complexes with non-inno cent ligands. B. Hirani, M. E. Thompson 11:00 1140. Quinone-annulated N-heterocyclic carbenes and their transition metal complexes. C. W. Bielawski 11:20 1141. Selective decarbonylation of aldehydes by a pincer rhodium(l) complex: The role of steric and electronic effects. K-W. Huang, D. C. Grills, J. H. Han, C. B. Musgrave, E. Fujita 11:40 1142. Synthesis and reactivity of group (V) PNP complexes. U. J. Kilgore, X. Yang, J. Tomaszewski, J. C. Huffman, D. J. Mindiola
Presiding WEDNESDAY AFTERNOON
8:30 1124. Synthesis and characterization of dinickel phosphide (Ni 2 P): HDS activity evaluation of nanoparticles and aerogels. K. Senevirathne, A. Bums, M. E. Bussell, S. L. Brock 8:50 1125. Synthesis and interconversion of catalytically relevant nanocrystalline intermetallics. R. E. Cable, R. E. Schaak 9:10 1126. Porous, systematically functionalized metal-organic frameworks constructed from building units prepared in the organic solid state. C. L. Mertzenich, G. S. Papaefstathiou, T. Friscic, D. C. Swenson, L. MacGillivray 9:30 1127. Synthesis of nanostructured aluminosilicates by flame aerosol routes for environmental applications. P. Worathanakul, P. Kongkachuichay, J. Jiang, P. Biswas 9:50 1128. Tailoring the metal and ceramic phase in high-temperature stable nanocomposites. T. Sanders, D. Kruse, G. Veser 10:10 1129. Sc3N@C78: Chemical reactivity and regioselectivity of functionalization. T. Cai, L Xu, C. D. Angeli, E. B. lezzi, J. E. Reid, A. Balch, M. M. Olmstead, H. W. Gibson, H. C. Dorn 10:30 Intermission. 10:40 1130. Molecular-size nanocage with microporous shell and functionalized core: Carbamate immolative dendritic synthesis strategy and characterization. J-K. Lee, M. C. Kung, C. M. Downing, Y-W. Suh, H. H. Kung 11:00 1131. Template-free preparation of hollow CdMo04 microspheres at room temperature. W-S. Wang, L. Zhen, C-Y. Xu, W-Z. Shao 11:20 1132. Pd nanostructures with wellcontrolled shapes and optical properties. Y. Xiong, Y. Xia 11:40 1133. Effect of solvent in the synthesis of CdSe quantum dots. N. Shukla, M. M. Nigra, A. J. Gellman 12:00 1134. A combined experimental and theoretical study of CdSe nanocrystal formation. H. Liu, J. S. Owen, J. C. Grossman, A. P. Alivisatos Section H McCormick Place Lakeside Room E255, Level 2 General Inorganic and Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers H. C. Malinakova,
Presiding
9:00 1135. Olefin deformation and its impor tance in metal-olefin bond strengths. D. L. Cedefio, D. N. Schlappi, R. Sniatynsky, C. R. Hexel, J. Martinez 9:20 1136. Sigma-CAM mechanism: ς-Complex assisted metathesis at late transition metals. R. N. Perutz, S. Sabo-Etienne
Section A McCormick Place Lakeside Room E270, Level 2 Nanoscience: Characterization and Application B. T. Donovan-Merkert and D. C. Crans, Organizers M. E. Castro,
Presiding
1:30 1143. A high-throughput SNP genotyping method with PCR on magnetic nano particles. N. He, S. Li, H. Liu, Q. He, Z. Wang, Y. Guo, J. Tang 1:50 1144. Synthesis and characterization of Pt and Ru nanoparticles. P. Santiago, M. Santiago Jr., E. Mercado, M. Gonzalez, M. E. Castro 2:10 1145. Ultrahigh-density data storage using molecular bits. R. A. Elgammal 2:30 1146. Er-doped Y 2 0 3 nanostructures. Y. Mao, J. P. Chang 2:50 1147. Use of silicate shells to prevent sintering during thermally induced chemi cal ordering of FePt nanoparticles. D. F. Reed, D. E. Nikles, J. W. Harrell 3:10 1148. Structural and chemical changes in ln-oxide nano-crystals: XRD and HRTEM study. H. Xu, R. R. Yeredla, H. Konishi, A. Narayanaswamy, X. Peng, X.Li 3:30 1149. Nanoparticle scintillators for radiation detection: Surface modification and performance of LaP0 4 :Ce. A. J. Rondinone, B. Kesanli, H. Luo, S. Brown, J. Woodward, S. Dai 3:50 Intermission. 4:00 1150. Size and shape-controlled syn thesis of iron oxide nanocrystals and their chemical conversions. Y. Hou, Z. Xu, S.Sun 4:20 1151. Improvement of DNA detection by flowing QCM detection mode and gold nanoparticle amplification. N. He, L. Nie, Y. Yang, H. Chen, S. Li 4:40 1152. In-situ electrochemical STM study of platinum thin films. Q. Xu, E. Kreidler, D. O. Wipf, T. He 5:00 1153. A novel high-throughput SNP genetyping approach based on magnetic nanoparticles and dual-color fluorescence hybridization. S. Li, N. He, H. Liu, Q. He, Z. Wang, Z. Wang, Y. Guo 5:20 1154. Anodized aluminum oxide (AAO) based nanowells for hydrogen detection and interference color sensing. H. H. Wang, F. Rumiche, A. Polar, E. Indacochea
INOR
Section B
5:05 Concluding Remarks.
Section F
McCormick Place Lakeside RoomE271C, Level 2
Section D
McCormick Place Lakeside Room E253C, Level 2
Nanoscience: Synthesis
McCormick Place Lakeside Room E253A, Level 2
Materials Synthesis
B. T. Donovan-Merkert and D. C. Crans, Organizers
Chemistry of Lanthanide and Actinide Systems
D. C. Crans, M. I. Khan,
A. Ivanisevic,
Presiding
S. Liu, Organizer,
1:30 1155. Core-shell-shell nanostructures with nanoparticles sandwiched in between metal oxides: Si02/Au nanoparticles/ nanoporous silica core-shell nanomaterials. Y - L Shi, T. Asefa 1:50 1156. Radial-position-controlled doping in CdS/ZnS core/shell nanocrystals. Y. Yang, 0 . Chen, A. Angerhofer, Y. C. Cao 2:10 1157. L10 Phase formation in layered FePt nanoparticles in their as-synthesized states. A. Ivanisevic, H. M. Song 2:30 1158. Successive ionic layer deposition of oxide nanolayers. T. I. Gilbert, V. P. Tolstoy, J. Schwank 2:50 1159. Preparation of ZnO nanosheets in solvothermal system based on selfassembly of nanoparticles. G. Pang, M. Yang, L. Jiang, D. Liang, S. Feng 3:10 Intermission. 3:20 1160. Novel synthesis of air-stable FeCo nanoparticles. G. S. Chaubey, N. Poudyal, C. Rong, J. P. Liu 3:40 1161. Diversity of structural types and single molecule magnetism in polynuclear iron clusters with alcohol-based ligands. R. Bagai, K. A. Abboud, G. Christou 4:00 1162. As-prepared single-crystalline hematite rhombohedra and subsequent conversion into monodisperse aggregates of magnetic nanocomposites of iron and magnetite. T-J. Park, S. S. Wong 4:20 1163. New iron oxide, manganese, oxide and iron-manganese oxide shaped nanoparticles: Synthesis, properties, and growth studies. C. Hofmann, T. Ould-Ely, I. Rusakova, D. Prieto-Centurion, K. H. Whitmire 4:40 1164. Precursors effect on ceramic nanomaterial phase and morphology. B. A. Hernandez-Sanchez, T. J. Boyle, L. N. Brewer
Section C McCormick Place Lakeside Room E271B, Level 2 One-dimensional Nanomaterials Energy Research S. Jin,
Organizer
M. Kuno and D. V. Talapin,
Presiding
2:00 Introductory Remarks. 2:05 1165. Single wall carbon nanotube scaffolds for photoelectrochemical solar cells. P. V. Kamat, A. Kongkanand, F. Vietmeyer 2:35 1166. Complex nanostructures for energy conversion and storage. Y. Wu 3:05 1167. Synthesis, characterization and physical properties of chromium disilicide nanowires. J. Szczech, S. Jin 3:25 1168. Electrochemical and electrocatalytic properties of chemically modified carbon nanofibers. R. J. Hamers 3:55 Intermission. 4:15 1169. Solar cells and batteries with inorganic nanowires. Y. Cui, C. Chan, H. Peng, J. Zhu 4:45 1170. Influence of lithiation on electro chemical properties of Mo03 nanobelts. L Mai, B. Hu, Y. Qi, B. Hu, Y. Dai, C. Zhou, E. Gu, W. Jin, W. Chen
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section Ε McCormick Place Lakeside Room E253B, Level 2 Theoretical and Computational Chemistry
A. Clark,
Organizer Presiding
Presiding
2:00 1171. Chemistry of bis(imido)uranium diiodide. J. M. Boncella, T. W. Hayton, R. L. Gdula, L. P. Spencer, B. L. Scott 2:20 1172. Exploiting the terminal uranyl oxygen atoms: Toward higher dimensional compounds. M. Frisch, C. L. Cahill 2:40 1173. Plutonium(VI) carbonate and nitrate aqueous solution complexation chemistry. S. D. Reilly, A. J. Gaunt, H. Boukhalfa, W. Runde, M. P. Neu 3:00 1174. Semiconductor nanoparticles as antennae for luminescent lanthanide cations. A. Yingling, D. Chengelis, S. Proviano, E. High 3:20 1175. Spectroscopic investigation of binding properties of water to Eu(lll) in 1 -butyl-3-methylimidazolium chloride. P. S. May, S. S. Samikkanu, K. Mellem 3:40 1176. Synthesis and reactivity of rare earth metal alkyl complexes supported by the neutral and monoanionic 6-amino-1,4diazepine derivatives. S. Ge, A. Meetsma, B. Hessen 4:00 1177. Toward understanding the highly efficient sensitization of Eu(lll) by 1,2 HOPO chelates. E. G. Moore, J. Xu, C. J. Jocher, E. J. Werner, Κ. Ν. Raymond
D. C. Crans,
5:10 1208. Synthesis, structural characterization, and photophysical properties of a family of dinuclear Au(l) benzimidazolethiolates. J. Schneider, Y-A. Lee, J. Perez, T. Hackett, C. Flaschenriem, W. W. Brennessel, R. Eisenberg 5:30 1209. Tropolonates and derivatives as sensitizers for near-infrared emitting lanthanide cations. J. Zhang, P. D. Badger, S. J. Geib, S. Petoud
1:30 1190. Degradable dendritic structuredirected synthesis strategy for porous nanocages. C M. Downing, M. N. Missaghi, M. C. Kung, H. H. Kung 1:50 1191. Heterobimetallic compounds of alkali and alkaline earth metals: Donor-free and heteroleptic species. M. F. Zuhiga, G. B. Deacon, K. Ruhlandt-Senge 2:10 1192. Protein-templated synthesis of uniform magnetite nanocrystals. T. Prozorov, R. Prozorov, S. K. Mallapragada, B. Narasimhan, M. Nilsen-Hamilton, T. J. Williams, D. A. Bazylinski 2:30 1193. Hydrothermal and microwave fabrication of ZnO nanorods using ethanolic quantum dot precursors. Y. Hara, J. R. S. Brownson, M. A. Anderson 2:50 1194. Harnessing the oxidation of organic components under hydrothermal conditions: Synthesis of uranium oxalates and glycolates via in situ ligand formation. K. E. Knope, C. L. Cahill 3:10 1195. Synthesis of polycarbosilane using a catalytic process. Y. Kim, D. H. Riu, D. G. Shin, H. R. Kim, W. T. Kwon, S. R. Kim 3:30 1196. Synthesis of redox and photoactive organo-functionalized mesoporous silicas. C T. Burns, S. Y. Choi, M. A. Firestone Section G McCormick Place Lakeside Room E253D, Level 2
Organizer
Presiding
1:30 1178. Tight binding-configuration inter action (TBCI): A non-iterative method to incorporate charges into tight binding. M. A. Iron, G. Staszewska, N. E. Schultz, T. J. Preston, D. G. Truhlar 1:50 1179. Understanding nonplanarity in metallabenzenes. J. Zhu, G. Jia, Z. Lin 2:10 1180. Extreme "inner polarization" effects in high-oxidation state 2nd-row compounds: The d orbitals strike back. J. M. Martin 2:30 1181. Theoretical investigation of feeble transition metal - arene interactions in the ArMMAr (M = Cr, Co, Fe; Ar = terphenyl) species bearing bulky aryl ligands: Direct impact on the structural trends in the CMMC cores. M. Brynda, A. D. Sutton, P. P. Power, G. La Macchia, L. Gagliardi 2:50 1182. Bader's analysis of transition state complexes in C-H bond activation chemistry. B. A. Vastine, M. B. Hall 3:10 1183. Pt(ll) metal complex uptake by PAMAM dendrimers: A computational study. F. Tarazona-Vasquez, P. B. Balbuena 3:30 1184. Theoretical investigation of methanol oxidation to formaldehyde on isolated vanadate species supported on silica. A. T. Bell, A. Goodrow 3:50 1185. Spin acceleration of oxidative dehydrogenation of propane on supported vanadium oxide catalysts. S. A. Zygmunt, J. W. Friedhoff, P. C. Redfern, P. Zapol, M. Sternberg, S. P. Adiga, L. A. Curtiss 4:10 1186. Computational search for para magnetic NMR parameters in transition metal complexes. R. Kohn 4:30 1187. More QR-SCMEH-MO calcula tions on diatomic transition metals "f" orbital systems- U2 and Nd2 molecules. E. A. Boudreaux Sr., E. Baxter 4:50 1188. U022+ hydration by DFT and MD simulation: Investigating the chemistry behind the success and failure of differing interatomic potentials. A. Clark 5:10 1189. Ab initio calculations on systems relevant for the chemistry of the atmo sphere. M. Rosi, G. de Pétris, A. Troiani
Coordination Chemistry: Characterization and Application D. C. Crans and K. J. Franz,
Section H McCormick Place Lakeside Room E255, Level 2 General Inorganic and Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers D. J . Mindiola,
Presiding
2:00 1210. Diiron model complexes related to Fe-only hydrogenase: Understanding key differences from the enzyme active site. C. M. Thomas, M. Y. Darensbourg, M. B. Hall 2:20 1211. Studies of the reactions between (Me 3 SiCH 2 )3WsCSiMe 3 and phosphines. B. A. Dougan, L. A. Morton, S. Chen, H. Qiu, Z-L. Xue 2:40 1212. Reversible isomerization of a diphosphine ligand and regiospecific C-H and P-C bond cleavage reactivity in the triosmium cluster Os 3 (CO) 10 (bmf). S. Kandala, M. G. Richmond 3:00 1213. Addition of ketenes to dihapto coordinated 2H-phenol complexes. M. A. Todd, W. D. Harman 3:20 1214. Oxidative addition and reductive elimination reactions of thiols with dialkyl platinum cyclooctadiene. A. K. F. Rahman, A. T. Rahman, D. Powell, A. Rahman 3:40 1215. Observation of C-N reductive elimination from an aryl-copper(lll) complex. L M. Huffman, S. S. Stahl 4:00 1216. Complexes of bulky azole-based multidentate ligands. E. S. Wiedner, M. J. A. Johnson
Organizers THURSDAY MORNING
M. J . Knapp,
Presiding Section A
1:30 1197. Reactivity worthy of Alfred Werner: Ligand substitution reactions in [Fe ' ( C N ) ^ ] 2 ' · 1 ' complexes. D. Y. Melgarejo, G. M. Chiarella, S. A. Koch 1:50 1198. Molecular bistability in a ruthenium disulfoxide complex. N. V. Mockus, J. J. Rack 2:10 1199. 8-Hydroxyquinolines as ancillary ligands: The impact of ligand modifications on cyclometalated iridium complexes. S. Kappaun, S. Sax, S. Eder, F. Stelzer, E. J. W. List, C. Slugovc 2:30 1200. Coupling Ru or Os light absorbers to reactive Pt complexes: Excited state reactivity and DNA photocleavage. R. Miao, D. F. Zigler, J. Brown, K. J. Brewer 2:50 1201. Dexter energy transfer between a ruthenium chromophore and a spincoupled acceptor. M. Soler, J. K. McCusker 3:10 1202. Improved turn-on times of lightemitting electrochemical cells. E. Zysman-Colman, J. Slinker, J. Parker, G. G. Malliaras, S. Bernhard 3:30 1203. Luminescence with a twist: Emission dissymmetry from chiral metal complexes. K. D. Oyler, F. J. Coughlin, M. Westrol, C. Kraml, N. Byrne, E. Zysman-Colman, S. Bernhard 3:50 1204. Excited state intramolecular proton transfer in 2-(2'-sulfonamidophenyl)benzimidazole derivatives: Impact of extended pi-conjugation. Y. Wu, C. J. Fahrni 4:10 1205. Optically pure ruthenium complexes for use as crystalline oxygen sensors. K. A. McGee, K. R. Mann 4:30 1206. Photoluminescence and photochemical upconversion. F. N. Castellano 4:50 1207. Fluorescent detection of explosives analogs by Zn(ll) coordination compounds. M. J. Knapp
McCormick Place East Room E270, Level 2 The Bioinorganic Chemistry Relating to Enzymes and Proteins D. C. Crans and S. L. Michel, Β. Μ. Hoffman,
Organizers
Presiding
9:00 Introductory Remarks. 9:05 1217. Cloning, expression and charac terization of chlorite dismutase from Dechloromonas aromatica. J. L. DuBois, B. R. Streit 9:25 1218. Converting MerR family metalloregulatory proteins to highly sensitive and selective metal ion biosensors. P. Chen, C. He 9:45 1219. Designed evolution of artificial metalloenzymes for enantioselective catalysis based on the biotin-avidin tech nology. T. R. Ward 10:05 1220. Lead(ll) coordination chemistry in lead(ll)-regulatory protein from Ralstonia metallidurans. J. Zhao, P. R. Chen, E. C. Wasinger, L. X. Chen, C. He 10:25 1221. Pseudomonas putida CadR, a cadmium(ll)-selective metalloregulatory protein, uses a distinct mechanism from the other MerR proteins. H. Chen, C. He 10:45 1222. Thermodynamics of Ni2+, Cu2+ and Zn2+ binding to the urease metallochaperone UreE. D. E. Wilcox, N. E. Grossoehme, S. B. Mulrooney, R. P. Hausinger 11:05 1223. Differential influence of interfacial dynamic processes on an electron transfer photocycle in mixed-metal hemo globin hybrids. A. D. Patel, J. M. Nocek, Β. Μ. Hoffman 11:25 1224. Electron transfers in protein/ nanoparticle hybrids. M. J. Knapp
TECH-81
TECHNICAL PROGRAM
ÎNOR 11:45 1225. Entrapment of MP-11 in Ti02 fibers. M. Macias, K. J. Balkus Jr. 12:05 1226. Insights on the molecular mechanism of action of the antiangiogenic copper chelator drug: ammonium tetrathiomolybdate. H. M. Alvarez, T. V. O'Halloran, R. Kelly, J. E. Penner-Hahn, B. Lai
Section D
Section F
Section H
McCormick Place Lakeside Room E253A, Level 2
McCormick Place Lakeside Room E253C, Level 2
McCormick Place Lakeside Room E255, Level 2
Main Group Chemistry
Organometallic Catalysts
Theoretical and Computational Chemistry
D. C. Crans,
D. C. Crans,
Section Β
A. W. Herlinger,
B. T. Donovan-Merkert and D. C. Crans, Organizers
McCormick Place Lakeside RoomE271C, Level 2
9:00 1242. Main group organyls supported by bis-phenol ligands: Synthesis, charac terization and evaluation in homogeneous catalysis. M. A. Munoz-Hernandez 9:20 1243. Microwave synthesis of ZIF-8. J. A. Losilla, K. Balkus Jr. 9:40 1244. Alkaline earth metal alkynes: Synthesis, structures and reactivity. K. Ruhlandt-Senge, M. A. Guino-o, J. S. Alexander, H. Hope, U. Englich 10:00 1245. Reactivity of isocyanides with compounds of the Group 13 elements. N. Kingsley, K. Kirschbaum, J. A. Teprovich Jr., R. A. Flowers II, M. R. Mason 10:20 1246. Synthesis, properties and reac tivity of tris(pentafluorophenyl)hydrocarbyborates. M. A. Blanchard, J. F. C. Turner 10:40 1247. Structural characterization and dynamic solution behavior of gem-dimetallic complexes. K. L. Hull, B. C. Noll, K. W. Henderson
Electrochemistry in Inorganic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers M. Yagi,
Presiding
9:00 1227. Determination of enrichment parameters after reduction of synthetic tritiated samples in a proton exchange membrane electrolyzer. A. M. Soreefan, T. A. DeVol 9:20 1228. Unbelievably fast and unique charge transport through a tris(2,2'-bipyridine)ruthenium(ll)-doped tungsten oxide film. M. Yagi, K. Sone 9:40 1229. Electrocrystallization of moleculebased M[TCNQ]2 magnets (M= Co, Ni): Toward morphology-tunable crystalline materials. A. Nafady, A. M. Bond 10:00 1230. Analysis of the electrochemical behavior of methyl-terminated Si(111) toward electro-oxidation and electrodeposition of metals. S. Maldonado, N. S. Lewis 10:20 1231. Mechanism of electrochemical reduction of hydrogen peroxide on copper in acidic sulfate solutions. K. L. Stewart, A. A. Gewirth 10:40 1232. Withdrawn. 11:00 1233. Oxidatively-activated ligandexchange reaction of CoCp(CO)(PPh3) complex in low polarity media. A. Nafady, W. E. Geiger Section C McCormick Place Lakeside Room E271B, Level 2 Environmental Inorganic Chemistry Cosponsored with SUST D. C. Crans and D. J . Nelson, H. Rhodes,
Organizers
Presiding
9:00 1234. Lagrangian water quality dynam ics in the San Luis Drain, California. E. C. Volkmar, R. A. Dahlgren, W. T. Stringfellow, S. S. Henson, S. E. Borglin, C. Kendall 9:20 1235. Tracking manganese interaction with carboxylic acid functionalized fused quartz/water interfaces with second har monic generation. C. T. Konek, M. J. Musorrafiti, P. A. Bertin, S. T. Nguyen, F. M. Geiger 9:40 1236. Genetics of iron acquisition by an environmental microbe and geochemical model, Pseudomonas mendocina ymp. J. L. DuBois, J. D. Awaya 10:00 1237. Heavy metal remediation using molybdenum oxide and tungsten oxide. M. Chehbouni, A. W. Apblett 10:20 1238. Second harmonic studies of chromium (VI) binding to alpha-aluminum oxide. M. J. Musorrafiti, C. T. Konek, F. M. Geiger 10:40 1239. Size fractionated chemical characteristics of aerosols in fertilizer manufacturing facilities. Y-M. Hsu, C-Y. Wu, D. A. Lundgren, B. K. Birky 11:00 1240. Understanding the removal of elemental mercury from flue gas using a Si02-Ti02 nanocomposite. Y. Li, P. Murphy, C-Y. Wu 11:20 1241. Removing algae with electroco agulation (EC). J-Q. Jiang
82-TECH
Organizer Presiding
Section Ε McCormick Place Lakeside Room E253B, Level 2 Nanoscience: Characterization and Application B. T. Donovan-Merkert and D. C. Crans, Organizers E. R. Zubarev,
R. Kohn, R. J . Meyer,
Presiding
9:00 1258. New synthetic strategy in organolanthanides chemistry: The "borohydride/ alkyl route". M. Visseaux, P. Zinck, M. Terrier, T. Chenal, A. Mortreux, P. Roussel 9:20 1259. Identification of nearly isoenergetic pathways for the reaction of dioxygen with a palladium-hydride complex. B. V. Popp, S. S. Stahl 9:40 1260. Synthesis, structure, and applica tions of metallacyclic alkylidene complexes of molybdenum. K. S. Lokare, A. L. Odom 10:00 1261. Mechanism of the catalytic double carbonylation of epoxides to suc cinic anhyrides. J. M. Rowley, T. L. Church, G. W. Coates 10:20 1262. Mechanistic insight into the decomposition of acyloxycarbenes and the relation to substituent exchange at the carbene carbon. S. R. Caskey, M. J. A. Johnson, J. W. Kampf 10:40 1263. Self-assembly of 2-D molybdenum(VI) coordination polymer via hydro gen bond crosslinkages and application in catalytic epoxidation. G. Wang, Y. Luan, Z. Shi, R. L Luck 11:00 1264. Determination of the active catalyst species via reaction modeling and in situ IR spectroscopy during carbonyl reduction with Shvo's hydroxycylopentadienyl ruthenium hydride catalyst. S. E. Beetner, C. P. Casey, J. B. Johnson
Presiding Section G
8:30 1248. Selective sub-10 nm etching of SiC"2 layer by carbothermal reduction using single walled carbon nanotubes. H. R. Byon, H. C. Choi 8:50 1249. Formation, microstructure, optical and magnetic properties, and applications as catalysts of Fe-doped trititanate nano tubes. W-Q. Han, W. Wen, L. Lewis, Y. Ding, J. Hanson, J. Rodriguez, Z. Liu 9:10 1250. Single-walled carbon nanohorns: Tunable media for hydrogen storage and metal nanoparticle decoration. H. Hu, B. Zhao, A. Puretzky, D. Styers-Barnett, C. Rouleau, D. B. Geohegan, Y. Liu, C. Brown, D. Neumann, H. Kabbour, C. Ahn, J. Zielinski, C. Coe, A. Cooper, L. Simpson, A. Dillon, P. Parilla, M. Heben, A. Kleinhammes, Y. Wu 9:30 1251. Carbon nanotube contrast agents for MRI. V. C. Moore, P. Joshi, J. L. Conyers 9:50 1252. Multimodal biomedical imaging with asymmetric single-walled carbon nanotube/iron oxide nanoparticle heterostructures. J. H. Choi, F. T. Nguyen, P. W. Barone, D. A. Heller, A. E. Moll, D. Patel, S. A. Boppart, M. S. Strano 10:10 Intermission. 10:20 1253. Purification of single-walled carbon nanotubes and production of conductive bio thin film. B. Zhao, A. A. Puretzky, H. Hu, D. Styers-Barnett, I. Ivanov, C. M. Rouleau, D. B. Geohegan 10:40 1254. Preparation, separation, and characterization of yttrium trimetallic nitride endohedral metallofullerenes, Y3N@C2n (40 (le}n{le}44). W. Fu, T. Zuo, L. Xu, H. C. Dorn 11:00 1255. Single molecule bound-free reactions of saturated hydrocarbons on Si(100): UHV-STM and quantum calcula tions. N. L. Yoder, M. C. Hersam, T. Seideman, R. Jorn, J. S. Fakonas 11:20 1256. Gas preconcentration, separa tion and detection with carbon nanotubes. M. Stadermann, A. D. McBrady, V. R. Reid, A. Noy, R. E. Synovec, O. Bakajin 11:40 1257. A predictive cage charge trans fer model (C2n)x- for trimetallic nitride template endohedral metallofullerenes (TNT-EMFs), M3N@C2n (40 {le}n {le}44). L Xu, T. Zuo, H. C. Dorn
Organizer
Presiding
McCormick Place Lakeside Room E253D, Level 2 Solid State Chemistry D. C. Crans, H-C. zur-Loye,
Organizer Presiding
9:00 1265. Synthesis of mixed-ligand coordi nation polymers containing 1,2,4-triazole, oxalate, and cadmium. J. M. Ellsworth, K. L. Seward, M. D. Smith, H-C. zur-Loye 9:20 1266. Design and synthesis of reactive solid-state materials. I. G. Georgiev, L. MacGillivray 9:40 1267. Syntheses and characterizations of mesh-adjustable molecular sieves (MAMSs) for gas separation. S. Ma, D. Sun, X-S. Wang, H-C. Zhou 10:00 1268. Synthesis of novel class II inorganic-organic hybrids: Surface modifi cations of Dion-Jacobson perovskites. P. Barber III, T. J. Hansen, H. C. zur Loye 10:20 1269. Structures and properties of mixed-valent, Ni 1 + /Ni 2 + , nickelates with infinite N i 0 2 layers. V. V. Poltavets, K. A. Lokshin, M. Croft, T. Egami, M. Greenblatt 10:40 1270. Temperature dependent X-ray diffraction studies on Gd 5 Ga x Ge 4 . x materi als: Phase transition and magneto-thermal properties. S. Misra, Y. Mozharivskyj, A. O. Tsokol, D. L. Schlagel, T. A. Lograsso, G. J. Miller 11:00 1271. Resolving the charge density wave distortion in the square nets of tellurium of the modulated RETe3 (RE=rare-earth element) materials. C. D. Malliakas, M. G. Kanatzidis, H. Kim, S. J. Billinge 11:20 1272. Quaternary thioarsenate com pounds from the alkali metal polythioarsenate fluxes. T. K. Bera, M. G. Kanatzidis 11:40 1273. Well-differentiated roles for the normal cation types in A - M g - l n systems (A = alkali or alkaline-earth metals). B. Li, J. D. Corbett 12:00 1274. Exploration of phase space using hydroxide fluxes: Materials discovery by crystal growth. H-C. zur Loye
9:00 1275. Magnetization of single-walled carbon nanotube. G. Shan, S. Bao 9:20 1276. An apparent violation of micro scopic reversibility: Mechanisms for ligand substitution reactions of oxorhenium(V) dithiolate complexes. X. Yang, M. B. Hall 9:40 1277. Backside and frontside SN2 substitution: Origin of reaction barriers and reasons for their absence. A. P. Bento, F. M. Bickelhaupt 10:00 1278. DFT study of unsaturated com pounds hydrosilylation with neutral hydrido(hydrosilylene)tungsten complex. X-H. Zhang THURSDAY AFTERNOON Section A McCormick Place East Room E270, Level 2 Applications of Organometallic Chemistry B. T. Donovan-Merkert and D. C. Crans, Organizers G. L Hillhouse,
Presiding
1:30 1279. Stable silver precursor for the aerosol-assisted growth of silver metal thin films. M. N. McCain, S. Schneider, T. J. Marks 1:50 1280. Sensing property of MnTPPCI LB films and a dinuclear Pt(ll) complex to organic vapors. I. Mathew, W. Sun 2:10 1281.Titanium(IV) heteroscorpionatebased thermally robust single-site ethylene polymerization catalysts. R. Eaves, S. R. Parkin, F. T. Ladipo 2:30 1282. Synthesis and characterization of a photoactivatable drug targeting Bcl-2 and Bcl-xL in cancer cells. J . Li, N. L. Oleinick, M. E. Kenney 2:50 1283. Evidence for cis-aminopalladation in palladium-catalyzed aerobic oxidative amination of alkenes. G. Liu, S. S. Stahl Section Β McCormick Place Lakeside RoomE271C, Level 2 Bioinorganic: DNA and RNA J. C. Dabrowiak, C. He,
Organizer
Presiding
1:30 1284. Density functional theory analysis of the stabilizing effects of stacking inter actions in nucleic acid base pair steps. V. R. Cooper, T. Thonhauser, A. Puzder, E. Schroder, B. I. Lundqvist, D. C. Langreth 1:50 1285. Structural basis of Mg2+ inhibi tion in RNA polymerase II transcription. D. Wang, D. A. Bushnell, R. D. Kornberg 2:10 1286. Synthesis and spectroscopic studies of biologically active lanthanide (lll)-catechin complexes. A. A. Ansari, N. Singh, S. Singh
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INOR/MEDI
Section C
Section F
McCormick Place Lakeside RoomE271B, Level 2
McCormick Place Lakeside Room E253C, Level 2
Coordination Chemistry: Synthesis
Materials Chemistry
D. C. Crans,
D. C. Crans,
I. Zharov,
Organizer
Presiding
1:30 1287. Binding modes of Ph2P(2CH2C5H4N) and PhP(2-CH2C5H4N)2 with Ag(l) and Cu(l). K. K. Klausmeyer, F. Hung 1:50 1288. Rare earth metal complexes containing polydentate ligands. P. K. Yuen 1289. Withdrawn. 2:10 1290. Formation of heteroligated Pt(ll) complexes by a ligand rearrangement process. P. A. Ulmann, A. M. Brown, M. V. Ovchinnikov, C. A. Mirkin, A. G. DiPasquale, A. L. Rheingold 2:30 1291. Late transition metal chemistry supported by a rigid PNP pincer-type ligand. D. Adhikari, F. Basuli, R. K. Szilagyi, J. C. Huffman, D. J. Mindiola
Organizer
W. L. Gladfelter,
Section G McCormick Place Lakeside Room E253D, Level 2 Nanoscience: Synthesis Development and Studies with Inorganic Catalysts K. Kustin,
Organizer
I. Nowak,
Presiding
B. T. Donovan-Merkert and D. C. Crans, Organizers P. Krai,
1:30 1292. Response reactions in the mechanisms of complex kinetic systems. I. Nagypâl, E. A. Hoffmann 1:50 1293. Studies of the effect of hydrogen bonds on manganese catalyzed dismutation of hydrogen peroxide. J. M. Peloquin, T. S. Broyles, B. Martin, K. Goodman, P. Nelson 2:10 1294. Catalytic aziridination with manganese corroie: The often postulated high-valent Mn(V) imido is not the group transfer reagent. M. J . Zdilla, M. M. Abu-Omar 2:30 1295. Reaction of molecular oxygen with palladium(ll)-hydride complexes: Mechanistic insights. M. M. Konnick, S. S. Stahl 2:50 1296. Stability and degradation processes of pentaerythritol tetranitrate on molybdenum (VI) oxide. M. L. Mileham, A. E. Stiegman, M. P. Kramer Section Ε McCormick Place Lakeside Room E253B, Level 2 Inorganic Chemistry in Water Cosponsored with SUST
Presiding
1:30 1304. Synthesis of hematite (a-Fe 2 0 3 ) nanocrystals with controlled size and morphology by forced hydrolysis. W. Wang, B. Gu, J. Y. Howe 1:50 1305. Effect of fractal dimensionality on optical properties of CdSe quantum dot gels. H. Yu, S. L. Brock 2:10 1306. Fabricating composite hydrosols of fullerene nanowhiskers shrouded by silver. C. L Raston, K. S. Iyer 2:30 1307. Preparation and characterization of branched coaxial nanorods formed in supercritical carbon dioxide. F. Cao, C. Chen, Q. Chen, W. Hu 2:50 1308. Preparation of nano nickel oxide by molten-salt synthesis. M-L. Zhang, Y-Z. Zheng 3:10 1309. Microwave assisted synthesis of silicon nanowires. N. Ndiege, R. I. Masel 3:30 1310. Galvanic replacement reaction between multiply twinned Ag particles and HAuCI4 in chloroform. X. Lu, H-Y. Tuan, J. Chen, Z-Y. Li, B. A. Korgel, M. Marquez, Y.Xia Section H McCormick Place Lakeside Room E255, Level 2 Spectroscopy in Inorganic Chemistry
D. C. Crans,
Organizer S. L. Michel,
G. M. Ferrence,
Organizer
Presiding Β. Μ. Hoffman,
1:30 1297. DFT studies of initial stage water adsorption on iron oxide surfaces: a-Fe203 (0001). S. Yin, X. Ma, D. E. Ellis 1:50 1298. Reactions of biologically impor tant radicals with the nitroxyl anion and nitroxyl (HNO). C. R. Cox, J. J. Kiddle, S. P. Mezyk 2:10 1299. Redox chemistry of platinumbased anticancer drugs under physiologi cal conditions. K. L. Swancutt, S. P. Mezyk, J. J. Kiddle
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Division of Medicinal Chemistry D. P. Rotella, Program Chair
Presiding
1:30 1300. Atomic layer deposition of compositionally graded (Hf02)x(ZrC2)ix(SiU2)6 5 films. T. L. Moersch, W. L. Gladfelter 1:50 1301. Highly selective catalytic olefin epoxidation with aqueous hydrogen perox ide upon surface modification of tantalasilica materials prepared via the TMP method. D. A. Ruddy, T. D. Tilley 2:10 1302. Chiral carboxylate metal-organic frameworks. J. A. Rood, B. C. Noll, K. W. Henderson 2:30 1303. Preparation and characterization of transparent and conductive porous titanium oxides by sol-gel process. U. Akoroda, S. Sambandam, W. Lu
Section D McCormick Place Lakeside Room E253A, Level 2
SUNDAY AFTERNOON
MEDI
Presiding
1:30 1311. Synthesis and characterization of infrared probes of vibrational relaxation in charge-transfer excited states. C. E. McCusker, J. K. McCusker 1:50 1312. High-frequency and -field electron paramagnetic resonance (HFEPR) spec troscopy of Co(ll) and Ni(ll) scorpionate complexes. J. Telser, J. Krzystek, A. Ozarowski, P. J. Desrochers, S. Trofimenko, D. C. Swenson 2:10 1313. Ultrafast structural dynamics of copper(l) bis-phenanthrolines in solution revealed by transient absorption and emission spectroscopy. G. B. Shaw, C. D. Grant, E. W. Castner Jr., G. J. Meyer, L. X. Chen
Social Hour: Sun SUNDAY MORNING Section A McCormick Place Lakeside Room E353 A/B, Level 3 Fragment-Based Drug Discovery Cosponsored with Teledyne Isco Presiding
9:00 1. Fragment based drug design. M. Shapiro 9:40 2. Fragment screening and its applica tion to drug design: The discovery of low molecular weight, non-peptidic, nanomolar inhibitors of beta-secretase. P. D. Edwards 10:20 3. Fragment to lead evolution using chemical microarray screening. H-D. Junker, T. Neumann, I. Ott, K. Burkert, O. Keil, K. Schmidt, R. Sekul 11:00 4. Structure activity relationships by mass spectrometry: Discovery of novel MMP3 inhibitors. D. A. Ockey, T. R. Gadek 11:40 5. Fragment-based drug discovery: From crystal to clinic. S. Howard 12:20 6. Strategies and experiences in fragment-based drug discovery. R. E. Hubbard Section Β McCormick Place Lakeside Room E352, Level 3 General Oral Session D. P. Rotella,
McCormick Place Lakeside Room E353 A/B, Level 3 First Time Disclosure of Clinical Candidates A. W. Stamford, Organizer,
SOCIAL EVENT:
J. S. Albert, Organizer,
Section A
Organizer
9:00 7. Easier and better exploitation of PhysChem properties in medicinal chemis try. S. Bhal, G. Pearl, K. Kassam 9:20 8. Independent expression of two genes using modified ecdysone receptors and small molecule actuators of a single chemotype. R. E. Hormann, O. Chortyk, J. L. Friz, C. S. Thompson, P. Kumar, C. Tice, B. Vertin, R. Palli, M. Kumar, A. Meyer, T. Meteyer, H. Smith, D. E. Cress, B. Li 9:40 9. Modeling subtype-selective agonists binding with a4b2 and a7 nicotinic acetyl choline receptors: Effects of local binding and long-range electrostatic interactions. X. Huang, F. Zheng, X. Chen, C-G. Zhan 10:00 10. Computational and experimental studies of free and enzyme-bound N-alkyltacrine derivatives. P. R. Carlier, L. D. Williams 10:20 11. Synthesis and structure-activity relationships of a series of sigma receptor ligands. R. Nahas, J. R. Lever, S. Z. Lever 10:40 12. Peptide ligands of regulators of G-protein signaling 4 (RGS4) identified by screening of a focused one-bead, onecompound peptide library. R. A. Roof, D. L. Roman, A. J. Turbiak, R. Neubig, H. I. Mosberg 11:00 13. Synthesis and biologic evaluation of radioiodinated 5-chloro-2-(6-iodo-4-oxo3,4-dihydroquinazolin-2-yl)phenyl phos phate (125IQ2-P, 5-CI) for enzyme-medi ated ^solubilization therapy. K. Wang, S. J. Adelstein, A. Wang 11:20 14. Synthesis, biological evaluation and docking studies inside PPAR alpha of resveratrol analogs. C. S. Mizuno, A. Patny, M. A. Avery, W. H. Yokoyama, A. M. Rimando Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN
Presiding
1:30 15. Identification of GSK625433: A novel clinical candidate for the treatment of hepatitis C. D. Haigh, E. M. Amphlett, G. S. Bravi, H. Bright, V. Chung, C. L. Chambers, A. G. Cheasty, M. A. Convery, M. R. Ellis, R. Fenwick, D. F. Gray, C. D. Hartley, P. D. Howes, R. L. Jarvest, K. J. Medhurst, A. Mehbob, D. Mesogiti, F. Mirzai, F. Nerozzi, N. R. Parry, N. Roughley, T. Skarzynski, M. J. Slater, S. A. Smith, R. Stocker, C. J. Theobald, P. J. Thomas, P. A. Thommes, J. H. Thorpe, C. S. Wilkinson, E. Williams 2:10 16. Identification and development of inhibitors of PI3K and related protein kinases for cancer treatment. M. Maira, F. Stauffer, P. Furet, H-G. Capraro, P. Holzer, C. Garcia-Echeverria 2:50 17. Preclinical antitumor activity of BMS-690514, a panHER/VEGFR2 kinase inhibitor. A. V. Gavai, P. Chen, D. Norris, B. E. Fink, H. Mastalerz, Y. Zhao, W-C. Han, G. Zhang, W. Johnson, E. Ruediger, P. Dextraze, J-P. Daris, S-H. Kim, K. Leavitt, K. Kim, S. Lu, P. Zheng, A. Mathur, D. Vyas, J. S. Tokarski, C. Yu, S. Oppenheimer, H. Zhang, F. Lee, T. W. Wong, G. D. Vite 3:30 18. The discovery of MK-0812, a potent and selective CCR2 antagonist. L. Yang, R. X. Jiao, C. Moyes, G. Morriello, G. Butora, K. Shankaran, A. Pasternak, S. Goble, C. Zhou, M. MacCoss, A-M. Cumiskey, L. Peterson, M. Forrest, J. M. Ayala, H. Jin, J. DeMartino, S. G. Mills 4:10 19. Discovery of PF-184298, a dual serotonin/noradrenaline reuptake inhibitor. G. A. Whitlock, F. Wakenhut, A. Stobie, P. V. Fish, M. J. Fray 4:50 20. Discovery of MK-0974: A potent, orally bioavailable calcitonin gene-related peptide (CGRP) receptor antagonist for the treatment of migraine. D. V. Paone, A. Shaw, D. Nguyen, C. Burgey, J. Deng, C. Stump, A. Quigley, J. DeSolms, S. Kane, K. Koblan, R. Bednar, J. Mallee, S. Mosser, C. Salvatore, D. McMasters, J. Hershey, H. Corcoran, B. Lyle, B. Wong, S. Roller, C. Miller-Stein, J. Rowe, S. Yu, S. Graham, J. Vacca, T. Williams Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN S U N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center General Poster Session Cosponsored with Eli Lilly D. P. Rotella,
Organizer
7:00-9:00 21. Synthesis of 4',4'-C-diaminomethyl nucleoside derivative as a building block for constructing libraries via amide bond formation. C-S. Yu, R-T. Wang, L-W. Chiang, K. Pei, H-L Huang, M-H. Lee 22. An improved method for synthesis of ceramide for constructing alpha-galactosyl ceramide analogs. C-S. Yu, C-H. Yeh, L-W. Chiang, S-D. Pan, K-H. Chang 23. Synthesis of rhamnosyl trisaccharide repeating unit to mimic the antigen deter minant of Pseudomonas syringae lipopolysaccharide. C-S. Yu, H-Y. Wang, L-W. Chiang, S-W. Chen, C-T. Pan 24. Preparation and screening of novel inhibi tors of MurG. A. E. Trunkfield, T. D. H. Bugg
TECH-83
MEDI 25. Inhibitors for the aminoacyl tRNA: lipid 2 ligase MurM from S. pneumoniae. E. Cressina, T. D. H. Bugg, A. J. Lloyd, C. Dowson, D. Roper 26. Total synthesis of IKD-8344. W. H. Kim 27. Novel diphenyl ethers: Design, docking studies and inhibition of enoyl ACP reduc tase from Plasmodium falciparum and Escherichia coli and their structure activity relationship. G. Kumar, M. Chhibber, P. Parasuraman, R. T. N. Chakravarthy, N. Surolia, A. Surolia 28. Mechanism of antimicrobial peptides studied by controlling the topology of peptide assembly. A. W. Young, Z. Liu, C. Zhou, N. R. Kallenbach 29. Molecular template for designing de novo antimicrobial peptide mimetics. C. Zhou, Z. Liu, J. Min, A. W. Young, Y-T. Chang, N. R. Kallenbach 30. De novo multivalent antimicrobial peptides as therapeutics against multidrug-resistant bacterial strain. Z. Liu, C. Zhou, A. W. Young, N. R. Kallenbach 31. Characterization of a small ribozyme with splicing activity: A step forward in the development of a molecular machine to treat pathogens. L. B. Harris, S. O. Rogers 32. Annulation route to kinamycin precursors. Y. Yuan, G. A. Kraus, A. J. Schuster 33. Minor groove binding agents as antibacterials. S. K. Vooturi, C. Cheung, M. Rybak, J. Baltz 34. Substrate mimics as novel inhibitors of the PIsX/PlsY pathway in S. pneumoniae. K. D. Grimes 35. Cloning, expression, and characterization of a K. pneumoniae acetyltransferase involved in virulence. A. E. Zercher, J. L DuBois 36. Novel preparation of nanosilver particles for bacteriostat drug and antimicrobial test. H. Feng, M. D. Wang, Z. L Fu 37. Screening of a peptide library for proteinprotein interaction inhibitors of LpxA. N. Ciminillo, G. D. Dotson 38. Expression, purification, and characteriza tion of Enterococcus faecalis phosphopantothenoylcysteine synthetase. J . Yao, G. D. Dotson 39. Synthesis and evaluation of catalytic intermediate-based inhibitors of phosphopantothenoylcysteine synthetase. J. Patrone, G. D. Dotson 40. Structure activity relationship study of para-substituted phenol derivatives, with comparison of minimum inhibition concen tration and zone of inhibition. J. St. Denis, W. W. Steiner, R. Priefer 41. Pseudans, a synthetic approach to HAQs found in Pseudomonas aeruginosa. W. M. Stalick, R. V. Honeychuck, R. R. Pant, M. Rogers 42. Systems biology solutions on bacterial infections: Optimization of the concentra tion of a generic quorum sensing inhibitor in Escherichia coli and Pseudomonas aeruginosa based on stochastic modeling. A. F. Gonzalez Barrios Sr., L. E. K. Achenie 43. Investigation of the methionine salvage pathway as a possible target for antimicro bial drugs. C. A. Isom 44. Chemical and antimicrobial properties of anise essential oil. Ε. Η. Hudson II, B. Woodard, K. Casmire, F. Abdel-Rahman, W. Zhang, M. A. Saleh 45. Chemical and antimicrobial properties of Chinese star anise essential oil. K. Casmire, B. Woodard, Ε. Η. Hudson II, F. Abdel-Rahman, W. Zhang, M. A. Saleh 46. Synthesis and potency of PA-824 and metronidazole analogs as probes for anaerobic vs. aerobic activity against mycobacterium tuberculosis. P. Kim, U. Manjunatha, C. E. Barry III, C. S. Dowd 47. Small molecule inhibitors of mycothiol production from mycobacterium tuberculo sis. B. B. Metaferia, S. S. U. Hussan, C. A. Bewley 48. Synthesis and antimycobacterial activity of 4-(5-substituted-1,3,4-oxadiazol-2-yl)pyridines. G. Navarrete-Vazquez, G. Molina-Salinas, Z. V. Duarte-Fajardo, J. Vargas-Villarreal, F. Gonzélez-Salazar, H. Tlahuext, S. Said-Fernândez, SE S
84-TECH
TECHNICAL PROGRAM 49. Inhibitors of Trypanosoma cruzi DHFR: Potential chemotherapeutic agents for Chaga's disease. B. A. Shinkre, O. Senkovich, A. Desai, S. E. Velu, D. Chattopadhyay 50. DNA binding properties of antiparasitic agents. B. Nguyen, F. A. Tanious, A. Kumar, D. W. Boykin, W. D. Wilson 51. Development of Quantitative StructureActivity Relationship (QSAR) models for a series of isoflavones as novel antigiardial agents. N. S. Telang, P. Mukherjee, M. A. Avery 52. Design, synthesis, and biological evaluation of tetramic acids as antibacterial agents. R. Yendapally, E. I. Carson, R. E. B. Lee, R. E. Lee 53. Structure-activity relationships of novel pyrimidine derivatives as Plasmodial ODCase inhibitors. A. M. Bello, E. Poduch, I. Crandall, L. Wei, K. C. Kain, E. F. Pai, L. P. Kotra 54. Characterization of novel inhibitors of orotidine 5'-monophosphate decarboxylase (ODCase) using isothermal calorimetry. E. Poduch, A. M. Bello, M. Fujihashi, E. F. Pai, L P. Kotra 55. Covalent inhibitor of orotidine 5'-monophosphate decarboxylase with antimalarial activity. A. M. Bello, E. Poduch, M. Fujihashi, Y. Li, I. Crandall, P. I. Lee, K. C. Kain, E. F. Pai, L. P. Kotra 56. Synthesis of cyclic disulfides as possible antimalarial agents. S. Espinosa, G. A. McConkey, T. Heikkilâ, C. P. Vlaar 57. The synthesis of novel 5- and 6-substituted quinazoline antimalarial compounds. V. E. Kokai, T. Vilaivan 58. New analogs of the natural antifungals cleistopholine and sampangine. O. Marcq, D. Sail, N. Chauhan 59. Design, synthesis and evaluation of 1 -(Dribityl)-1,7-dihydro-pyrazolo[3,4-d]pyrimidine-4,6-diones bearing alkyl phosphate substituents as inhibitors of lumazine synthase. Y. Zhang, A. Bâcher, M. Fisher, B. Illarionov, M. Cushman 60. Synthesis and antifungal activities of modified fluconazole derivatives. Ν. Η. Nam, S. Sardari, K. Parang 61. Optimizing the synthesis of N-methanocarbathymidine, a potent and selective antiviral agent. V. E. Marquez, O. R. Ludek 62. Synthesis and evaluation of a group of selective inhibitors of Ebola cell entry. M. V. Yermolina, J. Wang, D. J. Wardrop, L. Wang 63. Synthesis and antiviral activity of Abyssinone II analogs. R. M. Moriarty, B. C. Surve, R. Naithani, S. N. Chandersekera, V. Tiwari, D. Shukla 64. Synthesis and antiviral activity of Sulforamate derivatives. R. M. Moriarty, R. Naithani, B. C. Surve, V. Tiwari, D. Shukla 65. Synthesis and nuclear magnetic reso nance characterization of nelfinavir. J. Yan, G. Yao, L. Yang 66. Discovery of potent and orally bioavailable CCR5 antagonists: Part I. R. G. Wei, B. Chen, L. Dunning, E. Ho, S. Jaroch, W. Lee, J. Onuffer, B. Subramanyam, J. Shen, J-L Tseng, B. Ye, P. Gary 67. Quinolyl amide derivatives as CCR5 antagonists. S-F. Lu, L. Dunning, S. Jaroch, T. Kirkland, J. Onuffer, G. Phillips, B. Subramanyam, J-L. Tseng, M. Wei, H. Ye, B. Ye 68. 8-Hydroxy-5-(1-H or 1-alkyl-5-oxopyrrolidin-3-yl)-1,6-naphthyridine-7-carboxamide inhibitors of HIV-1 integrase. J. Y. Melamed, M. Egbertson, S. Varga, J. P. Vacca, P. A. Ciecko, G. Moyer, L Gabryelski, P. J. Felock, K. A. Stillmock, M. V. Witmer, D. Hazuda, W. A. Schleif, Y. Leonard, L Jin, J. D. Ellis, S. D. Young
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69. Binding specificity of HIV-fusion blocking protein (MVL) determined by NMR tech niques. S. S. U. Hussan, C. A. Bewley 70. Comparing the conformational behavior of a series of HIV-1 protease inhibitor drugs using the Low Mode:Monte Carlo confor mational search method. J . Lee, C. A. Parish 7 1 . How can (-)-epigallocatechin gallate from green tea prevent HIV-1 virus infection? Mechanistic insights from computational modeling and the implication for rational design of anti-HIV-1 entry inhibitors. A. Hamza, C-G. Zhan 72. Synthesis and biological evaluation of alkenyldiarylmethane HIV-1 non-nucleoside reverse transcriptase inhibitors that possess increased hydrolytic stability. M. D. Cullen, E. De Clercq, C. Pannecouque, T. L. Hartman, R. W. Buckheit Jr., B. L. Deng, M. Cushman 73. 3'-Fluoro-2', 3'-unsaturated carbocyclic nucleosides: Synthesis, anti-HIV activity and molecular modeling studies. J. Wang, Y. Jin, K. L. Rapp, R. F. Schinazi, C. K. Chu 74. Stereoselective, de novo synthetic route to a combinatorial library of peptide-linked nucleosides. K. W. C. Poon, A. Datta 75. Screening antiviral agents based on yeast killer system model. L. Pan, Y-W. Huang, Y. Yanrui 76. Total synthesis of carbocyclic sinefungin. X. Yin, G-X. Zhao, S. W. Schneller 77. Synthesis and biological properties of carbocyclic 6'-deaminosinefungin and related compounds. W. Ye, Q. Chen, S. W. Schneller 78. Design and synthesis of carbaformycin, carbaneplanicin and their 3-deaza ana logs. H. Wang, Y. Zhang, S. W. Schneller 79. 5'-Fluoro-5'-deoxyaristeromycin. W. Li, X. Yin, S. W. Schneller 80. 4'-Fluoro analog of 5'-noraristeromycin. W. Li, X. Yin, S. W. Schneller 8 1 . Enatioselective synthesis of carbocyclic 5'-norformycin. M. He, X. Yin, J. Zhou, S. W. Schneller 82. Synthesis and the antiviral activity of 3-methyl-3-deaza-5'-noraristeromycin. C. Liu, S. W. Schneller 83. Benzofuran inhibitors of hepatitis-C RNA polymerase: Synthesis of lead molecules including clinical candidate HCV-796. A. K. Saha, T. H. Faitg, B. A. Kulkarni, C. Blackledge, S. Masterson, Y. Deng, S. Rippin, D. Rys, T. Lessen, C. Cebula, L. Leister, J. Swestock, T. J. Nitz, H. Feng, C. J. Burns, D. C. Young, S. Chunduru 84. Optimization of N-alkyl indole allosteric inhibitors of the HCV NS5B polymerase enzyme. B. Pacini, S. Altamura, S. Avolio, M. Bisbocci, M. DiFilippo, S. DiMarco, O. Gonzalez Paz, R. Laufer, F. Narjes, G. Paonessa, M. Rowley, S. Harper 85. Docking and 3-D-QSAR analysis of HCV NS5B RNA-dependent RNA polymerase inhibitors based on a common benzothiadiazine scaffold. S. Odde, P. Sivaprakasam, R. J. Doerksen 86. Structure-activity relationship of a series of P2 proline arylether inhibitors of the HCV NS3«4A protease. J. J. Court, C. A. Gates, C. Lin, K. Lin, Y-P. Luong, J. H. van Drie, R. B. Perni 87. Tetrahydrocarbazoles as potential thera peutic agents for human papillomavirus infection. P. R. Sebahar, K. W. Brown, K. S. Gudmundsson, R. Harvey, L. Richardson, P. Sethna 88. Tetrahydrocarbazole-amides as potential agents for treatment of papillomavirus infection. K. S. Gudmundsson, S. Boggs, B. A. Johns, L. Richardson, P. R. Sebahar, J. G. Weatherhead, D. Haigh, K. W. Brown, R. Harvey, P. Sethna, Q. Zhang, P. Golden, S. Xie 89. 2-Substituted tetrahydrocarbazoles as potential therapeutic agents for human papillomavirus infection. L. D. Richardson, K. W. Brown, R. Harvey, K. S. Gudmundsson, P. R. Sebahar, P. Sethna 90. Studies toward a new foot-and-mouth disease antiviral agent. N. Roqué-Rosell, S. Curry, R. J. Leatherbarrow 9 1 . Synthesis of imidazolyl substituted heterosteroidal derivatives as potent aromatase inhibitors. R. Bansal, S. Guleria, R. W. Hartmann, A. Palusczak
92. Synthesis of 8-[4-(aminoethoxy)-3-methoxyphenyltheophylline derivatives as potent adenosine receptor antagonists. R. Bansal, G. Kumar, A. L. Harvey, L. Young 93. Synthesis, SAR and biological evaluation of racemic abyssinone II and analogs as potential aromatase inhibitors for prevention of breast cancer. A. Maiti, M. Cuendet, V. L. Croy, D. C. Endringer, J. M. Pezzuto, M. Cushman 94. Identification of a novel small molecule antagonist of anti-apoptotic Bcl-2 proteins: Bcl-2 protein binding, in vitro cytotoxicity, and synergism. C. Xing, J. M. Doshi 95. Design and evaluation of novel smac mimetics as potent inhibitors of XIAP. Y. Peng, H. Sun, Z. Nikolovska-Coleska, S. Qiu, C-Y. Yang, S. Wang 96. Novel, simplified α-helix mimetics targeted to Bcl-x L . J. M. Rodriguez, G-l. Lee, D. Dhar, A. D. Hamilton 97. Discovery and optimization of substituted N-Aryl-1H-pyrazolo[3,4-b]quinolin-4-amines as potent apoptosis inducers using a cell-based high throughput assay. H-Z. Zhang, G. Claassen, C. Crogan-Grundy, J. Drewe, S. Kasibhatla, B. Tseng, S. X. Cai 98. 4-Aryl-4H-chromenes as a new series of apoptosis inducers using a cell- and caspase-based high throughput screening assay: Structure-activity relationships of /V-substituted pyrrole fused at the 7, 8-positions. W. Kemnitzer, S. Kasibhatla, S. Jiang, H. Zhang, R. Denis, S. Lamothe, H. Gourdeau, B. Tseng, J. Drewe, S. X. Cai 99. Drug-ability case study: Exploration of structural modifications and their impact on oral bioavailability of novel radio-sensitization agents (A): Z-(±)-2-(1-Benzylindole-3yl-methylene)azabicyclo[2.2.2]octane-3-ol, (B): Z-(±)-2-(1 -Benzylindole-3-ylmethylene)azabicyclo[2.2.2]octane-3-one and (C): Z-(±)-2-[1-(4-chlorobenzyl)indole3-yl-methylene]azabicyclo[2.2.2]octane-3ol. A. M. Al-Ghananeem, Z. Al-Beyati, A. H. Malkawi, V. N. Sonar, M. Freeman, P. A. Crooks 100. Synthesis of carbon-11 labeled cyclofenil derivatives as new potential PET agents for imaging breast cancer estrogen recep tors. M. Gao, M. Wang, Q-H. Zheng 101. Generation of new chelates for targeted MRI and radioimmunotherapy. X. Ma, H. Song, H. Lee, S. Mhaske, S. Bhuniya, H-S. Chong 102. Fluorine-substituted 6-Aryl-1,4dihydrobenzo[d][1,3]oxazine-2-thiones for breast tumor imaging and radiotherapy: Synthesis and receptor binding affinity. H-B. Zhou, Κ. Ε. Carlson, J. A. Katzenellenbogen 103. Synthesis and evaluation of carrier linked small molecules as targeted chemo and binary radiotherapeutic agents. V. J. Reddy, V. R. Mereddy 104. Radiosynthesis of 18F-fluro-BMS-354825 for PET imaging of SRC expression in tumors. Y. Ying, U. Mukhopadhyay, M. M. Alauddin, W. Bornmann, J. Gelovani 105. Synthesis of [ 124 l]lodo-ABT-737, a PET imageable tracer for BCI-2 expression in tumors. D. Han, L. Guo, D. S. Maxwell, D. J. Yang, S. T. Lim, I. Samudio, M. Andreeff, W. G. Bornmann, J. G. Gelovani 106. Improved synthesis of 173-hydroxy-16a[ 124 l]iodowortmannin for molecular imaging of PI-3 kinases expression with PET. D. Han, L. Guo, D. J. Yang, H. Kurihara, H. H. Yeh, W. G. Bornmann, J. G. Gelovani 107. Synthesis toward the active side chains of avicins and their analogs. D. Han, W. G. Bornmann, J. U. Gutterman 108. An improved synthesis of beta-D-galactopyranosyl-(1,4')-2'-deoxy-2'-[18F]-fluorobeta-D-glucopyranoside for PET imaging of lactose-binding protein expression. Y. Ying, L Guo, P. Ghosh, M. M. Alauddin, W. Bornmann, J. Gelovani 109. STI571 Analogs: 18F- STI571 as poten tial agents for PET imaging of c-kit expres sion at a kinase level. Z. Peng, W. Bornmann, A. Pal, P. Ghosh, S. T. Lim, J. Gelovani, D. Maxwell, M. M. Alauddin 110. Activity of novel sulfonium-containing bisphosphonates in tumor cell lines: A QSAR analysis. M. P. Hudock, Y. Zhang, A. Leon, K. Krysiak, E. Oldfield
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111. Development of novel cucurbitacin derivatives through QSAR studies as anticancer candidates. A. J. Young, F. T. Halaweish 112. Functionalized bionanocomposites for guided hyperthermic ablation of brain tumors. E. A. Rozhkova, X. Liu, T. Rajh,. V. Novosad, S. D. Bader, A. J. Rosengart 113. Synthesis and biological activity of 2-amino-4-substitutedanilino-6-substituted phenylmethyl pyrrolo[2,3-d]pyrimidinés as inhibitors of multiple receptor tyrosine kinases. A. Gangjee, S. Kurup, M. Ihnat, D. Green 114. Structure-based drug design of c-kit inhibitors for use in the treatment of acute myeloid leukemia. D. S. Maxwell, A. Pal, Z. Peng, A. Shavrin, S. Faderl, D. Harris, Q. Van, Z. Liu, S. Verstovsek, T. Manshouri, A. Ferrajoli, H. Kantarjian, Z. Estrov, W. G. Bornmann 115. Structure-based drug design of c-met inhibitors for use in the treatment of multiple myeloma. D. S. Maxwell, Y. Ying, D. Han, Z. Peng, H. Kantarjian, C. Stellrecht, V. Gandhi, W. G. Bornmann 116. 3-Cyclohexylindoles: A new class of inhibitors of 3-phosphoinositide-dependent kinase 1 (PDK1). K. M. K. Kutterer, Z. Tang, A. Aplasca, A. Malana, B. Guo, X. Han, K. Arndt, A. Gopalsamy, J. W. Ellingboe 117. SAR of a series of 1H- and 3H-imidazo[4,5]pyridin-2-yl-pyridin-2(1H)one and 9H-purin-8-yl-pyridin-2(1H)-one inhibitors of IGF-1R Kinase. C. Ouellet, F. Beaulieu, M. D. Wittman, K. Zimmermann, J. Carboni, F. Y. Lee, P. Balimane, L. Discenza, A. Greer, A. Li, Z. Yang, J. Banville, A. Martel, R. Attar, M. Gottartis, D. M. Vyas 118. A novel series of low nM JAK2 selective inhibitors exhibit potent in vitro activities with favorable preclinical properties. C. C. Mak, J. Cao, C. Chow, R. Fine, J. Hood, X. Kang, B. Klebansky, D. Lohse, A. McPherson, G. Noronha, V. P. Pathak, J. Renick, R. Soil, B. Zeng 119. Design, syntheses and SAR of low nM inhibitors targeting JAK2. J . Cao, C. Chow, R. Fine, J. Hood, X. Kang, B. Klebansky, D. Lohse, C. C. Mak, A. McPherson, G. Noronha, V. P. Pathak, J. Renick, R. Soil, B. Zeng 120. Development of novel and potent inhibitors of JAK2: Structure activity relationship studies for optimiziation of JAK2 potency while minimizing JAK3 activity. A. McPherson, J. Cao, C. Chow, R. Fine, J. Hood, X. Kang, B. Klebansky, D. Lohse, C. C. Mak, G. Noronha, V. P. Pathak, J. Renick, R. Soil, B. Zeng 121. Development of highly selective Chk-1 inhibitors with low nanomolar cellular activity. F. A. Diaz, R. Holcomb, F. Farouz, G. Thorsett 122. Investigation of novel 7,8-disubstituted5,10-dihydro-dibenzo[b,e][1,4]diazepin-11 ones as potent and selective Chk1 inhibitors. L. A. Hasvold, L. Wang, G. M. Sullivan, M. Przytulinska, L. Hexamer, Z. Xiao, Z. Chen, W-Z. Gu, P. Merta, J. Xue, P. Kovar, H. Zhang, J. Bouska, C. Park, T. Sowin, S. Rosenberg, N-H. Lin 123. Investigation of novel 7-substituted and 8-substituted-5,10-dihydrodibenzo[b,e][1,4]diazepin-11-one based potent, and selective Chk-1 inhibitors. L. Hexamer, L. Wang, G. M. Sullivan, M. Przytulinska, Z. Chen, Z. Xiao, W-Z. Gu, J. Xue, M-H. Bui, P. Merta, P. Kovar, J. Bouska, J. Bauch, K. C. Marsh, H. Zhang, T. Sowin, S. H. Rosenberg, N-H. Lin 124. Aza-rebeccamycin analogs as potent Checkpoint kinase 1 inhibitors. M. Prudhomme, S. Messaoudi, F. Anizon, B. Pfeiffer, R. M. Golsteyn
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
125. Synthesis of novel macrocyclic bioreductive alkylating agents. J. M. Wilson, D. J. Robins, A. Sutherland 126. Synthesis of bis and trisbenzamidoximes. J. E. Johnson, C. Carvallo, N. Sanchez, V. Garza, D. C. Canseco, D. D. Dolliver, G. L. Eggleton, F. R. Fronczek 127. The synthesis of the stable substrate for imaging HSV1 -TK expression and its biological study. G. An, K. Lee, H. Rhee 128. Utilization of HPLC to determine a potential interaction between C^-benzylguanine and cisplatin. C. A. Rabik, M. E. Dolan 129. Synthesis of sansalvamide A derivatives: Novel templates as potent antitumor agents. E. K. Singh, R. Rodriguez, T. J. Styers, P-S. Pan, C-M. Pan, S. Ravula, S. Lapera, J. Cajica, J. D. Brown, E. Parry, S. McAlpine 130. Synthesis of FR235222 derivatives: Novel templates as potent anticancer agents. C-M. Pan, E. K. Singh, S. Ravula, S. McAlpine 131. The synthesis and structure-activity evaluation of deguelin analogs. Z. Peng, W. Bornmann, L. Gao, W-Y. Kim, H-Y. Lee 132. Molecularly engineered specificity in anticancer activity. A. Fernandez, Z. Peng, W. Bornmann, L-B. Gabriel, D. Maxwell 133. Synthesis, in vitro tubulin inhibition and cell cytotoxicity of cyclohexenone derivatives of combretastatin-A4. J. Ruprich, A. Prout, J. Dickson, B. Younglove, H. Mackay, K. Baxi, R. LeBlanc, L. Forrest, H. Holt Jr., P. Hills, S. Mooberry, T. Brown, M.Lee 134. Binding of f-PIP and JH-37 to the inverted CCAAT box-2 of the topoisomerase Να promoter. A. Sielaff, A. Cooper, H. Mackay, T. Brown, C. O'Hare, J. Kluza, M. Kotecha, M. Le, D. Hochhauser, J. A. Hartley, M. Lee 135. Discovery of potent EDG4 antagonists as potential anticancer agents. H. P. Beck, K. Dai, B. Frank, K. Hasslinger, C. Hedberg, R. Hungate, J. Jaen, T. Kohn, C. Li, L. Liang, J. Medina, S. Rubenstein, R. Schwandner, W. Shen, H. Wesche 136. Synthesis and CYP26A1 inhibitory activ ity of 1 -[benzofuran-2-yl-(4-alkyl/arylphenyl)-methyl]-1 H-triazoles and aminobenzooxazole derivatives. S. Pautus, M. P. Coogan, C. Simons 137. Synthesis of substituted stilbenes and benzanilides as therapeutics for cancer. M. I. Noce, J. J. Heynekamp, L. A. Hunsaker, L. M. Deck, D. L. Vander Jagt 138. Design and synthesis of PEG-containing CC-1065 analogs for targeted therapy of cancer. R. Y. Zhao, D. Sun, E. Cavanagh, M. Miller, B. Leece, H. Erickson, R. Singh, Y. Kovtun, V. Goldmacher, R. Chari 139. Synthesis and biological evaluation of novel T-type calcium channel blockers. H. N. Seo, J. Y. Choi, H. Rhim, A. N. Pae, D. J. Choo, J. Y. Lee 140. Anticancer activities of 3,4-dihydroquinazoline derivatives as T-type calcium channel blockers. J. Y. Choi, H. N. Seo, M. J. Lee, H. Rhim, D. J. Choo, J. Y. Lee 141. Enhancement of the anticancer activity of cladribine by application of the phosphoramidate protide approach. R. Valente, C. Congiatu, E. Walsby, K. Mills, C. McGuigan 142. Synthesis of isoprenoid bisphosphonate isomers and their impact on protein geranylgeranylation. J . S. Yu, A. J. Wiemer, K. M. Lamb, R. J. Hohl, D. F. Wiemer 143. A new versatile photoactivable probe designed to investigate the diphosphate binding site of enzymes using isoprenoid diphosphates as substrates. O. Henry, M. D. Distefano 144. Synthesis of deuterium-labeled isoprenoids. M. W. Amolins, R. A. Gibbs, A. Placzek 145. Synthesis and evaluation of peptide analogs designed to disrupt the interaction between Cdc42 and RhoGDI. J. W. Wollack, D. G. Mullen, N. A. Zeliadt, E. V. Wattenberg, M. D. Distefano 146. Insight into the structural requirements of famesyltransferase inhibitors based on 3-D QSAR CoMFA and CoMSIA models. D. S. Puntambekar, R. Giridhar, M. R. Yadav
147. Imidazole-containing famesyltransferase inhibitors: 3-D quantitative structure-activity relationship and molecular docking stud ies. A. Xie, S. Odde, P. Sivaprakasam, R. J. Doerksen 148. Development of peptide antagonists and agonists of the TGF-β signaling pathway. L Li, A. P. Hinck, F. M. Hoffmann, L. L. Kiessling 149. Discovery and SAR of A-620223, a potent and efficacious inhibitor of poly(ADP-ribose) polymerase for the treatment of cancer. G-D. Zhu, V. B. Gandhi, J. Gong, S. Thomas, W. Lubisch, R. Grandel, W. Wernet, Y. Luo, X. Liu, Y. Shi, V. Klinghofer, E. F. Johnson, D. Frost, J. Bouska, K. C. Marsh, C. Park, S. H. Rosenberg, V. L. Giranda, T. D. Penning 150. Synthesis and SAR of novel, potent and orally bioavailable benzimidazole inhibitors of Poly(ADP-ribose) Polymerase (PARP) with a quaternary methylene-amino sub stituent. V. Β. Gandhi, J. Gong, S. Thomas, Y. Luo, X. Liu, Y. Shi, V. Klinghofer, E. F. Johnson, D. Frost, C. Donawho, J. Bouska, C. Park, S. H. Rosenberg, V. Giranda, T. D. Penning, G-D. Zhu 151. Mutual prodrugs of all-trans retinoic acid and histone deacetylase inhibitors: Potent anticancer agents. L. K. Gediya, A. Khandelwal, J. Mehta, P. Purushottamachar, V. C. O. Njar 152. In vitro characterization of cryptophycin epoxidase. Y. Ding, Z. Q. Beck, W. H. Seufert, D. H. Sherman 153. G-quadruplex binding agents: 2-Carboxy4-hydroxybenzo-(h)-quinoline derivatives. H. Paritala, S. M. Firestine 154. Structure-activity relationships of monomethyl derivatives of quercetin on HSP70 production and HSP27 phosphorylation. R. Wang, C. Hunt, J-S. Taylor 155. Chimeric macrocycles as novel Hsp90 inhibitors. N. Ortuzar, B. S. J. Blagg 156. Structure-activity relationships of conformationally-biased chimeric inhibitors of Hsp90. M. K. Hadden, S. Apte, B. S. J. Blagg 157. Novobiocin: A bidirectional approach toward cytotoxic inhibitors of Hsp90. J. A. Burlison, D. J. Lubbers, C. Avila, J. Holzbeierlein, B. Blagg 158. Semi-synthesis and biological activity of camptothecin tripartate conjugates. C Samori, A. Battaglia, A. Guerrini, G. Varchi, G. L. Beretta, F. Zunino, G. Fontana, E. Bombardelli 159. Semi-synthesis and biological activity studies of 16a-thio-camptothecins. G. Fontana, C. Samori, A. Battaglia, G. Varchi, G. L. Beretta, F. Zunino, G. Bifulco, E. Bombardelli 160. Semi-synthesis and biological activity studies of C-ring modified camptothecins and 16a-thio-camptothecins. G. Varchi, A. Battaglia, C. Samori, A. Guerrini, G. L. Beretta, F. Zunino, G. Fontana, E. Bombardelli 161. Psoralen conjugates for visualization of localized genomic interstrand crosslinks. A. Kalliat Thazhathveetil, S-T. Liu, F. E. Indig, M. M. Seidman 162. Synthesis and anticancer properties of novel pyranopyridones. J. D. Bettale, M. A. Ogasawara, M. Manpadi, E. M. Elias, S. Rogelj, S. T. Shors, P. Y. Uglinskii, Ν. Μ. Evdokimov, I. V. Magedov, A. Kornienko 163. Synthesis and radiolabeling of SAHA analog for radio imaging of HDAC expres sion-occupancy in tumors during molecu lar-targeted therapy of cancer. A. Pal, H. Kurihara, Z. Peng, D. J. Yang, W. Bornmann, J. Gelovani 164. Net charge is not the primary determi nant of onconase cytotoxicity. R. F. Turcotte, R. T. Raines 165. Natural defense against cancer: Compu tational analysis of the role of the key residues of formamido-pyrimidine DNA glycosylase in lesion recognition. K. Song, C. De los santos, A. P. Grollman, C. Simmerling 166. 1-Azolyl-4-phenyl-2-butanones as heme oxygenase inhibitors: Probing for various azoles as pharmacophores. G. Roman, R. T. Kinobe, K. Nakatsu, W. A. Szarek
167. Structure-based design and evaluation of peptide and peptido-mimetic antagonists of Survivin. S. A. Kawamoto 168. Targeted degradation of aryl hydrocar bon receptor via the PROTAC approach: A chemical genetic tool for AHR biology. H. Lee, D. Puppala, E-Y. Choi, H. I. Swanson, K-B. Kim 169. 2-Amino-4-methyl-5-phenylethyl substituted-7-/V-benzyl-pyrrolo[2,3-cdpynmidines as novel antitumor antimitotic agents that also reverse tumor resistance. A. Gangjee, O. A. Namjoshi, S. N. Keller, C. D. Smith 170. Cytotoxicity of parthenolide analogs against leukemia cells in vitro. S. Nasim, P. A. Crooks 171. Polyamine/transition metal complexes as potential antitumor agents. H. Amunugama, A. Hirata, F. Hirata, R. A. Casera, A. M. Angeles-Boza, K. R. Dunbar, J-G. Delcros, P. M. Woster 172. Probing the mechanism of 3-deoxyschweinfurthin Β anticancer activity via fluorescence microscopy. J. D. Neighbors, C. H. Kuder, R. J. Hohl, D. F. Wiemer 173. Effects of C-ring substitution on the pharmacophore of the schweinfurthins. M. P. Callahan, J. D. Neighbors, D. F. Wiemer 174. Differential thermal denaturation profiles of structurally diverse DNA aptamers. B. D. Jeanfreau, G. R. Bishop 175. Correlating temperature-dependent fluorescence emission and circular dichroism spectra. J. A. James, G. R. Bishop 176. Statistical mechanical models for analyz ing the stabilities of drug-DNA complexes. A. C Holley, G. R. Bishop 177. Method development for the determina tion of the molar absorbance properties of DNA aptamers. H. K. Goel, G. R. Bishop 178. Effects of ion binding and solution pH on the molar absorbance properties of DNA aptamers. S. O. Gibson, G. R. Bishop 179. Energetic signatures for induced-fit binding modes in structurally diverse DNA aptamers. B. C Polander, G. R. Bishop 180. Highly regioselective synthesis of 5-fluorouridine ester derivatives catalyzed by Lipozyme TL IM in organic media. H. Wang, W-Y. Lou, H. Wu, M-H. Zong 181. Novel analogs of Atiprimod for targeting multiple myeloma. A. Kazimierski, K. Shailubhai, D. Picker, W. Priebe 182. Synthesis of ageladine A, analogs and their biological screening. S. R. Shengule, P. Karuso 183. Tandem enzymatic syntheses of TDPdeoxysugars and spinosyn analogs by in vitro recombination of natural product biosynthetic pathways. H-T. Chiu, Y - L Chen, C. C. Wu 184. Free radical chemistry of tobacco-spe cific nitrosamines. C R. Cox, J. J. Kiddle, S. P. Mezyk 185. Reaction of nitrosamines with biologically important free radicals under anaerobic and aerobic conditions. J. J. Kiddle, S. P. Mezyk, K. P. Madden 186. In silico design of effective inhibitors for α-tubulin. K. Diraviyam, D. Sept 187. A combinatorial study of group 3 and lanthanide based polymer supported Lewis acids. P. A. Boguszewski 188. A scaleable route to a polymer sup ported hypervalent iodine (V) oxidant. P. A. Boguszewski, M. J. I. Williamson 189. Advanced topics for use of RediSep® specialty media columns in flash chroma tography. V. D. Thomason, V. Williams 190. Analytical automation batch design for pharmacokinetic studies. B-L. Wan, K. D. Anderson 191. Novel approach for drug delivery: 'Tro jan" dendrimers. J. A. Valencia-Gallegos, M. M. Alvarez, P. Arce 192. Approaches to precision-guided nanoparticles: Focus on linker and targeting mol ecule design and synthesis. R. N. Hanson, J. A. Hendricks, K. Bailey 193. Asymmetric reduction of ketones with the spiroborate ester derived from diphenyl prolinol and ethylene glycol. M. De Jesus, W. Correa, V. Stepanenko, I. Guzman, W. de la Cruz, M. Ortiz, L Ortiz, C. Vazquez 194. Biological implications of the environ mental effects on tryptophan-singlet oxy gen interaction. C. L. Jones, Κ. Ν. Grier
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195. Chemical constituents of Calorhyllum membranaceum Gardn. X. Song, C. Han 196. Chemical constituents of the stem of Artabotrys hainanensis. C. Han, X. Song 197. Computational investigation on the reductive amination of pharmacologically important triquinanes. W. J. Geldenhuys, L-M. Bezuidenhout, S. F. Malan, C. J. Van der Schyf 198. Conformational features of substituted cyclopropanes in drug-like molecules: A brief guide for medicinal chemists. D. L. Cheney, J. X. Qiao 199. Controlled rate drug delivery systems: Effect of non-Fick diffusion-response to a pulse injection. K. R. Sharma 200. Design and synthesis of novel Xylosides as glycosaminoglycan primers. M. Ethirajan, X. Victor, V. Tran, K. Nguyen, K. Balagurunathan 201. Design and synthesis of a-sugar amino acids as inhibitors of protein-protein inter actions. S. K. Mamidyala, J. Baltz, D. Coen, S. M. Firestine 202. Synthesis and bioactivity of sulfonamide chalcones. D. H. Murray, L. Lange, A. Matak 203.17-Arylcarbamidomethyl-4-azasteroids as selective androgen receptor modulators. W. P. Dankulich, H. J. Mitchell, G. D. Hartman, R. S. Meissner MONDAY MORNING Section A McCormick Place Lakeside Room E353 A/B, Level 3 Drugs from Academia: Marketed Drugs Discovered in Academic Labs J. E. Macor, Organizer,
Presiding
9:00 204. Invention of SAHA, the first HDAC inhibitor approved by the FDA. R. Breslow 9:40 205. Darunavir, a new protease inhibitor to combat drug-resistance: Structurebased design targeting protein backbone. A. K. Ghosh 10:20 206. The discovery and development of 3'-heteranucleosides. D. C. Liotta 11:00 207. Discovery of Alimta, a broadly effective new antitumor agent. E. C. Taylor 11:40 208. The taxol story. R. A. Holton
MONDAY AFTERNOON Section A McCormick Place Lakeside Room E353 A/B, Level 3 Ligands for the Glucocorticoid Receptor S. McDonald and R. P. Trump, Organizers, Presiding 1:30 214. Introduction to the glucocorticoid receptor and modeling studies. E. L. Stewart, K. Biggadike 1:50 215. Nonsteroidal glucocorticoid recep tor modulators for use in inflammation and oncology. R. I. Higuchi, R. J. Ardecky, S. L Roach, A. R. Hudson, D. P. Phillips, J. S. Tyhonas, D. S. Karanewsky, K. B. Marschke, F. J. Lopez, E. G. Vajda, D. K. Rungta, E. A. Kallel, R. P. Bissonette, W. W. Lamph, J. Rosen, L. Zhi, A. Negro-Vilar, J. N. Miner 2:20 216. Non-steroidal GR agonists: Improving the established drugs? H. Rehwinkel, H. Schaecke, K. Asadullah, S. Baeurle, M. Berger, W-D. Doecke, H. Hennekes, S. Jaroch, K. Krolikiewicz, M. Lehmann, A. Mengel, R. Neuhaus, D. Nguyen, L. Roese, A. Rotgeri, N. Schmees, A. Schottelius, W. Skuballa, P. Strehlke 2:50 217. Identification and optimization of non-steroidal glucocorticoid receptor ago nists. D. S. Thomson 3:20 218. A design and iterative approach to non-steroidal and steroidal agonists. K. Biggadike, D. M. Coe, I. M. Mclay 4:00 219. Discovery of novel, selective glucocorticoid receptor modulators. A. Ali, C. F. Thompson, J. Balkovec, D. Graham, M. Greenlee, M. L Hammond, N. Quraishi, G. Rouen, C. Smith, J. R. Tata, G. Taylor, M. Einstein, L. Ge, G. Harris, T. M. Kelly, P. Mazur, S. Pandit, J. Santoro, A. Sitlani, C. Wang, J. Williamson, D. F. Miller, E. A. O'Neill, C. M. Thompson, D. M. Zaller, M. J. Forrest, E. Carballo-Jane, S. Luell, D. Visco, C. Rasa, K. Lowitz 4:30 220. Azadecalin as a scaffold for selec tive glucocorticoid receptor antagonists. R. D. Clark, N. C. Ray, H. J. Hunt, D. E. Clark, K. Williams, P. Blaney, C. Hurley, R. Devos, M. Wong, J. K. Belanoff Undergraduate Research Poster Session: Medicinal Sponsored by CHED, Cosponsored with SOCED, and MEDI
Section Β McCormick Place Lakeside Room E353 C, Level 3
M O N D A Y EVENING
Kinesin Spindle Protein Inhibitors
Section A
C. Cox and R. M. Garbaccio, Presiding
Hyatt Regency Chicago Riverside Center
Organizers,
9:00 Introductory Remarks. 9:05 209. Targeting kinesin spindle protein (KSP) for the treatment of cancer. K. W. Wood 9:40 210. Examining the chemical inhibition and microscopic properties of kinesin-5. Τ. Μ. Kapoor 10:15 211. Discovery and optimization of kinesin spindle protein (KSP) inhibitors. C. D. Cox, P. J. Coleman, Μ. Ε. Fraley, R. M. Garbaccio, M. J. Breslin, D. B. Whitman, J. D. Schreier, G. D. Hartman, M. Torrent, R. Lobell, C. Buser, W. Tao, H. Huber, Ν. Ε. Kohl, Y. Yan, L. C. Kuo 10:50 212. Discovery of novel heterocyclic inhibitors of kinesin spindle protein (KSP). X. S. Qian, A. I. McDonald, H-J. Zhou, B. Yao, L. W. Ashcraft, J. K. Huang, M. V. Marin, C. E. Aroyan, K. W. Wood, D. J. Morgans Jr., G. Bergnes 11:25 213. Dihydropyrimidones induce mitotic arrest and a monoastral phenotype consistent with inhibition of the mitotic kinesin Eg5 in cultured cells. L. J. Lombardo
D. P. Rotella,
Presiding
8:00-10:00 27, 35-36, 44, 53, 59, 66, 73, 76, 85, 89, 99, 103, 105, 113, 118, 127, 129, 138, 142, 146, 151, 156, 159, 162, 167, 180, 183, 186,189,192,198. See previous listings. 287-288, 304-305, 311, 321, 328, 332, 334, 338, 347, 349, 356, 360, 366, 368-369, 372-374, 378, 395, 407-408, 416-417, 425, 430, 433, 440, 443. See subse quent listings.
TUESDAY AFTERNOON Section A McCormick Place Lakeside Room E353 C, Level 3 Emerging Targets for the Treatment of Type-2 Diabetes G. Bebemitz and P. T. Cheng, Presiding
Organizers,
1:30 227. Discovery and biological evalua tion of a novel, potent and selective series of ACC2 inhibitors. Y. G. Gu, M. Weitzberg, R. F. Clark, X. Xu, Q. Li, T. Zhanq, T. M. Hansen, R. F. Keyes, G. Liu, Z. Xin, X. Wang, R. Wang, T. McNally, B. A. Zinker, B. W. Dickinson, N. L. Lubbers, Y. Yang, D. W. A. Beno, D. L. Widomski, J. F. Waring, S. L. Carroll, C. H. Healan-Greenberg, E. A. Blomme, E. U. Frevert, B. A. Beutel, H. L Sham, H. S. Camp 2:05 228. Discovery of potent and selective 11B-HSD-1 inhibitors. W. Yao, J. Zhuo, C. Zhang, M. Xu, D. Qian, D. Burns, C. He, Y. Li, E.*Shi, Q. Lin, L Chen, C. Agrios, L Weng, Y. Li, R. Huber, P. Scherle, S. Diamond, D. Hunter, M. Covington, C. Marando, R. Wynn, K. Katiyar, N. Contel, K. Vaddi, S. Yeleswaram, G. Hollis, S. Friedman, B. Metcalf 2:40 229. Bicyclo[2.2.2]octyltriazole inhibitors of 11beta-HSD1 are efficacious in animal models of metabolic disease. S. T. Waddell, M. Maletic, G. Santorelli, A. Leeman, D. Graham, J. M. Balkovec 3:15 230. Design and synthesis of novel glucokinase activators as potential treat ments for type 2 diabetes. D. McKerrecher, J. V. Allen, P. W. R. Caulkett, C. S. Donald, M. L. Fenwick, E. Grange, Κ. Μ. Johnson, C. Johnstone, C. D. Jones, K. G. Pike, J. W. Rayner, R. P. Walker 3:50 231. Discovery and SAR studies of thienopyridones: A class of small molecule AMPK activators. R. R. Iyengar, G. Zhao, A. S. Judd, L. Kifle, N. Cao, W. J. Chiou, B. L Cool, H. S. Camp, E. U. Frevert, T. M. Turner, K. C. Marsh, J. Liu, A. Mika, M. A. Perham, B. A. Zinker, H. L Sham, P. R. Kym
TUESDAY MORNING Section Β McCormick Place Lakeside Room E353 A/B, Level 3 Mechanistic Approaches to Increasing High Density Lipoprotein Cholesterol Cosponsored with Wyeth Research H. Elokdah and S. D. Larsen, Presiding
Organizers,
8:30 221. Introduction to mechanistic approaches to increasing high density lipoprotein cholesterol. G. P. Vlasuk
86-TECH
8:45 222. Azepine inhibitors of plasma cholesteryl ester transfer protein. N. B. Mantlo, T. Fields, X. Wang, M-C. Fernandez, A. I. Mateo, A. Escribano, E. M. M. de la Nava, S. Parthasarathy, M. W. Giese, M. Carson, T. P. Beyer, S. L. Cockerham, G. Cao, K. Kovach, S. Sweetana, A. Borel, T. M. Jones, E. A. Cannady, C. Cioffe, X. Chen, S. Dinn 9:25 223. Inhibitors of endothelial and hepatic lipases: Development and chal lenges. M. Mosior, H-S. Lin, P. Eacho, P. Foxworthy, M. E. Richett, R. W. Harper, J. E. Lopez, B. Chao, M. L. Chouinard 10:05 224. Niacin receptor agonists. G. Semple 10:45 225. New steroidal mimetics as novel LXR modulators. M. M. Abelman, R. H. Jiang, B. Joshi, J. Chisholm, J. Hao, N. Chu, Ν. Mollova, Κ. Leung, R. Lawn, J. A. Zablocki 11:25 226. Structure based design of nuclear receptor hormone ligands: Potent quinoline-based liver X receptor (LXR) agonists. R. L. Magolda
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
4:25 232. Stearoyl-CoA desaturase-1 inhibi tors: Discovery and in vivo evaluation. G. Liu, Z. Xin, H. Zhao, M. D. Serby, H. T. Smith, N. Cao, Τ. Κ. Surowy, A. Adler, A. Mika, T. B. Farb, C. Keegan, K. Landschulz, M. Brune, C. A. Collins, H. L Sham, H. S. Camp Section Β McCormick Place Lakeside Room E353 A/B, Level 3 General Oral Session Cosponsored with Advanced Chemistry Development D. P. Rotella, Organizer,
Presiding
1:30 233. SSA-426: A combined SSRI/5HT1A antagonist for the treatment of depression. G. Stack, M. Tran, B. Harrison, J. Gross, G. E. M. Husbands, D. A. Evrard, S. Rosenzweig-Lipson, L. A. Dawson, H. Q. Nguyen, T. Spangler, D. Smith, G. Hornby, R. Scerni, H. Gao, S. Kalgaonkar, G. Zhang, M. Abou-Gharbia, C. Kim, L. Schechter, T. Andrée 1:50 234. Aminohydantoins as highly potent, selective and orally active BACE1 inhibitors. M. S. Malamas, J. Erdei, I. Gunawan, N. Pawel, M. Chlenov, A. J. Robichaud, J. Turner, Y. Hu, E. Wagner, S. Aschmies, T. Comery, L. Di, K. Fan, R. Chopra, A. Oganesian, C. Huselton, J. Bard 2:10 235. Gamma-lactam diaminopropane inhibitors of BACE. Κ. Μ. Boy, J. M. Guernon, J. Shi, C. Zheng, A. Liauw, J. J. Bronson, J. E. Macor, A. P. Combs, G. Trainor, C. P. Decicco, A. Good, A. J. Tebben, J. H. Toyn, C. R. Burton, D. M. Barten, J. Marcinkeviciene, R. A. Copeland, J. K. Muckelbauer, P. E. Morin, K. Lentz, C. Albright, L A. Thompson III 2:30 236. DG-051 : A novel leukotriene A4 hydrolase inhibitor for the treatment of myocardial infarction and stroke. V. Sandanayaka, B. Mamat, P. Yu, L. Zhao, L Bedell, N. Bhagat, J. Winger, M. Keyvan, B. Bock, M. Krohn, P. Chandrasekar, X. Mo, L-M. Zhou, R. Mishra, E. Onua, J. Zhang, M. Porsteinsdottir, G. Halldorsdottir, H. Sigporsdottir, M. Friedman, D. Zembower, P. Andresson, J. Singh, M. Gurney 2:50 237. Discovery of peliglitazar, a potent oxybenzylglycine dual PPARa/7 activator with efficacious glucose and lipid-lowering activities. S. Chen, F. Qu, P. Devasthale, Z. Lai, C. Shao, W. Wang, S. Wu, H. Zhang, D. Farrelly, L. Moore, L. Gu, W. Sun, N. Flynn, T. Harrity, M. Cap, L. Kunselman, A. Peters, K. Locke, J. Lippy, L. Zhang, G. Chandrasena, V. Hosagrahara, P. Kadiyala, J. Muckelbauer, C. Chen, Y. An, A. Doweyko, D. Ryono, S. A. Biller, J. Wetterau, N. Hariharan, P. T. W. Cheng 3:10 238. Discovery of HCV-796: A potent and orally bioavailable hepatitis-C poly merase inhibitor under clinical develop ment. A. K. Saha, C. Young, A. M. Del Vecchio, T. A. Bailey, J. A. Reinhardt, B. A. Kulkami, T. H. Faitg, H. Feng, S. R. Rippin, C. W. Blackledge, D. J. Rys, T. A. Lessen, J. Swestock, Y. Deng, T. J. Nitz, S. Chunduru, R. Chopra, M. Collett, D. Pevear, A. Y. M. Howe, J. O'Connell, T. Mansour, C. J. Burns 3:30 239. Discovery and SAR of ABT-888, an inhibitor of poly(ADP-ribose) polymer ase (PARP) for the treatment of cancer. G-D. Zhu, J. Gong, V. B. Gandhi, Y. Luo, X. Liu, Y. Shi, V. Klinghofer, E. F. Johnson, D. Frost, C. Donawho, L. Rodriguez, G. Bukofzer, K. Jarvis, J. Bouska, A. Olson, K. C. Marsh, C. Park, S. Rosenberg, V. L. Giranda, T. D. Penning 3:50 240. SAR of 3-(6-(piperidin-4-yl)-1 Hbenzo[d]imidazol-2-yl)pyridin-2(1H)-ones as inhibitors of the insulin-like growth factor-1-receptor (IGF-1R) with broad spectrum in vivo activity. U. Velaparthi, M. D. Wittman, P. Liu, M. G. Saulnier, K. Zimmermann, J. Carboni, F. Y. Lee, Z. Yang, D. B. Frennesson, X. Sang, L. Aixin, P. Balimane, D. R. Langley, R. Attar, M. Gottardis, D. M. Vyas
4:10 241. Discovery of trisubstituted cyclohexanes as a new class of CCR2 antago nists. R. J. Cherney, R. Mo, D. T. Meyer, D. J. Nelson, Y. C. Lo, G. Yang, P. A. Scherle, S. Mandlekar, Z. R. Wasserman, H. Jezak, K. A. Solomon, A. J. Tebben, P. H. Carter, C. P. Decicco 4:30 242. Neohexyl derivatives of B-ring alkylaminobenzothiadiazine inhibitors of HCV NS5B polymerase. J. T. Randolph, P. P. Huang, D. K. Hutchinson, L L. Klein, D. A. Montgomery, S. V. Masse, W. M. Kati, D. Beno, D. J. Kempf
Advanced Mining and Use of Life Science Information Sponsored by CINF, Cosponsored with CSA Trust, BIOT, BTEC, MEDI, and COMP WEDNESDAY AFTERNOON Section A McCormick Place Lakeside Room E353 A/B, Level 3
Section A
ACS Award for Team Innovation: New Approaches to Confront Antibacterial Resistance Symposium in Honor of Steven J. Brickner, Michael R. Barbachyn, Douglas K. Hutchinson, and Peter R. Manninen
McCormick Place Lakeside Room E353 A/B, Level 3
S. F. Singleton and B. S. J . Blagg, Organizers, Presiding
Ε. Β. Hershberg Award for Important Discoveries in Medicinally Active Products: Estrogen Receptor Beta Symposium in Honor of John A. Katzenellenbogen Cosponsored with Eli Lilly
1:30 253. Evolution and inhibition of antibi otic resistance. F. Romesberg 2:10 254. Small molecule inhibitors of bacte rial MarA (AraC) transcriptional factors which prevent bacterial infection. O. K. Kim, L. K. Garrity-Ryan, J. C. Mecsas, S. B. Levy 2:50 255. Bacterial efflux pumps: Implica tions in antibiotic discovery and develop ment of novel inhibitors as potentiators of existing antimicrobial agents. M. N. Dudley, O. Lomovskaya 3:30 256. DNA repair, a novel target of antibiotics: Peptides and small molecules that bind Holliday junctions. A. M. Segall, J. L Boldt, G. D. Cassell, C. W. Gunderson, K. V. Kepple, I. Naili, N. Patel, N. Radosevich, L. Su 4:10 257. Award Address (ACS Award for Team Innovation, sponsored by Corpora tion Associates). Zyvox® (linezolid), the first member of a completely new class of antibacterial agents for treatment of seri ous gram-positive infections. S. J. Brickner, M. R. Barbachyn, D. K. Hutchinson, P. R. Manninen
WEDNESDAY MORNING
Β. Η. Norman, Organizer,
Presiding
9:00 Introductory Remarks. 9:10 243. Award Address (Ε. Β. Hershberg Award for Important Discoveries in Medici nally Active Products, sponsored by Schering-Plough Corporation). Estrogen receptors: Tools, travails, and triumphs in estrogen receptor biology, pharmacology and imaging. J. A. Katzenellenbogen 9:50 244. Structure-based design, synthesis, and evaluation of benzopyrans as selec tive estrogen receptor-beta agonists for the treatment of benign prostatic hyperpla sia. T. I. Richardson, J. Shah, B. H. Norman, J. S. Kroin, Ε. Μ. Thomas, J. A. Dodge, C. W. Lugar, S. A. Jones, L. A. Pfeifer, P. S. Borromeo, G. L. Durst, Y. Y. Wang, J. D. Durbin, C. Montrose-Rafizadeh, R. J. Barr, H. E. Osborne, R. M. Amos, K. Chen, V. Krishnan 10:25 245. Estrogen receptor-beta in the central nervous system. I. Merchenthaler 11:00 246. 8{beta}-Substituted estratrienes as ER{beta} selective ligands. O. Peters, N. Brâuer, P. Droescher, P. Muhn, K. Prelle, K-H. Fritzemeier 11:35 247. Design and synthesis of selective estrogen receptor β agonists as potential anti-inflammatory agents. R. E. Mewshaw, M. S. Malamas, A. T. Vu, E. Manas, S. M. Opal, J. C. Keith Jr., H. A. Harris Section Β McCormick Place Lakeside Room E353 C, Level 3 High Throughput Screening and Drug Discovery Cosponsored with CINF J. K. Padia, Organizer,
Presiding
9:00 248. Effective biological assay support for medicinal chemists. Y. Li 9:40 249. Use of BacMam transient expres sion technology to support HTS and profil ing of compounds targeting G proteincoupled receptors. Z. Wu 10:20 250. Discovery of novel inhibitors of methionine aminopeptidase by HTS. Q-Z. Ye 11:00 251. Application of a quantitative HTS approach for accelerating Hit-to-Lead process in discovery of glucocerebrosidase inhibitors. W. Zheng, J. K. Padia 11:40 252. Molecular profiles in drug discov ery: Using pathway signatures to identify inhibitors of the Beta-catenin and Aurora pathways. S. K. Horrigan
Section Β McCormick Place Lakeside Room E353 C, Level 3 Medicinal Chemistry of Ion Channels/Voltage-Gated Channels and Pain N. Tamayo and M. L. Brown, Presiding
1:30 258. Regulation of N-type calcium channels in the pain pathway. G. W. Zamponi 2:05 259. Ion channel assay technologies. O. McManus 2:40 260. Structural dynamics of voltagedependent ion channels. E. Perozo 3:15 261. Piperazine surrogates, a novel class of calcium channel blockers. H. Pajouhesh 3:50 262. Voltage-gated sodium channel blockers for the treatment of neuropathic pain. P. K. Chakravarty 4:25 263. Structure-activity relationships and in vivo profiles of amino acid ligands for the α2δ subunit of voltage-gated calcium channels. K. H. Mortell, D. J. Anderson, J. J. Lynch III, C-H. Lee, M. Gopalakrishnan W E D N E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center General Poster Session Cosponsored with Nature Reviews Drug Discovery D. P. Rotella,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizers,
Organizer
7:00-9:00 264. Design, synthesis, and evaluation of novel peptidomimetics. J. P. Cain, A. V. Mayorov, M. Cai, E. S. Palmer, B. Tan, K. B. Chandler, T. Yamamoto, P. Nair, S. Wallace, G. N. Ortiz, H. Wang, G. Santarelli, Y. S. Lee, R. R. Petrov, J. M. Ndungu, D. Trivedi, V. J. Hruby
265. Modeling study of the binding modes of mono- and dinucleotides at the human P2Y 2 receptor. A. A. Ivanov, K. A. Jacobson 266. How does dopamine transporter (DAT) reuptake dopamine: Insights from molecu lar modeling and molecular dynamics simulations. X. Huang, C-G. Zhan 267. Synthesis and evaluation of quinuclidine incorporated lobelane analogs as vesicular monoamine transporter ligand. G. Zheng, L. P. Dwoskin, A. G. Deaciuc, P. A. Crooks 268. Design and synthesis of lobelane ana logs targeting the vesicular monoamine transporter (VMAT2) as a potential treat ment for methamphetamine abuse. J. P. Culver, A. G. Deaciuc, L. P. Dwoskin, P. A. Crooks 269. Computational neural network analysis of the affinity of lobeline and tetrabenazine analogs for the vesicular monoamine transporter-2. F. Zheng, G. Zheng, A. G. Deaciuc, C-G. Zhan, L. P. Dwoskin, P. A. Crooks 270. Synthesis and biological activity of meperidine analogs as selective serotonin reuptake inhibitors. X. Gu, S. Izenwasser, M. L. Trudell 271. Synthesis and biological evaluation of 3-aryl-3-arylmethoxytropane derivatives at monoamine transporters. H. Kaur, S. Izenwasser, M. L. Trudell 272. Synthesis and biological activity at mono amine transporters of 3-[2-(diarylmethoxyethylidenyl)]-N-substituted tropane and azetidine analogs. S. A. Cararas, S. Izenwasser, M. L. Trudell 273. Structure activity relationship study of cis-(6-benzhydryl-piperidin-3-yl)-benzylamine and its constrained counterpart 1,4-diazabicyclo[3.3.1]nonane derivatives: Study on influence of exocyclic hydroxyl function on affinity for monoamine trans porters. M. Mishra, R. Kolhatkar, J. Zhen, M. Reith, A. Dutta 274. Synthesis and SAR evaluation of lactamfused chroman derivatives having dual affinity at serotonin 5-HT1A receptor and serotonin transporter. Z. Shen, N. T. Hatzenbuhler, D. A. Evrard, M. Chlenov, Β. L. Harrison, R. L. Magolda, M. Abou-Gharbia, G. Hornby, D. L. Smith, K. M. Sullivan, L. E. Schechter, T. H. Andrée, P. S. Ramamoorthy 275. Exploring the structural requirements for potency and selectivity exhibited by novel asymmetric tetrahydropyran inhibitors of SERT and NET using 3-D QSAR CoMFA method. P. S. Kharkar, M. Reith, A. Dutta 276. Novel concept of chromatography applied to screen the interaction between drugs and monoamine oxidase. P. Ma, S. Wang, F. Qu, Y. Deng 277. A new discovery platform for novel CNS therapeutics with potential to alter disease progression. H. A. Behanna, S. M. Roy, L Munoz, W. Hu, L. K. Wing, H. Ralay Ranaivo, L. Guo, L. Van Eldik, D. M. Watterson 278. Synthesis of heterocycle-based selective inhibitors of neuronal nitric oxide synthase with improved pharmacokinetic properties. G. R. Lawton, H. Ji, R. B. Silverman 279. Design and synthesis of propofol analogs as new anesthetic agents. I. M. Maciagiewicz, K. S. Bruzik, A. J. Hopfinger, A. Jenkins, N. Harrison 280. Sulfamides as new target for anconvulsant drugs: Design, synthesis and evaluation. L Gavernet, I. A. Barrios, J. E. Elvira, M. Sella Cravero, G. A. Samaja, V. Pastore, L. E. Bruno Blanch 281. Block of cyclic nucleotide-gated channels by tetracaine derivatives: Role of apolar interactions at two distinct locations. S. R. Kirk, T. Strassmaier, J. W. Karpen 282. Synthesis of cyclopropanated carbohydrates for employment as antiepileptic drugs. J. Talisman, C. H. Marzabadi 283. Modeling evolution of hydrogen bonding and stabilization of transition states in the process of cocaine hydrolysis catalyzed by human butyrylcholinesterase. D. Gao, C-G. Zhan 284. Synthesis and pharmacological evaluation of some quinoline derivatives as potential antiamnesic agents. P. Piplani, A. Rani, R. Sandhir, S. K. Kulkami
285. Synthesis of a carbon-11 labeled conformationally restricted rivastigmine analog for PET imaging of heart enzymes AChE and BChE. M. Wang, J-Q. Wang, M. Gao, Q-H. Zheng 286. Discovery of long acting inhaled muscarinic M3 receptor antagonists. U. Baettig, S. Collingwood, D. Janus, N. Devereux, E. Stanley, B. Cox, C. McCarthy, S. Charlton, J. Leighton-Davis, J. R. Fozard, F. Baur, D. Farr, L. Mazzoni, V. Patel 287. The effect of anesthetic molecule binding on neuronal nicotinic and GABA receptor model dynamics, gating mechanisms and open receptor states. R. J. Law, F. C. Lightstone 288. The mechanism of K+ ion pumping and double gating elucidated by simulations and mutagenesis experiments on the gastric Η,Κ-ATPase. R. J . Law, K. Munson, G. Sachs, F. C. Lightstone 289. Synthesis and initial evaluation of novel dipyridyl derivatives as potential radioli gands for imaging of the nicotinic acetyl choline receptors by positron-emission tomography (PET). Y. Gao, H. T. Ravert, D. P. Holt, J. Hilton, C. Endres, M. Alexander, A. Kumar, M. G. Pomper, A. Rahmim, H. Kuwabara, D. F. Wong, R. F. Dannals, A. G. Horti 290. Subtype-selective agonists binding with a4b2 and a7 nicotinic acetylcholine recep tors: From microscopic binding to phenomenological binding affinity. C-G. Zhan 291. PEG-ligand analogs for nicotinic acetyl choline receptors. B. A. Scates, N. J. Theising, T. G. Baker, B. C. Chastain, K. Tominaga, B. T. Elliott, R. W. Fitch 292. Development of the first predictive phar macophore models for sigma-1 and sigma-2 receptor antagonists. N. Singh, C. Mesangeau, S. Narayanan, J. Shaikh, R. R. Matsumoto, C. R. McCurdy 293. Preparation of piperazine derivatives as 5-HT7 receptor active agents. H-Y. P. Choo, A. N. Pae, H. Rhim, E. Yoo 294. Identification of enantiomerically pure 5-HTe receptor antagonists by chiral reso lution. C. M. Park, S. Kang, W. Park, N. Park, C. Seong 295. frans-2,3-Dihydroxy-6a,7,8,12b-tetrahydro-6H-chromeno[3,4-c]isoquinoline: A novel β-phenyl-dopamine template for D-| receptor activation. J. P. Cueva, B. R. Chemel, D. E. Nichols, V. J. Watts 296. Further structure activity relationship (SAR) study of novel hybrid 7-{[2-(4Phenyl-piperazin-1-yl)-ethyl]-propyl-amino}5,6,7,8-tetrahydro-naphthalen-2-ol analogs focusing on modification of the N-aromatic moiety: Development of a highly potent and selective lead molecule for the D3 dopamine receptor. B. Ghosh, J. Zhen, M. Reith, A. Dutta 297. Design, structure activity relationships and biological evaluation of novel D3 receptor preferring agonists: A potential neuroprotective treatment for Parkinson's disease. S. Biswas, S. Zhang, F. Fernandez, J. Zhen, M. Reith, A. Dutta 298. Optimization of a hit molecule derived from virtual high throughput screening for metabotropic glutamate receptor (group III) agonist activity. C. Selvam, N. Oueslati, I. Brabet, C. Goudet, N. Triballeau, H-O. Bertrand, J-P. Pin, F. Acher 299. Synthesis of subtype selective ligands for alpha 5-containing GABAA/Bz receptors to treat memory deficits. T. Clayton 300. Development of cyclopropylcarboxamide bradykinin B1 receptor antagonists with modified biphenyl motifs. R. K. Chang, C. N. Di Marco, K. L. Murphy, R. W. Ransom, D. R. Reiss, C. Tang, T. Prueksaritanont, D. J. Pettibone, M. G. Bock, S. D. Kuduk 301. 2-Aminobenzophenones as a novel class of BK-1 antagonists. D-S. Su 302. Design and synthesis of stereoenantiomeric benzodiazepine receptor ligands. S. Huang, M. Savic, R. Furtmuller, A. Duke, T. Clayton, W. Sieghart, J. K. Rowlett, J. M. Cook 303. Computational approaches to the predic tion of blood-brain barrier permeability: Comparative analysis of CNS drugs vs. the secretase inhibitors for Alzheimer's disease. G. M. Rishton, K. LaBonte, A. J. Williams, K. Kassam, E. Kolovanov
TECHNICAL PROGRAM
MEDI 304. New aids for molecular chaperones in combating β-amyloid formation. J. E. Gestwicki, A. J. Turbiak 305. CNI-1493 inhibits A3 production and prevents plaque formation in an animal model of Alzheimet's disease. Y. Al-Abed, R. Dodel, B. Aljabari, K. Keyvani, P. Marambaud, R. Kayed, R. Glabe, N. Goertz, S. Schnell, M. Bâcher 306. Synthesis of small molecule gammasecretase inhibitors for Alzheimer's disease. J. Pu, L Resnick, S. Aschmies, K. Atchison, J. Berkowitz, T. J. Caggiano, M. Chlenov, G. Diamantidis, B. Harrison, Y. Hu, D. Huryn, J. S. Jacobsen, M. Jin, A. Kreft, P. Lu, R. Martone, K. M. Morris, J. Sonnenberg-Reines, D. Riddell, J. E. Sabalski, S-C. Sun, E. Wagner, E. Wang, Z. Xu, H. Zhou 307. Hit-to-lead optimization of aminohydantoins as b-Secretase inhibitors. P. Nowak, A. Aulabaugh, J. Chen, D. C. Cole, R. Chopra, R. Cowling, M. Dar, J. W. Ellingboe, K. Y. Fan, B. Hu, S. Jacobsen, M. Jani, G. Jin, M-C. Lo, M. S. Malamas, E. S. Manas, R. Narasimhan, A. Robichaud, C. Sabus, J. R. Stock, M. Tischler, J. Turner, E. Wagner, P. Zhou, J. Bard 308. Carbocyclic substituted aminohydantoins as BACE1 inhibitors. J. Erdei, I. Gunawan, M. S. Malamas, P. Novak, J. Turner, A. J. Robichaud, J. Bard, Y. Hu, E. Wagner, L. Di, K. Fan, R. Chopra, A. Oganesian, C. Huselton 309. Piperidinyl-2-aminohydantoin derivatives for the inhibition of beta-secretase. Y. Yan, P. Zhou, M. S. Malamas, Y. Li, S. Aschmies, J. Bard, R. C. Bemotas, R. Chopra, T. Comery, K. Y. Fan, Y. Hu, A. Oganesian, J. Turner, E. Wagner, Z. Wang, P. Reinhart, A. J. Robichaud 310. Fragment based lead generation approaches for inhibitors of beta-secretase: Development of a novel series of dihydroisocytosine-based inhibitors. J. S. Albert, P. D. Edwards, D. Andisik, J. B. Campbell, R. Carr, G. Chessari, M. S. Congreve, G. M. Koether, R. C. Mauger, C. W. Murray, S. Patel, M. A. Sylvester 311. Fragment based lead generation approaches for inhibitors of beta-secretase: Development of a novel series of isocytosine-based inhibitors. J. S. Albert, P. D. Edwards, D. Andisik, J. B. Campbell, M. S. Congreve, R. Carr, G. Chessari, F. Edfeldt, R. H. Folmer, G. M. Koether, K. Kolmodin, C. W. Murray, L-L. Olsson, S. Patel, T. DeBeer 312. Synthesis of afunctional small molecules for imaging β-amyloid aggregation. A. H. Negussie, A. O. Akinola, S. Fung, K. C. Li, N. S. Danthi 313. Substituted biaryl imidazoles, oxazoles and thiazoles as sodium channel blockers. S. Tyagarajan, B. Zhou, W. H. Parsons, M. H. Fisher, M. J. Wyvratt, K. A. Lyons, T. Klatt, X. Li, S. Kumar, B. Williams, J. Felix, B. T. Priest, R. M. Brochu, V. Warren, M. S. Smith, M. Garcia, G. J. Kaczorowski, W. J. Martin, C. Abbadie, E. McGowan, N. Jochnowitz, P. K. Chakravarty 314. Substituted biaryl pyrazoles as sodium channel blockers. S. Tyagarajan, B. Zhou, B. Taylor, W. H. Parsons, M. H. Fisher, M. J. Wyvratt, K. A. Lyons, T. Klatt, X. Li, S. Kumar, B. Williams, J. Felix, Β. Τ. Priest, R. M. Brochu, V. Warren, M. Smith, M. Garcia, G. J. Kaczorowski, W. J. Martin, C. Abbadie, E. McGowan, N. Jochnowitz, P. K. Chakravarty 315. Synthesis of antagonists of acid sensing ion channels. Z. Liu, J. D. Rainier, R. W. Hughen, A. R. Light 316. Discovery and SAR of furan piperazines as sodium channel blockers for the treat ment of neuropathic pain. I. Drizin, R. J. Gregg, M. J. C. Scanio, L Shi, M. F. Gross, R. N. Atkinson, J. B. Thomas, M. S. Johnson, W. A. Carroll, B. E. Marron, M. L. Chapman, D. Liu, M. J. Krambis, C-C. Shieh, X. Zhang, G. Hernandez, D. M. Gauvin, J. P. Mikusa, C. Z. Zhu, S. Joshi, P. Honore, K. C. Marsh, R. Roeloffs, S. Werness, D. S. Krafte, M. F. Jarvis, C. R. Faltynek, M. E. Kort
88-TECH
317. Discovery and biological evaluation of 5-aryl-2-furfuramides, potent and selective blockers of the Na v 1.8 sodium channel with efficacy in models of neuropathic pain. M. E. Kort, I. Drizin, R. J. Gregg, M. J. C. Scanio, L. Shi, M. F. Gross, R. N. Atkinson, M. S. Johnson, G. F. Pacofsky, M. E. Secrest, J. B. Thomas, W. A. Carroll, B. E. Marron, M. L. Chapman, M. J. Krambis, D. Liu, C-C. Shieh, X. Zhang, G. Hernandez, J. P. Mikusa, C. Zhong, S. Joshi, P. Honore, R. Roeloffs, K. C. Marsh, B. P. Murray, J. Liu, S. Werness, C. R. Faltynek, D. S. Krafte, M. F. Jarvis 318. Improved synthesis of penciclovir. Y. Deng, N. He, S. LI 319. SAR development of potent, selective pyridine-based blockers of the Nav1.8 (PN3) sodium channel. B. E. Marron, R. N. Atkinson, J. B. Thomas, M. S. Johnson, G. J. Pacofsky, M. E. Secrest, L. Shi, M. E. Kort, I. Drizin, M. J. C. Scanio, R. J. Gregg, M. A. Matulenko, M. L Chapman, D. Liu, M. J. Krambis, X. Su, C-C. Shieh, X. Zhang, G. Hernandez, S. Joshi, P. Honore, K. C. Marsh, A. Knox, R. Roeloffs, S. Werness, M. F. Jarvis, C. R. Faltynek, D. S. Krafte 320. The discovery of potent, selective pyri dine-based blockers of the Nav1.8 (PN3) sodium channel. R. N. Atkinson, J. B. Thomas, M. S. Johnson, G. J. Pacofsky, M. E. Secrest, L. Shi, M. E. Kort, I. Drizin, R. J. Gregg, M. A. Matulenko, M. L Chapman, D. Liu, M. J. Krambis, X. Su, C-C. Shieh, X. Zhang, G. Hernandez, S. Joshi, P. Honore, K. C. Marsh, A. Knox, R. Roeloffs, S. Werness, D. S. Krafte, M. F. Jarvis, C. R. Faltynek, Β. Ε. Marron 321. Potent, selective pyrazine-based block ers of the Na v 1.8 (PN3) sodium channel. M. J. C. Scanio, L Shi, M. E. Kort, I. Drizin, R. J. Gregg, J. B. Thomas, R. N. Atkinson, M. S. Johnson, B. E. Marron, M. L. Chapman, D. Liu, M. J. Krambis, X. Su, C-C. Shieh, X. Zhang, G. Hernandez, S. Joshi, P. Honore, K. C. Marsh, A. Knox, S. Werness, D. S. Krafte, M. F. Jarvis, C. R. Faltynek 322. Development of imidazopyridine Nav1 blockers for the treatment of neuropathic pain. S. Β. Hoyt, C. London, D. J. Gorin, W. H. Parsons, A. E. Weber, C. Abbadie, R. M. Brochu, J. P. Felix, M. L Garcia, N. Jochnowitz, B. V. Karanam, S. Kumar, K. A. Lyons, X. Li, D. E. Maclntyre, E. McGowan, W. J. Martin, Β. Τ. Priest, M. M. Smith, V. A. Warren, B. S. Williams, G. J. Kaczorowski, J. L. Duffy 323. Polycyclic amine derivatives: The synthe sis of triquinylamines as calcium modula tors. L-M. Bezuidenhout, W. Liebenberg, S. F. Malan, C. J. Van der Schyf 324. Synthesis and SAR of heterocyclic KCNQ2 potassium channel modulators based on the 1,4-diaminobenzene tem plate. A. Ritzén, D. R. Grève, N. A. Khanzhin, M. B. Norgaard, M. Rottlânder, T. B. Stensb0l, L. Tagmose, C. W. Tornoe, W. P. Watson 325. Synthesis and SAR of trisubstituted anilines as novel KCNQ2 potassium channel modulators. C. W. Tornoe, D. R. Grève, N. A. Khanzhin, M. B. Norgaard, A. Ritzén, M. Rottlânder, T. B. Stensb0l, L. Tagmose, W. P. Watson 326. Synthesis and SAR of indolines as potent conformationally restricted KCNQ2 potassium channel openers. Ν. Α. Khanzhin, D. R. Grève, M. B. Norgaard, A. Ritzén, M. Rottlânder, T. B. Stensb0l, L. Tagmose, C. W. Tornoe, W. P. Watson 327. Synthesis and evaluation of new cathepsin D inhibitors containing substituted hydroxyethyl piperazine isosteres. P. Velusamy, D. Driver, W. E. Godwin, R. M. McConnell 328. Full length zinc selective inhibitors of matrix metalloproteinase. F. E. Jacobsen, C. A. F. de Oliveira, J. A. McCammon, S. M. Cohen 329. Design and synthesis of tryptophan butynyloxy carboxylate derivatives as TACE inhibitors. K. Park, J. I. Levin, A. Aplasca, A. Gopalsamy, J. W. Ellingboe, Y. Zhang, L Sun, W. Xu
330. Synthesis and properties of cyclocystine subunits (CCS): Application to thioredoxin reductase and hepcidin. E. L. Ruggles, R. J. Hondal, P. B. Deker 331. Identification of a contiguous binding site in PKC-zeta and the binding of ruboxistaurin to PKC-alpha, -beta and -zeta. S. Tang, V. Xiao, C. I. Whiteside, L. P. Kotra 332. Interactions of β-lactam antibiotics with proteases. P. M. Tschische, K. Majumder, S. Tang, E. Poduch, P. Dixit, L. P. Kotra 333. Design of N-Heteroaryl or N-Heteroarylmethyl-3-alkyl substituted piperazines as scaffolds for a Rho-kinase inhibition. I-H. Paik, W. H. Brooks, S. M. Sebti, A. D. Hamilton 334. Development of selective inhibitors of protein tyrosine phosphatases using com binatorial fluorogenic peptide substrates. S. Mitra, A. M. Barrios 335. Synthetic approaches to amino acid cyclobutanone derivatives. P. Kataria, N. Armoush, D. Becker 336. Progress toward amino acid cyclobuta none derivatives as potential serine prote ase inhibitors via a ketene [2+2] cycloaddi tion strategy. M. R. Lutz Jr., P. Farid, A. Panagopoulos, D. Becker 337. Synthesis and evaluation of aeruginosin analogs as serine protease inhibitors. G. Wang, X. Nie, B. Hopkinson, S. Cheuk 338. Peptide libraries containing Phe analogsreversible inhibitors of thrombin and potent inhibitors of platelets aggregation. C. Clement, A. Babinska, J. Gonzalez, M. Philipp 339. Synthesis and SAR study of 1 H-pyrrole2,5-dione and furan-2,5-dione derivatives as novel COX-2 inhibitors. J. T. Moon, J. H. Heo, J. Y. Jeon, J-Y. Kim, K-T. Lee, J. Y. Lee, D. J. Choo 340. Benzoxazole and pyridinothiazoles as 5-lipoxygenase inhibitors. H-Y. P. Choo, S-R. Oh, H-K. Lee, K. Ann, G. Han, J-H. Kim 341. Synthesis and SAR of pyrrolidine and piperidine aryl ethers as novel leukotriene A4 hydrolase inhibitors. M. Keyvan, V. Sandanayaka, B. Mamat, J. Winger, M. Krohn, G. Halldorsdottir, H. Sigporsdottir, D. Zembower, P. Andresson, J. Singh, M. Gurney 342. Discovery, synthesis, and SAR of novel arylpiperazine derivatives as leukotriene A4 hydrolase inhibitors. L-M. Zhou, V. Sandanayaka, B. Mamat, R. Mishra, G. Halldorsdottir, H. Sigporsdottir, D. Zembower, P. Andresson, J. Singh, M. Gurney 343. Discovery of novel pyrrolidine derivatives as potent leukotriene A4 hydrolase inhibi tors. P. Yu, V. Sandanayaka, L. Zhao, B. Mamat, R. Mishra, G. Halldorsdottir, H. Sigporsdottir, D. Zembower, P. Andresson, J. Singh, M. Gurney 344. Preparation of non-urea inhibitors of soluble epoxide hydrolase. A. S. Kumar, D. Chen, Z. N. Do, H. K. Webb, R. D. Gless 345. Synthesis and evaluation of conforma tionally restricted soluble epoxide hydro lase (sEH) inhibitors. S. H. Hwang, H-J. Tsai, C. Morisseau, Z. Do, B. D. Hammock 346. Preparation of sEH inhibitors with improved drug-like properties. P. A. Baecker, Z. N. Do, H. K. Webb, R. D. Gless, l-H. Kim, B. D. Hammock 347. Liposome mediated inhibition of carbonic anhydrase. J. A. Kooren, A. Elegbede, M. Haldar, S. Mallik, D. K. Srivastava 348. 3-D-QSAR and docking studies on 3-anilino-4-phenylmaleimides for glycogen synthase kinase-3a inhibition. P. Sivaprakasam, P. R. Daga, A. Xie, R. J. Doerksen
Please refrain from using cellular telephones and cameras during technical sessions.
349. Characterization of a catalytic ligand bridging metal ions in phosphodiesterases 4 and 5 by molecular dynamics simula tions and hybrid quantum mechanical/ molecular mechanical calculations. Y. Xiong, H-T. Lu, C-G. Zhan 350. Microscopic modes and free energies of 3-phosphoinositide-dependent kinase-1 (PDK1 ) binding with celecoxib and other inhibitors. M. D. M. AbdulHameed, A. Hamza, C-G. Zhan 351. Effect of trifluoroethanol on the structure and function of mesophilic and thermo philic chorismate mutases. E. Csuhai, P. Kast, D. Hilvert 352. Understanding the rate-determining step in the kinetic pathway of eubacterial tRNAguanine transglycosylase. S. M. Chervin, G. A. Garcia 353. Recognition of cognate tRNAs by the human tRNA-guanine transglycosylase. Y-C. Chen, G. A. Garcia 354. Regulation of human tRNA-guanine transglycosylase: Interactions of catalytic and regulatory subunits. K-H. Lee, G. A. Garcia 355. Modification of an mRNA involved in bacterial virulence by tRNA-guanine trans glycosylase. J. K. Cutcher, G. A. Garcia 356. Progress toward the development of synthetic transcriptional activators. R. J. Casey, B. B. Brennan, C. A. Bates, A. K. Mapp 357. Design, synthesis and biological activities of novel PPAR a/7 dual agonist as poten tial antidiabetics. Y-G. Suh, J-W. Jung, J. Jang, F-N. Li, S. J. Lee, N-J. Kim, B. W. Koo, K-O. Lee, M-K. Kim, J-K. Kim, J-l. Lim 358. Design, synthesis and biological evalua tion of novel PPARa/g dual agonist, lobeglitazone sulfate (CKD-501). S. K. Kang, H. W. Lee, S. K. Ahn, J. B. Ahn, D. J. Jeon, J. S. Shin, Y. M. Kwon, M. H. Ki 359. Novel pyrimidine-5-carboxylic acid as a potent and orally active PPAR7 partial agonist. S. Seto, K. Okada, K. Kiyota 360. Synthesis and LXR activity of 4-(3(phenylethynyl)phenyl quinolines. J. W. Ullrich, R. L Morris, P. Nambi, E. Quinet, L Chen, A. Halpern, Q-Y. Liu, D. Savio, M. Basso, R. Unwalla, A. Wilhelmsson, A. Goos Nilsson, C. Ursu, E. Arnelof, J. Sandberg, C. Enroth, J. Wrobel 361. Carboxylic acid based quinolines as liver χ receptor (LXR) modulators. B. Hu, M. Collini, J. Jetter, R. Unwalla, E. Quinet, D. Savio, A. Halpern, I. Feingold, A. Goos-Nilsson, A. Wilhelmsson, P. Nambi, J. Wrobel 362. Selective silyl ether protection of hydroxyls in 3,11B,173-estriols: A new approach to 11 β-methoxyestrogens. M. G. C. Kahn, R. M. Hoyte 363. Identification of peptides that bind to estrogen response elements: Using pep tide phage display library. M. Eshete, Z. Ndegwa 364. Withdrawn. 365. Estrogen receptor (ER) ligands that recruit FK506 binding proteins: A novel mechanism of ER antagonism? T. W. Moore, J. R. Gunther, J. A. Katzenellenbogen 366. Pyrimidine core small molecule inhibitors of estrogen and androgen receptor-coactivator binding. A. A. Parent, J. R. Gunther, J. P. Amin, J. A. Katzenellenbogen 367. Bioactive compounds with unusual elemental composition: Boron-nitrogen estrogen receptor ligands, structural fea tures of partial agonists. H-B. Zhou, K. W. Nettles, K. E. Carlson, F. Stossi, G. L. Greene, J. A. Katzenellenbogen 368. Synthesis of a selective proteolysis inducer (PROTAC): Chemically knocking out estrogen receptor function. M. K. Mann, J. A. Katzenellenbogen 369. Dual interaction assay receptor-corepressor/receptor-coactivator binding. M. Jeyakumar, P. Webb, T. S. Scanlan, J. A. Katzenellenbogen 370. Applying computational tools in drug discovery: Oxidative susceptibility and estrogen receptor interactions of arzoxifene analogs. I. Kastrati, Z. Qin, P. A. Petukhov, J. L. Bolton, G. R. J. Thatcher
MEDI 371. Improved synthetic technology of chlorodehydromethyltestosterone. Y. Deng, S. Li, N. He 372. Withdrawn. 373. Synthesis and evaluation of 17-alphaheteroarylvinyl estradiols as ligands for the estrogen receptor ligand binding domain (ER-LBD). S. Olmsted, R. N. Hanson, P. Tongcharoensirikul, E. McCaskill, R. B. Hochberg, D. C. Labaree 374. Quantitation of estrogens in male plasma using liquid chromatography with an electrochemical detector. A. Kallmerten, B. Rowland, M. Pomerantz, W. Oh, J. Glick 375. 3-(2,4-Dimethyl-9H-pyrido[2,3-b]indol-3yl)propanoic acid derivatives as potent and bioavailable microsomal triglyceride transfer protein(MTP) inhibitors with reduced cytochrome P450 3A4(CYP3A4) inhibitory activity. A. Suga, H. Kubota, M. Miura, N. Imanishi, D. Sasuga, H. Moritani, S. Naganuma, C. Kitada, M. Furutani, S. Sakamoto, S-l. Tsukamoto 376. Novel 4-phenyl-1,8-naphthyridin-2(1H)on-3-yl ureas: Synthesis and inhibitory activity against acyl-CoA:cholesterol acyltransferase. H. Ban, M. Muraoka, S. Ohnuma, K. loriya, N. Ohashi 377. Synthesis and SAR of aryl and heteroaryl 11B-HSD-1 inhibitors. H.Wang, J. Li, L Simpkins, J. Sutton, S. Wu, R. Smirk, D. Yoon, Z. Ruan, C. Cooper, K. V. Kirk, R. Hutchins, Y-X. Li, Z. Ma, R. Seethala, R. Golla, A. Nayeem, S. Krystek, D. Gordon, J. A. Robl, L. Hamann 378. Discovery of orally active butyrolactam 11b-HSD1 inhibitors for the treatment of metabolic syndrome. V. S. C. Yeh, R. Kurukulasuriya, D. Madar, F. A. Kerdesky, J. J. Rohde, M. Pliushchev, S. Fung, K. Monzon, W. J. Chiou, J. Wang, D. Stolarik, H. Imade, D. W. A. Beno, R. Shapiro, V. Knourek-Segel, Ε. Ν. Bush, D. M. Wilcox, P. Nguyen, M. Brune, P. B. Jacobson, J. T. Link 379. Structure-activity relationship study of stearoyl Co-Α desaturase-1 (SCD1) inhibi tors with privileged phenoxypiperidines. B. Liu, V. S. C. Yeh, J. Lynch, J. Freeman, Z. Xin, T. S. Suhar, N. Cao, H. T. Smith, H. S. Camp, C. A. Collins, H. L Sham, G.Liu 380. Withdrawn. 381. Novel urea-based stearoyl-CoA desaturase 1 inhibitors: Design, synthesis, and biological evaluation. Z. Xin, H. Zhao, M. D. Serby, B. Liu, M. Liu, B. G. Szczepankiewicz, L. T. Nelson, H. T. Smith, T. S. Suhar, N. Cao, T. K. Surowy, D. M. Wilcox, P. Nguyen, M. Voorbach, K. Landschulz, H. S. Camp, C. A. Collins, H. L Sham, G. Liu 382. Discovery of potent stearoyl-CoA desaturase 1 (SCD1) inhibitors via scaffold hop ping. H. Zhao, M. D. Serby, H. T. Smith, N. Cao, T. S. Suhar, T. K. Surowy, H. S. Camp, C. A. Collins, H. L Sham, G.Liu 383. Discovery of phenoxypiperidines as novel stearoyl-CoA desaturase inhibitors: From assay validation to lead develop ment. J. C. Freeman, J. K. Lynch, R. R. Iyengar, H. T. Smith, T. S. Suhar, L. E. Chovan, H. Xu, T. K. Surowy, C. A. Collins, P. R. Kym
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
384. Design and biological evaluation of small molecule ligands for the melanocortin-4 receptor: In vivo characterization of potent, selective MC4R agonists. R. T. Backer, K. Briner, M. P. Clay, I. Collado, L. S. Craft, P. J. Emmerson, M. J. Fisher, M. L. Heiman, J. L Hertel, S. Husain, S. L. Kuklish, T. D. Lindstrom, A. I. Mateo, J. T. Mullaney, T. P. O'Brien, P. L. Ornstein, T. I. Richardson, J. A. Shah, T. M. Williams, J. M. Zgombick 385. First pharmacophore and 3-D QSAR model for selective 5-hydroxytryptamine2C (5-HT2C) receptor agonists. T. Ramasamy, P. A. Petukhov 386. Synthesis and SAR of heteroaryl-fused piperidines as novel cannabinoid-1 recep tor antagonists. C. Sun, Y. Huang, R. Sulsky, Y. Zhu, L Kang, Y. Yang, R. A. Baska, M. J. Cullen, W. Keim, M. A. Pelleymounter, P. Stetsko, 0 . Gudmunsson, S. Johnghar, S. Wu, K. Behnia, K. E. Carlson, W. R. Ewing 387. Design and synthesis of 2,5-substituted pyridines as novel anticoagulant factor Xa inhibitors. Y-L. Li, K. A. Rossi, J. M. Luettgen, R. M. Knabb, R. R. Wexler, P. Y. S. Lam 388. Highly potent and selective Factor Xa inhibitors containing alpha-substituted arylcycloalkyl P4 residues: SAR studies of C3 substitution and the aryl binding site. J. X. Qiao, S. R. King, P. C. Wong, K. He, A. R. Rendina, J. M. Luettgen, R. M. Knabb, R. R. Wexler, P. Y. S. Lam 389. Novel sulfonylaminopiperidone deriva tives as potent coagulation factor Xa inhibitors. W. Han, Z. Hu, A. Rendina, J. Luettgen, K. He, P. C. Wong, R. M. Knabb, R. R. Wexler, P. Y. S. Lam 390. Chemical modification of heparin with deoxycholic acid for improvement of oral bioavailability. Y-K. Lee, O. M. Kwon, H. T. Moon, Y. Byun 391. Heparinoid-active sulfated polysaccha rides from marine green algae. W. Mao, H.Sun 392. VLA1 integrin inhibitors: Diaminopropionic acid derivatives. A. A. Thomas, R. Xu, S. C. Miller, S. A. Boyd, K. Condroski, I. Gunawardana, G. Zhang, M. L. Lupher Jr., F. Farouz, I. Jacobson, D. S. Staunton, E. D. Thorsett 393. VLA1 integrin inhibitors: Aminopiperidine amides. A. A. Thomas, S. C. Miller, S. A. Boyd, K. Condroski, J. De Meese, 1. Gunawardana, R. Xu, G. Zhang, M. L. Lupher Jr., F. S. Farouz, I. Jacobson, D. S. Staunton, E. D. Thorsett 394. Acrylamide amido acid derivatives as potent and selective VLA-1 antagonists: Optimization of the amido acid region. R. Xu, I. Gunawardana, Y. Le Huerou, S. C. Miller, S. A. Boyd, K. Condroski, J. De Meese, A. A. Thomas, G. Zhang, M. L Lupher Jr., L Sui, F. Farouz, I. C. Jacobson, D. S. Staunton, E. D. Thorsett 395. Discovery of potent and selective VLA-1 antagonists for the treatment of inflamma tory diseases: Modifications of B-ring portion of hit compound A-328282.0. I. Gunawardana, M. Yanik, R. Xu, S. C. Miller, S. Boyd, K. Condroski, M. L Lupher Jr., L. Sui, I. C. Jacobson, D. S. Staunton, E. D. Thorsett 396. Synthesis and structure-activity relation ship of novel phenylalanine derivatives as potent VLA-4 integrin antagonists. T. Okuzumi, S. Makino, K. Sagi, A. Chiba, Y. Satake, N. Suzuki, H. Izawa, T. Yoshimura, M. Murata, E. Nakanishi, T. Tsuji 397. Withdrawn. 398. Selective β 3 adrenergic receptor ago nists with reduced rat atrial tachycardia. F. C. Stevens, D. B. Bennett, W. E. Bloomquist, M. L. Cohen, C. A. Droste, M. L. Heiman, A. V. Kriauciunas, D. J. Sail, F. C. Tinsley, C. D.Jesudason 399. A new flavone 5-O-diglycoside from the leaves of Cephalotaxus sinensis (Rehd et Wile) Li. W. Li, R. Dai, Y. Yu, L. Li, Y. Deng 400. A novel C- glycoside favanoid from leaves of Belamcanda chinensis. L Li, Y. Yu, R. Dai, W. Li, W. Meng, Y. Deng
401. GLUT-4 translocation facilitating activity of flavonoids from Cephalotaxus sinensis on mice adipocytes. W. Li, Y. Deng, R. Dai, Y. Yu, L Li 402. Fluorescence-based probe for the detec tion of hydroxyl radicals produced by {gamma}-rays and Na 1 2 5 l in aqueous solution. A. Singh, S. J. Adelstein, A. I. Kassis 403. High-boiling solvents and morphology of crystals. C. Acquah, L. E. Achenie, A. T. Karunanithi, S. Sithambaram, S. L Suib 404. In-silico fragment-based pharmacophore design and lead optimization. S. Toba, K. Poptodorov, J. Sutter, A. J. Maynard, C. Keolmel 405. Amino acid esters of 3-(hydroxymethyl)phenyl guanidine: Affinity to PEPT 1 transporter. J . Sun, G. L. Amidon 406. Novel synthesis of 4-carboxy-4-pyridylpiperidines. Y. Wang, R. Nair 407. Predictive model of the inhibition of CYP3A4 by selected natural compounds. S. Thotakura, J. A. Darsey, K. Wang, J. T. Amason, C. M. Compadre 408. Synthesis of fluorinated dihydropyrazolopyrimidine derivatives as potential biologi cally active compounds. 0 . 0 . Fadeyi, K. Wash, C. O. Okoro 409. Synthesis of some alkenol and alkynol analogs of 1-octen-3-ol and investigation of their mosquito attractant properties. S. M. Farah, C. Ikediobi, L. M. Latinwo, L. Ayuk-Takem, J. Cilek, 0 . Okungbowa 410. Synthetic small molecule ligands for bulged RNA secondary structure. S. T. Meyer, P. J. Hergenrother 411. Structural characterization of unknown impurities in muraglitazar using LC/MS/MS and advanced NMR techniques. Q. Ye, Y. Huang, A. Rusowicz, T. Raglione, V. Palaniswamy 412. Benzindene prostacyclin prodrugs: Syn thesis, characterization and biological activity. R. M. Moriarty, A. Hirtopeanu, I. Dragutan, R. Naithani, K. Gao, K. R. Phares 413. Tackling barbiturates: Making a Phénobarbital chemiluminescent tracer. B. M. Bax, Z. Lin, Y. Pan, R. E. Reddy, B. T. Merchant, R. J. Himmelsbach 414. Designed synthetic spirocyclic helical compounds as binding agents for bulged DNA and RNA microenvironments. D. Ma, Y. Lin, G. B. Jones, N. Zhang, Z. Xiao, I. H. Goldberg 415. Enantioselective synthesis and biological evaluation of stereoisomers of 1-octen-3-ol and its analogs. A. 0 . Adesunloro, C. Ikediobi, L. M. Latinwo, L. Ayuk-Takem, J. Cilek 416. Synthesis and evaluation of functionalized carboranes as potential anticancer agents. A. V. Reddy, P. V. K. Reddy, S. C. Jonnalagadda, V. R. Mereddy 417. Extraction and fractionation of polyphenols from Chinese medicinal plant torreya grandis and their antioxidant activity against ferric reducing ability, DPPH and reducing power activity. M. K. Saeed IV, Y. Deng, R-J. Dai 418. Feigrisolide C: Structural revision and synthesis. J. H. Jung 419. FVP of steroid oxalate dimers for synthesis of androst-16-enes. A. B. Turner, L. Nahar 420. Genomic screening of Juzen-Taiho-to. T. H. Hasson, A. Kawamura 421. Improved synthesis of 1-0-acetyl-2,3,5tri-O-benzoyl-beta-D-ribofuranosefrom inosine. Y. Deng, D. Tao, N. He, S. Li 422. Interactions among the polymer components of cartilage matrix. F. Horkay, D. C. Lin, E. K. Dimitriadis, I. Horkayne-Szakaly, P. J. Basser 423. New synthetic methodology for the formation of quaternary carbon centers: A concise, microwave-assisted synthesis of cuparene in zeolite HY. T. Poon, L. Young 424. Novel inhibitors of cellular wound healing and cytokinesis. A. G. Clark, W. M. Bernent 425. Novel local drug delivery utilizing 1,8naphthalimide derivatives. P. D. Youso, R. E. Utecht 426. Predicting drug absorption from permeability measurements across a lipid-coated membrane using a diffusion cell and a UV spectrophotometer. A. Kraft, N. M. Howarth, H. N. Sheppard, H. Perston, J. Fouquet
427. Prodrugs of PROLI/NO, a nitric oxide donor. H. Chakrapani, J. E. Saavedra, B. M. Showalter, L. K. Keefer 428. Quantitative analysis and isolation of shikimic acid from Liquidambar styraciflua. T. Poon, L Enrich, A. Mohadjer 429. Rapid DMSO labeling for high yield radioiodinated pharmaceutical. K. Wang, S. J. Adelstein, A. I. Kassis 430. Screening of disulfide induced protein refolding intermediates by capillary isoelectric focusing. H. P. Gunawardena, J. Fredlin, K. van der Drift, K. Wee 431. Silica based metal scavengers for the purification of pharmaceutical active ingredients. F. Béland, A. Michaud, M. Morin 432. Structural basis for substrate flexibility and product diversity of cytochrome P450 PikC from Streptomyces venezuelae. S. Li, D. H. Sherman, L. M. Podust 433. Surface-functionalizable drug-conjugated polymer nanoparticles via ring-opening metathesis polymerization. D. Smith, P. J. Endres, K. W. Macrenaris, H. Cheng, S. M. Raja, T. R. Holden, P. A. Bertin, C. K-F. Shen, V. Band, H. Band, T. J. Meade, S. T. Nguyen 434. Synthesis of (Z)-2-acetamido-3- (1Hindol-3-yl) acrylic acid derivatives as tryptophan precursors from relatively inexpensive 2-nitrobenzaldehydes and ethyl diazoacetate. R. C. Todd, M. E. Dudley, M. M. Hossain, N. Uddin, M. S. Islam 435. Synthesis of 6-(4'-N,N-dimethylamino)pyrid-2'-yl-7-amino-4-methylcoumarin (DAMC) as a novel fluorophore. X. Wu, LHu 436. Synthesis of highly enantiopure primary amines by the catalytic reduction of benzyl oxime ethers using the novel spiroborate ester/borane system. F. G. Merced Ortiz, A. Ayala, Z. Oquendo, M. Ortiz, X. Huang 437. Synthesis, characterization, and evaluation of novel bioconjugation linkers. C. Y. Lee, M. R. Shepard, N. T. Zalenski, J. A. Muller II, D. W. Ki 438. Synthesis, resolution, and diastereoselectivity of the chiral auxiliary trans-2-(9Hfluoren-9-yl)cyclohexanol. M. A. Cheney, J. M. Salvador 439. Two new tetraoxygenated xanthones from the branch of Calophyllum membranaceum. X. Song, C. Han 440. Understanding the biosynthetic capability of marine cyanobacteria: Enzymatic study of the curacin A pathway. L. Gu, D. Sherman 441. Wittig reactions and rearrangements leading to benzophenone- and chromonebased ligands for evaluation as potential retinoids. S. Desai, W. Sun, P. J. Carroll, J. L. Gabriel, D. Soprano, D. J. Canney 442. Zirconium nitrate: A mild, efficient catalyst for the synthesis of 4 (3H)-quinazolinones under solvent free conditions. S. Gowravaram, N. Mallikarjuna Reddy, M. Nagendra Prasad, G. Santosh, J. S. Yadav 443. Toward achieving non-protein based selective retrieval of crosslinked peptides in mass spectrometric analysis of protein complexes. F. Yan, R. H. Angeletti THURSDAY MORNING Section A McCormick Place Lakeside Room E353 A/B, Level 3 General Oral Session D. P. Rotella,
Organizer
9:00 444. Neutron activation analysis determination of self-assembled monolayer (SAM) disruption in a bioelectrode: Kinetics of release of anti-inflammatory Au thiolate. M. Ovadia, D. Zavitz, H. A. Chou, D. J. Vanderah 9:20 445. Synthesis of a new prodrug linker system used for selective delivery of drugs to prostate cancer. G. A. Suaifan, M. D. Threadgill
TECH-89
TECHNICAL PROGRAM
MEDI/NUCL 9:40 446. Pyrrolotriazine dual EGFR/HER2 protein tyrosine kinase inhibitors with solubilizing groups at C-5. H. Mastalerz, M. Chang, P. Chen, D. Cook, P. Dextraze, B. E. Fink, A. Gavai, Β. Goyal, W-C. Han, W. Johnson, S-H. Kim, D. Langley, F. Lee, K. Leavitt, D. Norris, P. Marathe, A. Mathur, S. Oppenheimer, E. Ruediger, J. Tarrant, J. Tokarski, G. Vite, D. Vyas, H. Wong, T. Wong, H. Zhang, G. Zhang 10:00 447. Design of class selective HDAC inhibitors. G. Estiu, C. Harrison, O. Wiest, R. Mazitschek, J. Bradner 10:20 448. Structural insights into the binding sites of histone deacetylase isoforms HDAC1 and HDAC6: Implications in drug design. H. Yuan, Y. Chen, A. M. Gaysin, A. P. Kozikowski, P. A. Petukhov 10:40 449. Studies on the stability of HA 14-1, a small molecule antagonist for anti-apoptotic Bcl-2 protein. C. Xing, J. M. Doshi 11:00 450. Design, synthesis, and biochemi cal evaluation of Lumazine synthase inhibitors as potential antimicrobial agents. A. Talukdar, A. Bâcher, M. Fisher, Β. Illarionov, M. Cushman 11:20 451. Antitubercular nucleosides that inhibit siderophore biosynthesis. R. V. Somu, D. Wilson, C. Qiao, J. Vannada, E. Bennett, H. Boshoff, C. E. Barry III, C. C. Aldrich 11:40 452. Antibiotic microarrays to study resistance. M. D. Disney, O. J. Barrett 12:00 453. Design, synthesis and SAR of novel inhibitors for glutamate racemase (RacE2) from Bacillus anthracis. K. Gao, Z. Wang, D. C. Mulheam, H. Yu, G. R. J. Thatcher, M. E. Johnson THURSDAY AFTERNOON Section A McCormick Place Lakeside Room E353 A/B, Level 3
Section A
Division of Nuclear Chemistry & Technology
Hyatt Regency McCormick Pullman Modern Nuclear Reactors: Improvements of Existing Technology and Generation IV Developments
H. Nitsche, Program Chair
J. Vujic, T. J. Downar, and B. Wirth, Organizers
SUNDAY MORNING Section A Hyatt Regency McCormick Pullman Nuclear Energy: International Efforts Toward a Sustainable Future Cosponsored with SUST K. W. Thomas and S. C. Scott,
Organizers
8:00 Introductory Remarks. 8:05 1. The global nuclear energy partner ship. P. W. Lisowski 8:45 2. Transmutation of actinides in burner reactors: Transuranic fuels. K. Pasmehmetoglu 9:10 3. French considerations regarding nuclear fuel cycle closure. P. Brossard 9:35 Intermission. 9:55 4. Past experience in reprocessing of spent nuclear fuel. A. Buychkov 10:20 5. Development of fast reactor tech nology: Overview of the Chinese approach. M. Xu 10:45 6. An overview of JAEA safeguards for GNEP. M. Senzaki 11:10 7. Putting it all together: Integrated outlook for nuclear energy expansion. B. Richter
Hyatt Regency McCormick 22 A/B Presiding
1:30 454. Design, synthesis and pharmaco logical evaluation of novel analogs of the anti-addiction alkaloid, lobeline. A. P. Vartak, A. G. Deaciuc, L. P. Dwoskin, P. A. Crooks 1:50 455. 3-D-QSAR studies of Salvinorin A analogs as kappa opioid receptor agonists. D. Pandit, W. Harding, K. Tidgewell, M. Schmidt, A. Lozama, C. M. Dersch, W. J. Skawinski, R. B. Rothman, T. Prisinzano, C. A. Venanzi 2:10 456. Development of benzazepinone Nav1 blockers for the treatment of neuro pathic pain. S. B. Hoyt, C. London, D. J. Gorin, W. H. Parsons, A. E. Weber, C. Abbadie, R. M. Brochu, J. P. Felix, M. L. Garcia, N. Jochnowitz, B. V. Karanam, S. Kumar, K. A. Lyons, X. Li, D. E. Maclntyre, E. McGowan, W. J. Martin, B. T. Priest, M. M. Smith, V. A. Warren, B. S. Williams, G. J. Kaczorowski, J. L. Duffy 2:30 457. Prediction of the 3-D structure for FMRF-amide peptides bound to the mouse MrgC11 GPCR and experimental validation. J. Heo, S-K. Han, N. Vaidehi, J. Wendel, P. M. Kekenes-Huskey, W. A. Goddard III 2:50 458. Discovery of novel small molecule regulators of the integrin CD11b/CD18. J. Y. Park, M. A. Arnaout, V. Gupta 3:10 459. Why are we still doing drug discov ery? M. D. Segall 3:30 460. Developing magic bullets: Advances in heterocyclic ligands for acti vated αφ-\ integrin. R. D. Carpenter, K. S. Lam, M. J. Kurth 3:50 461. Synthesis and characterization of unnatural peptide inhibitors of thrombin activated platelet aggregation. F. M. Burke, M. Warnock, A. H. Schmaier, J. Hilfinger, H. I. Mosberg 4:10 462. Synthesis of 1,4-disubstituted piperazine analogs with moderate to high sigma subtype affinity and selectivity. R. Xu, J. R. Lever, S. Z. Lever 4:30 463. Medicinal chemistry vs. hERG. Z. Rankovic
90-TECH
SUNDAY AFTERNOON
Section Β
General Oral Session D. P. Rotella, Organizer,
NUCL
Actinide and Fission Product Isotope Needs for Energy and National Security Programs C. W . Alexander and C. A. McGrath, Organizers 8:00 Introductory Remarks. 8:10 8. Plutonium-244: Past, present, and future. A. Ghiorso 8:50 9. Large scale isotope production at the Savannah River Site(SRS) from 3H to 252Cf to present. M. G. Bronikowski, M. R. Williams, W. E. Bickford 9:15 10. Use of HFIR-produced actinide nuclides for nuclear structure studies. I. Ahmad 9:40 11. Heavy element nuclear and chemi cal properties determined by heavy ion irradiation of actinide targets. Κ. Ε. Gregorich 10:05 Intermission. 10:20 12. Isotope needs and availability for reference material production. S. A. Goldberg, B. C. Srinivasan, P. Mason 10:45 13. Actinide needs of the GNEP transmutation fuels development program. J. R. Kennedy 11:10 14. Actinide needs for multicycle partitioning-transmutation process develop ment. E. D. Collins, D. F. Williams, J-P. Renier 11:35 15. Needs for americium and curium isotopes in advanced fuel cycle research. K. Czerwinski
1:00 Introductory Remarks. 1:05 16. Overview of Global Nuclear Energy Partnership and advanced burner reactor. R. N. Hill, H. Khalil 1:45 17. The deep burn destruction of nuclear waste transuranics using the gas cooled reactor. F. Venneri 2:10 18. Nuclear battery type reactors. E. Greenspan, J . Vujic 2:35 Intermission. 2:55 19. Molten-salt reactors for transmuta tion of actinides from LWR. B. Becker, M. Fratoni, E. Greenspan 3:20 20. Applications of liquid salts for high temperature heat transport in nuclear systems. P. Peterson 3:45 2 1 . Hydride fuel for improving the design and performance of LWR. E. Greenspan 4:10 22. Advances in nuclear materials for next generation reactor systems. T. Allen 4:35 23. Reduction of environmental impact and expansion of capacity of geologic. J. Ann Section Β Hyatt Regency McCormick 22 A/B Actinide and Fission Product Isotope Needs for Energy and National Security Programs C. W. Alexander and C. A. McGrath, Organizers 1:00 24. Recent actinide targets for neutron cross section measurements. J. D. Baker, C. A. McGrath, T. S. Hill, R. Reifarth, T. A. Bredeweg, A. J. Couture, F. Tovesson 1:25 25. Neutron capture measurements on actinide and fission products using DANCE. R. Reifarth, A. Couture, J. D. Baker, T. Bredeweg, E-l. Esch, R. C. Haight, M. Jandel, J. M. O'Donnell, R. S. Rundberg, D. J. Vieira, J. Wouters 1:50 26. Radioisotopes for use in power sources. C. S. Murray 2:15 27. Criticality of a neptunium sphere. R. Sanchez, D. Loaiza, D. Hayes, C. Cappiello 2:40 Intermission. 2:55 28. Actinides are absolutely necessary for research. J. M. Kenneally 3:20 29. Nuclear Data Measurement Pro gram at LANSCE. R. O. Nelson 3:45 30. Coextraction of americium (VI) and the major actinides with tributyl phosphate. B. J . Mincher, N. C. Schmitt 4:10 3 1 . Evaluation of inorganic sorbents for separation of 9 9 Mo from highly concen trated uranium solutions. D. C. Stepinski, A. V. Gelis, A. J. Bakel, G. F. Vandegrift 4:35 32. Reversing the arrow of time: A tool for nuclear energy and security applica tions. J . Meeway, W. Loveland MONDAY MORNING Section A Hyatt Regency McCormick Pullman
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Nuclear Waste Forms: Current Solutions and Future Challenges S. Clark, R. C. Ewing, and W . J . Weber, Organizers 8:20 Introductory Remarks. 8:25 33. Integrated waste management strategy for tomorrow. D. Gombert II, J. Roach
9:05 34. Synthesis and characterization of technetium-zirconium alloys. K. Czerwinski, F. Poineau, T. Hartmann, G. Jarvinen 9:30 35. Options for decay storage and disposal of cesium and strontium from GNEP reprocessing schemes. M. D. Kaminski, C. J. Mertz 9:55 36. Alpha-damage and helium behavior in nuclear fuels and waste forms. T. Wiss, J-P. Hiemaut, D. Staicu, D. Roudil, X. Deschanels, R. Konings, V. Rondinella 10:35 Intermission. 10:45 37. Ion beam irradiation of (Y1xLax)2Ti207 and actinide-doped pyrochlore. J. Lian, R. Ewing, L Wang, S. V. Yudintsev 11:10 38. Predominance of surface charging on uranyl silicates. N. A. Wall, S. B. Clark, L C. Hull 11:35 39. Formation and alteration of coffinite (USi0 4 ) in the Grants uranium depos its, New Mexico. A. P. Deditius, S. Utsunomiya, R. C. Ewing Section Β Hyatt Regency McCormick 22 A/B Glenn T. Seaborg Award for Nuclear Chemistry: Symposium in Honor of Norbert G. Trautmann J. V. Kratz and H. Nitsche,
Organizers
8:30 Introductory Remarks. 8:45 40. Award Address (Glenn T. Seaborg Award for Nuclear Chemistry, sponsored by ACS Division of Nuclear Chemistry and Technology). Rapid chemical separation methods and resonance ionization mass spectrometry: Tools for nuclear research. N. Trautmann 9:30 4 1 . A perspective on the future of superheavy element (SHE) research. D. C. Hoffman 10:15 Intermission. 10:30 42. Aqueous-phase chemistry of the transactinide elements. J. V. Kratz 11:15 43. Gas phase chemistry of heaviest elements. H. Gaeggeler Calixarenes: State of the Art and Perspectives Sponsored by l&EC, Cosponsored with NUCL MONDAY AFTERNOON Section A Hyatt Regency McCormick Pullman Nuclear Waste Forms: Current Solutions and Future Challenges S. Clark, R. C. Ewing, and W. J. Weber, Organizers 1:20 Introductory Remarks. 1:25 44. Trends in bonding within An substi tuted zircon, using electronic structure to optimize classical interatomic potentials and facilitate molecular dynamics simula tion. A. Clark 2:05 45. Computational investigation of Np incorporation in boltwoodite. L. C. Shuller, R. Ewing, U. Becker 2:25 46. Thermodynamics of neptunium solid phases for modeling dissolved concentra tions. J. I. Friese, M. Douglas, R. F. Payne, M. K. Edwards, B. D. Hanson 2:45 Intermission. 2:55 47. Experimental measurements of uranyl oxide hydrate mineral solubilities at 298K. D. Gorman-Lewis, L. Mazeina, A. Navrotsky, J. E. Szymanowski, P. C. Burns, J. B. Fein 3:15 48. Neptunium association with second ary uranyl solid phases: Status and future needs. M. Douglas, J. I. Friese, R. F. Payne, M. K. Edwards, B. D. Hanson 3:35 49. Alternative matrices for sodiumbearing waste. J. Seghers, J. Braet, K. Lemmens, B. D. Begg, R. A. Day 3:55 50. Effect of Si02 (aq) activity on lanthanide borosilicate glass dissolution under acidic conditions. Ε. Μ. Pierce, D. M. Strachan, E. A. Rodriguez, J. C. Marra
NUCL 4:35 5 1 . Nanometric alteration layer analysis in the field of long term nuclear glass leaching. T. Chave, P. Frugier, A. Ayral, S. Gin
Section Β
Section Β
Section Β
Hyatt Regency McCormick Pullman
Hyatt Regency McCormick Pullman
Hyatt Regency McCormick 22A/B
Section Β
Spent Nuclear Fuel Reprocessing: Future, Present, and Past National and International Experiences
Spent Nuclear Fuel Reprocessing: Future, Present, and Past National and International Experiences
Fast Automated Radiochemistry Separations in Fundamental and Applied Nuclear Chemistry Attribution Science and Environmental Monitoring
Hyatt Regency McCormick 22A/B Glenn T. Seaborg Award for Nuclear Chemistry: Symposium in Honor of Norbert G. Trautmann J . V. Kratz and H. Nitsche,
Organizers
1:45 52. Resonant ionization mass spectros copy for nuclear studies. H-J. Kluge 2:30 53. Resonance ionization mass spec trometry for element- and isotope-selective trace analysis. N. Erdmann, J. V. Kratz, N. Trautmann, G. Passler, G. Huber, K. Wendt 3:15 Intermission. 3:30 54. Actinide speciation and interaction processes in the environment. H. Nitsche 4:15 55. Interactions of neptunium and plutonium with minerals and humic sub stances. T. Reich, J. V. Kratz, N. Trautmann Calixarenes: State of the Art and Perspectives Sponsored by l&EC, Cosponsored with NUCL M O N D A Y EVENING Section A
M. C. Regalbuto, B. A. Mover, and M. G. Bronikowski, Organizers 8:00 Introductory Remarks. 8:05 64. Spent nuclear fuel reprocessing: Where we have been and where we are going. R. G. Wymer 8:40 65. GNEP and the International Fuel Cycle. J. J. Laidler 9:15 66. Separations, coordination, and solvation of f-elements in ionic liquids. R. D. Rogers, N. J. Bridges, V. A. Cocalia, Κ. Ε. Gutowski 9:35 67. Distribution of C-14 labeled PEG400 in the HCCD-PEG solvent extraction system. T. A. Robinson, D. R. Peterman, R. S. Herbst 9:55 Intermission. 10:15 68. Present status and perspective on FR fuel cycle in Japan. H. Funasaka 10:50 69. Processing spent nuclear fuel in alkaline solutions: A feasible approach? W. Runde, R. Villarreal, G. Jarvinen 11:10 70. Overview of stripping improve ments for the Caustic-Side Solvent Extrac tion (CSSX) process. L. H. Delmau, E. Bazelaire, P. V. Bonnesen, N. L. Engle, M. G. Gorbunova, T. J. Haverlock, B. A. Moyer, D. D. Ensor, V. M. Meadors, B. W. Harmon, R. A. Bartsch, M. A. Surowiec
Hyatt Regency Chicago Riverside Center
TUESDAY AFTERNOON
Sci-Mix
Section A
H. Nitsche,
Organizer
8:00-10:00 56. Reaction mechanism of UN 2 conversion to UN. G. W. C. Suva, C. B. Yeamans, G. Cerefice, K. Czerwinski 57. Neptunium speciation in the aqueous phase of the UREX extraction system. B. S. Matteson, J. E. Bruso, P. Tkac, A. Paulenova 58. Cleanup of used solvent in Purex process by unsymmetric dimethylhydrazine oxa late. Y. Zhang, X. Wang, Z. Li, X. Liu 59. Electrochemical and chemical studies of thorium(IV)-based molten fluoride mixtures relevant to future nuclear systems. S. Delpech, G. S. Picard TUESDAY MORNING Section A Hyatt Regency McCormick 22A/B Proliferation Issues Related to Advanced Nuclear Fuel Cycles Benefits vs. Proliferation Risks for Advanced Fuel Cycles C. L. Hartmann-Siantar and A. Mcfarlane, Organizers 9:00 Introductory Remarks. 9:10 60. Proliferation-resistance of alternative fuel cycles. F. N. von Hippel 9:35 6 1 . Global Nuclear Energy Partnership as proposed will facilitate proliferation and the fast-neutron reactors are premature. R. L. Garwin 10:00 Intermission. 10:10 62. Moving to a new nuclear regime: Key issues at the the back end of the fuel cycle. T. H. Isaacs 10:35 63. The future of the nuclear fuel cycle. D. J . Hill 11:00 Panel Discussion.
Hyatt Regency McCormick 22A/B Proliferation Issues Related to Advanced Nuclear Fuel Cycles Science and Technology
M. C. Regalbuto, B. A. Moyer, and M. G. Bronikowski, Organizers 1:00 80. Separation chemistry of actinides: Recent developments. V. K. Manchanda 1:35 8 1 . Pertechnetate coordination to actinide cations in the presence of analogs to tri-n-butyl phosphate. I. May, S. M. Cornet, G. H. John, M. P. Redmond, C. A. Sharrad, A. D. Sutton, D. Collison, M. Helliwell, M. J. Sarsfield 2:10 82. Nitrate effects on uranium and plutonium extractions. A. D. Wright, K. Czerwinski 2:30 83. Effect of acetohydroxamic acid on equilibrium of Mo and Zr in the TBP and CMPCvTBP extraction systems. P. Tkac, A. Paulenova, B. S. Matteson 2:50 Intermission. 3:10 84. Aspects of reprocessing from the UK perspective including future technical challenges. R. J. Taylor 3:45 85. IRI's column separation techniques for establishing an advanced aqueous reprocessing system. Y. Wei 4:20 86. Synthesis and characterization of the solid uranyl-acetohydroxamic acid complex. C-M. S. Gong, F. Poineau, K. Czerwinski 4:40 87. Kinetics of hydrolytic degradation of acetohydroxamic acid. J. E. Bruso, M. A. Cleveland, A. Paulenova Chemical Evolution, Chemical Change Across Space and Time Chemical Evolution in Astrophysics Sponsored by CHED, Cosponsored with GEOC, and NUCL
1:30 7 1 . Enrichment plant safeguards: Cur rent safeguards and improvements with remote monitoring, mailbox system, and randomized inspection approaches. B. D. Boyer 1:50 72. International safeguards and the challenges for sensors, data integration, and data analysis. M. Schanfein 2:10 73. An experimental demonstration of real-time monitoring of plutonium content and thermal power of a reactor with a cubic meter antineutrino detector. A. Bernstein 2:30 74. Development of NDA measurement methodology and instrument for pressur ized water reactors spent fuel assemblies verification. Y. S. Ham, P. Song, I. Park, J. Kim, G. Min 2:50 75. Airborne radioactivity measure ments. T. Bowyer 3:10 Intermission. 3:30 76. Safeguards for the Advanced Fuel Cycle Facility. K. E. Thomas, S. Demuth, S. Tobin, I. R. Thomas 3:50 77. Nonproliferation aspects of the UREX+ processing suite. G. F. Vandegrift 4:10 78. Use of UV-Vis spectroscopy and TRLFS for material accountability in sol vent extraction processes. N. A. Smith, G. Cerefice, K. Czerwinski 4:30 79. Nuclear forensics: A key component of non-proliferation control. M. J. Kristo
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Chemical Evolution, Chemical Change Across Space and Time Geochemical Evolution of the Solar System and Earth Sponsored by CHED, Cosponsored with GEOC, and NUCL WEDNESDAY AFTERNOON Section A
Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Cosponsored with GEOC
Hyatt Regency McCormick Pullman Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Cosponsored with GEOC D. I. Kaplan and M. Zavarin,
8:30 Introductory Remarks. 8:35 96. Automated chemistry for national security applications. K. J. Moody 9:15 97. Automated gas-phase separation of environmental iodine in preparation for isotopic analysis. J. M. Schwantes, T. Simmons, R. Slaugh, E. Ortega, M. D. Engelmann 9:45 98. Comparison of capillary electropho resis and ion chromatography with UV-VIS absorption detection for the analysis of lanthanide and actinide elements. R. R. Foley, S. P. Lamont, R. E. Steiner 10:15 Intermission. 10:35 99. Characterization and evaluation of rapid column separation methods for automation. J. M. Gostic, R. C. Gostic, R. Sudowe, K. Czerwinski 11:05 100. Path to efficient data handling for high throughput radioanalytical proce dures. H. Ziegler
Hyatt Regency McCormick Pullman
WEDNESDAY MORNING Section A
C. L. Hartmann-Siantar and A. Mcfarlane, Organizers
D. A. Shaughnessy and R. Sudowe, Organizers, Presiding
Organizers
8:00 Introductory Remarks. 8:05 88. Scientific understanding aids pluto nium remediation at Rocky Flats. D. L Clark, D. R. Janecky, G. R. Choppin, L. J. Lane 8:35 89. Colloid transport of plutonium in the far-field of the Mayak Production Associa tion, Russia. S. Utsunomiya, R. C. Ewing, A. P. Novikov, S. N. Kalmykov, F. Horreard, A. Merkulov, S. B. Clark, B. F. Myasoedov, V. V. Tkachev 9:05 90. Modeling plutonium transport through sediment containing plutonium sources of various oxidation states: An 11-year lysimeter study. D. I. Demirkanli, F. J. Molz III, D. I. Kaplan, R. A. Fjeld, J. T. Coates 9:35 9 1 . Sorption of neptunium and pluto nium to Yucca Mountain tuff. T. A. Sullens, J. Daniels, K. Czerwinski 9:55 Intermission. 10:15 92. Subsurface bioimmobilization of plutonium and uranium: Experimental and model validation study. R. P. Deo, B. E. Rittmann, D. T. Reed, G. B. Smith 10:35 93. Kinetics of sorption and desorption of neptunium and plutonium in synthetic mineral suspensions. B. A. Powell, A. B. Kersting, M. Zavarin 10:55 94. Microbial impacts on the migration of actinides: Effects of exudates on the migration. T. Ohnuki, T. Ozaki, T. Yoshida, T. Nankawa, N. Kozai, F. Sakamoto, Y. Suzuki, A. J. Francis 11:15 95. EPS biocolloids as a transport agent for Pu. B. D. Honeyman
D. I. Kaplan and M. Zavarin,
Organizers
1:00 101. Strontium exchange and mobility at the Hanford Site, USA. C. Steefel, J..M. Zachara, P. C. Lichtner, S. A. Carroll 1:30 102. Strontium binding structures in designer swelling micas. G. M. Bowers, Μ. Ο Davis, R. Ravella, S. Komarneni, Κ. Τ. Mueller 1:50 103. Experimental approach for distin guishing between contaminant release by desorption and dissolution processes. J. A. Davis, D. L Bond, Y. Arai, J. M. Zachara 2:20 104. Microscopic mass transfer control ling source zone U(VI) reactivity at US Hanford Site. C. Liu, J. M. Zachara, P. Majors, J. P. McKinley 2:40 105. Using synchrotron X-ray tech niques to examine uranium speciation with depth in contaminated Hanford sediments. D. M. Singer, J. M. Zachara, G. E. Brown Jr. 3:00 Intermission. 3:20 106. Extracellular reduction of hexavalent uranium by Clostridium sp. D. Chidambaram, A. J. Francis 3:40 107. Mechanisms of uranium(VI) reduc tion by Clostridia. W. Gao, A. J. Francis 4:00 108. Immobilization of U(VI) accompa nying microbial iron reduction. T. Behrends, P. Van Cappellen 4:20 109. Interaction of methoxyethyl methyl imidazolium tetrafluoroborate with uranium and its application on uranium bioreduction. H. Wang, C. J. Dodge, S. V. Malhotra, A. J. Francis 4:40 110. Bioremediation of uranium in aerobic environments via bacterial phos phatase activity. M. J. Beazley, R. J. Martinez, S. M. Webb, P. A. Sobecky, M. Taillefert
TECH-91
TECHNICAL PROGRAM
NUCL/ORGN
Section Β Hyatt Regency McCormick 22A/B
11:40 126. Redox properties of groundwater in the vicinity of Yucca Mountain using trace element speciation determined by ion chromatography inductively coupled plasma mass spectrometry. J. V. Cizdziel, V. F. Hodge, K. Lindley, S. Gamage
Fast Automated Radiochemistry Separations in Fundamental and Applied Nuclear Chemistry Environmental Monitoring
Section Β
R. Sudowe and D. A. Shaughnessy, Organizers, Presiding
McCormick Place North Room Ν140, Level 1
1:20 Introductory Remarks. 1:30 111. Automated separation-based approaches to rapid radiochemical analy sis and sensing. J. W. Grate, O. Egorov, M. J. O'Hara 2:10 112. Rapid automated radiochemical analyzer for determination of Tc-99 and Sr-90 in nuclear waste processing streams. M. J. O'Hara, Ο. Β. Egorov, J. W. Grate, J. P. Clements, T. DeVol 2:40 Intermission. 3:00 113. Rapid chromatographic separation of actinides with ICP-MS detection for bioassay applications. D. S. Peterson, A. A. Plionis, E. R. Gonzales 3:30 114. Automated actinide separation and electrodeposition using HPLC. A. A. Plionis, D. S. Peterson, E. R. Gonzales 4:00 115. An automated system for the production of high purity radionuclides. D. R. McAlister, E. P. Horwitz, J. J. Hines, J. E. Young, J. T. Harvey
Fast Automated Radiochemistry Separations in Fundamental and Applied Nuclear Chemistry Heavy Element Research
Chemical Evolution, Chemical Change Across Space and Time Prebiotic Chemistry Sponsored by CHED, Cosponsored with GEOC, and NUCL THURSDAY MORNING
ORQN
R. Sudowe and D. A. Shaughnessy, Organizers, Presiding 8:30 Introductory Remarks. 8:40 127. Automated separation techniques in superheavy element chemistry. M. Schaedel 9:20 128. Rapid ion-exchange separation apparatus AIDA for heavy element chem istry. Y. Nagame, K. Akiyama, M. Asai, S. Goto, H. Haba, Y. Ishii, Y. Kasamatsu, I. Nishinaka, H. Tourne, A. Toyoshima, K. Tsukada 9:50 Intermission. 10:10 129. Fast and continuous liquid-liquid extraction with the computer controlled SISAK system. J. P. Omtvedt 10:40 130. MicroSISAK: A device for fast and continuous liquid-liquid-extractions on a μΙ-scale. K. Eberhardt, J. V. Kratz, P. Lob, G. Skarnemark 11:10 131. Future automation challenge: Chemistry of element 114. D. A. Shaughnessy 11:40 Concluding Remarks.
Section A Chemical Evolution, Chemical Change Across Space and Time Teaching Chemical Evolution Sponsored by CHED, Cosponsored with GEOC, and NUCL
McCormick Place North Room Ν139, Level 1 Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Cosponsored with GEOC
4:20 141. Dendritic chelating agents: Experi mental investigations of U(VI) binding to poly(amidoamine) and poly(propyleneimine) dendrimers in aqueous solu tions. M. Diallo, W. D. Arasho, J. H. Johnson, W. A. Goddard III 4:40 Concluding Remarks.
THURSDAY AFTERNOON
Divisioin of Organic Chemistry W. Greenlee and S. M. Sieburth, Program Chairs
S O C I A L [EVENTS: Social Hour: Wed, Sun SUNDAY MORNING Section A McCormick Place Lakeside Room E450 A/B, Level 4 Ernest Guenther Award in the Chemistry of Natural Products: Symposium in Honor of Dale L. Boger I. Ojima,
Organizer
8:45 Introductory Remarks. 8:50 1 . Natural and unnatural roles of natural products. J. Clardy 9:35 2. Total synthesis of polyene natural products using tin/boron linchpin systems. R. S. Coleman 10:20 3. Guanidinium toxins: Unique molecu lar targets for investigation. J. Du Bois 11:05 4. Award Address (Ernest Guenther Award in the Chemistry of Natural Prod ucts, sponsored by Givaudan). Natural products and nature's lessons. D. L. Boger
Section A Section Β
D. I. Kaplan and M. Zavarin,
Organizers
8:00 116. Interactions among phosphate amendments, microbes and uranium mobility in contaminated soils. A. S. Knox, D. I. Kaplan, R. L. Brigmon 8:20 117. Site characterization to support conceptual model development for subsur face radionuclide transport. R. G. Ford 8:50 118. Ferrous iron reduction of uranyl ions and its implications of a mobile reduced species: U(V). M. C. F. Wander, S. Kerisit, K. M. Rosso, M. A. A. Schoonen 9:10 119. Complexation and polymerization: interactions of uranium with organic mol ecules. P. Jha, G. P. Halada, B. Phillips, J. D. Kubicki, A. Ceballos 9:30 120. Role of Fe(ll) in the biotic and abiotic reduction of higher valent uranium and plutonium. D. T. Reed, B. E. Rittmann, S. E. Pepper, R. Deo 9:50 Intermission. 10:00 121. Stability of bacteriogenic uranium(IV) oxide nanoparticles for environ mental remediation. D. E. Giammar, K-U. Ulrich, S. F. Dixon, R. Bencheikh-Latmani, H. Veeramani, J. Sharp, E. Schofield, J. R. Bargar, B. M. Tebo 10:20 122. Solid phase biotransformation of camotite [K2(U02)2(V04)2]. S. Glasauer, S. C. Fakra, F. Islam, T. Beveridge, T. Tyliszczak, D. K. Shuh 10:40 123. Adsorption of uranium to goethite coated sand: Effect of pH and solid-tosolution ratio. V. A. Loganathan, S. R. Kanel, P. T. Clement, M. O. Barnett 11:00 124. Solid phase formation in iron, uranium, and silicate rich media. J. Daniels, T. A. Sullens, K. Czerwinski 11:20 125. Effect of carbonate and borate complexation on Nd 3 + and U 0 2 2 + solubil ity in WIPP brine. M. Borkowski, J-F. Lucchini, M. Richmann, S. Ballard, D. T. Reed
92-TECH
McCormick Place North Room Ν139, Level 1
McCormick Place Lakeside Room E451A/B, Level 4
Understanding Radionuclide Transport in the Environment: Remediation, Nuclear Waste Disposal, and Long-term Stewardship Cosponsored with GEOC D. I. Kaplan and M. Zavarin,
Organizers
1:00 132. Effective partition coefficients for radionuclide transport through saturated alluvium at the proposed high-level nuclear waste repository, Yucca Mountain, Nevada. C. D. Seism, P. Reimus, M. Ding, S. J. Chipera 1:20 133. Mechanisms of microbial transfor mations in TRU wastes. C. J. Dodge, A. J. Francis 1:40 134. Diffusion of iodine and rhenium in cemented waste forms. S. V. Mattigod, D. Wellman, G. A. Whyatt, M. Wood 2:00 135. Laboratory experiments of carbon-14 uptake on calcite and dolomite. R. L. Hershey, D. L. Decker, S. Earman, J-H. Ryu, P. Reimus, E. S. Garcia Jr. 2:20 Intermission. 2:40 136. Laboratory experiments of carbon-14 uptake and release from calcite. E. S. Garcia Jr., P. Reimus, R. L. Hershey, D. L. Decker, S. Earman 3:00 137. Remediation of radionuclides with bulk and nanoparticulate molybdenum oxides. A. W. Apblett, M. Chehbouni, B. P. Kiran 3:20 138. Applications of laser ablationICP/MS in understanding radionuclide transport. Q. Hu 3:40 139. Leaching of samples collected during the Glovebox Excavator Method Project. W. F. Bauer, G. S. Groenewold, B. J. Mincher, A. K. Gianotto, R. V. Fox 4:00 140. Second harmonic generation studies of metal ion binding to environ mental interfaces. F. M. Geiger
James Flack Norris Award in Physical Organic Chemistry: Symposium in Honor of Ben L. Feringa M. P. Doyle,
Presiding
9:00 5. Reaction chemistry meets lithogra phy. C. Nuckolls 9:40 6. Light-driven molecular machines that control guest motions. T. Aida, K. Kinbara, T. Muraoka 10:20 7. Physical organic chemistry on neuroreceptors and ion channels. D. A. Dougherty 11:00 8. Award Address (James Flack Norris Award in Physical Organic Chemis try, sponsored by the Northeastern Sec tion, ACS). The art of building small, from molecular switches to molecular motors. B. L. Feringa Section C McCormick Place East Room E350, Level 3 Biologically-Related Molecules and Processes R. Cheng,
8:40 11. An oxidation sensing mechanism is used by a global regulator of Staphylococ cus aureus. P. Chen, T. Bae, W. Williams, E. M. Duguid, P. Rice, O. Schneewind, C.He 9:00 12. Protein-DNA photocrosslinking. U. K. Shigdel, J. Zhang, C. He 9:20 13. Efficient tetrabutylammonium iodidecatalyzed synthesis of methyl 3,5-di-Oarylmethyl-alpha-D-ribofuranosidesand application to the synthesis of 2'-C-betaalkoxymethyluridines. N-S. Li, J. Lu, J. A. Piccirilli 9:40 14. Photochemical control of biological processes. D. D. Young, A. Deiters 10:00 15. Selective photolabeling of Lck kinase. S. Hindi, L James, D. Mihai, K. W. Cha, A. Kawamura 10:20 16. Synthesis and evaluation anthranilate 4H-oxazol-5-one compounds to inhibit phosphopantetheinyl transferase involved in secondary metabolism. M. D. Burkart, T. L Foley, B. S. Young 10:40 17. Synthesis of fluorescence-labeled fragments of the inhibitors of DNA-binding Id and their characterization by FRET spectroscopy. C. Cabrele, J. Svobodovâ, N. Colombo, A. Snyder 11:00 18. Synthesis of unusual trifluoromethyl amino acid derivatives via acid catalyzed addition of indoles to trifuoromethylated imines. A. Mohammed, L. Teixeira, V. Antonellis, B. Tôrôk 11:20 19. Targeting DNA internal loops with heterocyclic compounds. J. F. Arambula, S. C. Zimmerman 11:40 20. Toward a molecular host selective for uracil vs. thymine: Lessons from uracil DNA glycosylase. H. C. Ong, S. C. Zimmerman Section D McCormick Place East RoomE351, Level 3 New Reactions and Methodology M. B. Smith,
Presiding
8:00 2 1 . A new strategy for the synthesis of phenanthridone alkaloids. F. C. Gaenzler, M. B. Smith 8:20 22. Activation and application of alumina employing microwave irradiation. G. W. Kabalka, E. Dadush, R. M. Pagni, J. F. Green, A. Sease 8:40 23. Copper(l)-catalyzed 1,4-addition of alkenyl groups from alkenylzirconium and alkenylzinc reagents: New tools in synthesis of natural products. A. El-Batta, M. Bergdahl 9:00 24. Copper(ll)-catalyzed aminohydroxylation of olefins. T. P. Yoon, D. J. Michaelis, C. J. Shaffer, T. Benkovics 9:20 25. General method for synthesis of stereotetrads akin to dipropionates. A. El-Awa, X. Mollat Du Jourdin, P. L. Fuchs 9:40 26. Hydrocarbons to macrolactones. K. J. Fraunhoffer, N. Prabagaran, L. E. Sirois, M. C. White 10:00 27. Improved methodology for synthesis in flow reactors. P. Watts, C. Wiles 10:20 28. Incorporation of an in situ ethynylsilane deprotection utilizing amidine bases, copper (I) iodide and water into Sonogashira- and Glaser-type coupling reactions. M. J . Mio, B. S. Dagher, J. A. Heidt, A. D. Hinshaw, B. P. Vos 10:40 29. Microwave-assisted solventless reactions: The synthesis of 3-alkyl-oxazolidine-2,4-diones, N-lactyl-N,N'-dialkylureas and poly-N-lactyl-N-hexamethylen-N'hexamethylene ureas. G. Galliani, M. Orlandi, B. Rindone, F. Saliu, A. Terraneo, E-L. Tolppa
Presiding
8:00 9. Responsive luminescent lanthanidebased probes for peptide phosphorylation. M. S. Tremblay, M. H. Lee, M. Halim, Q. Zhu, A. A. Marti, J. Dyer, S. Jockusch, Ν. J. Turro, D. Sames 8:20 10. A general platform for the design of ratiometric, luminescent reporters based on heterometallic bis-lanthanide ensembles. M. S. Tremblay, M. Halim, D. Sames
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ORGN 11:00 30. Rapid synthesis of structurally diverse intermediates through a micro wave-promoted multicomponent reaction. G. S. Vanier 11:20 3 1 . Siloxy alkynes: Bronsted acidpromoted cyclization of 1 -siloxy-1,5-diynes and silver-catalyzed syn-selective hydroamination. J . Sun, S. A. Kozmin 11:40 32. Withdrawn. Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN SUNDAY AFTERNOON Section A McCormick Place Lakeside Room E450 A/B, Level 4 ACS Award for Creative Invention: Symposium in Honor of Bruce Ganem
2:20 47. Inhibition of pancreatic cancer cell growth by designed peptides. L. Aulisa, N. Forraz, C. McGuckin, J. D. Hartgerink 2:40 48. Peptide amphiphile nanofibers for biomimetic mineralization. V. M. Yuwono, J. Hartgerink 3:00 49. Mechanistic studies on Escherichia coli AlkB protein through a disulfide crosslinking strategy. C. Yi, C-G. Yang, E. M. Duguid, X. Jian, C. He 3:20 50. Nanoparticle mediated inhibition of the MDM2:p53 interaction. R. R. Arvizo, N. O. Fischer, D. J. Jerry, V. M. Rotello 3:40 5 1 . Structural study of ABH proteins by utilizing chemical crosslinking strategy. C-G. Yang, C. Sullivan, C. He 4:00 52. 1,5-Triazoles as cis peptide bond mimics. A. Tarn, U. Arnold, M. B. Soellner, R. T. Raines 4:20 53. Toward synthetic collagen - 1 . R. T. Raines 4:40 54. Toward synthetic collagen - 2. R. T. Raines
8:00-10:00
70. Practical synthesis of KRP203: An unusal styrene coupling reaction. M. Chino 71. Probing NO release by symmetrically substituted dibenzoylfuroxans. N. M. Wachter, W. F. Nirode 72. Process challenges with the scale up and purification of a potential antibacterial candidate. D. J. Watson, D. D. Hennings, B. Wong, M. Medina, J. DeMattei 73. Process for the preparation of amezinium methylsulfate and evaluation of critical parameters for technology transfer. M. S. Allen, S. R. Chemburkar, D. N. Heinrichsmeyer, B. J. Kotecki, R. Lorenzini, R. E. Reddy, P. R. Singam 74. Synthesis of a novel photochromicallycontrolled, activatable MRI contrast agent. C. Tu, A. Y. Louie 75. Can aziridines undergo base-promoted isomerization to allylic amines? M. Pichon, K. M. Morgan, G. Brown Jr., K. Montgomery, K. Peterson 76. Computational studies of Titanium cata lyzed alkene hydroamination. K. Cormier, M. Lewis 77. Conformational analysis of HIV gp41 inhibitors. S. M. Remmert, C. A. Parish, I. Robina 78. Controlling bimolecular photocycloaddition reactions in confined media. M. V. Maddipatla, L. S. Kaanumalle, A. Natarajan, M. Pattabiraman, R. V 79. Correlation of thiophene-S-oxide and selenophene-Se-oxide excited states with deoxygenation products. S. A. Stoffregen, M. J. Heying, P. Dickerson, W. S. Jenks 80. Photochemical adventures with substi tuted thiophene-S-oxides. M. J. Heying, M. Nag, S. A. Stoffregen, W. S. Jenks 8 1 . Desaturase reactions complicate the use of norcarane as a mechanistic probe. D. S. P. Lansakara-P, R. E. P. Chandrasena, H-Y. Kim, M. Newcomb, S. J. Lippard, L. G. Beauvais, L. J. Murray, V. Izzo, P. F. Hollenberg, M. J. Coon 82. Design principles to tune the optical prop erties of 1,3,4-oxadiazole-containing mol ecules. O. Bolton, J. Kim 83. Diels-Alder reaction involving an unusual dienophile: Computational and mechanistic study. J. R. Waas, D. A. Singleton, J. O. Besinaiz 84. Effect of thio-substitution on the mecha nisms of transesterification of ribonucleoside phosphodiester models. S. Iyer, A. C. Hengge 85. Enhancement of two-photon photochromism of a diarylethene via Foster's resonance energy transfer from 2PA fluorene dyes. K. D. Belfield, M. V. Bondar, C. C. Corredor, 0 . V. Przhonska 86. Epimerization kinetics of electronically altered 1 -phenyl-1,2,3,4-tetrahydro^carbolines. M. L. Van Linn, F. H. Fôrsterling, H. J. Kumpaty, J. R. Deschamps, J. M. Cook 87. Evaluation of the transition state structure of the enzymatic famesylation reaction. S. Lenevich, M. D. Distefano 88. Experimental and theoretical investigations of chloronium ions. J. W. Schubert, B. K. Ohta 89. Formation of compound I in P450: Photooxidation from compound II to compound 1. J. A. Halgrimson, M. Newcomb, R. Zhang, R. E. P. Chandrasena, J. H. Horner, T. M. Makris, S. G. Sligar 90. Highly reactive macrocyclic ligand-iron(V)oxo intermediates. Z. Pan, D. N. Harischandra, R. Zhang, M. Newcomb 9 1 . Hydride reduction of N-methylacridinium ion by isopropanol catalyzed by Zn(ll). Y. Lu, D. Endicott 92. Investigation into the mechanism of 1, 2-cyclohexanediol conversion on metal catalysts. G. Ludeman, D. G. Kovacs
66. Withdrawn. 67. Efficient and practical synthesis of Cerageins. X. Lai, Y. Feng, G. Nelson, P. B. Savage 68. Efficient synthesis of bioactive spirocompounds via RCM of "Zhan Catalyst". Z-J. Zhao, Z-Y. J. Zhan 69. Investigation of critical process param eters (CPP) for production of Veliflapon (DG-031). G. L. Stahl, S. Manna, L. A. Enache, F. W. Muellner
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section D C. A. Maryanoff,
Organizer
1:30 Introductory Remarks. 1:35 33. Discovery of Zetia: the long and winding road for the extraordinary journey from ACAT to Zetia to NPC1L1. B. McKittrick 2:20 35. Chemical approaches to neurobiol ogy. L. C. Hsieh-Wilson 3:05 36. Pharmaceutical alkaloids: The search for an effective smoking cessation treatment. J . W. Coe 3:50 Introduction of Awardee. 4:00 37. Award Address (ACS Award for Creative Invention, sponsored by Corpora tion Associates). Encomiums for zirco nium. B. Ganem Section Β McCormick Place Lakeside Room E451A/B, Level 4 ACS Award for Creative Research and Applications of Iodine Chemistry: Symposium in Honor of Peter J. Stang J. F. Stoddart,
Organizer
1:25 Introductory Remarks. 1:30 38. Iodine based reagents in the syn thesis of organic materials. R. R. Tykwinski 2:10 39. Chemistry of hypervalent iodine heterocycles and pseudo-heterocycles. V. V. Zhdankin 2:50 40. Iodide-catalyzed magic ring opening as an efficient route to donor-acceptor [2]catenanes. O. S. Miljanic, J. F. Stoddart 3:20 4 1 . Strong donor-acceptor chromophores for advanced materials applica tions. F. Diederich 4:00 42. Award Address (ACS Award for Creative Research and Applications of Iodine Chemistry, sponsored by SQM S.A). Polyvalent iodine chemistry. P. J. Stang
McCormick Place Lakeside Room E351, Level 3 New Reactions and Methodology F. Rivas,
Presiding
1:30 55. Lewis acid promoted 1,3-dipolar cycloaddition reactions in water. A. T. Hamme II, L. Hicks 1:50 56. Photoenolization reaction: A tool for organic synthesis. P. Klan, L. Plistil, T. Pospisil, A. Tazhe Veetil, J. Wirz 2:10 57. Catalytic version of the Mitsunobu reaction. P. H. Toy, T. Y. S. But 2:30 58. Electrophile-induced ether transfer. K. Liu, R. Kartika, R. E. Taylor 2:50 59. Intermolecular palladium-catalyzed aerobic oxidative amination of functionalized alkenes. M. M. Rogers, V. Kotov, J. Chatwichien, S. S. Stahl 3:10 60. Ligand modulation in Wacker oxida tions with simple terminal oxidants. C. N. Cornell, M. S. Sigman 3:30 6 1 . Neutral pyridinium salts for the arylmethylation of alcohols. G. B. Dudley 3:50 62. One-pot methylenation-hydroboration-cross-coupling reactions. C. Ladjel, H. Lebel 4:10 63. Stereoselective synthesis of 2,4,6trisubstituted tetrahydropyrans via electro phile-induced ether transfer. R. Kartika, R. E. Taylor 4:30 64. Tandem oxidation of allylic and benzylic alcohols to esters catalyzed by N-heterocyclic carbenes. K. A. Scheldt, B. E. Maki, A. Chan, Ε. Μ. Phillips 4:50 65. Water-driven chemoselective reac tions with biomolecules. P. Sejwal, Y. Han, Y-Y. Luk Claude S. Hudson Award in Carbohydrate Chemistry: Symposium in Honor of Pierre Sinay Sponsored by CARB, Cosponsored with HIST, MEDI, and ORGN S U N D A Y EVENING
Section C Section A McCormick Place Lakeside Room E350, Level 3 Biologically-Related Molecules and Processes W . Greenlee,
Organizer
1:00 43. Helix propensity of highly fluorinated amino acids. R. P. Cheng, H-P. Chiu 1:20 44. Effect of Lys side chain length on intrahelical Glu-Lys interactions. R. P. Cheng, P. Girinath 1:40 45. Catalytically caged isoprenoid diphosphates for the study of protein prenylation. A. J. DeGraw, M. Hast, L. S. Beese, M. D. Distefano 2:00 46. Protein famesyltransferase: A new tool for protein modification. B. P. Duckworth, J. Xu, A. Hosokawa, Z. Zhang, M. D. Distefano
Hyatt Regency Chicago Riverside Center Process R&D, Physical Organic Chemistry, Heterocycles, Aromatics, Metal-Mediated Reactions S. M. Sieburth,
Organizer
93. Kinetics and calculations in the N03promoted gas phase nitration of phenol with N02. G. Galliani, E. Bolzacchini, M. Bruschi, M. Orlandi, B. Rindone, J. Hjorth 94. Mechanism of molybdenum-catalyzed asymmetric allylations: Quantum mechanical insights into regioselectivity and enantioselectivity. J. A. R. Luft, Z-X. Yu, D. L. Hughes, G. C Lloyd-Jones, S. Krska, K. N. Houk 95. Mechanisms of halocarbene additions to cyclooctyne: An experimental and theoretical investigation. S. Bernard, D. Napolitano, K. Suski, M. Khrapunovich, D. C. Merrer 96. Mechanistic investigations of the Barbier allylation of benzaldehydes. P. Fristrup, J. H. Dam, R. Madsen 97. Nanosecond laser flash photolysis study of photochemical ring opening in phenyl aziridines. P. K. Das 98. New fluorene-based two-photon singlet oxygen photosensitizers. S. J. Andrasik, K. D. Belfield, M. V. Bondar, A. R. Morales, O. V. Przhonska, S. Yao 99. Understanding rotary motion in crystalline solids: Going beyond single molecular rotor systems. S. L. Gould, R. B. Rodriguez, M. Garcia-Garibay 100. Molecular gyroscopes and compasses: Engineering motion into organic crystalline materials. Z. J. O'Brien, M. A. Garcia-Garibay 101. One step synthesis of hexasubstituted ketones. S. Shiraki, M. Garcia-Garibay 102. Photochemical generation and trapping of oxyallyl in crystalline ketones. C-K. Tsai, C. P. Suhrada, P. McCarren, K. N. Houk, M. Garcia-Garibay 103. Photochemical studies of diphenylcyclopropenone in the solid state: Evidence of a quantum chain reaction. Κ. Κ. Chin, A. Natarajan, M. Garcia-Garibay 104. Photodecarbonylation of organic salts of crystalline ketones as nanocrystalline suspensions. F. Family, M. A. Garcia-Garibay 105. Selectivity in palladium-catalyzed crosscoupling reactions involving halo-heterocycles. Y. Garcia, C. Y. Legault, K. N. Houk, C. A. Merlic 106. Development of palladium(ll) catalyzed reactions for macrocyclization. J. M. Fernandez, C. A. Merlic 107. Pyrene and Ν,Ν-dimethylaniline as an electron donor-acceptor pair in bridged ir-stacked tertiary ureas: Dynamics and mechanism. T. A. Zeidan, Q. Wang, M. Raytschev, T. Fiebig, F. D. Lewis 108. Pyrolysis of phenethyl phenyl ether: The dramatic effect of pore confinement on product selectivity. M. K. Kidder, A. C. Buchanan III 109. Photochemistry of tetraaza-tetrapyridopentacene related compounds and their role in small molecule activation. W. Guo, S. O. Obare 110. Quantum mechanical studies of five, seven, and eight-membered enediynes. E. B. Wang, C. A. Parish 111. Photo-driven motor for acceleration of chemical reactions. Q-Z. Yang, Z. Huang, R. Boulatov 112. Radical reactions on silica surfaces: Importance of molecular orientation in hydrogen transfers. A. C. Buchanan III, M. Kidder 113. Reaction of hydroxyl radical with ben zene derivatives: Experimental and com putational studies. S. Xia, C. Luk, M. S. Platz, C. M. Hadad 114. Roles of the nitrogen lone-pair and the terminal carbon-carbon ιτ-bond in the electrocyclic ring closure of 7-azahepta1,2,4,6-tetraene: A CASSCF MO study. J. A. Duncan, D. E. G. Calkins, M. Chavarha 115. Stereoselective electron transfer cata lyzed Diels-Alder reactions. C. S. Sevov, O. Wiest 116. Study of lone pair-arene interactions in solution. Y. Zou, B. W. Gung 117. Substituent effects in radical cation Diels-Alder reactions. N. A. Valley, O. Wiest 118. Kinetic studies of alkene radical cations by competition methods and laser flash photolysis. J. H. Horner, M. Newcomb
TECH-93
ORGN 119. Synthesis and triplet energy studies on fluorene-, thiophene- and phenyl- based oligomers. P. Anzenbacher Jr., V. A. Montes, L. A. Estrada 120. Zeroing in on the halogen dance mechanism of bromonitrosulfolene. J. E. Elbert, B. A. Suchy 121. Abnormal Nazarov cyclization involving rearrangement: Formation of spiro compounds from alkylidene beta-keto esters. J. Huang, A. J. Frontier 122. Bennzannulation with tandem pericyclic reactions. K. A. Korthals, W. D. Wulff 123. Carbocyclic carbene ligands derived from aromatic nitrones: Formation and catalytic activity of their Pd (II) complexes. M. Zabawa, J. Woo, C. Zheng, Q. Yao 124. Convergent synthesis of Orienticin C aglycone via Ruthenium-mediated SjvjAr reaction as a powerful tool for the construction of biaryl ether linkages. A. J. Pearson, D. V. Ciurea 125. Cupric halide mediated cyclization reactions: Synthesis of 3-haloindoles and 3-halobenzo[c]thiophenes. M-J. Wu, W-D. Lu, Z-C. Chuang 126. Dehydroxylation of benzylic alcohols through the corresponding lithium salts. G. W. Kabalka, Y. Min-Liang, T. Quick 127. Density functional theory study of C-H activation of arènes and alkanes with Cp*RhPMe3. R. G. lafe, K. N. Houk 128. Development of efficient Cul-catalyzed synthesis of aryl ethers. F. N. Ngassa, E. Lindsey 129. Efficient one-pot synthesis of indoles from 2-nitroethynylarenes using indium and hydroiodic acid. B. H. Kim, J. S. Kim, J. H. Han, Y. M. Jun, B. M. Lee 130. Microwave assisted [2+2+2] cyclotrimerizations. D. D. Young, A. Deiters 131. Novel PIB-based metathesis catalyst. H. S. Bazzi, C. Hongfa, D. E. Bergbreiter 132. Dihydroboration of 1-alkynylphosphonates with 9-borabicyclo[3.3.1]nonane (9-BBN) followed by oxidation. N. G. Bhat, V. D. Garate 133. Novel route to (Z)-1-phenylselenyl-1alkenylboronate esters via hydroboration. N. G. Bhat, R. K. Ruiz 134. Novel synthesis of gem-dimetalloalkanes containing boron and germanium. N. G. Bhat, E. A. Cavazos 135. Hydroalumination of (Z)-1-trimethylgermyl-1 -alkenes followed by selective iodinolysis. N. G. Bhat, M. Martinez 136. One-pot methylenation-Heck coupling reactions. L. Brethous, H. Lebel 137. Iridium catalyzed olefination reaction: Mechanistic studies. C. Ladjel, H. Lebel 138. Oxazoline-based six-membered exo- and endocyclopalladated complexes. R. Y. Mawo, D. M. Johnson, J. L Wood, I. P. Smoliakova 139. Palladium α-chlorovinyl complexes: Synthesis and reactivity. Ν. Ε. Carpenter, K. McNeill, J. Benson, A. A. Peterson 140. Palladium catalyzed intramolecular alkenyl triflate-arene coupling: A C-H functionalization route to carbocycles. Μ. Ο Willis, A. Cruz 141. Palladium pincer complex catalyzed asymmetric transformations of sulfonimines. J. Aydin, O. A. Wallner, V. J. Olsson, K. J. Szabo 142. Palladium pincer complex catalyzed synthesis and application of allyl boronic acids. V. J. Olsson, S. Sebelius, N. Selander, K. J. Szabo 143. Allylation of aldehydes by allyl alcohols via palladium pincer complex catalyzed formation of transient allylboronic acids. N. Selander, S. Sebelius, V. J. Olsson, K. J. Szabo 144. Palladium-catalyzed coupling reactions involving N-alkoxyimidoyl halides and boronic acids. D. D. Dolliver, C. Poche, J. E. Johnson, A. S. McKim
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94-TECH
TECHNICAL PROGRAM 145. Optimization of the microwave-assisted Suzuki coupling reaction of 2,6-dichloropyridine with phenyl boronic acid. M. W. Thompson, N. S. Finney 146. Pd-catalyzed aryl boronic acid homocoupling applied to an iterative synthesis of eumelanin. M. J. Brenner, J. M. Belitsky 147. Palladium-catalyzed arylation of sulfon amides. J. B. Grimm, M. H. Katcher, A. B. Northrup, D. J. Witter 148. Palladium-catalyzed C-H activation of amide derivatives. O. Daugulis, D. Shabashov 149. Palladium-catalyzed Suzuki-Miryaura coupling reactions using neopentylphosphines. W. S. Brown, E. Pair, Q. Sonnier, M. Khan, K. H. Shaughnessy 150. Palladium-catalyzed tandem/domino reactions of 1,2-dihaloarenes and 2-haloaryl tosylates with hindered Grignard reagents. C-G. Dong, Q-S. Hu 151. Pd(0) catalyzed intramolecular alkylation: Stereoselective synthesis of furan and isoxazoline-2-oxide analogs. P. M. Khan, R. Wu, K. S. Bisht 152. Practical copper-catalyzed carbonnitrogen bond formation of functionalized heteroaryl bromides. P. E. Wiedeman, V. S. C. Yeh 153. Radical cyclization of bromoacetates and brominated acrylates in the presence of copper(l) homoscorpionate complexes. M. N. Balili, T. Pintauer 154. Reaction of ketyl of potassium bezophenone with nitrobenzene. M. Nodira Sr., T. Dilbar 155. Reductive deoxygenation of epoxides by niobium(lll). W. E. Knabe, K. Oh 156. Room temperature ionic liquids as sol vents for Schrock's catalyst and polydimethylsiloxane membranes for facilitating separation. A. L. Miller II, N. B. Bowden 157. Solvent effects in the rhodium-catalyzed cyclization of ortho-vinyl benzaldehyde. D. V. French, A. T. Morehead Jr. 158. Sonogashira coupling in the synthesis of modified 2'-deoxyribonucleoside deriva tives. F. N. Ngassa, M. T. Van Gessel 159. Studies on the development of catalytic protocols for asymmetric allylboration of carbonyl compounds using binene based boron reagents. S. Carlson, K. V. B. Josyula 160. Studies on the development of catalytic protocols for asymmetric allylboration of carbonyl compounds using pinene based boron reagents. K. V. B. Josyula, S. C. Jonnalagadda, V. R. Mereddy 161. Studies toward efficient and selective synthesis of amphotericin B. Q. Hu, E-l. Negishi 162. Synthesis of bicyclic alkaloid cores from substituted η 2 pyridine complexes. G. W. Kosturko 163. Synthesis of Cp*CH2PPh2 and its use as a ligand for the nickel-catalyzed crosscoupling reaction of alkyl halides with aryl Grignard reagents. M. Uemura, H. Yorimitsu, K. Oshima 164. Synthesis of cyclopalladated complexes on silica gel. I. P. Smoliakova, J. L. Wood, R. Y. Mawo 165. Unusual lability and stability of haloarenes in the presence of n-BuLi. D. Slocum, T. Reece, J. Bolton, S. Parmley, P. Whitley 166. Use of asymmetrical diyne formation en route to 3-D hydrocarbon cages. T. M. Mitzel, K. Spencer 167. Use of solvent conditions to control functional group formation in indium pro moted coupling reactions. T. M. Mitzel, T. Scarella, R. Suflas 168. Accelerating effects of N-methylformamide with respect to aqueous and organic conditions in indium metal pro moted coupling reactions. T. M. Mitzel, K. Frimpong 169. Zinc bromide-mediated syn additions to 4-epoxypentenosides: Stereoselective syntheses of L-idosides. G. Cheng, R-H. Fan, J. M. Hernandez-Torres, F. P. Boulineau, A. Wei 170. Zirconium mediated intramolecular hydroamination of aminoalkenes. S. Majumder, D. Swartz, A. L. Odom 171. Higher poly(acene)s: Hexacene and heptacene from their photoprecursors. · R. Mondai, B. K. Shah, D. C. Neckers
172. Superacid-catalyzed aza-Nazarov reac tions. D. A. Klumpp, Y. Zhang, P. J. Kindelin, M. J. O'Connor, P. M. Esteves, L. S. de Almeida 173. Synthesis of a water soluble [6]-semirubin. S. K. Dey, D. A. Lightner 174. Synthetic and biological studies of a key enzyme inhibitor in the detoxification cycle of Mycobacterium tuberculosis. C. J. Lovely, L. A. Schmid 175. Advances in Prins methodology: Synthe sis of novel azacycles. R. J. Parker, A. P. Dobbs, J. Skidmore 176. Synthesis and reactivity of Rh complexes with hindered pyrazole ligands. S. Neravetla, R. E. Hurt, D. B. Grotjahn 177. Synthesis of the first α-lactam containing an extra functional group at position 1. C. Burke, E. Ladyzhenskiy, V. O. Cesare 178. Synthesis, characterization and biological activity screenings of substituted phenyl azo coumarins and Schiff's bases. N. K. Sharma, A. Naqvi, S. Khan, P. K. Sharma, D. S. Seth 179. Synthesis, DFT and X-ray diffraction study of the first monoindeno-fused corannulene. A. S. Filatov, E. A. Jackson, L. T. Scott, M. A. Petrukhina 180. Toward synthesis of bis-semirubins. S. Datta, D. A. Lightner 181. Trapping the carbonyl oxide: Implications for the mechanism of ozonolysis in the presence of dimethylformamide. S. A. Vincent, M. D. Mosher 182. Unprecedented meso-alkylidenylporphyrinoids and their expanded analogs. C-H. Lee, S-D. Jeong, S-J. Hong, K. Park 183. Using acetoacetamides in the syntheses of pyrrole amides. M. T. Huggins, P. Barber 184. Synthesis and nonlinear optical proper ties of new substituted thiaheterohelicenes and their derivatives. Y. Hu, D. Evgeny, B. Wex, D. C. Neckers 185. Superacid-promoted Knorr cyclizations: Synthetic and mechanistic studies. D. A. Klumpp, K. K. Solingapuram sai 186. Synthesis and characterization of phenothiazine based photosensitizers for photodynamic therapy (PDT). P. B. Sanjeevaiah, D. S. Crumrine 187. Synthesis and characterization of squaraine dye-folic acid complex for photodynamic therapy (PDT). B. M. Zaitoun, D. S. Crumrine 188. Practical and large scale procedures for the synthesis of achiral and chiral benzoxaboroles. S. C. Jonnalagadda, D. Gunasekera, K. V. B. Josyula, P. Kiprof, V. R. Mereddy 189. Progress toward polyhydroxykekulene and zig-zag polyacenol through the syn theses of 4-dimethoxy-3,5-bis(carbomethoxymethyl)-cyclohexanone and 4-dimethoxy-3-carbomethoxymethyl-5cyclohexenone. K. Kratz, I. D. Reingold 190. Progress toward the synthesis of Phenanthrene-1,5,10-triol. C.J. Bowerman, I. D. Reingold 191. Progress toward the synthesis of 1,5methylenesemibullvalene: The first neutral bishomoaromatic compound. W. D. Carroll, I. D. Reingold 192. Rational synthesis of a 2-methyl N-confused porphyrin. A. L. Von Ruden, T. D. Lash 193. Reactions of amine nucleophiles with naphthalirnides and naphthalic anhydrides. L. L. Groess, D. E. Lewis 194. Stereoselective three component cou pling of aromatic aldehydes with proline: efficient synthesis of highly substituted oxazolidines. S. C. Jonnalagadda, V. Gyimah, V. R. Mereddy 195. New benzothiazines derived from dimethylsulfoximine. M. Harmata, C. Huang 196. New synthesis of alkylthioindoles without using thiols. H. Suzuki, Y. Mori, Y. Kasahara, K. Sawada, T. Hamashima, Y. Kamei, H. Okuno 197. Non-covalent interactions in heteroaromatic molecules. P. Kundu, J. F. Capitani, A. Mitra, P. J. Seaton 198. Novel routes to 3,5-disubstituted A2-isoxazolines. M. D. Mosher, A. L. Norman, K. A. Shurrush 199. One-pot synthesis of spiro(indoline-2,5'isoxazolines) and spiro(indoline-2,5'pyrazolines) via 1,3-dipolar cycloaddition. S. Dadiboyena, A. T. Hamme II
200. meso-Tetraaryloxybenziporphyrins, versatile ligands for organometallic chem istry. J. A. El-Beck, T. D. Lash 201. Microwave-assisted Clauson-Kass syn thesis of pyrroles. D. M. Ketcha, B. K. Southerland, N. Marketwala, T. Freeman 202. Microwave-assisted deprotection of N-(arylsulfonyl) indoles and pyrroles employing polymersupported base. D. M. Ketcha, P. Seymour, B. G. VanNess, B. K. Southerland 203. Microwave-assisted Diels-Alder cycload dition of 1 -(phenylsulfonyl)pyrrole with acetylenic dienophiles. D. M. Ketcha, B. G. VanNess, H. Tuerdi 204. Microwave-assisted Piloty-Robinson synthesis of 3,4-disubstituted pyrroles. K. A. Scheldt, B. Milgram, K. Eskildsen, W. R. Scheldt, S. Richter 205. Microwave-promoted assembly of cyclopentadienyl-cobalt complexes from substi tuted acetylenes. E. M. Harcourt, D. G. Hamilton 206. Efficient synthesis of 1,3,4,5-substituted pyrazoles under microwave irradiation. R. Kakarla, G. Li, S. W. Gerritz 207. Facile access to a range of heterocyclic chemo-types via a novel combination of flow hydrogénation and microwave incubation processes. A. G. Godfrey, T. Masquelin, C. Hulme 208. Convenient synthesis toward chiral tryptophan and its analogs. N. Uddin, M. S. Islam, R. C. Todd, M. M. Hossain 209. Facile synthesis of (3-Bromophenyl)bis(4-fluorophenyl)phosphine oxide and 3-bromo-3',5'-Difluoro diphenyl sulfone: Monomers for functionalized poly(arylene ether)s. B. S. Werry, E. Fossum 210. Effects of photoinduced electron transfer on fluorescence emission from perylenedicarboximides. S-W. Tarn-Chang, L. Huang 211. Facile synthesis of novel fused pyrimidines. R. B. Toche, B. K. Ghotekar, M. A. Kazi, D. B. Kendre, M. N. Jachak, R. W. Sabnis 212. Fluoride promoted conjugate addition of stabilized carbanions to silylated (Z)-2pyridine enynes: New synthesis of highly functionalized 3-substituted alkylindolizines. R. E. Sammelson, A. Hayford, C. Harrison, M. Garner, O. McClyde 213. Henry (nitroaldol) strategies for the synthesis of heterocyclic compounds. F. A. Luzzio, D. Y. Duveau, J. P. Ott 214. Influencing diastereoselectivity in the synthesis of acylpyrrolidines via an azaCope rearrangement—Mannich cyclization: Effects of reaction conditions, substrate structure, and aldehyde structure. W. A. Turley, E. L. Marrero, H. A. Lindsay 215. Interfacing chemistry with medicine: Designing heterocyclic libraries for pilot scale studies. R. D. Carpenter, K. S. Lam, M. J. Kurth 216. Intramolecular [2+2] cycloaddition approaches toward multi-substituted tetrahydrofurans. J. J. Labuda, K. Oh 217. A simple synthesis of 2,4-quinazolindiones and thio-equivalents. Y. Zhang, K. Massey, Z. Wang 218. An approach to the synthesis of amphorogynine D and related alkaloids. B. F. Johnson, H. A. Lindsay 219. An efficient one-pot synthesis of N-sulfonyl pyrroles, indoles and carbazoles via successive annelation. L. Teixeira, A. Mohammed, B. Tôrôk 220. A novel one-pot synthesis of N-acylindoles by tandem cyclialkylation/annelation of primary aromatic amides. O. De Paolis, A. Mohammed, B. Tôrôk 221. Novel one-pot synthesis of 1,3,5-Triphenylpyrazoles by microwave assisted solvent-free bifunctional catalysis. A. Schmidt, S. M. Landge, V. Outerbridge, B. Tôrôk 222. Benzo-fused heterocycles and carbocycles by intramolecular SNAr and tandem SN2-SNAr reactions. R. A. Bunce, T. Nago, N. Sonobe 223. Bicorannulenyl: DFT and crystallographic description of a novel corannulene derivative. A. S. Filatov, E. A. Jackson, L. T. Scott, M. A. Petrukhina 224. Boron dipyrromethene fluorescent probes for bioorthogonal labeling. O. Dilek, S. Bane
ORGN 225. Bransted acid catalyzed reactions of salicylaldehydes to benzo[b]furan-3-ethyl ester derivatives. M. E. Dudley, M. Hossain, M. M. Morshed 226. Study on transport and transformation of sulfadiazine in soil. W. Chunbo, Z. Congliang, W. Yan 227. Measurement and temperature depen dence of n-octanol-water partitioning coefficients for seven sulfonamides from (298.15 to 333.15) Κ. Z. Congliang, W. Yan, W. Fuan MONDAY MORNING Section A McCormick Place Lakeside Room E450 A/B, Level 4 Herbert C. Brown Award for Creative Research in Synthetic Methods: Symposium in Honor of David A. Evans Β. Β. Snider,
Section Β McCormick Place Lakeside Room E451 A/B, Level 4 Nakanishi Prize: Symposium in Honor of Hung-wen Liu Cosponsored with BIOL Organizer
8:15 Welcoming Remarks. 8:20 232. Thiamin: A simple vitamin with a complex biosynthetic pathway. T. P. Begley 9:10 233. Posttranslationally modified antimi crobial peptides. W. van der Donk 10:00 234. Novel features of natural product assembly line enzymology. C. T. Walsh 10:50 Introduction of Awardee. 11:00 235. Award Address (Nakanishi Prize, sponsored by The Nakanishi Prize Endowment). Biosynthetic and mechanistic studies of natural products. H-W. Liu 12:00 Concluding Remarks. Section C McCormick Place East Room E350, Level 3 Combinatorial and Process Chemistry B. McKittrick,
Presiding
8:00 236. Synthesis and separation of capreomycin analogs. D. D. Hennings, D. J. Watson, J. Lyssikatos 8:20 237. Process development of the CCK2 receptor ligand. L. Anzalone, A. F. Abdel-Magid, J. Cohen, S. Mehrman, F. J. Villani Jr. 8:40 238. Development of a scalable syn thetic process for DG-041, a potent EP3 receptor antagonist. S. Zegar, C. Tokar, L. Enache, W. Zeller, M. O'Connell, J. Singh, F. W. Muellner, D. E. Zembower 9:00 239. Combinatorial synthesis within continuous flow reactors. P. Watts, C. Wiles 9:20 240. Applications of polymer-bound phosphitylating reagents in the synthesis of organophosphorus compounds. Y. Ahmadibeni, M. Hanley, Η. Κ. Agarwal, K. Parang 9:40 241. Asymmetric synthesis using poly mer supported chiral auxiliaries. S. D. Bull, R. Green, M. Cheeseman, A. T. Merritt
3:05 260. Synthetic studies on conforma tional switches and natural products. U. Koert 3:50 Inroduction of Awardee. 3:55 261. Award Address (ACS Award for Creative Work in Synthetic Organic Chem istry, sponsored by Aldrich Chemical Company, Inc). Natural product synthesis: A stimulus for discovery. S. V. Ley Section Β McCormick Place Lakeside Room E451A/B, Level 4 Ronald Breslow Award for Achievement in Biomimetic Chemistry: Symposium in Honor of Francois Diederich
Section D
N. S. Goroff,
McCormick Place Lakeside RoomE351, Level 3
1:30 Introductory Remarks. 1:35 262. Reversible encapsulation. J. RebekJr. 2:20 263. Fabrication of anisotropic materials via molecular self-organization. S-W. Tarn-Chang, W. Seo, K. Rove, L. Huang, J. Helbley 3:05 264. Bioinspired supramolecular poly mer chemistry. S. C. Zimmerman, D. W. Kuykendall, H. Ong, T. Park 3:50 Introduction of Awardee. 4:00 265. Award Address (Ronald Breslow Award for Achievement in Biomimetic Chemistry, sponsored by The Ronald Breslow Endowment). Molecular recogni tion in chemistry and biology. F. Diederich
Presiding
8:30 Introductory Remarks. 8:35 228. Understanding selective yet gen eral chiral catalysts. E. N. Jacobsen 9:20 229. N-Heterocyclic carbenes in cataly sis and other reactions. F. Glorius 10:05 230. Design and synthesis of selective DPP-4 inhibitors: Discovery of JANUVIA™ (sitagliptin), a new treatment for type 2 diabetes. A. E. Weber 10:50 Introduction of Awardee. 11:00 231. Award Address (Herbert C. Brown Award for Creative Research in Synthetic Methods, sponsored by The Herbert C. Brown Award Endowment). Two decades of research on the DielsAlder reaction. D. A. Evans
S. Krane,
10:00 242. Multipolymer catalytic aerobic oxidation reactions of primary alcohols. P. H. Toy, C. W. Y. Chung 10:20 243. Solid-supported [2+2+2] cyclotrimerization reactions in the combinatorial assembly of functional molecules. A. Deiters 10:40 244. Synthesis and DNA interactions of novel substituted cyclam metal com plexes. A. V. Ramana, M. H. Todd, T. Paine 11:00 245. Exploring new chemical reactions on self-assembled monolayers of alkanthiolates on gold by SAMDI-MS. J. Li, M. Mrksich 11:20 246. Synthesis and label-free analysis of peptide arrays on self-assembled mono layers. A. H. Eisenberg, S. Kigar, M. Mrksich
New Reactions and Methodology Β. Κ. Banik,
Presiding
8:00 247. Lithium hexafluoroisopropoxide as a mild base for Horner-Wadsworth-Emmons olefinations of epimerizable alde hydes. L. K. Blasdel, A. G. Myers 8:20 248. Metathesis in new solvents - ionic liquids and polydimethylsiloxane - to introduce new selectivities and reactions. M. B. Runge, M. T. Mwangi, A. L Miller II, Ν. Β. Bowden 8:40 249. Polymer-supported azidoproazaphosphatrane: A reusable catalyst for 1,4 additions at room-temperature. V. R. Chinta Reddy, J. G. Verkade 9:00 250. Proazaphosphatranes: Highly effective non-ionic nucleophilic base cata lysts for the trifluoromethylation of carbonyl compounds. V. R. Chinta Reddy, J. G. Verkade 9:20 251. New synthetic methods to chiral oxazolidinones and oxazinanones. J. R. Ella-Menye, G. Wang 9:40 252. Nucleophilic acylation of quinone methides: An Umpolung strategy for the synthesis of α-aryl ketones. K. A. Scheldt, A. E. Mattson 10:00 253. Near-infrared fluorescent bisphosphonates: Synthesis and in vivo optical imaging of breast cancer microcal cification. K. R. Bhushan, R. E. Lenkinski, J. V. Frangioni 10:20 254. Near-infrared/magnetic reso nance dual contrast agents for imaging breast cancer microcalcification. Κ. R. Bhushan, R. E. Lenkinski, J. V. Frangioni 10:40 255. Oxidative rearrangements of arylalkanones with 1H-1-hydroxy-5-methyl1,2,3-benziodoxathiole 3,3-dioxide, a green alternative to Koser's reagent. M. W. Justik 11:00 256. Selective electrochemical dechlo rination of halopyridines. C. Wang, C. Scortichini 11:20 257. Practical β-lactone synthesis: Epoxide carbonylation at 1 atm. J. W. Kramer, E. B. Lobkovsky, G. W. Coates Landmark Stable Free Radicals of the 20th Century Sponsored by HIST, Cosponsored with ORGN MONDAY AFTERNOON Section A McCormick Place Lakeside Room E450 A/B, Level 4
Presiding
Section C McCormick Place Lakeside Room E350, Level 3 Asymmetric Syntheis of α-Amino Acids: Novel Developments and Future Directions V. A. Soloshonok and K. Izawa, Organizers 1:00 Introductory Remarks. 1:05 266. Recent developments in the appli cation of organometallic chemistry to amino acid synthesis. R. F. W. Jackson 1:30 267. Looking for efficiency in the prepa ration of heterocycle-tethered C-glycosyl amino acids via multicomponent reactions and 1,3-dipolar cycloadditions. A. Dondoni 1:55 268. Total synthesis of natural products possessing α,α-disubstituted α-amino acid substructure. Y. Ohfune 2:20 269. Synthesis of optically active α-methyl amino acids utilizing biotransfor mation as a key step. M. Yatagai, T. Hamada, H. Nozaki, S. Kuroda, K. Yokozeki, K. Izawa 2:45 270. New tricks in amino acid synthesis: Applications to complex natural products. R. M. Williams 3:10 271. Design of simple, yet very active chiral phase transfer catalysts for practical amino acid synthesis. K. Maruoka 3:35 272. Asymmetric synthesis of amino acids with a tetrasubstituted carbon center via memory of chirality. T. Kawabata 4:00 273. Production of α-amino acids using recombinant whole-cell catalysts. W. Wienand 4:25 274. The large scale synthesis of amino acids: So which catalyst is best? D. J. Ager 4:50 275. Integrated solution of non-natural aliphatic α-amino acid. M. Sugawara, M. Yamada 5:15 276. Unnatural amino acids in natural products and enzyme inhibitors. S. Hanessian, K. Ersmark, J. Del Valle
ACS Award for Creative Work in Synthetic Organic Chemistry: Symposium in Honor of Steven V. Ley H. M. L. Davies,
Organizer
1:30 Introductory Remarks. 1:35 258. C-H bond functionalization in organic synthesis. M. S. Sanford 2:20 259. Metal and non-metal catalysis for asymmetric synthesis. H. Yamamoto
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section D McCormick Place East Room E351, Level 3 New Reactions and Methodology U. Iserloh,
Presiding
1:00 277. Lewis acid-catalyzed 1,2-alkyl shift in allenyl ketones: Synthesis of multisubstituted furans. A. S. Dudnik, V. Gevorgyan 1:20 278. N-Fused 1,2,3-triazoles in the metal-carbenoid mediated syntheses of heteroaromatic compounds. S. N. Chuprakov, V. Gevorgyan 1:40 279. Unprecedented palladium-cata lyzed bicyclizations of dinitrostyrenes: Synthesis of pyrroloindoles. S. R. Banini, B. C. G. Soderberg 2:00 280. Lithium in alumina: A new entry to solid state organolithium reagents. P. Nandi, J. L. Dye, J. E. Jackson, P. Bentley, M. Lefenfeld 2:20 281. Modification of catalysts and reagents by combination of hydrophilic triazoles and hydrophobic perfluoroalkyl chains. A. Gheorghe, E. Cuevas-Yanez, O. Reiser 2:40 282. Multinuclear DOSY studies of organometallic systems. D. Li, J. Liu, P. G. Williard 3:00 283. New advances in N-heterocyclic carbene catalysis. K. A. Scheldt, A. Chan 3:20 284. New highly active Ruthenium catalysts for metathesis reactions. Z-Y. J. Zhan, G-Y. Zhang, D-W. Cui 3:40 285. Regioselective Barbier reactions of 2-Bromomethylcyclohexenone and intra molecular reductive cyclization reactions of the resulting products. R. N. Manchanayakage, S. T. Handy 4:00 286. Synthesis of fused pyrrolo-heterocycles via novel gold-catalyzed cascade transformation involving 1,2-migration of silicon, tin, and germanium. I. V. Seregin, V. Gevorgyan 4:20 287. Transition metal-catalyzed hydroand metal-metalation of cyclopropenes: Easy access to multisubstituted cyclopro panes. A. Trofimov, V. Gevorgyan Section Ε McCormick Place East Room E352, Level 3 Total Synthesis of Complex Molecules C. Maryanoff,
Presiding
1:00 288. Ritterazine natural products: Syn thesis, mechanistic studies, and reassign ment of the 5,5-spiroketal stereochemistry of ritterazines Β and F. S. T. Phillips, M. D. Shair 1:20 289. Approaches to the synthesis of the Cyclipostins and some phosphonate analogs. S. Bandyopadhyay, C. D. Spilling 1:40 290. Hydrocarbons to sugars. D. J. Covell, N. A. Vermeulen, M. C. White 2:00 291. Amino alcohols as potent organocatalysts in asymmetric aldol condensa tion: An enantioselective synthesis of Convolutamydine A. A. V. Malkov, M. Bella, M. A. Kabeshov, D. A. Malyshev, A. Parkin, P. Kocovsky 2:20 292. Approach to the total synthesis of Massileunicellin C. M. C. Mcintosh, Y. Chai, Z. Mou, T. D. Bateman 2:40 293. Asymmetric total synthesis and formal total synthesis of (+)-Eremantholide A. K. J. Hale, Y. Li 3:00 294. Bistramide A: Development of the pharmacophore model. S. A. Rizvi, S. A. Kozmin 3:20 295. Chasing molecules that were never there: Adventures in natural product synthesis and structure elucidation. J. W. Burton, H. M. Sheldrake, C. Jamieson, P. A. Broadwith 3:40 296. Development of practical, stereos elective synthesis of Spirofungin A. J. Marjanovic, S. A. Kozmin 4:00 297. Enantioselective synthesis of (—)-lobeline via desymmetrization. H. Jiang, X. Li, V. B. Birman 4:20 298. Enantioselective total synthesis of the osteoclastogenesis inhibitor (+)-symbioimine. R. J. Thomson, J. Kim
TECH-95
TEGHNICAL PROGRAM
ORGN MONDAY EVENING
Section C
Section Ε
Section C
Section A
McCormick Place Lakeside Room E350, Level 3
McCormick Place Lakeside Room E352, Level 3
McCormick Place East Room E350, Level 3
Hyatt Regency Chicago Riverside Center
Heterocycles and Aromatics
Total Synthesis of Complex Molecules
Heterocycles and Aromatics
Sci-Mix
Y. W u ,
J. S. Johnson,
S. M. Sieburth, Organizer
8:00 308. Synthesis of pyrazolo[1,5-a]pyrimidine regioisomers. A. Lee, L. K. Gavrin, B. A. Provencher, J. C. McKew 8:20 309. 1, 3-Dipolar cycloadditons of TMS diazomethane revisited. K. Rein, D. Simovic 8:40 310. A new synthetic route to 2,2'Bipyrroles. L. Jiao, Κ. Μ. Smith 9:00 311. A synthetic organic approach to uniform carbon nanotubes: Significant progress toward two armchair targets. E. A. Jackson, L. T. Scott 9:20 312. Dynamic covalent chemistry of boron-containing heteroaromatic systems. D. Philp 9:40 313. Effects of substituents on the electronic transition and fluorescence properties of perylenedicarboximides and perylenebis(dicarboximide)s. S-W. Tarn-Chang, L. Huang, T. D. Carson, G. Aryal 10:00 314. New synthesis of bacteriochlorins. W. G. O'Neal, P. A. Jacobi 10:20 315. Rothemund, 3+1 and calixazulene chemistry with 6-tert-butylazulene and 6-methylazulene. D. J. Phillips 10:40 316. Strategic combination of SuzukiMiyaura cross-coupling and olefin met athesis for benzoannulation strategy and synthesis of 1-benzazepine derivatives. S. Kotha, V. R. Shah 11:00 317. Synthesis and functionalization of azaspiro[4.5]decanes. R. Dalvi, F. C. Pigge 11:20 318. Synthesis and properties of methoxy bilirubin. S. K. Dey, D. A. Lightner 11:40 319. Synthesis of multi substituted 3-fluoro furans and 3,3-difluro hydrofurans. S. Arimitsu, J. M. Jacobsen, G. B. Hammond
8:00-10:00 69, 76, 88, 92, 96,111, 121, 143,156, 160, 166,171-172,174,191. See previous listinns
392, 398, 401, 405, 421, 430, 432, 448, 450, 454, 459, 481, 484, 497, 499, 514, 525, 620, 636-637, 648, 665-666, 675, 678, 692, 694, 706, 726, 737-738. See subsequent listings. TUESDAY MORNING Section A McCormick Place Lakeside Room E450 A/B, Level 4 ACS Award in Organometallic Chemistry: Symposium in Honor of David Milstein Cosponsored with I NOR K. M. Brummond,
Organizer
9:00 299. Selective organic and organome tallic transformations mediated by molecu lar and supramolecular environments. R. G. Bergman 9:40 300. New studies of iridium complexes relating to catalysis. M. Janka, D. J. Fox, A. C. Atesin, B. P. Gilmartin, A. J. Frontier, W. He, R. Eisenberg 10:20 301. Recent advances in stereoselec tive synthesis mediated by organometallic derivatives. I. Marek 11:00 Introduction of Awardee. 11:05 302. Award Address (ACS Award in Organometallic Chemistry, sponsored by The Dow Chemical Company Foundation). Endeavors in bond activation and cataly sis. D. Milstein
Presiding
Section D
New Reactions and Methodology
National Fresenius Award: Symposium in Honor of Phil S. Baran M. P. Sibi,
Organizer
8:00 303. A toolbox of hydrocarbon oxidation methods for synthesis. M. C. White 8:40 304. From targets to strategies and back again: Some examples from complex molecule synthesis. A. J. Phillips 9:20 305. Directed C-H activation reactions using Pd(ll) and Cu(ll) catalysts: Regioselectivity, stereoselectivity and catalytic turnover. J-Q. Yu, R. Giri, X. Chen 10:00 306. Total synthesis of amphidinolide E. W. R. Roush, P. J. Va 11:00 307. Award Address (National Frese nius Award, sponsored by Phi Lambda Upsilon, the National Chemistry Honor Society). The catalytic cycle of discovery in total synthesis. P. S. Baran
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
96-TECH
A. W . Stamford,
TUESDAY AFTERNOON Section A McCormick Place Lakeside Room E450 A/B, Level 4
McCormick Place Lakeside Room E351, Level 3
Section Β McCormick Place Lakeside Room E451 A/B, Level 4
Presiding
8:00 331. Studies directed toward the total synthesis of pederin. J. C Jewett, V. H. Rawal 8:20 332. Synthetic studies toward N-methyl welwitindolinone C isothiocyanate. V. Bhat, J. A. MacKay, V. H. Rawal 8:40 333. Synthetic studies toward hapalindoles. A. Davé, V. H. Rawal 9:00 334. Syntheses of complex tumor associated carbohydrate antigens. A. Miermont, Y. Jing, X. Huang 9:20 335. Synthetic studies directed toward the total synthesis of Okilactomycin and Chrolactornycin. K. A. Scheldt, W. J . Morris, D. W. Custar 9:40 336. Total syntheses of (±)-frondosin C and (±)-8-epi-frondosin C. T. V. Ovaska, X. Li, R. E. Kyne 10:00 337. Total synthesis efforts toward Cylindrospermopsin. J. Hang, Y. Shi, D. Y. Gin 10:20 338. Total synthesis of Aeruginosin 298-A analogs. G. Wang, X. Nie 10:40 339. Total synthesis of guaianolides. A. Schall, S. Kalidindi, W-B. Jeong, S. Mathai, D. Laventine, B. Nosse, R. Bandicchor, O. Reiser 11:00 340. Total synthesis of Papulacandin D. S. E. Denmark, C S. Regens, T. Kobayashi 11:20 341. Total synthesis of prekinamycin and progress toward kinamycins. Z. Zhao, L. Guo, V. B. Birman
Elias J. Corey Award for Outstanding Original Contribution in Organic Synthesis by a Young Investigator: Symposium in Honor of Michael J. Krische
Presiding
8:15 320. Gallium triflate catalyzed direct reductive amination of aldehydes. G. K. S. Prakash, T. Mathew, C. Do, C. Panja, G. A. Olah 8:35 321. Efficient one-pot synthesis of novel fluorinated heterocycles using trimethylsilyl trifluoromethanesulfonate as a metal-free, homogeneous, strong Lewis acid catalyst. G. K. S. Prakash, C Panja, C. Do, T. Mathew, G. A. Olah 8:55 322. Symbiotic reagent activation: Meerwein-Ponndorf-Verley reduction of silylglyoxylates by a magnesium alkoxides triggers second-stage aldolization. A. D. Satterfield, J. S. Johnson, X. Linghu 9:15 323. Accelerated reactions using nucleophile assisting leaving groups (NALGs): Applications to stereospecific alkyl halide synthesis. S. D. Lepore, D. Mondai, S. Li 9:35 324. An efficient C-C bond cleavage of 1,2-diols using tetraethylammonium super oxide. K. N. Singh, R. Kumar, M. Verma 9:55 325. Application of sulfur ylide technolo gies. D. C Forbes 10:15 326. Catalytic sp 3 C-H bond function alization: New developments in the direct α-arylation of (cyclic) saturated amines. M. Schniirch, D. V. Gribkov, S. J. Pastine, D. Sames 10:35 327. Cation radical [4 + 3] cycloaddi tions. D. H. Murray 10:55 328. Diastereoselective acyclic allylic diazene rearrangement. W. Qi, M. C. Mcintosh 11:15 329. Functionalization of the unactivated carbon-hydrogen bond via ozona tion. B. Rindone, F. Saliu 11:35 330. Homolytic substitution at sulfur: Radical synthesis of oxidized sulfur hetero cycles. E. Lacôte, L. Fensterbank, M. Malacria, J. Coulomb, V. Certal
K. Burgess,
Organizer
1:15 342. Recent developments in nickelcatalyzed reactions. J. Montgomery 1:55 343. Catalytic enantioselective annulations. J. W. Bode 2:35 344. New strategies in carbonyl umpolung. J. S. Johnson 3:15 345. Catalytic asymmetric C-C and C-N bond forming reactions. T. Rovis 3:55 346. Award Address (Elias J. Corey Award for Outstanding Original Contribution in Organic Synthesis by a Young Investigator, sponsored by The Pfizer Endowment Fund). Formation of C-C bonds via catalytic hydrogénation. M. J . Krische Section Β McCormick Place Lakeside RoomE451A/B, Level 4 Ralph F. Hirschmann Award in Peptide Chemistry: Symposium in Honor of Samuel H. Gellman S. D. Rychnovsky,
Organizer
1:15 347. Functional protein mimics based on sequence-specific peptoid foldamers. A. E. Barron 2:10 348. Folded peptides for asymmetric catalysis: Structures and functions. S. J . Miller 3:05 349. Nature vs. nurture in designed peptide structures. M. L. Waters 4:00 350. Award Address (Ralph F. Hirschmann Award in Peptide Chemistry, sponsored by Merck Research Laborato ries). From peptides to peptidic foldamers. S. H. Gellman
D. J. Phillips,
Presiding
1:00 351. Photochemical generation of highly reactive cyclic enediyne compounds. A. Polukhtine, G. Karpov, V. V. Popik 1:20 352. Aza-silyl Prins reaction: Synthesis of 1,2,5,6-tetrahydropyridines. R. J. Parker, A. P. Dobbs, J. Skidmore 1:40 353. Elegant synthesis of highly fluores cent monoarylide colorants. P. Sivarama Kumar, P. Bineesh, G. Shankarling, G. G. Pawar, V. R. Kanetkar, R. W. Sabnis 2:00 354. Synthesis of novel highly fluores cent hetero fused coumarin dyes. P. Bineesh, S. Katode, G. Shankarling, P. Sivarama Kumar, V. R. Kanetkar, R. W. Sabnis 2:20 355. Novel heterocyclic colorants derived from 3-amino-4-cyano-2-dihydropyrido[1,2-a]benzimidazol-1 -one. P. Bineesh, J. Shewale, R. Walavalkar, G. Shankarling, P. Sivarama Kumar, V. R. Kanetkar, R. W. Sabnis 2:40 356. Nucleophilic addition to a p-benzyne derived from an enediyne: A new mechanism for halide incorporation into aromatics. C. L. Perrin, B. L. Rodgers, W. Fenical, J. M. O'Connor 3:00 357. Oxacalixarene-linked porphyrins and their analogs. E. Hao, L. Jiao, F. R. Fronczek, K. M. Smith, M. G. H. Vicente 3:20 358. Preparation of 1,2,3-triazolecontaining multidentate chelators. J. T. Fletcher, B. J. Bumgamer, N. D. Engels 3:40 359. Toward the synthesis of a molecu lar trefoil knot. E. Zysman-Colman, K. Arias, J. C. Loren, A. Linden, J. S. Siegel 4:00 360. [3+2] Cycloadditions of ynamides to synthesize functionalized pyrazoles and triazoles. L. You, R. P. Hsung, X. Zhang, H.Li 4:20 361. Synthesis and application of 3-arylazo-1 H-pyrazolo[3,4-b]quinoxaline based disperse dyes. G. Shankarling, D. W. Rangnekar, V. R. Kanetkar, P. Bineesh, P. Sivaramkumar, R. W. Sabnis 4:40 362. Synthesis and application of 3-arylazo-4-cyano-5-(4-nitrophenyl)-1H-pyrazole based disperse dyes. G. Shankarling, D. W. Rangnekar, V. R. Kanetkar, P. Bineesh, P. Sivaramkumar, R. W. Sabnis Section D McCormick Place East Room E351, Level 3 Asymmetric Reactions and Syntheses B. Kenney,
Presiding
1:00 363. Catalytic asymmetric carboncarbon bond formation with Grignard reagents. B. L. Feringa 1:20 364. {alpha}-TMS-propargylic carbamines via asymmetric allenylboration. A. Z. Gonzalez, J. A. Soderquist 1:40 365. New silicon-based chiral derivatizing agents. J. R. Gonzalez, J. A. Soderquist 2:00 366. Application of virtual ligand screen ing methods for asymmetric, rhodium catalyzed hydrogénations of enamides. P. J. Donoghue, O. Wiest, P-O. Norrby, P. Helquist 2:20 367. Catalytic activity of nonaromatic amidine derivatives in acylation reactions. X. Li, Z. Han, V. B. Birman 2:40 368. Catalytic asymmetric Claisen rearrangement: Development and application. M. Hiersemann 3:00 369. Highly antiselective dihydroxylations of 1,2-dialkyl substituted (2)-allylic amines. Y. G. Kim, J. Jeon, M. Shin, J. W. Yoo, J. S. Oh, J. G. Bae, S. H. Jung 3:20 370. Highly enantioselective catalytic indium-mediated allylation of hydrazones. G. R. Cook, R. Kargbo
ORGN 3:40 371. Ir-catalyzed enantioselective allylation of enamines. D. J. Weix, J. F. Hartwig 4:00 372. Palladium-catalyzed enantioselective diboration of prochiral aliènes: Catalyst development and mechanism. H. E. Burks, J. P. Morken 4:20 373. Lewis acid mediated highly selective halogenation of silyl enolates and aromatic compounds. Y. Zhang, H. Yamamoto 4:40 374. Development and application of bis-hydroxamic acid (BHA)-molybdenum complexes to perform catalytic asymmetric oxidation of olefins and sulfides. H. Yamamoto, A. Barlan Section Ε McCormick Place East Room E352, Level 3 Total Synthesis of Complex Molecules A. B. Cooper,
Presiding
1:00 375. Studies toward the total synthesis of related icetexone and anastomosine natural products. J. L. Grove, G. F. Majetich 1:20 376. Asymmetric total syntheses of salviasperanol, brussonol, demethylsavicanol and grandione. G. F. Majetich, G. Zou 1:40 377. Total synthesis of (-)-himgaline. U. Shah, S. Chackalamannil, A. K. Ganguly, M. V. Chelliah, S. Kolotuchin, A. Buevich, A. T. McPhail 2:00 378. Role of the C7-hydroxy group in epothilone D. X. Zhang, R. E. Taylor 2:20 379. Structure-activity relationship study of myriaporones. M. Roy, R. E. Taylor 2:40 380. Studies toward cyclic guanidine synthesis pertinent to axinellamine and palau'amine. L Tang, D. Romo 3:00 381. Studies toward oroidin-derived alkaloids. S. Wang, D. Romo 3:20 382. Studies toward the synthesis of aerothionin and related natural products. S. Bardhan, J. A. Porco Jr. 3:40 383. Studies toward the synthesis of polyisoprenylated phloroglucinol natural products. J . Qi, J. A. Porco Jr. 4:00 384. Studies toward the total synthesis of (+)-aigialospirol. R. Figueroa, R. P. Hsung 4:20 385. Studies toward the synthesis and structure elucidatiuon of chamuvarinin. V. Reddy, G. J. Florence T U E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center New Reactions and Methodology, Total Synthesis, Materials, Devices and Switches, Lipids, Nucleotides and Mimetics S. M. Sieburth,
Organizer
8:00-10:00 386. Building blocks for polyamide synthesis: N-formamido-containing mono- and diheterocyclic pyrrole- and imidazole-2-carboxylic acids. J. Sexton, Z. Taherbhai, P. Nolan, J. Jones, P. Uthe, T. Brown, M.Lee 387. Tetrakis (triphenylphosphine) palladium (0): An investigation of stability and reac tivity. R. C. Todd, J. Kubeika, K. V. B. Josyula, P. Gao 388. A universal chemoenzymatic method for nanostructure assembly. B. P. Duckworth, J. Xu, T. A. Taton, M. D. Distefano 389. Design, synthesis, and antiviral evalua tion of some 3'-carboxymethyl-3'-deoxyadenosine derivatives. H. Shi, P. Ke, M. A. Peterson 390. Efficient synthesis of carboxyethyl pyrrole derivatives. L. Lu, R. G. Salomon 391. Highly enhanced enzymatic regioselective benzoylation of 1-/ibefaj-D-arabinofuranosylcytosine with an ionic liquid-contain ing medium. Z. Y. Tan, M. H. Zong 392. Modifying the bicyclo[3.1.0]hexane pseudosugar ring of carbocyclic nucleosides to improve recognition by herpes thymidine kinase. M. J. Comin, V. E. Marquez
393. Synthesis of 2'-methoxyl-3'-thioguanosine phosphoramidite. J . Lu, N-S. Li, J. A. Piccirilli 394. Novel method for the synthesis of N4-methyl and hydroxy cytidine phosphoramidites. J . Lu, N-S. Li, J. A. Piccirilli 395. Synthesis of the phosphoramidite deriva tives of 2'-C-alpha-(hydroxyalkyl) and 2'-C-alpha-alkylcytidine: Analogs for prob ing solvent interactions with RNA. N-S. Li, J. A. Piccirilli 396. Structural and biochemical studies of protein prenyltransferases using a photoactivatible isoprenoid diphosphate analog containing a stable phosphonate linkage. A. J. DeGraw, Z. Zhao, H. A. Taban, W. Xie, D. K. Shintani, C. McMahan, M. D. Distefano 397. Synthesis and cryoprotection properties of L- and meso-trehalose. S-K. Seo, M. L. McClintock, A. Wei 398. Synthesis of sulfur and fluorine-contain ing fatty acid substrate analogs for studies of prostaglandin H synthases and lipoxy genases. C. Jacquot, W. A. van der Donk 399. Synthesis, oligonucleotide incorporation, and base pair stability of 9-deaza-2'deoxyguanosine: An analog of 8-oxo-2'deoxyguanosine. J. L. Carman, M. Summers, M. Hamm 400. Synthetic HDL mimics: MRI contrast agents targeted to arterial cholesterol buildup. D. P. Cormode, K. C. Briley-Saebo, J. G. S. Aguinaldo, W. J. M. Mulder, E. A. Fisher, Z. A. Fayad 401. A general scaffold for the synthesis of dysiherbaine and its analogs. C. W. Kang, S. R. Gilbertson 402. Chemical studies toward the total syn thesis of azaspirene: A novel angiogenesis inhibitor. A. El-Batta, M. Bergdahl 403. Chemoselective ruthenium mediated SNAr approach: Application in the synthe sis of vancomycin aglycon. S. Basu, A. J. Pearson 404. Design and synthesis of pyrrolo[2,1c][1,4]benzodiazepine analogs. J-J. Wang, M-K. Hsu, Y-K. Shen, W-P. Hu, Y-M. Tsai 405. Dimerization strategies for the construc tion of the central core of lomaiviticins. S. Achanta, P. Padakanti, V. B. Birman 406. Efforts toward the total synthesis of kendomycin. M. M. Jacobson, S. D. Burke 407. First total synthesis of the cis-clerodane diterpenoids solidagolactones IV and V. H-J. Liu, Y - L Ho, K-S. Shia 408. First total synthesis of the irciniasulfonic acids. A. P. Dobbs, A. Venturelli, R. J. Parker, L. Butler 409. Gold-catalyzed cycloisomerization to enable the practical approach to pleuromutilin. V. Shubinets 410. Highly efficient syntheses of hyaluronic acid oligosaccharides. X. Lu, L. Huang, B. Sun, X. Huang 411. Highly selective sialylation and total syntheses of tumor-related antigens N3 by the iterative one-pot synthesis strategy. B. Sun, Y. Zeng, X. Huang 412. Nucleotide synthesis and formation of carbamoyl phosphate from urea, pyruvate and phosphate. R. S. Bozov 413. Progress toward the total synthesis of N-methylwelwitindolinone C isothiocyanate. D. A. Allen, M. E. Jung 414. Progress toward the synthesis of (-)dictyostatin and 16-normethyldictyostatin. A. K. Dilger, V. Gopalsamuthiram, S. D. Burke 415. Progress toward the synthesis of peyssonenynes A & B. R. V. Lerum, J. D. Chisholm 416. Progress towards the total synthesis of aplyronine A. A. El-Awa, M. Noshi, P. L. Fuchs 417. Progress toward the total synthesis of axinellamine A and massadine. Ν. Μ. Hernandez, S. Rasapalli, Y. He, C. J. Lovely
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
418. Progress toward the total synthesis of the bisindole alkaloid angusticraline: Emphasis on the northern hemisphere as well as the total synthesis of other monomeric indole alkaloids. C. R. Edwankar, R. Edwankar, J. M. Cook 419. Ring opening-closing metathesis of 7-azanorbomene and the applications in the studies of total synthesis toward rostratins. Z. Liu, J. D. Rainier 420. Spirastrellolide A progress C1-C23. J. H. Yang, J. Liu, R. P. Hsung 421. Stereoselective [4 + 3] cycloadditions of nitrogen-stabilized oxyallyl cations with pyrroles: An approach to parvineostemonine. J. E. Antoline, J. Huang, Z. Song, G. Li, R. P. Hsung 422. Studies toward the total synthesis of fusidilactone C. S. K. Ghosh, Y. Wei, J. Wang, R. P. Hsung 423. Stereoselective cyclopropanation of enamides. T. Lu, Ζ. Song, R. P. Hsung, Z. F. Al-Rashid, C. Ko, Y. Tang 424. Dipolar cycloaddition of ynamides and azides. X. Zhang, H. Li, R. P. Hsung, L. You, Y. Tang 425. Synthetic studies toward the aziridinomitosene of FK317. S. Deeter, M. Kim, E. Vedejs 426. Total synthesis of laurenditerpenol. G-Y. J . Im, M. E. Jung 427. Total synthesis of schweinfurthin G. N. R. Mente, J. D. Neighbors, D. F. Wiemer 428. Toward the total synthesis of gymnasterkoreayne B. B. W. Gung, D. T. Craft 429. Toward the total synthesis of bryostatin 1 : Synthesis of the northern fragment (C1-C16). H. Seradj, E. A. Voight, S. D. Burke 430. Toward the total synthesis of hexacyclinic acid. G. A. Rolla, P. A. Clarke 431. Toward the total synthesis of teucrin A. H-J. Liu, l-C. Chen, Y-K. Wu, J-L Zhu 432. Use of a novel [ 4 + 2 ] phosphine cata lyzed annulation toward the total synthesis of corynantheine indole alkaloids. R. A. Villa, O. Kwon 433. ir-Dimer formation as the driving force for calix[4]arene-based molecular actua tors. C. Song, T. M. Swager 434. Amine-reactive fluorine-based probes: Synthesis, optical characterization, bioconjugation, and two-photon fluorescence imaging. A. R. Morales, K. D. Belfield, Z-L. Huang 435. Antiparallel coiled coil crosslinks in self-assembled β-hairpin hydrogels. R. P. Nagarkar, J. P. Schneider 436. Blue-emitting oligophenyleneethynylenes: Synthesis, characterization and effect of hydrogen-bond-assisted Il-stacking on the optical properties. N. Sanyal, P. M. Lahti 437. Carbon dioxide removal performance and evaluation of the ionomer membrane for application in an artificial lung. Z. Feng, T. Wang 438. Covalent organic frameworks. J. L. Mendoza, H. M. El-Kaderi, J. Hunt, A. P. Côté, O. M. Yaghi 439. Crystalline molecular compasses: Incorporating dipoles into volume conserving rotators. S. D. Karlen, M. A. Garcia-Garibay 440. Design and synthesis of electro-optical sensors that distinguish between organophosphorus pesticides and chemical warfare agent mimics. B. J. Engelmann, S. O. Obare 441. Dicyanomethylenedihydrofuran (DCDHF) single molecule fluorophores for cellular applications. H. Wang, Z. Lu, S. J. Lord, K. A. Willets, W. E. Moerner, R. J. Twieg 442. Dimethylaminostyryl terpyridine derivative (MNpvpt) as a luminescence pH sensor. S. Vaidya, X. Y. Wang, R. H. Schmehl 443. Effect of functionalization on acenes and their electronic properties. S. S. Subramanian, S. R. Parkin, J. E. Anthony 444. Fluorescent DNA nanotags: Supramolecular fluorescent labels based on intercalating dye arrays assembled on nanostructured DNA templates. A. L Benvin, Y. Creeger, G. W. Fisher, B. Ballou, A. S. Waggoner, B. A. Armitage 445. Imidazole-based excited state intramolecular proton transfer molecules with highly efficient fluorescence and electroluminescence emission. S. Park, J. Seo, S. H. Kim, S. Y. Park
446. Improved photosensitive polymeric materials for 3-D WORM optical data storage using two-photon fluorescent writing and readout. K. D. Belfield, C. O. Yanez, S. Yao, Z-L. Huang, C. C. Corredor 447. Rotaxane dynamics in cellular transport. J . Zhu, D. B. Smithrud 448. Investigating the delivery mechanism of fluoresceinated peptides via a host-[2]rotaxane. X. Wang, D. B. Smithrud 449. Total synthesis of a novel host-[3]rotaxane as intracellular transport agent. X. Bao, D. B. Smithrud 450. Molecular photonic wire behavior of electroluminescent materials. V. A. Montes, P. Anzenbacher Jr. 451. New materials for high efficiency organic light emitting diodes. L E. Hayden, S. C. Jones 452. New photoreactive silicone-based biocompatible material. N. K. Urdabayev 453. Oligomeric dithieno[3,2-b:2'3'-d]pyrroles: Precursors for new conjugated systems and models of effective conjugation length. A. R. Wohl, S. C. Rasmussen 454. Photophysical studies of a rotary bis(pphenyleneethynyl)pentiptycene derivative. M. A. Jimenez, M. Garcia-Garibay 455. Planar β-linked oligothiophenes based on thieno[3,2-fc]thiophene and dithieno[3,2/?,2',3'-cdthiophene fused units. L. San Miguel, A. J. Matzger 456. Regio- and chemoselective covalent immobilization of proteins to gold surfaces through unnatural amino acids. R. F. H. Bohaty, C. D. Poulter 457. RET-based two-photon photochromic optical data storage. C. C. Corredor, Z-L. Huang, K. D. Belfield, A. R. Morales, M. V. Bondar 458. Storage capacity determinations for two-photon 3-D optical data storage in a bichromophoric RET-based photochromic system. Z-L. Huang, G. Calbris, C. C. Corredor, K. D. Belfield 459. Switchable container molecules: Synthe sis and reversibly controllable formation of inclusion compounds. T. Gottschalk, B. Jaun, F. Diederich 460. Synthesis and characterization of dendron-modified xanthene dyes. J. M. McKay, S. C. Zimmerman 461. Synthesis and photophysical properties of carbazole-based blue emitting dendrimers. R. M. Adhikari, R. Mondai, Β. Κ. Shah, D. C. Neckers 462. Synthesis of acryloyl amino acid methyl ester and its application on thermo-responsive polymer. L. Chen, R-J. Dai, W. Liu 463. Synthesis of asymmetric thieno[3,4bjpyrazine-based terthienyls as precursors to low band gap materials. K. J. Syltie, L. Wen, S. C. Rasmussen 464. Synthesis of dithieno[3,2-b:2',3' djpyrrolebased diarylethylenes as polymer precur sors. S. J. Evenson, A. R. Wohl, S. C. Rasmussen 465. Synthesis of highly soluble and oxida tive^ stable pentacenes. S. S. Palayangoda, B. K. Shah, R. Mondai, D. C. Neckers 466. Synthesis of rhodamine Β lactams for the differentiation of biogenic carboxylic acid. K. M. Yehl, C. J. Stephenson, K. D. Shimizu 467. Toward enforcing the face-to-face stack ing of tetracene and pentacene semicon ductor building blocks. S. X. Gu 468. Two-photon absorbing fluorescent nanoparticle composites. S. Yao, K. D. Belfield, Z-L. Huang 469. Advances in epoxide-based polypropionate synthesis: Protecting group effect in the regioselectivity of 2-methyl-3,4-epoxy alcohol cleavage. Ε. Μ. Valentin, G. Torres, J. A. Prieto 470. Application of selenocarboxylate/azide amidation to amino acids and peptides. X. Wu, L Hu 471. Asymmetric enolization of prochiral cyclic ketones by polymer-supported lithium amides. L. Ma, P. G. Williard 472. Synthesis of homoallyl ethers via iron(lll) tosylate catalyzed allylation of acetals. R. S. Mohan, E. D. Anderson, A. C. Palma 473. Bismuth compounds in organic synthe sis: Bismuth bromide catalyzed synthesis of substituted quinolines. R. S. Mohan, J. L. Rogers, H. Yung
TECH-97
ORGN 474. Bismuth compounds in organic synthe sis: Bismuth iodide catalyzed deprotection of acetals and ketals in water. R. S. Mohan, A. D. Bailey, A. R. Baru 475. Bismuth nitrate catalyzed-michael reac tion in water. B. K. Banik, I. Garcia, D. Owens 476. Bismuth nitrate-catalyzed synthesis of 3-pyrrole substituted monocyclic β-lactams. B. K. Banik, I. Salinas, H. Aguilar 477. Bismuth salts-catalyzed peracetylation of sugars. Β. Κ. Banik, J. Lerma, M. Hernandez, H. Aguilar 478. Preparation of aspirin through bismuth nitrate-catalyzed reaction. Β. Κ. Banik, Y. Garcia, I. Garcia 479. Iodine-catalyzed synthesis of pyrrolesubstituted indolinone. Β. Κ. Banik, F. Morales, M. Cardona 480. Nitration of estrone through bismuth nitrate-induced reaction. Β. Κ. Banik, H. Aguilar, A. Bose, W. P. Sanjoto, S. Villarreal 481. Bora-Demjanov rearrangement: Detec tion of reactive boretane intermediate, mechanistic studies, and application. M. Rubin, M. Rubina 482. Development of novel cyclopropylaminophosphine ligands for transition metal catalysis in carbon dioxide-expanded solvents. M. Rubin, W. M. Sherrill 483. Byproduct isolation and characterization from reductive amination reaction in the synthesis of PEPCK inhibitors. S. Li 484. Combination of catalytic hydroamination and the Strecker reaction: Applications and mechanistic insight. A. V. Lee, L. L. Schafer 485. Copper(ll)-catalyzed aminohydroxylation of furan derivatives. T. P. Yoon, T. Benkovics 486. Copper(ll)-mediated aminohydroxylation of olefins with N-sulfonyl oxaziridines. D. J. Michaelis, T. P. Yoon, C. J. Shaffer 487. Cu-Catalyzed 1,3-migration of phosphate group: Synthesis of phosphatyloxy-containing heterocycles. D. Cernaks, V. Gevorgyan 488. Decarbonylation of protected phenylpyrrolidinones in the solid-state as an entry to the total synthesis of natural products. M. J. E. Resendiz, M. Garcia-Garibay 489. Design and development of a bioorthogonal heterocycle formation using pyrrolysine. J. Chang, M. L. Wong, L. L. Kiessling 490. Direct amide aldol reactions with alde hydes: Surprising Weinreb amide reactiv ity. J. C. Adrian Jr., R. K. Peters 491. Enantioenriched α-substituted aldehydes via diastereoselective enamine alkylation. N. S. Kaka, D. M. Hodgson 492. Epoxide-based approach toward the preparation of scytophycin C polypropionate chain. J. Rentas, D. Rodriguez, R. R. Rodriguez, J. A. Prieto 493. Studies toward the convergent synthesis of the polypropionate chain of lankanolide using an epoxide cleavage approach. R. R. Rodriguez, E. Hemadez, J. A. Prieto 494. Evaluation of stereo-electronic properties desired for a suitable rhodium catalyst affording alkynylrhodium additions to aldehydes and 1,2-dicarbonyl compounds. P. K. Dhondi, J. D. Chisholm 495. Exploring new substrates and reagents in organocatalytic Mitsunobu reactions. T. Y. S. But, P. H. Toy 496. Exploring the reactivity of α-alkyl allenoates as a 1,4-dipole synthon in phosphine catalysis: Synthesis of highly substituted cyclohexenes via [4+2] annulation. Y. S. Tran, Ο. Kwon 497. Facile synthesis of imidazo[1,2-c]-pyrimidines via a [4+1]-cycloaddition. H. Hu, M. Alvim-Gaston, C. Hulme, M. Umkehrer, G. Ross, N. Jâger, C. Burdack, J. Kolb 498. First transamination reactions for the one-pot synthesis and applications of substituted zwitterionic quinones. Q-Z. Yang, O. Siri, P. Braunstein 499. General method for the synthesis of 2,4-disubstituted-5-hydroxythazoles. Q. Qiao, R. Dominique, R. Goodnow Jr. 500. Highly efficient synthesis of bis-tetrahydrofuran system: An alternative synthesis of annonaceous acetogenins and corresponding structure-activity relationship studies. J . Yan, C. Vasileiou, B. Borhan
VB-lfcCH
TECHNICAL PROGRAM 501. Improved procedure for the reductive alkylation of aromatic aldehydes with malononitrile. F. Tayyari, R. E. Sammelson 502. Investigation on photophysics and morphology of photo-responsive perylene diimid-azobenzene dyad. Y. Feng, W. Feng Sr. 503. Lithiation: Electrophile trapping of simple aziridine building blocks. S. P. Hughes, D. M. Hodgson 504. Microwave enhanced amination reactions involving dihalocompounds. M. Al-Masum, J. Akther 505. Microwave enhanced cross-coupling reactions involving alkenyl-and alkynyltrifluoroborates. G. W. Kabalka, A. Navarane, L. L. Zhou 506. Montmorillonite K10 clay-catalyzed addition and cyclization reactions of aldehydes. M. R. Dintzner, A. J. Little, M. Pacilli, D. J. Pileggi 507. Multicomponent synthesis of novel medicinally relevant indenoheterocycles. K. M. Cotter, S. K. Rastogi, M. Manpadi, P. Y. Uglinskii, I. V. Magedov, A. Komienko 508. Multicomponent diversity oriented organocatalysis (DOS). V. R. Konda, M. F. A. Adamo 509. New and improved one-step synthesis of donor acceptor cyanostilbenes. D. H. Murray 510. New N-heterocyclic carbenes for catalysis. M. Heitbaum, F. Glorius 511. New strategies for synthesis of complex prenylated aromatic compounds. K. D. Boss, D. F. Wiemer 512. New synthetic procedure for the alkylation of indoles. K. Natsuko, V. H. Rawal 513. Oxidation of 3-acetyl-4-hydroxycoumarin benzoylhydrazone with lead tetraacetate. A. Kotali, D. Nasiopoulou, P. A. Harris 514. Oxidative cyclization of ω-unsaturated O-alkyl hydroxamates: Progress toward the de novo synthesis of tamiflu. D. J. Wardrop, A. D. Sussman 515. P(RNCH2CH2)3N: An efficient roomtemperature promoter for the synthesis of a,b-unsaturated esters, fluorides and nitriles using Wadsworth-Emmons phosphonates. V. R. Chinta Reddy, J. G. Verkade 516. Palladium-catalyzed intermolecular aminoacetoxylation of alkenes. G. Liu, S. S. Stahl 517. Pd-Catalyzed cascade arylation/annulation of o-alkynyl biaryls. N. Chemyak, V. Gevorgyan 518. Pd-catalyzed reactions of triallyl(phenyl)germanes. J-P. Pitteloud, S. F. Wnuk 519. Phosphine-catalyzed synthesis of highly functionalized coumarin derivatives. C. E. Henry, O. Kwon 520. Practical application of Taylor's Method for the synthesis of 3,4-substituted-5amino-isothiazoles. S. L. Kuklish, M. J. Fisher, A. M. Kempema, S. C. Mauldin, A. Merschaert, R. T. Backer 521. Reusable resin-supported ruthenium catalysts highly efficient for metathesis reactions. Z-Y. J. Zhan, D-L. Wu, D-W. Cui 522. Selective formation of six membered cyclic sulfones and sulfonates by C-H insertion. A. V. Novikov, J. P. John 523. Stereoselective fluoromethylation of alcohols. G. K. S. Prakash, S. Chacko, S. Alconcel, G. A. Olah 524. Stereoselective syntheses of halogenated (Z.E)- and (Z-Z)-1,4-dienes. G. W. Kabalka, M-L. Yao, S. Borella 525. Studies directed toward a new method for dihydropyran synthesis. L. McNulty, K. Borin 526. Study on synthesis lubricating oil from vegetable oil by a new method. W. Liu, L. Yang, R. Dai, H. Wu 527. Study on the enantioseparation mecha nism of chiral amine by the crystallization method. W. Liu, L. Yang, R. Dai, Y. Deng 528. Sulfonamide metathesis: A novel strat egy for the preparation of sulfonamides. M. H. Katcher, J. B. Grimm, A. B. Northrup, D. J. Witter 529. Synthesis of a-fluoro-p-trifluoromethylα-β-unsaturated esters by Wittig and Homer-Wadsworth-Emmons coupling. S. M. Landge, B. Torek 530. Synthesis of bromostyrenes via facial Hunsdiecker reaction. C-L. Kao, Y-H. Haung, Y-H. Cheng, C-W. W. Chang
531. Synthesis of p-isopropylbenzoic acid from {beta}-pinene. J. Jianzhong 532. Toward peptidic ligands for the asym metric osmium tetroxide-mediated dihydroxylation of olefins. D. C. Whitehead, B. Borhan 533. Unusual Lewis acid effects in the Prins reaction: Applications in the total synthesis of centrolobine. A. P. Dobbs, M. J. Penny, D. Gough, P. Jones 534. Use and reuse of ionic liquid technolo gies. D. C. Forbes, S. A. Patrawala, A. M. Law 535. Continuous flow reactor for direct uncatalyzed amination of 2-chloropyridines. E. Tesfu, B. C. Hamper
9:55 548. Chemical synthesis inspired by biosynthetic pathways. E. J. Sorensen 10:35 549. Exploring biosynthetic relation ships among furanocembranoids. D. Trauner 11:15 550. Synthetic strategies for natural products premised on biosynthetic propos als. D. Romo Section D McCormick Place Lakeside Room E351, Level 3 Asymmetric Reactions and Syntheses G. R. Cook,
Presiding
WEDNESDAY MORNING Section A McCormick Place Lakeside Room E450 A/B, Level 4 Francis P. Garvan-John M. Olin Medal: Symposium in Honor of Laura L. Kiessling Cosponsored with WCC D. Huryn, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 536. Sulfation pathways in mycobacterium tuberculosis: New opportunities for drug development. C. R. Bertozzi 9:10 537. Automated iterative solution-phase synthesis and its application to glycomics. N. L. Pohl 9:45 538. Chemical control of gene activa tion. A. K. Mapp 10:20 539. Synthetic ligands that disrupt bacterial quorum sensing pathways and outcomes. H. E. Blackwell 10:55 Introduction of Awardee. 11:00 540. Award Address (Francis P. Garvan- John M. Olin Medal, sponsored by Francis P. Garvan- John M. Olin Medal Endowment). Illuminating and inhibiting carbohydrate biosynthetic pathways. L. L. Kiessling 12:00 Closing Remarks. Section Β McCormick Place Lakeside Room E451A/B, Level 4 ACS Award for Research at an Undergraduate Institution: Symposium in Honor of Cheryl D. Stevenson Cosponsored with WCC R. A. Volkmann,
Organizer
8:15 Introductory Remarks. 8:20 541. Diblock oligomers for molecular electronics. L. Yu 9:00 542. Electronic interactions in Π-stacked tertiary arylureas. F. D. Lewis 9:40 543. Progress toward the chemical synthesis of single chirality, uniform diam eter carbon nanotubes. L. T. Scott 10:20 544. Aromatic chemistry for the cre ation of polymer actuators. Τ. Μ. Swager 11:00 Introduction of Awardee. 11:10 545. Award Address (ACS Award for Research at an Undergraduate Institution, sponsored by Research Corporation). New annulynes and annulenylenes. C. D. Stevenson Section C McCormick Place Lakeside Room E350 : Level 3 Biomimetic Natural and Unnatural Products Synthesis
8:00 551. Vanadium catalyzed asymmetric epoxidation of allylic alcohols and homoallylic alcohols. W. Zhang, H. Yamamoto 8:20 552. Catalytic enantioselective allenylation reactions of aldehydes with tethered bis(8-quinolinolato) (TBOx) chromium complex. G. Xia, H. Yamamoto 8:40 553. Alkenyl substituted tetrahydrofurans via enantiospecific aldehyde/cyclopro pane cycloadditions. S. Sanders 554. Withdrawn. 9:00 555. Chiral bicyclic guanidine-catalyzed enantioselective reactions of anthrones. J. Shen 9:20 556. Chiral Bronsted acid-catalyzed asymmetric aza Diels-Alder reactions. T. Akiyama, J. Itoh, K. Fuchibe 9:40 557. Chiral Lewis-acid catalyzed carbonyl-ene reactions. G. Hutson, V. H. Rawal 10:00 558. Hydrogen bond catalysis: Gen eration of quaternary chiral centers through diasteroselective and enantio selective Mukaiyama aldol reactions of ketones. V. B. Gondi, V. H. Rawal 10:20 559. Enantioselective and diastereo selective organocatalytic aminomethylation of adehydes: A role for ionic interactions and efficient access to enantiomerically pure 32-amino acids. Y. Chi, S. H. Gellman 10:40 560. Temporary stereocentres for the asymmetric synthesis of chiral aldehydes. S. D. Bull, D. G. Niyadurupola, M. Cheeseman, I. R. Davies, R. Wisedale 11:00 561. Asymmetric synthesis of 2° and 3° optically active carbinols via methallylboration of aldehydes and ketones with S-methallyl-10-TMS(Ph)-9borabicyclo[3.3.2]decane reagents. J. G. Roman, J. A. Soderquist 11:20 562. Asymmetric synthesis of {alpha}allenyl carbamines via the propargylboration of Λ/-Η aldimines with S-({gamma}TMS-propargyl)-10-TMS-9borabicyclo[3.3.2]decane. E. Alicea, J. A. Soderquist Section Ε McCormick Place Lakeside Room E352, Level 3 Total Synthesis of Complex Molecules S. Chackalamannil,
Presiding
8:00 563. Intramolecular formal oxa-[3 + 3] cycloaddition approach to the ABD system of (±) phomactin A. Y. Tang, K. P. Cole, R. P. Hsung, G. Li 8:20 564. Iterative one-pot synthesis of the tumor-associated carbohydrate antigen Globo-H. Z. Wang, L. Zhou, K. El-Boubbou, X. Huang 8:40 565. New strategy to the pyranyl moiety of (+)-zincophorin via a stereoselective hetero [4+2] cycloaddition with a chiral allenamide. Z. Song, R. P. Hsung
G. A. Sulikowski, D. Romo, and F. E. McDonald, Organizers 8:30 Introductory Remarks. 8:35 546. Pyrrole-2-aminoimidazole marine metabolites: Isolation and biomimetic synthesis convergence. A. Al-Mourabit, C. Vergne, T. Perez, M-T. Martin, M-T. Adeline 9:15 547. New chemical reactions inspired by complex natural products. J. A. Porco Jr.
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ORGN 9:00 566. Organocatalytic reactions in the total synthesis of UCS1025A. M. Christmann, R. M. de Figueiredo, W. C. Jacobs 9:20 567. Progress toward the total synthe sis of gambieric acids: Construction of the GHIJ ring system. X. Zhao, P. A. Evans 9:40 568. Progress toward the total synthe sis of norrisolide. Κ. Ε. Granger, R. L. Casaubon, M. L. Snapper 10:00 569. Progress toward the total synthe sis of squamocin-N and (+)-asimilobin. M. W. Dodge, S. D. Burke 10:20 570. Racemic and enantioselective syntheses of wine lactone. J. T. Ippoliti, M. J. Moen 10:40 571. Recent developments in silylPrins reactions: Toward the total synthesis of kendomycin. A. P. Dobbs, D. Gough, S. Martinovic, J. Warne, S. Newberry, D. Khan 11:00 572. Studies toward the total synthesis of vancomycin aglycon: A ruthenium mediated SNAr approach. S. Basu, A. J. Pearson 11:20 573. Toward the synthesis of secopseudopteroxazole. M. Harmata, P. Zheng WEDNESDAY AFTERNOON Section A McCormick Place Lakeside Room E450 A/B, Level 4 Nobel Laureate Signature Award for Graduate Education in Chemistry: Symposium in Honor of Anirban Banerjee and Gregory L. Verdine A. Abdel-Magid,
Organizer
1:00 Introductory Remarks. 1:05 574. Chemical biology of mutagenic translesion DNA replicaton. L. S. Beese, J. Warren, G. Hsu, E. Wu 2:00 575. On the power of chemical synthe sis. S. Danishefsky 3:00 576. Award Address (Nobel Laureate Signature Award for Graduate Education in Chemistry, sponsored by Mallinckrodt Baker, Inc). Drugging the undruggable. G. L Verdine 4:00 577. Award Address (Nobel Laureate Signature Award for Graduate Education in Chemistry, sponsored by Mallinckrodt Baker, Inc). Covalent trapping and struc tural studies of intermediates in the base excision repair pathway. A. Banerjee, G. L Verdine Section Β McCormick Place Lakeside Room E451 A/B, Level 4 Biomimetic Natural and Unnatural Products Synthesis G. A. Sulikowski, D. Romo, and F. E. McDonald, Organizers 1:00 578. Biomimetic synthesis via polyepoxide cyclizations. F. E. McDonald 1:40 579. Origins of triterpenoid skeletal diversity. S. P. T. Matsuda 2:20 580. Challenges and opportunities in natural product glycosylation. J. S. Thorson 3:00 581. Biosynthetic halogenations: Enzy matic logic and machinery. C. T. Walsh 3:40 582. Biomimetic total syntheses of prenylated indole alkaloids. R. M. Williams 4:20 583. Precursor directed biosynthesis: Glycosylation of synthetic aglycone conge ners of apoptolidinone. G. A. Sulikowski
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Section C
Section Ε
McCormick Place Lakeside Room E350, Level 3
McCormick Place Lakeside Room E352, Level 3
Metal-Mediated Reactions and Syntheses
Molecular Recognition and Self-Assembly
N. G. Bhat,
M. T. Huggins,
Presiding
1:00 584. Golden age of catalysis. N. Krause 1:20 585. Small but effective: Copper hydride-catalyzed synthesis of a-hydroxyallenes. N. Krause, C. Deutsch, Β. Η. Lipshutz 1:40 586. Gold and silver mediated nitrene transfer reactions. Z. Li, C. He 2:00 587. Preparation of carbamates via cobalt-catalyzed oxidative carbonylation of aromatic or aliphatic primary amines and aliphatic secondary amines. B. Rindone, F. Saliu 2:20 588. Rhodium(l)-catalyzed [2+2+2] cycloadditions of ynamides in the synthe sis of amide-substituted chiral biaryls. J. Oppenheimer, M. R. Tracey, R. P. Hsung 2:40 589. Radical cyclization of bromoacetates and brominated acrylates in the presence of copper(l) homoscorpionate complexes. T. Pintauer 3:00 590. Copper mediated diarylation as a strategy for the synthesis of tertiary squaramides. R. S. Muthyala, V. Ramalingam, N. Bhagirath 3:20 591. Mechanistic studies of the coppercatalyzed electrophilic amination of O-benzoyl hydroxylamines. M. J. Campbell, J. S.Johnson 3:40 592. Titanium mediated conversion of allyl alcohols to secondary allylic amines. B. Ramanathan, A. L. Odom 593. Withdrawn. 4:00 594. Formation of polycyclic scaffolds from tungsten-arene complexes. E. C. Lis Jr., W. H. Myers, W. D. Harman Section D McCormick Place Lakeside Room E351, Level 3 Asymmetric Reactions and Syntheses J-Q. Yu,
Presiding
1:00 595. Enantioselective rhodium-cata lyzed allylations of α-alkoxy ketone enolates. M. J. Lawler, P. A. Evans 1:20 596. Acylphosphonates as donor and acceptor in organocatalytic asymmetric reactions. A. S. Demir, Ô. Reis, I. Esiringu, S. Eymur, B. Reis, S. Baris, H. Yalcinkaya 1:40 597. Asymmetric Michael addition of lithium propionate enolates to α, β unsat urated esters toward the total synthesis of lonomycin A. S. Jo, R. A. Holton 2:00 598. Catalytic enantioselective synthe sis of flavanones and chromanones. K. A. Scheldt, M. Biddle 2:20 599. Highly enantioselective intramo lecular Michael additions catalyzed by N-heterocyclic carbenes. K. A. Scheldt, E. M. Phillips, M. Wadamoto, A. Chan 2:40 600. Synthesis of tertiary β-hydroxy amides by enolate additions to acylsilanes. K. A. Scheldt, R. B. Lettan II, T. E. Reynolds, C. V. Galliford 3:00 601. Stereoselective Lewis acid-cata lyzed α-acylvinyl anion addition reactions. Τ. Ε. Reynolds, A. Bharadwaj, K. A. Scheldt 3:20 602. Michael addition reactions of chiral benzothiazines. M. Harmata, Y. Chen 3:40 603. Selectivity in asymmetric sulfoxida tion of nitrogen containing heterocycles. S. Muthu, H-J. Federsel, A. Ertan, K. J. Szabo 4:00 604. Stereoselective synthesis of N-alkylaziridines from N-chloroamines. S. P. Bew 4:20 605. Use of the temporary connection in stereoselective allylation. J. Beignet, L. R. Cox 4:40 606. Using ligand scaffold optimization to achieve the efficient rhodium-catalyzed asymmetric hydroboration of styrènes. S. A. Moteki, Ν. Thacker, J. M. Takacs
Presiding
1:00 607. Biomimicing behavior of amino acid-functionalized gold nanoparticles in enthalpy-entropy compensation. M. De, C-C. You, V. M. Rotello 1:20 608. Model systems for flavoenzyme activity: Synthetic flavoenzyme mimics via nanoparticle and polymeric scaffolds. B. J. Jordan, G. Cooke, J. F. Garety, M. A. Pollier, N. Kryvokhyzha, A. Bayir, G. Rabani, A. Verma, V. M. Rotello 1:40 609. General purpose ditopic hydrogen bonding module and its use to generate unique polymer architectures. Ε. Μ. Todd, S. C. Zimmerman 2:00 610. High-affinity quadruply hydrogenbonding module mediated self-assembly on surfaces. D. W. Kuykendall, H. C. Ong, S. C. Zimmerman 2:20 611. Sensing of aqueous anions with calix[4]pyrrole isomers. M. A. Palacios, R. Nishiyabu, G. Zyryanov, P. Anzenbacher Jr. 2:40 612. New pyrrole- and (thio)urea-based tripodal anion receptors. G. Zyryanov, P. Anzenbacher Jr. 3:00 613. Exploring the reactivity of cocrystals using liquid-assisted grinding. T. Friscic, W. Jones, W. D. S. Motherwell 3:20 614. Modeling the anion response of a luminescent Eu(lll) macrocyclic system. C. G. Gulgas, T. M. Reineke 3:40 615. Relay mechanism for anion trans port through membranes. E. J. O'Neil, B. A. McNally, B. D. Smith 4:00 616. Selection, replication and amplifi cation as tools in organic chemistry. D. Philp 4:20 617. Theoretical and experimental investigations of anion-π interactions with complex anions. B. L. Schottel, I. D. Giles, L M. Perez, K. R. Dunbar 4:40 618. Toward sacrificial handles in tem plate-controlled solid-state reactions. P. Kaushik, T. Friscic, L. R. MacGillivray W E D N E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Asymmetric Reactions, Combinatorial Chemistry, Molecular Recognition and Self-Assembly, Proteins, Peptides, Amino Acids and Enzyme Inhibitors S. M. Sieburth,
Organizer
8:00-10:00 619. Application of solvent engineering on lipase PS-catalyzed acylation of aracytiding by using a cosolvent mixture. X-F. Li, M-H. Zong 620. Biocompatibility of ionic liquids and their use for efficient biocatalysis with baker's yeast cells. W-Y. Lou, M-H. Zong 621. Highly efficient acylation of 5-fluorouridine catalyzed by Novozym 435 in organic media. H. Wang, H. Wu, W-Y. Lou, M-H.Zong 622. Preparation, characterization and cata lytic performance of a novel sugar- based solid acid catalyst. W-Y. Lou, Z-Q. Duan, H. Wu, M-H. Zong 623. Effect of molecular weight on enzymatic acylation of konjac glucomannan. Z-G. Chen, M-H. Zong 624. Preparation and characterization of 2,6-dimethylphenyl boronic acid. N. He, Y. Deng, H. Jiang, Y. Zhang, Q. He 625. Application of nanocapsules prepared from chitooligosaccharides and low molecular weight alginate. T. Wang, Z. Feng, N. He 626. Synthesis of nanorods PEDOT by tem plate-free self-assemble method. W. Feng Sr., Y. Li 627. A large combinatorial screen of metal scavenging polymers using high through put ICP analysis techniques. P. A. Boguszewski, G. Hibberd
628. Automated iterative solution-phase synthesis of rhamnogalacturonan I frag ments. Y. Chai, N. L Pohl 629. Automated solution-phase iterative synthesis using fluorocarbon tags. G. Park, N. L. Pohl 630. Bifunctional polymeric organocatalysts and their use in Morita-Baylis-Hillman reactions. C. K-W. Kwong, R. Huang, M. Zhang, M. Shi, P. H. Toy 631. Dithiocarbamate-, dithiobenzoate-, and nitroxyl- based free radicals in dynamic combinatorial chemistry: Library generation and deconvolution. D. Crich, A. A. Bowers, D. Grant 632. Design and synthesis of non-native ligands for the interception of quorum sensing in Gram-negative bacteria: New methods to attenuate pathogenesis and symbiosis. G. D. Geske, J. C. O'Neill, Q. Lin, M. E. Mattmann, H. E. Blackwell 633. Evaluation of 2,5-diketopiperazines as quorum sensing modulators. J. C. O'Neill, Q. Lin, G. D. Geske, B. Carlson, H. E. Blackwell 634. Rapid identification of antibacterial com pounds against Staphylococcus aureus using small molecule macroarrays. J. R. Stringer, M. D. Bowman, J. C. O'Neill, H. E. Blackwell 635. New methods to control peptoid second ary structure using electronically deacti vated and sterically hindered amide side chains. S. A. Fowler, B. C. Gorske, H. E. Blackwell 636. Fourier transform analysis for linear, periodic combinatorial arrays. P. Geissinger, A. W. Schwabacher 637. New multicomponent transition metalcatalyzed method for parallel synthesis of combinatorial libraries of Hexahydro-1 Hisoindolones. L. Zhang, H. C. Malinakova 638. Rapid solution phase synthesis and purification of urea and thiourea by utilizing microwave energy and silica-bound isocyanate. S. Ghassemi 639. Solid-phase synthesis of 5'-0-(alpha,beta-methylene)triphosphate and 5'-0(beta,gamma-methylene)triphosphate derivatives of nucleosides. Y. Ahmadibeni, K. Parang 640. Solid-phase synthesis of symmetrical dinucleoside monophosphodiesters, diphosphodiesters, triphosphodiesters, and tetraphosphodiesters. Y. Ahmadibeni, K. Parang 641. Synthesis of nucleoside 5'-0-beta-triphosphates containing alpha-beta methy lene bridge. Y. Ahmadibeni, M. Hanley, H. K. Agarwal, K. Parang 642. Synthetic strategies for generating sul fated oligosaccharide libraries on solidphase supports. R. Liu, J. M. Hernândez-Torres, R. Fan, A. Wei 643. Alternative substrates for chain elongation enzymes. N. A. Heaps, C. D. Poulter 644. Amplification of enantiomeric concentrations under credible prebiotic conditions. R. Breslow, M. Levine 645. An artificial β-sheet that dimerizes through parallel β-sheet interactions. S. Levin, J. S. Nowick 646. Chemical proteomic approach to identify new DNA damage sensory and repair proteins. E. A. Korobkova, C. He 647. Azido-proteins: Semisynthesis and appli cations. J. Kalia, R. T. Raines 648. Nanomaterials from self-assembling collagen building blocks. D. Gottlieb, R. T. Raines 649. Synthetic probes for elucidating the mechanism of prolyl 4-hydroxylase. K. L. Gorres, R. T. Raines 650. Contribution of a highly conserved serine residue to ribonuclease activity and stabil ity. R. J. Johnson, S. R. Un, R. T. Raines 651. Tuning the pKa of fluorescein: Implica tions for binding assays. L. D. Lavis, T. J. Rutkoski, R. T. Raines 652. Synthesis and characterization of diamino analog of dithiothreitol. N. M. McElfresh, R. T. Raines 653. Effects of hydroxyl-group alkylation on hydroxyproline-containing collagen triple helices. F. W. Kotch, R. T. Raines 654. Synthesis of superbly hyperstable colla gen triple helices via integration of steric and stereoelectronic effects. M. D. Shoulders, R. T. Raines
TECH-99
ORGN 655. Design and synthesis of spiroketal ana logs of didemnaketal A and B. X. Fan, D. H. Rich 656. Design and synthesis of pentaseter analogs of didemnaketal A and B. X. Fan, D. H. Rich 657. Stereoselective synthesis of pentaseter analogs of didemnaketal A and B. X. Fan, D. H. Rich 658. Development of mycobacterial growth inhibitors that target UGM. E. Dykhuizen, J. F. May, A. Tongpenyai, L. L. Kiessling 659. On the substrate specificity of dehydra tion by lacticin 481 synthetase. X. Zhang, W. A. van der Donk 660. Engineering of lantibiotic peptides through the incorporation of nonproteinogenic amino acids. M. R. Levengood, W. A. van der Donk 661. Investigation of substrate specificity of the bifunctional lantibiotic enzyme LctM. G. C. Patton, C. Chatterjee, W. A. van der Donk 662. Investigation of the protease domain of the lacticin 481 transporter LctT. L. A. Furgerson, C. Chatterjee, W. A. van der Donk 663. Mechanistic studies of phosphite dehy drogenase. E. Fogle, W. van der Donk 664. Synthetic and biosynthetic studies of the phosphonate antibiotic A53868. J. T. Whitteck, W. A. van der Donk 665. New genetically encoded fluorophores for multicolor live cell imaging. H-W. Ai, P. Wong, R. E. Campbell 666. Kinase-catalyzed protein tagging for phosphoprotein detection, purification, and assay development. K. D. Green, H. Santhaseyan, M. K. H. Pflum 667. Oxidation reduction condensation as a tool for monitoring protein phosphorylation. M. Warthaka, P. Karwowska-Desaulniers, M. K. H. Pflum 668. Steric requirements of HDAC inhibitors: Inhibition by SAHA analogs functionalized near the hydroxamic acid. A. V. Bieliauskas, Μ. Κ. Η. Pflum 669. Receptor oligomerization in leukocyte chemotaxis. C. Jiarpinitnun, A. C. Lamanna, L. L. Kiessling 670. Stereoselective synthesis of aminoboronic acids via alkylation under PTC condi tions. V. J. Reddy, S. C. Jonnalagadda, V. R. Mereddy 671. Symmetry code of proteomics and genomics. D. Gurel, O. Gurel 672. Synthesis and characterization of highly structured pentapeptides containing dipropylglycine. J . Wang, R. P. Hammer 673. Targeting the transcriptional machinery to generate potent artificial activators. C. Y. Majmudar, J. K. Lum, A. K. Mapp 674. Targeting the transcriptional machinery with peptidomimetics. J-P. Desaulniers, A. K. Mapp 675. The interaction of Buforin II with lipid vesicles of varying composition. J. L Chen, E. Fleming, N. P. Maharaj, E. H. Ooi, D. E. Elmore 676. Total synthesis of the a-glucosidase inhibitors schulzeine Β & C. D. J. Wardrop, E. G. Bowen 677. Using water-driven reactions to label peptides, proteins and cells. P. Sejwal, Y. Han, Y-Y. Luk 678. A fluorinated porphyrin tweezer: Powerful reporter of absolute configurations for erythro- and threo-diols, amino alcohols and diamines. X. Li, M. Tanasova, B. Borhan 679. Bulky porphyrin tweezer: Powerful tool for stereochemical assignment of chirality in 3- and 4-substituted carboxylic acids. M. Tanasova, B. Borhan 680. Carbonyl condensation chemistry for rotaxane formation. A. M. Cagulada, D. G. Hamilton 681. Calix[4]resorcarenes as chiral NMR discriminating agents. C. M. O'Farrell, T. J. Wenzel 682. Carboxymethylated cyclodextrins and their lanthanide complexes as chiral NMR discriminating agents. K. A. Provencher, T. J. Wenzel 683. Chiral NMR discrimination of secondary amines using (18-crown-6)-2,3,11,12tetracarboxylic acid. A. E. Lovely, T. J. Wenzel 684. Amplification of a molecular Solomon knot. C. D. Pentecost, K. S. Chichak, A. J. Peters, S. J. Cantrill, J. F. Stoddart
100-TECH
TEGHNICAL PROGRAM 685. Cooperative nature of the Borromean ring synthesis. C. S. Joiner, C. D. Pentecost, K. S. Chichak, A. J. Peters, S. J. Cantrill, J. F. Stoddart 686. Synthesis and dynamic studies of polyrotaxanes and pseudopolyrotaxanes based on DNP and CBPQT4+. W. Zhang, W. R. Dichtel, J. R. Heath, J. F. Stoddart 687. Hydrophobic DNA interactions. Y. Zheng, F. D. Lewis 688. Investigating the role of the N-terminus formamido group of distamycin. L. Westrate, H. Mackay, B. Nguyen, W. D. Wilson, J. Kluza, J. Hartley, M. Lee, T. Brown 689. Investigations into anion-{pi} interactions involving complex anions. I. D. Giles, B. L Schottel, L M. Perez, K. R. Dunbar 690. Modulation of enzyme structure and function using nanoparticles. C-C. You, M. De, S. S. Agasti, V. M. Rotello 691. Molecular recognition of base flipping in damaged DNA: Experimental and theoreti cal insights. L. L. O'Neil, O. Wiest 692. Novel amphiphilic self-assembling bisurea macrocycles. J . Yang, L. S. Shimizu 693. Oligosulfonimide dendrimers: Isomerism and supramolecular applications. O. Lukin, D. Schubert, V. Gramlich 694. Photoinduced gel-to-sol phase transition accompanied by the remarkable fluores cence change. J. W. Chung, B-K. An, S. Y. Park 695. Preparation of imprinted silica gel sur faces through reversible covalent attach ment of template. R. M. Jorgensen, J. A. McNeal, D. R. Wilkerson, J. P. Deluca 696. Modular synthesis of dynamic rotaxanes. P. C. Haussmann, J. F. Stoddart 697. Quantifying supramolecular interactions using modern numerical techniques. T. B. Gasa, J. M. Spruell, W. R. Dichtel, P. Kuzmic, J. F. Stoddart 698. Quinoxaline-calix[4]pyrrole conjugates as tunable colorimetric receptor models for anions. C-H. Lee, M-S. Kim 699. Tightly connected calix[4]pyrrole/ calix[4]crown-5 conjugates: Models for ditopic ion-pair recognition and salt con tainer. C-H. Lee, M-J. Lee, J. S. Kim 700. Reduction and luminescence chemistry of 1,8-anthraquinone-18-crown-5. M. Kadarkaraisamy, E. Dufek, A. G. Sykes 701. Sensing of biomolecules by molecular constructs based on genetically engi neered peptides. T. Kacar, C. So, M. Galan, H. Fong, M. Hnilova, C. Tamerler, M. Sarikaya 702. Solid-state and computational studies of anion-ττ interactions. C. Anderson, C. Matthew, M. Lewis 703. Synthesis and biophysical evaluation of a series of Η-pin polyamides designed to bind in a staggered motif to duplex DNA. J. Lajiness, P. Uthe, H. Mackay, J. Jones, K. Blackmon, C. O'Hare, J. A. Hartley, B. Nguyen, W. D. Wilson, T. Brown, M.Lee 704. Synthesis and characterization of glycolipids as novel hydrogelators. S. Cheuk, B. Hopkinson, G. Wang 705. Synthesis and self-assembly of 8-Aryl-2'deoxyguanosine derivatives in aqueous media. M. Garcia-Arriaga, J. M. Rivera 706. Dynamics of metal transport across a liquid membrane mediated by self-as sembled ionophores. M. Martin-Hidalgo, K. Camacho-Soto, V. Gubala, J. M. Rivera 707. Synthesis and supramolecular properties of dendronized 8-aryl-2'-deoxyguanosine analogs. J. E. Betancourt, J. M. Rivera 708. Synthesis of diamido-bipyridine ligands. A. E. Oberlink 709. Synthesis of divalent and tetravalent glycoconjugates for pathogen detection. D. Siler, C. McGannon, R. R. Kale, M. Brothers, D. M. Hatch, A. A. Kulkarni, A. Weiss, S. S. Iyer 710. Synthesis, NMR characterization and supramolecular structure of coumarins derivatives. R. Santos, A. Peraza, I. Padilla, E. Garcia, F. Martinez 711. Synthetic melanin as an environmental remediation agent. W. C. Boyd, J. M. Belitsky 712. The design and synthesis of proteomimetics using 4-substituted 2,3 -naphthalimides. P. Nandhikonda
713. Tripod-type anion receptors: Solid state, solution and theoretical studies. G. Zyryanov, M. A. Palacios, P. Anzenbacher Jr. 714. Turn-on fluorescent organogel triggered by complexation with silver. J. Seo, J. W. Chung, S. Y. Park 715. A new general approach for the synthe sis of unusual amino acids. Κ. Ν. Fanning, A. Sutherland 716. Progress in application of allylic hydroxyphosphonates for the convergent stereocontrolled synthesis of tetrahydrofuran fragments of Amphidinolide C. H. M. Goode, D. A. Smith III, C. D. Spilling 717. Application of α-hydroxy phosphonates to the synthesis of cyclic ether-containing natural products. N. Sutivisedsak, C. D. Spilling 718. Autoinduction in the asymmetric Pudovik reaction. D. A. Smith III, C. D. Spilling 719. Applications of the asymmetric aziridination (AZ) reaction - ring expansion and regio-selective ring opening reactions. Z. Lu, W. D. Wulff 720. Asymmetric aryl transfer from arylzinc reagents to isoquinoline nitrones and mechanistic studies by diffusion-ordered NMR spectroscopy. S. Wang, M. B. Onaran, D. Li, C. T. Seto 721. Application and utility of pyrazolidinone auxiliaries in enantioselective transforma tions. L. Stanley, M. P. Sibi 722. Asymmetric organocatalyst mediated radical reactions. M. Hasegawa, J. Zimmerman, M. P. Sibi 723. Asymmetric synthesis of 2,3-disubstituted cyclic ketones by conjugate radical additions to unsaturated cyclic ketones: An effect of oxygen at β' position. S. Nad, M. P. Sibi 724. Highly regio- and enantioselective conju gate addition of hydrazines to α,β-unsaturated imides. T. Soeta, M. P. Sibi 725. Asymmetric synthesis of protected β-amino acids by organocatalytic rear rangement reactions. S. Kobbelgaard, K. A. Jorgensen 726. Chiral reduction of diketone compounds with carrot pieces. B. W. Baldwin 727. Triazinones: Synthesis and development of a novel class of chiral templates for asymmetric synthesis. J. A. Groeper, S. R. Hitchcock 728. Design, synthesis and asymmetric 1,2addition reactions of oxazolidines derived from (1 fî,2S)-Ephedrine and (1 S,2S)Pseudoephedrine. R. W. Parrott II, S. R. Hitchcock 729. Exploration of a Ce-quaternary oxadiazinanone's potential as a chiral auxiliary in asymmetric reactions. D. D. Dore, S. R. Hitchcock 730. Efforts toward the development of novel tridentate ligands for use in catalytic asymmetric synthesis from Ephedra alkaloids. L J. Sinnott, S. R. Hitchcock 731. Designing chiral Bronsted acid for asymmetric cyclopropanation. M. M. Morshed, M. E. Dudley, R. D. Theys, M. M. Hossain 732. Development of force field based virtual ligand screening methods for asymmetric, rhodium catalyzed hydrogénations of enamides. P. J. Donoghue, O. Wiest, P-O. Norrby, P. Helquist 733. Efficient asymmetric synthesis of the C1-C6 portion of the psymberin using Evans auxiliary controlled reaction. A. Pal, Y. Ying, Z. Peng, W. Bornmann 734. Stereoselective dynthesis C8-C25 fragment of psymberin. Y. Ying, Z. Peng, A. Pal, W. Bornmann 735. Enantio- and diastereoselective Mukaiyama aldol reactions of simple ketene acetals promoted by hydrogen bonding catalysts. C. J . Lim, C. Kilbane, M. Gravel, V. H. Rawal
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736. Highly diastereo- and enantioselective direct aldol reaction in water. S. Aratake, T. Okano, T. Itoh, T. Sumiya, M. Shoji, Y. Hayashi 737. Highly enantioselective chiral anionmediated Diels-Alder cycloadditions. T. P. Yoon, C. P. Allen 738. Highly enantioselective borane reduction of acetylpyridines with chiral spiriborates. V. Stepanenko, M. Ortiz-Marciales, M. De Jesus, W. Correa, L. Ortiz 739. Kinetic resolution of propargylic alcohols using CI-PIQ and BTM. V. B. Birman, L Guo 740. Structural variation of CI-PIQ and BTM, enantioselective acyl transfer catalysts. J. K. Boppisetti, X. Li, V. B. Birman 741. Manganese mediated radical-ionic annulation unlocks a (^-symmetry-breaking strategy toward quinine. C. S. Korapala, J. Qin, M. Soukri, G. K. Friestad 742. New strategies for asymmetric hydrogénation reactions. Y. Gnas, F. Glorius 743. Novel approach to the asymmetric Heck reaction. L. Penn, A. Shpruhman, D. Gelman 744. One-pot preparation of highly substituted tetrahydropyran-4-ones. S. P. P. D. Santos, P. A. Clarke 745. Organocatalytic asymmetric Diels-Alder reactions with novel chiral hydrazines. G. R. Cook, D. Vaughn, S. Bhor 746. Organocatalytic stereoselective a-functionalization of aldehydes. A. Kjsersgaard, K. A. Jergensen 747. Stereodivergent multicomponent synthesis of functionalized pyrrolidines. P. Garner, J . Hu, H. U. Kaniskan 748. Studies directed toward determining the relative stereochemistry of members of the amphidinol family of marine natural products. P. Kommana, S. W. Chung, L. Liu, W. A. Donaldson 749. Studies toward the synthesis of entEnigmol and ent-lsoenigmol. D. L. Gray, F. E. McDonald 750. Synthetic studies toward the monomeric pyrrole-imidazole alkaloids cyclooroidin and agelastatin. S. Mukherjee, S. Rasapalli, C. J. Lovely 751. The first enantiospecific total synthesis of the important biogenetic intermediates, (+)polyneuridine and (+)-polyneuridine aldehyde, as well as 16-epi-vellosimine and macusine A. W. Yin, J. Ma, J. M. Cook 752. Toward the total synthesis of petrosynol. A. O. Omollo III, B. W. Gung THURSDAY MORNING Section A McCormick Place Lakeside Room E450 A/B, Level 4 Materials, Devices, and Switches P. Anzenbacher Jr.,
Presiding
8:00 753. Degradable polymeric materials containing 1,3,5-triazaadamantanes. R. E. Kohman, A. M. Balija, S. C. Zimmerman 8:20 754. Exploring the dynamics of ringclosing metathesis of dendrimers. S. L Elmer, S. C. Zimmerman 8:40 755. Novel well-defined photoconducting discotic liquid crystals. Q. Li, X. Zhou 9:00 756. Detection and identification of proteins based on nanoparticle-fluorescent polymer arrays. C-C. You, O. R. Miranda, B. Gider, P. S. Ghosh, l-B. Kim, U. H. F. Bunz, V. M. Rotello 9:20 757. Developing control of solid-state structure of oligothiophene and oligoacene derivatives. A. Sokolov, L. R. MacGillivray 9:40 758. Effect of central metal ions on first hyperpolarizability and two photon absorption of unsymmetrical metal porphyrins. P. Ray 10:00 759. Host-rotaxanes as cellular delivery agents. D. B. Smithrud 10:20 760. Perfluorometallofluorenes as η-type building blocks for organic electron ics. K. Geramita, J. Mcbee, T. D. Tilley 10:40 761. Piperylene sulfone: A labile and recyclable polar aprotic solvent. D. Vinci 11:00 762. Progress toward new isobenzofuran-based polymeric materials. S. Meek, T. M. Swager
lORGN 11:20 763. Synthesis and luminescent stud ies of some novel segmented copolymers based on para-bis (aryleneethynyl) ben zenes. N. Sanyal, P. M. Lahti, A. Cirpan, F. E. Karasz 11:40 764. Isomeric oligosulfonimide dendrimers: Topology vs. constitution. O. Lukin, D. Schubert Section Β McCormick Place Lakeside RoomE451A/B, Level 4 Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High Energy Species C. A. Parish,
Presiding
8:00 765. Small Pd and Ru clusters interac tion with alcohols. D. G. Kovacs 8:20 766. A new electron injection and detection system for studying excess electron transfer in DNA. L Xu, M. Newcomb, M. Lai, J. Jin 8:40 767. Rate constants for reactions of triethylborane-water and -methanol com plexes as hydrogen atom donors to alkyl radicals. J. Jin, M. Newcomb 9:00 768. Kinetics of intramolecular 1,5- and 1,6-hydrogen atom transfer reactions. C. B. DeZutter, J. H. Horner, M. Newcomb 9:20 769. Distance and sequence depen dence of DNA electron transfer. P. Daublain, H. Zhu, B. Cohen, M. R. Wasielewski, F. D. Lewis 9:40 770. Dynamics of photoinduced charge transfer in Perylene diimide DNA hairpins. T. A. Zeidan, R. F. Kelley, R. Carmielli, M. R. Wasielewski, F. D. Lewis 10:00 771. Pyrene excimer fluorescence as a probe for parallel G-quadruplex forma tion. H. Zhu, F. D. Lewis 10:20 772. Glycerol hydrogenolysis to pro pylene glycol: Mechanistic insights. S. Marincean, J. E. Jackson, D. J. Miller 10:40 773. Investigation of glycosylate mechanisms: The effects of thioglycoside aglycons on anomeric reactivities. X. Li, L Huang, X. Huang 11:00 774. Naphthalimide-protein interaction of the photocrosslinking agent N-butyl-4butylamino-1,8-naphthalimide. B. A. Ristow, R. Utecht 11:20 775. Probing CH/pi interactions between [60]fullerene and phenyl substi tuted acenes. J. E. Rainbolt, G. P. Miller 11:40 776. Secondary deuterium isotope effects on acidity of carboxylic acids and phenols. C. L. Perrin, Y. Dong Section C McCormick Place Lakeside Room E350, Level 3 Metal-Mediated Reactions and Syntheses T. Pintauer,
Presiding
8:00 777. Acidic, oxidative cross-coupling: Hydrocarbons, carboxylic acids and organoboronic acids toward complex molecules. J. H. Delcamp, M. C. White 8:20 778. Employment of functionalized allyl boronic acids in palladium catalyzed regioselective coupling with aryl halides. V. J. Olsson, S. Sebelius, O. A. Wallner, K. J. Szabo 8:40 779. Generation of boron enolates from diaminoborane chlorides and ketones. L Ma, P. G. Williard 9:00 780. Cause and effect analysis of deborylation through planned experimenta tion. R. C. Todd, K. V. B. Josyula, K. Gorr, K. Priebe, P. Gao
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
9:20 781. Cross metathesis of (2-alkenylpentenediyl)iron complexes: Applications to the synthesis of 3,6-disubstituted-1,4cycloheptadienes and biscyclopropanes. W. A. Donaldson, R. K. Pandey, N. J. Wallock 9:40 782. Silicon-accelerated alkylation of an aryl organolithium. M. Harmata, P. Zheng 10:00 783. Mechanistic studies of acyloxy and phosphatyloxy migrations in the metalcatalyzed synthesis of furans. T. Schwier, V. Gevorgyan 10:20 784. Alkyllithium reagent insights via 7 Li NMR spectroscopy. D. Slocum, T. Reece, B. McClure, P. Whitley, R. W. Holman 10:40 785. Withdrawn. 11:00 786. Sequential silylcarbocyclization/ silicon-based cross-coupling reactions. S. E. Denmark, J. H-C. Liu 11:20 787. Tandem C-N, C-C bond forming reaction: Applications in the synthesis of diamines, α-amino alcohols and α-amino acid derivatives. A. V. Lee, L. L. Schafer Section D McCormick Place Lakeside Room E351, Level 3
2:00 802. Bitopic fluoroionophores: Fluores cent probes for zinc ion analysis over large dynamic ranges. L. Zhu, L. Zhang 2:20 803. Nanolithography via AFM-mediated "click" chemistry. D. A. Long, K. Unal, R. C. Pratt, M. Malkoch, J. Frommer 2:40 804. Photoisomehzation and fluorescent vaporsensing properties of a dimethylaminostyryl terpyridine derivative (MNpvpt). S. Vaidya, X. Y. Wang, R. H. Schmehl 3:00 805. Photoresponsive azobenzene chromophore-modified multiwalled carbon nanotubes: Synthesis, optical properties and photophysics. W. Feng Sr., Y. Feng 3:20 806. Self-assembled host-guest materi als for organic electroluminescence. P. Anzenbacher Jr. 3:40 807. Structural characterization of phenyl-cored thiophene dendrimers for organic photovoltaics. J. T. Wasacz, N. Kopidakis, W. J. Mitchell, G. Rumbles, S. E. Shaheen, K. A. O. Pacheco 4:00 808. Synthesis of mono- and bi-functionalized dendrimers. P. Goyal, K. Yoon, M. Week 4:20 809. Précipitons: Controlling solubility with light. M. R. Ams, C. S. Wilcox Section Β
Molecular Recognition and Self-Assembly D. Bong,
Presiding
8:00 788. Self-assembly and stability of heterotrimeric collagen mimics. V. Gauba, J. Hartgerink 8:20 789. Synthetic eumelanin. J. M. Belitsky 8:40 790. Use of terahertz time-domain spectroscopy for cocrystal characterisation and quantitative monitoring of cocrystal formation via mechanochemistry. K. L. Nguyen, T. Friscic, G. M. Day, W. Jones, L. F. Gladden 9:00 791. Controlling the nanoarchitechture of self-assembled coiled-coil peptide nanofiber scaffolds. H. Dong, J. Hartgerink 9:20 792. DNA-mediated organization of nanoparticles into discrete assemblies: Control over geometry, modularity, write/ erase and structural switching. H. F. Sleiman, F. A. Aldaye 9:40 793. Hydrogen-bonded helical organic nanotubes: Formation and properties. G. D. Pantos, J-L. Wietor, P. Pengo, J. Κ. Μ. Sanders 10:00 794. Characterization and conforma tional analysis of a melamine dendrimer. K. X. Moreno, E. E. Simanek 10:20 795. Clicked bistable [2]rotaxanes. I. Aprahamian, T. Ikeda, W. R. Dichtel, J. F. Stoddart 10:40 796. Halogen bonding in some halo aromatic compounds. V. R. Vangala, F. C. Pigge 11:00 797. Synthesis and biological evalua tion of novel bifunctional ligands. H-S. Chong, X. Ma, H. Song 11:20 798. Withdrawn. THURSDAY AFTERNOON Section A McCormick Place Lakeside Room E450 A/B, Level 4 Materials, Devices, and Switches P. Ray,
Presiding
1:00 799. Electronic properties and environ mental stability in core-substituted rylene imide semiconductors. B. A. Jones, A. Facchetti, T. J. Marks, M. R. Wasielewski 1:20 800. Individually addressable micronand nano-scale organic light emitting diodes (OLEDs). M. T. Russell, L. S. C. Pingree, M. C. Hersam, T. J. Marks 1:40 801. Aromatic diimides from the DielsAlder trapping of o-methylphenyl ketone derived photoenols: Synthesis and photophysics. M. A. Meador, D. S. Tyson, F. Ilhan
McCormick Place Lakeside Room E451 A/B, Level 4 Physical Organic Chemistry: Calculations, Mechanisms, Photochemistry, and High Energy Species D. G. Kovacs,
Presiding
1:00 810. Confirmation of the bidentate intermediate in the cleavage of highly substituted epoxy alcohols with organoalane reagents: Experimental and theoreti cal NMR studies. G. Torres, Y. Ishikawa, J. A. Prieto 1:20 811. Ab initio study of the kinetics of hydrogen abstraction reactions occurring in the pyrolysis of phenethyl phenyl ether. A. Beste, A. C. Buchanan III, B. C. Hathorn, R. J. Harrison 1:40 812. Competition between Diels-Alder and hetero-Diels-Alder reactions: The effect of Lewis acid catalysis on unsymmetrical bifurcating potential energy sur face. N. Çelebi-Ôlçiim, V. Aviyente, K. N. Houk 2:00 813. Dichlorodiazirine and dichlorocarbene. R. A. Moss, J. Tian, G. Chu 2:20 814. Dynamics in the mechanisms of carbene additions to strained C-C bonds. D. C Merrer 2:40 815. Minding the gap: Variations on the Bergman theme - Electrocyclizations of penta-, hepta- and octa-diynes. C A. Parish 3:00 816. Particle size effects on Ti02mediated photocatalytic degradation. W. S. Jenks, T. Hathway, Y-C. Oh 3:20 817. Photochemistry of oxobutanones: Understanding the role of hydrogen bonding in photoenolization mechanism for the photorelease of alcohols by computational and experimental methods. S. Muthukrishnan, A. Konosonoks, A. D. Gudmundsdottir 3:40 818. Structural implications of the absence of equilibrium isotope shifts in aziridinium imide. B. K. Ohta 4:00 819. Studies on the single-crystal-tosingle-crystal photoarrangement of α-san tonin in the crystalline state by X-ray diffraction. A. Natarajan, C-K. Tsai, S. I. Khan, M. Garcia-Garibay 4:20 820. Synthesis, characterization and identification of tetramethylene diperoxide dicarbamide by direct analysis in real time-mass spectrometry and vibrational spectroscopy. A. J. Pena-Quevedo, L. A. Rivera, F. R. Roman, N. Mina, R. B. Cody, S. P. Hernandez 4:40 821. Theoretical investigations of the mechanism for the rhodium-catalyzed decarbonylation. P. Fristrup, R. Madsen
Section C McCormick Place Lakeside Room E350, Level 3 Metal-Mediated Reactions and Syntheses J. Chao,
Presiding
1:00 822. Palladium-catalyzed oxidative cross-coupling of two different organometallic reagents. Y. Zhao, R. Wang, H. Wang, Y. Hu, X. Hou, H. Zhang, L Zhu, A. Lei 1:20 823. Dienamides as participants in palladium-catalyzed bisdiene carbocyclizations. R. N. Andrews, J. M. Takacs 1:40 824. Heterogeneous Pd/C-catalyzed aromatic amination. Y. Monguchi, K. Kitamoto, S. Mori, T. Yanase, Y. Mizoguchi, T. Ikawa, T. Maegawa, H. Sajiki 2:00 825. Novel redox reactions between sec-alcohols and ketones using Pd/CH 2 0 - D 2 0 . H. Esaki, R. Ohtaki, T. Maegawa, Y. Monguchi, H. Sajiki 2:20 826. Palladium-catalyzed C-H bond arylation with aryl chlorides. H. A. Chiong, O. Daugulis 2:40 827. Palladium-catalyzed synthesis of 9-fluorenylidene derivatives via aryne annulation. S. A. Worlikar, R. C. Larock 3:00 828. Synthesis and transformation of allyl and allenyl-metal species using palla dium pincer complex catalysis. K. J. Szabo 3:20 829. Unprecedented palladium-medi ated carbon-fluorine bond cleavage: Rel evance to the synthesis of fluoroalkene dipeptidomimetics. T. Narumi, E. Inokuchi, K. Tomita, S. Oishi, H. Ohno, N. Fujii 3:40 830. Proximity effects in the palladiumcatalyzed substitution of aryl fluorides. S. Yu, S. Bahmanyar, B. C. Borer, Y. M. Kim, D. Kurtz 4:00 831. Occlusion of Grubbs' metathesis catalysts in PDMS: Serendipitous discov ery of new reactivities in aqueous sol vents. M. T. Mwangi, M. B. Runge, N. B. Bowden 4:20 832. Stereospecific cross-coupling of a-(thiocarbamoyl)organostannanes with alkenyl, aryl, and heteroaryl iodides. J. R. Falck, P. K. Patel, A. Bandyopadhyay Section D McCormick Place Lakeside Room E351, Level 3 Molecular Recognition and Self-Assembly J. M. Belitsky,
Presiding
1:00 833. Membrane activation: Selective vesicle fusion via small-molecule recogni tion. D. Bong 1:20 834. Self-assembled bis-urea macrocycle used as a confined environment for photodimerization of enones. J. Yang, L. S. Shimizu 1:40 835. Self-assembled chromophores as artificial antenna systems. T. S. Balaban 2:00 836. Collagen-related peptides: Selfassembly of short, single strands into a functional biomaterial of micrometer scale. M. A. Cejas, W. A. Kinney, C. Chen, G. C. Leo, T. Brett, J. G. Vinter, P. P. Joshi, B. E. Maryanoff 2:20 837. Concave TTF-type architectures and their self-assembly with fullerenes. E. M. Perez, G. Fernandez, M. Sierra, L Sanchez, E. Ortf, N. Martin 2:40 838. Non-covalently linked and selfassembled zinc porphyrin/zinc naphthalocyanine-SWCNT nanohybrids for photoin duced electron transfer. R. Chitta, A. S. D. Sandanayaka, A. L. Schumacher, L. D'Souza, Y. Araki, O. Ito, F. D'Souza 3:00 839. Anion recognition and transport by a short peptide of alpha-aminoxy acid. X. Li, D.Yang 3:20 840. Boronic acids as sensors for anions. E. K. Galbraith, M. G. Davidson, T. D. James 3:40 841. Dipyrrinones: A new potential use in anion binding chemistry. M. T. Huggins, C. Musto, L. Munro, V. J. Catalano
TECH-101
TECHNICAL PROGRAM
ORGN/PETR 4:00 842. Response-selective fluorescent sensors based on molecular recognition. D. J. Dyer, R. Xu, I. Kimaru, C. Cook, L. Wang, M. E. McCarroll 4:20 843. Synthesis of multivalent tailored glycoconjugates for the specific detection of toxins and pathogens. S. S. Iyer, D. M. Hatch, B. H. Halsall, W. Heineman, A. Jurkeva, R. R. Kale, C. McGannon, K. Schuelter, A. Weiss 4:40 844. Triaroylbenzenes: Versatile supramolecular building blocks. M. K. Dighe, F. C. Pigge
PETR Division of Petroleum Chemistry Y. Wang and J. D. Allison, Program Chairs
3:15 Intermission. 3:30 9. Chemistry and kinetics of gasoline sulfur reduction. B. R. Cook, J. M. McConnachie, T. R. Halbert, J. P. Greeley, R. H. Ernst, G. B. Brignac, R. A. Demmin 4:20 10. Effects of boron and phosphorus addition to NiMo supported on AI203 and carbon nanotubes: Impact on the morphology and activity for hydrotreating of gas oils. A. K. Dalai Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR MONDAY MORNING Section A McCormick Place North Room N426A, Level 4 Chemistry of Sulfur and Desulfurization Oxidation and Membrane Desulfurization
O T H E R S Y M P O S I A OF INTEREST: Automotive Chemistry: More Than Just the Tail Pipe (see SOCED, Sun, Mon) SOCIAL EVENTS: Dinner: Tue Executive Committee: Sat Program Committee: Sat BUSINESS MEETING: Business Meeting: Tue SUNDAY MORNING Section A McCormick Place North Room N426A, Level 4 Chemistry of Sulfur and Desulfurization Hydroprocessing and Catalysis C. L Marshall, C. Song, and J. M. McConnachie, Organizers
C. L Marshall, C. Song, and J. M. McConnachie, Organizers 8:30 Introductory Remarks. 8:35 1 1 . Outlook for energy: View to 2030. J. M. McConnachie 9:25 12. Oxidative desulfurization: A new technology for ULSD. R. Gatan 10:15 13. Oxidative desulfurization of real diesel by using molecular oxygen as an oxidant. X. Wang, X. Ma, R. Sundararaman, L. Sun, C. Song 10:40 Intermission. 10:55 14. Influence of gasoline components on membrane desulfurization performance. L Lin, Y. Kong, K. Xie, J. Yang, D. Shi 11:20 15. Desulfurization performance of crosslinked polyethylene glycol membranes. L. Lin, Y. Kong, K. Xie, J. Yang, D.Shi Automotive Chemistry: More Than Just the Tail Pipe Sponsored by SOCED, Cosponsored with ENVR, FUEL, and PETR
TUESDAY MORNING Section A McCormick Place North Room N426A, Level 4 Advances in Selective Heterogeneous Catalytic Oxidation Microporous, Mesoporous and Molecular-type Catalyst Systems S. T. Oyama,
Organizer
8:25 Introductory Remarks. 8:30 2 1 . Iron(lll) porphyrin catalyzed epoxidation of olefins by hydrogen peroxide: An analysis of the reaction mechanism and the factors affecting catalyst activity and selectivity. A. T. Bell, N. Stephenson 9:00 22. FTIR and UV/vis spectroscopic studies of reaction intermediates during direct propylene epoxidation using H2 and 0 2 over a Au-Ba/Ti-TUD catalyst. S. T. Oyama, J. J. Bravo-Suârez, J. Lu, Κ. Κ. Bando 9:30 23. Hydrocarbon autoxidation chemis try: New mechanism, new opportunities. I. Hermans, E. Breynaert, A. Maes, J. Peeters, P. A. Jacobs 10:00 24. K-OMS-2 Catalyzed liquid phase synthesis of quinoxalines. S. Sithambaram, W. N. Li, Y. Ding, R. Kumar, S. L Suib 10:30 Intermission. 10:40 25. Building block-based catalysts: Tailoring next generation titanosilicates and vanadosilicates. R. T. Mayes, M-Y. Lee, C. E. Barnes 11:10 26. Highly selective catalytic oxidation reactions: I. Oxidative dehydrogenation of propane (ODHP) by size-selected platinum catalysts, and II: Oxidation of alkenes on size-selected silver and gold clusters and nanoparticles. S. Vajda, G. E. Ballentine, S. Mucherie, C. L Marshall, J. W. Elam, M. J. Pellin, B. Lee, C-T. Lo, S. Seifert, R. Winans, J. M. Calo 11:40 27. Cu20/Ce02 nanoparticle systems for CO oxidation. B. White, J. Raitano, A. Hall, S-W. Chan, S. P. O'Brien, N. J. Turro
MONDAY AFTERNOON Section Β Section A
8:30 Introductory Remarks. 8:35 1. Heavy gas oil desulfurization: A review. T. V. Choudhary 9:25 2. Hydrocracking and clean fuels pro duction. S. Abdo 10:15 Intermission. 10:30 3. Desulfurization reactions on metal carbides and phosphides: Complex role of C and Ρ sites. J. A. Rodriguez, P. Liu 11:20 4. Effect of titania addition to bulk Ni 2 P catalysts on HDN of quinoline. M. Lu, A. Wang, X. Li, X. Duan, Y. Teng, Y. Wang, C. Song, Y. Hu 11:45 5. Selective deep desulfurization with less hydrogen consumption in LCO. W. Pang, J-K. Lee, S. Lim, S-H. Yoon, I. Mochida SUNDAY AFTERNOON
Section A McCormick Place North Room N426A, Level 4 Chemistry of Sulfur and Desulfurization Hydroprocessing and Catalysis C. L. Marshall, C. Song, and J. M. McConnachie, Organizers 1:20 Introductory Remarks. 1:25 6. Catalytic distillation: Applications in petrochemical processes. F. T. T. Ng 2:15 7. Hydrogénation and direct desulfurization reaction pathways in thiophene hydrodesulfurization over MoS 2 catalysts at realistic conditions: A density functional study. P. G. Moses, B. Hinnemann, H. Topsoe, J. K. Norskov 2:45 8. Sulfur tolerance of bimetallic alloys: A density functional theory study. R. Nabar, J. M. McConnachie, T. A. Barckholtz, M. Mavrikakis
102-TECH
McCormick Place North Room N426A, Level 4
McCormick Place Lakeside Room E354, Level 3 General Posters
Chemistry of Sulfur and Desulfurization Adsorption Desulfurization C. L. Marshall, C. Song, and J. M. McConnachie, Organizers 1:30 Introductory Remarks. 1:35 16. Selective adsorption of sulfur containing compounds. A. J. Hemandez-Maldonado, Y. Wang, F. H. Yang, A. Jayaraman, Y. Li, R. T. Yang 2:25 17. Effects of loaded metals on adsorptive desulfurization and denitrogenation on activated carbon. J. H. Kim, C. Song 2:50 Intermission. 3:05 18. AgN03 as a desulfurizing adsorbent for light hydrocarbon fuels. L. Li, D. L. King 3:30 19. Selective removal of sulfur from diesel and jet fuels over regenerable multicomponent metal oxide sorbents for fuel cell applications. F. Sun, S. Watanabe, X. Ma, C. Song 3:55 20. Improvement of desulfurization capacity of nickel-based adsorbent for jet fuel by adding alkanol. J. L. demons, X. Ma, C. Song 4:20 Concluding Remarks.
Please refrain from using cellular telephones and cameras during technical sessions.
Y. W a n g ,
Organizer
9:00-11:00 28. Catalytic liquefaction of rice husk on nanoparticle Cl-/Zr02. Z. Le, H. Zhang, R. Ruan, L Hong 29. Characterization of Ce-modified HZSM-5 zeolite. H. Yu, L. Luo, L Sun, H. Li, D. Xia, R.Lv 30. CO Oxidation over silica-based Au cata lysts. H. Zhu, S. H. Overbury, S. Dai 31. Direct oxidation of propane to acrolein over Si02 supported MoBiTe mixed oxide catalyst. Y. He, Y. Wu, X. Yi, X. Zhang, F. Ying, W. Weng, H. Wan 32. Effect of different types inocula on the anaerobic digestion of cattle manure. Z. Xiang, L. Jindun 33. Interaction asphaltene-resin study by fluorescent resonance energy transference (FRET). S. Suarez Torres Jr., H. Flores Ramirez Sr., E. Santos Santos, E. Buenrostro Gonzâle Jr., J. A. Aburto Anel Sr., E. F. Lejarazo Gomez Jr., R. Baena Mancilla 34. Investigation on a new reformulated oxygenate of EGMEE as an oxygenated diesel fuel. H. Guo, L Li, S. Liu, L Zhou, J. Chen 35. Microfibrous entrapment of supported catalysts in microreactors for hydrogen production from ammonia decomposition. S. Zhao, W. R. Ashurst, D. R. Cahela, B. J. Tatarchuk 36. Optimization of two-stage riser catalytic cracking in Yumen Petrochemical Factory. Y. Xinghua, L. Chunyi, Y. Chaohe, S. Honghong, S. Yunchao, L. Yonghong
37. Preparation, characterization and ethane oxidative dehydrogenation performance of nanostructured Zr-Ni-O. Y. Wu, Y. He, T. Wu, W. Weng, H. Wan 38. Reaction of n-alkanes in the presence of activation-catalysts. K. Bayasgalan, V. Bembel, A. K. Golovko, S. Bat-Ochir 39. Refining highly paraffinic crude oil by a liquefied gas. D. Badamdorj, A. Golovko, V. Surkov, T. Mumeren 40. Research on change of family composition and properties of Gudao paving asphalt on aging. L. Liu 41. Study on reaction rules of decreasing FCC gasoline olefin content. X. Yan, Y. Yuxia, Z. Suoqi, L Chunyi, Y. Chaohe, S. Honghong, Z. Jianfang 42. Study on the catalytic reaction of Di-nbutyl sulfide over ZSM-5 zeolite. L. Sun, H. Yu, L Luo, H. Li, D. Xia, R. Lv 43. Supported Pt-Ce catalysts for water gas shift reaction. H. C. Lee, D. Lee, Y. Potapova, K. H. Lee, E-Y. Ko, Ε. D. Park, S. Kim 44. Synthesis and characterization of a novel soluble binuclear carboxyl metal phthalocyanine. Y. Zhang Sr. 45. The characterization and selective hydro génation of supported nickel-cerium catalyst. R. Lu TUESDAY AFTERNOON Section A McCormick Place North Room N426A, Level 4 Advances in Selective Heterogeneous Catalytic Oxidation Monolayer and Bulk Catalyst Systems R. Radhakrishnan,
Organizer
1:25 Introductory Remarks. 1:30 46. Operando spectroscopy of propylene oxidation to acrolein over well-defined supported vanadia catalysts. C. Zhao, I. E. Wachs 2:00 47. Role of excess Mo03 in iron-molybdate methanol oxidation catalysts. K. Routray, I. E. Wachs 2:30 48. Is there a relationship between the M = 0 bond length (strength) of bulk mixed metal oxides and catalytic activity? K. Routray, L. Briand, I. E. Wachs 3:00 Intermission. 3:10 49. Thermal transformation of the Mo-V-Te-0 M1 to M2 phases: Synthesis, structural characteristics and catalytic performance in propane ammoxidation. P. Korovchenko, V. Guliants, M. O. Guerrero-Perez 3:40 50. On cooperation of the Mo-V-TeNb-0 M1 and M2 phases in propane ammoxidation to acrylonitrile. P. Korovchenko, V. Guliants 4:10 5 1 . Effect of metal substituents on the structure and performance of Mo-V based mixed oxide system in propane ammoxidation. N. R. Shiju, V. Guliants 4:40 52. A kinetic and spectroscopic study of reaction intermediates during acetone oxidation with ozone. S. T. Oyama, C. Reed, Y. Xi, Y-K. Lee WEDNESDAY MORNING Section A McCormick Place North Room N426A, Level 4 Chemistry of Petroleum and Emerging Technologies J. F. Schabron and N. W . Standish, Presiding 8:30 Introductory Remarks. 8:35 53. Studies on the catalytic pyrolysis of C4 hydrocarbon to ethylene and propylene. X. Yan, L. Xiaohong, Z. Suoqi, L. Chunyi, Y. Chaohe, S. Honghong, Z. Jianfang 9:05 54. Zeolites with uniform intracrystal mesopore as cracking catalyst. H. Wang, T. J. Pinnavaia 9:35 Intermission.
PETR/PHYS 9:50 55. Issues in the production and con version of lignocellulosic biomass crops to ethanol. H-J. G. Jung, B. S. Dien, K. P. Vogel 10:20 56. Low-temperature pyrolysis of bioethanol wheat residue. J. M. Andresen, Z. Zulhisham Faizal 10:50 57. Research on a new peanut oil monoester as a clean diesel engine fuel. H. Guo, D. Jiang, S. Liu, J. Chen, L Zhou 11:20 Concluding Remarks.
PHYS Division of Physical Chemistry G. A. Voth, Program Chair
Section C
SOCIAL EVENT: Ahmed Zewail Prize in Molecular Sciences Reception: Mon
WEDNESDAY AFTERNOON Section A
SUNDAY MORNING
McCormick Place North Room N426A, Level 4
McCormick Place South RoomS401D, Level 4 Biophysics of RNA RNA Structure J. D. Puglisi and J . R. Williamson, Organizers
9:50 30. Formation of polymeric fences in planar model membranes: An experimen tal platform for the study of hop diffusion. A. P. Siegel, M. J. Murcia, J. Ruehe, C. A. Naumann 10:10 Intermission. 10:30 3 1 . Lighting up liquid/liquid interfaces. P. R. Unwin, S. E. Dale, F. Li 11:10 32. Dynamic adsorption of the azacrown ethers at the liquid-liquid interface. K. Wojciechowski 11:50 33. Effects of reorientation in vibra tional sum frequency spectroscopy. J. Fourkas, R. A. Walker, E. Gershgoren Biological Surface Chemistry Lipid Bilayers Sponsored by COLL, Cosponsored with PHYS
Section A
Chemistry of Petroleum and Emerging Technologies T. R. Gallant and P. R. Robinson, Presiding 1:30 Introductory Remarks. 1:35 58. Asphaltene determinator: On-column precipitation and redissolution of asphaltenes. J. F. Schabron, J. F. Rovani Jr. 2:05 59. Evaluation of solubility parameters for oils that contain no asphaltenes. P. Rahimi, Y. D. Oh, R. McNamara, T. Alem, I. A. Wiehe 2:35 60. Mechanistic investigation of a highly fouling crude oil. P. Rahimi, Y. D. Oh, R. McNamara, T. Alem, I. A. Wiehe 3:05 Intermission. 3:15 6 1 . Novel thin-films platinum electrodes with excellent oxygen reduction and methanol oxidation properties. A. Bose, D. Thati, R. Subramanian 3:45 62. Surface modification effects of silica support by organic solvents for FischerTropsch synthesis catalysts. Y. Zhang, K. Hanayama, N. Tsubaki 4:15 63. Oil generating potential of coals from lower Benue trough, Nigeria. O. S. S. Sojinu, O. Sonibare THURSDAY MORNING Section A McCormick Place North Room N426A, Level 4 Chemistry of Petroleum and Emerging Technologies P. Rahimi and P. O'Connor,
11:00 14. Contributions from mechanical and electrical anharmonicities to NIR VCD spectra. S. Abbate, G. Longhi, R. Gangemi, F. Gangemi 11:20 15. Calculation of molecular chiroptical properties using density functional theory. J. R. Cheeseman
Presiding
8:30 Introductory Remarks. 8:35 64. Thermal decomposition processes of kerogen from molecular dynamics simulations using the ReaxFF reactive force field. E. Salmon, F. Lorant, F. Behar, A. C. van Duin, W. A. Goddard III 9:05 65. Powerwave an enhanced oil recov ery technology. T. Spanos 9:35 66. Characterization of asphaltenic deposits. A. M. Kharrat 10:05 Intermission. 10:15 67. Withdrawn. 10:45 68. Studies on conversion of CGO by two-stage riser fluid catalytic cracking. Y. Qi Min, L. Chun yi, Y. Chao he, W. Yi Hang, Z. Zhao tao, S. Hong hong
A. R. Ferré-D'Amaré, McCormick Place South Room S401B/C, Level 4 Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Spectroscopy as a Probe of Dynamics J. E. Straub,
Organizer
M. T. Zanni, Organizer,
Section Β McCormick Place South RoomS401A, Level 4 Implications and Applications of Chirality in Physical Chemistry Theory and Computation of Chiroptical Properties
8:00 16. Structural basis of glmS ribozyme activation by its coenzyme glucosamine-6phosphate. A. R. Ferré-D'Amaré, D. J. Klein 8:40 17. Structural and mechanistic studies of riboswitch RNAs. R. T. Batey 9:20 18. Progress toward accurate 3-D structure prediction of nucleic acids. J. SantaLucia Jr. 10:00 Intermission. 10:20 19. The RNA Ontology Consortium. N. B. Leontis 10:40 20. Chaperone-assisted RNA crystallography: selection and cocrystallization of FAB-P4P6 complex. J. A. Piccirilli 11:20 2 1 . Structural studies of RNase P, a universal ribozyme. A. Mondragon, A. Torres-Larios, Κ. Κ. Swinger, A. S. Krasilnikov, T. Pan Section D McCormick Place South Room S402A, Level 4 Measures of Accuracy and Reliability in Molecular Simulation Materials Simulation Cosponsored with COMP R. Friesner and T. E. Cheatham III, Organizers J. J. De Pablo,
Presiding
8:20 22. Multiscale modeling of polymeric materials in external fields. J. J. de Pablo 9:00 23. Verification and validation in molecular simulations: From first principles to empirical potentials. J . I. Siepmann 9:40 24. Molecular dynamics simulation for predicting the solubility of the anticancer drug docetaxel in pharmaceutical excipi ents. L. K. Huynh, J-C. Leroux, P. Delmas, C. Allen 10:00 25. Accuracy and practicality in pre dicting structures and properties from first principles. W. A. Goddard III 10:40 26. Accuracy and validity of firstprinciples-based simulations of materials behavior. E. A. Carter 11:20 27. Wide-angle solution X-ray scatter ing as benchmark of molecular dynamics simulations for supramolecules: From cyclodextrin to DNA. X. Zuo, G. Cui, K. M. Merz Jr., D. M. Tiede
P. H. Vaccaro and Κ. Β. Wiberg, Organizers
McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Transport/Reactivity Cosponsored with COLL R. A. Walker,
McCormick Place South Room S401 B/C, Level 4 Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Spectroscopy as a Probe of Dynamics M. T. Zanni and J . E. Straub, G. Haran,
Organizers
Presiding
1:20 34. Dynamics of protein folding. W. A. Eaton 2:00 35. Coherent interferometric detection of infrared emission from bacteriorhodopsin. J-L. Martin, M. H. Vos, M. Joffre 2:40 36. Connecting the wiggling and jiggling of atoms to measurements: Capturing differences in local solvent structure around peptides. G. Gnanakaran, D. Paschek, S. M. Decatur, A. E. Garcia, R. Hochstrasser 3:00 Intermission. 3:20 37. Vibrational spectroscopic probe of a global-scale biological system: NASA's Orbiting Carbon Observatory. P. L. DeCola, C. E. Miller, D. Crisp 3:40 38. Terahertz spectroscopy and model ing of biosystems and materials. E. J. Heilweil 4:00 39. Cysteine-based vibrational probes of local structure and dynamics. C. H. Londergan, M. Maienschein-Cline, C. Reynoso 4:20 40. Beta-amyloid peptide dimer forma tion and structure by fluorescence reso nance energy transfer and correlation microscopy. J. Han, E. Mei, M-P. Kung, H. F. Kung, H-L. Dai 4:40 4 1 . Probing allostery with time-resolved UV resonance raman spectroscopy: Ter tiary and quaternary motions in hemoglo bin. G. Balakrishnan, C. Ho, T. G. Spiro Section Β McCormick Place South RoomS401A, Level 4 Implications and Applications of Chirality in Physical Chemistry Linear Chiroptical Spectroscopy
P. H. Vaccaro,
Presiding
8:00 9. From cosmic chirality to molecular structure and behavior: Lord Kelvin's legacy. L. D. Barron 8:40 10. First principles simulations of vibronic structure in Circular-Dichroism spectra. M. Nooijen 9:20 11. Resonance vibrational raman opti cal activity within time-dependent density functional theory. L Jensen, G. C. Schatz 9:40 12. Induced VCD analyzed in terms of molecular orbital contributions. V-P. Nicu, J. Neugebauer, J. Autschbach, E. J. Baerends 10:00 Intermission. 10:20 13. Modeling solvent effects on chirop tical properties. K. Ruud
Section A
T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers
Section Ε
T. D. Crawford, Organizer,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Presiding
8:00 Introductory Remarks. 8:10 1. Probing ligand dynamics in heme proteins with time-resolved vibrational spectroscopy, time-resolved X-ray crystal lography, and MD simulations. P. A. Anfinrud, F. Schotte, G. Hummer 8:50 2. Force spectroscopy of proteins at surfaces. G. C. Walker, S. Zou, P. Y. Meadows 9:30 3. Dynamics and conformations of a Gly-Ala dipeptide by 2-D infrared spectros copy. P. Foggi, M. Candelaresi, R. Chelli, J. D. Palmer 9:50 Intermission. 10:10 4. Resonance hyper-Raman spectros copy of nonlinear optical chromophores. A. M. Kelley 10:30 5. Correlation between side chain helix propensity and fast folding dynamics of α-helical peptides. M. Volk, A. Pozo Ramajo, J. Wang, C. Palmer, E. Fouts, E. A. Gooding 10:50 6. Probing osmolyte induced perturba tions of hydration shell waters and hydra tion shell-dependent protein properties in solution and sol-gel matrices. J. M. Friedman, C. J. Roche, F. Guo, D. Dantsker, U. Samuni 11:10 7. Two-color infrared hole burning experiments in phospholipid membranes. V. V. Volkov, D. J. Palmer, R. Righini 11:30 8. Polarized stimulated emission depletion in the EGFP chromophore. A. J. Bain, T. A. Masters, R. J. Marsh, D. A. Armoogum, B. Larijani
SUNDAY AFTERNOON
Presiding
Organizer
M. L. Schlossman, Organizer,
Presiding
8:20 Introductory Remarks. 8:30 28. Molecular dynamics studies of the structure of the liquid/liquid interface: Implications for charge transfer reactions. I. Benjamin 9:10 29. Functionalized interfaces for photoenergy conversion. Η. Η. Girault, M. Hojeij, B. Su
Presiding
1:20 42. Concerted application of density functional theory calculations of vibrational circular dichroism, electronic circular dichroism, and optical rotation to the determination of absolute configuration. P. J . Stephens, F. J. Devlin, J. J. Pan 2:00 43. Absolute configuration of bioactive flexible natural products from DFT optical rotations based on Monte Carlo conforma tional search and ab initio geometries. R. J. Doerksen, S. Odde, A. Xie, R. Mohamed, R. Stanikunite, Z. Bie, M. T. Hamann, S. A. Ross 2:20 44. Probing the chiroptical response of a single molecule. M. D. Barnes 3:00 45. Chirality effects on the excited-state proton transfer reactions. K. M. Solntsev, L M. Tolbert, D. Huppert
TjECH-103
TECHNICAL PROGRAM
PHYS 3:20 Intermission. 3:40 46. Complimentarity in chiroptical spectrosopic methods. P. L. Polavarapu 4:20 47. Sum-over-states calculations of optical rotation. K. B. Wiberg, Y-G. Wang 4:40 48. Advances in the theoretical formal ism of natural and magnetic vibrational optical activity. L. A. Nafie
3:00 Intermission. 3:20 64. Surface hydration dynamics and protein-water interactions. D. Zhong 4:00 65. Computational studies of hydrogen bonded liquid interfaces. L. X. Dang 4:40 66. Molecular interactions at the oil/ aqueous interface. C. L. McFearin, G. L. Richmond
Section C
Section Β
Section F McCormick Place South Room S401D, Level 4
J. D. Puglisi and J . R. Williamson, Organizers X. Zhuang,
Presiding
1:20 49. Single-molecule studies of nucleic acid-protein interactions. X. Zhuang 2:00 50. Folding of a Mg(l Independent Riboswitch. K. B. Hall 2:40 5 1 . A comparative study of nucleic acid dynamics using solution and solid state NMR. G. P. Drobny, P. Miller, Z. Shajani, G. Goobes, D. Caplow, G. Varani 3:20 Intermission. 3:40 52. Measuring nanometer distances in nucleic acids using a sequence-indepen dent nitroxide probe. P. Z. Qin, Q. Cai, I. S. Haworth, A. K. Kusnetzow, W. L Hubbell, G. P. Gacho 4:00 53. Kinetics, thermodynamics, and spectroscopy of intermolecular domain docking in the hairpin ribozyme. C. G. Hoogstraten, M. Sumita, J. E. Johnson Jr., K. R. Julien 4:40 54. Stretching RNA. D. Thirumalai Section D McCormick Place South Room S402A, Level 4 Measures of Accuracy and Reliability in Molecular Simulation Enzyme and Ribozyme Function Cosponsored with COM Ρ R. Friesner and T. E. Cheatham III, Organizers D. M. York,
Presiding
1:20 55. Theoretical studies of ribozyme catalysis. D. M. York 2:00 56. On accuracy and reliability in simu lations of enzyme catalysis. A. Warshel 2:40 57. Toward accurate descriptions of phosphate hydrolysis reactions with QM/MM approach. Y. Yang, Q. Cui 3:00 58. Evaluation of recent methods for examining macromolecular systems. B. R. Brooks, J. B. Klauda, H. L Woodcock III, X. Wu 3:40 59. Is the Ewald summation still neces sary? Pairwise alternatives to the accepted standard for'long-range electrostatics. J. D. Gezelter, C. J. Fennell 4:20 60. "Proton holes" in long-range proton transfer reactions in solution and enzymes. D. Riccardi, P. Koenig, Q. Cui Section Ε McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Structuring of Water Cosponsored with COLL M. L. Schlossman,
McCormick Place South RoomS401A, Level 4
McCormick Place South Room S406A, Level 4
Biophysics of RNA Dynamics
10:50 76. Towards a molecular movie: Tran sient 2-D-IR spectroscopy of peptide dynamics. P. Hamm, C. Kolano, J. Helbing, J. Bredenbeck, M. Kozinski, W. Sander 11:30 77. Using optical pulses as smart reagents in chemical transformation: A case study. R. J . Sension
Capturing Complexity in Physical Sciences Simulation Chemical Kinetics and Dynamics Cosponsored with COMP C. Wolverton and K. Raghavachari, Organizers
Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry Solar Photon Conversion Cosponsored with PRES, and SUST A. Nozik,
Organizer
M. Cardillo, W . F. Schneider, Organizer,
Presiding
1:20 Introductory Remarks. 1:25 67. Simulations of interfacial structures and dynamics. W. L. Hase, Ο. A. Mazyar, L. L. Dai 2:05 68. Automatically and correctly captur ing complexity in chemical kinetic simula tions. W. H. Green Jr. 2:45 69. Formation of perfluorocarboxylic acids, CxF2x+1C(0)OH, during the atmo spheric oxidation of fluorotelomer alcohols (n-CxF2x+1CH2CH20H). T. J. Wellington, M. D. Hurley, J. Xia, D. J. Wuebbles, S. Sillman, A. Ito, J. E. Penner, D. A. Ellis, J. Martin, S. A. Mabury, O. J. Nielsen, M. P. Sulbaek Andersen 3:05 Intermission. 3:15 70. The multiscale challenge in the formation of carbonaceous nanoparticles. A. Violi 3:55 7 1 . New electronic structure methods for large reactive radicals and diradicals. M. Head-Gordon 4:35 72. Mechanism of PH 3 -induced surface chemistry on InP compound semiconduc tor surfaces. U. Das, K. Raghavachari Biological Surface Chemistry Lipid Bilayers Sponsored by COLL, Cosponsored with PHYS MONDAY MORNING Section A McCormick Place South Room S401B/C, Level 4 Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Multidimensional Infrared Spectroscopy M. T. Zanni and J . E. Straub, M. A. El-Sayed,
Organizers
Presiding
8:20 Introductory Remarks. 8:30 73. Award Address (Ahmed Zewail Award in Ultrafast Science and Technol ogy, sponsored by Ahmed Zewail Endow ment Fund). 2-D Infrared spectroscopy. R. M. Hochstrasser 9:10 74. Relaxation-assisted 2-D IR spec troscopy. D. V. Kurochkin, S. R. G. Naraharisetty, I. V. Rubtsov 9:50 Intermission. 10:10 75. 2-D infrared probes of peptide structure and dynamics. N-H. Ge
8:00 78. Scientific challenges in sustainable energy technology. N. S. Lewis 8:40 79. Mesoscopic injection solar cells. M. Graetzel 9:20 80. The Power of the Sun: A film. W. Kohn 10:20 Intermission. 10:40 8 1 . Hybrid-nanorod polymer solar cells. A. P. Alivisatos 11:20 82. Third generation solar photon conversion. A. J. Nozik Section C McCormick Place South Room S401D, Level 4 Biophysics of RNA RNA-Protein Complexes J. D. Puglisi and J . R. Williamson, Organizers A. L. Feig,
Presiding
8:00 83. Thermodynamic analysis of kissing hairpins and hairpin-bulge interactions involved in ncRNA mediated gene regula tion. A. L. Feig 8:40 84. RNA and protein structural require ments in NCp7 chaperoned HIV-1 DIS maturation. J . P. Marino 9:20 85. RNA base replacements: Studying sequence recognition in RNA interference. E. T. Kool 10:00 Intermission. 10:20 86. Crystal structures of IRE-mRNA regulatory sequences and protein repres sor, IRP1. E. C.Theil 10:40 87. Cryo-Em results on mRNA-tRNA translocation in the 80S ribosome. J. Frank, D. Taylor, J. Nilsson, R. Jorgensen, R. Merrill, G. R. Andersen, P. Nissen 11:20 88. Decoding by the ribosome: Energy landscapes and conformational changes. K. Y. Sanbonmatsu, A. Vaiana, S. Joseph, C-S. Tung Section D McCormick Place South Room S402A, Level 4 Measures of Accuracy and Reliability in Molecular Simulation Simulation Methods/Force Fields Cosponsored with COMP R. Friesner and T. E. Cheatham III, Organizers
Organizer R. M. Levy,
R. A. Walker, Organizer,
Presiding
Presiding
1:20 6 1 . Combining surface nonlinear spec troscopy and molecular dynamics simula tions to understand molecular structure and bonding at a series of liquid-liquid interfaces. G. L. Richmond 2:00 62. Structure, dynamics, and solvation at aqueous interfaces. S. Garde 2:40 63. Hydrophobic size effects measured by single molecule force spectroscopy. C. Ray, J. R. Brown, B. B. Akhremitchev
104-TECH
Presiding
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
8:20 89. Effective interactions in condensed phase systems. G. A. Voth 9:00 90. Quantity begets quality: Assessing and enhancing sampling adequacy in molecular dynamics simulations. D. E. Shaw 9:40 9 1 . Agreement with the Maxwell-Boltzmann distribution can be a flawed diag nostic for both accuracy and temperature in molecular dynamics simulations. R. B. Shirts, S. R. Burt, A. M. Johnson
10:00 92. Accuracy and reliability in biomo lecular simulations: How accurate, reliable, and efficient is the replica exchange simu lation method? R. Levy, A. K. Felts, E. Gallicchio, M. Andrée, W. Zheng 10:40 93. Connecting NMR relaxation parameters to MD simulations: A new look at an old problem. D. A. Case 11:20 94. Increasingly accurate implicit solvent models: What will it take? J. M. Swanson Section Ε McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Nanoparticles Cosponsored with COLL M. L. Schlossman,
Organizer
R. A. Walker, Organizer,
Presiding
8:20 95. Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles. B. P. Binks 9:00 96. Formation of nanocrystalline ultrathin films of materials liquid-liquid interface. C. N. R. Rao 9:40 97. Specific and nonspecific solvation at liquid interfaces. M. R. Brindza, R. A. Walker 10:00 Intermission. 10:20 98. Particle deposition and assembly at the liquid/liquid interface. A. I. Campbell, R. A. Dryfe, H. Ho, K. Luo 11:00 99. Nanoparticle to microparticle to live nerve cell tissue aqueous interfaces. Κ. Β. Eisenthal Section F McCormick Place South Room S406A, Level 4 Capturing Complexity in Physical Sciences Simulation Condensed Matter Cosponsored with COMP W. F. Schneider and K. Raghavachari, Organizers C. M. Wolverton, Organizer,
Presiding
8:20 100. Computational quantum con densed matter physics, then and now: In memory of Ken Hass. A. J. Freeman 9:00 101. Density-functional based simula tion of spin-ordered molecular magnets. M. R. Pederson 9:40 102. First principles predictions of structure and cohesion of alumina grain boundaries. I. Milas, B. Hinnemann, E. A. Carter 10:00 Intermission. 10:15 103. Simulations of the long time scale evolution of defects in solids. H. Jonsson, G. Henkelman, A. Pedersen, J-C. Berthet 10:55 104. A practical approach to the pre diction of crystal structure by merging data-mining methods with first principles quantum mechanics. G. Céder, C. Fischer, D. Morgan 11:35 105. Predicting the future. B. Goodman Biological Surface Chemistry Lipid Bilayers Sponsored by COLL, Cosponsored with PHYS Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Sponsored by COLL, Cosponsored with PHYS
PHYS MONDAY AFTERNOON
Section D
Section A
McCormick Place South Room S402A, Level 4
McCormick Place South Room S402B, Level 4 Ahmed Zewail Prize in Molecular Sciences Intermolecular Forces S. S. Hall and K. Nederveen, D. C. Clary,
Organizers
Measures of Accuracy and Reliability in Molecular Simulation Protein-Ligand Interactions Cosponsored with COMP R. Friesner and T. E. Cheatham III, Organizers
Presiding M. P. Jacobson,
1:20 Introductory Remarks. 1:25 106. Toward a first principles' universal potential energy surface for water from VRT spectroscopy of clusters. R. J . Saykally 2:15 107. Ab initio intermolecular force fields tested by spectroscopy: State of the art. A. van der Avoird 3:05 Intermission. 3:10 108. 4-D Visualization of chemical and biological forces. A. H. Zewail 4:00 Award Presentation, D. C. Clary. 4:10 109. Award Address (Ahmed Zewail Prize in Molecular Sciences, sponsored by Elsevier). Intermolecular forces. A. D. Buckingham 5:10 Concluding Remarks. Section Β McCormick Place South Room S401B, Level 4
Presiding
1:20 121. Hybrid quantum/classical molecu lar dynamics of hydrogen transfer reac tions in enzymes. S. Hammes-Schiffer 2:00 122. Strengths and limitations of implicit solvent models for studying protein-ligand interactions. M. P. Jacobson 2:40 123. Realistic, quantitative descriptions of electron-transfer reactions: Diabatic free-energy surfaces from first-principles molecular dynamics. P. H-L. Sit, M. Cococcioni, N. Marzari 3:00 124. Accuracy in QM/MM simulations of organic and enzymatic reactions. W. L. Jorgensen, J. Tirado-Rives 3:40 125. Describing fundamental properties of protein-ligand binding through database mining. H. A. Carlson 4:20 126. Assessing the accuracy of free energies calculated by molecular simula tion. D. A. Kofke Section Ε
Realizing the Full Potential of Solar Energy Conversion through Basic Research in Chemistry and Biochemistry Solar Fuels and Biofuels Cosponsored with PRES, and SUST A. Nozik, Organizer,
Presiding
1:20 110. Solar fuels: A reaction chemistry of renewable energy. D. G. Nocera 2:00 111. Sensitizer-modified proteins for solar-driven water splitting. H. B. Gray, J. L Dempsey, C. Shih, Κ. Μ. Lancaster, C. Wilson, J. R. Winkler 2:40 Intermission. 3:00 112. Biomass recalcitrance: Barrier to economic ethanol biorefineries. M. E. Himmel, W. S. Adney, S-Y. Ding, D. K.Johnson 3:40 113. Nature's renewable energy blue print: Future fuel from biomimics and microbial cell factories. G. C. Dismukes 4:20 114. Photobiological and bio-hybrid hydrogen production based on the activity of hydrogenase enzymes. M. Ghirardi Section C McCormick Place South Room S401D, Level 4 Biophysics of RNA Catalytic RNAs
P. C. Bevilacqua,
Organizers
Presiding
1:20 127. Investigations of Raman coher ence and ligand binding in heme and heme proteins. P. M. Champion 2:00 128. Ultrafast infrared studies of com plex organometallic reactions. C. B. Harris 2:40 129. Vibrational spectra of simple hydrogen bonded crystals by inelastic scattering of neutrons and X-rays. H. P. Trommsdorff, M. Johnson 3:00 130. 2-D Electronic spectroscopy. G. R. Fleming 3:40 Intermission. 4:00 131. Influence of environment and substrate binding on the dynamics of heme proteins. I. J. Finkelstein, H. Ishikawa, S. Kim, M. D. Fayer 4:40 132. Self-assembly where kinetics trumps thermodynamics. D. Chandler Section F
J. D. Puglisi and J . R. Williamson, Organizers Presiding
1:00 115. Catalytic mechanism of the hairpin ribozyme. M. J. Fedor, Y. I. Kuzmin, C. P. Da Costa, J. W. Cottrell 1:40 116. Folding of rRNA shapes the early steps of 30 S ribosome assembly. T. Adilakshmi, D. L. Bellur, P. Ramaswamy, S. A. Woodson 2:20 117. Physical studies of RNA-metal ion interactions. M. Harris 3:00 Intermission. 3:20 118. Diels-Alder ribozyme catalysis: A computational approach. X. Zhang, T. C. Bruice 3:40 119. General acid-base catalysis and pKa shifting in RNA: Insights from ribozymes and model oligonucleotides. P. C. Bevilacqua, T. S. Brown, D. M. Chadalavada, J. T. Lecomte, E. M. Moody, S-l. Nakano, N. A. Siegfried, R. Yajima 4:20 120. The structure and catalytic mecha nism of the VS ribozyme. D. M. Lilley, T. J. Wilson, J. Ouellet, J. Lipfert, A. McLeod
McCormick Place South Room S406A, Level 4 Capturing Complexity in Physical Sciences Simulation Catalysis and Surfaces Cosponsored with COMP W . F. Schneider and C. M. Wolverton, Organizers K. Raghavachari, Organizer,
Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Sponsored by COLL, Cosponsored with PHYS The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Sponsored by INOR, Cosponsored with PHYS Undergraduate Research Poster Session: Physical Chemistry Sponsored by CHED, Cosponsored with SOCED, and PHYS M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center
G. A. Voth,
Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Spectroscopy as a Probe of Dynamics
C. V. Shank,
Biological Surface Chemistry Protein Adsorption and AFM Sponsored by COLL, Cosponsored with PHYS
Sci-Mix
McCormick Place South Room S401B/C, Level 4
M. T. Zanni and J . E. Straub,
3:55 137. Modeling light interaction with materials: Techniques to successfully incorporate chemistry and physics in molecular simulation. P. F. Conforti, M. Prasad, B. J. Garrison 4:35 138. Investigation of NO oxidation catalysis on Pt(111) with regard to reaction conditions. R. B. Getman, W. F. Schneider
Presiding
1:20 133. Inspiration to materials design from density functional theory calculations? J. K. Norskov, M. Andersson, J. P. Greeley, T. Bligaard, C. H. Christensen 2:00 134. Simulating the complexity in catalysis. M. Neurock 2:40 135. Simulating supported catalysts in realistic environments. W. F. Schneider, Y.Xu 3:00 Intermission. 3:15 136. Capturing complexity in catalysis using transition metal complexes: Methane to methanol conversion and enantioselective ring opening of terminal epoxides. C. B. Musgrave, A. Paul, L. P. C. Nielsen, E. N. Jacobsen
Foundations of Surface Chemistry: Symposium in Honor of 2007 ACS Award Winners John T. Yates, Hans-Joachim Freund, Charles T. Campbell, Bruce E. Koel Sponsored by COLL, Cosponsored with PHYS The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Sponsored by INOR, Cosponsored with PHYS TUESDAY AFTERNOON Section A McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Nanoparticles Cosponsored with COLL M. L. Schlossman and R. A. Walker, Organizers A. I. Campbell,
Organizer
8:00-10:00 257, 268, 270, 280, 282, 293, 296, 301, 364, 366, 371, 388, 398, 401, 413, 422, 424, 429, 434, 456, 465, 483, 493, 519, 523, 528, 532, 557, 565. See subsequent listings. Biological Surface Chemistry Posters Sponsored by COLL, Cosponsored with PHYS TUESDAY MORNING Section A McCormick Place South Room S406A, Level 4 ACS National Awards in Physical Chemistry: Symposium in Honor of Rodney J. Bartlett, Michael D. Fayer, Jean H. Futrell, Keith E. Gubbins, John T. Yates, Xiaowei Zhuang G. A. Voth,
11:40 144. Award Address (Joel Henry Hildebrand Award in the Theoretical and Experimental Chemistry of Liquids, spon sored by ExxonMobil Research and Engi neering Company). Confinement effects on chemical reactions: Toward an inte grated rational catalyst design. K. E. Gubbins, E. E. Santiso, M. K. Kostov, L S. Huang, A. M. George, M. B. Nardelli
Organizer
8:20 139. Award Address (Frank H. Field and Joe L. Franklin Award for Outstanding Achievement in Mass Spectrometry, spon sored by Waters Corporation). Tandem mass spectrometry studies of collisional activation and dissociation of complex polyatomic ions. J. H. Futrell 9:00 140. Award Address (Peter Debye Award in Physical Chemistry, sponsored by E. I. du Pont de Nemours & Company). Alkanethiol surface chemistry on Au(111): New insight into self assembly using the low temperature STM. J . T. Yates Jr., D. C. Sorescu, P. Maksymovych 9:40 141. Award Address (ACS Award in Theoretical Chemistry, sponsored by IBM Corporation). Coupled-cluster theory in quantum chemistry: The emergence of a new paradigm. R. J. Bartlett 10:20 142. Award Address (ACS Award in Pure Chemistry, sponsored by Alpha Chi Sigma Fraternity and the Alpha Chi Sigma Educational Foundation). Single-molecule imaging of biomolecular and cellular pro cesses. X.Zhuang 11:00 143. Award Address (E. Bright Wil son Award in Spectroscopy, sponsored by the American Chemical Society). Ultrafast 2-D infrared vibrational echo chemical exchange spectroscopy studies of chemi cal processes. M. D. Fayer, J. Zheng, K. Kwak
Presiding
1:20 145. Directed self-assembly of nanopar ticles at oil/water interfaces. T. P. Russell, J. He, Q. Zhang, S. Gupta, T. Emrick, Z. Niu, Q. Wang 2:00 146. Withdrawn. 2:40 147. Novel even-order nonlinear spec troscopy for liquid interfaces: Interfacespecific hydrogen bonds and interfacial polarity. S. Yamaguchi, S. Sen, T. Tahara 3:00 Intermission. 3:20 148. X-ray study of the electric double layer at the n-hexane/nanocolloidal silica interface. A. M. Tikhonov 4:00 149. Assembly of nanopàrticle at polymeric interfaces: Strong supramolecular interactions as ordering principles. W. H. Binder, R. Zirbs, C. Kluger, M. Josipovic 4:40 150. Investigating the mechanism of protein solvation by isotropic membrane mimetics. G. Krilov Section Β McCormick Place South Room S401A, Level 4 Implications and Applications of Chirality in Physical Chemistry Theory and Computation of Chiroptical Properties T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers J. R. Cheeseman,
Presiding
1:20 151. Chirality in NMR spectroscopy. A. D. Buckingham 2:00 152. Static and dynamic contributions to ORD and CD. M. L. Abrams, T. D. Crawford 2:20 153. Solvation and selectivity at chiral interfaces. N. M. Cann, C. Zhao, S. Nita
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-105
TECHNICAL PROGRAM
PHYS 3:00 154. Mechanism of chiral separations in 2-D systems. I. Paci, I. Szleifer, M. A. Ratner 3:20 Intermission. 3:40 155. Time-dependent density-functional computations of CD and ORD of organic molecules and metal complexes. J. Autschbach 4:20 156. Computation of the electronic circular dichroism of polypeptides and oligoureas. J. D. Hirst 4:40 157. Studies of chirality at the interface between theory and experiment. D. N. Beratan, P. Wipf, G. Zuber, P. Mukopadhyay, M-R. Goldsmith Section C McCormick Place South Room S401D, Level 4 Biophysics of RNA RNA Folding J. D. Puglisi and J . R. Williamson, Organizers T. Pan,
Presiding
1:20 158. Structural determination of RNA folding intermediates. T. Pan 2:00 159. Traversing the RNA folding land scape. D. Herschlag 2:40 160. Distinct contribution of electrostat ics, initial conformational ensemble and macromolecular stability in RNA folding. M. Brenowitz, A. Laederach, I. Shcherbakova, M. Jonikas, R. B. Altman 3:20 Intermission. 3:40 161. Cooperative tertiary interactions determine the speed and accuracy of RNA folding. S. Chauhan, S. A. Woodson 4:00 162. Early events in RNA folding: Ionnucleic acid interactions. L. Pollack 4:40 163. New RNA-binding peptidomimetic structures that repress HIV viral replication by specifically inhibiting Tat-dependent transcriptional activation. G. Varani
Section Ε
WEDNESDAY MORNING
McCormick Place South Room S401B/C, Level 4
Section A
Capturing Complexity in Physical Sciences Simulation Oxides and Hydrides Cosponsored with COMP C. M. Wolverton and K. Raghavachari, Organizers W . F. Schneider, Organizer,
McCormick Place South Room S406A, Level 4 Dynamics on the Nanoscale Quantum Dots
Presiding
Presiding
Biological Surface Chemistry Nonlinear Optics Sponsored by COLL, Cosponsored with PHYS The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Sponsored by INOR, Cosponsored with PHYS T U E S D A Y EVENING The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Sponsored by INOR, Cosponsored with PHYS
Please refrain from using cellular telephones and cameras during technical sessions.
106-TECH
Measures of Accuracy and Reliability in Molecular Simulation Protein Dynamics, Solvation, and Association Cosponsored with COMP
Organizers
Presiding
8:20 182. Control of vibrational population transfer in a dense fluid. S. A. Rice 9:00 183. Enzyme dynamics in binary and ternary complexes of formate dehydroge nase. C. M. Cheatum, J. N. Bandana, S. Dutta, S. E. Hill, A. Kohen 9:40 Intermission. 10:00 184. Temperature dependence of ultrafast structural dynamics in pure water: A 2-D-IR photon echo study. R. J. D. Miller 10:40 185. Multidimensional correlation spectroscopies: From NMR to X-rays. S. Mukamel, W. Zhuang, D. Abramavicius, D. Voronine, T. Hayashi, L. Yang, R. Oszwaldowski, I. Schweigert 11:20 186. Linear and nonlinear infrared spectroscopy for frustrated system below and above the freezing temperature. Y. Tanimura Section Β
T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers
Organizer
1:20 176. Structural and chemical transfor mations in nanocrystals. A. P. Alivisatos 2:00 177. Light harvesting and carrier trans port in core/barrier/shell semiconductor nanocrystals. P. Kambhampati, E. A. Dias, S. L. Sewall 2:20 178. Nanoscale phenomena in solids and liquids investigated by first principles. G. Galli 3:00 179. Carrier dynamics and multiple exciton generation in semiconductor nanocrystals: Applications to third genera tion solar photon conversion. A. J . Nozik, R. J. Ellingson, M. C. Beard, J. C. Johnson, J. Luther, K. A. Gerth, M. Hanna 3:40 180. Photoexcitation and electron transfer in quantum dots at surfaces: A density matrix treatment of their dissipative dynamics. D. A. Micha, A. Leathers 4:00 181. Photogeneration and recombina tion of multiexcitons in nanocrystal quan tum dots in relation to solar energy con version. V. I. Klimov
1:20 164. Using Folding ©home distributed computing for high precision tests of accuracy in protein kinetics and thermody namics. V. S. Pande 2:00 165. Can molecular dynamics simula tions accurately model conformational changes in proteins? C. L. Simmerling 2:40 166. Conformation and dynamics of a three-helix bundle from experiment and simulation. J. D. Hirst 3:00 167. Activity coefficient comparisons of forcefields: High precision chemical poten tials of urea. B. M. Pettitt, H. Kokubo 3:40 168. Simulations of peptide inhibitors of Amyloid-beta aggregation. J-E. Shea 4:20 169. Fretting about FRET: Correlation between κ and ft D. B. VanBeek, M. C. Zwier, J. M. Short, B. P. Krueger
M. T. Zanni and J . E. Straub,
Implications and Applications of Chirality in Physical Chemistry Emerging Probes of Chiral Molecules and Their Interactions
O. V. Prezhdo, Organizer,
C. L. Simmerling,
McCormick Place South Room S402A, Level 4
McCormick Place South RoomS401A, Level 4
Section F
McCormick Place South Room S402A, Level 4
R. Friesner and T. E. Cheatham III, Organizers
Section D Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Multidimensional Infrared Spectroscopy
J. B. Asbury,
Section D
Measures of Accuracy and Reliability in Molecular Simulation Protein Dynamics, Solvation, and Association Cosponsored with COMP
McCormick Place South RoomS401B/C, Level 4
Presiding
1:20 170. Predicting the thermodynamics and initial kinetics of complex hydride systems. J. K. Johnson, S. Alapati, B. Dai, D. S. Sholl 2:00 171. Novel combinations of high density hydrogen storage materials. C. Wolverton, A. Sudik, J. Yang, D. Siegel 2:20 172. First-principles density functional studies of high-performance hydrogen storage materials. V. Ozolins, A. Akbarzadeh, E. H. Majzoub, D. Siegel, C. Wolverton 3:00 Intermission. 3:15 173. Computational search for dehydrogenation pathways and destabilization schemes in complex metal hydrides. D. J. Siegel, C. Wolverton, V. Ozolins 3:35 174. Oxidation mechanism and ferryl formation on alpha-Fe203 (0001) surface. A. M. Chaka, E. A. A. Jarvis 4:15 175. The surface science of T i 0 2 : Insights from first principles simulations. A. Selloni
P. J . Reid,
11:20 198. Studying RNA-ligand interactions using fluorescent oligonucleotides. Y. Tor 12:00 199. Simulations of the nascent pep tide in the ribosome exit tunnel. V. S. Pande
M. D. Barnes,
A. E. Roitberg,
Presiding
8:20 200. Molecular excited state electron transfer dynamics in the condensed phase. P. J. Rossky 9:00 201. Beyond force fields: Sampling and folding with QM and QM/MM hamiltonians. G. D. M. Seabra, R. C. Walker, A. E. Roitberg 9:40 202. Coarse-grained modeling of the self-assembly of proteins. H. Hwang, G. C. Schatz, M. A. Ratner 10:00 203. Protein dynamics and solvation from molecular simulations: Comparison to time-resolved and high-pressure X-ray crystallography. G. Hummer 10:40 204. Biomolecular solvation: From molecular to continuum models. F. Dong, J. A. Wagoner, N. A. Baker 11:20 205. Alternative binding modes in Orf2 catalyzed prenylation: Identification and validation. G. Cui, X. Li, K. M. Merz Jr. Section Ε McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Ionic and Electrical Phenomena Cosponsored with COLL
Presiding
8:00 187. Chiral recognition in jet-cooled complexes. A. Zehnacker-Rentien, K. Le Barbu-Debus 8:40 188. Experimental measurements with chiral synchrotron radiation. C. Sanders, R. W. Hansen, P. A. Snyder 9:00 189. Exploring chirality and chiral recog nition on the molecular level using experi mental spectroscopic and ab initio meth ods. Y. Xu 9:40 Intermission. 10:00 190. Photoelectron circular dichroism from randomly oriented enantiomers. I. Powis 10:40 191. Intrinsic optical activity: Influence of conformational effects and solutesolvent perturbations. P. H. Vaccaro, K. B. Wiberg, S. M. Wilson, Y-G. Wang, J. R. Cheeseman, M. J. Frisch 11:00 192. Coherent control of chiral sys tems. P. Brumer 11:40 193. New approaches to optical activ ity measurements. P. Fischer, A. Ghosh Section C McCormick Place South Room S401D, Level 4 Biophysics of RNA Structure and Dynamics J. D. Puglisi and J . R. Williamson, Organizers S. E. Butcher,
R. Friesner and T. E. Cheatham III, Organizers
Presiding
8:20 194. Structural studies of the core spliceosomal RNAs. S. E. Butcher 9:00 195. Structural studies of the splicing machinery by electron cryomicroscopy. H. Stark 9:40 196. Single molecule fluorescence and force study of the hairpin ribozyme. T. Ha 10:20 Intermission. 10:40 197. NMR studies of RNA folding and dynamics. H. Schwalbe
M. L. Schlossman and R. A. Walker, Organizers P. Vanysek,
Presiding
8:20 206. Electrowetting with electrolytes. M. Urbakh, C. W. Monroe, L. I. Daikhin, A. A. Komyshev 9:00 207. X-ray scattering from an electrolyte interface. G. Luo, S. Malkova, J. Yoon, D. Schultz, B. Lin, I. Benjamin, P. Vanysek, M. L. Schlossman 9:40 208. Structure of the interface between two immiscible liquids and interfacial tension. A. G. Volkov, M. I. Volkova, V. S. Markin 10:00 Intermission. 10:20 209. Effect of counter ion size and charge on the structure of amphipiles adsorbed at a liquid-liquid interface using neutron reflectometry. A. Zarbakhsh, J. R. P. Webster 11:00 210. Electrochemical and spectro scopic investigation of the room tempera ture ionic liquid/aqueous interface. J. B. Rollins, B. D. Fitchett, J. C. Conboy 11:40 211. Orientation of surface-active ions at the interface between water and a hydrophobic room-temperature ionic liquid studied by optical second harmonic gen eration spectroscopy. N. Nishi, R. Ishimatsu, M. Yamamoto, T. Kakiuchi Section F McCormick Place South Room S406A, Level 4 Dynamics on the Nanoscale Carbon Nanotubes O. V. Prezhdo,
Organizer
P. J. Reid, Organizer,
Presiding
8:20 212. Single carbon nanotube photonics and the role of excitons. T. D. Krauss, L. Huang, L. Carlson
9:00 213. Heat conduction in molecular junctions: A unified approach. M. Galperin, A. Nitzan, M. A. Ratner 9:20 214. Photoexcitation dynamics in chiral enriched single wall carbon nanotubes. G. Lanzani 10:00 215. Exciton dynamics in carbon nanotubes and nanotube aggregates. T. Hertel, J. Crochet, Z. Zhu, M. Arnold, M. C. Hersam 10:40 216. SWCNT based nanostructured hybrid assemblies for next generation solar cells. P. V. Kamat, F. Vietmeyer, A. Kongkanand 11:00 217. Theoretical study of photoexcited dynamics in conjugated polymers and carbon nanotubes. S. Tretiak Arthur W. Adamson Award for Distinguished Service in the Advancement of Surface Chemistry: Symposium in Honor of Charles T. Campbell Sponsored by COLL, Cosponsored with PHYS Biological Surface Chemistry Polymer Interfaces Sponsored by COLL, Cosponsored with PHYS The Proton: New Physical and Structural Aspects of Acidity and H-Bonding Sponsored by INOR, Cosponsored with PHYS WEDNESDAY AFTERNOON Section A McCormick Place South Room S401B/C, Level 4 Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Vibrational Probes of Biomolecules M. T. Zanni and J . E. Straub, K. J . Kubarych,
Organizers
Presiding
1:20 218. Peptide solvation, aggregation dynamics, and amyloid morphology via isotope-edited infrared spectroscopy. S. M. Decatur 2:00 219. Infrared study of the hydration, folding and aggregation of short peptides. F. Gai 2:40 220. Folding dynamics of isotopically labeled beta-hairpin peptides. K. Hauser, C. Krejtschi, R. Huang, T. A. Keiderling 3:00 Intermission. 3:20 221. IR- and fluorescence-detected fast folding dynamics. M. Gruebele 4:00 222. Direct observation of specific protein vibrations. F. Romesberg 4:40 223. Vibrational stark effect probes: Calculation and measurement of electro static fields in human aldose reductase using a nitrile probe. L. J. Webb, V. Oklejas, D. L. Ensign, V. S. Pande, S. G. Boxer Section Β McCormick Place South RoomS401A, Level 4 Implications and Applications of Chirality in Physical Chemistry Chiral Surfaces and Structures T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers Ν. Μ. Cann,
Presiding
1:20 224. Raising flags: Chemical marker group STM probes of self-assembly and chirality at liquid-solid and vacuum-solid interfaces. G. W. Flynn 2:00 225. Enantiospecific adsorption in chiral gold nanoclusters. I. L. Garzon, X. Lopez-Lozano, L. A. Perez 2:20 226. Optical rotation and circular extinc tion in single crystals, mixed crystals, and polycrystals. B. Kahr 3:00 Intermission. 3:20 227. Theoretical studies of chiral adsorption on flat and chiral metal sur faces. D. Sholl, B. Bhatia, J. N. James
4:00 228. Optical circular dichroism of bare and passivated Au chiral nanoclusters. C. Noguez, A. Sanchez-Castillo, F. J. Hidalgo, O. Pulci, R. Del Sole, I. L. Garzon 4:20 229. Chelation-enhanced circular dichroism as a tool to study stereodynamic molecules in solution. J. W. Canary 5:00 230. Dynamic chiroptical inversion of metallo-peptide complex upon achiral nitrate anion. H. Miyake, H. Kamon, H. Sugimoto, H. Tsukube
Section Ε
Section C
1:20 243. Modeling realistic nanostructures with maximally-localized Wannier func tions. N. Marzari 2:00 244. Nanoscale dielectrics: Physical and dielectric properties from first prin ciples. R. Ramprasad, N. Shi, C. Tang 2:40 245. Monte Carlo-based simulations of the formation of graphite oxide. J. T. Paci, T. Belytschko, G. C. Schatz 3:00 Intermission. 3:15 246. Atomic scale design of nanostruc tures. J. Bernholc 3:55 247. Simulation of nano and biomolecu lar systems. K. Morokuma 4:35 248. Meshing multiple length scales "on-the-fly" in molecular simulation. C. M. Taylor
McCormick Place South Room S402A, Level 4 Measures of Accuracy and Reliability in Molecular Simulation Force Fields/Simulation Methods Cosponsored with COMP R. Friesner and T. E. Cheatham III, Organizers A. D. MacKerell Jr.,
Presiding
1:20 231. Effects of different ensembles in molecular dynamics. B. J . Berne 2:00 232. Optimization and validation of a polarizable force field based on the classi cal Drude oscillator. A. D. MacKerell Jr. 2:40 233. The dielectric constant of liquid NMA from a polarizable Drude oscillator model. E. Harder, V. M. Anisimov, A. D. MacKerell Jr., B. Roux 3:00 234. Extending the reach of molecular force fields. W. Damm, J. Maple, M. Reboul, T. A. Halgren 3:40 235. Improved force fields and simula tion methodologies for biological macromolecules. C. L Brooks III 4:20 236. Nucleation: A new challenge to current force fields. R. B. Nellas, M. E. McKenzie, S. J. Keasler, B. Chen Section D McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Surfactants Cosponsored with COLL M. L. Schlossman and R. A. Walker, Organizers P. B. Moore,
Presiding
1:20 237. Thermodynamic and structure studies of adsorbed films at oil/water interfaces. M. Aratono, T. Takiue, H. Matsubara, S. V. Pingali, A. M. Tikhonov, M. L Schlossman 2:00 238. Tuning liquid-liquid and liquid-solid interfaces with carbon dioxide. K. P. Johnston, S. Adkins, X. Chen, J. Dickson, G. Gupta, M. Patel, T. Milner, P. J. Rossky 2:40 239. Self-assembly of lipids and pro teins at the aqueous-liquid crystal inter face. M-V. Meli, J. M. Brake, J. K. Gupta, S. Teren, N. L. Abbott 3:00 Intermission. 3:20 240. Molecular origins of interfacial activity at the crude oil-water interface. R. Varadaraj 4:00 241. Water next to model biomem branes. M. L. Berkowitz, S. Bhide 4:40 242. Interaction of HIV-1 N-terminal peptide with erythrocyte membrane mim ics. C. Liu, A. Ivankin, I. Kuzmenko, M. T. Dohm, D. Gidalevitz
McCormick Place South Room S406A, Level 4 Capturing Complexity in Physical Sciences Simulation Nanotechnology Cosponsored with COMP W. F. Schneider and K. Raghavachari, Organizers C. M. Wolverton, Organizer,
Section F McCormick Place South Room S401D, Level 4 Dynamics on the Nanoscale Polymers P. J . Reid,
Organizer
O. V. Prezhdo, Organizer,
Presiding
1:20 249. Exciton dynamics in supramolecular nanostructures. C. Silva 2:00 250. Interplay between microstructure and activity in organic photovoltaic materi als studied with ultrafast multidimensional infrared vibrational spectroscopy. J. B. Asbury, L W. Barbour, M. Hegadorn 2:20 251. Spectroelectrochemistry studies of the charging and discharging of single conjugated-polymer nanoparticles. P. F. Barbara, A. J. Bard, R. Palacios, F-R. F. Fan 3:00 252. Lattice theory of excitonic and charge-transfer dynamics in DNA. E. R. Bittner 3:40 253. Exciton dynamics in poly(3hexylthiophene) measured by ultrafast fluorescence upconversion. N. P. Wells, D. A. Blank 4:00 254. Understanding how solvent struc ture and counterion distribution control quantum solvation in liquids. B. J. Schwartz Arthur W. Adamson Award for Distinguished Service in the Advancement of Surface Chemistry: Symposium in Honor of Charles T. Campbell Sponsored by COLL, Cosponsored with PHYS Biological Surface Chemistry Fluidics, Patterning, and Biofilms Sponsored by COLL, Cosponsored with PHYS W E D N E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center General Posters Experiment: Spectroscopy and Imaging, Interfaces, Condensed Matter, Kinetics G. A. Voth,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Presiding
Organizer
7:30-10:00 255. Adsorption behavior of HtBDC on Cu(100). C. Skibo, R. Schlittler, J. K. Gimzewski 256. Amine ligand exchange kinetics of cad mium selenide semiconductor nanocrystals. C. G. Handford, J. Thessing, X. Peng
257. ANNs optimization of preparation condi tion of LB high temperature shift catalyst under lower steam to gas ratio. W. Lingchao, W. Fuan 258. Application of microsphere templating to create porous optical fiber claddings for crossed-fiber sensor arrays. P. E. Henning, M. V. Rigo, P. Geissinger 259. Bioinspired water oxidation catalysts for renewable energy production. R. Brimblecombe, J. Scarino, G. Swiegers, G. C. Dismukes, L Spiccia 260. Circular dichroism laser mass spectrom etry of 3-methylcyclopentanone. A. Bornschlegl, U. Boesl 261. C 0 2 primary gas mixtures: gravimetric preparation and verification by internal consistency. J-Y. Lee, J. B. Lee, D. M. Moon, H-S. Yoo, J. S. Kim 262. Comparative study of the photochemical reaction of cyclohexane and cyclohexene with chromyl chloride and ozone. M. D. Hoops, B. S. Ault 263. Comprehensive study of the kinetics and mechanisms of the oxidation of thiourea and its metabolites by oxychlorine species. R. H. Simoyi, E. Chikwana, M. K. Morakinyo, A. Otoikhian, B. S. Martincigh 264. Computational and spectroscopic investi gation of 7-azaindole: Solvation and intermolecular interactions. M. Z. Kamrath, K. M. Cruse, N. R. Erickson, J. M. Smith 265. Continuous wave cavity ringdown spec troscopy (CW-CRDS) of C6o in the mid-IR at 8.5pm using a quantum cascade laser and a slit-jet expansion source. B. E. Brumfield, S. L. Widicus Weaver, S. S. Howard, C. F. Gmachl, B. J. McCall 266. Continuous-wave cavity ringdown spec troscopy of molecular ions in a fast ion beam. S. L. Widicus Weaver, A. A. Mills, B. J. McCall 267. Cyclophanes as a means for removal of PAHs from solution. T. Buthelezi 268. Design and characterization of cyanoaza heterocycles for use as η-type organic semiconductors materials. J. Gallegos, P. G. Rasmussen, A. H. Francis 269. Detection of hydroperoxy and compound I species in the oxidative reactions of myoglobin. H. D. Arbelo, J. Lopez-Garriga 270. Determination of 222 cryptand-ion bind ing selectivities with DFT Methods, NMR spectroscopy, and X-ray crystallography. J . W. Su, R. R. Bumette 271. Development of 3,5-dimethyljulolidine as a conformationally-restricted donor in electron donor-acceptor systems. S. M. Mickley, B. Cohen, A. M. Vega, M. R. Wasielewski 272. Effect of the Gouy phase on the coher ent control of the ionization and dissocia tion of molecules. V. J. Barge, Z. Hu, R. J. Gordon 273. Electron hopping in multi-chromophore systems studied by ENDOR spectroscopy. T. M. Wilson, M. J. Tauber, J. M. Giaimo, M. R. Wasielewski 274. Electronic spectrum of tantalum hydride. T. D. Varberg, T. Vervoort, K. J. Manke 275. Energy and electron transfer from an organic free radical. E. M. Schierloh, B. Cohen, M. R. Wasielewski 276. Energy levels of oligothiophenes in the higher excited triplet states. Y. Oseki, M. Fujitsuka, M. Sakamoto, X. Cai, T. Majima 277. Excited-state double proton transfer for 11-propyl- 6H- indolo [2, 3-b] quinoline in dimer, hetero-dimmer with 7-azaindole and in protic solvents. P. T. Chou, M-L. Ho 278. Excited-state triple proton relay in the cyclic complexes of 7-hydroxyquinoline(alcohol) 2 . O-H. Kwon, Y-S. Lee, S. Y. Park, D-J. Jang 279. Exploring nucleotide-cation interactions at various conditions. Z. Song, J. Eady, R. Sutton, A. Sims 280. Femtosecond laser photodisruption of the trabecular meshwork as a possible treatment for glaucoma. T. E. Witt, Y. Liu, R. J. Gordon, H. Nakamura, D. Edward 281. Fluorine NMR investigation of the aminofluorene-induced conformational heteroge neity in translesion synthesis. F. Liang, B.Cho 282. Hydrophobic size effects measured by single molecule force spectroscopy. C. Ray, J. R. Brown, B. B. Akhremitchev
PHYS 283. Imaging of surface-enhanced raman scattering "hotspots" by the photochemical reduction of a self-assembled monolayer. M. A. Young, R. P. Van Duyne 284. Indirect anodic oxidation of 2-methylnaphthalene to 2-methylnaphthoquinone1,4. S. Chengying, L. Zhisheng, W. Liucheng, Z. Jianhong, Z. Mingxing 285. Infrared absorption spectroscopy of the 14N2+ Meinel system 2-1 band. B. Negru, M. Wiczer, S. L. Widicus Weaver, J. P. DiGangi, B. A. Tom, B. J. McCall 286. Infrared scattering and absorption char acteristics of multi-component aerosols. S. M. McGinty, G. Dickey, R. F. Niedziela 287. Inter- and intramolecular forces in deuterofluorocarbons. D. L. M. Suess, G. P. O'Donoghue, D. P. Richardson, J. W. Thoman Jr. 288. Intercalations of organic molecules into organic solids. R. A. Hickerson, A. Beatty 289. Interfacial structure and dynamics in organic photovoltaics: From solar cells to single molecules. M. L. Blumenfeld, J. M. Tyler, O. L. A. Monti 290. Investigating the effect of zwitterions on the cybotactic region of polar cosolvent molecules in scC0 2 . S. G. Mayer, J. D. Heser, S. F. Knackstedt, G. M. Portillo, J. M. Siegel 291. Investigation of the interaction between polyoxometalates and oxide surfaces. J. Bean, J. Valenstein, K. Pontarelli, C. M. Teague 292. Investigation of the intermolecular inter actions of HCFC-21 and HCFC-22 with OCS and CO2 by microwave spectroscopy and ab initio calculations. R. A. Peebles, A. L. Steber 293. Investigation of the silk of the common Chilean tarantula, Grammostola rosea, using solid state NMR spectroscopy. M. F. Cuddy II, T. Link, B. A. Lawrence 294. Investigation on reverse water-gas shift over La2Ni04 catalyst by cw-cavity enhanced absorption spectroscopy during CH4/C02 reforming. B. Liu, L Li, C. Au, A. S. C. Cheung 295. Investigations of non-polar interactions in the antifreeze activity of random alanine/ lysine polypeptides. A. Wierzbicki, C. A. Knight, P. A. Cziko 296. Ion calorimetry: Using mass spectrom etry to measure melting points. C. M. Neal, A. K. Starace, M. F. Jarrold 297. Ions at the air/water interface: Inhibition or enhancement of neutral solute adsorp tion? K. A. Lawrence, C. L. Huffman 298. Kinetic law in direct electrosynthesis process of chromium trioxide from sodium chromate. C. Li, T. Qi, F. Wang, Y. Zhang, G. Chen, P. Zhang 299. Laser amplification materials by develop ing hybrid glasses doped with (Erbiumions/CdSe) nanoparticles. Κ. Μ. Choi 300. Laser-induced phosphorescence and cavity Ringdown spectroscopy for real time in situ detection of glyoxal at atmospheri cally relevant concentrations. A. J. Huisman, J. R. Hottle, M. M. Galloway, F. N. Keutsch 301. Leucyl-tRNA synthetase protein domain tethers differentially impact chemical activities. A. P. Mascarenhas, S. A. Martinis 302. Localized surface plasmon resonance modifications by dipole coupling in 2-D silver nanoparticle arrays. J. Sung, E. C. McLellan, R. P. Van Duyne, K. G. Spears 303. Localized surface plasmon resonance study of Rhodamine 6G on noble metal surface. J. Zhao, L. Jensen, G. C. Schatz, R. P. Van Duyne 304. Maxwell-Boltzman statistics applied to the temperature dependent ro-vibrational spectra of HCI/DCI. J. M. Siegel, G. M. Portillo, S. G. Mayer 305. Measurement and correlation of solubili ties for six sulfonamides in water from (298.15 to 333.15) K. Z. Congliang, W. Yan, W. Fuan 306. Mechanism for the ablation of Si111 with pairs of ultrashort laser pulses. S. Singha, Z. Hu, Y. Liu, R. J. Gordon 307. Molecular dynamics of bridge molecules in covalently bound donor-bridge-acceptor (D-B-A) systems. A. Butler, Z. E. X. Dance, J. V. Lockard, A. M. Vega, M. R. Wasielewski
108-TECH
TECHNICAL PROGRAM 308. Multi cyclic electrochemical alloying/ dealloying approach to uniform nanoporous gold film. F. Jia, L. Zhang 309. Multilayer assemblies for light energy conversion. M. Hojeij, N. Eugster, B. Su, H. H. Girault 310. Non-exponential relaxations of poly(cyclohexyl acrylate): Comparison of singlemolecule and ensemble fluorescence studies. C-Y. J . Wei, D. A. Vanden Bout 311. Nonphotochemical laser induced nucleation from a supercooled thermotropic liquid crystal. X. Sun, B. A. Garetz, M. Moreira, P. Palffy-Muhoray 312. Oriented growth of pentacene films on self-assembled monolayer-modified silicon oxide surfaces. W-S. Hu, Y-T. Tao, H-H. Wang 313. Oxidation of a dimethylthiourea metabo lite by iodine and acidified iodate: N, N'-dimethylaminoiminomethanesulfinic acid. R. H. Simoyi, A. Otoikhian, J. L. Petersen 314. Oxyhalogen-sulfur chemistry: Kinetics and mechanism of oxidation of /acetylthiourea by chlorine and chlorine dioxide. R. H. Simoyi, O. Olagunju, R. O. Olojo, P. D. Siegel 315. Perylene diimide cyclophanes as models for charge transfer through ir stacks. J. Vura-Weis, M. A. Ratner, M. R. Wasielewski 316. Phase transition of adsorbed film of 1-tetradecanol at perfluorohexane/water interface. K. Kashimoto, H. Matsubara, M. Aratono, T. Takiue 317. Photochemical inhibition of the enzyme histidase by PUVA therapy. J. T. Reilly, K. Troester 318. Photodissociation dynamics of 1,2dibromoethane at 234nm and 267nm by means of ion velocity imaging. J. R. Greene, X. Yang, J. Huang, W. M. Jackson, J. S. Francisco 319. Photodissociation dynamics of hydrated adenine cluster cations. H. S. Park, S. H. Nam, J. K. Song, S. Ryu, S. M. Park 320. Photophysical properties of novel carbaporphyrins. J. Brgoch, D. L Cederîo 321. Pi-stacked nanostructures bearing charge-separating triads with long-lived radical pair states. J. Bullock, R. F. Kelley, B. Cohen, M. R. Wasielewski 322. Piping hot research: Construction of an acoustic array. Ο. Μ. Ezeokoli, A. Turns, D. K. McGill 323. Plasmonic properties of copper nanopar ticles fabricated by nanosphere lithogra phy. G. H. Chan, J. Zhao, G. C. Schatz, R. P. Van Duyne 324. Protein-mediated DNA charge transport in a nucleosome core particle. W. B. Davis, C. C. Bjorklund 325. Quantum dot-based energy transfer to photodynamic therapy agents. S. Dayal, N. L. Oleinick, M. E. Kenney, C. Burda 326. Raft domain coupling in planar model membranes. S. Garg, J. Ruehe, K. Luetke, R. Jordan, C. A. Naumann 327. Reactions of rVOX(CH 3 CN) n ] + with H 2 0 and 0 2 . C. A. Deakyne, H. M. Thomas, C. M. Leavitt, M. J. Van Stipdonk 328. Single molecule fluorescence activation, enhancement and decay in CdSe quan tum dots: A warning from the nanoworld to the life sciences. S. F. Lee, M. A. Osborne 329. Single-molecule fluorescence imaging of the remote T i 0 2 photocatalytic reaction. T. Tachikawa, K. Naito, M. Fujitsuka, T. Majima 330. Solvation dynamics of chiral and achiral anthracene derivatives. Ν. Μ. Dickson, T. L. Gustafson 331. Solvation of carboxylic acids at the organic-water interface studied by vibra tional sum frequency spectroscopy. D. K. Beaman, G. L. Richmond 332. Solvent dependence of tris(2,2'-bipyridyl) dichloro-ruthenium(ll) hexahydrate lumi nescence. R. A. Vogt 333. Solvent effects on dye structure and electron transport properties in semicon ducting nanocrystalline T i 0 2 . J. A. Downing, D. Zhang, J. L. McHale 334. Spectroscopic investigation of ternary CTAB reverse micelles in cyclohexane: Initial insights into the dynamics of water in these confined environments. K. A. Fransted, C. T. Cooper, B. S. Lynn, B. L Gourley
335. Spectroscopy and femtosecond dynam ics of excited-state proton coupled charge transfer reaction. Y-M. Cheng 336. Structural changes of alkanethiol selfassembled monolayers from gas-phase collisions. N. A. Kautz, D. P. Fogarty, S. A. Kandel 337. Structure of a 1,2-dichloroethane(BTPPATPFB)/water(NaCI) interface. J. Yoon, B. Hou, G. Luo, C-H. Chen, N. Laanait, B. Lin, P. Vanysek, M. L. Schlossman 338. Study of changes in the green band of polyfluorene emission spectrum using single molecule technique. Y. H. Kim, D. A. Vanden Bout 339. Study on green electrosynthesis of chromium trioxide from potassium dichromate and removal of contaminants in membrane. C. Li, T. Qi, F. Wang, Y. Zhang, G. Chen 340. Synthesis and crystal structure of dehy drated sodium zeolite Y (FAU), INa71l[Si121AI710384]-FAU. S. M. Seo, G. H. Kim, Y. H. Kim, J. J. Kim, S. O. Ko, O. S. Lee, W. T. Lim 341. Synthesis and crystal structure of Pbl2 in the sodalite cavities of zeolite A (LTA). G. H. Kim, H. S. Lee, S. M. Seo, Y. J. Choi, S. Y. Choi, W. T. Lim 342. Synthesis and crystal structure of Znl2 in the sodalite cavities of zeolite A (LTA). S. M. Seo, G. H. Kim, H. S. Lee, J. H. Choi, W. T. Lim 343. Synthesis of solid super acid catalyst TÏ02/S042- using to ptoydimethylsiloxane. Z. Jianhong, Z. Mingxing, W. Liucheng, S. Chengying, L Zhisheng 344. Temperature and pressure dependence of the light and heavy water ultraviolet absorption band edge. T. W. Marin 345. Temperature dependent magnetic field effects on charge recombination of a new p-oligophenyl-linked donor-bridge-acceptor system. A. M. Vega, M. J. Ahrens, M. R. Wasielewski 346. Templated vesicles as optical nanosensors. I. A. Banerjee, M. Henricus 347. The mechanism of radiationless deactivation in unsymmetric rhodamine dyes: Influence of two different electron donating groups. X. Song, J. W. Foley 348. Thermodynamic properties of cyclophane-anthracene systems. T. Buthelezi, K. Milner, C. Davies 349. Thermodynamic studies of Congo red and thioflavin Τ dye binding to insulin amyloid fibrils using isothermal titration calorimetry. C. C. Kitts, D. A. Vanden Bout 350. Toward understanding Hofmeister effects: Partitioning of ions between bulk aqueous solution and biopolymer surface. L. M. Pegram, Μ. Τ. Record Jr. 351. Triplet excited states of cyclic enones characterized by vibronically resolved laser spectroscopy. L. M. Hoffelt, M. G. Springer, S. Drucker 352. Unimolecular dissociation and photodis sociation dynamics of aniline + -(water) n (n=1-16) cluster cations. S. H. Nam, H. S. Park, J. K. Song, S. M. Park 353. X-ray reflectivity study of lipid monolay ers at the electrified 1,2-dichloroethane/ water interface. B. Hou, J. Yoon, C-H. Chen, N. Laanait, B. Lin, P. Vanysek, M. L. Schlossman Section Β Hyatt Regency Chicago Riverside Center General Posters Theory: Electronic Structure, Kinetics, Thermodynamics, Statistical Mechanics G. A. Voth,
Organizer
7:30-10:00 354. A density functional theory (DFT) study of the CO frequency on Pt/Au bimetallic clusters. M. M. Sadek, L. Wang 355. A Monte Carlo study of hydrogen stor age in charged metal-organic framework materials. A. C. Stern, J. L. Belof, M. Eddaoudi, B. Space 356. A novel nucleotide flipping mechanism for the human DNA. J . Hu 357. A theoretical examination of the isomerization pathways for ΗΒ1Ό3 isomers. S. Guha, J. S. Francisco
358. Ab initio molecular orbital study of allyl radicals and DMPO/OH spin adduct. A. J. I. Perkowski, M. Danilczuk, J. E. Stevens, S. Schlick 359. Accuracy in theoretical excited-state dipole moments. R. A. King 360. Analytical representation of the BeckeRoussel exchange functional combined with new meta-GGA correlation functional. E. Proynov, J. Kong 361. Application of the electrostatically embedded many-body method to the study of water clusters. Ε. Ε. Dahlke, D. G. Truhlar 362. Aromatic molecular structure probed by the comparison of density functional calcu lations with INS spectra and crystal diffrac tion. N. Verdal, S. A. Rivera, C. Middleton, W. Ouellette, B. S. Hudson 363. Calculation of the heat capacity of NO + at high temperatures. L. Biolsi 364. Carbon-13 NMR shifts of nonprotonated carbon atoms of aromatic amino acids in peptides and proteins. D. Mukkamala, Y. Zhang, H. Sun, F. Cheng, E. Oldfield 365. Cluster models of trinuclear rhenium adsorbed on gamma-AI203 surface. W. Lin, W. F. Schneider 366. Coarse-grained modeling of self-assem bly processes in peptide amphiphiles systems. Y. Jung 367. Computation of the lithium hydride + molecular hydrogen interaction energy. B. K. Taylor, S. A. Moss 368. Computational DFT binding affinities and photoelectron spectra of small ligated gold clusters. J. M. Roden, Ο Μ. Aikens, G. C. Schatz 369. Computational studies of the interaction of sulfur trioxide with large water clusters. J. M. Standard, Μ. Τ. Van der Hoven 370. Computational study of tocopherol regeneration kinetics. A. L. Cooksy, R. Lui 371. Conformational analysis of methoxysubstituted benzenes: Comparing INS spectra to DFT calculations and crystallographic analysis. N. Verdal, B. S. Hudson, Z. Pan, K. D. M. Harris 372. Crucial role of the internal aqueous solvent structure in electrostatic interac tions at the protein-solvent interface. A. Rubinstein, S. Sherman 373. Density functional theory for self-assem bly of inhomogeneous spherocylindric fluids between two hard walls. D. Cao 374. Density-functional calculations of the optical properties of GaN:ZnO solid solu tion. L. Zhao, J. T. Muckerman, M. D. Newton 375. DFT study on Ru(ll) porphyrin-catalyzed intramolecular amidation of sulfamate esters. X. Lin, D. L. Phillips 376. Direct dynamics simulations of O+HCI at hyperthermal collision energies. J. P. Camden, G. C. Schatz 377. Dissipative particle dynamics simulation for nanoparticle aggregates. S. Ryu, S. Y. Park, G. C. Schatz 378. Effect of defects on the mechanical properties of carbon nanotubes. T. Belytschko, R. Khare, S. L. Mielke, J. T. Paci, R. S. Ruoff, G. C. Schatz, D. Troya, S. Zhang 379. Electric field enhancement and light transmission in nanohole systems. K. L Shuford, M. Ratner, S. K. Gray, G. C. Schatz 380. Electronic tensor shapes and invariants as potential new pharmacophore and olfactophore descriptors. G. Zuber, P. Mukhopadhyay, D. N. Beratan, P. Wipf 381. Evaluation of nonwoven webs from spectral deconvolution of compression data. J. R. Feldkamp
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PHYS
382. Explicit simulations of human Lymphotactin (hLtn) reveals that the temperature dependence of salt-protein association is sequence specific. L. Ma, M. S. Formaneck, Q. Cui 383. Exploration of representation depen dence of approximate methods for com puting non-adiabatic time correlation functions. L. Chen 384. Extending mean field descriptions of wetting to complex systems. I. AI Hroub, M. G. Reuter, C. M. Taylor 385. Geodesic path picture for slow dynamics in supercooled liquids. C. Wang, R. M. Strati 386. Heat transport through nanojunctions: A multilayer multiconfiguration time-depen dent Hartree approach. K. A. Velizhanin, H. Wang, M. Thoss 387. Hydrogen adsorption and dissociation over Mg clusters. L. Cheng, J. Liu, Q. Ge 388. Hydrogen bond dynamics at the interface between water and carboxylic acid-termi nated self-assembled monolayers. N. D. Winter, J. S. Vieceli, I. Benjamin 389. Influence of structural dynamics on charge recombination rates: Evidence from EPR spectroscopy and computation. Q. Mi, E. A. Weiss, M. A. Ratner, M. R. Wasielewski 390. Interaction of Pt clusters with oxygen vacancies on anatase TiO 2 (101). Y. Han, C-J. Liu, Q. Ge 391. Interparticle electron transfer dynamics in Langmuir monolayers of metal nanoparticles stabilized with amphiphilic fatty acids. J . Kim, D. Lee 392. Intersystem crossing effects in the 0(3P)+C2H4 reaction dynamics. W. Hu, B. Maiti, G. Lendvay, G. C. Schatz 393. Intramolecular Η-bonding effects on ion binding by aromatic amides: An ab initio study. R. D. Parra, M. B. Ghorbanpour, M. Wemhoff, P. Kofoed 394. Lennard-Jones repulsive potential and phase equilibrium of monoatomic, diatomic and triatomic molecules. D. A. Bernard-Brunei, J. J. Potoff 395. Light absorption by clusters of metal nanoparticles: Effects of substrate and aggregation. A. O. Pinchuk, G. C. Schatz, B. Grzybowski, A. M. Kalsin 396. MD simulations of lipid molecule extrac tions from boundaries and pure domains in lipid bilayers. R. D. Swenson, D. D. Busath 397. Mechanical properties of ultrananocrystalline diamond: A theoretical study. J. T. Paci, T. Belytschko, G. C. Schatz 398. Molecular dynamics simulations of meth ane hydrate using polarizable force fields. H. Jiang, K. D. Jordan, C. Taylor 399. Molecular dynamics simulations of the coalescence of iridium clusters. T. L. Pawluk, L. Wang 400. Molecular reorientation in complex envi ronments. M. F. Gelin, D. S. Kosov 401. Non-natural peptide: Structure and dynamics. X. Zhu, A. Yethiraj, Q. Cui 402. Numerical simulations of adsorption of linear alkanes in silicalite. R. A. Sultanov, A. V. Khugaev, D. Guster, M. Nordby 403. O2 Chemisorption on PtVFe nanopar ticles: A density functional theory study. J. I. Williams, L Wang 404. Obtaining quantum mechanical rate constants directly from ab initio calcula tions. A. Arnaldsson, H. Jonsson 405. On the derivation of an expression for relaxation time from Stokes-Einstein rela tion. K. R. Sharma 406. Optical activity of an oriented water molecule. C. M. Isborn, K. Claborn, B. Kahr, X. Li 407. Oxygen reactions at a transition metal oxide surface. H. Wang, W. F. Schneider 408. Phase equilibria of two-Yukawa fluids confined in slit pores by density functional theory. X. Wang, Y. Wei, S. Yan, D. Fu
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409. Protein/ligand interactions in phenylala nine hydroxylase: DFT and ab initio results. M. E. Hofto, J. Cross, M. Cafiero 410. Proton mobility in methoxide-methanol clusters. J. G. Livingston, V. F. DeTuri 411. Proton transfer between chloroform and methoxide in methanol: Microsolvation study of carbanion formation in a protic solvent. D. Cordaro, J. Killeen, V. F. DeTuri 412. Semiclassical wavepacket study of ozone forming reaction. E. Vetoshkin, D. Babikov 413. Slow solvent dynamics in high-energy solute rotational energy relaxation. G. Tao, R. M. Stratt 414. Stability of N12C12H12 and the effects of endohedral atoms and ions. D. L. Strout, D. McAdory, J. Jones, A. Gilchrist, D. Shields, R. Langham, K. Casey 415. Structure of the polarized liquid/liquid interface. B. Su, Ν. Eugster, H. H. Girault 416. Temperature dependence of optical rotation in rigid organic molecules calcu lated by vibrational averaging. B. C. Mort, J. Autschbach 417. Time dependent density functional theory calculations of circular dichroism and optical rotation of tris-bidentate transition metal complexes with unsaturated ligands. M. Rudolph, J. Autschbach 418. Use of density functional theory based electronic and structural properties for predicting the binding affinity of BH4 analogs. J. Cross, M. E. Hofto, M. Cafiero 419. Vapor phase synthesis and characteriza tion of silica-doped rare earth oxide nano particles. C. A. Sweet, G. P. Glaspell II, M. S. El-Shall 420. Vibrational spectroscopy of TNT on clay minerals. L. F. Alzate, N. Mina, C. M. Ramos 421. W4 Theory for computational thermo chemistry: In pursuit of confident sub-kJ/ mol predictions. A. Karton, E. Rabinovich, J. M. Martin, B. Ruscic 422. Was Boltzmann wrong? R. B. Shirts
Section C Hyatt Regency Chicago Riverside Center General Posters Capturing Complexity in Physical Sciences Simulation G. A. Voth,
Organizer
7:30-10:00 423. Ab initio study of the interaction and mechanism of addition of POSS-T8 to the Si(100) surface. B. Tejerina, M. S. Gordon 424. Computational model of chaperoninmediated protein folding. G. Stan, D. Thirumalai, G. H. Lorimer, B. R. Brooks 425. Core-shell metallocarbons: Metal cages filled with molecular carbon radicals. F. Y. Naumkin 426. Delineation of the phosphoryl transfer reaction in DNA synthesis/repair by a high fidelity polymerase from Bacillus stearothermophilus (BF). R. Venkatramani, R. Radhakrishnan 427. Electron transfer reaction of hydroxyl radical in NaCI solution. M-K. Tsai, M. Valiev, G. K. Schenter, M. Dupuis, B. C. Garrett 428. Excited state dynamics of DNA and RNA bases. H. R. Hudock, B. G. Levine, T. J. Martinez 429. Excited states of DNA hairpins. S. Tonzani, G. C. Schatz 430. Harpooning through a molecule: Longrange charge-transfer insertion complexes. F. Y. Naumkin 431. Path Integral: Differential geometry method for simulating rigid water clusters below 230K. E. Curotto 432. Spontaneous corrugation of dipolar membranes. X. Sun, J. D. Gezelter 433. The ensemble effects of PdAu bimetallic surfaces. D. Yuan 434. The free energy landscape of receptor mediated cell adhesion. T. Yang, M. H. Zaman 435. Withdrawn.
Section D Hyatt Regency Chicago Riverside Center General Posters Dynamics on the Nanoscale G. A. Voth,
Organizer
7:30-10:00 436. Charge transfer through multiple spatial pathways in donor-bridge-acceptor mol ecules. R. H. Goldsmith, M. R. Wasielewski, M. A. Ratner 437. Coaxial GaN nanowire structure, proper ties and applications. J. B. Halpern, I. C. Bell III, M. He, V. Ayers, B. W. Jacobs, A. D. Baczewski, K. McElroy, M. A. Tupta, R. E. Stallcup II, A. Hartman, M. A. Crimp 438. Cooling times of metal nanoparticles measured through transient grating spec troscopy: Silver nanoparticles in aqueous solutions. V. A. Senekerimyan, H. Y. Seferyan, A. Wark, D. Whitmore, I. Goldshleger, R. Zadoyan, R. M. Com, V. A. Apkarian 439. Coulombic dragging of molecules on surfaces induced by separately flowing polar liquids. P. Krai, B. Wang 440. Delocalized photoluminescence intensity fluctuations observed over entire lengths of semiconductor nanowires. J. Glennon, R. Tang, W. E. Buhro, R. A. Loomis 441. Detection of DNA hybridization using multi-layered nanohole arrays. D. Y. Kim, M. H. Lee, T. W. Odom 442. Dimerization of decacyclene on copper surfaces. L M. Wesoloski, A. Stieg, M. Kunitake, J. K. Gimzewski 443. Direct imaging of electronic energy transfer by ultrafast fluorescence micros copy. A. M. Muller, C. J. Bardeen 444. Dynamics of nanostructures investigated by ultrafast electron nano-crystallography. C-Y. Ruan, Y. Murooka, R. K. Raman, R. A. Murdick 445. Effect of quantum and dielectric confine ment on the exciton-exciton interaction energy in type-ll core/shell semiconductor nanocrystals. A. Piryatinski, S. A. Ivanov, S. Tretiak, V. I. Klimov 446. Withdrawn. 447. Withdrawn. 448. Excimer formation of pyrene molecules on gold nanoparticles. S. Volkén-Kacso, Β. Janko, I. Kosztin 449. Exciton derealization and superradiance in anthracene thin films. T. S. Ahn, F. C. Spano, C. J. Bardeen 450. Extraordinary atomic mobility of Au{111} at 80 Kelvin: Effect of styrene adsorption. A. E. Baber, S. C. Jensen, E. V. Iski, E. C. H. Sykes 451. Femtosecond time-resolved quatum dot-based energy transfer. C. Burda 452. Fluorescence dynamics of single CdSe semiconductor nanocrystals: A cautionary tale of activation, enhancement and rntermittency in the life of a quantum dot. M. A. Osborne, S. F. Lee 453. Generalized model for carrier multiplica tion in semiconductor nanocrystals. A. Piryatinski, V. I. Klimov 454. Intraband spectroscopy and dynamics of ll-VI core/shell systems. P. Guyot-Sionnest, A. Pandey 455. Withdrawn. 456. Linker-controlled energy and charge transfer within chlorophyll trefoils. R. F. Kelley, M. J. Tauber, M. R. Wasielewski 457. Manipulating light on dielectric surfaces: Confining standing waves in optical cor rals. Y. Babayan, T. W. Odom 458. Molecular self-assembled nanodielectric capacitors investigated by variable-tem perature direct current measurements. S. A. DiBenedetto, J. Letizia, A. Facchetti, T. J. Marks, M. A. Ratner 459. Molecular wires: A Fock space approach. T. Hansen, V. Mujica, M. A. Ratner 460. Multiple exciton generation and fusion in novel covalently linked tetracene dimers. A. M. Millier, Y. S. Avlasevich, K. Mullen, W. W. Schôller, R. O. Al-Kaysi, C. J. Bardeen
461. Near-resonance plasmonic trapping of single and multiple Au nanoparticles. K. C. Toussaint Jr., M. Liu, M. Pelton, J. Pesic, P. Guyot-Sionnest, N. F. Scherer 462. Nuclear dynamics and solvation on the nanoscale: Excited state dynamics of pure water and transient X-ray absorption measurements of Br atom and Br2" anion. C. G. Elles, I. A. Shkrob, R. A. Crowell 463. Optical control of confined acoustic phonon in colloidal nanocrystals. D. H. Son, T-Y. Chen, H. S. Son 464. Optical coupling in 1- and 2-D arrays of nanoparticles produced by electron beam lithography. E. C. Mc Lei Ian, S. Zou, K. G. Spears, G. C. Schatz, R. P. Van Duyne 465. Phonon-dressed exciton dynamics in thylakoid membrane and light reaction rate in chloroplast. S. N. Datta 466. Reversible bending and twisting in molecular crystal nanorods generated by localized photoexcitation. C. J. Bardeen, R. O. Al-Kaysi, A. M. Muller 467. Selective functionalization and optical properties of magnetic nanopyramids. J. Lee, W. Hasan, M. H. Lee, J. Henzie, T. W. Odom 468. Simulations of laser-induced glass formation in Ag-Cu nanoparticles. C. F. Vardeman II, J. D. Gezelter 469. Single-molecule electron transfer dynamics at dye-sensitized Ti02 nanoparticles. H. P. Lu 470. State-to-state femtosecond relaxation dynamics of excitons in semiconductor quantum dots. P. Kambhampati, S. L. Sewall, R. R. Cooney, K. E. Anderson, E. A. Dias 471. Strong plasmonic coupling and nonlinear response in 2-D Au nanoparticle arrays. M. J. Guffey, H. Y. Kim, N. F. Scherer 472. Strong polarization-dependent color and enhanced optical transmission from anisotropic gold nanohole arrays. M. H. Lee, J. Henzie, H. Gao, T. W. Odom 473. Thermo-mechanical alignment of gold nanorods in transient grating geometry. H. Y. Seferyan, V. A. Senekerimyan, A. Wark, D. Whitmore, I. Goldshleger, R. Zadoyan, R. M. Com, V. A. Apkarian 474. Thermodynamics of activated phase transitions of 8CB: DSC and MC calorimetry. D. Sharma, J. C. MacDonald, G. S. lannacchione 475. THz time domain spectroscopic study of charged η-type CdSe quantum dots. P. K. Mandai, V. Chikan 476. Time-resolved EPR studies of charge, spin, and energy transfer in a series of Donor-Bridge-Acceptor p-phenylene oligo mers. Z. E. X. Dance, M. J. Ahrens, M. A. Ratner, M. R. Wasielewski 477. Ultrafast chemical dynamics of nanotechnology energetic materials. M. Zamkov, R. Conner, D. D. Dlott 478. Ultrafast fluorescence upconversion measurements of exciton dynamics in spiral thiophene dendrimers. A. S. Huss, N. P. Wells, D. A. Blank Section Ε Hyatt Regency Chicago Riverside Center General Posters The Biophysics of RNA G. A. Voth,
Organizer
7:30-10:00 479. Compact folds by randomly generated RNA sequences. U. Mohanty 480. Computer simulations of the energetics of codon recognition, peptidyl transfer and termination on the ribosome. S. Trobro, M. Almlôf, M. Andér, J. Aqvist 481. Distance measurements in nucleic acids using a sequence-independent nitroxide probe and cw-EPR spectroscopy. Q. Cai, P. Z. Qin 482. Dynamics of ternary complex EFTu(GTP)aa-tRNA on the ribosome. U. Mohanty 483. Elucidation of a function for an idiosyncratic protein domain of leucyl-tRNA synthetase. M. T. Vu, S. A. Martinis 484. Elucidation of a translocation pathway for Escherichia coli leucyl-tRNA synthetase. R. A. Hellmann, S. A. Martinis
TECH-109
TECHNICAL PROGRAM
PHYS 485. Folding cooperative dictates extent of pKa shifting in RNA and DNA. N. A. Siegfried, S. L. Metzger, P. C. Bevilacqua 486. Long-lived intermediates in the formation of nucleic acid hairpins. A. Van Orden, J. Jung, R. Ihly, R. Nayak 487. Measuring RNA dynamics through linker polymers. C. Hyeon, D. Thirumalai 488. Mechanism of pre-mRNA splicing as studied using FRET with novel PNA-based probes. A. Jaquins-Gerstl, L. Yu, K. Robertson, S. Y. Kwan, B. A. Armitage, A-J. Lopez, L. A. Peteanu 489. Molecular dynamics analysis of hydrogen bonding in HIV rev-RRE complex. J. A. Chenault, B. D. Sitzmann, A. M. Knolhoff, M. C. Nagan 490. Molecular dynamics simulations of Esherichia coli tRNA P h e . B. D. Sitzmann, M. C. Nagan 491. Molecular dynamics studies of the human immunodeficiency virus rev-RRE complex under varying salt concentrations. B. R. Miller III, A. K. Sezhiyan, J. D. Brune, J. A. Chenault, M. C. Nagan 492. Probing pathways and kinetic barriers in the mechanical unfolding and refolding of RNA. C. Hyeon, R. I. Dima, D. Thirumalai 493. Redundant amino acid correction mechanisms of leucyl-tRNA synthetases. M. T. Boniecki, M. T. Vu, A. K. Betha, S. A. Martinis 494. Ribose dynamics studies in leadzyme. M. Sumita, K. R. Julien, C. G. Hoogstraten 495. Simple molecular model for the influence of secondary structure stability on thermo stability in functional nucleic acids. J. M. Blose, S. K. Silverman, P. C. Bevilacqua 496. Single Molecule measurements reveal the deeply fluted free energy surface of a large collapsed state RNA. G. J. Smith, K. T. Lee, X. Qu, J. Pesic, Z. Xie, T. Sosnick, T. Pan, N. F. Scherer 497. Single-Molecule Mg2+ nonequilibrium jump experiments reveal details of the early folding pathways of a large RNA. X. Qu, K. T. Lee, G. J. Smith, A. Ma, A. Dinner, T. Sosnick, T. Pan, N. F. Scherer 498. Thermodynamic characterization of single mismatches in naturally occurring RNA. A. R. Davis, B. M. Znosko 499. Thermodynamic characterization of tandem mismatches in naturally occurring RNA. M. E. Sedabres, Β. Μ. Znosko Section F Hyatt Regency Chicago Riverside Center General Posters Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment G. A. Voth,
Organizer
7:30-10:00 500. Anharmonicity in a quantum computer based on vibrational eigenstates. M. Zhao, D. Babikov 501. Assessment of thermal stability of azurin Pae upon disulfide bond reduction. Q. Huang, E. Quinones 502. C-D modes as potential structural report ers via 2-D IR spectroscopy. S. R. G. Naraharisetty, I. V. Rubtsov 503. Characterization of a water-hexafluorobenzene complex using matrix isolation infrared spectroscopy. J. C. Amicangelo, N. L. Saxton, C. J. Lee, D. G. Irwin 504. Characterization of the SH3 domain of Bruton's tyrosine kinase by Raman spec troscopy. R. E. Rivera-Hainaj, J. Fowler, R. Ombrembowski 505. Computational studies of C^N bonds as vibrational probes of protein structure and dynamics. B. A. Lindquist, S. A. Corcelli 506. Direct interrogation of low frequency solvent motions during intermolecular electron transfer. M. J. Ammend, D. F. Underwood, D. A. Blank 507. DNA at interfaces studied by sum fre quency generation. G. Y. Stokes, A. B. Voges, J. M. Gibbs, F. C. Boman, B. R. Stepp, S. T. Nguyen, F. M. Geiger
110-TECH
508. Dual-frequency 2-D IR study of vibra tional energy transport in molecules. D. V. Kurochkin, I. V. Rubtsov 509. Dynamics in the spectral densities of pyridinium charge transfer complexes by polarizability response spectroscopy. A. M. Moran, R. A. Nome, S. Park, N. Scherer 510. Dynamics of intermolecular vibrational modes in biological electron transfer reac tions. W. F. Beck, K. L. Dillman, K. R. Shelly 511. Elucidating structural dynamics coupled to charge transfer in donor-bridge-acceptor molecules using femtosecond time-re solved stimulated raman spectroscopy. J. V. Lockard, A. Butler, M. R. Wasielewski 512. Excited-state molecular structural dynamics of nickel porphyrins. X. Zhang, E. C. Wasinger, A. Z. Muresan, K. Attenkofer, G. Jennings, J. S. Lindsey, L. X. Chen 513. Exposing the origins of vibrational cou pling in DNA with 2-D infrared spectros copy. A. T. Krummel, M. T. Zanni 514. Femtosecond spectroscopy of single photosynthetic reaction center crystals from Rhodobacter sphaeroides. L. Huang, G. P. Wiederrecht, S. Schlesselman, C. Xydis, P. D. Laible, D. K. Hanson, D. M. Tiede 515. Frequency- and time-resolved coherence transfer spectroscopy. M. A. Rickard, N. A. Mathew, A. V. Pakoulev, K. M. Kornau, J. C. Wright 516. High resolution terahertz spectroscopy and modeling of peptide nanotubes. K. Siegrist, R. Balu, S. Gregurick, D. F. Plusquellic 517. Infrared line shapes of alpha carbondeuterium labeled alanine in water, poly peptides and proteins. C. S. Kinnaman, M. E. Cremeens, F. E. Romesberg, S. A. Corcelli 518. Withdrawn. 519. Membrane peptide folding with IR spec troscopy. Y. Ling, M. T. Zanni 520. Microstructure of organic photovoltaic bulk heterojunction thin films examined with ultrafast polarization resolved 2-D IR spectroscopy. L. W. Barbour, M. Hegadom, J. B. Asbury 521. Multidimensional infrared spectroscopy using chirped pulse upconversion. M. J . Nee, R. McCanne, K. J. Kubarych 522. Multifrequency EPR studies of photosystem II single crystals. A. Gunn, R. D. Britt, B. Thangaraj, I. Grotjohann, P. Fromme 523. Multifrequency EPR studies of the fluorophenoxyl and fluoro-tyrosyl radicals. M. Brynda, A. Gunn, R. D. Britt 524. Multifrequency EPR studies on trapped PcyA radical intermediates. A. Gunn, M. Brynda, C. P. Aznar, M. Dicus, R. D. Britt, W. Sughrue, J. C. Lagarias, F. Allen-Piccolo, A. J. Fisher 525. Withdrawn. 526. New interpretation of acetonitrile IR spectra and its relation to proteins. E. M. Kosower, G. Markovich, G. Borz 527. Resolving structural events in hairpin peptide unfolding with temperature-jump 2-D IR and DVE spectroscopy. A. W. Smith, A. Tokmakoff 528. Reversible aggregation, slow dynamics and conformational hysteresis in poly-Llysine. E. A. Gooding, B. Karlow, N. La Porte, E. Medina-Gray, B. Munda, T-H. Luu, J. McAuley, B. Takebe, E. Wilbanks 529. Selective vibrational population with phase tailored mid-IR pulses. D. B. Strasfeld, S. H. Shim, M. T. Zanni 530. Spectroscopic studies of the phylloquinone acceptors in Photosystem I. S. L. Bender, J. Keough, B. A. Barry 531. Structural disorder of ΟΌ3ζ transmem brane domain studied with 2-D IR spec troscopy and molecular dyamics simula tions. P. Mukherjee, M. T. Zanni 532. Structure and dynamics of soft inter faces. J. B. Asbury, L. W. Barbour, M. Hegadom
533. Surface enhanced Raman spectroscopy (SERS) of cysteine containing dipeptides on gold nanoshells. F. Wei, J. Hartgerink 534. Theoretical studies of static field enhanced SFG spectroscopy at aqueous interfaces. T. J. Green, B. Space 535. Theoretical study on vibrational energy relaxation of metalloporphyrin complexes. Y. Zhang, J. E. Straub 536. 3-D infrared-Raman spectroscopy of normal and deuterated nitromethane. S. Shigeto, Y. Pang, Y. Fang, D. D. Dlott 537. Time-resolved isotope-edited infrared spectroscopy reveals that the α-helix folds more rapidly at the C-terminus than at the N-terminus. M. Volk, A. Pozo Ramajo, A. Starzyk, S. A. Petty, S. M. Decatur 538. Time-resolved measurements of vibra tional energy transfer in liquid chloroform by IR-Raman spectroscopy. Y. Fang, Y. Pang, S. Shigeto, Z. Wang, D. D. Dlott 539. Time-resolved resonance Raman and DFT study of the structure and dynamics of the photochemistry for benzophenone in iso-propyl alcohol. Y. DU, C. Ma, W. M. Kwok, D. L. Phillips 540. Time-resolved resonance Raman study of the reaction of 2-fluorenylnitrenium ion with 2-fluorenylazide. J . Xue, Z. Guo, P. Y. Chan, L M. Chu, T. But, D. L Phillips 541. 2-D infrared spectra collected with shaped mid-IR pulses. S-H. Shim, D. B. Strasfeld, M. T. Zanni 542. 2-D infrared spectroscopy of peptide aggregates: Structure determination complementary to solid state NMR. W. Zhuang, D. Abramavicius, D. Voronine, S. Mukamel 543. Ultrafast heterogeneous dynamics of molecular aggregates revealed by 2-D optical spectroscopy. I. Stiopkin, T. Brixner, M. Yang, G. R. Fleming 544. Withdrawn. 545. Ultrafast nonequilibrium chemical exchange: Phototriggered Fourier trans form multidimensional infrared spectros copy. R. McCanne, M. J. Nee, K. J. Kubarych 546. Unfolded peptides probed by vibrational spectroscopies. R. Schweitzer-Stenner, T. Measey 547. Use of coherent multidimensional spec troscopy to examine the coupling between widely-separated vibrational modes. N. A. Mathew, Κ. Μ. Kornau, M. A. Rickard, A. V. Pakoulev, B. M. Kroncke, J. C. Wright 548. Vibrational dynamics of biomolecules probed using 2-D IR. M. T. Zanni 549. Vibrational energy relaxation of confined water (H20 and D20) in reverse micelles. Y. Pang, S. Shigeto, Z. Wang, D. D. Dlott 550. Vibrational frequencies of glycine(H20)n (n = 1-8) clusters. C. M. Aikens, M. S. Gordon 551. Vibrational markers for proton transfer reactions through water in partially aque ous environments. E. Pines, D. Pines, E. T. J. Nibbering, O. F. Mohammed 552. Withdrawn. 553. Zinc-initiated folding kinetics of a zincbinding peptide: The CH11 domain. J. Tang, S-G. Kang, J. G. Saven, F. Gai
Section G Hyatt Regency Chicago Riverside Center General Posters Implications and Applications of Chirality in Physical Chemistry G. A. Voth,
Organizer
7:30-10:00 554. "Solvation" of a chiral molecule: Rota tional spectroscopic sudy of the Popylene oxide - (Water) w = i . 3 clusters in the gas phase. Z. Su, Y. Xu 555. A molecular dynamics study of analyte resolution on the Whelk-0 1 chiral station ary phase. C. Zhao, N. M. Cann 556. CD-MPI: Two color multi photon ioniza tion of chiral ketones. A. Bornschlegl, U. Boesl, C. Logé 557. Chiral induction in ethanol: Development of a polarizable, flexible solvent model. S. Wang, N. M. Cann 558. Chirality and liquid crystals: A molecular dynamics study. R. Pecheanu, N. M. Cann 559. Chiroptical effects in the second harmonic generation from collagens I and IV. A-M. Pena, T. Boulesteix, T. Dartigalongue, M. Simpler, M-C. Schanne-Klein, F. Hache 560. Determination of the absolute configuration of 2,2'-diphenyl-[3,3'-biphenanthrene]4,4'-diol (VAPOL) using chiroptical spectroscopic methods. A. G. Petrovic, S. E. Vick, P. L. Polavarapu 561. Intermolecular hydrogen bonding effect on the VA and VCD spectra: Experimental and DFT studies of lactic acid in water and in methanol. M. Losada, Y. Xu 562. Modeling chiroptical properties of molecules in solution. P. Mukhopadhyay, G. Zuber, M-R. Goldsmith, D. N. Beratan, P. Wipf 563. Molybdenum center of xanthine oxidoreductase: Chiral switching and substrate coordination. P-P. Mich, R. Hille 564. Solvation and selectivity at the interface of the N-(3,5-dinitrobenzoyl)-phenylglycine chiral stationary phase. S. Nita, J. H. Horton, N. M. Cann 565. Symmetry, chirality and geometry: Chemical variation and the effects on molecular conductance. G. C. Solomon, M. A. Rainer, V. Mujica 566. Time-dependent density functional theory calculation of specific rotation using molecular dynamics and explicit solvation. M. D. Kundrat, J. Autschbach THURSDAY MORNING Section A McCormick Place South Room S401B/C, Level 4 Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Multidimensional Infrared Spectroscopy M. T. Zanni and J . E. Straub, A. Massari,
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Organizers
Presiding
8:20 567. 2-D IR Spectroscopy of ubiquitin unfolding dynamics. H. S. Chung, Z. Ganim, A. Tokmakoff 9:00 568. Computational 2-D optical spectroscopy of biomolecules. M. Cho 9:40 Intermission. 10:00 569. Ultrafast dynamics of intra- and intermolecular vibrations in hydrogen bonded systems. T. Elsaesser, J. R. Dwyer, S. Ashihara, N. Huse, A. Espagne, E. T. J. Nibbering 10:40 570. Vibrational spectral diffusion and energy relaxation of azide ion in water. J. L. Skinner 11:20 571. Quantum-classical description of transient amide I vibrational spectra. G. Stock
PHYS/POLY Section Β
Section Ε
McCormick Place South RoomS401A, Level 4
McCormick Place South Room S406A, Level 4
Implications and Applications of Chirality in Physical Chemistry Non-linear Chiroptical Spectroscopy
Capturing Complexity in Physical Sciences Simulation Electronic Structure Methods Cosponsored with COMP
T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers K. Ruud,
Presiding
McCormick Place South RoomS401A, Level 4
K. Raghavachari, Organizer,
Implications and Applications of Chirality in Physical Chemistry Origins of Homochirality
Presiding
8:20 589. New hybrid functionals for ab initio calculations of properties of solids. G. E. Scuseria 9:00 590. Finding reaction coordinates in complex systems via likelihood maximiza tion. B. L Trout, B. Peters, G. Beckham 9:40 591. Barriers and pathways to quantita tive modeling. A. K. Wilson, N. DeYonker, T. R. Cundari 10:00 Intermission. 10:15 592. Quantum/classical dynamics of nuclei and electrons in large systems. S. S. Iyengar 10:55 593. Large-scale ab initio simulations for semiconductor technology. W. Andreoni 11:35 594. Adaptive partitioning in multilevel/ multiscale simulations. A. Heyden, D. G. Truhlar
Section C
McCormick Place South RoomS401D, Level 4
Measures of Accuracy and Reliability in Molecular Simulation Ion Channels/Membranes Cosponsored with COMP R. Friesner and T. E. Cheatham III, Organizers B. Roux,
Presiding
8:20 579. Computational studies of ion hydration. T. Withfield, G. Lamoureux, S. Varma, S. B. Rempe, B. Roux 9:00 580. Validating membrane simulations through comparison with NMR and X-ray scattering experiments. S. E. Feller 9:40 581. Benchmarking simple force fields of biomolecules against neutron scattering. A. Luzar, A. K. Soper, J. Teixeira, S. Longeville, C. Daub, S. E. McLain, I. H. Zgani 10:20 582. Correspondence of simulation and experiment for lipid bilayers. R. W. Pastor Section D McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Interfacial Structure and Surfactants Cosponsored with COLL M. L Schlossman and R. A. Walker, Organizers M. Aratono,
Presiding
8:20 584. Molecular dynamics simulation of octanol/water interfaces. P. B. Moore 9:00 585. Optical chirality of molecular aggregates at liquid/liquid interface. H. Watarai 9:40 586. Novel state of the adsorbed film of 1 H,1 H,10H,10H-perfluorodecane-1,10-diol at the hexane/water interface. T. Takiue, H. Inomata, D. Murakami, H. Matsubara, M. Aratono 10:00 Intermission. 10:20 587. Structural order and dynamics at water/hydrocarbon interfaces. J. Chowdhary, Β. Μ. Ladanyi 11:00 588. An ellipsometry study of density profiles at the oil/water interface. J. P. R. Day, C. D. Bain
Section Β
W. F. Schneider and C. M. Wolverton, Organizers
8:00 572. Sum-frequency spectroscopy for probing molecular chirality. N. Ji, K. Zhang, H. Yang, Y. R. Shen 8:40 573. Time-resolved circular dichroism in the ultraviolet: A new user-friendly tech nique. F. Hache, C. Niezborala 9:00 574. Molecular mechanisms driving the chiral sensitivity of second order nonlinear optics. G. J. Simpson 9:40 575. Chiral atmospheric heterogeneous chemistry. F. M. Geiger, G. Y. Stokes, A. B. Voges 10:00 Intermission. 10:20 576. Nonlinear optics and chirality. T. Verbiest 11:00 577. Nonlinear optical activity of DNA polymers. V. J. Hall, R. Plocinik, R. D. Wampler, C. Dehen, G. J. Simpson 11:20 578. Linear and nonlinear optical activity studies. R. N. Compton
McCormick Place South Room S402A, Level 4
3:20 604. Heat transport in proteins. D. M. Leitner 4:00 605. Macromolecular dielectric fluctua tions at the mesoscopic and molecular scales. R. F. Loring 4:40 606. Computational studies of vibra tional probes in proteins. S. A. Corcelli
T. D. Crawford, P. H. Vaccaro, and Κ. Β. Wiberg, Organizers L. D. Barron,
Section Ε
Presiding
Dynamics on the Nanoscale Single Molecule
1:20 607. Overview of the origins and impli cations of homochirality. A. J. MacDermott 2:00 608. Magneto-chiral anisotropy. G. L. Rikken 2:40 609. Chiral memory in porphyrin aggre gates. R. Purrello 3:00 Intermission. 3:20 610. How important is parity violation for molecular and biomolecular chirality? M. Quack 4:00 611. Amplification of chirality in 2-D crystal lattices. K-H. Ernst, R. Fasel, M. Parschau 4:20 612. Chiral rhenium complexes: New candidates for parity violation measure ments. J. Crassous, L. Guy, T. Saue, C. Chardonnet 4:40 613. Kinetics of conglomerate crystalli zation in the presence of chiral impurities. D. K. Kondepudi, K. Crook
O. V. Prezhdo,
Section C
Section F
Organizer
P. J. Reid, Organizer,
Presiding
8:20 595. Statistical analysis of single mol ecule sequences. J . Cao 9:00 596. Fluorescence dynamics of single CdSe-ZnS quantum dot clusters. A. Van Orden, M. Yu 9:20 597. Surface dynamics and charge transfer in single-molecule Raman spec troscopy. G. Haran, T. Shegai 10:00 598. Near-field scanning optical microscopy (NSOM) studies of conjugated polymer heterojunctions. D. A. Vanden Bout 10:40 599. E-e correlation in electron dynam ics in the presence of strong e-ph interac tion. Y. Dahnovsky 11:00 600. Probing sol-gel-derived mesoporous silica films one molecule at a time. D. A. Higgins, F. Ye, H. Dong, M. M. Collinson
McCormick Place South Room S402B, Level 4 Structure and Dynamics at the Liquid-Liquid Interface Micelles and Aggregates Cosponsored with COLL
McCormick Place South Room S401D, Level 4 Dynamics on the Nanoscale Sensitized Nanoparticles P. J . Reid,
Β. Μ. Ladanyi,
Section A
Section D
McCormick Place South Room S401B/C, Level 4
McCormick Place South Room S406A, Level 4
Vibrational Spectroscopy as a Probe of Biomolecular Structure and Dynamics: Theory and Experiment Vibrational Probes of Biomolecules
Capturing Complexity in Physical Sciences Simulation Liquids and Interfaces Cosponsored with COMP
Biological Surface Chemistry Nanomaterials and Thin Films Sponsored by COLL, Cosponsored with PHYS
Division of Polymer Chemistry Κ. Ε. Uhrich and C. Landry-Coltrain, Program Chairs SUNDAY MORNING Section A McCormick Place South Room S501B/C/D, Level 5 ACS Award in Polymer Chemistry: Symposium in Honor of Ludwik Leibler Self-Assembling Soft Materials A. Karim,
M. T. Zanni,
Organizer
C. M. Wolverton and K. Raghavachari, Organizers Presiding W. F. Schneider, Organizer,
1:20 601. Infrared-Raman studies of vibra tional energy transfer. D. D. Dlott, Y. Pang, Z. Wang, Y. Fang, S. Shigeto 2:00 602. Taking a closer look at biomol ecules using IR and THz spectroscopy: From the THz dance of sugars and pro teins with water to infrared imaging. M. Havenith 2:40 603. Vibrational anharmonic coupling in bioorganic crystals. R. Balu, K. Siegrist, D. Plusquellic, S. K. Gregurick 3:00 Intermission.
Presiding
1:20 625. Electron transfer from molecules to nanoparticles: Dependence on the density of states. T. Lian 2:00 626. Theoretical studies of electronic relaxation in sensitized Ti02 surfaces. V. S. Batista, S. G. Abuabara 2:40 627. Dynamics of photo-induced heter ogeneous electron transfer. F. Willig 3:20 628. Quantum simulation of photoin duced electron injection processes at dye-semiconductor interfaces. H. Wang, M. Thoss 4:00 629. Spectroscopic studies of solvent effects on dynamics and structure of nanocrystalline T1O2 interfaces. J. A. Downing, F. J. Knorr, D. Zhang, J. L. McHale
Presiding
THURSDAY AFTERNOON
J. E. Straub, Organizer,
Organizer
O. V. Prezhdo, Organizer,
M. L. Schlossman and R. A. Walker, Organizers
1:20 614. Structure and dynamics at inter faces in reverse micelles. Ν. Ε. Levinger, D. C. Crans, B. Baruah 2:00 615. Dynamics in aqueous polymer aggregate solutions. E. W. Castner Jr., C. D. Grant, K. E. Steege, J. Wang, K. E. Uhrich 2:40 616. Vibrational and photodetachment dynamics of anions in reverse micelles. J. C. Owrutsky, G. M. Sando, K. Dahl 3:20 617. Modification in rheological proper ties due to charged network of ionic sili cone surfactants at water-oil interface. S. C. Mehta, P. Somasundaran
Biological Surface Chemistry Biosensors Sponsored by COLL, Cosponsored with PHYS
3:00 Intermission. 3:15 621. Photoinduced isomerization in complex environments from first principles. T. J. Martinez, C. Ko, B. G. Levine, C. Punwong, A. Virshup 3:55 622. The enhanced harmonic Fourier Beads method with novel free energy gradient approximation for quantitative studies of rare events via reaction path ensembles. I. V. Khavrutskii, C. L. Brooks III 4:15 623. Extended-molecule investigations of organic-modified metal and semicon ductor surfaces. C. Risko, T. J. Marks, M. Ratner 4:35 624. Water adsorption on a-AI 2 O 3 (0001 ) surface: A DFT investiga tion. V. A. Ranea, W. F. Schneider, I. Carmichael
Presiding
1:20 618. Simulating retention in reversedphase liquid chromatography. J. I. Siepmann, J. L. Rafferty, L. Sun, M. R. Schure 2:00 619. A molecular-level perspective on vibrational dynamics in liquids. C. M. Morales, W. H. Thompson 2:40 620. Using cluster-based simulations to calculate detailed solvation properties for complex systems. S. J. Keasler, B. Chen, R. B. Nellas
Organizer
R. M. Briber,
Presiding
E. J . Amis, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 1. Supramolecular assembly of inhomogenous polymers. G. H. Fredrickson, W. B. Lee, Ε. Η. Feng, R. Elliott
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECHNICAL PROGRAM 9:00 2. How ideal are ideal-like polymers? M. Rubinstein, D. Shirvanyants, S. Panyukov 9:25 3. New complexities in block copolymer phase behavior. T. P. Lodge 9:50 4. Influence of salt complexes on block copolymers. T. P. Russell, J-Y. Wang, T. Xu, S. Gupta 10:15 Intermission. 10:35 5. Designing polymers for therapeutic applications. J. M. J. Fréchet 11:00 6. Some new lights on an old reaction: The cationic (co)polymerization of 1,3,5trioxane. J. P. Vairon, Κ. Sharavanan, Ε. Ortega, M. Moreau, C. Lorthioir, F. Lauprêtre, P. Desbois, R. F. M. Lange 11:25 7. Photonic and phononic polymers. E. L. Thomas 11:50 8. Nanostructured functional polymers prepared by ATRP with ppm amounts of Cu. K. Matyjaszewski
9:20 2 1 . Characterizing dispersion of layered nanocomposites via melt rheology. H. Kim, C. W. Macosko 9:50 22. Theory of relaxation, physical aging and mechanical properties of polymer glasses. K. S. Schweizer, K. Chen 10:20 Intermission. 10:35 23. Designed interfaces in nanoparticle filled polymer composites. S. L. Lewis, Y. Li, B. C. Benicewicz, S. K. Kumar, L. S. Schadler 11:05 24. Shear-induced orientation in exfoli ated polystyrene/clay nanocomposites. W. R. Burghardt, L. M. Dykes, J. M. Torkelson 11:25 25. Effect of carbon nanoparticle geometry on the interphase in PMMA nanocomposites. K. W. Putz, L. C. Brinson, R. Thillaiyan, L. Jamison 11:45 26. Annealing, structural changes, and migration of polypropylene nanocompos ites. M. Lewin, Y. Tang 12:05 27. Supported metallocene catalysis for in situ synthesis of high energy density metal oxide nanocomposites. N. Guo, S. A. DiBenedetto, T. J. Marks, D-K. Kwon, M. T. Lanagan
9:05 37. Polymer brushes: From microstruc tured polymer layers to nanophase sepa rated and nanogradient materials. J. Ruehe, C. Schuh, A. Kopychev, R. Konradi, S. Santer, O. Prucker 9:35 38. Gradient and patterned polymer brushes using microchannel confinement. K. L. Beers, C. Xu 10:05 39. Surface-initiated ATRP on planar surfaces from adsorbed polyelectrolyte macroinitiators. S. Edmondson, C-D. Vo, S. P. Armes 10:25 Intermission. 10:35 40. Functionalization via surfaceinitiated living radical polymerizations. G. D. Fu, S. C. Wuang, F. J. Xu, K. G. Neoh, E. T. Kang 11:05 4 1 . Polymer brushes and grafts from photopolymer film surfaces. S. B. Jhaveri, I. W. Moran, D. Koylu, K. R. Carter 11:35 42. Liquid hybrid polymer brushes with rapid reversible switching behavior. M. Motornov, R. Sheparovych, I. Tokarev, Y. Roiter, S. Minko 11:55 43. Solvent-assisted polymer grafting. B. Zdyrko, I. Luzinov
Undergraduate Research in Polymer Science Cosponsored with PRES
Section D
S. Ε. Morgan and S. Nazarenko, Organizers, Presiding
McCormick Place South RoomS501A, Level 5
Nanostructures from Block Copolymers and Supramolecular Polymers Inorganic Hybrids Sponsored by PMSE, Cosponsored with POLY
8:30 Introductory Remarks. 8:50 9. Dye polymers as a drug release system and an electrocatalyst for Nadh oxidation. A. Blackwell, S. D. Minteer 9:10 10. Investigation of solution self-assem bly and film formation behavior of the hydrophobin ABH1 from Agaricus bisporus. M. C. Arnold, R. Misra, J. Li, G. C. Cannon, S. Heinhorst, S. E. Morgan 9:30 11. Phase selective solubility of poly(N,N-dialkylacrylamides)s. N. Aviles-Ramos, D. Ortiz-Acosta, D. E. Bergbreiter 9:50 12. PLGA/collagen/HA nanofibrous scaffold for bone tissue engineering. M. V. Jose, K. Johnson, V. Thomas, D. R. Dean 10:10 13. Toward the development of an azure C mediated chitosan membrane based bioanode. T. Klotzbach, S. D. Minteer 10:30 Intermission. 10:50 14. Preparation of (2,4,6-tribromophenyl)diphenylphosphate for use as a dual-functional flame retardant. Β. A. Howell, S. M. June 11:10 15. Simulation of reversibly associated polymers with orientational specificity. M. C. Hagy, C-C. Chen, E. E. Dormidontova 11:30 16. Synthesis and thermotropic behav ior of polynorbomenes with laterally attached 2,5-bis[(4'-n-alkylthiobenzoyl)oxy]benzyl mesogens. S. F. Bancroft, M. J. Thompson, N. Frimpong, R. J. Mullins, C. Pugh 11:50 17. Synthesis of amphiphilic block copolymers via reversible addition-frag mentation chain transfer polymerization. K. A. Mirkin, S. Venkataraman, J. Ma, D. L. Kaplan, K. L. Wooley 12:10 18. Template-assisted fabrication of organic-inorganic hybrid nanofibers. M. Raimondi, A. P. E. Soliani, I. Tokarev, S. Minko
Carl S. Marvel Creative Polymer Chemistry Award: Symposium in Honor of Anne Mayes
SUNDAY AFTERNOON
M. Olvera de la Cruz,
McCormick Place South RoomS501B/C/D, Level 5
Section Β McCormick Place South Room S503B, Level 5
Organizer
8:30 Introductory Remarks. 8:40 28. Templated self assembly of block copolymers: Top down helps bottom up. E. L. Thomas 9:05 29. Shear alignment of microdomains in block copolymer thin films. R. A. Register, A. P. Marencic, D. E. Angelescu, M. W. Wu, J. H. Waller, D. H. Adamson, P. M. Chaikin 9:30 30. Unconventional nanostructures and nanopattems from functionalized block copolymers. C. J. Hawker 9:55 3 1 . Complex constructs having nanoscale features by combining incompatible polymer components. K. L. Wooley, J. W. Bartels, C. Cheng, W. Du, Κ. Τ. Powell 10:20 Intermission. 10:30 32. Nanoscale crafting of bioactive supramolecular polymers. S. I. Stupp 10:55 33. Engineering immunity: Using polymers to probe and prod cells of the immune system. D. J. Irvine 11:20 34. Playing with electrochemical and biological function in nanoscale assem blies. P. T. Hammond 11:45 35. Electroactive star molecules. M. E. Galvin Section Ε McCormick Place South Room S502A/B, Level 5 Polymer Surfaces and Interfaces Polymer Brushes Cosponsored with PMSE J. P. Youngblood, A. J. Crosby, R. C. Advincula, and Y-C. I. Chang, Organizers
Section C K. L. Beers and K. R. Carter, McCormick Place South Room S503A, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Nanocomposites
Presiding
8:30 Introductory Remarks. 8:35 36. Grafting from and onto surfaces via atom transfer radical polymerization. K. Matyjaszewski, H. Dong, W. Jakubowski, J. Pietrasik
J. M. Torkelson and K. R. Shull, Organizers 8:15 Introductory Remarks. 8:20 19. Polymer nanocomposites with prescribed morphology: Going beyond nanoparticle-filled polymers. R. Vaia, H. Koerner, W. Lu, E. Manias 8:50 20. Graphene-based materials. R. S. Ruoff, S. Watcharotone, I. Jung, S. Stankovich, R. Piner, D. A. Dikin, S. Nguyen
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Section A
ACS Award in Polymer Chemistry: Symposium in Honor of Ludwik Leibler Self-Assembling Soft Materials A. Karim,
Organizer
R. Briber,
Presiding
E. J . Amis, Organizer,
Presiding
1:45 44. Nanostructured materials at ARKEMA: From nitroxydes to carbon nanotubes. C. Collette 2:10 45. Ordered structures and nanostruc tured blends from polydisperse polymers: The reactive blending route. I. Iliopoulos 2:35 46. Engineering nanocontinuous poly meric materials. F. S. Bates 3:00 47. Withdrawn. 3:25 Intermission. 3:40 48. Nanoparticle-stabilized phospholipid vesicles and other novel colloidal particles. S. Granick 4:05 49. Colloidal polymers, molecules, and atoms. D. J. Pine 4:30 50. Facile imaging of self-assembly of magnetic nanoparticles using fossilized liquid assembly. J. J. Benkoski, S. E. Bowles, R. L Jones, J. F. Douglas, J. Pyun, A. Karim 4:55 5 1 . Award Address (ACS Award in Polymer Chemistry, sponsored by Exxon Mobil Chemical Company). Surprises and joys of self-assembly. L. Leibler Section Β McCormick Place South Room S503B, Level 5 Combinatorial and High Throughput Polymer Chemistry New Technologies and Measurements K. L. Beers and E. J . Amis,
Organizers
1:30 52. Rapid physical characterization of a family of polyolefins using high throughput techniques. S. J. Schofer, H. Hahn, V. Murphy, D. A. Hajduk, G. M. Diamond, Y. Chen, R. D. Doolen, M. Smith 2:00 53. Wireless resonant sensor array system for high-throughput materials screening. R. A. Potyrailo, W. G. Morris 2:30 54. Spectral imaging techniques as a truly parallel high-throughput screening tool. J. Lauterbach 3:00 55. A multi-sample melt micro-rheometer. K. B. Migler, A. J. Bur, D. Moon
3:30 56. A high throughput system for accel erated weathering and automated charac terization of polymeric materials. J. W. Chin, E. Byrd, B. Dickens, R. Clemenzi, J. Hettenhouser, A. Ellison, J. Garver, D. Stanley, V. Colomb, J. Martin 3:50 57. Microfluidic dynamic light scattering used for high throughput measurements. T. Q. Chastek, K. L. Beers, E. J. Amis 4:20 58. Continuous microfluidic reactors for polymer particles. Z. Nie, M. Seo, W. Li, S. Xu, P. Lewis, E. Kumacheva 4:50 59. Pushing the envelope: Strategies for adapting combi methods to new mate rials systems. M. J. Fasolka Section C McCormick Place South Room S503A, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Nanostructured Surfaces J. M. Torkelson and K. R. Shull, Organizers 1:25 Introductory Remarks. 1:30 60. Templated admicellar polymeriza tion as a method to produce nanostruc tured polymers on solid surfaces. B. P. Grady, M. Marquez 2:00 6 1 . Driven self assembly of block copolymer nanocomposites on nanopattemed substrates for lithographic applica tions. F. A. Detcheverry, Y. Papakonstantopoulos, K. C. Daoulas, M. P. Stoykovich, P. F. Nealey, M. Miiller, J. J. de Pablo 2:30 62. Patterning organic semiconductors using polymer surface patterns. Z. Bao 3:00 Intermission. 3:15 63. Formation of polymer nanostruc tures by micro/nanofluidics and supercriti cal fluids. J. Guan, L. J . Lee 3:45 64. Synthetic gecko foot-hairs from multiwalled carbon nanotubes. A. Dhinojwala, L. Ge, S. Sethi, B. Yurdumakan, C. Lijie, P. M. Ajayan 4:15 65. Octavinylsilsesquioxane, a perfect nanobuilding block. M. Roll, M. Z. Asuncion, R. M. Laine 4:35 66. New aminophenylsilsesquioxanes, synthesis, properties and epoxy nanocom posites. R. Laine, K. Takahashi, M. Roll Section D McCormick Place South RoomS501A, Level 5 Carl S. Marvel Creative Polymer Chemistry Award: Symposium in Honor of Anne Mayes M. Olvera de la Cruz,
Organizer
1:30 67. Gradient library approaches for the design of nanostructured polymer films. M. J. Fasolka 1:55 68. Faceting of ionic shells into icosahedra via electrostatics. G. Vernizzi, M. Olvera de la Cruz 2:20 69. Self-assembly in ionomers. S. K. Kumar 2:45 70. Self-assembly of multicomponent block copolymers in dilute solution. M. A. Hillmyer, F. S. Bates, T. P. Lodge, J. A. Zupancich, W. Edmonds, Z. Li, C. Liu 3:10 Intermission. 3:20 7 1 . From nanoparticles to nanopolymers. F. Stellacci 3:45 72. Instabilities in cylindrical nanopores. T. P. Russell, J-T. Chen, M. Zhang 4:10 73. Patterned surfaces segregate com pliant microcapsules. A. Alexeev, R. Verberg, A. C. Balazs 4:35 74. Molecularly assembled multilayers: From fundamentals to applications. M. Rubner
POLY
Section E McCormick Place South Room S502A/B, Level 5 Polymer Surfaces and Interfaces Responsive Surfaces, Interfaces, and Films Cosponsored with PMSE A. J . Crosby, R. C. Advincula, and Y-C. I. Chang, Organizers R. C. Hayward,
Presiding
J. P. Youngblood, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 75. Surfaces with responsive topogra phy: Creasing of soft materials under compression. R. C. Hayward, V. Trujillo, G. Tucker, E. Memis 2:05 76. Hydrophilic and oleophobic stimuliresponsive surfaces. J. P. Youngblood, J. A. Howarter 2:35 77. Microporous thin film membranes from pH-responsive polymer. I. Tokarev, M. Orlov, S. Minko 2:55 78. Photoreversibly tunable wettability on nanostructured surfaces. K. Cho, H. S. Lim, J. T. Han, D. Kwak 3:15 Intermission. 3:25 79. Responsive surfaces obtained from colloidal dispersions stabilized by bioactive molecules. M. W. Urban 3:55 80. Self-assembly on an adaptive, patterned substrate. S. Yang 4:25 8 1 . Investigation of doubly-responsive photopolymerized poly(methacrylic acid)block-poly(N-isopropylacrylamide) brushes. S. B. Rahane, A. T. Metters, S. M. Kilbey 4:45 82. Stimuli-responsive LBL films from controlled architecture polyelectrolytes synthesized via RAFT polymerization. S. E. Morgan, P. J. Jones, A. Lamont, C. A. Harris, C. L. McCormick 5:05 83. Wetting on microstructured (ultra)hydrophobic surfaces. C. Dorrer, J. Riihe Nanostructures from Block Copolymers and Supramolecular Polymers Architecture-Driven Nanostructures Sponsored by PMSE, Cosponsored with POLY S U N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Excellence in Graduate Polymer Science Research Symposium Cosponsored with PROF, YCC, and PRES Η. Ν. Cheng, Ε. Η. Martin, and C. J . Ellison, Organizers 6:00-8:00 84. Influence of branched PEG chains on polymer micelles: How to build a better drug delivery system. J . Wang, L. del Rosario, K. E. Uhrich 85. Label free and self-signal amplifying DNA microarray sensor. K. Lee, J-M. Rouillard, E. Gulari, J. Kim 86. Selective phosphate recognition by triurea-based molecularly imprinted poly mers. X. Wu, K. Goswami, K. D. Shimizu 87. Selective filtration of water-oil mixtures by stimuli-responsive brushes. J. A. Howarter, J. P. Youngblood 88. Selective wetting and adhesion on micropillar arrays grafted with thermoresponsive polymer brushes. Y. Zhang, S. Qin, J. A. Taylor, J. Aizenberg, S. Yang 89. Impacts of molecular weight, repeat unit structure, chain stiffness, composition, and sample geometry on the Tg-nanoconfinement effect. M. K. Mundra, C. J. Ellison, J. M. Torkelson 90. General ability of nanoparticles to induce defects in model cell membranes. P. Leroueil, S. A. Berry, J. R. Baker Jr., B. G. Orr, M. Banaszak Holl 9 1 . Responsive polyelectrolyte membranes. M. Orlov, S. Minko, I. Tokarev 92. Scaling down organic single-crystal tran sistors. A. L. Briseno, Z. Bao, Y. Xia
93. Base-free Suzuki polymerization for the synthesis of carboxylic-acid functionalized conjugated polymers as dye sensitizers in Graetzel photovoltaic cells. R. N. Brookins, Q. Qiao, K. S. Schanze, J. R. Reynolds 94. Living ROMP of novel cationic monomers in a novel 2,2,2-trifluoroethanol/methylene chloride solvent mixture. D. A. Rankin, A. B. Lowe 95. Preparation of well-defined azobenzene polymers by ring opening metathesis polymerization. R. H. Lambeth III, J. S. Moore 96. New initiators for living radical polymeriza tion: Cp2TiCI-catalyzed set reduction of aldehydes. A. D. Asandei, Y. Chen 97. Soluble polymer-bound ATRP polymeriza tion catalysts. P. N. Hamilton, D. E. Bergbreiter 98. Surface modification using thiol-ene and thiol-acrylate polymerizations. V. Khire, D. S. W. Benoit, K. S. Anseth, C. N. Bowman 99. Synthesis, characterization, and selfassembly of large comb block copolymers. Μ. Β. Runge, Ν. Β. Bowden 100. Novel synthesis and polymerization of protected dihydroxy 7-member cyclic carbonate. R. Wu, K. Bisht
112. The effect of molecular weight on polyvi nyl alcohol)/clay aerogel composite proper ties. K. Lamison, M. D. Gawryla, D. A. Schiraldi 113. Synthesis and characterization of 2,2,4,4,8,8,10,10-octamethyl-6-methyleneundecane: Structural conformation of coupled polyisobutylene. L. K. Kemp, J. E. Poelma, R. F. Storey 114. The effects of adding natural fibers to polymer/clay aerogel composites. K. Finlay, M. D. Gawryla, D. A. Schiraldi 115. Use of a conjugated polymer-based sensor array to assess the quality of fish. I. Tran, T. L. Nelson, M. S. Maynor, J. J. Lavigne
Section Β
8:25 116. From polyurethanes to higher performance segmented and multiblock copolymers: Tutorial. J. E. McGrath 9:10 117. Microstructural organization of polydimethylsiloxane based segmented polyurethane copolymers. R. Hernandez, J. Weksler, A. Padsalgikar, J. Runt 9:35 118. Effect of soft segment molecular weight on the structure-property relation ships of segmented non-chain extended polyureas based on single isocyanate molecules as hard segments. S. Das, I. Yilgor, E. Yilgor, B. Inci, O. Tezgel, F. L. Beyer, G. L. Wilkes 10:00 119. Copoly(ether-esters) with long soft blocks. A. Schmidt, J. Krijgsman 10:25 Intermission. 10:35 120. Wholly aromatic rod-rod type block molecules: Synthesis and selfassembled structure studies. T. Hayakawa, R. Goseki, M-A. Kakimoto, M. Tokita, J. Watanabe, S. Horiuchi 11:00 121. Triblock copolymer based on monodisperse aramide segments: Synthe sis, mechanical and Theological properties. A. Arun, R. J. Gaymans 11:25 122. Comb block copolymers: Synthe sis and assembly into photonic band gap materials. M. B. Runge, Ν. Β. Bowden 11:50 123. Structure-property relationships of segmented polyurethanes and polyureas based on single isocyanate molecules as hard segments. S. Das, D. B. Klinedinst, I. Yilgor, F. L. Beyer, S. Toki, B. S. Hsiao, G. L. Wilkes
Hyatt Regency Chicago Riverside Center Undergraduate Research in Polymer Science Cosponsored with PRES S. Ε. Morgan and S. Nazarenko, Organizers, Presiding 6:00-8:00 101. Crosslinked diisocyanate/clay aerogel composites. A. E. Reinardy, M. D. Gawryla, D. A. Schiraldi 102. Graft co-polymers by ring-opening me tathesis polymerization from a main chain containing latent monomers. K. Wangkanont, M. J. Allen, L. L. Kiessling 103. Ion beam patterning of diblock copoly mer thin films. R. Allen, H-C. Kim, J. Baglin, O-H. Park, J. Y. Cheng 104. Elastomeric polymer/clay aerogel com posites. E. Arndt, M. D. Gawryla, D. A. Schiraldi 105. Manufacture and testing of a self-healing bladder material. B. Beiermann, M. Keller, N. Sottos 106. Organocatalytic ring opening polymeriza tion of cyclic monomers: Mechanistic and synthetic studies. F. A. Leibfarth, B. G. G. Lohmeijer, F. Nederberg, R. C. Pratt, J. W. Logan, R. M. Waymouth, J. L. Hedrick 107. Solution and thermal properties of opti cally transparent polyhedral oligomeric silsesquioxane/polystyrene hybrid nanocomposites. K. Hamilton, L. Wahl, R. Misra, S. E. Morgan 108. Synthesis and aggregation studies of valine-containing block copolymers. W. H. Parsons, A. P. Piatt, K. E. Rutledge, S. Gajria, S. L. Goh 109. Synthesis and characterization of poly propylene fumarate-co-L-lactic acid) for orthopedic applications. M. D. Schmidt, D. S. Fletcher, J. M. Krzykowski, H. L Wallner, J. P. Droske 110. Synthesis and characterization of selfassembling polyboronates. C. S. Baraty, B. M. Rambo, T. Israsena Na Ayudhya, J. J. Lavigne 111. Tailoring the degree of branching in poly(arylene ether sulfone)s via reactivitybased control. N. R. Hendricks, P. Himmelberg, E. A. Fossum
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
MONDAY MORNING Section A McCormick Place South Room S501B/C, Level 5 Segmented Block Copolymers R. J . Gaymans and T. E. Long, Organizers
Section Β McCormick Place South RoomS501D, Level 5 Combinatorial and High Throughput Polymer Chemistry Library Design and Synthesis K. L. Beers and E. J. Amis,
Organizers
8:30 124. Gradient polymer films on surfaces - using thiol-ene and thiol-acrylate polymer izations. V. Khire, C. N. Bowman 8:50 125. Statistical copolymer brush compo sition gradients via microchannel confined surface-initiated photopolymerization. D. L Patton, C. Xu, K. L. Beers 9:10 126. Combinatorial methods for tissue engineering. M. L. Becker, N. D. Gallant, K. A. Lavery, E. J. Amis 9:40 127. High throughput screening of compositional variables in a siloxaneurethane coatings systems for marine applications. D. C. Webster, P. Majumdar, A. Ekin, R. J. Pieper 10:10 128. Synthesis and characterization of polyurethane dispersions by traditional and automated methods. M. J. Nasrullah, R. R. Roesler, P. D. Schmitt, J. A. Bahr, C. Gallagher-Lein, D. C. Webster
10:30 129. Acrylic polyol composition and its effect on the fouling-release performance of siloxane-urethane coatings developed using combinatorial/high throughput meth ods. R. J. Pieper, S. J. Stafslien, J. Daniels, D. C. Webster 10:50 130. Synthesis and screening of polymer libraries for LCST behavior and mechanical properties. R. Hoogenboom, D. Fournier, J. M. Kranenburg, U. S. Schubert 11:20 131. Automated parallel hetero geneous polymerizations. C. Guerrero-Sanchez, M. M. W. Fijten, U. S. Schubert 11:40 132. The development of a combinato rial/high-throughput workflow for hybrid organic-inorganic coating research. B. J. Chisholm, M. Berry, J. A. Bahr, J. He, J. Li, V. Bonitz, G. Bierwagen 12:10 133. The application of combinatorial/ high-throughput methods to atom transfer radical polymerization of polymerizable triclosan derivatives. S-B. Choi, L. Jarabek, B. J. Chisholm, P. Boudjouk 12:30 134. Incorporation of quaternary ammonium salts in silanol terminated polydimethylsiloxane using a high-through put combinatorial approach. P. Majumdar, E. Lee, K. Ward, B. J. Chisholm Section C McCormick Place South Room S502A, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Nanocomposites J. M. Torkelson and K. R. Shull, Organizers 8:25 Introductory Remarks. 8:30 135. Hierarchically structured nanocom posites: Assembly and properties. E. P. Giannelis 9:00 136. Two approaches to improved properties in nanotube/polymer compos ites: Grafting and spatial heterogeneity. M. Mu, M. Moniruzzaman, K. I. Winey 9:30 137. Dynamic consequences of fractal network structure of nanotubes in poly mers. T. Chatterjee, R. Krishnamoorti 10:00 138. Selective dispersion of nanofillers in PET/PC blends, tailored by thermody namics of mixing and melt-processing conditions. E. Manias, M. J. Heidecker, J-Y. Chung, J. Mason 10:30 Intermission. 10:45 139. Melt intercalation/exfoliation of polystyrene-sodium-montmorillonite nanocomposites using sulfonated polysty rene ionomer compatibilizers. R. A. Weiss, N. Bhiwankar 11:15 140. Solid-state shear pulverization: A novel, continuous, mechanical process for making well-dispersed or well-exfoliated polymer nanocomposites. J. M. Torkelson, K. Wakabayashi, Y. Tao, K. G. Kasimatis, L. M. Dykes, W. R. Burghardt 11:35 141. Well-exfoliated polyolefin-clay nanocomposites made by solid-state shear pulverization. C. Pierre, K. Kasimatis, J. M. Torkelson 11:55 142. Gelation and rheology of short carbon nanotubes/isotactic polypropylene composites. D. Xu, Z. Wang Section D McCormick Place South Room S502B, Level 5 Excellence in Graduate Polymer Science Research Symposium Cosponsored with YCC, PROF, and PRES Ε. Η. Martin,
Organizer
H. N. Cheng and C. J . Ellison,
Presiding
8:25 Introductory Remarks. 8:30 143. Formation and mechanics of electrospun polymer jets. Μ. Ε. Helgeson, K. N. Grammatikos, J. M. Deitzel, N. Wagner
TECH-113
TECHNICAL PROGRAM
POLY 8:55 144. Self-assembled inorganic inter faces as a tool for control over conducting polymer conductivity. J. J. Martin, C. J. Timpson, A. Sattler, J. P. Gaffney, K. Pueschel, W. E. Jones Jr. 9:20 145. Anisotropic encapsulation of superparamagnetic nanocrystals in poly meric biphasic nanocolloids. K-H. Roh, J. Lahann 9:45 146. Peptide-polymer surface interac tions. N. Singh, S. M. Husson 10:10 Intermission. 10:25 147. Novel biopolymeric networks fabricated using nanostructured lyotropic liquid crystalline templates. J. D. Clapper, C. A. Guymon 10:50 148. Monte Carlo simulation of selfassembling supramolecular gel. S. Wang, C-C. Chen, E. E. Dormidontova 11:15 149. Noncovalent assembly of erodible drug-delivery matrices based on polysac charide-peptide interactions. L. Zhang, E. M. Furst, K. L. Kiick Section Ε McCormick Place South RoomS501A, Level 5 Polymer Surfaces and Interfaces Multilayers, Thin Films and Surface Characterization Cosponsored with PMSE A. J . Crosby and Y-C. I. Chang, Organizers R. Advincula and J . P. Youngblood, Organizers, Presiding 8:30 Introductory Remarks. 8:35 150. Free standing flex Lbl films with encapsulated nanoparticles. V. V. Tsukruk 9:05 151. Layer-by-layer bioassay develop ment using polyelectrolytes and organophosphorus hydrolase. R. M. Leblanc, C. A. Constantine, J. Orbulescu 9:35 152. Nanoparticle multilayers. M. Rubner 10:05 153. Nanopatterning and electrochemi cal crosslinking of carbazole functionalized layer-by-layer precursor polyelectrolyte ultrathin films. R. Advincula 10:35 Intermission. 10:45 154. Nanoporous block copolymer micelle/micelle multilayer films with dual optical properties. K. Char, J. Cho, J. Hong, F. Caruso 11:15 155. Hydrophobic hydration of single polymer chains studied by force spectros copy. N. Gunari, G. Walker 11:45 156. NMR studies of structure and dynamics of polymers at the clay interface. P. A. Mirau, J. A. Garber, H. Koerner, R. Vaia 12:05 157. Observation of a single adsorbed polymer's conformation on mica with scanning probe microscopy: Effects of retraction rate and dwell time. B. Brotherson, Y. Deng, P. J. Ludovice, L. A. Bottomley 12:25 158. Dilational viscoelastic behavior in 2-D polymer systems with nanofillers. W. Yin, S. M. Huffer, J. Deng, J. R. Hottle, H-J. Kim, A. R. Esker ACS Award in Applied Polymer Science: Symposium in Honor of Harry Allcock Sponsored by PMSE, Cosponsored with POLY Nanostructures from Block Copolymers and Supramolecular Polymers Active Nanostructures Sponsored by PMSE, Cosponsored with POLY Undergraduate Research Poster Session: Polymer Chemistry Sponsored by CHED, Cosponsored with SOCED, POLY, and PMSE
MONDAY AFTERNOON Section A McCormick Place South Room S501B/C, Level 5 Segmented Block Copolymers R. J . Gaymans and T. E. Long, Organizers 1:35 159. Structure-properties behavior of segmented polyurethanes, polyureas and poly(urethane ureas): Tutorial. G. L. Wilkes 2:20 160. Segmented polyurethane and polyurea copolymers with hard segments based on single diisocyanate molecules: Influence of diisocyanate chain symmetry on morphology and properties. I. Yilgor, E. Yilgor, B. Inci, O. Tezgel, S. Das, G. L. Wilkes, F. L. Beyer 2:45 161. Effect of chain extenders on shape-memory properties of segmented copolymers with aramid hard segments and polycaprolactone soft segments. A. Kraft, L. Gamier 3:10 162. Poly (ether-b-amide) copolymers phase organization as revealed by solid state NMR and impact upon properties. E. Rene-Paul Sr., P. Frederic, T. Piotr 3:35 Intermission. 3:45 163. Synthesis of highly branched sulfonated polysulfones for high perfor mance electromechanical transducers. A. J. Duncan, T. Long, D. J. Leo 4:10 164. Use of ionic liquids in rod-coil block copolyimides for improved lithium ion conduction. M. A. B. Meador, D. M. Tigelaar, K. Chapin, W. R. Bennett 4:35 165. High yield synthesis of star poly mers with low polydispersity by crosslink ing macromonomers in ATRP. H. Gao, S. Ohno, K. Matyjaszewski 5:00 166. Thermoplastic polyester-ether copolymers. P. Vollenberg Section Β McCormick Place South Room S501D, Level 5 Polymer Performance, Degradation, and Materials Selection Polymer Photodegradation M. Celina, J . S. Wiggins, and N. C. Billingham, Organizers 1:25 Introductory Remarks. 1:30 167. Polymer weathering and stabiliza tion: A tutorial. J. E. Pickett 2:30 168. Effect of strain on durability of model elastomers. C. C. White, D. Hunston, K. T. Tan 3:00 169. FTIR measurement of C 0 2 photogeneration from polyethylene, polypropyl ene and polyester films. T. A. Egerton, P. A. Christensen, S. S. Fernando, J. R. White 3:20 Intermission. 3:40 170. Effect of pigment dispersion on optical properties and durability of a Ti02 pigmented epoxy coating. L-P. Sung, X. Gu, C. Clerici, H. Hu, E. Loizou, D. L Ho 4:00 171. Profluorescent nitroxides: Novel probes of polypropylene degradation. J. P. Bunco, G. A. George, S. E. Bottle 4:20 172. Photolysis and photo-oxidation in engineering plastics. P. Gijsman Section C McCormick Place South Room S502A, Level 5
Section D McCormick Place South Room S502B, Level 5 Excellence in Graduate Polymer Science Research Symposium Cosponsored with YCC, PROF, and PRES Η. Ν. Cheng and C. J. Ellison, Ε. Η. Martin, Organizer,
Unconventional Processes for Nanostructured and Microstructured Polymer Systems Blends
1:25 Introductory Remarks. 1:30 173. Dynamics of ternary mixtures with photosensitive chemical reactions: Creat ing 3-D ordered blends. A. C. Balazs
2:35 190. Monitoring polymer surface struc tural changes in water and in response to protein adsorption in situ. Z. Chen 2:55 191. Synthesis, characterization, and biocompatibility of vinyl pyridine-based bactericidal polymer surfaces. T. R. Stratton, Β. Ο Allison, B. Applegate, J. P. Youngblood 3:15 Intermission. 3:25 192. Biomineralization of inorganic thin films mediated by surface-grafted polypep tide brushes. Y-C. I. Chang, J-C. Wu, C-C. Chen, Y. Wang 3:55 193. Functionalization of shell crosslinked nanoparticles and their biodistribution assessment. J. Xu, G. Sun, A. Hagooly, R. Rossin, Z. Li, K-l. Fukukawa, M. J. Welch, C. J. Hawker, K. L. Wooley 4:25 194. Chemical attachment of penicillin to expanded polytetrafluoroethylene (ePTFE) surfaces leading to antimicrobial properties. N. Aumsuwan, M. W. Urban 4:45 195. Direct visualization of lipid mem brane disruption by antibacterial pyridinium polymers in GUV model systems. V. Sambhy, D. Eves, A. G. Ewing, A. Sen 5:05 196. Protein resistant properties of bifunctional glycerol dendrons. M. Wyszogrodzka, R. Haag ACS Award in Applied Polymer Science: Symposium in Honor of Harry Allcock Sponsored by PMSE, Cosponsored with POLY
Organizers
Presiding
1:15 Introductory Remarks. 1:20 Recognition of Poster Presenters. 1:30 181. Novel star-branched polymers via a combination of quasiliving cationic and atom transfer radical polymerizations. L K. Kemp, K. R. Slye, R. F. Storey 1:55 182. Atom transfer radical polymeriza tion in two-step emulsion. K. Min, H. Gao, K. Matyjaszewski 2:20 183. Surface segregation in polymer blends induced by surface freezing. S. Prasad, L. Hanne, A. Dhinojwala 2:45 184. Proton exchange membranes for fuel cell applications. A. Roy, X. Yu, H-S. Lee, A. S. Badami, S. Dunn, J. E. McGrath 3:10 Intermission. 3:25 185. General strategy for the synthesis of biologically active block copolymers. E. E. McElroy, J. K. Pontrello, L. L. Kiessling 3:50 186. Simple approach to the chemical modification and crosslinking of poly(epsilon-caprolactone) in the synthesis of novel degradable polyester materials. B. A. Van Horn, K. L. Wooley 4:15 187. Gradient copolymers: Exploiting the synthesis, characterization and appli cation of a new class of copolymer materi als. J . Kim, J. M. Torkelson 4:40 Remarks. Katie Hunt, ACS President. 4:50 Networking.
Nanostructures from Block Copolymers and Supramolecular Polymers Thin Films and Confinement Sponsored by PMSE, Cosponsored with POLY M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Sci-Mix Κ. Ε. Uhrich,
Organizer
8:00-10:00 27, 39, 81, 122, 131, 142, 157-158, 169, 175, 177,191-192,195. See previous listings. 197-198, 208-209, 211, 243, 246, 470-471, 490, 501, 511, 536, 540, 549, 551, 557, 562-563, 568, 570, 573, 576-577, 587588, 599, 610, 615-616, 624-625. See subsequent listings. TUESDAY MORNING
McCormick Place South Room S504A, Level 5 Segmented Block Copolymers R. J . Gaymans and T. E. Long, Organizers
Section Ε McCormick Place South Room S501A, Level 5 Polymer Surfaces and Interfaces Biopolymer/Bioactive Surfaces Cosponsored with PMSE J. P. Youngblood, A. J. Crosby, and R. C. Advincula, Organizers Z. Chen,
Presiding
Y-C. I. Chang, Organizer,
J. M. Torkelson and K. R. Shull, Organizers
114-TECH
2:00 174. Bicontinuous polymeric microemulsions as templates for nanoporous materi als. N. Zhou, T. P. Lodge, F. S. Bates 2:30 175. Phase separation: A simple and versatile route to polymeric nanostruc tures. Y. Xia 3:00 Intermission. 3:15 176. Miniature mixers for novel polymer nanocomposites and specialty polymer blends. U. Sundararaj 3:45 177. Nanostructuring polymers with cyclodextrins. M. Rusa, T. Uyar, C. C. Rusa, A. E. Tonelli 4:15 178. High internal phase emulsion polymers: Interpenetrating polymer net works and organic-inorganic hybrids. M. S. Silverstein 4:35 179. Nano - and microfibrillar compos ites from polymer blends: Manufacturing, properties and applications. S. Fakirov 4:55 180. Solid-state-shear pulverization for effective dispersion and compatibilization in polymer blends: Micro- and nanoscale morphology. K. Wakabayashi, A. H. Lebovitz, Y. Tao, J. M. Torkelson
8:30 197. Deformation-induced structural changes in poly(ether ester)s thermoplas tic elastomers as revealed by X-ray radia tion from synchrotron. S. Fakirov 9:15 198. Atomic force microscopic study of microphase-separated structure of poly urethane elastomers. K. Kojio, S. Kugumiya, M. Furukawa 9:40 199. Influence of liquid-liquid demixed vs. crystalline morphology on the proper ties of segmented block copolymers. R. J . Gaymans, M. van der Schuur
Presiding
1:30 Introductory Remarks. 1:35 188. Plasma deposited poly(N-isopropylacrylamide) surfaces: Powerful tools for biology and medical devices. B. D. Ratner, H. Canavan, X. Cheng, M. Tunc, M. Humayun 2:05 189. Synthesis of controlled layers of poly(acrylic acid) and their interaction with aminofunctional silsesquioxane nanopar ticles. A. H. E. Muller, M. Retsch, A. Walther, K. Loos
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
POLY 10:05 200. Structure, process, and property relationships of olefin block copolymers via in-situ synchrotron X-ray studies. F. Zuo, X. Chen, J. K. Keum, Y. Mao, B. S. Hsiao, H. Chen, D. Chiu, S-Y. Lai 10:30 Intermission. 10:40 201. Rate dependent mechanical performance of ethylene-methacrylic acid ( E M M ) copolymers and POSS-enhanced E M M nanocomposites. S. Deschanel, M. C. Boyce, R. E. Cohen 11:05 202. Large deformation rate-depen dent stress-strain behavior of polyurea and polyurethane. S. S. Sarva, S. Deschanel, M. C. Boyce, W. Chen 11:30 203. Connecting morphological evolu tion to thermomechanical properties of a model thermoplastic polyurethane-clay nanocomposite. S. M. Lift, G. H. McKinley 11:55 204. New block copolymers comprised of polyisobutylene and poly(vinylferrocene) segments. T. Higashihara, R. Faust Section Β McCormick Place South Room S503B, Level 5 Polymer Performance, Degradation, and Materials Selection Environmental Degradation and Controlled Drug Release M. Celina, J. S. Wiggins, and N. C. Billingham, Organizers 8:00 205. Environmentally degradable polyolefins. G. Swift, R. Bacui 8:30 206. Degradable polymers and their interaction with the environment. A-C. Albertsson, M. Hakkarainen 9:00 207. Marine-degradable thermoplastic polyurethanes. S. J. Moravek, T. R. Cooper, M. K. Hassan, J. S. Wiggins, K. A. Mauritz, R. F. Storey 9:30 Intermission. 9:50 208. Tutorial: Recent developments in synthetic biodegradable polymers. A. J. Domb 10:40 209. High throughput approaches to biomaterials for tissue engineering and drug delivery. D. G. Anderson 11:10 210. Effect of drug characteristics on the degradation rate of polymeric matrices. N. Dan, K. Metzger, K. Werner, S. J. Siegel 11:40 211. Biodegradable polymers for cancer therapy. A. J. Domb, S. Ariella, B. Vaisman, A. Nyska, Y. Levy Section C McCormick Place South Room S503A, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Block Copolymers J. M. Torkelson and K. R. Shull, Organizers 8:25 Introductory Remarks. 8:30 212. Templating with nanostructured polymers prepared by ATRP. K. Matyjaszewski 9:00 213. Block copolymer based strategies for controlling the arrangement of open and closed nanoreactors on planar sub strates. R. E. Cohen 9:30 214. Bicontinuous morphologies in block copolymer-nanoparticle composites. V. Ganesan, V. Pryamitsyn 10:00 215. Expanding the scope of nanostuctures possible from block copolymers: Role of selective deposition solvent. J. Choi, B. G. G. Lohmeijer, R. C. Pratt, G. Dubois, J. E. Frommer, F. Nederberg, H-C. Kim, R. M. Waymouth, J. L Hedrick 10:30 216. Block copolymer electrolytes for lithium battery applications. N. P. Balsara, M. Singh 11:00 Intermission. 11:15 217. Fabrication of nanoparticle arrays using directed assembly of block copoly mers. H. Kang, A. Mangham, M. P. Stoykovich, R. J. Hamers, P. F. Nealey
11:45 218. Continuous processing and deformation mechanisms of ultra-oriented SEBS triblock elastomers. A. J. Lesser 12:15 219. Self-assembly of methacrylic hydrogels by solvent exchange. M. Guvendiren, K. R. Shull 12:35 220. Aqueous-only pH-induced micelle assembly of poly(acrylic acid)-b-poly(phydroxystyrene). N. S. Lee, Y. Li, M. C. Ruda, K. L. Wooley
Active Nanostructures Sponsored by PMSE, Cosponsored with POLY TUESDAY AFTERNOON Section A McCormick Place South Room S504A, Level 5 Segmented Block Copolymers
Section D R. J . Gaymans and T. E. Long, Organizers
McCormick Place South RoomS501A, Level 5 30 Years of Conducting Polymers Alan G. MacDiarmid Memorial and Plenary Lectures S. A. Jenekhe, J. P. Armistead, C. Y. C. Lee, and A. B. Holmes, Organizers K. J. Wynne,
Presiding
8:00 Alan G. MacDiarmid Memorial: Reflec tions on his life and contributions. A. Heeger, A. Epstein, R. Baughman, R. Kaner, B. Wayland, G. Gentile, and K. Wynne 9:15 222. Thirty years of conducting poly mers: Time flies when you are having fun. A. J. Heeger 9:45 223. Poly(diacetylene)s and their impact for understanding polyconjugated macromolecules. G. Wegner 10:15 Intermission. 10:30 224. Charge transport in conjugated polymers: Thirty years of progress in theoretical description. J-L. Brédas 11:00 225. Preparation of new phenylene-, thiophene-, and pyrrole-based pi-conjugated polymers. T. Yamamoto 11:30 226. Realizing the amplification of molecular wire sensors: Isolated nanoscopic conduction pathways. T. Swager Section Ε McCormick Place South Room S501B/C/D, Level 5 Polymer Surfaces and Interfaces Interfacial Physics and Adhesion Cosponsored with PMSE J. P. Youngblood, R. C. Advincula, and Y-C. I. Chang, Organizers K. Dalnoki-Veress,
Presiding
A. J. Crosby, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 227. Adhesion of gels. S. W. Wai, H. R. Brown, G. Spinks 9:00 228. Bioinspired crack trapping for enhanced adhesion. A. Jagota, N. J. Glassmaker, C-Y. Hui, W. Noderer, M. K. Chaudhury 9:25 229. Bioinspired adhesion on incision patterned elastic film. M. K. Chaudhury, A. Ghatak, J. Y. Chung 9:50 230. Nature's instabilities: Inspiring the control of adhesion, optics, and sensors in soft polymers. E. P. Chan, D. P. Holmes, A. J. Crosby 10:15 Intermission. 10:25 231. Capillary wrinkling of thin floating films. T. P. Russell, J. Huang, N. Menon, W. H. de Jeu 10:50 232. Diblock-copolymers can form nearly conical equilibrium droplets. A. B. Croll, M. V. Massa, M. W. Matsen, Κ. Dalnoki-Veress 11:15 233. Perturbations by surfaces and interfaces to Tg that propagate hundreds of nanometers in films: Implications for the nature of the glass transition of polymers. J. M. Torkelson, R. D. Priestley, M. K. Mundra, P. Rittigstein, L. J. Broadbelt, C. J. Ellison 11:40 234. Contact studies of weakly com pressed PEG brushes with a quartz crystal resonator. K. R. Shull, D. A. Brass Nanostructures from Block Copolymers and Supramolecular Polymers
1:35 235. Microstructural organization and performance of segmented polyurethane copolymers: Tutorial. J. Runt 2:20 236. Synthesis, characterization and properties of copolyesters based on poly(trimethylene terephthalate). G. Li, H. Zou, J. Jin, J. Jiang 2:45 237. Michael addition of acetoacetate functionalized oligomers: From biomedical applications to novel elastomers. T. E. Long, S. R. Williams, B. D. Mather, Κ. Μ. Miller 3:10 238. Synthesis and characterization of azobenzene containing photoresponsive rod-coil polymers. D. S. Tyson, W. Minton, A. A. Accurso, P. Desupda, A. A. Figueroa, D. A. Scheiman, M. A. Meador 3:35 Intermission. 3:45 239. Syntheses of telechelic multiblock copolymers by using RAFT polymerization. J . Ma, S. Venkataraman, D. L. Kaplan, K. L. Wooley 4:10 240. Direct activation vs. transformation of polystyryllithium and polyisoprenyllithium living ends for ethylene oxide and propyl ene oxide anionic polymerization: Applica tion to the synthesis of diblock copoly mers. V. Rejsek, S. Carlotti, A. Deffieux 4:35 241. Phase transition of well-defined methoxyoligo(oxyethylene) styrene block copolymers in concentrated aqueous solutions. F. Hua, K. Hong, P. F. Britt, J. W. Mays 5:00 242. Repeating sequence copolymers of fluorene and methylene. T. Y. Meyer, J. E. Copenhafer Section Β McCormick Place South Room S503B, Level 5 Polymer Performance, Degradation, and Materials Selection Biomaterials and Environmental Degradation M. Celina, J . S. Wiggins, and N. C. Billingham, Organizers 1:30 243. Tutorial: Biodegradable polymer performance in medical devices. S. Venkatraman, F. Boey, L. P. Tan 2:20 244. Degradable electrospun porous silicon-biopolymer composites for orthope dic tissue engineering. J. L. Coffer, D. Fan, G. R. Akkaraju, E. F. Couch, L. T. Canham 2:50 245. Controlled degradation of the bioresorable polymer polycaprolactone. U. Little, D. G. Dickson, D. F. Buchanan, P. E-H. Jones, D. Farrar 3:10 246. Controlling the depth-dependent hydrolytic degradation of polylactide using high energy radiation. D. J. Leonard, F. J. Buchanan 3:30 Intermission. 3:50 247. Mechanism of polyester degrada tion by enzymes. R-J. Mueller 4:20 248. Compostability of biodegradable polymers in real and simulated conditions. R. Auras 4:50 249. Synthesis and (bio)degradation of poly(ethyl glyoxylate). B. Belloncle, F. Burel, C. Bunel 5:10 250. Biodegradable, high oxygen barrier films based on polyhydroxylated dendritic polymers crosslinked with 1,6-hexametheylene diisocyanate. J. Pratt, B. G. Olson, S. Nazarenko, M. K. Hassan, W. L. Jarrett Jr., J. S. Wiggins, J. W. Rawlins
Section C McCormick Place South Room S503A, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Thin Films J. M. Torkelson and K. R. Shull, Organizers 1:25 Introductory Remarks. 1:30 251. Unconventional processing for defects control in block-copolymer thin films. A. Karim, S. Kim, B. Berry, R. M. Briber, H-C. Kim 2:00 252. In-situ nanoparticle formation in homopolymer and block copolymer films: Surface segregation and self-assembly. R. J. Composto, N. Clarke, G. Buxton, R. Deshmukh 2:30 253. Writing mesoscale patterns in block copolymer thin films via channel flow of a nonsolvent fluid. R. A. Register, V. Pelletier, D. H. Adamson, P. M. Chaikin 3:00 Intermission. 3:15 254. Micro and nanofabrication via reaction-diffusion. B. A. Grzybowski 3:45 255. Silsesquioxane barrier materials. M. Asuncion, R. Laine 4:05 256. Mechanistic aspects of formation of ordered arrays of air bubbles in polymer films. V. Sharma, M. Srinivasarao 4:25 257. Evolution of nanostructure on surfaces coated with ultrathin multilayer films. N. J. Fredin, J. Zhang, D. M. Lynn Section D McCormick Place South Room S502A/B, Level 5 30 Years of Conducting Polymers Synthesis S. A. Jenekhe, J. P. Armistead, and C. Y. C. Lee, Organizers A. B. Holmes, Organizer,
Presiding
1:30 258. Twenty years of development of low bandgap conjugated polymers. F. Wudl 2:00 259. Controlled electroactivity in polyheterocycles. J. R. Reynolds 2:30 260. η-Type conjugated polymers. S. A. Jenekhe 3:00 261. Silicon-containing dendritic triscyclometalated Ir(lll) complexes and their electrophosphorescence in a polymer host. Y. You, C-G. An, D-S. Lee, J-J. Kim, S. Y. Park 3:20 Intermission. 3:35 262. Conjugated macromolecules from acetylenic building blocks. M. HàuGler, Β. Ζ. Tang 4:05 263. Synthesis and charge transport properties of new pentacene derivatives. Z. Bao 4:35 264. Dependence of polyacetylene conductivity on doping level: An epilogue. J. B. Schlenoff 4:55 265. Construction of superhierarchical structure of helical polyacetylene by using liquid crystal field. K. Akagi
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-115
TECHNICAL PROGRAM
POLY Section Ε
Thin Films and Confinement Sponsored by PMSE, Cosponsored with POLY
McCormick Place South Room S501B/C/D, Level 5
T U E S D A Y EVENING
Polymer Surfaces and Interfaces Self-Assembly, Adsorption and Patterning Cosponsored with PMSE J. P. Youngblood, R. C. Advincula, and Y-C. I. Chang, Organizers B-H. Sohn,
Hyatt Regency Chicago Riverside Center General Papers and Segmented Block Copolymers
Presiding
A. J . Crosby, Organizer,
Presiding
1:30 Introductory Remarks. 1:35 266. Control and prevention of polymer film buckling by incorporating surface topographies and nanoparticles. T. R. Hendricks, I. Lee 1:55 267. Thin films of diblock copolymer micelles for controlled light emission of fluorescent dyes. S. I. Yoo, W-C. Zin, K. S. Kim, S. H. Bae, B-H. Sohn 2:25 268. Morphological consequences of assembling surfactant nanoparticles on block copolymer interfaces. B. J. Kim, G. H. Fredrickson, C. J. Hawker, E. J. Kramer 2:55 269. Theoretical and experimental studies on the surface structures of conju gated rod-coil block copolymer brushes. W. C. Wu, Y. Tian, C-Y. Chen, C-S. Lee, Y-J. Sheng, W-C. Chen, Α. Κ. Υ. Jen 3:25 Intermission. 3:35 270. Highly ordered Langmuir films of amphiphilic polypropylene imine) dendrimers at the water-air interface. A. Su, S. Tan, P. Thapa, Β. Ν. Flanders, W. T. Ford 3:55 271. Controlling diblock copolymer nanopatterning and nanoporosity on sur faces using small molecules. R. E. Prud'homme, A. Laforgue, D. Gaspard, C. G. Bazuin 4:25 272. Compression-induced nanostructures of hydrophobically modified poly-(2isopropyl-2-oxazoline)s at the air/water interface. R. Obeid, R. Advincula, F. M. Winnik 4:55 273. Sterically-stabilized latexes as foam stabilizers. S. P. Armes, S. Fujii, P. D. Iddon 5:25 274. Displacer effects on the adsorption of polystyrenes in nanoporous silica. C. Y. Ryu, C. Kim, J. Batson, S. Kumar Section F McCormick Place South RoomS501A, Level 5 ACS Award in the Chemistry of Materials: Symposium in Honor of Robert S. Langer Κ. Ε. Uhrich and G. A. Ameer,
Organizers
1:30 275. Self-assembly in regenerative and cancer therapies. S. I. Stupp 1:55 276. Engineering complex bioelastomers for vascular and orthopaedic applica tions via non-complex chemistry. G. A. Ameer 2:20 277. De novo engineering of tissue: Teaching old materials new tricks. V. P. Shastri 2:45 278. Adhesive polymers inspired by marine glue proteins. P. B. Messersmith 3:10 Intermission. 3:20 279. Controlled radical polymerization strategies to synthesize protein-polymer conjugates for medicine and biotechnol ogy. H. D. Maynard 3:45 280. Engineering active interfaces between cells and materials. M. Mrksich 4:10 281. Rationally designed linear-dendritic targeted delivery systems. P. T. Hammond 4:35 282. Award Address (ACS Award in the Chemistry of Materials, sponsored by E. I. du Pont de Nemours & Company). Polymers for drug delivery and tissue engineering. R. S. Langer Nanostructures from Block Copolymers and Supramolecular Polymers
116-TECH
Section A
R. J. Gaymans and T. E. Long, Organizers D. Garcia, Organizer,
Presiding
6:00-8:00 283. Influence of the skin-core morphology of injection molded polypropylene on the migration and distribution of a phenolic antioxidant. P. Vandervorst, N. C. Billingham 284. Preparation of organoclay nanocomposites from biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (Nodax)™. X. Zhang, R. Abou-Hussein, M. K. Hassan, I. Noda, J. E. Mark 285. Probing early aggregation and conforma tional transition of amyloid peptides with nonlinear and time-resolved fluorescence spectroscopy. Y. Wang, T. Goodson III 286. In vitro mineralization of phosphate containing polymer ad-layers. S. Suzuki, L. Rintoul, M. J. Monteiro, E. Wentrup-Byme, L. Grondahl 287. Urea and thiourea based multi-armed functional monomers for molecular recog nition and imprinting. Y. Zhang, K. D. Shimizu 288. Conjugated polymers containing first row transition metal complexes. S. Yuan, R. Jaramillo, T. F. Rosenbaum, L. Yu 289. Electrospray ionization time of flight mass spectrometry analysis of perfluoroalkyl acrylic oligomers synthesized using atom transfer radical polymerization. T. Romack, A. S. Danell, T. M. Cottone, S. K. Dutta 290. Influence of stereotacticity defects on the crystallization of isotactic polypropylene. R. Ozisik, X. Chen, S. K. Kumar, W. L. Mattice, P. Choi 291. MHMA-based clay nanocomposite via photopolymerization. E. Kaya, L. J. Mathias 292. Novel conjugated poly(aromatic diacetylene)s containing triphenylamine-substituted fluorene. H. Peng, D. Chang, B. Tang 293. Physical and electric properties of a PTFE-containing gas diffusion layer for proton exchange membrane fuel cell. Y. Chen-Yang, T. Hung, J. Huang, F. Yang 294. Ultrafast spectroscopic and nonlinear optical characterization of the molecular dynamics of a herpes simplex virus (HSV) receptor polypeptide. O. J. Brown, T. Goodson III 295. Controlled condensative block copolymerization of aminobenzoic acids. K. Ohshimizu, Y. Shibasaki, M. Ueda 296. Investigating copolymer architectures: Determination of reactivity ratios for disubstituted lactide monomers. E. B. Vogel, M. R. Smith III, G. L Baker 297. Control of interfacial properties of silica nanoparticles with grafted mixed polymer shell. M. Motornov, R. Sheparovych, R. Lupitskyy, E. MacWilliams, O. Hoy, I. Luzinov, S. Minko
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298. Novel catalysts for the synthesis of poly(2,6-dimethyl-1,4-phenyleneoxide) (PPO) in purely aqueous environment. E. M. Tee, B. Berry, R. Shekhawat, T. Viswanathan 299. Enhancement of glass transition tem perature for MMA copolymers with fluorinated aryl methacrylates involving intermolecular interaction. H. Teng 300. Nanocomposite based on thiol-ene photopolymerization. H. Wei, S. K. Goswami, L. J. Mathias, C. E. Hoyle 301. Patterning of block copolymer microdomain orientations in thin films. I. In, S-M. Park, Y-H. La, P. F. Nealey, P. Gopalan 302. Synthesis and SEC characterization of polyisobutylenes from the 4-(2-methoxyisopropyl) styrène inimer. E. A. Foreman, L. M. Dos Santos, J. E. Puskas 303. UV grafting of poly (ethylene glycol) methacrylate onto poly (vinyl chloride). E. Arenas, E. Bucio, G. Burillo 304. Study of polyelectrolyte brushes. D. J. Sandberg, T. Seery, A. Vobrynin 305. Analysis of the architecture of polyisobutylenes by multidetection SEC and selective chemical link destruction. L. M. Dos Santos, E. A. Foreman, M. Y. Sen, J. E. Puskas 306. Click functionalization of aliphatic polyesters. A. H. Brown, D. O. Downing, V. V. Sheares 307. Composite proton exchange membranes for fuel cells: Direct polymerization of sodium styrenesulfonate from silica surfaces. Q. Yuan, G. L. Baker 308. Hyperbranching polymerization of glycerol and fumaric acid. B. S. Werry, E. Fossum 309. Synthesis and cyclopolymerization of a non-symmetric functional divinyl monomer. B. Dizman, L. J. Mathias 310. Manipulation of the branching structures of hyperbranched poly(arylene ether phosphine oxide)s using an A2 + B2 + B3 approach. M. Simons, E. Fossum 311. Synthesis of p-phenylenevinylene dendrons. P. A. Bell, T. M. Chapman 312. Deposition methods for 3-aminopropyltriethoxysilane films. J. A. Howarter, J. P. Youngblood 313. Tailoring branching via reactivity ratio controlled polymerization reactions of AB2 monomers. A. M. Ike, D. R. Douglass, E. A. Fossum 314. Density functional calculations as a probe of hydrogen bond strength and mesophase stability in supramolecular liquid crystalline polymers. C. J. Cook, J. A. Phillips, K. N. Wiegel 315. Gas-phase reactions of PPI dendrimers and analogs complexed with divalent zinc. J. D. Batchelor, J. T. Kilgore, R. Harmon, W. D. Price 316. Polymerization of phthalide-based compounds having tandem-reaction enhancement of branching (TREB) reactivity resulting in increased degree of branching. J. Wang, D. M. Johnson 317. Thermal polymerization of bisphenol cyanates to new resin materials. T. S. Filipova, J. T. Reams, D. A. Boyles 318. Aromatic copolycarbonates of bisphenol A and triptycene-1,4-hydroquinone. D. A. Boyles, T. S. Filipova, J. T. Bendler 319. Spherical assembly of gold nanoparticles via good-solvent evaporation process. J. C. Cho, J. Lee, M-S. Kim, N. A. Kotov, J.Kim 320. Synthesis of astaxanthin initiated poly(lactide) by organocatalysis. H. Middleton, A. P. Dove, D. M. Haddleton 321. Effect of ligand and initiator structures on the equilibrium constants in Atrp. W. Tang, Y. Kwak, N. V. Tsarevsky, K. Matyjaszewski 322. Confocal Raman spectroscopy and principal component analysis of multi-layer polymer films. D. Garcia 323. Synthesis and polymerization of ether dimers of octadecyl and 2-ethylhexyl a(hydroxymethyl) acrylates. H. Tas, L. J. Mathias 324. Poly(s-caprolactone)/organo-modified montmorillonite nanocomposites by in-situ polymerization. E. Tarkin Tas, S. Κ. Goswami, B. R. Nayak, L. J. Mathias 325. Initiation of butyl methacrylate polymer ization in the presence of pentametyl diethylenetriamine and air. E. Dogan, S. Bayrak, A. E. Acar
326. Raft cyclopolymerization of tert-butyl alpha-(hydroxymethyl)acrylate (TBHMA) ether dimer. S. Erkoc, A. E. Acar 327. Synthesis of living/controlled cyclopolymers with six-membered tetrahydropyran repeat units and their corresponding block copolymers. S. Erkoc, P. Ulus, L. J. Mathias, A. E. Acar 328. Synthesis of novel cyclopolymers via ATRP for potential use in powder coatings. A. Can, E. Goroglu, A. E. Acar 329. Cyclopolymerization of bulky adamantyl and cyclohexyl alpha-(hydroxymethyl)acrylate ether dimers by ATRP. G. Kocasakal, C. Yilmaz, A. E. Acar 330. Intermediacy of radicals in rearrange ment and decomposition of metal-alkyl species: Relevance to metal-mediated polymerization of polar vinyl monomers. M. L. Nagel, A. Sen 331. Improved monomer synthesis for hyper branched poly(arylene-ether-ketone-imide)part II. D. H. Wang, T. Marsh, Z. Yu, E. Fossum, P. T. Mather, L-S. Tan 332. Catalytic regio-controlled oxidative cou pling polymerization of 2,5-dimethylphenol. Y. Suzuki, Y. Shibasaki, M. Ueda 333. Controlling polymerizations initiated by Lewis acid-induced /V-methyleneamines: Effect of solvent, Lewis acid, and addi tives. N. A. Cohen, E. S. Tillman 334. Grafting of detonation nanodiamond with m-poly(etherketone) in polyphosphoric acid. D. H. Wang, L. S. Tan, H. Huang, L. Dai, E. Osawa 335. Ionic liquids and their application in cellulose chemistry. T. Erdmenger, C. Haensch, R. Hoogenboom, U. S. Schubert 336. Peptide containing polyolefins engi neered for biological applications. J. K. Leonard, K. B. Wagener 337. Synthesis of Mg(OH)2/polystyrene nanocomposite with core-shell structure by borane chemistry. G. J. Jiang, M-J. Chang, G-H. Lai, H-M. Cheng Jr. 338. Free radical copolymerization behaviors and copolymer properties of 1-vinylnaphthalene and fluorinated styrènes. C. N. Tang, M. Paz-Pazos, C. Pugh 339. Heteroatomic-core supramolecular liquid crystalline polymers. D. K. Witte, P. J. Yanzer, Κ. Ν. Wiegel 340. Hydrosilylation polymerization of cage silsesquioxane hydrosilanes with di-vinyl or di-yne derivatives. Y. Ishida, M. Seino, R. Kikuchi, T. Hayakawa, M-A. Kakimoto, H. Oikawa 341. Novel copolymers of vinyl acetate and halogen ring-substituted 2-phenyl-1,1dicyanoethylenes. G. B. Kharas, S. M. Russell, R. M. Doshi, M. Y. Hijazin, E. Korkofigas, N. Kuzenkova, B. Leung, H. Martinez, F. A. Merchant, N. T. Meschbach, E. S. Opiola 342. Unsaturated polyesters prepared under mild reaction conditions by aliphatic nucleophilic substitution reactions. A. Parthiban, T. R. Babu Rao 343. Phase diagram for the conformational behavior of a long chain flexible polyion in poor solvents. C-Y. Shew 344. Synthesis of titania shell on polystyrene core with tunable thickness. M. Agrawal, A. Pich, S. Gupta, N. E. Zafeiropoulos, M. Stamm 345. A new method for encapsulation of proteins in silica aerogels: Using a fluores cent protein as a model. Y. W. Chen-Yang, Y. K. Li, T. Y. Wu, T. Y. Jinn 346. Redistribution/dehydrocatenation of n-Bu3SnH mediated by group 4 transition metal complexes. H-G. Woo, S-Y. Kim, Y-M. Hwang, M-S. Cho, B-S. Pyo, B-H. Kim 347. Cationic polymerization of vinyl deriva tives promoted by thianthrene cation radical. H-G. Woo, M-H. Kim, M-S. Cho, B-S. Pyo, B-H. Kim, H. Li 348. Mass spectrometry of dendrimer metal complexes. J. D. Batchelor, G. A. Harbour, W. D. Price 349. Cp 2 TiCI catalyzed graft copolymerization of styrene and (meth)acrylates from the epoxides of glycidyl methacrylate copoly mers. A. D. Asandei, G. Saha 350. Role of excess Zn in Cp2TiCl2-catalyzed styrene polymerizations from oxiranes, carbonyls and thermal initiators. A. D. Asandei, Y. Chen, G. Saha, I. W. Moran
POLY
351. Living ring opening polymerization of caprolactone with dichlorotitanium bisphenolates. A. D. Asandei, G. Saha, T. A. Hanna, L. Liu 352. Chemical modifications for advanced soft lithography. Κ. Μ. Choi 353. Glucose biosensor based on PEM films/ sol-gel matrix composite membrane. X. Xu, W. Feng Sr. 354. Preparation and characterization of guanidinylated chitosan. Y. Hu, Y. Du, L. Wang, T. Feng, J. Ding 355. Hydrophobical self-association of N-acylated chitosan. Y. Hu, Y. Du 356. Microwave synthesis of poly (vinyl alcohol)-graft-poly ({epsilon}-caprolactone) copolymers. Z. Yu, L. Liu 357. Behavior of macromolecular tertiary amine in photopolymerization. F. Sun, H. Du, Y. Huang, A. Korigodski 358. Effect of ultrasonic irradiation on enzy matic modification of konjac glucomannan. Z-G. Chen, Y-B. Han, Z-X. Gu 359. Novel amphiphilic poly(ester-urethanes) based on poly (R-3-hydroxybutyrate) (PHB): Synthesis and biocompatibility. Z. Li, S. Cheng, X. Fang, Q. Liu, S. Li, L Wu, K. Xu, G-Q. Chen 360. The AFM study on the surface morphol ogy of a novel hydrogenated elastomer and its sulfonated derivatives. X. Liang, T. Qiu, B. Han, X. Li 361. In-situ polymerization of Ab2 monomer in the presence of carbon nanotubes in polyphosphoric acid. J-Y. Choi, D. H. Wang, L-S. Tan, J-B. Baek 362. Grafting of poly(ether-ketones) onto graphite via in-situ polymeryzation of 3and 4-phenoxybenzoic acids in polyphos phoric acid. S-J. Oh, E-K. Choi, L-S. Tan, J-B. Baek 363. Grafting of hyperbranched polyphenylene sulfide onto the surface of functionalized multi-walled carbon nanotube. I. Y. Jeon, J-Y. Choi, L-S. Tan, J-B. Baek 364. Novel fluorescent polymer nanoparticles with chemically bonded tetraphenylethylene derivatives. C-M. Xing, Y. Hong, Y. Dong, J. W. Y. Lam, A. Qin, M. HàuBler, Β. Ζ. Tang 365. Synthesis of conjugated organometallic hyperbranched polymers by copolycyclotrimerization of ferrocene-containing diynes and monoynes. J. Shi, B. Tong, W. Zhao, J. Shen, J. Zhi, Y. Dong, M. HâuBler, J. Wing Yip Lam, B. Tang 366. Facile synthesis of poly(aroyltriazole)s by metal-free 1,3-dipolar polycycloaddition (click polymerization). A. Qin, C. K. W. Jim, J. W. Y. Lam, M. HâuBler, Y. Dong, Β. Ζ. Tang 367. Study on chain extending of poly(l-lactic acid) by triphenyl phosphite addition during the processing. J . Xie, R. Yang 368. Dodecanol encapsulation by polymer through emulsion polymerization and its release thereafter. X. Z. Kong, X. Zhao, X. Zhu, Z. Zhang 369. Photosensitive properties of a novel uv-curable polysiloxane urethane diacrylate oligomer. F. Sun, J. Xiong, H. Du 370. Preparation of P(St-BA-AA) hollow latex particles. Q. L. Zhang 371. Synthesis and thermal properties of side-chain liquid-crystalline poly(ethyleneimine)s with mesogenic groups. M. Xie, C. Zhang 372. Synthesis and liquid crystallinity of poly(ethyleneimine)s with cyanobiphenyl side chains. M. Xie, C. Zhang 373. Monte Carlo simulation on dynamic behavior of polymer chain. Q. L. Zhang Jr. 374. Permeability of copoly(ether-esters). J. Krijgsman, A. Schmidt 375. High Tg segmented copolymers with monodisperse crystallizable segments. J. Krijgsman, G. J. Biemond, R. Stephen, R. J. Gaymans 376. Gas permeability of PEO-based seg mented block copolymers. D. Husken, T. Visser, M. Wessling, R. J . Gaymans 377. Polyurethane triblock copolymers based on monodispersed amide segment synthesis, mechanical, elastic and Theo logical properties. A. Arun, K. K. J. Baack, R. J. Gaymans 378. Polyurethanes with a diamine-diamide chain extender. D. De, R. J. Gaymans
379. Synthesis and characterization of seg mented multiblock sulfonated polyarylenethioethersulfones for proton exchange membranes. Z. Bai, M. Yoonessi, S. Juhl, L. F. Drummy, H. Koemer, M. F. Durstock, T. D. Dang 380. The chemoenzymatic synthesis of novel amphiphilic pentablock copolymer. Y. Li, S. Wang, W. Wang, K. Sha, Y. Xu, J. Wang 381. The chemoenzymatic synthesis of poly(2,2,2-trichloroethyl 10-hydroxydecanate)-block-polystyrene combining selfcondensation polymerization and ATRP. K. Sha, Y. Li, S. W. Wang, Y. L. Zhao, J. Y. Wang 382. Highly branched, segmented polyurea elastomers through oligomeric A 2 + B 3 approach. S. Cakir, E. Yilgor, I. Yilgor, C. Oguz, M. Gallivan 383. Substituted benzyl alcohol based afunc tional initiators suitable for atom transfer radical polymerization and ring opening polymerization. A. Likhitsup, A. Parthiban, C. L. L. Chai, L. K. Shuang 384. Synthesis and characterization of block copolymers based on hyperbranched polysiloxysilane. M. Melira, M. Seino, T. Hayakawa, M-A. Kakimoto 385. Characterization of biostability and vas cular compatibility and safety of different compositions of poly(styrene-b-isobutylene-b-styrene) copolymers. F. Strickler, M. Boden, R. Richard, S. McFadden, M. Bravo, J. Lindquist, P. Straumann, R. Faust 386. Dipropargyl ethers of high aspect ratio bisphenols. T. S. Filipova, D. A. Boyles, J. T. Reams 387. Synthesis of block copolymers by a combination of RAFT polymerization with click chemistry. Y. Li, B. C. Benicewicz Section Β Hyatt Regency Chicago Riverside Center Combinatorial and High Throughput Polymer Chemistry K. L. Beers and E. J. Amis,
Organizers
6:00-8:00 388. ATRP and free radical polymerizations using high throughput approach: Effect of inhibitor. M. J. Nasrullah, D. C. Webster 389. Automated software tool for the rapid evaluation of bacterial biofilm retraction on fouling-release marine coatings. S. J. Stafslien, J. Daniels, J. A. Bahr, B. Mayo, B. J. Chisholm, R. J. Pieper, D. Webster, E. Ribeiro 390. Combinatorial exploration of tethered biocides in marine coatings. A. J. Kugel, S. M. Ebert, B. J. Chisholm 391. High-throughput investigations on the nitroxide mediated polymerization condi tions using an automated parallel synthe sizer. C. R. Becer, R. M. Paulus, R. Hoogenboom, U. S. Schubert 392. Synthesis of polymer-grafted PAMAM-gPSt with a shell of PSt grafts on the sur face of PAMAM dendrimer by ATRP. Y. Zhao, Y. Song, W. Jiang, W. Wang, J. Wang 393. The application of combinatorial/highthroughput methods to the development of hybrid organic-inorganic coatings for the protection of aluminum alloys (2024-T3). B. J. Chisholm, M. Berry, J. A. Bahr, J. He, J. Li, D. Battocchi, G. Bierwagen
Section C Hyatt Regency Chicago Riverside Center Unconventional Processes for Nanostructured and Microstructured Polymers and Emerging Frontiers in Polyolefins Posters J. M. Torkelson, K. R. Shull, P. Arjunan, E. B. Coughlin, and S. A. Miller, Organizers 6:00-8:00 394. Addition of gradient copolymers as a new route for polymer blend compatibilization: Effects of structure, molecular weight and composition of gradient copolymers. J. Kim, J. M. Torkelson 395. Compatibilization of polystyrene/polycaprolactone blends via hydrogen bonding effects: Addition of styrene/hydroxystyrene "blocky" gradient copolymer as interfacial agent. R. W. Sandoval, J. Kim, J. M. Torkelson 396. Crosslinking 3-D assemblies of silica nanoparticles (aerogels) by surface-initi ated free radical polymerization of styrene and methylmethacrylate. N. Leventis, S. Mulik, C. Sotiriou-Leventis 397. Enhanced barrier and mechanical prop erties associated with granule morphology in polyethylene/starch blends: "Damaging" starch by solid-state shear pulverization. A. M. Walker, Y. Tao, J. M. Torkelson 398. Fabrication of microporous films utilizing polystyrene-/poly(aromatic amide dendronized styrene) with carboxyl end groups. T. Hirai, R. Kikuchi, T. Hayakawa, M-A. Kakimoto 399. Gradient copolymer design for damping behavior over broad temperature ranges. M. M. Mok, J. M. Torkelson 400. Rheological behavior of multiwalled carbon nanotubes/polystyrene nanocomposites. Q. Zhang, F. Fang, Z. Chang, D. Chen, M. Zhu 401. Synthesis of polystyrene-sepiolite nanocomposites. Z. Le, X. Yang, R. Ruan, Y. Huang 402. Synthesis of sulfonic acid-terminated, four-armed dendrons. R. Goseki, F. Morishita, M. Watanabe, T. Hayakawa, M-A. Kakimoto, M. Tokita, J. Watanabe 403. Toughening of ceramics via in situ poly merization. C-H. H. Hsiung, K. T. Faber, K. R. Shull 404. The para-octaiodophenylsilsesquioxane, [p-IC6H4Si01.5]8, a perfect nanobuilding block. M. Roll, M. Z. Asuncion, R. Laine 405. Metallocene catalyzed olefin polymeriza tion in presence of diethyl zinc: Molecular weight control and polyolefin functionalization. J. O. Ring, R. Mulhaupt 406. Branch density effects on crystallization kinetics and multiple melting behaviors of ethylene-hexene copolymers. J. Qiu, Z. Wang, Q. Zhou 407. Sequence distribution and crystallization kinetics of random propylene ethylene copolymers up to 25 mol% ethylene. Y. Chiari, K. Jeon, R. G. Alamo 408. Electrical conductivity and crystalline morphology of single-walled carbon nanotube/linear polyethylene nanocomposites. K. Jeon, R. G. Alamo, L Lumata, T. Tokumoto, J. S. Brooks 409. Development of a new packing material for the high temperature size exclusion chromatography of polyolefins. J. A. McConville, G. Saunders, L. Gilbert, I. Willoughby Section D Hyatt Regency Chicago Riverside Center 30 Years of Conducting Polymers S. A. Jenekhe and J. P. Armistead,
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Organizers 6:00-8:00 410. Comparison of initiator to catalyst stoichiometry in Cp 2 TiCI-mediated styrene poly merizations from peroxides, aldehydes and epoxides. A. D. Asandei, G. Saha, Y. Chen, I. W. Moran
411. Controlled release from biomems devices utilizing electroactive polymers. P. J. Kinlen, Y. Ding, J. Ulyanova, A. Pellin, S. Hou, R. Giedd, R. Patel, M. Curry 412. Facile synthesis of P3HT-P2VP block copolymers and their self-assembly behav ior. W-C. Yen, Y-H. Lee, C-C. Ho, C-A. Dai, W-F. Su 413. PEO based block copolymer as all-solid state battery electrolyte. A. Ghosh, P. Kofinas 414. Triptycene-containing PPEs: Effect of perfluoroalkyl substitution on polymer aggregation. Z. Chen, T. M. Swager 415. 3,4-Ethylenedioxythiophene (edot) based processable precursor polymers for the synthesis of poly(3,4-ethylenedioxythiophene) (pedot). J. G. Bokria, A. Kumar, V. Seshadri, A. Tran, G. A. Sotzing 416. Effect of silane substitution on solid-state oxidative conversion of poly[(2,2'-bithienyl)dialkylsilane] precursors to poly(bithiophene). J. Choi, G. A. Sotzing 417. Carboxylic acid-modified EDOT for biofunctionalization of neural probe elec trodes. L K. Povlich, J. C. Cho, S. Spanninga, D. C. Martin, J. Kim 418. Cascade synthesis of enzymatic ringopening polymerization and atom transfer radical polymerization. X. Liu, J. Wang 419. Characterization of N-functionalized poly(dithieno[3,2-b:2',3'-d]pyrrole)sin ternary blend bulk heterojunction struc tured organic electronic devices. W. J. Belcher, S. C. Rasmussen, P. C. Dastoor 420. Chemiluminescent conjugated polyelectrolytes. Y. Liu, K. S. Schanze 421. Comparison of two precursor routes to conducting polythiophenes. S. A. Pendergraph, M. S. Yavuz, G. A. Sotzing 422. Conducting polymer nanoarchitectures from diverse synthetic routes. M. G. Han, S. Foulger, S. S. Im 423. Conjugated polymers of bis(2-(3,4ethylenedioxy)-thienyl)-thiophene (BEDOT-T) from poly(arylsilane) precur sors via solid-state oxidative conversion. M. S. Yavuz, S. A. Pendergraph, G. A. Sotzing 424. Conjugated polythiophenes from poly(NVinylpyrrolidone) precursor conversion in the solid swollen state. M. Ombaba, G. A. Sotzing 425. Difussion coefficient of Lithium Triflate ions in polyterthiophene-co-polynorbornene submicron fibers and films by electro chemical potential step experiments. C. I. Asemota, G. A. Sotzing, T. Otero 426. Directly grafts the conjugated polymer to nanoparticle surface synthesis, character ization and application for organic elec tronic devices. H-S. Wang, K-H. Wei 427. Dual-polymer electrochromic film charac terization using bipotentiosatic control. E. Unur, J-H. Jung, R. J. Mortimer, J. R. Reynolds 428. Effects of acceptors on the electronic and optoelectronic properties of fluorene based donor-acceptor-donor copolymers. W-Y. Lee, T-F. Wang, W-C. Chen, C-S. Tuan, J-L. Lin 429. Electrochemical tuning of the optical properties of crystalline colloidal arrays composed of poly(3,4-ethylenedioxythiophene)-coated silica particles. J. Norton, M. G. Han, P. Jiang, D. D. Evanoff Jr., S. E. Creager, S. Foulger 430. Enhance photocurrent in poly(3hexylthiophene)/gold nanoparticle compos ite films by gold surface plasmon reso nance. M-Y. Chiu, K-H. Wei 431. Formulation and characterization of ultrahigh conductive epoxy composites. S. M. Rhodes 432. Highly conductive DEHSS-doped PANI synthesized in different protonic acids medium. L Kwong Seng, N. Kuramoto 433. Highly fluorescent oligothiophenes incor porating central dithieno[3,2-b:2',3'-d]pyrroles: Side chain effects on solution and solid-state properties. H. Mo, S. C. Rasmussen 434. Low band gap donor-acceptor polymers. T. T. Steckler, J. R. Reynolds 435. N-alkylated poly(3,4-propylenedioxypyrrole)s as soluble and processable electroactive materials with tunable electronic and optical properties. J-H. Jung, R. M. Walczak, E. Unur, J. R. Reynolds
ÎECH-117
TECHNICAL PROGRAM
POLY 436. Optically active polyfluorene aggregates induced by chiral solvents. Y. Nakano, Y. Liu, M. Fujiki, M. Ishikawa, M. Naito, H. Onouchi 437. Patterning of electrochromic polyterthiophene fiber mats and films and potential applications. C. I. Asemota, M. Rousselle, A. Kumar, G. A. Sotzing 438. Poly(3,4-ethyelendioxythiophene) PEDOT via solid-state oxidative conver sion of a Germane polymer precursor. M. Ombaba, G. A. Sotzing 439. Poly(3,4-ethylenedioxythiophene) (PEDOT) from processable precursors via bromine vapor exposure. J. G. Bokria, A. Kumar, V. Seshadri, A. Tran, G. A. Sotzing 440. Poly(alkylaminothiophene)s: Heteroatomic analogs of polyalkoxythiophenes or a unique new class of polythiophenes? C. L. Heth, S. D. Rothstein, D. E. Tallman, S. C. Rasmussen 441. Polybithiophene from melt processed poly[(2,2'-bithienyl)dimethylsilane] using solid-state oxidative conversion. J. Choi, G. H. Ling, M. Shaw, G. A. Sotzing 442. Regioregular random copolymers of 3-alkylthiophene and thiophene. S. A. Sydlik, R. D. McCullough 443. Schizophobic fluorinated/zwitterionic copolyelectrolytes. R. M. Jisr, J. B. Schlenoff 444. Study on the molding characteristics of injection molded conductive plastic used for bipolar plate of fuel cell. S-C. Chen, M-Y. Shih, Y-C. Lin, J-A. Chang 445. Supercapacitors based on polymeric dioxypyrroles and single walled carbon nanotubes. M. Ertas, R. K. Das, A. G. Rinzler, J. R. Reynolds 446. Synthesis and optoelectronic properties of poly(quinoxaline vinylene) and its ran dom copolymer with fluorene. C-C. Chueh, W-Y. Lee, W-C. Chen 447. Synthesis of a novel pH-sensory and highly stable conjugated copolymer con taining oxadiazole derivatives. K. Lee, H-J. Kim, J. C. Cho, J. Kim 448. Synthesis of metal thiophenedithiolenes for the production of magnetic conducting polymers. C. M. Amb, S. C. Rasmussen 449. Synthesis of soluble crosslinked poly (styrene-divinylbenzene-natural rubber) and molecule size determination. F. Li, B. Wu, R. Sun, D. Liu, X. Chen, Y. Wang, J. Chen, Q. Zhou 450. Synthesis of thieno[3,4-b]pyrazine oligo mers as precursors to low band gap materials and models of effective conjuga tion. L. Wen, S. C. Rasmussen Section Ε Hyatt Regency Chicago Riverside Center Polymer Surfaces and Interfaces J. P. Youngblood, A. J. Crosby, R. Advincula, and Y-C. I. Chang, Organizers 6:00-8:00 451. Black lipid membranes on polymer modified substrates: An approach toward a planar patch clamping technique. G. Baaken, M. Sondermann, O. Prucker, J. Behrends, J. Riihe 452. Characterization of polymer brushes in microcapillaries. A. N. Constable, W. J. Brittain 453. Effect of Tg on the self-organization of gradient fluorinated polyacrylates latex blends. C. Zhang, Y. Hu, Y. Chen 454. Functionalization of hyperbranched polysiloxysilane at focal point. Y. Yamada, R. Kikuchi, T. Hayakawa, M-A. Kakimoto 455. Improved interfacial adhesion between metal and polymer utilizing a biomimetic initiator. L. K. Meade, X. Fan, P. B. Messersmith, L. C. Brinson 456. Interfacial behavior of the thermo-responsive pentablock copolymer. S. Peleshanko, K. Anderson, M. D. Goodman, M. D. Determan, S. K. Mallapragada, V. V. Tsukruk 457. Limiting Theological properties of octaisobutyl-POSS and poly(dimethylsiloxane) blends. S. M. Huffer, W. Yin, A. R. Esker
T18-TECH
458. Modification of nylon membrane surface with thin polymer layer via "grafting to" approach. O. Burtovyy, V. Klep, T. Turel, Y. Gowayed, I. Luzinov 459. Polymer brushes grafted from patterned chemically active surfaces via atom trans fer radical polymerization. C. R. Becer, C. Haensch, S. Hoeppener, R. Hoogenboom, U. S. Schubert 460. Polysaccharide self-assembly onto cellulose via surface plasmon resonance spectroscopy. A. Kaya, W. G. Glasser, A. R. Esker 461. Preparation of PLGA:PAMAM dendrimers blend nanoparticles as novel gene delivery carriers. H. Li, J. Liu 462. Stimuli-responsive surfaces using polyampholyte polymer brushes prepared via atom transfer radical polymerization. C. D. Cyrus 463. Structure and scaling behavior of poly mer brushes with multiple tethers. J. Alonzo, Z. Huang, H. Ji, J. W. Mays, M. D. Dadmun, S. M. Kilbey 464. Surface grafting on polyvinyl chloride) via physisorbed free radical initiation. Κ. Μ. McGinty 465. Substituent effects in ATRP of polysty rene brushes. S. Saha, Z. Bao, M. L. Bruening, G. L. Baker 466. Synthesis of polyacrylamide-silica hybrid nanoparticle using RAFT polymerization and click chemistry. R. Ranjan, W. J. Brittain 467. Temperature gradient interaction chro matography of pi-conjugated PPV-based oligomers. J . Han, N. Chen, J. Hyun, C. Y. Ryu WEDNESDAY MORNING
Section Β McCormick Place South Room S502A, Level 5 Polymer Performance, Degradation, and Materials Selection Service Life Prediction M. Celina, J. S. Wiggins, and N. C. Billingham, Organizers 8:25 Introductory Remarks. 8:30 478. Oxidative degradation of polymers: A tutorial on what we don't know. N. C. Billingham 9:30 479. Lifetime prediction: Different strate gies by example. U. W. Gedde 10:00 Intermission. 10:20 480. Use of a respirometer to measure oxidation rates of polymeric materials. R. A. Assink, M. Celina, T. L. Garcia 10:40 481. Accelerated degradation of syn tactic polysulfide in the presence of Viton A. A. L. Vance, C. A. Harvey, C. T. Alviso 11:00 482. Durability aspects of poly(pphenylene benzobisoxazole) fibers used in body armor. J. W. Chin, A. L. Forster, K. Rice 11:20 483. Performance and operation of PVDF-based adaptive polymers in space. M. Celina, T. R. Dargaville, G. D. Jones
9:50 496. Exciton migration in rigid rod conjugated polymers. A. B. Walker, S. Athanasopoulos, D. Martinez, D. Beljonne, E. Hennebicq 10:10 497. Single molecule surface enhanced Raman spectroscopy of conju gated polymers. M. J. Walter, N. J. Borys, J. M. Lupton 10:30 Intermission. 10:45 498. New structure-function relation ships in conjugated polyelectrolytes. G. C. Bazan, R. Yang, A. Garcia, J. Hong, T-Q. Nguyen, G. Keller 11:15 499. PPEs as biosensory materials. U. H. F. Bunz, l-B. Kim, R. L Phillips, B. E. Carson, C. Kub 11:45 500. Biotechnical aspects of conduc tive polymers: Biosensors, biochips and biocompatibility. A. Guiseppi-Elie, W. Torres 12:15 501. Conjugated polyelectrolytes featuring carboxylate side groups: Synthe sis, amplified fluorescence quenching and sensitized solar cells. X. Zhao, H. Jiang, K. S. Schanze Section Ε McCormick Place South Room S501B/C/D, Level 5 Polymer Surfaces and Interfaces Polymer Nanocomposites, Particles, Hydrogels and Emulsions Cosponsored with PMSE
Section C McCormick Place South Room S501D, Level 5 Unconventional Processes for Nanostructured and Microstructured Polymer Systems Novel Molecular Assembly
J. P. Youngblood, A. J . Crosby, R. C. Advincula, and Y-C. I. Chang, Organizers R. Krishnamoorti and T. Emrick,
Presiding
Section A McCormick Place South Room S503A, Level 5 General Papers Polymer Synthesis and Characterization D. Garcia,
Organizer
M. Scandone,
Presiding
8:30 468. Synthesis and characterization of random copolyimides. R. Narain, B. Francis, K. Babooram, R. Subramanian, R. Bissessur 8:50 469. Analysis of polymeric IR spectra via principal component analysis (PCA) and visualization tools. G. M. Banik, M. Scandone, M. D'Souza 9:10 470. Thermodynamics of aggregate solvation in poly(dioctylfluorene) solutions. C. C. Kitts, D. A. Vanden Bout 9:30 471. Tunable thermoreversible polymer networks by multifunctional hydrogen bonding self assembly. K. P. Nair, V. Breedveld, M. Week 9:50 472. Microwave-assisted synthesis and properties of novel poly(2-oxazoline)s. R. Hoogenboom, M. M. W. Fijten, H. Thijs, U. S. Schubert 10:10 473. Acrylates as end-group function alization agents in ROMP. C. Lexer, R. Saf, F. Stelzer, C. Slugovc 10:30 474. Effects of solvents on conforma tional rigidity of poly(2,6-di-iso-propylphenyl methacrylate) in dilute solutions. N. Hamidi 10:50 475. GPC-MALS characterization of fluoropolymers in trifluorotoluene mobile phase. T. Romack, Z. J. Harrison, D. V. French, D. H. Amin, J. L Hartsell, J. D. Meyers 11:10 476. Rational design of electron trans porting polymers: High electron mobilities in phenacyl-thiophene molecules and polymers. J. Letizia, A. Facchetti, M. A. Ratner, T. J. Marks 11:30 477. Synthesis and crosslinking of poly(arylene ether sulfone) blend mem branes. M. Paul, A. Roy, H. B. Park, B. D. Freeman, J. S. Riffle, J. E. McGrath
J. M. Torkelson and K. R. Shull, Organizers 8:25 Introductory Remarks. 8:30 484. Multicompartment micelles from the assembly of charged triblocks or diblock copolymer blends with multivalent organic counterions. D. J. Pochan 9:00 485. Thermosensitive reactive poly mers: "Smart" crosslinkers for aqueous formulations. I. Iliopoulos 9:30 486. Synthesis of vinyl polymer-silica nanocomposite particles. S. P. Armes, J-J. Yuan, A. Schmid 10:00 Intermission. 10:15 487. An overview of gelcasting. M. A. Janney 10:45 488. Acrylic triblock copolymer gels for thermoreversible gelcasting of ceramics. M. E. Seitz, W. R. Burghardt, K. T. Faber, K. R. Shull 11:05 489. Thermoreversible gelcasting of porous aluminum oxide preforms. N. O. Shanti, K. T. Faber 11:25 490. DNA-directed synthesis of polyaniline and poly(4-aminobiphenyl) oligom ers. B. Datta, G. B. Schuster 11:45 491. Funtionalized block copolymers: Their self assembly and magnetic proper ties. G. N. Tew 12:05 492. Facile surface functionalization of gold nanoparticles with well-defined RAFT prepared glycopolymers. R. Narain, H. Cai, A. Housni
8:30 Introductory Remarks. 8:35 502. Polymer-functionalized semicon ductor nanorods. Q. Zhang, S. Gupta, T. P. Russell, T. Emrick 9:05 503. Reversibly porating materials via microemulsion polymerization. J. Texter, F.Yan 9:35 504. Silica-polymer hybrids: Structure, dynamics and processing. V. Goel, J. Sharma, J. Pietrasik, H. Dong, K. Matyjaszewski, R. Krishnamoorti 10:05 505. Silanated alumina for novel epoxy composites. L. M. McGrath, J. L. Lenhart, R. S. Pamas 10:25 Intermission. 10:35 506. Pattern formation and shape changes in self-oscillating polymer gels. A. C. Balazs, V. Yashin 11:05 507. How does the nature of the steric stabilizer affect the Pickering emulsifier performance of lightly crosslinked, acidswellable poly(2-vinylpyridine) latexes? D. Dupin, S. P. Armes 11:35 508. Modified filler-matrix interfaces in polymeric composites used as dental restoratives. P. K. Shah, J. W. Stansbury 11:55 509. Suppression of physical aging in PMMA-silica nanocomposites: Using spin coating solvent to control polymer-nanofiller interaction. P. Rittigstein, J. M. Torkelson 12:15 510. Fluoropolyurethane hybrids for thin film applications. N. K. Dutta, A. Govindraj Kannan, N. Roy Choudhury
Section D McCormick Place South RoomS501A, Level 5 30 Years of Conducting Polymers Theory/Novel Devices
Nanostructures from Block Copolymers and Supramolecular Polymers Bioinspired Self-Assembly Sponsored by PMSE, Cosponsored with POLY
S. A. Jenekhe, J. P. Armistead, and A. B. Holmes, Organizers C. Y. C. Lee, Organizer,
Presiding
8:30 493. Current induced fluorescence and electron counting-statistics of single mol ecules in junctions. S. Mukamel, J. Maddox, U. Harbola, M. Esposito 9:00 494. Nature and dynamics of electronic excitations in conjugated polymers. D. Beljonne 9:20 495. Ionic motion in polymeric hosts: Some materials, some mechanisms and some models. M. A. Ratner
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
POLY WEDNESDAY AFTERNOON Section A McCormick Place South Room S503A, Level 5 General Papers Polymers and Biology/Polymers in Nanotechnology D. Garcia, H. Liu,
4:50 529. Degradation of polymers by chlo rine and chlorine species. K. Jacobson 5:10 530. Environmentally benign mild degradative transformation of polyvinyl chlo ride) into useful products. G. Szarka, B. Ivan
Section Ε McCormick Place South Room S501B/C/D, Level 5
Section C
Polymer Surfaces and Interfaces Chemistry at Surfaces and Interfaces Cosponsored with PMSE
McCormick Place South Room S502A, Level 5
A. J. Crosby, R. C. Advincula, and Y-C. I. Chang, Organizers
Emerging Frontiers in Polyolefins Catalyst Development/Polymerization
M. D. Dadmun,
Organizer
Presiding
1:30 511. Novel antibacterial polymers. B. Dizman, M. O. Elasri, L. J. Mathias 1:50 512. Synthesis and characterization of novel absorbable cyanoacrylate adhesives for medical applications. H. Liu, S. Gonzalez 2:10 513. Solution properties of antitumor sulfated derivatives of {beta}-D-glucan from Poria cocos. Y. Wang, W. Xu, H. Chen 2:30 514. Biocompatible thermoplastic poly ester urethanejs with novel soft seg ments. B. F. Pierce, A. H. Brown, M. R. Cottle, V. V. Sheares 2:50 515. Acid labile sugar based hydrogels for protein encapsulation and release. R. Narain, L. Lane 3:10 516. Surface modification and polymer grafting "from" and "through" titania nanoparticles. B. J. Lowes, A. G. Bohrer, T. Tran, D. A. Shipp 3:30 517. In-situ formation of (amide-imide)silica composites by the sol-gel process. R. Narain, K. Babooram, B. Francis, R. Bissessur 3:50 518. Influence of nanoparticles on crystallization of isotactic polypropylene. R. Ozisik, X. Chen, S. K. Kumar 4:10 519. Synthesis of new acrylate-based cationic surfmers and their use in the synthesis of PMMA-clay nanocomposite via heterophase polymerization. J-F. Morizur, L. J. Mathias 4:30 520. Organic core-shell nanoobjects by living anionic polymerization. H. Peng, Y. T. Zhu Section Β McCormick Place South Room S502B, Level 5 Polymer Performance, Degradation, and Materials Selection Modeling and Materials Degradation M. Celina, J. S. Wiggins, and N. C. Billingham, Organizers 1:30 521. Mechanistic modeling of polysty rene pyrolysis: Reaction pathways and product distribution. S. E. Levine, L. J. Broadbelt 1:50 522. A non-empirical model for the lifetime prediction of polymers exposed in oxidative environment. X. Colin, B. Fayolle, L. Audouin, J. Verdu 2:20 523. How to relate chemical kinetics data to embrittlement in polymer oxidative aging? B. Fayolle, X. Colin, L. Audouin, J. Verdu 2:40 524. Degradation mechanism and kinetic modeling of intumescent flame retarded polyvinyl acetate). B. Rimez, G. Van Assche, H. Rahier, B. van Mele 3:00 Intermission. 3:20 525. Weathering characteristics of resorcinol polyarylate copolymers. J. E. Pickett, P. D. Sybert, R. L. Carter, D. A. Gibson, S. T. Rice 3:50 526. Aging of the binder in plasticbonded explosive PBX 9501 and freeradical oxidation. J. D. Kress, D. A. Wrobleski, D. A. Langlois, E. B. Orler, J. M. Lightfoot, W. A. Rodin, C. Huddleston, L Woods, B. G. Russell, M. R. Salazar, D. Pauler 4:10 527. Accelerated aging and character ization of a poly(ester urethane) binder. D. A. Wrobleski, D. A. Langlois, E. B. Orler, A. Labouriau, M. Uribe, R. Houlton, J. D. Kress 4:30 528. Nylon degradation: Thermaloxidative vs. humidity. R. Bernstein, D. K. Derzon, K. T. Gillen
S. A. Miller and P. Arjunan, Ε. Β. Coughiin, Organizer,
Organizers Presiding
1:30 531. Chain-walking vs. insertion with Ni-iminophosphonamide catalysts. S. Collins, J. Chai, Z. Flisak, M. Nele, T. Ziegler, J. B. P. Soares 2:05 532. Single component, well-defined catalysts for the copolymerization of olefins and acrylates to linear, high molecular weight, random copolymers. B. L Goodall, N. T. Allen, D. M. Conner, T. C. Kirk, L H. Mcintosh III, H. Shen 2:40 533. Olefin addition polymerization of cyclobutene-type monomers with early and late transition metal compounds. W. Risse, Κ. Curran, L Boggioni, I. Tritto 3:15 534. Novel materials by catalytic poly merization of olefins in emulsion. J. P. Claverie, B. L. Goodall, K. Skupov, P. Marella, J. Hobbs 3:50 535. Highly syndiotactic copolymers of propylene and higher alpha-olefins. S. A. Miller, E. D. Schwerdtfeger 4:25 536. Single-site catalyst for the copoly merization of ethylene with methyl acrylate. M. J . Miri, M. J. Fullana, S. Vadhavkar, X. Mai, J. D. Soucy Section D McCormick Place South RoomS501A, Level 5 30 Years of Conducting Polymers Processing / Morphology
Presiding
J. P. Youngblood, Organizer,
THURSDAY MORNING
J. P. Armistead, C. Y. C. Lee, and A. B. Holmes, Organizers
Section A
S. A. Jenekhe, Organizer,
McCormick Place South Room S503A, Level 5
Presiding
1:30 537. Synthesis and applications of conducting polymer nanofibers. R. B. Kaner, H. D. Tran, R. W. Kojima, J. M. D'Arcy, C. Baker, S. Virji, Β. Η. Weiller 2:00 538. Semiconducting polymers in con fined spaces. S. H. Tolbert 2:30 539. Investigation of polyaniline nanofiber mophology. A. R. Hopkins, S-J. Hwang 2:50 540. Synthesis and applications of aligned polyaniline and polypyrrole nanofi bers. N-R. Chiou, C. Lu, J. Guan, L. J. Lee, A. J. Epstein 3:10 Intermission. 3:25 541. Surprising very large impact of small magnetic and electric fields on conducting polymers. A. J. Epstein 3:55 542. Nanoscale interface engineering and the performance on organic memory devices. Y. Yang, R. Tseng 4:25 543. Electrochromic conducting poly mers in window, display, and variable optical attenuator devices. A. L. Dyer, C. R. G. Grenier, J. R. Reynolds 4:45 544. Modulation of conducting polymer sheet conductivity by transition metal complex monolayers. J. J. Martin, C. J. Timpson, A. Sattler, J. P. Gaffney, K. Pueschel, J. Shah, W. E. Jones Jr. 5:05 545. Nanostructured η-channel ladder polymer transistors and complementary inverters. A. L. Briseno, J. M. Hancock, Y. Xia, S. A. Jenekhe
Presiding
1:30 Introductory Remarks. 1:35 546. Monitoring the reaction of telechelics at a soft polymeric interface to form interfacial modifiers. M. D. Dadmun, J. K. Rice, H. Ji, J. W. Mays, V. Krikorian, E. L. Thomas, G. D. Smith, D. Bedrov 2:05 547. Generation of superhydrophobic surfaces using facially amphiphilic dendrimers. Y. Chen, A. V. Ambade, S. Thayumanavan 2:35 548. Plasma surface functionalization of polyphosphazenes. L. Steely, H. R. Allcock, S. H. Kim, J. H. Kim, B-K. Kang 2:55 549. Surface characterization of oxy gen-plasma treated POSS-based acrylic polymer thin films. Β. Η. Augustine, W. C. Hughes, K. Zimmermann, A. J. Figueiredo, X. Guo, C. C. Chusuei 3:15 Intermission. 3:25 550. Using light to modify surfaces. J. T. Koberstein, G. T. Carroll, N. J. Turro 3:55 551. Selective electroless metallization of elastomeric substrates. T. B. Carmichael, C. M. Mailloux, M. S. Miller, B. J. Sahli 4:15 552. Thin films of poly(styrene-altmaleic anhydride) by initiated chemical vapor deposition. W. E. Tenhaeff, K. K. Gleason 4:35 553. Looped polymer brushes at the solid-fluid interface formed by preferential adsorption of amphiphilic star block copolymers. J. Alonzo, H. Ji, J. W. Mays, M. D. Dadmun, S. M. Kilbey
General Papers Polymer Synthesis and Characterization D. Garcia,
11:10 562. Synthesis of ferroelectric poly mers with tunable dielectric constants. Y. Lu, J. Claude, Q. Wang 11:30 563. New methods for graft copolymer synthesis: Mixed graft copolymers via iterative Cp2TiCI-catalyzed radical ring opening of poly(glycidyl methacrylate) epoxides. A. D. Asandei, G. Saha 11:50 564. Manipulation of core crosslinked star polymer architecture via degradation and chain extension. J. T. Wiltshire, G. G. Qiao 12:10 565. Synthesis and polymerization of sulfolane-3- propenyl ether. A. P. Purdy, J. Pinney Section Β McCormick Place South Room S502B, Level 5 Polymer Performance, Degradation, and Materials Selection Thermal Degradation and Characterization M. Celina, J. S. Wiggins, and N. C. Billingham, Organizers 8:30 566. Polymer thermal stability: Effects of layered metal hydroxide additives. J. M. Hosssenlopp, E. Kandare 9:00 567. Investigating the aging behavior of polysiloxane nanocomposites with degradative thermal analysis and broadband dielectric spectroscopy. J. P. Lewicki, D. Hayward, J. J. Liggat, R. A. Pethrick 9:20 568. Poly(arylate-co-phosphonate)s: Synthesis and characterization. T. Ranganathan, T. Emrick 9:40 569. New cyanate ester and poly-pphenylene resins with low moisture absorption and improved thermal stability. A. J. Guenthner, M. E. Wright, G. R. Yandek, B. J. Petteys, D. Connor 10:00 Intermission. 10:20 570. The practical use of chemiluminescence in thermal oxidation of polymers based on the most probable mechanism of light emission. J. Rychly, L. Matisova-Rychla 10:50 571. Probing degradation in complex engineering silicones by 1H multiple quan tum NMR. R. Maxwell, S. Chinn, J. L. Herberg, J. Giuliani 11:10 572. Spectroscopic investigation of degradation in RTV siloxane foams. A. Labouriau, T. Stephens, D. Taylor, D. Bowen 11:30 573. NMR investigation of filler effects of gamma irradiated polyurethane adhe sives. S. Chinn, E. L. Gjersing, R. Maxwell, R. Cohenour
Organizer Section C
L. J . Rozanski,
Presiding
8:30 554. Influence of hydrogen bonding on the photoreactivity of cinnamate functionalized flexible acrylic copolymers. M. P. Cashion, B. R. Mohns, T. E. Long 8:50 555. Kinetics and properties of flame resistant styrenic copolymers. A. C. Rosario, C. G. Handford, T. A. Kemp, M. J. Sumner, J. S. Riffle 9:10 556. Effect of branch density on polyoxymethylene copolymers. A. D. Kg, C. J. Price, S. A. Miller 9:30 557. Excimer emission in Di-alkyl poly(p-phenylene ethynylene) LEDs. L. J. Rozanski, D. A. Vanden Bout, U. H. F. Bunz 9:50 558. Kinetic modeling of surface-initi ated photoiniferter-mediated photopolymerization in presence of tetraethylthiuram disulfide. S. B. Rahane, A. T. Metters, S. M. Kilbey 10:10 559. Study of room-temperaturecrosslinking fluorinated acrylate copolymer latex. Y. Chen, L Du 10:30 560. pH-Responsive fluorene-pyridine copolymers: A fundamental study on the effects of protonation. S. Kappaun, K. Waich, S. Horner, L. Romaner, A-M. Kelterer, T. Mayr, E. Zojer, C. Slugovc 10:50 561. Thermoresponsive poly(/V-isopropylacrylamide-co-/V,/V'-cystaminebisacrylamide) thin films on gold. E. J. Park, D. D. Draper, N. T. Flynn
McCormick Place South Room S502C, Level 5 Emerging Frontiers in Polyolefins Catalyst Development/Polymerization P. Arjunan and Ε. Β. Coughiin, S. A. Miller,
Organizers
Presiding
9:00 574. Well-defined poly(propylene-gstyrene) graft copolymers by combining quasiliving ATRP and metallocene cataly sis: A semi-combinatorial approach. T. Fonagy, U. Schulze, H. Komber, D. Voigt, J. Pionteck, B. Ivan 9:35 575. Polymerization of alpha-olefins by new diamine-diphenolate Group 4 com plexes. M. Kol, S. Segal, A. Yeori, S. Gendler, E. Sergeeva, D. Reshef, I. Goldberg
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-419
TECHNICAL PROGRAM
POLY/PMSE 10:10 576. Long chain branched isotactic polypropylene via metallocene catalyst and T-reagent. J. Langston, J-Y. Dong, T. C. M. Chung 10:45 577. High performance metallocene catalysts. A. Razavi 11:20 578. Progress on the polar monomer problem. R. F. Jordan
THURSDAY AFTERNOON
Emerging Frontiers in Polyolefins Characterization/Composites
Section D
Section A
P. Arjunan,
McCormick Place South RoomS501A, Level 5
McCormick Place South Room S503A, Level 5
Ε. Β. Coughlin, Organizer,
30 Years of Conducting Polymers Devices/Photovoltaics
General Papers
11:05 595. Eliminating reductions in the glass transition temperature at the free surface of polystyrene films: Studies with bilayer films of different polymers. C. B. Roth, W. F. Jager, J. M. Torkelson
Polymer Synthesis and Characterization S. A. Jenekhe, C. Y. C. Lee, and A. B. Holmes, Organizers
D. Garcia,
J. P. Armistead, Organizer,
J. V. Crivello,
Presiding
8:30 579. Fullerene derivatives and conju gated polymers. J. C. Hummelen 9:00 580. Structure - property relation and design of optimized materials for bulkheterojunction solar cells: Toward 10 % energy conversion efficiency. C. J. Brabec 9:30 581. Rod-Coil graft copolymers from poly(3-hexylthiophene) precursors. X. Chen, X. Han, G. Vamvounis, S. Holdcroft 10:00 582. Development of conjugated polymers for use in all-polymer solar cells. B. C. Thompson, D. Kavulak, K. Sivula, T. Clem, T. Holcombe, P. B. Armstrong, M. A. Oar, J. M. J. Frechet 10:20 Intermission. 10:35 583. Exciton transport and inorganic/ organic photovoltaics. M. D. McGehee, S. R. Scully 11:05 584. New low-bandgap poly(2,7carbazole) derivatives in high performance solar cells. N. Blouin, A. Michaud, M. Leclerc 11:25 585. Photoelectric processes of organic vs. inorganic semiconductors. S-S. Sun 11:45 586. Photoluminescent studies of new conjugated fluorinated aryl ether polymers. S. T. lacono, S. M. Budy, J. Moody, D. W. Smith Jr. Section Ε McCormick Place South Room S501B/C/D, Level 5
J. P. Youngblood, R. C. Advincula, and Y-C. I. Chang, Organizers Presiding
A. J . Crosby, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 587. Dry/wet nanoadhesive inspired by mussel and gecko adhesion. H. Lee, P. B. Messersmith 8:55 588. Lateral distribution of surfactants in waterborne pressure sensitive adhesive films: Theory and experiment. C-H. Lei, K. Ouzineb, O. Dupont, A. Routh, V. Gundabala, S. Hinder, J. Keddie 9:15 589. Friction reduction using self-as sembled hydrogels. M. J. Mackel, J. A. Komfield 9:35 590. Surface ATRP of hydrophilic monomers from ultrafine aqueous silica sols using anionic polyelectrolytic macroinitiators. C-D. Vo, A. Schmid, S. P. Armes 9:55 Intermission. 591. Withdrawn. 10:05 592. How polymers diffuse in molecularly-thin films. J. S. S. Wong, L. Hong, S. C. Bae, S. Granick 10:25 593. Confinement, composition, and spin-coating effects on the glass transition temperature and stress relaxation of thin films of polystyrene and styrene-containing random copolymers. M. K. Mundra, C. J. Ellison, R. E. Behling, J. M. Torkelson 10:45 594. Confinement and interfacial effects on the dynamics and glass transi tion of thin polymer films: Novel fluores cence and dielectric spectroscopy studies. R. D. Priestley, L. J. Broadbelt, K. Fukao, J. M. Torkelson
120-TECH
Presiding
1:30 596. Withdrawn. 1:50 597. Micellization studies of functional block copolymers derived by ROMP. K. Stubenrauch, C. Moitzi, G. Fritz, O. Glatter, F. Stelzer, G. Trimmel 2:10 598. Release behavior of a barnacle reattached to silicone coatings. J . Kim, R. Hoshaw, S. J. Stafslien, J. Daniels 2:30 599. Effect of solvent quality on the properties of multi-responsive metallosupramolecular gels. W. Weng, A. M. Jamieson, S. Rowan 2:50 600. Amorphous unsaturated aliphatic polyesters derived from dicarboxylic mono mers synthesized by Diels-Alder chemis try. A. H. Brown, V. V. Sheares 3:10 601. Annulated ditopic N-heterocyclic carbenes as modular components in main-chain organometallic polymers. C. W. Bielawski 3:30 602. Synthesis and characterization of vinyl-triazole based monomers and poly mers. H. B. Nulwala, K. Takizawa, R. Thibault, B. Taft, B. H. Lipshutz, C. Hawker 3:50 603. Controlled synthesis of bimodal polyethylene using supported dual cata lysts. N. Kukalyekar, S. Rastogi, J. C. Chadwick 4:10 604. Organotitanium-catalyzed synthe sis of polystyrene in the presence of organosilanes. S. B. Amin, T. J. Marks Section Β
Polymer Surfaces and Interfaces General Topics Cosponsored with PMSE
J. S. S. W o n g ,
Organizer
McCormick Place South Room S502B, Level 5 Polymer Performance, Degradation, and Materials Selection New Materials M. Celina, J . S. Wiggins, and N. C. Billingham, Organizers 1:30 605. Aging of foamed polysiloxanes incorporating nanoparticles. J. J. Murphy, M. Patel, P. R. Morrell, J. E. Meegan, T. C. Swain 2:00 606. Novel biomimetic protein-based hydrogel with superior elasticity. N. K. Dutta, N. D. Tran, Μ. Υ. Truong, N. Roy Choudhury, A. J. Hill, C. Elvin 2:20 607. Degradable thermoplastic polyurethanes based on 4,4'-dicyclohexylmethane diisocyanate. S. J. Moravek, T. R. Cooper, M. K. Hassan, J. S. Wiggins, K. A. Mauritz, R. F. Storey 2:40 608. Thermally reversible crosslinked polymers: Polyurethanes for coating appli cations. S. M. Budy, D. W. Smith Jr. 3:00 Intermission. 3:30 609. Degradation of novolak containing metal nitrates and formation of yttriumbarium-copper oxide. M. S. Silverstein, Y. Lumelsky 3:50 610. Polymerization of soybean oil in supercritical carbon dioxide. Z. Liu, B. K. Sharma, S. Erhan 4:10 611. Degradation of crosslinked unsat urated polyesters by using subcritical water. K. Suyama, M. Kubota, M. Shirai, H. Yoshida 4:30 612. Synthesis of poly(D.L-Lactide) functionalized with pendant carboxylic acid groups. T. R. Cooper, M. K. Hassan, K. A. Mauritz, R. F. Storey
Section C
PMSE
McCormick Place South Room S502A, Level 5
Organizer
Division of Polymeric Materials: Science & Engineering D. Webster, Program Chair
Presiding
1:30 613. Rheologically detected interplay between phase separation and crystalliza tion for polyolefin blends: How strong effects spinodal decomposition can bring on the simultaneously occurring crystalliza tion. J. Qiu, Z. Wang 2:05 614. Real-time observation and charac terization of phase transitions in polyolefins by atomic force microscopy. F. Mirabella 2:40 615. Reorganization and crystallization of quenched mesomorphic isotactic poly propylene during thermal annealing. J. Zhao, Z. Wang, B. S. Hsiao 3:15 616. Crystallization of isotactic poly(propylenes) with enhanced melt strength. R. G. Alamo, A. Ghosal 3:50 617. Synthesis of functionalized polyolefin/montmorillonite nanocomposites. J-Y. Dong, Y. Hu Section D McCormick Place South RoomS501A, Level 5 30 Years of Conducting Polymers LEDs and Synthesis C. Y. C. Lee and A. B. Holmes, Organizers J. P. Armistead and S. A. Jenekhe, Organizers, Presiding 1:30 618. Seeing the light with polymers. A. B. Holmes 2:00 619. Morphological dependence of conjugated polymer photophysics. L J . Rothberg, C. J. Collison, C. Cuppoletti, J. Wesely 2:30 620. Electronic, optoelectronic, and light-emitting properties of fluorene-quinoxaline and -pyrazinoquinoxaline conju gated alternating and random copolymers. K-F. Cheng, W-Y. Lee, W. C. Wu, M. H. Lai, C-F. Wang, W-C. Chen 2:50 621. Molecular design on soluble conju gated polymers for electronic and electro chemical applications. S-A. Chen 3:20 Intermission. 3:35 622. New ττ-conjugated organoboron polymers. Y. Chujo, Y. Nagata 4:05 623. Color changing electrochromic fibers. G. A. Sotzing, M. Acik, C. I. Asemota, J. G. Bokria, J. Choi, M. Invernale, A. Kumar, K-R. Lee, Y. Ner, M. Rousselle, A. Tran, M. S. Yavuz 4:35 624. Dithieno[3,2-b:2',3'-d]pyrrole-based materials: Oligomers and polymers with enhanced fluorescence. K. Ogawa, H. Mo, K. R. Radke, S. C. Rasmussen 4:55 625. Naphthalenetetracarboxylic diimide-grafted poly(3,4-ethylenedioxythiophene)s. N. C. Tansil, H-H. Yu, E. A. B. Kantchev, J. Y. Ying
SOCIAL EVENTS: Breakfast: Sun, Mon, Tue, Wed, Thu PMSE/POLY Break Room: Sun, Mon, Tue, Wed, Thu POLY/PMSE Awards Reception: Mon Poster Session and Social Hour: Tue Program Committee Lunch: Tue BUSINESS M E E T I N G S : Business Meeting and Chair's Remarks: The PMSE Strategic Plan: Mon Executive Committee Meeting: Sun SUNDAY MORNING Section A McCormick Place South Room S504B/C, Level 5 Polymer-Directed Mineralization Lessons from Nature - Biomineralization Mechanisms and Structure S. Yang, F. Meldrum, and H. Côlfen, Organizers N. Kroger, Organizer,
Presiding
8:25 Introductory Remarks. 8:30 1. Silicatein proteins reveal unique mechanisms of hierarchical self-assembly and catalytic nanofabrication, leading to a new, generic, low-temperature method for catalytic nanofabrication. D. E. Morse, M. M. Murr, B. Schwenzer, J. R. Gomm, R. L. Brutchey 9:00 2. Making magnets by microbes: Biochemical and genetic control of magnetosome biomineralization in magnetotactic bacteria. D. Schuler 9:30 3. Biogenic nanostructured silica formation in diatoms: Proteins, genes, and structure. M. Hildebrand 10:00 Intermission. 10:20 4. In vivo immobilization of functional proteins in diatom silica. N. Poulsen, C. Berne, J. Spain, N. Kroger 10:40 5. Microstructural deformation and plasticity of bone. H. S. Gupta, P. Fratzl, W. Wagermaier, J. Seto, M. Kerschnitzki, G. Benecke, P. Zaslansky, P. Boesecke, H. O. K. Kirchner 11:10 6. Structure and dynamics of poly(Llysine) in silica nanocomposites. P. A. Mirau, J. A. Garber, M. Lyons 11:30 7. Bone-like nanocomposites: Implications for bone formation in vivo. M. J. Olszta, X. Cheng, S. S. Jee, R. Kumar, Y-Y. Kim, M. J. Kaufman, E. P. Douglas, L. B. Gower Section Β McCormick Place South Room S504D, Level 5 Materials for Probing and Manipulating Living Cells Model Cell-Interactive Surfaces D. J . Irvine, Organizer,
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Presiding
8:30 Introductory Remarks. 8:35 8. Defined materials to reveal spatial regulation of cellular signaling. B. A. Baird, D. A. Holowka 9:05 9. Model surfaces to study cell adhe sion and function. C. S. Chen 9:35 10. Cellular microarrays by chemically amplified constructive microlithography. L. Andruzzi, G. Schwake, J. O. Radier, Κ. Ε. Sohn, Τ. Ε. Mates, Ε. J. Kramer
9:55 11. Controlled synthesis and use of peptide-polymer hybrid molecules to promote the adhesion and spreading of living cells on artificial surfaces. M. A. Biesalski, S. Duman, K. Shroff, J. Ruhe 10:15 Intermission. 10:35 12. Checking on neurons with microfluidics and surface science methods. N. L. Jeon 11:05 13. Hydrophobicity contrast surfaces for directing cell adhesion and motility. M. D. Moussallem, J. B. Schlenoff, S. G. Olenych, T. C. S. Keller 11:25 14. Surface-attached polymer networks: Versatile surface architectures for controlling the interaction of surfaces with cell membrane models and cells. 0 . Prucker, A. Wôrz, G. Baaken, M. Sundermann, J. Behrends, U. Egert, J. Ruehe 11:45 15. Quantifying cell receptor-adhesion ligand bonds in 3-D culture with FRET. H. J. Kong, T. Boonthekul, D. J. Mooney Section C McCormick Place South Room S505A, Level 5 Nanostructures from Block Copolymers and Supramolecular Polymers Inorganic Hybrids Cosponsored with POLY C. Y. Ryu, D. A. Savin, and B. Gong, Organizers T. S. Bailey, Organizer,
Presiding
8:30 16. Novel nanostructures based upon polyferrocenylsilane block copolymer self-assembly. M. A. Winnik, G. Guerin, H. Wang, X-S. Wang, I. Manners 9:05 17. Recognition-mediated assembly of nanoscale systems. V. M. Rotello 9:40 Intermission . 9:50 18. Block copolymer templated surfactant-modified magnetic nanoparticles. T-l. Yang, L. C. Kempel, P. Kofinas 10:10 19. Hybrid nanomaterials from hierarchical self-assembly of nanoparticles and clusters on diblock copolymer films. S. B. Darling, A. Hoffmann, N. A. Yufa, S. D. Bader, S. J. Sibener 10:30 20. Morphology and thermal properties of polycarbosilane-gf-PMMA copolymers. J. Hyun, C. Y. Ryu, L. V. Interrante 10:50 Intermission . 11:00 2 1 . Preparation of highly ordered silica and vanadium oxide nanoparticles on surfaces using diblock copolymer micelles as templates. A. Frômsdorf, S. V. Roth, H. Stillrich, S. Putter 11:20 22. Synthesis and assembly properties of amphiphilic organoboron block copolymers. F. Jâkle, C. Cui, Y. Qin, J. S. Banipal 11:40 23. Synthesis and study of hybrid organic-inorganic POSS-PS-POSS triblock copolymers. G. A. Gadodia, L. Yang, G. Cardoen, T. P. Russell, E. B. Coughlin Section D McCormick Place South Room S505B, Level 5 General Papers and New Concepts in Polymeric Materials Nanocomposites D. Webster,
Organizer
Q. Huo and J. P. Oberhauser,
Presiding
8:00 24. Dynamic mechanical properties of poly(methyl methacrylate)-silica nanoparticle composites. A. Kraft, P. M. E. Adams, V. Arrighi, J. Harkins, A. McAnaw, 1. J. McEwen, S. J. Mayhew, L. Ragupathy, C. Waring 8:20 25. Kinetic models for CNT modified epoxy composites: An application related status review. G. K. R. Raja Manuri Venkata, V. Avadhanam 8:40 26. Hybrid nanocomposite membranes for PEMFC applications. F. Niepceron, H. Galiano, A. Balland-Longeau, P. Mazabraud, J. F. Tassin
9:00 27. Thermal behavior of trisilanolphenylPOSS filled poly(t-butyl acrylate) ultrathin films. U. Karabiyik, R. Paul, M. C. Swift, A. R. Esker 9:20 28. Melt extrusion process for exfoliation of polyamide 6/clay nanocomposites: Study of oxygen permeability. S. K. Swain, A. I. Isayev 9:40 29. Direct laser writing of microstructures on nanocomposite materials. H. Chen, X. Liu, H. Muthuraman, J. Zou, J. Wang, Q. Dai, Q. Huo 10:00 Intermission. 10:10 30. Synthetic smectic clay for the reinforcement of epoxy polymers. S. Xue, T. J. Pinnavaia 10:30 3 1 . Poly(e-caprolactone) initiation with acid functional imidazolium modified montmorillonite and its use to make nanocomposites. X. Xun, J. Wang, S. K. Goswami, L. J. Mathias 10:50 32. Polymer/clay aerogel composites. D. A. Schiraldi, M. D. Gawryla, S. A. Bandi, A. E. Reinardy, E. Arndt, K. Finlay, K. Lamison 11:10 33. Quiescent and flow-induced crystallization of polypropylene-clay nanocomposites. M. A. Treece, J. P. Oberhauser 11:30 34. Rheology and mesoscale structure of polystyrene-clay nanocomposite solutions: Depletion flocculation vs. polymer bridging. J . Li, J. M. Fitz-Gerald, J. P. Oberhauser 11:50 35. Preferred orientation of organoclay in nanocomposites by 3-D-TEM and directional SAXS study. P. Nawani, C. Burger, M. Gelfer, B. Chu, B. S. Hsiao, A. H. Tsou, W. Weng Polymer Surfaces and Interfaces Polymer Brushes Sponsored by POLY, Cosponsored with PMSE SUNDAY AFTERNOON Section A McCormick Place South Room S504B/C, Level 5 Polymer-Directed Mineralization Mineralization Directed by Biopolymers S. Yang, F. Meldrum, and H. Côlfen, Organizers M. Hildebrand,
Presiding
N. Kroger, Organizer,
Presiding
1:30 36. Biomineralization and catalysis of mesostructured silica templated by condensable peptidic "lizard" amphiphiles with a cleavable alkyl tail. K. Kinbara, W. Otani, T. Aida 2:00 37. Biological routes to inorganic material synthesis. W. J. Crookes-Goodson, J. M. Slocik, M. M. Tomczak, R. R. Naik, L. F. Drummy 2:30 38. Using the interfaces in self-assembled protein cage architectures for materials synthesis. T. Douglas, M. J. Young 3:00 39. Bio-enabled synthesis of amorphous and crystalline titania at ambient temperature and neutral pH. N. Kroger, M. B. Dickerson, G. Ahmad, K. H. Sandhage, N. C. Poulsen 3:20 Intermission. 3:40 40. Rapid peptide-induced formation of phase pure, crystalline C a M o 0 4 phosphor microparticles from aqueous precursor solutions. G. Ahmad, M. B. Dickerson, B. Church, Y. Cai, E. Ernst, S. E. Jones, R. R. Naik, J. S. King, C. J. Summers, N. Kroger, K. H. Sandhage 4:10 4 1 . Self-assembly and mineralization of artificial spicules of marine sponges. M. N. Tahir, S. Wolf, W. E. G. Muller, H-C. Schroder, N. Loges, W. Tremel 4:40 42. Withdrawn.
Please refrain from using cellular telephones and cameras during technical sessions.
Section Β McCormick Place South Room S504D, Level 5 Materials for Probing and Manipulating Living Cells Particle-Cell Interactions and Intracellular Delivery D. J. Irvine, Organizer,
Presiding
1:30 Introductory Remarks. 1:50 43. Shape-induced inhibition of phago cytosis by macrophages. J. Champion, Y. Katare, S. Mitragotri 2:20 44. PCADK: A new polyketal for drug delivery. N. Murthy, M. Heffernan, S. Yang, S. Lee, S. Khaja, S. Wilson 2:50 45. Intracellular drug delivery via pHsensitive hydrogel nanoparticles. Y. Hu, T. Litwin, P. S. Doyle, D. J . Irvine 3:10 46. Glycoconjugates enhanced phago cytosis of B. cereus spores using Dictyostelium discoideum as a model. O. Tarasenko, E. Burton, S. Desikan, J. Bush, P. Alusta Section C McCormick Place South Room S505A, Level 5 Nanostructures from Block Copolymers and Supramolecular Polymers Architecture-Driven Nanostructures Cosponsored with POLY C. Y. Ryu, T. S. Bailey, and B. Gong, Organizers D. A. Savin, Organizer,
Presiding
1:30 47. Multicompartment micelles in mixed systems. A. Triftaridou, C. Liu, Z. Li, M. Hillmyer, T. P. Lodge 2:05 48. Supramolecular assemblies from amphiphilic homopolymers. S. Thayumanavan 2:40 Intermission . 2:50 49. Janus discs: Preparation, sizetunability, visualization, self-assembly. A. Walther, X. André, M. Drechsler, V. Abetz, Α. Η. Ε. Muller 3:10 50. Poly(imide siloxane) block copoly mers and their morphologies from dilute solutions. C-K. Ku, Y-D. Lee 3:30 5 1 . High hard block content polyurethanes: Morphology and phase behav ior. A. Saiani, J. S. Higgins 3:50 Intermission . 52. Withdrawn. 4:00 53. Multicompartment micelles from ABC triblock terpolymers. F. Schacher, A. Walther, M. Ruppel, Α. Η. Ε. Muller 4:20 54. Role of the architecture of block copolymers on their interfacial behavior. S. Peleshanko, R. Gunawidjaja, V. V. Tsukruk Section D McCormick Place South Room S505B, Level 5 General Papers and New Concepts in Polymeric Materials Characterization D. Webster,
Organizer
J. E. Marszalek and D. L. Frattarelli, Presiding 1:00 55. Langevin dynamics simulation of amphiphilic linear-dendritic block copoly mer self-assembly. N. W. Suek, M. H. Lamm 1:20 56. First cumulant of the dynamic structure factor for flexible polymers: Excluded-volume effects. M. Osa, N. Sawatari, T. Yoshizaki, H. Yamakawa 1:40 57. Coarse-grained simulation of atactic polystyrene on a bond fluctuation lattice from rotational isomeric state theory. N. Waheed, Y. B. Tatek, W. L Mattice 2:00 58. Characterizing electrospun fibers of poly(ether) imide solutions by relation to their dielectric properties. K. C. Mills, E. Franzek, J. P. Hinestroza
2:20 59. Dielectric spectroscopy of vinylidene fluoride copolymers and terpolymers with different compositions. L. E. Norena, K. Xu, J. Claude, Y. Lu, Q. Wang 2:40 60. Small-angle neutron scattering investigation of a structural change in the light induced polymerization of the dodecyl acrylate microemulsion. J. E. Marszalek, J. A. Pojman, C. E. Hoyle, K. Page 3:00 Intermission. 3:10 6 1 . Molecular and thin-film NLO response amplification via introduction of a strong Bronsted acid. D. L. Frattarelli, M. Schiavo, T. J. Marks, A. Facchetti, M. A. Ratner 3:30 62. Investigating the two-photon absorption behavior and coupling of excited states in cyclic thiophenes using ultrafast spectroscopy. A. Bhaskar, G. Ramakrishna, T. Goodson III 3:50 63. Detection of trivalent and hexavalent chromium using structurally colored biopolymer thin films. M. D. Cathell, C. L. Schauer 4:10 64. Autooxidation study of model fatty acid functionalized methacrylic copoly mers. M. S. Black, J. H. Whittemore IV, J. W. Rawlins 4:30 65. Mechanical degradation of linear polymers and polymer nanogels in extensional flow. M. Sun, W. Ng, A. E. Barron 4:50 66. Effect on morphological transitions in block copolymers and their effect on mechanical behavior. M. Mamodia, A. J. Lesser Polymer Surfaces and Interfaces Responsive Surfaces, Interfaces, and Films Sponsored by POLY, Cosponsored with PMSE MONDAY MORNING Section A McCormick Place South Room S504B/C, Level 5 Polymer-Directed Mineralization Mineralization Directed by Synthetic Polymers S. Yang, N. Kroger, and F. Meldrum, Organizers H. Côlfen, Organizer,
Presiding
8:30 67. Self-organized crystal growth of hierarchically structured inorganic crystals in cooperation with polymeric species. H. Imai, Y. Oaki, A. Kotachi 9:00 68. Polymer controlled crystallization of inorganic minerals: The roles of a mixed solvent and air/solution interface. S-H. Yu 9:30 69. Self-organized surfactants as templates for the mineralization of C a C 0 3 . D. C. Popescu, M. M. Smulders, B. P. Pichon, P. H. H. Bomans, N. Chebotareva, R. P. Sijbesma, P. M. Frederik, N. A. J. M. Sommerdijk 10:00 Intermission. 10:20 70. Precursor structures during crystallization of C a C 0 3 and control by polyelectrolytes. J. Rieger 10:50 7 1 . Polymer-directed synthesis of inorganic materials with controlled morphologies and architectures. L. Qi 11:20 72. Patterned mineral films using the polymer-induced liquid precursor process. Y-Y. Kim, E. P. Douglas, L. B. Gower Section Β McCormick Place South Room S504D, Level 5 Cooperative Research Award: Symposium in Honor of Alec Scranton, Christopher Bowman, Joe Oxman, Michael Idacavage, John Woods and Donald Herr D. A. Schiraldi, Organizer,
Presiding
8:30 Introductory Remarks. 8:35 73. Cyanoacrylate-based photoreactive polymers and their applications. J. G. Woods
TECHNICAL PROGRAM
PMSE 9:05 74. Evaluation of initiator systems for controlled and sequentially curable freeradical/cationic hybrid photopolymerizations. J. D. Oxman, A. B. Scranton, D. W. Jacobs, M. C. Trom, V. Sipani, B. Reek 9:35 75. Ester-free thiol-ene photopolymer systems. D. Herr 10:05 Intermission. 10:20 76. Photopolymerization of thiol-enes: Click to the future. C. E. Hoyle 10:50 77. Development of photopolymerized clay-polymer nanocomposites utilizing polymerizable surfactants. C. A. Guymon 11:20 78. Photopolymerization of thick systems and elimination of oxygen inhibition. A. B. Scranton, N. S. Kenning, L. Gou 11:50 79. Thiol-ene photopolymerization reactions: Fundamentals, development, and applications. C. N. Bowman, N. B. Cramer, T. Y. Lee, J. A. Carioscia Section C McCormick Place South Room S505A, Level 5
Section Ε McCormick Place South Room S503A/B, Level 5 ACS Award in Applied Polymer Science: Symposium in Honor of Harry Allcock Cosponsored with POLY K. J. Wynne and P. Wisian-Neilson, Organizers, Presiding
Nanostructures from Block Copolymers and Supramolecular Polymers Active Nanostructures Cosponsored with POLY C. Y. Ryu, D. A. Savin, and T. S. Bailey, Organizers B. Gong, Organizer,
11:00 92. Design and assembly of functional materials for controlled, non-viral gene delivery. J. M. Saul, l-K. Park, M. Linnes, B. D. Ratner, D. Qin, S. Jiang, C. Giachelli, S. H. Pun 11:30 93. In-situ ATR-FTIR and AFM studies on poly(etyhleneimine )/poly(acrylic acid) multilayers: Dependence on medium parameters and protein selectivity. M. Muller, K. Bohata, B. Ke3ler, W. Ouyang, Z. Pientka, E. Brynda 11:50 94. Functionalization of poly[oligo(ethylene glycol)methacrylate] brushes on titanium. J. E. Raynor, T. A. Pétrie, A. J. Garcia, D. M. Collard
Presiding
8:30 80. Supramolecular polymers formed by intermolecular interaction of hydrogen bonding. T. Park, S. C. Zimmerman, H. C. Ong, E. M. Todd, D. W. Kuykendall, K. Quansah 9:05 8 1 . Reversible nanostructures from rod amphiphiles. M. Lee 9:40 Intermission . 9:50 82. Smart self-assemblies from block copolymers obtained via RAFT polymerization. S. Perrier 10:10 83. Temperature and pH responsive block copolymer assemblies from polypeptides. S. S. Naik, K. E. Gebhardt, G. Venkatachalam, D. A. Savin 10:30 84. Nanofibers with tunable stiffness from self-assembly of an amphiphilic wedge-coil molecule. J-K. Kim, E. Lee, M. Lee 10:50 Intermission . 11:00 85. Photoresponsive lamellar structures utilizing azobenzene-modified surfactants. D. Abdallah, Y. Li, D. A. Shipp 11:20 86. Synthesis and study of triblock copolymer assemblies containing a thermoresponsive N-isopropyl acrylamide block. A. Sundararaman, T. Stephan, R. B. Grubbs 11:40 87. Morphological transformation and photophysical properties of fluorene based rod-coil copolymers in solution. Y-C. Tung, W. C. Wu, W-C. Chen
8:30 Introductory Remarks. 8:35 95. Development of polyphosphazenes for surface and biomedical applications. A. Singh, L Steely, N. Krogman, H. R. Allcock 9:05 96. Materials for power. D. T. Welna 9:35 97. Polyphosphazene poly(lactide-coglycolide) blends: The development of a novel biomedical material. C. T. Laurencin, L. S. Nair, M. Deng 10:05 Intermission. 10:20 98. Polymerization of cyclophosphazenes with methacrylate containing substituents. C. W. Allen 10:50 99. Fluoropolymer surface science including unusual surface morphology (TM-AFM) and wetting behavior of bis(trifluoroethoxy)phosphazene. A. Mullins, Y. Zheng, L. Steely, H. R. Allcock, K. J. Wynne 11:20 100. ATRP: A versatile methodology to prepare polymers for various applica tions. K. Matyjaszewski ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu Next Generation Product R&D: Science and Engineering Sponsored by BMGT, Cosponsored with PMSE, and WCC Polymer Surfaces and Interfaces Multilayers, Thin Films and Surface Characterization Sponsored by POLY, Cosponsored with PMSE Undergraduate Research Poster Session: Polymer Chemistry Sponsored by CHED, Cosponsored with SOCED, POLY, and PMSE MONDAY AFTERNOON Section A McCormick Place South Room S504B/C, Level 5
Section D McCormick Place South Room S505B, Level 5
Polymer-Directed Mineralization Mineralization at Surface/Polymer Interface
Designed Macromolecular Assemblies for Biomedical Applications Surfaces
S. Yang, N. Kroger, and H. Côlfen, Organizers
T. M. Reineke,
F. Meldrum, Organizer,
Organizer
J. H. Collier and W. L. Murphy, Organizers, Presiding 8:25 Introductory Remarks. 8:30 88. Mussel-inspired polymers for surface modification: Preventing and encouraging bioadhesion. P. B. Messersmith 9:00 89. Multilayered polyelectrolyte assemblies as platforms for surface-mediated delivery of DNA. D. M. Lynn 9:30 90. Tailored substrates for cell biology. M. Mrksich 10:00 Intermission. 10:30 9 1 . Polymers for patterning proteins in specific orientations at the micro- and nanoscale. H. D. Maynard
122-TECH
Presiding
1:30 101. Programming nanostructures for mineralization. S. I. Stupp 2:00 102. Structural and biomolecular controls on templated nucleation and growth of calcite. J. J. De Yoreo, J. R. I. Lee, S. Elhadj, D. Wang, Y-J. Han, T. M. Willey, R. W. Meulenberg, L. J. Terminello, T. van Buuren, P. M. Dove 2:30 103. Morphogenesis evolution of calcite crystals on self-assembled monolayers in the presence of polymer additives. T. Wang, J. Aizenberg, H. G. Borner, S. Yang
2:50 104. Studying the nucleation and growth of calcium carbonate. R. S. K. Lam, F. Meldrum, F. Pacha 3:10 Intermission. 3:30 105. Conformai mineralization on nanostructured 3-D bioclastic templates using dendritic hydroxyl amplification for enhanced surface sol-gel processing. M. R. Weatherspoon, M. B. Dickerson, G. Wang, Y. Cai, S. C. Jones, K. H. Sandhage, S. R. Marder 4:00 106. Importance of the hydrophobic core of nanostructures prepared from amphiphilic block copolymers to the morphology of calcium carbonate crystals. S. Venkataraman, K. Qi, B. Wopenka, J. D. Pasteris, K. L. Wooley 4:20 107. Polymer brushes as ionotropic matrices for the directed fabrication of microstructured calcite thin films. Η-A. Klok, S. Tugulu, M. Harms, M. Fricke, D. Volkmer 4:40 108. Directed nucleation and growth of cadmium sulfide on photo-oxidized poly ethylene terephthalate) and their device applications. F. F. Amos, S. A. Morin, S.Jin 5:00 Business Meeting and Chair's Remarks: The PMSE Strategic Plan. Section Β McCormick Place South Room S504D, Level 5 Conjugated Oligomers and Polymers Synthetic Methods and New Materials for Thin-Film Electronics B. de Boer and A. Facchetti, Presiding
Organizers,
1:30 109. New organic semiconductors for sensors, diodes, magnetics, and floating gate devices. H. E. Katz 2:00 110. New organic materials for high performance transistors. Z. Bao 2:30 111. Thieno[3,2-t]thiophene semicon ducting copolymers for organic field effect transistor (OFET) applications. S. Tierney, C. Bailey, W. Duffy, M. Heeney, I. MacDonald, M. Shkunov, D. Sparrowe, W. Zhang, I. McCulloch 2:50 112. Synthesis and characterization of alternating thiophene-perfluoroarene copolymers and fully/partially fluorinated small-molecule polycyclics. Y. Wang, M. D. Watson 3:10 Intermission. 3:30 113. New polymers for organic electron ics. F. Wudl, S. Patil, J. Yang, F. Marchioni, R. Chiechi 4:00 114. Oligo- and polythiophenes contain ing organoborane moieties. F. Jàkle, A. Sundararaman, H. Li, K. Venkatasubbaiah 4:20 115. Symmetric and unsymmetric conjugated thiopheno azomethines synthesized selectively by a one-pot method. M. Bourgeaux, S. Dufresne, S. Perez Guarin, W. G. Skene 4:40 116. Synthesis of a new low energy gap, processable, and functionable conjugated polymer poly(3-dodecyl-2,5-thienylenevinylene). T. Cleveland, C. Zhang, S-S. Sun 5:00 117. Polyarylsilanes and polyarylgermanes as precursors to conductive polymers: Processing and morphology control. G. A. Sotzing, C. I. Asemota, J. G. Bokria, J. Choi, A. Kumar, Y. Ner, M. Ombaba, V. Seshadri, A. Tran, M. S. Yavuz
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
Section C McCormick Place South Room S505A, Level 5 Nanostructures from Block Copolymers and Supramolecular Polymers Thin Films and Confinement Cosponsored with POLY D. A. Savin, T. S. Bailey, and B. Gong, Organizers C. Y. Ryu, Organizer,
Presiding
1:30 118. Directed assembly of block copolymers to pattern isolated features and essential integrated circuit geometries. M. P. Stoykovich, H. Kang, G. Liu, K. C. Daoulas, M. Muller, J. J. dePablo, P. F. Nealey 2:05 119. Semiconducting block copolymers: Optimized synthesis and processing for efficient photovoltaic devices. G. Hadziioannou 2:40 Intermission . 2:50 120. Self-aligned, self-assembled organosilicate line patterns from blockcopolymer mediated self-assembly. H-C. Kim, L. Sundstrom, C. Rettner, J. Y. Cheng, O-H. Park, W. Hinsberg, R. D. Miller, M. Hart 3:10 121. Hard-surface effect and mixed lamellae in symmetric diblock copolymer thin films. D. Meng, Q. Wang 3:30 122. Directed self-assembly of blockcopolymer-based hybrid nanostructures. J. Y. Cheng, R. Ruiz, C. T. Black, H-C. Kim 3:50 Intermission . 4:00 123. Effects of zone annealing on thin films of block copolymers. B. C. Berry, R. L Jones, A. Karim 4:20 124. Nanocavities via amphiphilic block copolymer thin films. A. C. Miller, R. D. Bennett, P. T. Hammond, R. E. Cohen, D. J. Irvine 4:40 125. Symmetric diblock copolymers in nanopores: Monte Carlo simulations and strong-stretching theory. Q. Wang Section D McCormick Place South Room S505B, Level 5 Designed Macromolecular Assemblies for Biomedical Applications Scaffolds T. M. Reineke,
Organizer
J. H. Collier and W. L. Murphy, Organizers, Presiding 1:40 126. Fully degradable functionalized polymers: A versatile approach using ring-opening polymerization of cyclic carbonates. R. C. Pratt, F. Nederberg, B. G. G. Lohmeijer, R. M. Waymouth, J. L. Hedrick 2:00 127. Polyarginine segments in block copolypeptides drive both vesicular assembly and intracellular delivery. T. J. Deming, E. Holowka, V. Sun, D. Kamei 2:30 128. Non-covalent assembly of peptidegrowth factor complexes to spatially control cell activity. G. Hudalla, W. L. Murphy 3:00 129. Non-canonical amino acids in protein engineering and analysis. D. A. Tirrell 3:30 Intermission. 4:00 130. Environmentally sensitive gels assembled through protein-polysaccharide interactions. K. C. Butterfield, B. Seal, J. Chaput, A. Panitch 4:30 131. Self-assembling peptide nanofibers with orthogonal control over assembly conditions, extent of assembly and bioactive function. S. E. Paramonov, H. Dong, K. Galler, J. D. Hartgerink 5:00 132. Self-assembling β-hairpin peptide hydrogels: Effect of strand symmetry on the fibrillar nanostructure. R. P. Nagarkar, R. A. Hule, D. J. Pochan, J. P. Schneider
PMSE
Section E McCormick Place South Room S503A/B, Level 5 ACS Award in Applied Polymer Science: Symposium in Honor of Harry Allcock Cosponsored with POLY K. J. Wynne and P. Wisian-Neilson, Organizers, Presiding 1:30 133. Organic-inorganic polymer nanohybrids. Y. Chujo 2:00 134. Silylamino and silylanilino derivatives of phosphorus and boron. R. H. Neilson 2:30 135. Fluorescent organic nanotubes: Self-assembly and biosensory characteristics. C. Kim 3:00 Intermission. 3:15 136. Cyclic and polymeric (alkyl/arylphosphazenes). P. Wisian-Neilson 3:45 137. Functional and supramolecular metallopolymers. I. Manners 4:15 138. Award Address (ACS Award in Applied Polymer Science, sponsored by Eastman Chemical Company). Control of properties in hybrid inorganic-organic polymers: Polyphosphazenes as biomedical, energy-related and optical materials. H. R. Allcock 5:00 Concluding Remarks. ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu Next Generation Product R&D: Science and Engineering Sponsored by BMGT, Cosponsored with PMSE, and WCC Polymer Surfaces and Interfaces Biopolymer/Bioactive Surfaces Sponsored by POLY, Cosponsored with PMSE M O N D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Sci-Mix D. Webster, Organizer,
Presiding
8:00-10:00 207, 211, 213, 218, 224, 245, 249, 275, 280-281, 283, 289-290, 296, 301, 305306, 315, 319, 323-324, 327-328, 330, 332-333, 337, 345, 356-357, 359, 362, 364, 371, 375-376, 382-384, 386, 389390, 396-397, 399, 401, 403-404, 406. See subsequent listings. TUESDAY MORNING
10:40 142. Double direct templating of periodically nanostructured inorganic hollow microspheres. P. V. Braun, A. Wolosiuk, D. Son, D. V. Gough 11:10 143. Biomimetic assembly of zinc oxide microarrays on flexible polycarbonate film. S. A. Morin, F. F. Amos, S. Jin 11:30 144. Polymerization shrinkage stress development and mechanical strength of ACP acrylic resin composites. J. M. Antonucci, J. N. R. O'Donnell, D. Skrtic 11:50 Concluding Remarks.
11:00 158. Chemically and electrically tun able block copolymer photonic gels: Exceptionally large tunability via uniaxial swelling. Y. Kang, J. Walish, T. Gorishnyy, E. L. Thomas 11:20 159. Toward polyion complex aggre gates with segregating solvating chains. Z. Hordyjewicz-Baran, H. Schlaad 11:40 160. Supramolecularly modified PEG hydrogels. T. W. Baughman, E. W. Meijer Section D McCormick Place South Room S505B, Level 5
Section Β McCormick Place South Room S504D, Level 5
Designed Macromolecular Assemblies for Biomedical Applications Scaffolds
Conjugated Oligomers and Polymers Synthetic Methods and New Materials for Thin-Film Electronics
T. M. Reineke, Organizer,
B. de Boer and A. Facchetti, Presiding
Organizers,
8:30 145. Modular approach to conjugated oligomers and their application in molecu lar electronics. L. Yu, G. Lin, Y. Liang, S. Yuan, Y. Lee 9:00 146. Design aspects of functionalized organic semiconductors. J. E. Anthony 9:30 147. Smart sunglasses and goggles based on electrochromic polymers. C. Ma, M. Taya, C. Xu 9:50 148. Dielectric properties of [Rh(1,4diisocyanobenzene)+4/2 (Cl)"] n with respect to moisture. C. G. Carson, R. A. Gerhardt, R. Tannenbaum 10:10 Intermission. 10:30 149. Development of 3,6 dialkylthieno[3,2-b]thiophene semiconducting co-polymers for OFET applications. I. McCulloch, C. Bailey, W. Duffy, M. Heeney, M. Shkunov, D. Sparrowe, S. Tierney, W. Zhang 11:00 150. Mono-end functionalized conju gated polymers for donor-bridge-acceptor (DBA) block copolymers. C. Zhang, T. Cleveland, S-S. Sun 11:20 151. Conjugated fluoreno azomethines: Photophysical and electrochemical investigation. S. Perez Guarin, A. Sylla, S. Dufresne, D. Tsang, W. G. Skene 11:40 152. Surface and interface properties of poly (3, 4-ethylenedioxythiophene) via oxidative chemical vapor deposition (oCVD). S. G. Im, E. A. Olivetti, K. K. Gleason Section C McCormick Place South Room S505A, Level 5
J. H. Collier and W. L. Murphy,
Organizers
Presiding
8:25 Introductory Remarks. 8:30 161. Studying protein function and controlling cell adhesion with polymer brushes. Η-A. Klok, S. Tugulu, A. Arnold, I. Sielaff, K. Johnsson, P. Silacci, N. Stergiopulos 8:50 162. Smart biohybrid materials. P. S. Stayton, A. S. Hoffman 9:20 163. Peptide mimics of the extracellular matrix: Non-covalent and covalent strate gies. J. L. Jones, S. A. Cronier, J. H. Collier 9:50 164. Organic delivery vehicles for prob ing and treating biological systems: Adapt ing fabrication processes from the elec tronics industry for use in nanomedicine. J. M. DeSimone, S. E. A. Gratton, A. L. Galloway, A. J. Murphy, P. D. Pohlhaus 10:20 Intermission. 10:50 165. Polyvalent recognition of biopolymers: The design of potent inhibitors of anthrax toxin. P. Rai, M. Yanjarappa, K. Gujraty, A. Saraph, A. Joshi, V. Poon, C. Padala, S. Kate, J. Mogridge, R. S. Kane 11:20 166. Receptor-responsive, proteincrosslinked polymeric hydrogels. Ν. Yamaguchi, L. Zhang, B. S. Chae, C. Palla, E. M. Furst, K. L. Kiick 11:50 167. Self-assembling multifunctional nanoparticles from elastin-like polypep tides. Z. Megeed, K. Rege, L. Selby, M. L. Yarmush Polymer Surfaces and Interfaces Interfacial Physics and Adhesion Sponsored by POLY, Cosponsored with PMSE TUESDAY AFTERNOON
Section A McCormick Place South Room S504B/C, Level 5 Polymer-Directed Mineralization Mineralization on Patterned Polymer Templates and Filled Polymers N. Kroger, F. Meldrum, and H. Côlfen, Organizers S. Yang, Organizer,
Presiding
9:00 139. Growing crystals in and on micropatterns. J. Aizenberg 9:30 140. Bioinspired mineralization of 3-D polyelectrolyte scaffolds. J. A. Lewis 10:00 141. Biomimetic synthesis of titania on micropatterned polymer templates. J. Ford, S. Yang 10:20 Intermission.
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Nanostructures from Block Copolymers and Supramolecular Polymers Active Nanostructures Cosponsored with POLY
Section A
C. Y. Ryu, D. A. Savin, and T. S. Bailey, Organizers
General Papers and New Concepts in Polymeric Materials Nanotechnology
B. Gong, Organizer,
McCormick Place South Room S504B/C, Level 5
Presiding D. Webster,
8:30 153. Terpyridine-functionalized (metallo-)star polymers. C. Guerrero-Sanchez, C. Ott, U. S. Schubert 9:05 154. Supramolecular graft-copolymers based on complementary quadruple hydrogen bonding. R. P. Sijbesma, G. B. W. L. Ligthart, H. Ohkawa, E. W. Meijer 9:40 Intermission . 9:50 155. Amphiphilic hyperbranched-hyperbranched block copolymers based on polycarbosilane and polyglycerol. H. Schiile, J. Nieberle, H. Frey 10:10 156. Architecture of nanostructured inclusion complexes composed of amylose and synthetic polymers in polymerization systems. J-l. Kadokawa, Y. Kaneko, K. Beppu 10:30 157. Polymeric self-assembly driven by molecular recognition. A. Nelson, D. Chun 10:50 Intermission .
Organizer
T. Goodson III and Β. Μ. Eick,
Presiding
1:00 168. Dispersions of carbon nanotubes in polyol ester oils for heat transfer appli cations. H. Hong, B. Wright, W. Roy 1:20 169. Ordered honeycomb-structured films from fluoro-polyimide. L. Wang Sr., Y. Tian Jr., H. Ding Jr., B. Liu Sr. 1:40 170. Electrospinning of ceramic nanofibers. B. M. Eick, J. P. Youngblood 2:00 171. Syntheses of polyesters having precisely tuned sizes. K. Takizawa, N. N. Oza, J. Cordaro, C. J. Hawker 2:20 172. Preparation of honeycomb films from a hydrophobic polymer and the differences between hydrophobic and hydrophilic polymers on pattern formation. Y. Tian, H. Ding, L. Wang Sr., B. Liu Sr. 2:40 173. Air-gap sacrificial materials: Initiated-CVD synthesis, characterization and air-gap construction. L. H. Lee, Κ. Κ. Gleason
3:00 Intermission. 3:10 174. Effects of different dispersing agents on polymer carbon nanotube composites. E. Camponeschi, H. Garmestani, R. Tannenbaum 3:30 175. Inter particle electromagnetic coupling in assembled gold-polylysine hybrid nanonecklace particles. G. Ramakrishna, Q. Dai, J. Zou, Q. Huo, T. Goodson III 3:50 176. Preferential location of conducting carbon black in multiphase polymer com posites. Q. Zhang, H. Xiong, W. Li, D. Chen, M. Zhu 4:10 177. Preparation and characterization of fibriform nanocomposites of polylactic acid/attapulgite. X. Fan, S. Tang, J. Shao, LU 4:30 178. Development of functional high temperature polymers for molecular recog nition processes. G. F. Eade, D. J. Milliron, A. Nelson, R. C. Pratt, J. L. Hedrick 4:50 179. Versatile conductive patterning using exfoliated graphite nanoplatelets, copper, and polyelectrolytes. T. R. Hendricks, J. Lu, L. T. Drzal, I. Lee Section Β McCormick Place South Room S504D, Level 5 Conjugated Oligomers and Polymers Materials Characterization and Field-Effect Devices B. de Boer and A. Facchetti, Presiding
Organizers,
1:30 180. Charge transport at organic-or ganic heterointerfaces. H. Sirringhaus 2:00 181. Controlling the microstructure of polymeric semiconductors and investigat ing its effect on charge transport. A. Salleo, L. H. Jimison, M. L. Chabinyc, M. F. Toney 2:30 182. Discrete reactive conjugated oligomers for electronic devices. C. B. Nielsen, J. R. Reynolds, M. M. Jacob, F. Wang, R. D. Rauh 2:50 183. Solution processable quaterthiophene-containing carbosilane dendrimers. S. A. Ponomarenko, E. A. Tatarinova, T. Meyer-Friedrichsen, S. Kirchmeyer, S. Setayesh, D. D. Leeuw, S. Magonov, A. M. Muzafarov 3:10 Intermission. 3:30 184. Push and pull of electrons in polyheterocycles. J. R. Reynolds, A. L. Dyer, M. Ertas, E. M. Galand, Y-G. Kim, T. T. Steckler, B. C. Thompsom, H. Turkcu 3:50 185. Printed plastic switches and organic transistors for large-area electron ics. T. Someya, T. Sekitani, Y. Kato, Y. Noguchi, S. Nakano, S. Takatani, M. Takamiya, T. Sakurai 4:20 186. Self-assembled nanostructures of oligo(2,5-bis(hexyloxy)-p-phenylenevinylene) and its hybrids. C-C. Hsieh, J-H. Jaw, K-F. Lin, T. Ogawa, T. Nemoto, S. Isoda 4:40 187. Carboxylic acid-functionalized polyethylenedioxythiophenes (PEDOTs) : Syntheses, characterization, and electronic properties. E. M. Ali, E. A. B. Kantchev, H-H. Yu, J. Y. Ying 5:00 188. Aqueous polyalkyne dispersions. J. Huber, S. Mecking Section C McCormick Place South Room S505A, Level 5 Nanostructures from Block Copolymers and Supramolecular Polymers Thin Films and Confinement Cosponsored with POLY C. Y. Ryu, D. A. Savin, and B. Gong, Organizers T. S. Bailey, Organizer,
Presiding
1:30 189. Self-assembly in thin films of rod-coil block copolymers. B. D. Olsen, X. Li, J. Wang, R. A. Segalman 2:05 190. Nanostructures from confined self-assembly of block copolymers. A-C. Shi 2:40 Intermission .
TECH-123
TECHNICAL PROGRAM
PMSE 2:50 191. Polystyrene-i>poly(ethylene oxide) blends: Effect of molecular weight and composition. J. Logan, B. Schiller, T. Wu, S. M. Baker 3:10 192. Synthesis and morphology of ABC triblock copolymers containing styrene and 4-vinylpyridine. C. Tang, M. Dimitriou, G. H. Fredrickson, E. J. Kramer, C. J. Hawker 3:30 193. Microphase separation of block copolymers under cylindrical confinement: Electrospun fibers with internal structure. M. Ma, V. Krikorian, J. H. Yu, E. L. Thomas, G. C. Rutledge 3:50 Intermission . 4:00 194. Single chain in mean field simula tions and experimental studies of directed block copolymer assembly on patterned substrates. K. C. Daoulas, M. P. Stoykovich, H. Kang, G. Liu, J. J. De Pablo, P. F. Nealey, M. Muller 4:20 195. Versatile layer-by-layer surface modification using functionalized starpolymers and epitaxial polyvalent selfassembly. J . Sly, J. D. J. Samuel, C. S. Bonifacio, L. Chang, V. Y. Lee, M. McNeil, W. P. Risk, C. M. Jefferson; R. D. Miller 4:40 196. Microphase separated block copolymers prepared by ROMP. K. Stubenrauch, G. Fritz, O. Glatter, E. Ingolic, W. Grogger, F. Stelzer, G. Trimmel Section D McCormick Place South Room S505B, Level 5 Designed Macromolecular Assemblies for Biomedical Applications Drug and Gene Delivery W . L. Murphy,
Organizer
J. H. Collier and T. M. Reineke, Organizers, Presiding 1:40 197. Quantitative studies of multivalent polymers designed for targeted drug delivery. M. M. Banaszak Holl, P. Leroueil, S. Hong, J. R. Baker Jr., B. G. Orr, S. DiMaggio, C. Kelly 2:00 198. Macromolecules with tailored non-covalent interactions for biomedical applications. J. M. Layman, A. A. Hirani, M. T. Hunley, Y. W. Lee, B. Lepene, C. D. Thatcher, T. E. Long 2:30 199. Glycopolymers for DNA drug delivery to cardiomyocytes. Y. Liu, K. Fichter, J. Gulick, J. Robbins, T. M. Reineke 3:00 200. Novel polymer-drug conjugates. B. M. Cooper, B. Parrish, T. Emrick 3:30 Intermission. 4:00 201. Doxorubicin-conjugated amphiphilic scorpion-like macromolecules: Syn thesis, characterization and intracellular drug delivery. K. E. Uhrich, L. del Rosario, J. Djordjevic, J. Wang 4:30 202. Preparation of high-boron content diblock copolymers for BNCT applications. Y. C. Simon, T. Eren, E. B. Coughlin 4:50 203. Polymeric nanoparticles with controlled sizes for targeted drug delivery. R. Tong, J. Cheng 5:10 204. Hyperbranched fluoropolymers (HBFP(III)), designed as complex nanostructures for potential imaging and thera peutic delivery. K. T. Powell, C. Cheng, W. Du, K. L. Wooley Polymer Surfaces and Interfaces Self-Assembly, Adsorption and Patterning Sponsored by POLY, Cosponsored with PMSE
Please refrain from using cellular telephones and cameras during technical sessions.
124-TECH
T U E S D A Y EVENING Section A Hyatt Regency Chicago Riverside Center Joint PMSE/POLY Poster Session D. Webster, Organizer,
Presiding
6:00-8:00 Conjugated Oligomers and Polymers. 205. Polymer blend dielectrics for organic thin-film-transistors: Update on dielectric properties and device performance. H. Yan, A. Facchetti, T. J. Marks 206. Silole-based polymeric semiconductors for organic thin-film transistors. H. Usta, G. Lu, A. Facchetti, T. J. Marks Designed Macromolecular Assemblies for Biomedical Applications. 207. Reactive block copolymer scaffolds prepared by RAFT polymerization. R. C. Li, J. Hwang, H. D. Maynard 208. Immobilization of biomolecules on pulsed plasma polymerized poly(vinylacetic acid) thin films. D. Bhattacharyya, K. Pillai, Ο. Chyan, L. Tang, R. B. Timmons 209. Effect of NaCI on properties of freeze/ thawed hydrogels composed of polyvinyl alcohol) and chitosan. G. He, H. Zheng, J. Chen, H. Qin 210. Effect of spatial relationship between positive charge and alkyl tail on the biocidal activity of pyridinium polymers. V. Sambhy, J. L. Hoar, B. R. Peterson, A. Sen 211. Aminooxy functionalized polymers by ATRP for chemoselective conjugation to proteins. K. L. Heredia, Z. P. Tolstyka, H. D. Maynard 212. Association of hydrotropic dendrimers in aqueous solution: Effects on solubilization of poorly soluble drugs. T. Ooya, Y. Takaoka, H. Sano 213. Controlled release with ultra-thin poly meric nanocomposite films. C. Jiang, D. Zimnitsky, C. Tucker, C. Liu, V. V. Tsukruk 214. Formation and characterization of a stimulus-responsitive dynamic hydrogel based on a nanometer-scale protein conformational change. Z. Sui, W. L. Murphy 215. Monomodal polyelectrolyte complex nanoparticles: Preparation by consecutive centrifugation and protein interaction. W. Ouyang, B. Ke3ler, S. Richter, M. Muller 216. Study of interactions between anionic surfactants and collagen. Y. Li, A. Asadi, M. R. Monroe, E. P. Douglas 217. Site specific targeting for treatment of cancer using temperature sensitive nano particles. D. Singh, V. Choudhary, V. Koul, D. Kuckling, A. K. Dinda, H-J. P. Adler 218. Well-defined glycopolymers synthesized from an ATRP amino acid initiator. R. M. Broyer, H. D. Maynard 219. Synthesis of complex hyperbranched polymer amphiphiles. J. Nieberle, F. Wurm, H. Frey 220. Synthesis of dual-responsive block copolymers of poly(acrylic acid) and poly[oligo(oxyethylene) styrene] and their self-assembly in water. F. Hua, K. Hong, P. F. Britt, J. W. Mays 221. Synthesis of poly(methyl methacrylateco-hydroxyethyl methacrylate)-b-polyisobutylene-b-poly(methyl methacrylate-co hydroxyethyl methacrylate). D. Feng, R. Faust 222. Preparation and characterization of multiwalled carbon nanotube/chitosan fibers by electrospinning. W. Feng Sr., Z.Wu 223. Preparation and characterization of polyvinyl alcohol)/carboxymethyl chitosan hydrogels obtained by freezing/thawing techniques. G. He Sr., H. Zheng Sr., Z. Fu, H.Qin 224. Assembling salicylic acids into a drugtree: A novel platform for drug delivery. S. Tang, S. M. June, B. A. Howell, M. Chai 225. Withdrawn.
Nanostructures from Block Copolymers and Supramolecular Polymers. 226. Competitive adsorption of polystyrenes in cyclohexane into nanoporous silica. F. Tsai, C. Kim, C. Y. Ryu 227. Novel class of organic-inorganic nanohybrids from functionalized silsesquioxanebased nanoparticles and micelles of poly(n-butyl acrylate)-£>/oc/c-poly(acrylic acid). M. Schumacher, M. Ruppel, M. Burkhardt, M. Drechsler, O. Colombani, R. Schweins, Α. Η. Ε. Muller General Papers/New Concepts in Polymeric Materials. 228. Reaction between organotin polymers and the matrix material 2,5-dihydroxy benzoic acid. C. E. Carraher Jr., G. Barot, A. J. Battin 229. Molecular weight calculations for high mass polymers. C. E. Carraher Jr. 230. Ability of a series of organotin polyethyl ene glycols) to inhibit various cancer cell lines. K. Shahi, M. R. Roner, C. E. Carraher Jr., G. Barot 231. Ability of organotin polymers derived from diaminopyrimidines to inhibit cancer cell growth. K. Shahi, M. R. Roner, C. E. Carraher Jr., A. J. Battin 232. F MALDI MS for polymers from cipro floxacin and organotin dihalides. A. Zhao, C. E. Carraher Jr. 233. Synthesis and structural characterization of diallyltin and divinyltin poly(amine esters) containing ciprofloxacin. A. Zhao, C. E. Carraher Jr. 234. Antibacterial and antiyeast activity of aliphatic organotin polyethers. Y. Naoshima, K. Nagao, G. Barot, C. E. Carraher Jr. 235. F MALDI TOF MS of organotin polyethers from aliphatic methylene diols. G. Barot, C. E. Carraher Jr. 236. TOF F MALDI MS of the organotin ether derived from 2-butyne-1,4-diol and dibutyltin dichloride. G. Barot, C. E. Carraher Jr. 237. Ability of dibutyltin polypyrimidine amines to inhibit bacteria and yeast. Y. Naoshima, K. Nagao, A. J. Battin, C. E. Carraher Jr. 238. Synthesis and characterization of diallyl tin and divinyltin derivatives of acyclovir. T. S. Sabir, C. E. Carraher Jr. 239. Electrical conductivity of titanocene polyester derivatives of terephthalic acid. A. J. Battin, C. E. Carraher Jr. 240. Aggregation-induced emission enhance ment of polyacetylenes. C. K. W. Jim, A. Qin, J. W. Y. Lam, M. Hâu3ler, Β. Ζ. Tang 241. New catalysts for polymerizations of 1-chloro-2-phenylacetylenes. J. Liu, J. Sun, Y. Dong, J. W. Y. Lam, W. Yuan, H. Xu, Β. Ζ. Tang 242. Unique photoluminescence from nonconjugated alternating copolymer poly[(maleic anhydride)-a/f-(vinyl acetate)]. C-M. Xing, J. W. Y. Lam, A. Qin, Y. Dong, M. H a u l e r , W-T. Yang, Β. Ζ. Tang 243. Rheological properties of soy protein isolate and polyurethane in polyacrylonitrile/dimethyl sulfoxide solution. R. Xiao, D. Yin, L Gu 244. Characterization of polyacrylonitrile/soy protein isolate blend fiber. R. Xiao, Q. Zhu, LGu 245. Size exclusion chromatography coupled to on-line Fourier transform infra red spectroscopy: A powerful tool for polymer characterization. J. A. McConville, S. O'Donohue, G. Saunders, A. Woods 246. Automatic continuous on-line monitoring of copper-mediated living radical polymer izations. J. A. McConville, G. Saunders, I. Willoughby, S. O'Donohue 247. Synthesis of PEO -b- PNiPAM via RAFT polymerization and its use for preparation of gold nanoparticle. H. J. Jeon, H. S. Park, D. H. Go, K. M. Kim, S-Y. Choi, H-O. Yoo, H. S. Kim, J. Kim 248. Synthesis of water-soluble chitosan using anhydride-terminated poly(ethylene oxide). D. H. Go, H. S. Park, H. J. Jeon, S. Y. Choi, K. M. Kim, Y. W. Kim, J. Kim 249. Controlled styrene radical polymerization initiated by epoxide ring opening with dichlorotitanium phenoxides. A. D. Asandei, Y. Chen, L. Tang, T. A. Hanna, L. Liu
250. Effect of styrene/initiator ratios in Cp 2 TiCI catalyzed radical polymerizations from oxiranes, carbonyls and thermal initiators. A. D. Asandei, Y. Chen, G. Saha, I. W. Moran 251. Poly(glycidyl methacrylate) graft copoly mers with styrene and methacrylates by Cp2TiCI-catalyzed epoxide radical ring opening. A. D. Asandei, G. Saha 252. Temperature dependence of styrene polymerizations initiated by Cp 2 TiCI from epoxides, aldehydes and peroxides. A. D. Asandei, G. Saha, Y. Chen, I. W. Moran 253. Preparation and character of blend gel beads in colon specific drug delivery. Y. Xu, C. Zhan, L. Wang, Y. Lou 254. Preparation and character of nanopar ticles based on crosslinking between Ca 2 + and carboxymethyl chitosan. Y. Xu, C. Zhan, H. Zheng, L. Wang 255. Preparation and character of alginate and sodium carboxymethyl cellulose blend beads as floating drug delivery system. Y. Xu, C. Zhan, L Wang, H. Zheng 256. Encapsulation of carbon nanotubes poly(2-ethyl-2-oxazoline)-t>/oc/f-poly(ecaprolactone). C. Park, S. Lee, J. H. Lee, J. Lim, S. C. Lee, M. Park, J. Kim, C. R. Park, C. Kim 257. Formation of metal nanoparticles in the template of polymer micelle. C. Park, M. Rhue, J. Lim, H. J. Park, Ε. Κ. Choi, C.Kim 258. Nanovalves for mesoporous silica par ticles based on polypseudorotaxane motif. C. Park, K. Oh, S. C. Lee, C. Kim 259. Cyclodextrin-covered organic nanotubes: Self-assembly and functionalization. C. Park, M. S. Im, J. Lim, S. Lee, C. Kim 260. Effects of diamine structure on swelling of polyimide membranes. L. Yang, B. Sun Sr., Y. Xu, C. Chen, J. Li 261. Swelling characteristics of polyimide membrane in different aqueous solutions. L Yang, B. Sun Sr., Y. Xu, C. Chen, J. Li 262. Effects of different solvents and mono mer structures on swelling of polyimide membranes. L. Yang, B. Sun Sr., Y. Xu, C. Chen, J. Li 263. Functional organic-inorganic hybrid materials for optical waveguide applica tions. J. K. Han, Y. K. Kwon 264. Synthesis and morphology of a nanostructured chemosensor incorporated with an ESIPT molecule and polydiacetylene. J. M. Jung, Y. K. Kwon 265. In situ electrospinning route for the carbon/Cu 2 S heterostructured nanofibers. C. Wang, J. Li 266. Preparation and characteristics of ultrafine fiber from electrospinning of BPDAODA poly(amic acid) solution. J. Liu, N. Hu, C. Wang 267. Preparation of asymmetric porous gelatin scaffolds. Y. Huo, Y. Huang 268. Synthesis and bacteriostatic activity of novel Ce(lll)-gelatin complex. T. Wei, Y. Huang 269. Effect of molecular structure of carboxy methyl chitosan and preparative condition on protein encapsulation of carboxymethyl chitosan nanoparticles. J. Tan, R. Wei, J. Chen, C. Zhan, Y. Xu 270. Swelling and sustained drug release profiles of beads based on ionic crosslinkage. Y. Xu, C. Zhan, H. Zheng 271. Effect of pH on the composite modulus of soy protein aggregates and carboxylated styrene-butadiene latex. L. Jong, S. C. Peterson 272. Green composites of natural rubber and defatted soy flour. L. Jong 273. Surface resistivity of hydrophilic poly urethane dispersion containing MWNT. H. Cheong, I-J. Chin 274. Synthesis and characterization of the hyperbranched urethane-g-acrylic polymer with unsaturated double bond and hydroxyl functional group. H. Cheong, l-J. Chin 275. High-interlayer-spacing modification of layered clays and their amphiphilic selfassembling properties. J-J. Lin, Y. M. Chen 276. Mechanistic aspects of clay intercalation with amphiphilic poly(styrene-co-maleic anhydride)-grafting polyamine salts. J-J. Lin, Y-C. Hsu, K-L. Wei
PMSE 277. Synthesis of poly(4-vinylphenol) deriva tives and preparation of multilayered films from aqueous media. V. M. Carroll, M. A. Baumler, J. C. Cadwalader, J. R. Drapo, M. L Ingalsbe, M. S. Pinto, M. A. van Dongen, R. Priefer 278. Nanoencapsulation of isocyanate func tional cores by hydroxyl or amine functionalized shells. H. Yang, S. K. Mendon, J. W. Rawlins 279. Novel silica-encapsulated dendrimerpalladium catalyst. D. Vincent, S. R. Clarke, P. R. Dvornic, C. Hartmann-Thompson, J. G. Matisons 280. Towards biosensors based on covalently functionalized poly(pyrrolepropylic acid) nanowires. A. K. Wanekaya, S. Tolani 281. Novel synthesis of poly(phenylene ethynylene) composed of alternating fluorinated and non-fluorinated units. T. Dutta, M. D. Watson 282. Synthesis and optical properties of unsymmetrical benzoperylenes. V. Sivamurugan, S. Valiyaveettil 283. Incorporation of microencapsulated dicyclopentadiene into an acrylic bone cement matrix. P. Biggs, L. Jones II, G. Lewis 284. Adsorption of nitrogen oxide on immer sion modified activated carbon fiber felt. X. Song, H. Zhang, C. Wang 285. Alkoxysilane oligomer modified epoxy coatings. H. Gu, M. D. Soucek 286. Characterization and curing behavior of polyamine crosslinked a, β-unsaturated resin via aza-Michael reaction. D. M. Park, H. Cheong, I-J. Chin 287. Cure characterization of polyimidegraphite composite by FTIR-photoacoustic spectroscopy. R. Vijayaraghavan, C. S. P. Sung 288. Determination of gelation time using rheological methods. C. Liu, C. Vailhe 289. Dynamic viscoelastic properties of hydroxyl-terminated poly(amidoamine) dendrimer physiological saline solutions. D-H. Zhang, N. Ravi 290. Energy storage study of ferroelectric P(VDF-TrFE-CTFE) terpolymers. Z. Zhang, W. Chen, T. C. Chung 291. Energy transfer in a dendrimer exhibiting a delocalized donor and a localized accep tor. K. V. Hagedorn, O. Varnavski, J. F. Hartwig, T. Goodson III 292. Epoxy nanocomposites from dual-functionalized clay prepared from one-pot reaction. J. Wang, L. J. Mathias 293. Epoxy nanocomposites with organoclay containing mixed pendant groups or with ' mixed organoclays. C. Chen 294. FEM analysis of the thermal residual stress of carbon fiber/PPESK composite. C. Lu, P. Chen, B. Yu, Q. Yu, S. Liu 295. Formation of micellar structure in algi nate. S. Sankaran, R. L. Arechederra, S. D. Minteer 296. Gate dielectric chemical control of pentacene film microstructure and field-effect transistor performance. C. Kim, A. Facchetti, T. J. Marks 297. Influence of polyborosiloxane on the flame retardancy of polyethylene terephthalate-clay nanocomposite. Y. Huo, Q. Fan, N. Dembsey, P. K. Patra 298. Kinetics of the dynamic elastic modulus recovery during annealing for poly(dimethylsiloxane) composites with nanosilica. G. Lin, X. Zhang, Y. Qian, L Zhang 299. Light induced fluorescent patterning of polybenzoxazole and enhanced emission of hydroxyphenyl-benzoxazole oligomer. H-J. Kim, T. Kim, J. K. Lee, T. S. Lee, J.Kim 300. Morphology and properties of polyacrylates-silica nanocomposites. J-N. Li, W. Li, Q-L. Yuan, S-S. Wu 301. Nanophase-separated structure from a diblock-type supramacromolecule via biocomplemetary hydrogen bonding. A. Noro, Y. Nagata, A. Takano, Y. Matsushita 302. Novel copolymers of vinyl acetate and alkyl ring-substituted 2-phenyl-1,1-dicyanoethylenes. G. B. Kharas, S. M. Russell, D. P. Baecher, J. H. Becker, S. Borgmeyer, J. Mancias, E. Duzo, A. M. Delgado, T. Rose, M. K. Hartmann 303. Organic-inorganic hybrid filler to improve physical properties of poly(lactic acid). F. Jin, M. Satoh
304. Overview of continuous polymerization process technology. K. R. Sharma 305. Patterning of electrochromic polyterthiophene fiber mats and films and potential applications. C. I. Asemota, M. Rousselle, A. Kumar, G. A. Sotzing 306. Polymer/clay and polymer/ceramic aero gel composites. M. D. Gawryla, S. A. Bandi, D. A. Schiraldi 307. Positive temperature coefficient resistivity effect in polyorganosiloxane modified polyolefin composites. D. W. Kang, B. C. Lee, O. Kim 308. Square arrays of vertical cylinders of PS-b-PMMA on chemically spot-patterned surfaces. S-M. Park, H. H. Solak, Y-H. La, P. F. Nealey 309. Preparation and characterization of a novel carboxymethyl chitosan hydrogel for drug controlled release. H. Zheng, H. Qin, J. Huo, P. Xu, G. He 310. Preparation of organoclay and its appli cation in acrylic coatings. N. Jiratumnukul, T. Pissaroop 311. Preparation of poly(styrene-co-maleic anhydride) (SMA) hydrogel nanofiber by electrospinning. H-Q. Liu, C. Tang, S. Ye 312. Properties of homogeneously modified starch and its blend with poly(e-caprolactone). Y. Li, J. Lin, C. Lu, S. Cheng 313. Schizophrenic micelles from a poly(acrylic ac\d)-block poly(/V,/V-diethylacrylamide) copolymer. X. Andre, M. Burkhardt, M. Drechsler, P. Lindner, M. Gradzielski, A. H. E. Muller 314. Stimulus responsive aggregation of a novel rod-coil type double hydrophilic block copolymer containing rigid strictly alternating polyampholyte in aqueous solution. M. Mao, S. R. Turner 315. Structural differences in aerogels pre pared with different clay minerals. J. R. Johnson III, D. A. Schiraldi 316. Study on effect of feed ratio on con trolled cross-linking polymerization pro cess. F. Li, R. Sun, Q. Zhou, X. Cheng, X. Zhou, Z. Liu, D. Liu, J. Chen 317. Study on the properties of protein A immunoadsorbent using an activated agarose as a carrier. Z. Wang, G. Li, X. Zhang, L. Wu, D. Yang 318. Surface-initiated ATRP polymerization from self-assembled peptide nanotubes: Synthesis of polymer-wrapped peptide nanotubes. J. Couet, M. A. Biesalski 319. Synthesis and characterization of novel copolymer for reversible bioconjugation. S. Ghosh, M. Lartey, S. Basu, B. S. Sandanaraj, S. Thayumanavan 320. Synthesis and characterization of poly(3hexylthiophene)-polyethylene block copolymers. C. B. Nielsen, R. A. J. Janssen 321. Synthesis and dyed poly(trimethylene terephthalate) fibers with novel waterrepellent azo dyes. S-K. Liao, P-H. Huang, C-F. Yu, S-M. Lin 322. Synthesis and evalution of new amor phous biodegradable elastomers. J . Liu, D. A. Olson, V. V. Sheares 323. Synthesis, self-assembly and character ization of a novel rod-coil-rod block copoly mer containing conjugated oligomers. K. Li, Q. Wang 324. Biological effect of amine density within poly(glycoamidoamine) DNA delivery vehicles. C-C. Lee, T. M. Reineke 325. The preparation and the properties of the gelatin/XNBR blends. X. Li, X. Xin, Y. Yin 326. White light-emitting diodes by blending poly (oxadiazole-co-fluorene) (POXF) and MEH-PPV. M-S. Kim, K. Lee, H-J. Kim, M. Shtein, J. Kim 327. Novel approach toward biogenic amine sensing using cross-reactive poly(thiophene)s sensor arrays. T. K. Deason, M. S. Maynor, T. L. Nelson, J. J. Lavigne 328. Ampholytic diblock-copolymers by the RAFT technique: Candidates for selfassembled micelles for drug delivery. A. Licea-Claverie, C. Obeso-Vera, Μ. Ο Flores-Parra, J. M. Comejo-Bravo, C. W. Frank 329. Anion sensors in polyurethane matrices: Synergy between matrix and sensor mate rials improves selectivity of the sensing process. M. A. Palacios, R. Pohl, G. Zyryanov, P. Anzenbacher Jr.
330. Antifouling block copolymer surfaces that resist settlement of barnacle larvae. C. J. Weinman, S. Krishnan, D. Park, M. Y. Paik, K. Wong, D. A. Fischer, D. L Handlin Jr., G. L. Kowalke, D. E. Wendt, K. E. Sohn, E. J. Kramer, C. K. Ober 331. Antimicrobial cellulosic fibers with incor poration of aminopyridinium salts. T. Zhao, G.Sun 332. Atomistic simulations of graphite polypro pylene nanocomposites including covalent graphite modification. R. N. Chambliss, M. S. Reeves 333. Azide end-capped hyperbranched polyglycerol: Complex polymer structures via click chemistry. Y. Shen, Z. Shen, J. Nieberle, E. Barriau, H. Frey 334. Behavior of matching molecular weight linear and star PEG self-assembled mono layers upon protein adsorption. C. F. Jullian, R. O. Claus, W. B. Spillman Jr., J. L. Robertson 335. Bio-degradable/absorbable polymer alloys. H. T. Oyama, Y. lizuka 336. Carbocationic polymerization of styrene under environmentally benign conditions. K. Verebélyi, P. W. Groh, B. Ivan 337. Characterization of copolymers hydrogel vitreous substitutes that gel in situ. K. E. Swindle, P. D. Hamilton, Y-B. Shui, D. C. Beebe, N. Ravi 338. Characterization of nanoclays in solvents. M. F. Tse, B. S. Hsiao, P. Nawani 339. Characterization of water in nation by near-IR, solid-state NMR studies and conductivity measurement. D. Koo, C. S. P. Sung 340. Chitosan modified electrodes for ethanol/ oxygen biofuel cells. R. Duma, S. D. Minteer 341. Comparative study on Z-supported RAFT polymerization based on silica particles and Merrifield resin. Y. Zhao, S. Perrier 342. Confinement of diblock copolymers in submicro-pattems for hierarchically ordered nanostructures. S. Kim, K. Char, B-H. Sohn 343. Controlled release of low molecular weight cationic molecules from electrospun weak polyelectrolyte fibers. A. Chunder, S. Sarkar, Y. Yu, L. Zhai 344. Controlling refractive index of methyl methacrylate/styrene/acrylonitrile terpolymer through continuous process. Y. Jin, J. K. Hong, W. S. Park, B. D. Lee, J. I. Kim 345. Copolymerization of 2-hydroxyethyl acrylate and 2-hydroxyethyl methacrylate: Controlling the water content of hydrogels. W. T. Grubbs, A. Ramirez 346. Delivery of antisense DNA to nuclear telomere RNA by use of a natural polysaccharide of schizophyllan. J. Minari, T. Kubo, N. Shimada, Y. Takeda, T. Nagasaki, S. Shinkai, K. Sakurai 347. Dielectric and mechanical behavior of surface-modified BaTi06/polyamide-6 composite films. S-S. Lee, T. H. Kim, J. Kim 348. Effect of antisettling agent on the performance of copper-based conductive coatings. Z. Li, X. Liu, X. Wang, Y. Zhang 349. Effect of hydrogen bond on the interaction between the superplasticizer molecules and cement particles. W. Li, Q. Pan, J. Zhang, C. Li, M. Pei, X. Z. Kong, X. Zhu 350. Effect of hydrogen bonding on properties of styrene/vinyl phenol copolymers. G. Chigwada, B. G. Olson, M. K. Hassan, K. A. Mauritz, S. Nazarenko 351. Effect of moisture absorption on property of epoxy resin/cyanate ester/glass cloth composites. L. Huang Sr., C. Wang, Y. Lu Sr. 352. Effect of solvents on the properties of thermoplastic polyurethane/clay nanocomposites. C. H. Dan, W. T. Kim, J . H. Kim 353. Effects of molecular weight on poly(galactaramidoamine) toxicity and DNA delivery. V. P. Taori, T. M. Reineke 354. Effects of nanoparticles with various structures on soy protein-based nanocomposites. M. Wei, J. Yu, J. Huang 355. Effects of secondary amine number in trehalose click polymers for transfection. K. Kizjakina, T. M. Reineke
356. Electrospun PCL/CNF scaffolds with controlled surface chemistry. H. Deshpande, M. V. Jose, V. Thomas, W. C. Clem, S. Chowdhary, D. R. Dean, E. Nyairo 357. Excellent control over branching kinetics via a one-pot RAFT polymerization reaction. P. Mounteney, S. P. Rannard, P. Findlay, D. J. Duncalf, S. Perrier 358. Exploring cellular internalization mechanisms of polymeric gene delivery vectors. P. M. McLendon, T. M. Reineke 359. Exploring the mechanism of acrylic/alkyd hybrid systems by means of one- and two-dimensional NMR. J. S. Hasseman, M. Thatte, M. D. Soucek 360. Fabrication of organic dyes/PMMA 1D nanocomposite with FRET properties. K. J . Lee, J. Jang 361. Functional self-assembled monolayers for large photoinduced charge transfer in organic field-effect transistors. P. Paoprasert, B. Park, I. In, J. Zwickey, P. G. Evans, P. Gopalan 362. Gadolinium-containing glyco-polymers for MRI. J. M. Bryson, T. M. Reineke 363. Graphoepitaxy and orientational control of lithographically pattemable diblock copolymers by solvent annealing. J. K. Bosworth, E. L. Schwartz, J. Q. Huang, A. W. Ko, R. Ruiz, C. T. Black, C. K. Ober 364. Hierarchical fabrication of linear (1-D) arrays of metal and metal oxide nanoparticles using block copolymer templates. Y-H. La, M. P. Stoykovich, S-M. Park, P. F. Nealey 365. High performance soft lithography by developing photocurable stamps. Κ. Μ. Choi 366. Highly mobile antimicrobial silicone oligomers. J. H. Wynne, R. R. Pant, J. P. Buckley, C. T. Lloyd, P. G. Santangelo, B. T. Rasley 367. Hyperbranched polymer nanocomposites with composition dependent morphologies. J. J. Decker, G. Chigwada, B. G. Olson, D. A. Wicks, S. Nazarenko 368. In situ polymerized phenolic bonded NdFeB magnets. L. Huang, H. Yan, Y. Lu 369. Layered-clay-skeleton initiated epoxy polymerization and formation of unique silicate/polymer hybrid assemblies. J-J. Lin, Y-N. Chan, R-J. Jeng 370. Lipase-immobilized electrospun polyacrylonitrile nanofibrous membrane. J-P. Chen, S-F. Li, W-T. Wu 371. Mechanical investigations of wheat gluten/thiolated polyvinyl alcohol) blends. R. Dicharry, P. Ye, G. Saha, E. Waxman, R. S. Parnas, A. D. Asandei 372. Microwave synthesis of star-shaped poly({epsilon}-caprolactone) with polyol initiator. Z. Yu, L. Liu 373. Moisture outgassing from silica-filled polydimethylsiloxane TR55 and S5370. L. N. Dinh, A. K. Burnham, M. A. Schildbach, R. S. Maxwell, B. Balazs, W. McLean II 374. Multiphoton fluorescence quenching of conjugated polymers for TNT detection. A. Narayanan, O. P. Varnavski, T. M. Swager, T. Goodson III 375. Nanorings from the self-assembly of amphiphilic molecular dumbbells. E. Lee, J-K. Kim, M. Lee 376. Novel branched structure material with high frequency dielectric response. M. Guo, T. Goodson III 377. Novel dual crosslinked complex gel bead based on carboxymethyl chitosan/alginate for oral delivery of protein drugs. H. Zheng, H. Qin, C. Zhang, G. He 378. Novel preparative method of polylactide microspheres and effect on anisodamine encapsulation efficiency. Y. Lou, X. Yan, F. Zhao, H. Yang, Q. Song
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TECH-125
TECHNICAL PROGRAM
PMSE 379. Novel strategy for polymer/carbon nanotube composites preparation: Ultrahigh shearing. G-X. Chen, H. Shimizu 380. PAN-based mesoporous carbon with tunable pore diameter: Synthesis and electrochemical performance. M. Choi, J. Jang 381. Phase behavior of blends of PS-fr-PB diblock copolymer and PS homopolymer in emulsion droplets. S-J. Jeon, G-R. Yi, S-M. Yang 382. Photopatternable nanoporous titania films by coassembly of diblock copolymer and chemically modified titanium alkoxide. O-H. Park, J. Y. Cheng, H. S. Kim, P. M. Rice, T. Topuria, L. E. Krupp, R. D. Miller, H-C. Kim 383. Polyacrylonitrile-fifrafrpoly(ethylene glycol) (PAN-g-PEG) for size-selective, fouling resistant nanofiltration (NF) mem branes. A. Asatekin, A. M. Mayes 384. Polyelectrolyte templating of calcium carbonate microspheres and 3D scaffolds. S. T. Parker, J. A. Lewis 385. Polymerization of di(ethylene glycol) 2-ethyl hexyl ether acrylate via reversible addition-fragmentation chain transfer polymerization. S. Venkataraman, K. L. Wooley 386. Polyphenylene based branched poly mers: Synthesis, characterization and properties investigation. H. Zhuang, S. Valiyaveettil 387. Preparation and characterization of silk fibroin/bacterial cellulose composite films. R. Jung, H. S. Kim, W-l. Park, H-J. Jin 388. Preparation of aligned polyetherimide fiber by electrospinning. S. Moon, H. Kim, J. Choi, R. J. Farris 389. Preparation of low T g phosphate glasses and their blends with polymers for high barrier applications. M. Gupta, T. Deans, D. A. Schiraldi 390. Robust and biocompatible ultrathin silk fibroin films. C. Jiang, X. Wang, R. Gunawidjaja, Y-H. Lin, R. R. Naik, M. K. Gupta, D. L. Kaplan, V. V. Tsukruk 391. Study on amphiphile triblock copolymer: Cholesteryl-PCL-mPEG. J . Guo, J. Sun, D. Zhao, H. Cao, H. Yang 392. Study on inclusion complexes formed by cholesteryl-(e-caprolactone) polymer and 7-cyclodextrin. J . Sun, J. Guo, H. Cao, H. Yang 393. Supramolecular assembly in common organic solvent from block copolymer and organic acid. H. Peng, Y. T. Zhu 394. Synthesis and characterization of novel biomaterials based on cyclic acetal and PEG hydrogels. S. Kaihara, J. P. Fisher, S. Matsumura 395. Synthesis and mobility of novel ionic silicones. R. R. Pant, J. H. Wynne, J. P. Buckley 396. Synthesis and properties of telechelic poly(lactic acid) ionomers. A. J . Ro, R. A. Weiss, S. J. Huang 397. Synthesis of functionalized hexacene for OTFT application. B. Purushothaman, S. R. Parkin, J. E. Anthony 398. Synthesis of modified polybutadiene by sol-gel process and its application to dye-sensitized solar cell. Y-S. Yeo, J-K. Lee, M-R. Kim 399. Synthesis, optical and thermal properties of oligothiophenesilane dendrimers. O. V. Borshchev, S. A. Ponomarenko, N. M. Surin, Y. N. Luponosov, M. I. Buzin, A. M. Muzafarov 400. TEM studies of wheat gluten/thiolated poly (vinyl alcohol) blends. J. Dong, R. Dicharry, R. S. Parnas, A. D. Asandei 401. Templated microreactors: A synthetic approach to enzyme entrapment. D. V. Gough, A. Wolosiuk, P. V. Braun 402. Comparison of the rheological properties of m-LLDPE and commercial PEs. J. Yang, L. Li, Z. Zhang 403. Thiol-ene photopolymerization kinetics study of difunctional thiol with various alkenes. K. Wutticharoenwong, M. D. Soucek 404. Tunable hydrogels prepared from star PDMS and linear PEO. K. R. Regan, Y. Hou, M. S. Hanh, H. Liao, M. A. Grunlan 405. Unusual location of a broad glass transi tion temperature in gradient copolymer. C, L. H. Wong, J. Kim, J. M. Torkelson 406. Use of new tetraalkylborate initiators for remote polymerization of acrylates. A. A. Ermoshkin, E. S. Nikolaeva, D. C. Neckers, A. V. Fedorov
126-TECH
407. Mechanical properties of self-assembled nanostructural lipid tubules. Y. Zhao, J. Fang WEDNESDAY MORNING Section A
Section C
McCormick Place South Room S504B/C, Level 5 Polymer-Based Nanoparticles and Nanostructures S. Rowan,
Organizer
A. L. Frischknecht and M. E. Mackay, Organizers, Presiding 8:25 Introductory Remarks. 8:30 408. Controlled assembly of nanopar ticles using biological and abiotic building blocks. V. M. Rotello 9:10 409. Self-assembly of polymer-tethered nanoparticle shape amphiphiles. S. C. Glotzer, M. A. Horsch, C. R. lacovella, A. S. Keys, E. R. Chan, X. Zhang, Z. Zhang 9:50 410. Implementation of dentric molecu lar transporter into nanoobjects with con trol of delivery to intracellular compart ments. K. Huang, M. J. Cohen, T. A. Croce, S. K. Hamilton, B. L. Evans, B. Voss, H. Hamm, E. Harth 10:30 411. Conducting polymer-cellulose nanocomposites. C. Weder 11:10 412. Polymerization of the ligands of gold nanoparticles segregated to an oil/ water interface. E. Glogowski, J. He, R. Tangirala, T. P. Russell, T. Emrick 11:50 413. Stimuli-responsive polymer microgel particles. W. Richtering, M. Keerl, J. E. Wong, C. B. Muller Section Β McCormick Place South Room S504D, Level 5 Conjugated Oligomers and Polymers Materials Characterization and Field-Effect Devices B. de Boer and A. Facchetti, Presiding
11:20 420. Ultrafast energy transfer in conjugated systems based on fluorene oligomers and aluminum tris(8-quinolinolate). V. A. Montes, P. Anzenbacher Jr. 11:40 421. Novel fluorene-based copolymer for cyan and green light-emitting diodes. J. Li, G. Lu, A. Facchetti, T. J. Marks
Organizers,
8:30 414. Scaling behavior and transport phenomena in organic and polymer tran sistors. A. Dodabalapur, L. Wang, D. Fine, D. Basu 9:00 415. Microstructure foundations of high carrier mobility in polymer semiconductors. D. M. DeLongchamp, R. J. Kline, E. K. Lin, D. A. Fischer, L J. Richter, A. J. Moad, M. Heeney, I. McCulloch, J. E. Northrup 9:30 416. Interesting sensory molecules based on cross conjugated water soluble poly(para-phenylenes). H. Li, S. Valiyaveettil 9:50 417. High mobilities for block copoly mers of regioregular poly(3-hexylthiophene). G. Sauvé, R. D. McCullough 10:10 Intermission. 10:30 418. Combining soft and hard materials for unconventional electronics. L. Wang, M-H. Yoon, A. Facchetti, T. J. Marks 11:00 419. Tuning of molecular and solid state electronic properties by fluorination: A theoretical study. J. Gierschner, B. Miliân Medina, H-J. Egelhaaf, D. Beljonne, J-L. Brédas
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
McCormick Place South Room S505A, Level 5 Nanostructures from Block Copolymers and Supramolecular Polymers Bioinspired Self-Assembly Cosponsored with POLY C. Y. Ryu, T. S. Bailey, and B. Gong, Organizers D. A. Savin, Organizer,
Presiding
8:30 422. Microphase separation in designed block copolymers. A. R. Khokhlov, P. G. Khalatur 9:05 423. Nucleobase-containing triblock copolymers as templates for the dispersion of guest molecules at the nanoscale. B. D. Mather, M. B. Baker, T. E. Long, F. L. Beyer 9:40 Intermission . 10:00 424. Softness and order in self-assembled materials. C. Schellbach, A. Fromsdorf, P. Lindner, S. V. Roth, S. Fôrster 10:35 425. Amphiphilic supramolecular polymers based on coiled-coil peptide mediated self-assembly. H. Robson Marsden, A. V. Korobko, E. N. van Leeuwen, N. A. J. M. Sommerdijk, A. Kros 10:55 426. Synthesis of membrane-disruptive diblock copolymers for non-viral drug delivery. A. J. Convertine, R. E. Johns, A. S. Hoffman, P. Stayton 11:15 Intermission . 11:35 427. Combining rigid self-assembling peptide rings with soft polymers for the construction of shape-defined hybrid nanostructures. M. A. Biesalski, S. Duman, J. Couet 11:55 428. Grafting short peptides onto polybutadiene-b/oc/c-poly(ethylene oxide): A new platform for self-assembling hybrid amphiphiles. Y. Geng 12:15 429. Supramolecular nanoplatelets assembled from pluronic/cyclodextrin polyrotaxanes and reinforced soy proteinbased nanocomposites thereof. Z. Zhou, H. Zheng, J. Yu, J. Huang Section D McCormick Place South Room S505B, Level 5 Designed Macromolecular Assemblies for Biomedical Applications Biomaterials
11:00 436. Novel designed immunoisolatory membranes of PDMAAm/PDMS. J. P. Kennedy, G. Erdodi, J. Kang, D. Ely 11:20 437. Study of homogeneity and template removal during virus imprinted polymer synthesis. L. D. Bolisay, J. N. Culver, P. Kofinas 11:40 438. Photoswitch assembly of dispiropyran-polymer conjugates. T. Fujiwara, A. Vandenbos, K. Fukushima Polymer Surfaces and Interfaces Polymer Nanocomposites, Particles, Hydrogels and Emulsions Sponsored by POLY, Cosponsored with PMSE WEDNESDAY AFTERNOON Section A McCormick Place South Room S504B/C, Level 5 Polymer-Based Nanoparticles and Nanostructures S. Rowan,
Organizer
M. E. Mackay and A. L. Frischknecht, Organizers, Presiding 1:30 439. Nanoparticles and nanocages originating from well-defined brush block copolymers. C. Cheng, K. Qi, E. Khoshdel, K. L Wooley 2:10 440. Nanoparticles in polymer solutions: Phase behavior, gelation and elastic modulus. M. Surve, V. Pryamitsyn, V. Ganesan 2:50 441. Simulation of nanoparticle formation by irreversible collapse of unfolded macromolecular precursors. P. M. Duxbury, J. Liu, M. E. Mackay 3:30 442. Conformational changes of chain molecules on an adsorbing substrate: Solvent and temperature effects. E. S. McGarrity, T. E. Bohnsack, A. L. Frischknecht, M. E. Mackay 3:50 443. In-situ formation of Ag nanoparticles in polystyrene (PS) core-poly acrylic acid (PAA) brush particles by UV-irradiation. Y. Lu, Y. Mei, M. Schrinner, M. Ballauff 4:10 444. Measurement of nanoparticle diffusion coefficients in polymer melts: Breakdown of the continuum StokesEinstein relation. A. Tuteja, M. E. Mackay, S. Narayanan, M. S. Wong, C. Hawker . 4:30 445. Preparation of functional ferromagnetic colloids and assembly into 1-D mesostructures. B. D. Korth, P. Keng, B. Kim, J. Pyun 4:50 446. Nanoblossoms: Photoinduced stretching and photoinduced dissolution of polycation stars by switching the charge of counterions. F. A. Plamper, A. H. E. Muller, M. Ballauff 5:10 447. Nanostructured composites of polymers and ionic liquids. Y. He, P. M. Simone, T. P. Lodge Section Β
J. H. Collier and T. M. Reineke, Organizers W. L. Murphy, Organizer,
McCormick Place South Room S504D, Level 5
Presiding
8:25 Introductory Remarks. 8:30 430. Biofunctional nanorods in supramolecular thermoplastic elastomers. E. Wisse, E. W. Meijer 8:50 431. Synthesis of functional lactide copolymers. D. E. Noga, A. Kumar, D. M. Collard, M. Week, A. Garcia 9:10 432. Protein, cell and bacterial fouling resistance of peptidomimetic polymer modified titanium surfaces. A. R. Statz, M. O. Honaberger, A. E. Barron, P. B. Messersmith 9:30 433. Molecularly imprinted polymers for selective recognition of signal peptides. D. S. Janiak, J. N. Culver, P. Kofinas 9:50 Intermission. 10:20 434. Antibacterial materials for coatings and general applications: Pyridinium polymers and silver bromide based nanocomposites. V. Sambhy, B. R. Peterson, A. Sen 10:40 435. Control of DNA incorporation into poly-L-lysine multilayers. A. C. Dorris, C. J. Barrett
Conjugated Oligomers and Polymers Photovoltaics and Light-Emitting Devices B. de Boer and A. Facchetti, Presiding
Organizers,
1:30 448. Interface modifications in hybrid organic-inorganic photovoltaic cells using benzoic acid derivatives. S. R. Scully, C. T. Goh, M. D. McGehee 2:00 449. Self-assembled nanostructures for organic photovoltaics. J. Bullock, R. F. Kelley, M. R. Wasielewski 2:30 450. Photoinduced electron transfer in a molecular donor-acceptor quartet. Y. Liang, L X. Chen, S. Xiao, L. Yu 2:50 451. PolydiacetyleneATi02 nanocom posites for photovoltaic applications. Y. Wang, L. Li, F. Yan, L. A. Samuelson, J. Kumar 3:10 Intermission. 3:30 452. Electron and hole transport in poly(p-phenylene vinylene). P. W. M. Blom, M. M. Mandoc, N. I. Craciun, B. de Boer
PMSE
4:00 453. Nature of electronic excitations in conjugated polymers: Role of conformational kinks and chemical defects. E. G. Hennebicq, D. Beljonne, C. Deleener, J-L. Brédas 4:20 454. Bulk-heterojunction organic solar cells: Interfacial engineering routes to increased open-circuit voltage and power conversion efficiency. A. W. Hains, A. B. F. Martinson, M. D. Irwin, H. Yan, T. J. Marks 4:40 455. Atomic force photovoltaic microscopy. B. J. Leever, L. S. C. Pingree, A. W. Hains, M. D. Irwin, T. J. Marks, M. C. Hersam 5:00 456. Novel conjugated oligomers for organic electronics. J. M. Hancock, A. P. Gifford, Y. Zhu, S. A. Jenekhe
Section C McCormick Place South Room S505A, Level 5 General Papers and New Concepts in Polymeric Materials Synthesis D. Webster,
Organizer
M. J . Nasrullah and R. Hoogenboom, Presiding 1:00 457. Controlled free radical polymerization mediated by cysteine and glutathionebased chain transfer agents. Y. Zhao, S. Perrier 1:20 458. New approach to end-graft charged polymer onto mica and silica surfaces. B. Liberelle, S. Giasson 1:40 459. New developments in controlled anionic polymerization of propylene oxide. A. Labbé, S. Carlotti, A. Deffieux 2:00 460. Seeded semi-continuous emulsion polymerization of n-BA/MMA/GMA: Effect of copolymer composition on the adhesive properties. S. Mishra, V. Choudhary, J. Singh 2:20 461. Surface-initiated atom transfer radical polymerization of styrene: Observed transition from first-order to zero-order reaction kinetics. A. Samadi, S. M. Kilbey II, S. M. Husson 2:40 462. Block copolymer of η-butyl acrylate and styrene by RAFT: First practical isola tion and measurements of "dead chains". M. J. Nasrullah, V. Raghunadh, C. Y. Ryu, B. C. Benicewicz 3:00 Intermission. 3:10 463. Microwave-assisted polymeriza tions: From discovery to upscaling. R. Hoogenboom, R. M. Paulus, U. S. Schubert 3:30 464. Synthesis and characterization of soluble polyimide membrane materials for pervaporation of n-octane/thiophene mix tures. L. Wang Sr., Y. Tian Jr., H. Ding Jr., B. Liu Sr. 3:50 465. Synthesis and characterization of sulfonated polyimides for fuel cell applica tions. P. Chhabra, V. Choudhary 4:10 466. Synthesis of acrylic telechelic siloxanes for UV curable applications. R. Chakraborty, M. D. Soucek 4:30 467. Bimodal polyethylene: Synthesis and study of shear induced oriented struc tures generated from high molecular weight polyethylene chains. N. Kukalyekar, L. Balzano, J. C. Chadwick, S. Rastogi 4:50 468. Utilizing d-limonene as a chain transfer agent and renewable solvent for ring opening metathesis polymerizations. R. Mathers, K. C. McMahon, J. R. Baker
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogranV.
Section D McCormick Place South Room S505B, Level 5 Designed Macromolecular Assemblies for Biomedical Applications Biomaterials J. H. Collier, T. M. Reineke, and W. L. Murphy, Organizers A. Coury,
Presiding
1:30 469. Understanding DNA binding mechanisms of trehalose-based polymeric gene delivery vectors. L. E. Prevette, M. L. Lynch, T. M. Reineke 1:50 470. Impact of chemical modification on the physical and biological properties of hyaluronan. D. Gianolio, L. Avila, L. Young, L Yang, G. Ulinski, D. Hempel, M. Perricone, R. J. Miller 2:10 471. Cationic and biodegradable poly mer micelles for efficient gene delivery and effect of core-shell structure. Y-Y. Yang, Y. Wang, C. Y. Ke 2:30 472. Synthesis and characterization of stimuli-responsive core-shell nanogels. D. Kuckling, S. Mendrek, H-J. Adler, A. Dworak 2:50 473. Non-covalent synthesis of a multi valent enzyme. I. van Baal, E. H. M. Lempens, J. L. J. van Dongen, M. Merkx, E. W. Meijer 3:10 Intermission. 3:40 474. Engineering multicomponent assemblies of proteins: Investigating collective protein function and dynamics with molecular precision. M. R. Diehl 4:00 475. Small angle neutron scattering studies of the counterion effects on the molecular conformation and structure of charged G4 PAMAM dendrimers in aque ous solutions. Y. Liu, W-R. Chen, L. Porcar 4:20 476. Design and synthesis of novel amphiphilic polymers for MRI and selective targeting in cancer diagnosis/therapy. M. K. Pandey, R. Tyagi, R. Kumar, V. S. Parmar, A. C. Watterson, J. Kumar, M. T. Hardiman, J. Zhou, K. P. Brower, R. J. Fisher, C. K. Colton 4:40 477. Effect of electrostatic interactions on collagen fibrillogenesis. Y. Li, A. Asadi, M. R. Monroe, E. P. Douglas 5:00 478. Polysaccharides for skin scaffolds. B. T. L. Smith, J. M. Ebaugh, B. Kross, A. Mueller Polymer Surfaces and Interfaces Chemistry at Surfaces and Interfaces Sponsored by POLY, Cosponsored with PMSE THURSDAY MORNING Section A McCormick Place South Room S504B/C, Level 5 Polymer-Based Nanoparticles and Nanostructures S. Rowan,
Organizer
A. L. Frischknecht and M. E. Mackay, Organizers, Presiding 8:30 479. Synthesis of polyphenylacetylene brushes on substrates using anchored organometallic catalysts. K. D. Dronavajjala, R. Rajagopalan, D. L. Allara, H. C. Foley 8:50 480. Tunable release of anionic polyelectrolytes from multilayered polyelectrolyte films. J. Zhang, D. M. Lynn 9:10 481. pH induced conformational transi tion in polyelectrolyte brushlike macromolecules. J. R. Boyce, H-l. Lee, K. Matyjaszewski, S. S. Sheiko 9:30 482. Novel self-assembling nucleobase scaffold coating with nanoscale control. A. M. S. Kumar, S. Sivakova, J. D. Fox, J. E. Green, S. J. Rowan, R. E. Marchant 9:50 483. Hierarchically ordered micelles and materials constructed through self-assem bly of charged triblock copolymers. H. Cui, Z. Chen, K. L. Wooley, D. J. Pochan
10:10 484. Novel fabrication of anisotropic polymer nanoparticles using solvent-aided nanoinjection molding process. D. Srivastava, I. Lee 10:30 485. Synthesis of maleimide functionalizedpoly(e-caprolactone)-b-poly(ethylene glycol) for nanoparticle formation. S. Ji, T. R. Hoye, C. W. Macosko 10:50 486. Synthesis, degradation, in vitro release, and bioconjugation of functional nanogels prepared by inverse miniemulsion ATRP for biomedical applications. J. K. Oh, D. J. Siegwart, K. Matyjaszewski 11:10 487. Preparation and characterization of polypyrrole nanodisc templated by tobacco mosaic virus. S. Li, Z. Niu, Q. Wang 11:30 488. Polymer hybrids of manganese based single molecule magnets: Synthesis and analysis. L. P. Johnson, J. G. Matisons, S. R. Clarke 11:50 489. Deformation and failure mecha nisms of glassy polymer nanocomposites. J-Y. Lee, Q. Zhang, T. Emrick, A. J. Crosby Section Β McCormick Place South Room S504D, Level 5 Conjugated Oligomers and Polymers Molecular Electronics and Nanomaterials B. de Boer and A. Facchetti, Presiding
Organizers,
8:30 490. Modeling insights in organic elec tronics: Formalisms and results. M. A. Ratner 9:00 491. Designing, measuring and control ling molecular- and supramolecular-scale properties for molecular devices. P. S. Weiss 9:30 492. Facile synthesis, electronic and optical properties of regioregular head-totail oligothiazoles. L Gan, L. Yu 9:50 493. Polydiacetylene based monolayer field effect transistors. J. S. S. Jespher Daniel, J. C. Scott, C. T. Rettner, S. A. Swanson, K. Fujita, A. Y. Wong, C. J-H. Cho, G. G. Fuller, R. D. Miller 10:10 Intermission. 10:30 494. Self-assembly, characterization and conduction properties of oligomers in solid state junctions. D. L. Allara, T. S. Mayer, H. Yoon, M. Maitani, M. Cabassi, C. McGuiness, O. Cabarcos 11:00 495. Self-assembled monolayer and multilayer films for non-volatile memories and chemical sensors. M. Altman, T. Gupta, T. Zubkov, R. Cohen, M. E. van der Boom 11:30 496. Polymeric and molecular thin film modeling vs. experimental dielectric response. S. A. DiBenedetto, I. Paci, A. Facchetti, T. J. Marks, M. A. Ratner 11:50 497. Uniaxial optical and electronic properties of 1 -D nanomaterials fabricated from rigid, planar semiconductor mol ecules. L. Zang, J. S. Moore, M. Yen, K. Balakrishnan, J. Huang, A. Datar, X. Yang, T. Naddo Section C McCormick Place South Room S505A, Level 5 General Papers and New Concepts in Polymeric Materials New Materials D. Webster,
Organizer
J. W. Wackerly and M. S. Black,
Presiding
8:00 498. Electrospinning physical gels: The case of stereocomplex PMMA. M. Crne, J. O. Park, M. Srinivasarao 8:20 499. Immobilization of cofacially aligned porphyrins. Y. Lee, D-C. Lee, G. Morales, LYu 8:40 500. Systematic coarse-graining of a phase-separating polymer blend: Polyisoprene and polystyrene. Q. Sun, R. Faller
9:00 501. In-situ synthesis of single-layer white luminescent polymers for bright white light-emitting-diodes through plasma polymerization. C-C Chang, Y-H. Chang, Y-C. Chen, J-H. Jou, K-C. Hwang, C-M. Yang 9:20 502. Powder casting stabilization over colloid deposition for layer-by-layer assem bly. D. G. Abebe, T. R. Farhat 9:40 503. Dual cure mechanisms in the cationic photopolymerization of partially epoxidized soybean oil. M. S. Black, J. H. Whittemore IV, J. W. Rawlins 10:00 Intermission. 10:10 504. Influences of the compatibility between the polymer and its solvent on regular pattern formation by water droplets templating. S. Liu, Y. Tian, H. Ding, L Wang, B. Liu 10:30 505. Strongly interacting organic conjugated dendrimers for light harvesting and nonlinear optical applications. O. Varnavski, O. Mongin, M. Blanchard-Desce, T. Goodson III 10:50 506. Optimization of an implantable glucose sensor via layer-by-layer assem bly of outer diffusion limiting membrane. S. Vaddiraju, R. Tipnis, F. Jain, D. J. Burgess, F. Papadimitrakopoulos 11:10 507. Porous PPS membrane with high durability against solvents by a thermally induced phase separation method. H. Ding, Y. Tian, L Wang Sr., B. Liu 11:30 508. Preparation of ultrahigh molecular weight polyethylene membrane via ther mally induced phase separation method. H. Ding, Y. Tian, L Wang Sr., B. Liu 11:50 509. Responsive hydrogels as optical sensors. J. W. Wackerly, Ν. Η. Mack, V. Malyarchuck, J. A. Rogers, R. G. Nuzzo, J. S. Moore Polymer Surfaces and Interfaces General Topics Sponsored by POLY, Cosponsored with PMSE THURSDAY AFTERNOON Section A McCormick Place South Room S504B/C, Level 5 Polymer-Based Nanoparticles and Nanostructures S. Rowan,
Organizer
M. E. Mackay and A. L. Frischknecht, Organizers, Presiding 1:30 510. pH-responsive polymer microgel particles: Matrices for metal nanocrystals. M. Vamvakaki, D. Palioura, S. P. Armes, S. H. Anastasiadis 1:50 511. Iron tris(dibenzoylmethane-polylactide) nanoparticles. A. Pfister, J. Chen, Y. J. Chen, C. L Fraser 2:10 512. Multilayered polycarbonate/polyvinylidene fluoride films for high energy density capacitor applications. M. A. Wolak, M-J. Pan, M. MacKey, L Flandin, E. Baer, J. S. Shirk 2:30 513. Probing the structure of waterborne core-shell particles in pressuresensitive adhesives with atomic force microscopy. C-H. Lei, K. Ouzineb, O. Dupont, J. L. Keddie 2:50 514. Impact on glass transition tem perature of confinement in 1-D patterned polymer nanostructures. M. K. Mundra, S. Donthu, V. P. Dravid, J. M. Torkelson 3:10 515. Blocked diisocyanate incorporation into polystyrene nanospheres. H. Yang, S. K. Mendon, J. W. Rawlins 3:30 516. Monodisperse polymer-virus nano particles. J. Cornelissen, F. D. Sikkema, M. Comellas-Aragones, A. de la Escosura Navazo, B. J. M. Verduin, R. J. M. Nolte 3:50 517. Recognition induced polymeric nanocomposite: Control of shape, location, and function. H. Xu, R. Shenhar, R. Hong, S. Srivastava, V. M. Rotello 4:10 518. Block copolymer micelles in ionic liquids. C. Guerrero-Sanchez, D. Wouters, S. Hoeppener, J-F. Gohy, H. Thijs, R. Hoogenboom, U. S. Schubert
TECH-127
TECHNICAL PROGRAM
PMSE/PROF/SCHB 4:30 519. Arylene ethynylene macrocycles: Investigating the self-assembly and their respective binding with fullerenes - a new insight for development of opto-electronic devices. K. Balakrishnan, A. Datar, J. Huang, X. Yang, J. S. Moore, L Zang 4:50 Concluding Remarks.
Division of Professional Relations
Women Achieving Success: The ACS as a Platform in Leadership Development Sponsored by WCC, Cosponsored with PROF, and PRES
3:45 1. Working as a solo practitioner: Deal ing with professional and trade organiza tions. J. H. Lauterbach 4:45 Concluding Remarks.
TUESDAY AFTERNOON
Section A
C. J. Bannochie, Program Chair
Section A
Hyatt Regency McCormick 23A/B
SUNDAY AFTERNOON
Hyatt Regency McCormick 20A/B
PROF
Section Β McCormick Place South Room S504D, Level 5 Conjugated Oligomers and Polymers Molecular Electronics and Nanomaterials B. de Boer and A. Facchetti, Presiding
Organizers, S U N D A Y EVENING
1:30 520. Films of carbon nanotubes for polymer electronics. J. A. Rogers 2:00 521. High carrier density and metallic conductivity in organic semiconductors achieved by electrostatic charge injection. C. D. Frisbie 2:30 522. Ultra-thin layer-by-layer films with conjugated polyelectrolytes. C. Jiang, Y-H. Lin, J. Xu, Z. Lin, V. V. Tsukruk 2:50 523. Delocalized excitations in cyclic thiophenes. O. Vamavski, K. Hegadom, P. Bâuerle, T. Goodson III Section C
General Papers and New Concepts in Polymeric Materials Biomaterials D. Webster,
Organizer Presiding
1:00 524. Vegetable oil macromonomer swollen emulsions based on 2-(dimethylamino)ethyl methacrylate. G. Hao, G. Tregre, J. W. Rawlins 1:20 525. Glycoconjugates and their role in phagocytosis and destruction of B. cereus spores. O. Tarasenko, E. Burton, L. Soderberg, P. Alusta 1:40 526. Application of thermoplastic polyurethane/zinc oxide composite and visiblelight cured urethane-acrylate monomer in dental root canal material. K-H. Liao, J-L Han, C-P. Lin, K-H. Hsieh 2:00 527. Effect of ions on the thermodynamic properties of biopolymer gels. F. Horkay, P. J. Basser 2:20 528. Novel biocomposites from polylactide (PLA) and bamboo fibers. M. S. Huda, L T. Drzal, S. Sahoo, H. Hamada, M. Misra 2:40 529. Rubbery thermosets prepared by ring opening metathesis polymerization of a functionalized castor oil and cyclooctene. P. H. Henna, R. C. Larock 3:00 Intermission. 3:10 530. Optimizing the acid catalyzed synthesis of hyperbranched poly(glyceroldiacid) oligomers. V. T. Wyatt, A. Nunez, T. A. Foglia, W. N. Marmer 3:30 531. POSS-based photocured double networks as biodegradable shape memory polymers. K. M. Lee, T. Chung, P. T. Mather 3:50 532. Study of polyurethane materials immobilized with bioactive fungal polysaccharide derivatives. Y. Wang, W. Xu, H. Chen 4:10 533. In vitro release and in vivo biodistribution of paclitaxel from a chitosan-egg phosphatidylcholine implant system. P. Lim Soo, J. Grant, E. Ho, M. Mak, M. Piquette-Miller, C. Allen 4:30 534. DNA degradation in transient extensional flow by transient extension and hydrodynamic shear. M. Sun, W. Ng, A. E. Barron 4:50 535. Electrospun poly(L-lactic acid)/ multiwalled carbon nanotubes/hydroxyapatite nanofibrous membranes for guided tissue regeneration. S. Wu, X. Yang, X. Deng
128-TECH
Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with PROF, YCC, and PRES MONDAY MORNING Section A Hyatt Regency McCormick 21C Benefit Trends for the Chemical Workforce Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC J. Bingham and K. Siam,
McCormick Place South Room S505A, Level 5
V. T. Wyatt and P. Henna,
Starting a Successful Research Program at a Predominantly Undergraduate Institution Sponsored by YCC, Cosponsored with Council on Undergraduate Research, CHED, and PROF
Organizers
8:30 Introductory Remarks. 8:35 1. National trends in employee benefits. W. J. Wiatrowski 9:05 2. Benefit trends in the chemistry workforce. D. R. Webb 9:35 3. Trends in HR benefits. J. Doran 10:05 Intermission. 10:20 4. Benefits at small chemical companies. R. J. Versic 10:50 5. Benefits at large chemical companies. C. Todd 11:20 6. ACS member insurance program. J. Parr 11:50 Concluding Remarks. Career Experiences at the Interface of Chemistry and Biology Sponsored by YCC, Cosponsored with WCC, and PROF Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES MONDAY AFTERNOON Chemistry Pedagogy 101 Sponsored by YCC, Cosponsored with CHED, and PROF Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES M O N D A Y EVENING Section A
Ethics for the Chemical Professional Cosponsored with Committee on Ethics, and CEPA D. J. Chesney,
Organizer
1:00 Introductory Remarks. 1:05 10. Ethics in sports officiating. K. Vitense 1:35 11. Ethical case studies I: A problem solving approach. T. R. LeBon 2:05 12. Academic ethical case studies: Gender issues. S. M. Schelble 2:35 13. Ethical case studies II: A problem solving approach. T. R. LeBon 3:05 Intermission. 3:20 14. Postcards from the edge. J. P. Stoner 3:50 15. Professional ethics: A comparison of scientific societies and organizations. D. J. Chesney Women Achieving Success: The ACS as a Platform in Leadership Development Sponsored by WCC, Cosponsored with PROF, and PRES WEDNESDAY MORNING Hog Butchers, Tool Makers, and Stackers of Wheat: Chicago-Area Chemical Industry and Government-Sponsored Laboratories Sponsored by HIST, Cosponsored with ACS Chicago Section, l&EC, PROF, and SCHB WEDNESDAY AFTERNOON Educating the Laughing, Stormy, Husky Youth of the Midwest: Chicago-Area Colleges and Universities Sponsored by HIST, Cosponsored with ACS Chicago Section, PROF, and CHED
SGHB Division of Small Chemical Businesses P. J. Bonk and J. H. Lauterbach, Program Chairs
Single Interest Group (SIG) Topics: Business Start Ups and Consulting Business Start Ups Cosponsored with CEPA S. Shah,
Organizer
2:25 Introductory Remarks. 2:30 2. The what, why and how of business financing. S. Shah 3:30 Concluding Remarks. MONDAY MORNING Section A Hyatt Regency McCormick 23A/B Interfacing Big Pharma with Emerging Technologies Cosponsored with Brinks, Hofer, Gilson & Lione: IP Law Worldwide M. Lefenfeld,
8:35 4. How to get a fair shake from pharma. P. Karabatsos 9:05 5. Investing in emerging technologies: Harris & Harris Group's approach. D. B. Wolfe 9:35 Intermission. 9:45 6. Advancing R&D through moderniza tion of software platforms. F. Brown 10:15 7. Chemistry innovation at SigmaAldrich. C. D. Hewitt 10:45 8. Application of emerging technolo gies in pharmaceutical process research and development: Safe and efficient alter native to alkali metals. B. Gorin, K. Nguyen, A. Q. Lu 11:15 9. New products for chiral chemistry based on a novel nanotechnology approach. R. Valluzzi 11:45 Concluding Remarks. Benefit Trends for the Chemical Workforce Sponsored by PROF, Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC MONDAY AFTERNOON
SOCIAL EVENTS: Executive Committee: Sun Reception: Mon Social Hour: Tue
Hyatt Regency Chicago Riverside Center
SUNDAY AFTERNOON
Sci-Mix
Section A
Hyatt Regency McCormick 23A/B Interfacing Big Pharma with Emerging Technologies Cosponsored with Brinks, Hofer, Gilson & Lione: IP Law Worldwide M. Lefenfeld,
C. J . Bannochie,
Organizer
8:00-10:00 7. A new vision for the Division of Professional Relations. C. J. Bannochie, B. E. Moriarty 8. Globalization and what this means to us. Β. Ε. Moriarty 9. Developing soft skills provides career options. J. K. Borchardt 15. See subsequent listings.
Hyatt Regency McCormick 23A/B Single Interest Group (SIG) Topics: Business Start Ups and Consulting Consulting Cosponsored with CEPA S. Shah,
Organizer
3:40 Introductory Remarks.
TUESDAY MORNING General Papers Pertaining to Management of the Chemical Enterprise Sponsored by BMGT, Cosponsored with PROF
Organizer
8:00 Introductory Remarks. 8:05 3. How to be David against Goliath: Competing with pharma on a shoestring budget. K. S. Mrksich
Please refrain from using cellular telephones and cameras during technical sessions.
Organizer
1:15 Introductory Remarks. 1:20 10. Biotechnological applications of cell membrane-coated colloids. J. T. Groves 1:50 11. Simulated moving bed chromatogra phy for chiral separations in the pharma ceutical industry. D. J. Coughlin 2:20 12. Positioning for success in licensing. R. Carpenter 2:50 13. Systanix: From classroom to board room. D. T. McQuade 3:20 Intermission. 3:30 14. New stabilized alkali metals and their derivatives for pharmaceutical synthe sis. M. Lefenfeld, J. L. Dye, R. A. Fisher 4:00 15. Modeling and simulations in phar maceutical industry: A materials science perspective. M. Petersen 4:30 16. Identifying technologies to fill the green toolbox. J. B. Manley, B. W. Cue Jr. 5:00 Concluding Remarks.
SGHB/BTEC/GATL/MTLS/GHi/CEPA/CEl Beyond the Bench: Non-Traditional Careers in Chemistry Sponsored by CHAL, Cosponsored with CHED, CINF, SCHB, WCC, and YCC TUESDAY MORNING
Catalysis & Surface Science Secretariat
M O N D A Y EVENING Catalysis Posters Sponsored by COLL, Cosponsored with CATL
MONDAY MORNING
Hyatt Regency McCormick 23A/B
Section A
Safety and Health Issues at Small Chemical Businesses Cosponsored with Chemical Safety Board, and CHAS J. Jones and P. J . Bonk,
Organizers
8:00 Introductory Remarks. 8:05 17. U.S. Chemical Safety Board: Les sons learned and hazard recognition at chemical businesses. C. W. Merritt 8:50 18. Health and safety plans for small business. C. Marlowe 9:20 19. Chemical Safety Manual for Small Businesses. K. P. Fivizzani 9:50 20. Green chemistry prevents chemical accidents. J. L. Young, D. Hammond, P. T. Anastas 10:20 Intermission. 10:30 2 1 . Chemical Homeland Security System. G. R. Thompson 11:00 22. Identifying reactive hazards: Case studies. N. Langerman 11:30 23. Withdrawn. 12:00 Panel Discussion. From Lab to Market: Protecting and Commercializing New Knowledge Sponsored by CHAL, Cosponsored with BMGT, and SCHB TUESDAY AFTERNOON Section A Hyatt Regency McCormick 23A/B Best Steps for the Chemical Entrepreneur
Hyatt Regency McCormick 21 A/B
From Lab to Market: Protecting and Commercializing New Knowledge Sponsored by CHAL, Cosponsored with BMGT, and SCHB WEDNESDAY MORNING Hog Butchers, Tool Makers, and Stackers of Wheat: Chicago-Area Chemical Industry and Government-Sponsored Laboratories Sponsored by HIST, Cosponsored with ACS Chicago Section, l&EC, PROF, and SCHB
BTEC Biotechnology Secretariat J . Fin ley, Secretary
General
WEDNESDAY MORNING Advanced Mining and Use of Life Science Information Sponsored by CINF, Cosponsored with CSA Trust, BIOT, BTEC, MEDI, and COMP
General
Catalysts for Biorenewable Energy Applications Cosponsored with COLL, l&EC, PETR
TUESDAY MORNING
V. S-Y. Lin,
The Priestley Medal: Symposium in Honor of George M. Whitesides Sponsored by COLL, Cosponsored with MTLS
Organizer
8:30 Introductory Remarks. 8:35 1. Renewable fuels: New opportunities for catalysis and process research. L. E. Manzer 9:15 2. Catalytic cracking of cellulose. A. Fukuoka 9:45 3. New homogeneous catalysts for selective deoxygenations of sugar polyols to polymer precursors and fine chemicals: Motivation, strategies, challenges and catalyst design. M. Schlaf, R. Dykeman, K. Luska, M. Thibault, Ζ. Xie 10:15 Intermission. 10:30 4. Conversion of biomass-derived syngas to alcohols and C2 oxygenates using supported Rh catalysts in a microchannel reactor. J . Hu, Y. Wang, C. Cao, D. C. Elliott, D. J. Stevens, J. F. White 11:00 5. Investigation of functionaiized mesoporous carbons as heterogeneous catalyst for biodiesel production. C. Liang, S. Dai, N. S. Chong, V. S-Y. Lin 11:30 6. Modified plant oils as drying oils for linseed oil replacement in inks and alkyd resins. J. G. Verkade
CHI Chicago Local Section B. E. Morlarty, Program Chair
Section A
Catalysts for Biorenewable Energy Applications Surface Chemistry Cosponsored with COLL, l&EC, PETR V. S-Y. Lin,
SUNDAY MORNING Sustainability and Chemical Education: Industry's Perspective Sponsored by CHED, Cosponsored with l&EC, CEI, and SUST MONDAY MORNING Sustainability and Chemistry: Tomorrow's Challenge for Today's Students Sponsored by SOCED, Cosponsored with SOCED, CEI, PRES, and SUST
Hog Butchers, Tool Makers, and Stackers of Wheat: Chicago-Area Chemical Industry and Government-Sponsored Laboratories Sponsored by HIST, Cosponsored with ACS Chicago Section, l&EC, PROF, and SCHB
Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Health and Regulatory Concerns of DBPs and Analytical Methods Sponsored by ENVR, Cosponsored with CEI, and SUST
WEDNESDAY AFTERNOON
TUESDAY AFTERNOON
Educating the Laughing, Stormy, Husky Youth of the Midwest: Chicago-Area Colleges and Universities Sponsored by HIST, Cosponsored with ACS Chicago Section, PROF, and CHED
Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Reactivity of NOM toward DBP Formation Sponsored by ENVR, Cosponsored with CEI, and SUST
Committee on Economic & Professional Affairs S. C. Waller, Program Chair
Organizer
1:30 7. Nanostructured catalysts: Where materials science meets catalysis. C. E. Barnes, R. T. Mayes, M-Y. Lee, G. T. Eldridge, J. Clark 1:50 8. Gold nanoparticle catalyzed aerobic oxidation of alcohols. E. Taarning, C. H. Christensen, K. Egeblad, B. Jorgensen, R. Madsen 2:10 9. Gold catalysis: A theoretical approach. H. Falsig, B. H. Larsen, T. Bligaard, C. H. Christensen, J. K. Norskov 2:30 10. Ni-olivine catalysts for tar removal in hydorgen-rich streams. J. Kuhn, Z. Zhao, U. S. Ozkan, L Felix, R. Slimane 2:50 11. Surface chemistry of iron oxide and gold modified iron oxide thin films. P. R. Davies, A. F. Carley, S. Saipanya, B. Lewis 3:10 12. Hydrogen generation via steam reforming of acetic acid over bimetallic catalyst. G. Lu 3:30 13. Single-step synthesis of highly ordered metal/porous support nanocomposite catalyst materials in mixed surfac tant mesophase. J. Sarkar, A. Bose, C. J. Brooks, G. Ramanath, V. T. John 3:50 14. Effects of precursors on the surface Mn species and SCR activities of MnOX/ Ti02 catalysts. J. Chen, J. Li, C. Luo 4:10 15. X-ray photoelectron spectrocopy of RDX on Si(110): Evidence for a new form of RDX. M. Gonzalez, S. P. Hernandez, M. E. Castro 4:30 16. Ab-initio simulations of the mechan ics, electron transport and chemical reac tivity of metal nanowires. J. A. Torres 4:50 17. Kinetics of oxidation of amino acids by N-bromophthalimide in the presence of surfactants in perchloric acid medium. A. K. Singh, G. K. Joshi, Y. R. Katre
E. Warren, Program Chair
TUESDAY MORNING
CEPA
Hyatt Regency McCormick 21 A/B
Committee on Environmental Improvement
WEDNESDAY MORNING
MONDAY AFTERNOON
Organizer
2:00 Introductory Remarks. 2:10 24. Best steps for the chemical entre preneur. G. Arnold, J. Agiato, I. Barash, M. Lessman-Katz, S. Shah, E. H. Wagener 3:10 Intermission. 3:20 25. Best steps for the chemical entre preneur: Part two. G. Arnold, J. Agiato, I. Barash, M. Lessman-Katz, S. Shah, Ε. Η. Wagener 4:20 Concluding Remarks.
Materials Chemistry Secretariat S. H. Foulger, Secretary
Ethics for the Chemical Professional Sponsored by PROF, Cosponsored with Committee on Ethics, and CEPA
(SU
MTLS
Section A
G. Arnold,
CATL
SUNDAY AFTERNOON Single Interest Group (SIG) Topics: Business Start Ups and Consulting Consulting Sponsored by SCHB, Cosponsored with CEPA
WEDNESDAY MORNING Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Probing Formation of DBPs Sponsored by ENVR, Cosponsored with CEI, and SUST WEDNESDAY AFTERNOON Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation and Control of Regulated DBPs Sponsored by ENVR, Cosponsored with CEI, and SUST W E D N E S D A Y EVENING
Single Interest Group (SIG) Topics: Business Start Ups and Consulting Business Start Ups Sponsored by SCHB, Cosponsored with CEPA MONDAY MORNING Benefit Trends for the Chemical Workforce Sponsored by PROF, Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC TUESDAY AFTERNOON Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Sponsored by PRES, Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT
Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Poster Session Sponsored by ENVR, Cosponsored with CEI, and SUST THURSDAY MORNING New Energy Technology Low Energy Nuclear Transmutation Sponsored by ENVR, Cosponsored with CEI Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water Formation, Fate, and Control of Nitrosamines Sponsored by ENVR, Cosponsored with CEI, and SUST THURSDAY AFTERNOON New Energy Technology Sponsored by ENVR, Cosponsored with CEI
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
Occurrence, Formation, Health Effects and Control of Disinfection By-Products in Drinking Water DBP Issues in Distribution Systems Sponsored by ENVR, Cosponsored with CEI, and SUST
TECH-129
ETHC/CMA/COMSCI/CPT/CA/IAC/SOCED/WCG
ETHC
I
Committee on Ethics M . A . C a v a n a u g h , Program
Chair
Τ ΕC Η ΝIC A L P RO G RA M Section A
Development and Implementation of Learning Objectives in Chemistry Departments: A View of Progress at a Myriad of Institutions Sponsored by CHED, Cosponsored with CPT
The Westin Michigan Avenue Consort
TUESDAY AFTERNOON Ethics for the Chemical Professional Sponsored by PROF, Cosponsored with CEPA, and ETHC
Committee on Minority Affairs L. M . W a t k i n s , Program
CA
Chair
Corporation Associates Chair
Benefits Trends for the Chemical Workforce Sponsored by PROF, Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC
IAC International Activities Committee
MONDAY MORNING N . I. M c C l e l l a n d , Program Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP MONDAY AFTERNOON Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
Chair
9:00 Introductory Remarks. 9:05 5. Sustainability and chemistry: Tomor row's challenge for today's students. M. A. Fisher 9:55 Concluding Remarks. Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP Undergraduate Research Poster Session: Analytical Chemistry Sponsored by CHED, Cosponsored with SOCED, and ANYL Undergraduate Research Poster Session: Chemical Education Sponsored by CHED, Cosponsored with SOCED Undergraduate Research Poster Session: Polymer Chemistry Sponsored by CHED, Cosponsored with SOCED, POLY, and PMSE
TUESDAY AFTERNOON
MONDAY AFTERNOON
Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Sponsored by PRES, Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT
Section A The Westin Michigan Avenue Consort Undergraduate Eminent Scientist Lecture Featuring Omar Yaghi
WEDNESDAY AFTERNOON
M. A. Benvenuto,
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
5:00 Introductory Remarks. 5:05 6. Pores without walls for clean energy. Ο. Μ. Yaghi 5:55 Concluding Remarks.
B. B a l a z s a n d J . L. W e s e m a n n ,
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Committee on Science C . W . R i b e s , Program
Society Committee on Education
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Chairs
SUNDAY AFTERNOON Section A The Westin Michigan Avenue Consort
TUESDAY MORNING The Evolving Network of Scientific Communication Sponsored by CINF, Cosponsored with COMSCI
Automotive Chemistry: More Than Just the Tail Pipe Cosponsored with ENVR, FUEL, and PETR
TUESDAY AFTERNOON M. A. Benvenuto, Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Sponsored by PRES, Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT The Evolving Network of Scientific Communication Sponsored by CINF, Cosponsored with COMSCI
Organizer
2:00 Introductory Remarks. 2:05 1. Chemist role in automotive design. H. K. Phlegm 2:30 2. Atmospheric science in the auto industry. M. Hurley 2:55 Concluding Remarks.
Organizer
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP Undergraduate Research Poster Session: Biochemistry Sponsored by CHED, Cosponsored with SOCED, BIOL, and BIOT Undergraduate Research Poster Session: Environmental Chemistry Sponsored by CHED, Cosponsored with SOCED, and ENVR Undergraduate Research Poster Session: Inorganic Chemistry Sponsored by CHED, Cosponsored with SOCED WEDNESDAY AFTERNOON Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
The Westin Michigan Avenue Consort
Committee on Professional Training W . F. P o l i k , Program
TUESDAY AFTERNOON Benchmarking the Research Competitiveness of U.S. Chemistry and Chemical Engineering Sponsored by PRES, Cosponsored with International Activities Committee, CHED, CEPA, COMSCI, and CPT
130-TECH
10:00 Introductory Remarks. 10:05 3. Automotive coatings. L. N. Price 10:30 4. Characterization of perfluorinated sulfonic acid membranes for PEM fuel cells. C. Hayden, K. Olson, T. Xie, D. Eckel, J. Healy, J. Abbott, G. Ye, G. Goward 10:55 Concluding Remarks.
SOCIAL E V E N T S : WCC 80th Anniversary Reception: Sat WCC Luncheon: Tue Women and Industry Breakfast: Mon BUSINESS M E E T I N G S : Executive Committee Meeting: Sat Open Meeting: Sat SUNDAY MORNING Community College Led Advances in Undergraduate Education Sponsored by CHED, Cosponsored with CMA, WCC, and YCC Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin Sponsored by COMP, Cosponsored with CINF, and WCC High School Teachers Program: Inquiring Minds Want to Know Sponsored by CHED, Cosponsored with WCC Young Scientist Pre- and Post-Doctoral Research Award Symposium Sponsored by AGRO, Cosponsored with WCC SUNDAY AFTERNOON ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Sponsored by COMP, Cosponsored with WCC Computer Assisted Drug Design: Reminiscing about the Future, A Symposium Honoring Yvonne C. Martin Sponsored by CINF, Cosponsored with COMP, and WCC High School Teachers Program: Inquiring Minds Want to Know Sponsored by CHED, Cosponsored with WCC Young Scientist Pre- and Post-Doctoral Research Award Symposium Sponsored by AGRO, Cosponsored with WCC MONDAY MORNING ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Sponsored by COMP, Cosponsored with WCC ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu Next Generation Product R&D: Science and Engineering Sponsored by BMGT, Cosponsored with PMSE, and WCC
Career Experiences at the Interface of Chemistry and Biology Sponsored by YCC, Cosponsored with WCC, and PROF
Chair Organizer
Chairs
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
Automotive Chemistry: More Than Just the Tail Pipe Cosponsored with ENVR, FUEL, and PETR M. A. Benvenuto,
R. D. L i b b y , J . M . I r i a r t e - G r o s s , a n d A . S . H i n k l e , Program
Benefit Trends for the Chemical Workforce Sponsored by PROF, Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC
MONDAY MORNING Section A
OPT
Women Chemists Committee
Organizer
MONDAY MORNING
SUNDAY MORNING Community College Led Advances in Undergraduate Education Sponsored by CHED, Cosponsored with CMA, WCC, and YCC
Sustainability and Chemistry: Tomorrow's Challenge for Today's Students Cosponsored with SOCED, CEI, PRES, and SUST J. L. W e s e m a n n ,
L. W . M c Q u i r e , Program
CMA
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THURSDAY MORNING
Photographing or recording meeting sessions and/or activities other than your own are prohibited at all official ACS events without written consent from ACS.
MONDAY AFTERNOON ACS Award in Industrial Chemistry: Symposium in Honor of Margaret M. Wu
WCC/YCC Next Generation Product R&D: Science and Engineering Sponsored by BMGT, Cosponsored with PMSE, and WCC
Molecular Recognition and Drug Delivery Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR
SUNDAY AFTERNOON
Beyond the Bench: Non-Traditional Careers in Chemistry Sponsored by CHAL, Cosponsored with CHED, CINF, SCHB, WCC, and YCC
WEDNESDAY MORNING
Hyatt Regency McCormick 24A
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP Exploring and Exploiting Nature with Biomimetics Biomolecular Self-assembly and Biocatalysis Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR TUESDAY MORNING Section A Sheraton Chicago Chicago Ballroom IX Women Achieving Success: The ACS as a Platform in Leadership Development Cosponsored with PROF, and PRES J. Cohen,
Organizer
9:00 Introductory Remarks. 9:05 1. Volunteering for positive change. A. S. Hinkle 9:35 2. The value of professional service. C. Erwin 10:05 3. Expanding your competencies through involvement in ACS. C. Ribes 10:35 16. Developing leaders, from handson-experience to leadership training pro grams. M. G. Chan 11:05 Concluding Remarks. ACS Award for Computers in Chemical and Pharmaceutical Research: Symposium in Honor of Emily A. Carter Sponsored by COMP, Cosponsored with WCC Exploring and Exploiting Nature with Biomimetics Rational Manipulation of Biomolecular Architecture Sponsored by CHED, Cosponsored with WCC, BIOL, and INOR TUESDAY AFTERNOON
Sheraton Chicago Chicago Ballroom IX Women Achieving Success: The ACS as a Platform in Leadership Development Cosponsored with PROF, and PRES J. Cohen,
Organizer
2:00 Introductory Remarks. 2:05 4. Leading by example: Madeleine Joullie the ultimate mentor. E. A. Nalley 2:40 5. What makes for an effective female leader? Ν. Β. Jackson 3:15 6. Leadership development within the Organic Division of ACS. C. A. Maryanoff 3:50 8. Collaboration and materials chemistry for electronics. E. Reichmanis 4:25 7. The characteristics of highly success ful women scientists. M. Jacobs 5:00 Concluding Remarks. Exploring and Exploiting Nature with Biomimetics
Benefit Trends for the Chemical Workforce Sponsored by PROF, Cosponsored with Corporation Associates, CEPA, SCHB, WCC, and YCC
Section A
Section A Sheraton Chicago Chicago Ballroom IX ACS Award for Encouraging Women into Careers in the Chemical Sciences: Symposium in Honor of Bojan H. Jennings Cosponsored with CHED S. T. Purrington,
Organizer
8:55 Introductory Remarks. 9:00 9. Bojan Jennings' contribution to my career in science education. B-J. Janes 9:20 10. Tools for encouraging women in chemistry. S. R. Epstein 9:40 11. On the junction between chemistry and mechanics applied to concrete. H. M. Jennings 10:00 12. Molecules and masterpieces. L. J. Muller 10:20 Intermission. 10:35 13. Bojan Jennings: Teacher and life-long mentor. S. J. Filak 10:55 14. Divalent metal cations support the folding of metalloproteins. E. Pastra-Landis 11:15 15. Preparing and retaining future scientists through a unique laboratory experience. D. S. Amenta 11:35 Concluding Remarks. ACS Award for Research at an Undergraduate Institution: Symposium in Honor of Cheryl D. Stevenson Sponsored by ORGN, Cosponsored with WCC Francis P. Garvan-John M. Olin Medal: Symposium in Honor of Laura L. Kiessling Sponsored by ORGN, Cosponsored with WCC
Starting a Successful Research Program at a Predominantly Undergraduate Institution Cosponsored with Council on Undergraduate Research, CHED, and PROF M. D. Schuh,
Organizer
1:00 Introductory Remarks. 1:05 1. What is undergraduate research and why do research at a predominantly undergraduate institution? T. J. Wenzel 1:15 2. What type of research should a new faculty member pursue? K. K. Karukstis 1:25 3. Selection of and working with under graduates. Κ. Κ. Karukstis 1:35 4. Establishing and enhancing an insti tutional environment. J. C. de Paula 1:50 5. Art and necessity of gaining internal support from institutional administrators. M. L. Druelinger 2:05 6. Life in academia: Myths, reality and mentoring. L. Winfield 2:20 Discussion. 3:00 Intermission. 3:15 Session Remarks. 3:20 7. Research Corporation opportunities in the physical sciences. S. Ronco 3:40 8. Funding opportunities at the NSF for faculty at predominantly undergraduate institutions (PUIs). C. D. Pibel 4:00 9. Writing more competitive grant pro posals. T. J. Wenzel 4:20 Panel Discussion. S U N D A Y EVENING Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with PROF, YCC, and PRES MONDAY MORNING Section A
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
YCC Younger Chemists Committee A. C. Myers and M. Jeffries-EL, Program Chairs
SOCIAL EVENT: Reception: Sun BUSINESS M E E T I N G : Open Meeting: Sun SUNDAY MORNING Community College Led Advances in Undergraduate Education Sponsored by CHED, Cosponsored with CMA, WCC, and YCC
Hyatt Regency McCormick 24A/B Career Experiences at the Interface of Chemistry and Biology Cosponsored with WCC, and PROF D. Levy and A. Mahapatro,
Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES MONDAY AFTERNOON Section A Hyatt Regency McCormick 24A/B Chemistry Pedagogy 101 Cosponsored with CHED, and PROF R. E. Forslund, S. Pazicni, and G. Thomas, Organizers 1:30 Introductory Remarks. 1:35 18. Adopting ACS Exams as part of your assessment strategies for teaching. T. Holme, K. Murphy 1:55 19. Engaging students in lecture with clickers. D. Bunce 2:15 20. Make LeChatelier your companion: Reflections of a first-year college faculty member. P. L. Daubenmire 2:35 2 1 . POGIL: A student-centered approach to classroom instruction. R. S. Moog 2:55 Discussion. 3:15 Concluding Remarks. Beyond the Bench: Non-Traditional Careers in Chemistry Sponsored by CHAL, Cosponsored with CHED, CINF, SCHB, WCC, and YCC Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
WEDNESDAY AFTERNOON ACS Award for Encouraging Disadvantaged Students into Careers in the Chemical Sciences: Symposium in Honor of Robyn E. Hannigan Sponsored by GEOC, Cosponsored with WCC
Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
Organizers
8:30 Introductory Remarks. 8:35 10. From beta-peptides to peptide nucleic acids: Development of non-natural oligomers. D. H. Appella 8:55 1 1 . Choices, choices: Impact of crosstraining in biology on an early medicinal chemistry career in the biotech and phar maceutical industries. K. H. Mortell 9:15 12. Rural upbringing to urban chemistry: Experiences at the interface. M. B. Steffensen 9:35 13. From the bench to the bar: Oppor tunities at the interface of chemistry, biol ogy and law. J. I. Wasserman 9:55 Intermission. 10:10 14. Membrane proteins at the inter face. L. Columbus 10:30 15. From specialist to generalist. L. E. Strong 10:50 16. Nanobiotechnology at the interface of chemistry and biology. N. O. Fischer 11:10 17. Getting away from the bench: An editor's perspective. C. M. Goodman, T. L. Sheppard 11:30 Panel Discussion. 11:50 Concluding Remarks.
Excellence in Graduate Polymer Science Research Symposium Sponsored by POLY, Cosponsored with YCC, PROF, and PRES WEDNESDAY AFTERNOON Broadening Participation in Undergraduate Research Sponsored by CHED, Cosponsored with CMA, WCC, YCC, SOCED, and COMP
The official technical program for the 233rd National Meeting is available online at oasys2.confex.com/acs/233nm/ techprogram/.
TEGH-131
